CN1262883C - 影印用于平版印刷工艺中的自动化液体分配的方法和系统 - Google Patents
影印用于平版印刷工艺中的自动化液体分配的方法和系统 Download PDFInfo
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Abstract
公开了一种在平版印刷过程中用于在平坦材料的表面,或包括半导体晶片的基片上分配液体的自动化液体分配方法和系统。该分配方法使用可以在液体分配器尖端和基片之间产生相对横向运动的液体分配器和基片台。还描述了一种用于使用基本上无图案的平坦模板在基片上创建平坦表面的方法和装置。
Description
发明背景
发明领域
本发明涉及可用于平版印刷工艺中的自动化液体分配方法和系统。
相关技术的描述
平版印刷是能够在基片上印刷尺寸小于50nm的特征的技术。平版印刷具有取代光刻作为用于在100nm以下的区间上制造半导体的一个选择。在九十年代已经引入了几种平版印刷工艺。然而,它们中的大多数都有局限性,使得它们不能真正替代光刻。这些现有技术的局限包括,例如高温变异,需要高压和使用弹性模板。
近年来,平版印刷工艺可用来在室温和低压的条件下,从石英模板上将高分辨率图案转印到基片表面。在Step和Flash平版印刷(SFIL)工艺中,在光固化液体材料存在的情况下,将刚性石英模板与基片表面间接接触。通过使用光将该液体材料固化并将模板上的图案印刷到固化的液体上。
使用刚性和透明模板可以实施作为SFIL工艺的一部分的高分辨率重叠。同时,应用可在低压和室温条件下通过光固化工艺的低粘性液体材料产生最小化的不希望的层变形。这种变形可导致重叠对齐难以实施。
气泡和局部化变形是引起平版印刷制造的装置中大多数缺陷的原因。用于这些印刷过程中的印刷压力可引起扭曲使得重叠对齐极端困难。用于平版印刷过程中的以亚100纳米级的小面积和液体体积使得这种体积的应用对于成功进行平版印刷来说很重要。
在基片上添加液体薄层的现有技术包括使用旋转涂层方法。旋转涂层方法依赖于将相对高粘度(例如大于大约20厘泊(cps))的液体应用在基片上。高粘度液体的使用允许使液体均匀地分配在光可固化组合物中,该组合物是在光存在时能够进行化学反应的组合物。可诱导化学反应的光包括紫外光(例如具有大约300nm到大约400nm波长的光)、有光化性的光、可见光、红外光和诸如电子束和X线源的辐射源。可以用很多形式证明化学变化。化学变化可包括,但不限于引起聚合发生的任何化学反应。在一些实施方案中,化学变化引起形成透镜组合物内引发剂种类的形成,所述引发剂种类能够引发化学聚合反应。
在一个实施方案中,光可固化组合物可以是光阻组合物。光阻组合物包括暴露于UV光下可固化的任何组合物。光阻组合物的特征在于仅有暴露于光(例如紫外光)下的组合物部分可进行光化学反应。通常用于半导体工业的各种光阻组合物都可以使用。在一个实施方案中,光可固化组合物包括酰化单体。
在大多数光刻工艺中,光阻材料典型的具有高粘性(大于大约20厘泊(cps))。在平版印刷中,使用高粘性液体使得很难产生100nm以下的结构。已经发现,低粘性液体产生100nm以下结构的精确的多的复制品。在一个实施方案中,光可固化液体可具有低于大约20cps,优选低于大约10cps,更优选低于大约5cps的粘度。
在将光可固化液体应用到基片上后,将图案模板定向到其上应用有光可固化液体的基片的部分上。在半导体工艺中,可以在单一基片上形成多个半导体装置。每单个半导体装置可以由多层形成。这些层可以在前面重叠形成的层上顺序形成层。由于半导体装置的单个元件小的形体尺寸,每一层与其它层的对齐对于半导体装置的适当功能来说十分关键。在固化前,模板和基片可适当地对齐,以确保新形成的层与下面的层匹配。
在完成模板和基片的对齐之后,可以完成加工。可以将固化光应用到光可固化液体上。固化光引起液体至少部分固化。在液体至少部分固化之后,可以将模板取出,这时固化的液体将包括与蚀刻到模板上的图案互补的结构。
可以通过各种方法将光可固化液体应用到基片上。在一个实施方案中,可以将液体分配器连接到平版印刷装置的顶部框架上。可以构建液体分配器以分配光可固化液体到基片上。可以使用的液体分配器的例子包括,但不限于:基于置换的液体分配器、微螺线管液体分配器和压电促动的液体分配器。通过液体分配器以预定图案可以将液体应用到基片上。预定图案可以是线、多条线或小点图案。
在一个实施方案中,可以将液体分配器连接到平版印刷装置的框架上。可以将基片安装在位于定向台下方的基片台上。可以构建基片台以可控制地在基本上平行于模板的平面上移动。通过相对于液体分配器移动基片可以将光可固化液体应用到基片上,并控制添加到基片上的液体的量。以这种方式,可以以多种图案将液体添加到基片上。可以预定这种图案以消除或最小化模板和基片之间形成气泡或穴。在使用时,当模板靠近基片定位时,可以分配液体以填满模板和基片间的间隙。在填充间隙时,随着液体填充间隙可出现气泡或穴。气泡或穴的形成是由于图案,在填充间隙前液体形成闭合环路。在一些实施方案中,可以预定图案,使得可以避免形成闭合环路的情况。可以用于最小化气泡和穴形成的图案包括正弦曲线图案、X图案和包括多个液体小滴的图案。
平版印刷工艺可用于在基片上创建平面。这里所用的平面性是由基片表面的曲率变化所限定。例如,1微米的平面性指的是表面的曲率变化为限定平面的中心点的上和/或下1微米。在一个实施方案中,可以使用无图案的基本上平的模板来创建基片上的平坦的固化层。平坦的模板可具有多个小于大约500纳米。为了使表面平坦,可以在基片上放置光可固化液体。可以使无图案的基本上平坦的模板与液体接触。通过使固化光导向光可固化液体,可以在基片表面形成平坦的固化液体层。
当有或无图案的模板与基片表面上的液体接触时,液体会在模板上施加变形力。这种力会引起模板以一种会改变所需要的印刷特征的方式发生变形。在一些实施方案中,可以使用这种变形力自我校正模板和基片之间的位置。在大多数实施方案中,需要模板与基片平行。由于基片和模板的表面上都包括多个不规则特征,这里所用的“平行定向”是指中线(即,通过模板或基片的中心所画的实线)彼此平行。在一些实施方案中,这里公开的装置可用于相对于基片以基本上平行的布置来定位模板。这些装置可包括促动器和允许相对于表面准确定位模板的柔性元件。
在另一个实施方案中,用于相对于基片定位模板的装置可包括设计在装置中的预定柔性。例如,可以构建柔性元件以相应施加到模板上的压力来移动。当模板靠近基片定位时,液体对抗模板的压力可引起柔性元件移动。通过控制液体的图案和柔性臂允许的移动量,模板可“自我校正”到基本上平行定向。液体对抗模板的力可引起模板围绕由柔性元件的移动限定的支点而运动。
这里公开的技术可用于多种装置。例如,可以生产半导体装置。半导体装置可包括至少一些具有横向尺寸小于大约200纳米,优选小于大约100纳米的特征。通过在半导体基片上形成印刷的光阻层和使用该印刷的光阻层作为掩模在半导体基片上形成图案可形成这种特征。可以从平版印刷工艺中形成的具有尺寸小于大约250纳米的特征的其它装置包括光电装置、生物装置、MEMS装置、光子装置、表面声波装置、微流体装置和微型光学装置。
附图说明
在阅读下列详细描述和参考伴随的附图之后,本发明的其它目的和优点会变得更加明显,其中:
图1A和1B描绘模板和基片之间的缝隙的横截面图;
图2A-2E描绘平版印刷处理的横截面图;
图3描绘示出平版印刷处理的步骤序列的处理流程图;
图4描绘根据第一实施方案用于形成平版印刷模板处理的横截面图;
图5描绘根据第二实施方案用于形成平版印刷模板处理的横截面图;
图6描绘将可校正的流施加到基片处理的顶视图;
图7描绘用于在平版印刷处理期间分发流的设备的示意图;
图8描绘用于平版印刷处理的流分发图案;
图9描绘包括在基片上的多个滴的流图案;
图10描绘用于在平版印刷处理期间分发流的另一设备的示意图;
图11描绘包括多条实际上是平行的线的流图案;
图12描绘定向台的投影图;
图13描绘组装以进行利用的第一和第二柔性元件;
图14描绘柔性臂的概略图;
本发明允许有各种改进和选择形式,其特定实施方案例如由图解形式显示,这里将详细描述。然而,应该理解的是这里的附图和详细描述不是要将本发明限定到这里所述的特定形式,本发明涵盖落在由所附的权利要求书限定的本发明的精神和范围内的所有改进、等同物和替换物。
本发明的详细描述
这里描述的实施方案一般涉及制造小装置的系统、装置和相关处理。更具体说,这里的实施方案涉及平版印刷的系统、装置和相关处理。例如,这些实施方案具有在基片,例如半导体晶片上印刷非常小的特征的用途。应该理解的是这些实施方案还具有其它方面的用途,例如节省成本的微电机系统(或MEMS)。这些实施方案还具有制造其它种类装置,包括,但不限于用于数据储存的图案磁介质、微型光学装置、生物和化学装置、X-线光学装置等。
现在来看附图,特别来看图1A和1B,图中显示了相对于基片20预先放置的模板12的布置,其中的基片20上准备使用平版印刷来印刷所需的特征。具体地说,模板12可包括一个被制造成具有所需特征的形状的表面14,它反过来可以转引到基片20上。在一些实施方案中,转印层18可放在基片20和模板12之间。转印层18可经印刷层16从模板12接受所需的特征。如本领域所共知的,转印层18可使得从低纵横比印刷的特征中获得高纵横比结构(或特征)。
为了平版印刷的目的,重要的是保持模板12和基片20尽可能地彼此靠近并几乎平行。例如,对于大约100nm宽和大约100nm深的特征来说,为了成功进行平版印刷处理,可能需要在基片20的印刷区域上有大约200nm或更小,变化小于大约50nm的平均间隙。这里所给的实施方案提供了一种控制模板12和基片20之间空间的方法,用于在具有如此严格和精确的间隙要求的条件下成功进行平版印刷。
图1A和1B说明了在平版印刷中可能遇到的两种类型的问题。在图1A中,由于模板12在印刷层16的一端与基片20靠近,所以形成一个楔形印刷层16。图1A说明了在图案转印期间保持模板12和基片20充分平行的重要性。图1B显示太厚的印刷层16。这两种情况都是很不理想的。这里的实施方案提供了能够消除图1A和1B以及现有平版印刷技术中相关的其它定向问题的系统、加工和相关装置。
图2A到2E说明了统一用30代表的平版印刷处理的实施方案。在图2A中,可以在相对于基片20的空间定向模板12,从而在分隔模板12和基片20的空间处形成间隙31。模板12的表面14可以用薄层13处理,薄层13降低模板表面能量并帮助模板12从基片20分离。下面讨论定向的方式和用于控制模板12和基片20之间间隙的装置。下一步,可以用于处理过的表面14的形状一致的物质40填充间隙31。或者,在一个实施方案中,可以在将模板12相对于基片20移动到所需位置之前将物质40分配到基片20上。
物质40可以形成如图1A和1B所示的印刷层16的印刷层。优选物质40可以是液体,从而可以在不需要高温的条件下很容易地填充间隙31,并且可以不需要高压而使间隙靠近。下面将详细讨论关于物质40的适当选择。
可以将固化剂32应用到模板12以引起物质40变硬并确保由间隙31限定的空间的形状。以这种方式,所需的特征44(图2D)可以从模板12转印到基片20的上表面上。也可以将转印层18直接提供到基片20的上表面上。转印层18可以便于从模板12转印的特征放大以产生一个高纵横比的特征。
如图2D所示,可以将模板12从基片20移走而留下所需的特征44。必须使模板12和基片20分隔从而不需要从基片20的表面剪或撕扯而使所需的特征44保持完好。这里的实施方案提供了一种方法和相关的系统,用于在印刷后从基片20剥离或拉出(这里简称为“剥和拉”方法)模板12,从而保持所需的特征44完好无损。
最后,在图2E中,如使用共知的双层阻抗处理,通过转印层18的作用是从模板12转印到基片20的特征44的垂直截面尺寸放大。可以使用已知技术将所得的结构进一步加工以完成制造过程。图3以流程表形式概述了用50统一表示的平版印刷过程的实施方案。首先,在步骤52,可以进行模板和基片的路线定向,从而达到模板和基片的粗略对齐。在步骤52的路线定向的优点在于它可以允许在制造环境中进行预校准,所述制造环境是有许多装置准备以高效并高产率制造的环境。例如,在基片包括半导体晶片上多个模具之一的情况下,在单一生产运行中,一旦在第一模具上进行路线对齐(步骤52),就可以应用到所有其它模具上。以这种方式,生产周期可以缩短并且产率可以增加。
在步骤54,可以将物质分配到基片上。物质可以是光可固化的有机硅溶液,或其它当暴露于活性光时可以变成固体的有机液体。使用液体这一事实可以消除在现有平版印刷技术中所需要的高温和高压。下一步,在步骤56,可以控制模板和基片之间的间隔,从而在两层之间形成相对均一的间隙,以允许在成功印刷中所需的精确定向。这里的实施方案提供了用于步骤56所需的定向(粗糙和精细)的装置和系统。
在步骤58,随着关于基片和物质而精细定向模板,可以使间隙靠近。可以固化该物质(步骤59),使得该物质变硬形成具有模板特征的形状。下面,在步骤60,可以使模板从基片分离,导致印刷在模板上的特征转印到基片上。最后,在步骤62可以使用初步蚀刻以除去残余材料和共知的氧化蚀刻技术以蚀刻转印层来蚀刻结构。
在各种实施方案中,模板上可以与无图案的区域结合,i)模板表面的平面,ii)在模板的凹口,iii)在模板的突出,或iv)上面所述的组合部分。模板上可以形成一个突起,它可以是刚性的。这种突起可以提供一个均匀的间隔层,用于承受颗粒和光学装置,如光栅、全息图等。或者,模板上可以形成能够压缩的突起。
一般来说,模板可以由一个从i)侧面,ii)背面,iii)前面或iv)上述组合经表面接触来支撑它的刚体。模板支持体具有在施加压力的情况下防止其变形或扭曲的优势。在一些实施方案中,可以用反射涂层在模板的某些区域形成涂层。在某些这种实施方案中,在模板的反射涂层处可以形成孔使得光可以穿过或通过模板。这种涂层在利用干涉仪进行模板定位以重叠校正的情况下有用。这种涂层还使得可以用照射通过模板的侧面而不是顶部的固化剂源进行固化。这还可允许在其它事务中在模板支架、间隙探测技术和重叠标记检测系统的设计方面具有弹性。可以在i)法线入射到模板,ii)以一定角度入射到模板,或iii)通过模板的侧表面入射来进行模板的暴露。在某些实施方案中,刚性的模板可以结合有柔性的物质。
可以用光学平版印刷、电子束平版印刷、离子束平版印刷、X线平版印刷、极端紫外线平版印刷、扫描探针平版印刷、聚焦离子束制粉、干涉仪平版印刷、外延生长、薄膜沉积、化学蚀刻、等离子蚀刻、离子制粉、反应离子蚀刻或上述组合来制造模板。可以在具有平面、抛物面、球面或其他表面形态的基片上形成模板。可以与具有平面、抛物面、球面或其他表面形态的基片一起使用模板。基片可以包含有预定的图案形态和/或多材料的膜堆
在图4描绘的实施方案中,可以形成具有高分辨率、浅深度模具图案602和低分辨率、高深度周边图案603两者的单个、厚的基片601。在图5描绘的实施方案中,可以形成具有高分辨率、浅深度模具图案701的薄基片702(例如石英晶片)。然后可以从基片702切割模具图案701。然后可以将模具图案701粘合到厚的基片703上,选择尺寸使其适合于印刷机上的印刷模板固定器。这种粘合优选使用具有与模板材料的固化剂(例如UV光)类似的折射指数的粘合剂704来获得。
在一个实施方案中,模板可以包括用于基于材料的物理特性以及模板的几何结构控制液体扩散的机构。不会引起基片面积损失的可以容受的过量液体的量可以由各种材料的表面能、液体密度和模板的几何结构来限定。因此,可以使用一个缓解结构以夹卷包围在所需模制或图案区域周围的过量液体。这个区域可以统称为“截口”。截口处的缓解结构可以使用用于构建如上所述的图案或模制缓解结构的标准加工技术凹陷入模板表面。
在传统的光刻中,在光掩膜设计中的光学近端校正。可以将类似的概念应用到微型和毫微模制或平版印刷中。在平版印刷过程中的完全不同在于误差不是由于衍射或光干涉引起的,而是由于在加工过程中可能发生的物理特性的变化所引起的。这些变化可确定在模板的几何形态中的特性或设计的缓解校正的需要。
对于平版印刷过程,可能涉及到模板的耐用性和其释放特性。耐用的模板可以由硅或二氧化硅基质构成。其它适宜的材料可包括,但不限于碳化硅锗、氮化镓、锗化硅、蓝宝石、砷化镓、外延型硅、聚硅、氧化栅、石英或它们的组合物。模板可以包括用于形成可检测特征,例如对齐标记的材料。例如,可检测特征可以由SiOx形成,其中的x小于2。在一些实施方案中,x可以是大约1.5。认为这种材料可以对可见光不透明,但是对于某些活性光波长透明。
通过实验已经发现经由处理模板以在模板的表面形成薄层可以改善模板的耐用性。例如,可以在表面上形成烷基硅烷、氟代烷基硅烷或氟代烷基三氯硅烷层,特别是可以使用十三氟代-1,1,2,2-四氢辛基三氯代硅烷(C5F13C2SiCl3)。这种处理可以在模板的表面上形成自装配单层(SAM)。
可以优化表面处理过程以产生低表面能涂层。这种涂层可用于制备用于平版印刷中的模板。处理的模板相对于未处理的模板可具有所需的释放特性。例如,新处理的模板可具有的表面自由能λ处理的为大约14达因/厘米。未处理的模板表面可具有的表面自由能λ处理的为大约65达因/厘米。这里描述的处理方法可产生具有高耐用性水平的膜。耐用性是非常需要的,因为它可以导致模板耐受制造设置中的多次印刷。
可以使用液相加工或蒸汽相加工的方法在模板表面上形成涂层。在液相加工中,可以将基片浸入到前体和溶剂的溶液中。在蒸汽相加工中,可以经隋性载体气体转运前体。获得用于液相处理中的纯的无水溶剂可能很困难。处理期间体相中的水可能导致凝块沉积,这可能反过来影响涂层的最终质量或覆盖。在蒸汽相加工的一个实施方案中,可以将模板放置在真空室内,之后可以循环净化真空室以除去过量水。一些可吸收的水可以保留在模板的表面上。可能需要少量的水以完成形成涂层的表面反应。认为反应可以通过如下反应式描述:
为了促进该反应可以经温度控制盘将模板的温度调整到所需的反应温度。然后将前体送进反应室保留预定的时间。诸如模板温度、前体浓度、流体几何学等反应参数可以根据特定的反应前体和模板基片组合物而定。
如前面提到的,物质40可以是液体,从而使得它可以填充到间隙31的空间内。例如,物质40可以是低粘度液体单体溶液。合适的溶液可以具有大约0.01厘泊到大约100厘泊范围的粘度(在25℃下测定的)。对于高分辨率结构(例如100nm以下)特别需要低粘度。特别是,在50nm以下方案中,溶液的粘度应该在或低于25厘泊,或更优选低于5厘泊(在25℃下测定的)。在一个实施方案中,适当的溶液可以包括50%重量的正丁基丙烯酸盐和50%SIA 0210.0(3-丙烯酰氧丙基三三甲基硅氧烷)硅烷的混合物。可以向该溶液中加入小量的聚合引发剂(例如光引发剂)。例如,3%重量的1∶1 Irg819和Irg 184,和5%重量的SIB 1402.0是比较合适的。这种混合物的粘度大约是1厘泊。
在一个实施方案中,平版印刷系统可包括用于将液体分配的剂片(例如半导体晶片)的表面的自动化液体分配方法和系统。这种分配方法可使用具有一个或多个延伸的分配端的模块自动化液体分配器。这种分配方法可使用X-Y台以在分配器尖端和基片之间产生相对横向运动。这种分配方法可以消除使用低粘度液体的平版印刷中出现的几个问题。例如,该方法可以消除印刷区域的气泡捕获和局部变形。实施方案还可以提供在将液体扩散到印刷模板和基片之间的整个间隙时,没有不必要的浪费过量液体而获得低印刷压力的方法。
在一个实施方案中,对于1平方英寸印刷面积典型的分配体积可以小于大约130nl(毫微升)。分配后,后面的方法可以包括将模板和基片组件暴露于固化剂下。模板从基片的分离可以将转印的图像留在印刷表面的顶部。转印的图像可位于保留暴露的材料的薄层上。保留层可被称为“基层”。该基层应该薄且均匀以用于可制造的印刷。
印刷加工可包括施加到模板和基片界面的高压和/或高温。然而,为了可以制造包括高分辨率重叠对齐的平版印刷过程的目的,应该避免高压和高温。这里描述的实施方案通过使用低粘度光可固化液体而避免了对高温的需要。另外,通过减少将液体扩散到整个印刷区域所需的挤压力而最小化印刷压力。因此,为了基于液体的平版印刷的目的,液体分配过程应该满足以下特性:
1.在模板和基片之间没有应当捕获的气泡;
2.应该避免分配器尖端和基片之间的直接接触以产生最小化颗粒;
3.应该最小化填充模板和基片之间间隙所需的压力;
4.应该最小化非均匀液体集结和/或压力梯度以减少模板-基片界面的非均匀局部变形;和
5.应该最小化分配的液体的浪费。
在一些实施方案中,可以利用在基于可置换的液体分配器尖端和基片之间的相对运动,以在印刷区域形成具有基本上连续线条的图案。通过平衡分配的速率和相对运动可控制线条的截面尺寸和线条的形状。在分配过程中,分配器尖端可以靠近基片固定(例如在数十微米级)。在图6A和6B中描绘形成线条图案的两种方法。图10A和10B中描绘的线条图案是正弦曲线图案。然而,也可能是其它图案。正如图10A和10B中描绘的,可以使用单一分配器尖端1001或多个分配器尖端1002画出连续线条图案。
分配率Vd和基片的相对横向移动速率Vs可以具有如下关系:
Vd=Vd/td(分配体积/分配时期), (1)
Vs=L/td(线长度/分配时期), (2)
Vd=aL(这里“a”是线条图案的截面积),(3)
因此,
Vd=aVs (4)
初始线条图案的宽度通常可依赖于分配器的尖端的大小。分配器的尖端可以固定。在一个实施方案中,可以使用液体分配控制器1111(如图7所描绘的)以控制分配的液体的体积(Vd)和分配液体所用的时间(td)。如果Vd和td是固定的,线条长度的增加会导致线条图案的截面高度下降。通过增加周期性图案的空间频率可获得图案长度的增加。降低图案高度可导致在印刷过程中转移的液体量下降。与单一分配尖端的情况相比,通过使用连接到同一分配线的多个尖端,可以更快地形成具有长长度的线条图案。在一个实施方案中,基于液体分配系统的转移可包括:液体容器1101、入口管1102、入口阀1103、出口阀1104、注射器1105、注射器促动器1106、分配器尖端1107、X台促动器1109、Y台促动器1110、分配器控制器1111、XY台控制器1112和主控制计算机1113。基于分配器的适宜的转移可以从Hsmilton公司购买。
图8显示了几个不希望的用于低粘度液体的液体图案或分配方法。这些分配图案可导致一个或多个问题包括:捕获气泡、局部变形和浪费液体。例如,在印刷区域1201的中心分配一滴液体,或分配不规则线条1205可导致模板和/或基片的局部变形。在环形图案中分配几滴1202,或线条1206可导致气泡的捕获。其它具有几乎靠近环形图案1204的分配图案可类似地导致气泡捕获。同样地,喷雾或随机放置小滴1203也可导致气泡的捕获。用低粘度液体旋转涂敷基片,会由于薄膜不稳定而可引起“去湿”问题。去湿会造成在基片上形成多个小液滴,而不是形成薄的均匀的液体层。
在一个实施方案中,液体分配方法可分配之后随着其扩展会形成连续体的多个小液滴。图9描绘使用5滴液体的情况。这里,使用5滴仅仅是为了说明的目的。可以使用这种方法实现其它“开放”的图案,诸如正弦线、“W”或“X”。随着模板-基片间隙下降,圆滴1301可变薄变宽,引起周围液滴融合成1302。因此,即使初始分配可以不包括连续形式,扩展的液体会从模板和基片之间的间隙排气。应该以这样的方式分配用于这种方法中的有效图案,即随着小滴的扩展,它们不会捕获模板和基片之间的任何气体。
其体积可以准确指定的小液滴可以使用具有压力支持元件的微型电磁阀来分配。其他类型的液体分配促动器可包括压电促动分配器。与基于转移的液体分配器相比,具有微型电磁阀分配器的系统的优点包括更快的分配时间和更准确的体积控制。这些优点对于大量印刷(例如几个英寸截面)来说尤其需要。图10显示了包括多个微型电磁阀的系统的一个实施例。该系统包括:液体容器1401、入口管1402、入口阀1403、泵1404、出口阀1405、泵控制器1406、微型电磁阀1407、微型电磁阀控制器1408、X-Y台1409、X-Y台控制器1410和主控制计算机1412。基片1411可以放在X-Y台1409上。合适的微型阀分配器系统可以从Lee公司得到。
图11A显示了可以用于大规模(例如,大于几英寸)的印刷区域的分配图案。在这些实施例中,可以分配液体1503的平行线。液体1503的平行线可以按照下列方式扩展:在模板1501接近基片1502时,从缝隙中排出空气。为了按照所希望的方式扩展线1503,模板1501可以以有意楔入的结构(如图11B所示)接近缝隙。即,模板/基片缝隙可以沿着线1503(楔形角可以平行于线1503)接近。
提供分布良好的初始液体层的优点在于可以补偿模板和基片之间的定向误差。这可能是由于液体薄层的流体动力学和定向台的顺应性。模板的下部可以比模板的其它部分早接触分配的液体。随着模板和基片之间间隙变小,模板的下部和上部之间反应力的不平衡增加。这种力的不平衡可能导致模板和基片之间的校正运动,使得它们基本上保持平行。
成功的平版印刷需要模板相对于基片精确地对齐和定向,以控制模板和基片之间的间隙。这里的实施方案可提供在产品制造过程中获得精确的对齐和间隙控制的系统。在一个实施方案中,该系统可包括高分辨率X-Y平移台。在一个实施方案中,该系统可提供用于用于执行模板和基片表面之间初对齐和路线对齐操作的预校准台,以使相对对齐落在精细运动定向台的运动范围内。这个预校准台可已经仅在新的模板安装在仪器(有时称为步进器)的时候才需要。预校准台可以由基板、柔性元件和多个测微计或连接到基板和柔性元件的高分辨率促动器组成。
图12描绘了一个用100代表的系统的组件,它用于关于诸如基片20的有待印刷的基片校准和定向诸如模版12的模板。系统100可用于机器中,如步进器中,用于使用这里描述的平版印刷方法在生产环境中批量制造装置。如图所示,系统100可以安装在顶部框架110上,顶部框架110可对机架120提供支持。机架120可包括用于关于基片路线对齐模版150的预校准台(图12未显示)。
机架120可以用附着在机架120对面的中部框架114上的导轴112a连接到中部框架114。在一个实施方案中,可以使用三个导轴(图12中未显示背导轴),用以在模版150的垂直平移期间支撑上下滑动的机架120。连接到中部框架114周围的相应导轴112a和112b上的滑动器116a和116b可促进机架120的上下运动。
系统100可包括连接到机架120底部的盘形底座122。底座122可连接到盘形柔性环124上。柔性环124可支撑包括第一柔性元件126和第二柔性元件128的下部放置的定向台。典型地,模板150可包括其上印有所希望的特征的一片石英。模板150还可以根据已知的方法包括其它物质。
系统100可包括能够精确控制模板150从而能够获得模板与基片之间精确的定向对齐和保持均匀的间隙的机构。另外,系统100可提供在印刷后不用从基片表面剪下特征而将模板150从基片的表面分离的方法。通过第一和第二柔性元件126和128的结构可分别促进精确的对齐和间隙控制。
在一个实施方案中,通过设计模板,使得基片和模板之间的最小间隙落在可使用感测技术的范围内,可获得高分辨率间隙感测。可以独立于实际图案表面操作这个测量的间隙。这使得可以在感测技术的有用范围内执行间隙控制。例如,如果将使用有用感测范围在大约150纳米到20微米之间的光谱反射性分析技术来分析该间隙,则模板可具有形成在模板上的具有大约150纳米深度或更大的特征。这可保证将被感测到的最小间隙大于150纳米。
由于模板被朝向基片降低,基片和模板之间的液体会被排出。当粘着力接近施加的压缩力的平衡条件时,即片和模板之间的间隙会接近实际底限。这在模板的表面接近基片时可能发生。例如,当14kPa的力在一秒内施加到半径为1厘米的模板上时,该方案中对于1cP液体的间隙高度大约为100纳米。结果,该间隙可以自我限制,保持一个均匀并平行的间隙。同样,可以排出(或夹卷)能清楚预测量的液体。根据仔细的液体动力学和表面现象计算可预测夹卷的液体的体积。
为了规模化生产印刷图案,需要控制模板相对于基片之间的倾度和间隙。为了完成定向和间隙控制,可以使用以标线制造技术生产的模板与诸如以下的间隙感测技术结合,i)单波长干涉仪,ii)波长干涉仪,iii)椭圆光度法,iv)电容感测器或v)压力感测器。
参考图13,柔性接点160和162可以是一个槽口形状,用于提供刚性体164,166,208和210围绕枢轴运动,所属枢轴位于槽口的最薄截面上。这种结构可提供两个(2)基于柔性的亚系统,用于具有退耦顺应运动轴180和200的精细退耦定向台250。柔性元件126和128可经表面紧密配合而组装,使得模板150的运动可围绕支点252发生,基本上消除了可引起从基片上剪切印刷的特征的“摇摆”和其他运动。因此,定向台250可精确地移动模板150围绕支点252运动。从而消除在平版印刷后从基片上剪切所需的特征。
参考图14,图中描绘了一般用300代表的柔性模型,用于理解诸如定向台250这种精细退耦定向台的操作原理。柔性模型300可包括四个(4)平行接点:接点1、2、3和4,用于在它的法向和旋转结构中提供四-棒-连接系统。线310可穿过接点1和2。线312可穿过接点3和4。可选择角α1和α2,使得顺应对齐轴(或定向轴)基本上位于模板-晶片界面254上。为了精细定向变化,位于接点2和3之间的刚性体314可围绕由点C表示的轴旋转。刚性体314可以是柔性元件126和128的刚性体170和206的典型代表。
垂直于第一柔性元件(如图13所示)安装第二柔性元件可提供具有两个退耦定向轴的装置,所属两个轴彼此正交并位于模板-基片界面254上。柔性元件适于具有一个开口,用于使固化剂(例如UV光)穿过模板150。
定向台250能够相对于基片精细对齐和精确运动模板150。理想的是,定向调整可导致在界面上忽略横向运动,并在与界面表面正交的周围忽略扭曲运动,这是由于选择性限制高结构硬度的原因。具有柔性接点160和162的柔性元件126和128另一个优点在于它们不会像在一般摩擦接点处一样产生颗粒。这在成功进行平版印刷过程中是一个重要的因素,因为颗粒对这种过程特别有害。
由于需要精细间隙控制,这里提供的实施方案可需要能够测量模板和基片之间小至500纳米或更小数量级的小间隙的间隙感测方法。这种间隙感测方法可需要大约50纳米或更小的分辨率。理想的是,可实时提供这种间隙感测。实时提供间隙感测可使得要使用的间隙感测产生反馈信号以主动地控制促动器。
本发明参考各种示例性实施方案进行了描述,这些描述不应该理解为对本发明的限制。本领域技术人员在参考本说明书的情况下很明显可以对示意性实施方案以及本发明的其它实施方案进行改进和组合。因此,所附的权利要求包括这些改进或实施方案。
Claims (10)
1.一种在基片上形成层的方法,包括:
将一种液体施加到所述基片上作为多个具有固定距离间隔的液滴,在所述多个具有固定距离间隔的液滴之间存在着气体;
将模板放置叠加在所述多个具有固定距离间隔的液滴上,并与所述基片保持定距离间隔;以及
扩展所述多个具有固定距离间隔的液滴中的液体以在所述基片上形成所述液体的连续层,同时保持所述模板与基片间隔定距离,以限定它们之间的间隙,从而所述多个具有固定距离间隔的液滴可以限定所述间隙中通过所述间隙排气的开口。
2.权利要求1的方法,其中将所述液体施加到所述基片上还包括使用压电促动的分配器分配所述液体。
3.权利要求1的方法,其中进一步包括在将所述液体施加到所述基片上之前,在所述基片上形成转印层。
4.权利要求1的方法,其中施加所述液体还包括将所述多个具有固定距离间隔的液滴配置成一种形状,该形状是从一组由曲线和线性形状构成的形状中选择出来。
5.权利要求1的方法,其中所述扩展进一步包括用所述液体基本上填充该间隙。
6.权利要求1的方法,其中放置所述模板进一步包括定位所述基片上的模板基本上非平行于所述基片;而所述扩展进一步包括朝着所述基片移动所述模板,其中随着所述模板朝向所述基片移动,所述模板相对于所述基片保留在一个基本上非平行的方向;当所述模板与所述液体接触之后,将所述模板定位在与所述基片基本平行的方向以限定所述间隙。
7.权利要求1的方法,其中放置所述模板进一步包括排列所述有图案模板位于第一平面,所述基片位于第二平面,使所述第一平面相对于所述第二平面倾斜延伸;而所述扩展进一步包括在所述有图案模板和所述基片之间提供相对运动,使得所述有图案模板在不同时间接触所述预定图案的不同区域,直到获得所述空间关系,此时,所述有图案模板基本上平行于所述基片而定位,限定所述间隙。
8.权利要求1、2、3、4、5、6和7中任一所述的方法,其中施加所述液体进一步包括以预定图案安排所述多个具有固定距离间隔的液滴。
9.权利要求8的方法,其中所述预定图案包括多个离散的所述液体材料液滴,并且其中所述液滴包括预定体积并间隔预定距离,从而抑制气泡形成。
10.权利要求8的方法,其中从包括所述液体材料的连续正弦曲线图案、所述图案材料的连续X形图案、多个所述液体材料的彼此平行间隔的连续线中选择所述预定图案。
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EP2270592B1 (en) | 2015-09-02 |
WO2002006902A2 (en) | 2002-01-24 |
KR20030079910A (ko) | 2003-10-10 |
EP2270592A3 (en) | 2011-11-30 |
US9223202B2 (en) | 2015-12-29 |
WO2002006902A3 (en) | 2002-10-03 |
EP2270592A2 (en) | 2011-01-05 |
US20020094496A1 (en) | 2002-07-18 |
JP2011176321A (ja) | 2011-09-08 |
JP2004504714A (ja) | 2004-02-12 |
US20080199816A1 (en) | 2008-08-21 |
AU2001277907A1 (en) | 2002-01-30 |
CN1455888A (zh) | 2003-11-12 |
JP4740518B2 (ja) | 2011-08-03 |
KR100827741B1 (ko) | 2008-05-07 |
EP1303793B1 (en) | 2015-01-28 |
JP5325914B2 (ja) | 2013-10-23 |
EP1303793A2 (en) | 2003-04-23 |
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