CN1856512A - 含有二羧酸酯内部给体的自限制催化剂组合物和丙烯聚合方法 - Google Patents
含有二羧酸酯内部给体的自限制催化剂组合物和丙烯聚合方法 Download PDFInfo
- Publication number
- CN1856512A CN1856512A CNA2004800275598A CN200480027559A CN1856512A CN 1856512 A CN1856512 A CN 1856512A CN A2004800275598 A CNA2004800275598 A CN A2004800275598A CN 200480027559 A CN200480027559 A CN 200480027559A CN 1856512 A CN1856512 A CN 1856512A
- Authority
- CN
- China
- Prior art keywords
- mixture
- sca
- catalyst composition
- polymerization
- dimethoxy silane
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Granted
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Classifications
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
- C08F10/00—Homopolymers and copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
- C08F4/00—Polymerisation catalysts
- C08F4/42—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors
- C08F4/44—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides
- C08F4/60—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides together with refractory metals, iron group metals, platinum group metals, manganese, rhenium technetium or compounds thereof
- C08F4/62—Refractory metals or compounds thereof
- C08F4/64—Titanium, zirconium, hafnium or compounds thereof
- C08F4/642—Component covered by group C08F4/64 with an organo-aluminium compound
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
- C08F10/00—Homopolymers and copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond
- C08F10/04—Monomers containing three or four carbon atoms
- C08F10/06—Propene
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
- C08F110/00—Homopolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond
- C08F110/04—Monomers containing three or four carbon atoms
- C08F110/06—Propene
Landscapes
- Chemical & Material Sciences (AREA)
- Health & Medical Sciences (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Medicinal Chemistry (AREA)
- Polymers & Plastics (AREA)
- Organic Chemistry (AREA)
- Engineering & Computer Science (AREA)
- Materials Engineering (AREA)
- Transition And Organic Metals Composition Catalysts For Addition Polymerization (AREA)
Abstract
Description
试验 | SCA混合物 | 硅烷/酯(mol%) | 温度(℃) | 标准化活性(kg/g cat.) | A/A67(%) |
12456789101112131415161718192021 | DCPDMS/PEEB““““MChDMS/PEEB“““““““““MChDMS/EB““““““NPTMS/PEEB | 2/98“100/02/98““5/95““100/0““4/96““100/0““2/98 | 6710067100671001156710011567100115671001156710011567 | 3.963.494.715.282.941.510.653.161.100.883.584.092.273.161.060.793.584.092.272.50 | 100881001121005122100352810011463100332510011463100 |
22 “23 “24 “25 “26 “27 “28 “29 “30 “31 “32 “33 “34 “35 “ | ““10/90““15/85““50/50““100/0““ | 10013067100130671001306710013067100130 | 1.270.602.151.250.602.121.250.542.341.310.622.956.270.51 | 512410058281005925100562610021317 |
Claims (10)
Applications Claiming Priority (3)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
US50531403P | 2003-09-23 | 2003-09-23 | |
US60/505,314 | 2003-09-23 | ||
PCT/US2004/026642 WO2005035595A1 (en) | 2003-09-23 | 2004-08-18 | Self limiting catalyst composition with dicarboxylic acid ester internal donor and propylene polymerization process |
Publications (2)
Publication Number | Publication Date |
---|---|
CN1856512A true CN1856512A (zh) | 2006-11-01 |
CN1856512B CN1856512B (zh) | 2010-06-02 |
Family
ID=34434880
Family Applications (1)
Application Number | Title | Priority Date | Filing Date |
---|---|---|---|
CN2004800275598A Expired - Fee Related CN1856512B (zh) | 2003-09-23 | 2004-08-18 | 含有二羧酸酯内部给体的自限制催化剂组合物和丙烯聚合方法 |
Country Status (10)
Country | Link |
---|---|
US (1) | US7381779B2 (zh) |
EP (1) | EP1668044B1 (zh) |
JP (1) | JP5248774B2 (zh) |
KR (1) | KR101109270B1 (zh) |
CN (1) | CN1856512B (zh) |
AR (1) | AR045801A1 (zh) |
EG (1) | EG24474A (zh) |
MY (1) | MY142371A (zh) |
RU (1) | RU2345094C2 (zh) |
WO (1) | WO2005035595A1 (zh) |
Cited By (2)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
CN105764936A (zh) * | 2013-11-27 | 2016-07-13 | 格雷斯公司 | 主催化剂颗粒及抗冲共聚物的聚合方法 |
CN109096417A (zh) * | 2017-06-21 | 2018-12-28 | 中国石油化工股份有限公司 | 一种用于烯烃聚合的催化剂和烯烃聚合方法 |
Families Citing this family (16)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
KR101146472B1 (ko) * | 2003-09-23 | 2012-05-21 | 유니온 카바이드 케미칼즈 앤드 플라스틱스 테크날러지 엘엘씨 | 모노카르복실산 에스테르 내부 공여체를 갖는 자가-소멸촉매 조성물 및 프로필렌 중합 방법 |
US10647788B2 (en) | 2007-08-24 | 2020-05-12 | W. R. Grace & Co-.Conn. | Self-limiting catalyst system with controlled aluminum to SCA ratio and method |
KR101787927B1 (ko) | 2007-12-21 | 2017-10-18 | 더블유.알. 그레이스 앤드 캄파니-콘. | 두자리 내부 공여체를 가진 자기-제한성 촉매 조성물 |
KR101539284B1 (ko) * | 2008-03-18 | 2015-07-24 | 릴라이언스 인더스트리즈 리미티드 | 프로필렌 중합 촉매 시스템 |
KR101539286B1 (ko) * | 2008-05-21 | 2015-07-29 | 릴라이언스 인더스트리즈 리미티드 | 올레핀 중합을 위한 촉매 시스템 |
EP2315789B1 (en) * | 2008-08-21 | 2015-09-02 | W.R. Grace & CO. - CONN. | Catalyst composition with mixed selectivity control agent and polymerisation method using it |
WO2010065359A1 (en) * | 2008-11-25 | 2010-06-10 | Union Carbide Chemicals & Plastics Technology Llc | Procatalyst composition multiple internal donor having silyl ester and method |
US8088872B2 (en) * | 2008-11-25 | 2012-01-03 | Dow Global Technologies Llc | Procatalyst composition including silyl ester internal donor and method |
JP2013530295A (ja) | 2010-06-30 | 2013-07-25 | ダウ グローバル テクノロジーズ エルエルシー | エチレン重合用の自己制御触媒組成物 |
US10195581B2 (en) | 2012-03-26 | 2019-02-05 | Unchained Labs | Parallel reactor systems and methods for preparing materials |
EP2958950B1 (en) | 2013-02-19 | 2019-09-11 | Reliance Industries Limited | An improved magnesium dichloride supported titanium catalyst composition for polyolefin polymerization |
EP2992335B1 (en) | 2013-04-30 | 2018-04-18 | Unchained Labs | Methods for sampling from non-atmospheric vessels in a parallel reactor system |
CN105980422B (zh) | 2013-08-19 | 2019-05-21 | 陶氏环球技术有限责任公司 | 用于在使用自限性试剂的聚合工艺中生产乙烯类聚合物的方法 |
SG11201603120RA (en) | 2013-10-29 | 2016-05-30 | Grace W R & Co | Propylene ethylene random copolymer suitable for pipe |
RU2692246C1 (ru) | 2017-06-15 | 2019-06-24 | Индийская Нефтяная Корпорация Лимитэд | Внешний донор для полимеризации олефинов |
WO2019094216A1 (en) | 2017-11-13 | 2019-05-16 | W.R. Grace & Co.-Conn. | Catalyst components for propylene polymerization |
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US5066737A (en) * | 1990-10-22 | 1991-11-19 | Shell Oil Company | Olefin polymerization catalyst |
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-
2004
- 2004-08-18 US US10/568,931 patent/US7381779B2/en not_active Expired - Fee Related
- 2004-08-18 RU RU2006113604/04A patent/RU2345094C2/ru not_active IP Right Cessation
- 2004-08-18 CN CN2004800275598A patent/CN1856512B/zh not_active Expired - Fee Related
- 2004-08-18 EP EP04781352.2A patent/EP1668044B1/en not_active Not-in-force
- 2004-08-18 KR KR1020067005662A patent/KR101109270B1/ko not_active IP Right Cessation
- 2004-08-18 JP JP2006527997A patent/JP5248774B2/ja not_active Expired - Fee Related
- 2004-08-18 WO PCT/US2004/026642 patent/WO2005035595A1/en active Application Filing
- 2004-09-20 MY MYPI20043836A patent/MY142371A/en unknown
- 2004-09-22 AR ARP040103414A patent/AR045801A1/es unknown
-
2006
- 2006-03-20 EG EGNA2006000277 patent/EG24474A/xx active
Cited By (4)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
CN105764936A (zh) * | 2013-11-27 | 2016-07-13 | 格雷斯公司 | 主催化剂颗粒及抗冲共聚物的聚合方法 |
CN105764936B (zh) * | 2013-11-27 | 2018-05-11 | 格雷斯公司 | 主催化剂颗粒及抗冲共聚物的聚合方法 |
US10059784B2 (en) | 2013-11-27 | 2018-08-28 | W. R. Grace & Co.-Conn. | Procatalyst particles and polymerization process for impact copolymers |
CN109096417A (zh) * | 2017-06-21 | 2018-12-28 | 中国石油化工股份有限公司 | 一种用于烯烃聚合的催化剂和烯烃聚合方法 |
Also Published As
Publication number | Publication date |
---|---|
US7381779B2 (en) | 2008-06-03 |
RU2006113604A (ru) | 2006-08-27 |
EG24474A (en) | 2009-08-03 |
US20070032375A1 (en) | 2007-02-08 |
CN1856512B (zh) | 2010-06-02 |
AR045801A1 (es) | 2005-11-16 |
KR101109270B1 (ko) | 2012-01-30 |
RU2345094C2 (ru) | 2009-01-27 |
WO2005035595A1 (en) | 2005-04-21 |
KR20060126941A (ko) | 2006-12-11 |
MY142371A (en) | 2010-11-30 |
EP1668044A1 (en) | 2006-06-14 |
JP5248774B2 (ja) | 2013-07-31 |
JP2007506837A (ja) | 2007-03-22 |
EP1668044B1 (en) | 2014-05-07 |
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