DE10148570A1 - Composition containing fungus and polymeric additive, useful for controlling pests, e.g. insects on plants, has increased activity and stability - Google Patents

Abstract

Composition (X) comprises, (by wt.%): (1) a specific additive (A1) at (0.001-2); (2) at least one auxiliary (A2) at (0-20); (3) water (A3) to make 100%; and (4) a fungus (A4) at 1-10<10> colony-forming units/g of (A1)-(A3), or components of the fungus at 10<-3> to 5\*10<5> mg/kg of composition. Composition (X) comprises, (by wt.%): (1) a specific additive (A1) at (0.001-2); (2) at least one auxiliary (A2) at (0-20); (3) water (A3) to make 100%; and (4) a fungus (A4) at 1-10<10> colony-forming units/g of (A1)-(A3), or components of the fungus at 10<-3> to 5\*10<5> mg/kg of composition. (A1) comprises (by wt.%) crosslinked polymer (10-80) (a1); hydrophobic, organic liquid (20-80) (a2); at least one water-in-oil emulsifier (0.5-10) (a3) and oil-in-water emulsifier (a4), and additives (0-20) (a5). Independent claims are also included for: (1) A method for preparing (X); and (2) a plant protection or pesticidal composition (Y) that contains an additive (C1) similar to A1.

Description

The invention relates to a composition comprising an additive, Microorganisms, auxiliaries and water, a process for producing them Composition, a composition obtainable by this process, a method of controlling organisms using the Composition for controlling organisms, the use of the Additive, the use of a combination of the additive and Microorganisms, a plant protection or pesticide Process for the preparation of a crop protection or Pesticide and the agent obtainable by the process.

DE 197 07 178 A1 discloses biological crop protection agents for controlling Pest populations of tropical rice cultivation, consisting of Conidiopore mixtures of the genera Beauveria, Metarhischem, Paecilomyces or Verticillium, combined with oils or seed extracts from different species of the genus Pachyrhizius. The disadvantage of that described in this document Plant protection products consist in the low storage stability of the fungal spores.

In general, the invention is based on the object, which results from the prior art Technology overcome disadvantages.

Furthermore, the object of the invention is a composition To provide an increased effectiveness compared to the prior art in the fight against organisms.

• 1. ein Additiv in einer Menge in einem Bereich von 0,001 bis 2,0 Gew.-%, bevorzugt in einem Bereich von 0,01 bis 1 Gew.-% und darüber hinaus bevorzugt in einem Bereich von 0,25 bis 0,75 Gew.-%,
• 2. einen oder mehrere Hilfsstoffe in einer Menge in einem Bereich von 0 bis 20 -Gew.-%, bevorzugt in einem Bereich von 0,01 bis 10 Gew.-% und besonders bevorzugt in einem Bereich von 0,1 bis 5 Gew.-%,
• 3. eine solche Menge Wasser, das die Summe der Bestandteile (A1) bis (A3) 100 Gew.-% beträgt, sowie
• 4. pilzliche Organismen in einer Menge in einem Bereich von 10⁰ bis 10¹⁰, bevorzugt 102 bis 108 und besonders bevorzugt 10³ bis 10⁷ colony forming units (cfu) pro Gramm der Komponenten (A1) bis (A3) der Zusammensetzung oder Bestandteile von pilzliche Organismen in einer Menge in einem Bereich von 10^-3 bis 5.10⁵ mg/kg Zusammensetzung, bevorzugt von 0,1 bis 5.10⁴ mg/kg Zusammensetzung und besonders bevorzugt von 5 bis 5.10⁴ mg/kg Zusammensetzung, oder vorzugsweise eine Mischung aus pilzliche Organismen und Bestandteilen von pilzlichen Organismen und besonders bevorzugt pilzliche Organismen

wobei das Additiv (A1) vorzugsweise aus einer Wasser-in-Öl-Polymerdispersion stammend, auf

• 1. einem vernetzten Polymer in einer Menge in einem Bereich von 10 bis 79 Gew.-%, bevorzugt in einem Bereich von 20 bis 50 Gew.-% und darüber hinaus bevorzugt in einem Bereich von 25 bis 35 Gew.-%, jeweils bezogen auf das Gesamtgewicht des Additivs (A1),
• 2. einer hydrophoben, organischen Flüssigkeit in einer Menge in einem Bereich von 20 bis 80 Gew.-%, bevorzugt in einem Bereich von 25 bis 50 Gew.-% und darüber hinaus bevorzugt in einem Bereich von 30 bis 40 Gew.-%, jeweils bezogen auf das Gesamtgewicht des Additivs (A1),
• 3. einem oder mehreren Wasser-in-Öl-Emulgatoren in einer Menge in einem Bereich von 0,5 bis 10 Gew.-%, bevorzugt in einem Bereich von 1 bis 8 Gew.-% und darüber hinaus bevorzugt in einem Bereich von 2 bis 6 Gew.-%, jeweils bezogen auf das Gesamtgewicht des Additivs (A1),
• 4. einem oder mehreren Öl-in-Wasser-Emulgatoren in einer Menge in einem Bereich von 0,5 bis 10 Gew.-%, bevorzugt in einem Bereich von 1 bis 8 -Gew.-% und darüber hinaus bevorzugt in einem Bereich von 2 bis 6 Gew.-%, jeweils bezogen auf das Gesamtgewicht des Additivs (A1),
• 5. einem oder mehreren Zusatzstoffen in einer Menge in einem Bereich von 0 bis 20 Gew.-%, bevorzugt in einem Bereich von 0,01 bis 10 Gew.-% und darüber hinaus bevorzugt in einem Bereich von 0,1 bis 5 Gew.-%, jeweils bezogen auf das Gesamtgewicht des Additivs (A1), sowie
• 6. auf einer solchen Menge Wasser basiert, das die Summe (a1) bis (a6) 100 -Gew.-% beträgt.

The above objects are achieved by including a composition

• 1. an additive in an amount in a range from 0.001 to 2.0% by weight, preferably in a range from 0.01 to 1% by weight and moreover preferably in a range from 0.25 to 0.75 wt .-%,
• 2. one or more auxiliary substances in an amount in a range from 0 to 20% by weight, preferably in a range from 0.01 to 10% by weight and particularly preferably in a range from 0.1 to 5% by weight. -%
• 3. such an amount of water that the sum of the components (A1) to (A3) is 100% by weight, and
• 4. fungal organisms in an amount in a range from 10 ⁰ to 10 ¹⁰ , preferably 102 to 108 and particularly preferably 10 ³ to 10 ⁷ colony forming units (cfu) per gram of components (A1) to (A3) of the composition or constituents of fungal organisms in an amount in a range from 10 ^-3 to 5.10 ⁵ mg / kg composition, preferably from 0.1 to 5.10 ⁴ mg / kg composition and particularly preferably from 5 to 5.10 ⁴ mg / kg composition, or preferably a mixture from fungal organisms and components of fungal organisms and particularly preferably fungal organisms

the additive (A1) preferably originating from a water-in-oil polymer dispersion

• 1. a crosslinked polymer in an amount in a range from 10 to 79% by weight, preferably in a range from 20 to 50% by weight and more preferably in a range from 25 to 35% by weight, in each case based on the total weight of the additive (A1),
• 2. a hydrophobic organic liquid in an amount in a range from 20 to 80% by weight, preferably in a range from 25 to 50% by weight and moreover preferably in a range from 30 to 40% by weight, each based on the total weight of the additive (A1),
• 3. one or more water-in-oil emulsifiers in an amount in a range from 0.5 to 10% by weight, preferably in a range from 1 to 8% by weight and moreover preferably in a range from 2 up to 6% by weight, based in each case on the total weight of the additive (A1),
• 4. one or more oil-in-water emulsifiers in an amount in a range from 0.5 to 10% by weight, preferably in a range from 1 to 8% by weight and moreover preferably in a range from 2 to 6% by weight, based in each case on the total weight of the additive (A1),
• 5. one or more additives in an amount in a range from 0 to 20% by weight, preferably in a range from 0.01 to 10% by weight and moreover preferably in a range from 0.1 to 5% by weight. -%, each based on the total weight of the additive (A1), and
• 6. based on such an amount of water that the sum (a1) to (a6) is 100% by weight.

• 1. Verringerte Fließgeschwindigkeit der Zusammensetzung um mindestens 50%, bevorzugt um mindestens 75%, besonders bevorzugt um mindestens 95%, jeweils im Vergleich zur Fließgeschwindigkeit von Wasser;
• 2. Verlängerte Zeitspanne, die vergeht, bis das in 10 g der Zusammensetzung enthaltene Wasser bei 22°C und einem Druck von 1 bar verdunstet sind, im Vergleich zur Zeitspanne, die vergeht, bis die gleiche Menge Wasser ohne das Additiv unter den gleichen Bedingungen verdunstet ist, um mindestens 1 Stunde.

In a preferred embodiment of the composition according to the invention, the additive in a composition consisting of water and the additive in an amount of 0.5% by weight, based on the total weight of the composition, has at least one of the following properties, determined according to the test methods described herein on:

• 1. Reduced flow rate of the composition by at least 50%, preferably by at least 75%, particularly preferably by at least 95%, in each case compared to the flow rate of water;
• 2. Extended period of time that passes until the water contained in 10 g of the composition has evaporated at 22 ° C. and a pressure of 1 bar compared to the period of time that elapses before the same amount of water without the additive is used under the same conditions evaporated by at least 1 hour.

• 1. Vernngerte Fließgeschwindigkeit der wässrigen Mischung um mindestens 75%, vorzugsweise um mindestens 95%, jeweils im Vergleich zur Fließgeschwindigkeit von Wasser;
• 2. Verlängerte Zeitspanne, die vergeht, bis das in 10 g der Zusammensetzung enthaltene Wasser bei 22°C und einem Druck von 1 bar verdunstet sind, im Vergleich zur Zeitspanne, die vergeht, bis die gleiche Menge Wasser ohne das Additiv unter den gleichen Bedingungen verdunstet ist, um mindestens 2 Stunden.

In a further preferred embodiment of the composition according to the invention, the additive (A1) in a composition consisting of water and the additive in an amount of 1.5% by weight, based on the total weight of the composition, has at least one of the following, according to the Test methods described herein have specific properties:

• 1. Reduced flow rate of the aqueous mixture by at least 75%, preferably by at least 95%, in each case compared to the flow rate of water;
• 2. Extended period of time that passes until the water contained in 10 g of the composition has evaporated at 22 ° C. and a pressure of 1 bar compared to the period of time that elapses before the same amount of water without the additive is used under the same conditions evaporated to at least 2 hours.

The crosslinked polymers (a1) are a class of polymers which are preferably produced by inverse emulsion polymerization. Thereby one produces in a continuous, water-immiscible organic phase with the addition of water-in-oil emulsifiers finely divided, swollen polymers. The finely divided polymers are preferably with water swollen.

The crosslinked polymers (a1) are preferably Wasserquchlbarc polymers.

• 1. (α1) 0,1 bis 99,999 Gew.-%, bevorzugt 20 bis 98,99 Gew.-% und besonders bevorzugt 30 bis 98,95 Gew.-% polymerisierten, ethylenisch ungesättigten, säuregruppenhaltigen Monomeren oder deren Salze oder polymerisierten, ethylenisch ungesättigten, einen protonierten oder quartemierten Stickstoff beinhaltenden Monomeren, oder deren Mischungen, wobei mindestens ethylenisch ungesättigte, säuregruppenhaltige Monomere, vorzugsweise Acrylsäure, beinhaltende Mischungen besonders bevorzugt sind,
• 2. (α2) 0 bis 70 Gew.-%, bevorzugt 1 bis 60 Gew.-% und besonders bevorzugt 1 bis 40 Gew.-% polymerisierten, ethylenisch ungesättigten, mit (α1) copolymerisierbaren Monomeren,
• 3. (α3) 0,001 bis 10 Gew.-%, bevorzugt 0,01 bis 7 Gew.-% und besonders bevorzugt 0,05 bis 5 Gew.-% eines oder mehrerer Vernetzer, sowie
• 4. (α4) 0 bis 20 Gew.-%, bevorzugt 0,01 bis 7 Gew.-% und besonders bevorzugt 0,05 bis 5 Gew.-% eines oder mehrer Adjuvantien, wobei die Summe der Gewichtsmengen (α1) bis (α4) 100 Gew.-% beträgt.

The polymer (a1) is preferably based on

• 1. (α1) 0.1 to 99.999% by weight, preferably 20 to 98.99% by weight and particularly preferably 30 to 98.95% by weight of polymerized, ethylenically unsaturated, acid group-containing monomers or their salts or polymerized, ethylenically unsaturated monomers containing a protonated or quaternized nitrogen, or mixtures thereof, particular preference being given to mixtures containing at least ethylenically unsaturated monomers containing acid groups, preferably acrylic acid,
• 2. (α2) 0 to 70% by weight, preferably 1 to 60% by weight and particularly preferably 1 to 40% by weight of polymerized, ethylenically unsaturated monomers copolymerizable with (α1),
• 3. (α3) 0.001 to 10% by weight, preferably 0.01 to 7% by weight and particularly preferably 0.05 to 5% by weight of one or more crosslinking agents, and
• 4. (α4) 0 to 20% by weight, preferably 0.01 to 7% by weight and particularly preferably 0.05 to 5% by weight of one or more adjuvants, the sum of the amounts by weight (α1) to ( α4) is 100% by weight.

It is preferred according to the invention that at least 50 mol% is preferred at least 90 mol% and particularly preferably at least 99.9 mol% of the Monomers in the polymer (a1) are water-soluble.

The monoethylenically unsaturated, acid group-containing monomers (α1) can partially or completely, preferably partially neutralized. Preferably are the monoethylenically unsaturated monomers containing acid groups at least 25 mol%, particularly preferably at least 50 mol% and above also preferably neutralized to 50-90 mol%. The neutralization takes place preferably before the polymerization. The neutralization can also be carried out with Alkali metal hydroxides, alkaline earth metal hydroxides, ammonia and Carbonates and bicarbonates are made. Any other base is also conceivable, which forms a water-soluble salt with the acid. Mixed neutralization too with different bases is conceivable. Neutralization with is preferred Ammonia or with alkali metal hydroxides, particularly preferably with Sodium hydroxide or with ammonia.

Preferred monoethylenically unsaturated monomers containing acid groups (α1) are acrylic acid, methacrylic acid, ethacrylic acid, α-chloroacrylic acid, α-cyanoacrylic acid, β-methylacrylic acid (crotonic acid), α-phenylacrylic acid, β-acryloxypropionic acid, sorbic acid, α-chlorosorbic acid, 2'- Methyl isocrotonic acid, cinnamic acid, p-chlorocinnamic acid, β-stearyl acid, itaconic acid, Citraconic acid, mesaconic acid, glutaconic acid, aconitic acid, maleic acid, Fumaric acid, tricarboxyethylene and maleic anhydride, being acrylic acid as well as methacrylic acid and acrylic acid are particularly preferred.

In addition to these monomers containing carboxylate groups are considered to be monoethylenic unsaturated monomers (α1) containing acid groups, furthermore ethylenically unsaturated sulfonic acid monomers or ethylenically unsaturated Phosphonic acid monomers preferred.

Ethylenically unsaturated sulfonic acid monomers are allylsulfonic acid or aliphatic or aromatic vinyl sulfonic acids or acrylic or methacrylic sulfonic acids preferred. As aliphatic or aromatic Vinyl sulfonic acids are vinyl sulfonic acid, 4-vinylbenzyl sulfonic acid, Vinyltoluenesulfonic acid and stryrolsulfonic acid are preferred. As an acrylic or Methacrylic sulfonic acids are sulfoethyl (meth) acrylate, sulfopropyl (meth) acrylate and, 2-hydroxy-3-methacryloxypropylsulfonic acid. As (Meth) acrylamidoalkylsulfonic acid is 2-acrylamido-2-methylpropanesulfonic acid prefers.

Furthermore, ethylenically unsaturated phosphonic acid monomers, such as Vinylphosphonic acid, allylphosphonic acid, vinylbenzylphosphonic acid, (Meth) acrylamidoalkylphosphonic acids, acrylamidoalkyldiphosphonic acids, phosphonomethylated vinylamines and (meth) acrylicphosphonic acid derivatives prefers.

As ethylenically unsaturated monomers containing a protonated nitrogen (α1) are preferably dialkylaminoalkyl (meth) acrylates in protonated form, for example dimethylaminoethyl (meth) acrylate hydrochloride or Dimethylaminoethyl (meth) acrylate hydrosulfate, as well as dialkylaminoalkyl (meth) acrylamides in protonated form, for example dimethylaminoethyl (meth) acrylamide hydrochloride, dimethylaminopropyl (meth) acrylamide Hydrochloride, dimethylaminopropyl (meth) acrylamide hydrosulfate or Dimethylaminoethyl (meth) acrylamide hydrosulfate is preferred.

As ethylenically unsaturated, containing a quaternized nitrogen Monomers (α1) are dialkylammonium alkyl (meth) acrylates in quaternized form, for example trimethylammonium ethyl (meth) acrylate methosulfate or Dimethylethylammoniumethyl (meth) acrylate ethosulfate and (Meth) acrylamidoalkyl dialkylamines in quaternized form, for example (Meth) acrylamidopropyltrimethylammonium chloride, Tremethylammoniumethyl (meth) acrylate chloride or (meth) acrylamidopropyltrimethylammonium sulfate prefers.

It is preferred according to the invention that the polymer is at least 30% by weight, preferably at least 50% by weight and more preferably also there is at least 90% by weight of monomers containing carboxylate groups. It is According to the invention, it is particularly preferred that the polymer is at least 30% by weight, preferably consists of at least 50 wt .-% of acrylic acid which preferably at least 20 mol%, particularly preferably at least 50 mol% is neutralized.

As monoethylenically unsaturated monomers (α2) copolymerizable with (α1) acrylamides, methacrylamides and vinylamides are preferred.

Possible (meth) acrylamides are besides acrylamide and methacrylamide alkyl substituted (meth) acrylamides or aminoalkyl substituted derivatives of (Meth) acrylamides, such as N-methylol (meth) acrylamide, N, N-dimethylamino (meth) acrylamide, dimethyl (meth) acrylamide or diethyl (meth) acrylamide. Possible vinylamides are, for example, N-vinylamides, N-vinylformamides, N-vinyl acetamides, N-vinyl-N-methylacetamides, N-vinyl-N-methylformamides, Vinylpyrrolidone. Acrylamide is particularly preferred among these monomers.

Furthermore, as monoethylenically unsaturated, with (α1) copolymerizable monomers (α2) water-dispersible monomers prefers. As water-dispersible monomers are acrylic acid esters and Methacrylic acid esters, such as methyl (meth) acrylate, propyl (meth) acrylate or Butyl (meth) acrylate, and also vinyl acetate, styrene and isobutylene are preferred.

Crosslinkers (α3) preferred according to the invention are compounds which at least have two ethylenically unsaturated groups within one molecule (Crosslinker class I), compounds that have at least two functional groups have that with functional groups of the monomers (α1) or (α2) in one Condensation reaction (= condensation crosslinker), in an addition reaction or can react in a ring opening reaction (crosslinker class II), Compounds which have at least one ethylenically unsaturated group and at least one functional group with functional groups of Monomers (α1) or (α2) in a condensation reaction, in one Addition reaction or can react in a ring opening reaction (Crosslinker class III), or polyvalent metal cations (Crosslinker class IV). The crosslinking class I crosslinking of the polymers through the radical polymerization of the ethylenically unsaturated groups of the crosslinker molecule with the monoethylenically unsaturated monomers (α1) or (α2) reached while at the compounds of crosslinker class II and the polyvalent metal cations crosslinker class IV by crosslinking the polymers Condensation reaction of the functional groups (crosslinker class II) or through electrostatic interaction of the polyvalent metal cation (crosslinking class IV) is achieved with the functional groups of the monomers (α1) or (α2). Correspondingly, there is a crosslink class III Crosslinking of the polymer both by radical polymerization of the ethylenically unsaturated group as well as by condensation reaction between the functional group of the crosslinker and the functional groups of the Monomers (α1) or (α2).

Examples of crosslinker class I compounds Alkenyldi (meth) acrylates, for example ethylene glycol di (meth) acrylate, 1,3-propylene glycol di (meth) acrylate, 1,4-butylene glycol di (meth) acrylate, 1,3-butylene glycol di (meth) acrylate, 1,6-hexanediol di (meth) acrylate, 1,10-decanediol di (meth) acrylate, 1,12-dodecanediol di (meth) acrylate, 1,18-octadecanediol di (meth) acrylate, Cyclopentanediol di (meth) acrylate, neopentyl glycol di (meth) acrylate, methylenedi (meth) acrylate or pentaerythritol di (meth) acrylate, alkenyldi (meth) acrylamides, for example N-methyldi (meth) acrylamide, N, N'-3-methylbutylidenebis (meth) acrylamide, N, N'- (1,2-di-hydroxyethylene) bis (meth) acrylamide, N, N'-hexamethylenebis (meth) acrylamide or N, N'-methylenebis (meth) acrylamide, Polyalkoxy di (meth) acrylates, for example diethylene glycol di (meth) acrylate, Triethylene glycol di (meth) acrylate, tetraethylene glycol di (meth) acrylate, Dipropylene glycol di (meth) acrylate, tripropylene glycol di (meth) acrylate or Tetrapropylene glycol di (meth) acrylate, bisphenol A di (meth) acrylate, ethoxylated bisphenol A di (meth) acrylate, benzylidinedi (meth) acrylate, 1,3-di (meth) acryloyloxypropanol-2, Hydroquinone di (meth) acrylate, di (meth) acrylate ester preferably with 1 to 30 moles of alkylene oxide per hydroxyl group oxyalkylated, preferably ethoxylated Trimethylolpropane, thioethylene glycol di (meth) acrylate, Thiopropylene glycol di (meth) acrylate, thiopolyethylene glycol di (meth) acrylate, Thiopolypropylene glycol di (meth) acrylate, divinyl ether, for example 1,4-butanediol divinyl ether, Divinyl esters, for example divinyl adipate, alkanedienes, for example butadiene or 1,6-hexadiene, divinylbenzene, di (meth) allyl compounds, for example Di (meth) allyl phthalate or di (meth) allyl succinate, homo- and copolymers of Di (meth) allyldimethylammonium chloride and homo- and copolymers of Diethyl (meth) Allylaminomethyl (meth) acrylatammoniumchlorid, Vinyl (meth) acrylic compounds, for example vinyl (meth) acrylate, (Meth) allyl (meth) acrylic compounds, for example (meth) allyl (meth) acrylate, with 1 to 30 moles of ethylene oxide per hydroxyl group of ethoxylated (meth) allyl (meth) acrylate, Di (meth) allyl esters of polycarboxylic acids, for example di (meth) allyl maleate, Di (meth) allyl fumarate, di (meth) allyl succinate or di (meth) allyl terephthalate, Compounds with 3 or more ethylenically unsaturated, radical polymerizable groups such as glycerol tri (meth) acrylate, (meth) acrylate esters with preferably 1 to 30 moles of ethylene oxide per hydroxyl group Glycerol, trimethylolpropane tri (meth) acrylate, tri (meth) acrylate ester of preferably oxyalkylated with 1 to 30 mol of alkylene oxide per hydroxyl group, preferably ethoxylated trimethylolpropane, trimethacrylamide, (Meth) allylidenedi (meth) acrylate, 3-allyloxy-1,2-propanediol di (meth) acrylate, Tri (meth) allyl cyanurate, tri (meth) allyl isocyanurate, pentaerythritol tetra (meth) acrylate, Pentaerythritol tri (meth) acrylate, (meth) acrylic acid ester with preferably 1 to 30 moles of ethylene oxide per hydroxyl group of oxyethylated pentaerythritol, tris (2- hydroxyethyl) isocyanurate tri (meth) acrylate, trivinyl trimellitate, tri (meth) allylamine, Di (meth) allylalkylamines, for example di (meth) allylmethylamine, Tri (meth) allyl phosphate tetra (meth) allylethylenediamine, poly (meth) allyl ester, Tetra (meth) allyloxyethane or tetra (meth) allylammonium halide.

Preferred compounds of crosslinker class II are compounds which have at least two functional groups which are in one Condensation reaction (= condensation crosslinker), in an addition reaction or in a ring opening reaction with the functional groups of the monomers (α1) or (α2), preferably react with acid groups, the monomers (α1) can. In these functional groups of the compounds of the crosslinking class II is preferably alcohol, amine, aldehyde, glycidyl, Isocyanate, carbonate or epichlor functions.

Examples of crosslinker class II include polyols, for example ethylene glycol, polyethylene glycols such as diethylene glycol, Triethylene glycol and tetraethylene glycol, propylene glycol, polypropylene glycols such as dipropylene glycol, tripropylene glycol or tetrapropylene glycol, 1,3-butanediol, 1,4-butanediol, 1,5-pentanediol, 2,4-pentanediol, 1,6-hexanediol, 2,5-hexanediol, glycerin, polyglycerin, trimethylolpropane, polyoxypropylene, Oxyethylene-oxypropylene block copolymers, sorbitan fatty acid esters, Polyoxyethylenesuritan fatty acid esters, pentaerythritol, polyvinyl alcohol and Sorbitol, amino alcohols, for example ethanolamine, diethanolamine, Triethanolamine or propanolamine, polyamine compounds, for example Ethylene diamine, diethylene triaamine, triethylene tetraamine, tetraethylene pentaamine or pentaethylene hexamine and their reaction products with epichlorohydrin, Polyglycidyl ether compounds such as ethylene glycol diglycidyl ether, Polyethylene glycol diglycidyl ether, glycerol diglycidyl ether, glycerol polyglycidyl ether, Pentareritrite polyglycidyl ether, propylene glycol diglycidyl ether, Polypropylene glycol diglycidyl ether, neopentyl glycol diglycidyl ether, Hexanediol glycidyl ether, trimethylolpropane polyglycidyl ether, Sorbitol polyglycidyl ether, diglycidyl phthalate, Adipic acid diglycidyl ether, 1,4-phenylene-bis (2-oxazoline), glycidol, polyisocyanates, preferably diisocyanates such as 2,4-toluenediisocyanate and Hexamethylene diisocyanate, polyaziridine compounds such as 2,2-bishydroxymethylbutanol-tris [3- (1-aziridinyl) propionate], 1,6-hexamethylene diethylene urea and diphenylmethane-bis-4,4'-N, N'-diethylene urea, halo epoxides for example epichlorohydrin and epibromohydrin and α-methylepichlorohydrin, Alkylene carbonates such as 1,3-dioxolan-2-one (ethylene carbonate), 4-methyl-1,3- dioxolan-2-one (propylene carbonate), 4,5-dimethyl-1,3-dioxolan-2-one, 4,4-dimethyl-1,3-dioxolan-2-one, 4-ethyl-1,3-dioxolan-2-one, 4-hydroxymethyl-1,3- dioxolan-2-one, 1,3-dioxan-2-one, 4-methyl-1,3-dioxan-2-one, 4,6-dimethyl-1,3- dioxan-2-one, 1,3-dioxolan-2-one, poly-1,3-dioxolan-2-one, polyquaternary amines such as condensation products of dimethylamines and epichlorohydrin. As Compounds of crosslinker class II are also polyoxazolines such as 1,2- Ethylene bisoxazoline, crosslinker with silane groups such as γ Glycidoxypropyltrimethoxysilane and γ-aminopropyltrimethoxysilane, Oxazolidinones such as 2-oxazolidinone, bis- and poly-2-oxazolidinorie and Diglycol silicates preferred.

As class III compounds, hydroxyl- or amino group-containing esters the (meth) acrylic acid, such as 2-hydroxyethyl (meth) acrylate, and (meth) acrylamides containing hydroxyl or amino groups, or Mono (meth) allyl compounds of diols preferred.

The polyvalent metal cations of crosslinker class IV are preferably derived from mono- or polyvalent cations, the monovalent in particular from alkali metals such as potassium, sodium, lithium, lithium being preferred. Preferred divalent cations are derived from zinc, beryllium, alkaline earth metals, such as magnesium, calcium, strontium, magnesium being preferred. Other higher-value cations which can be used according to the invention are cations of aluminum, iron, chromium, manganese, titanium, zirconium and other transition metals, and also double salts of such cations or mixtures of the salts mentioned. Aluminum salts and alums and their different hydrates such as, for. B. AlCl ₃ × 6H ₂ O, NaAl (SO ₄ ) ₂ × 12 H ₂ O, KAl (SO ₄ ) ₂ × 12 H ₂ O or Al ₂ (SO ₄ ) ₃ X 14-18 H ₂ O are used.

Al ₂ (SO ₄ ) ₃ and its hydrates are particularly preferably used as crosslinking agents of crosslinking class IV.

Preferred polymers (a1) are polymers obtained by crosslinking the following Crosslinker classes or by crosslinkers of the following combinations of Networking classes are networked: I, II, III, IV, I II, I III, I IV, I II III, I II IV, I III IV, II III IV, II IV or III IV. The above combinations of Crosslinker classes each represent a preferred embodiment of Crosslinking a polymer.

Further preferred embodiments of the polymers (a1) are polymers which by any of the aforementioned crosslinkers of the crosslinking classes I are networked. Among them, water-soluble crosslinkers are preferred. In this Are N, N'-methylenebisacrylamide, Polyethylene glycol di (meth) acrylates, triallylmethylammonium chloride, Tetraallylammonium chloride and with 9 moles of ethylene oxide per mole of acrylic acid Allylnonaethylene glycol acrylate is particularly preferred.

The adjuvants (α4) in the polymers (a1) are preferably fillers, Odor binders, dyes, antifreeze, binders, UV stabilizers or Contain antioxidants.

The hydrophobic organic liquid (a2) can be any hydrophobic organic liquid known to the person skilled in the art as the continuous phase in inverse emulsion polymerization. Preferred hydrophobic, organic liquids (a2) are aromatic and aliphatic linear, branched and cyclic hydrocarbons. These include hydrocarbons or their mixtures, preferably n- and / or iso-paraffins, ligroin with a boiling range from 150 to 200 ° C., in particular also distillates from predominantly paraffinic and naphthenic-based petroleum, such as the so-called white oils. Furthermore, linear and branched liquid esters of natural and synthetic origin can also be contained as a continuous phase. This includes the natural oils, the main constituent of which are primarily triglycerides with a mono- or polyunsaturated carboxylic acid part derived from saturated C ₁₀ to C ₃₀ fatty acids, and the esters made therefrom with aliphatic alcohols. Preferred hydrohobic organic liquids (a2) are also those aliphatic dicarboxylic acid esters which are described in DE 35 24 950 A1, the disclosure of which is hereby introduced as a reference. Mixtures of the abovementioned liquids can also be present as hydrophobic, organic liquid (a2) in the water-in-oil polymer dispersions according to the invention.

As water-in-oil emulsifiers (a3), those skilled in the art as water-in-oil Emulsifiers used in inverse emulsion polymerization Compounds in the water-in-oil polymer dispersion according to the invention be included. Water-in-oil emulsifiers (a3) with HLB values are preferred from 1 to 10, preferably from 2 to 8 and more preferably from 3 to 5 (Römpps Chemie Lexikon, 10th edition, p. 1764, Franck'sche Verlagshandlung Stuttgart). Preferred emulsifiers are e.g. B. sorbitan monostearate and Sorbitan monooleate, fatty acid glycerides, di- and polyglycerol, sorbitol, sorbitan and Addition products of alkylene oxides such as ethylene oxide and propylene oxide higher linear and branched alcohols or alkylphenol. Still as water In-oil emulsifiers are preferred polymeric emulsifiers, as described for example in DE-C-24 12 266 are described, the disclosure of which is hereby incorporated by reference is introduced. Very particularly preferred emulsifiers are polymers Emulsifiers with the trade name Hypermer® (ICI, London, England). As Water-in-oil emulsifiers (a3) can also contain mixtures of different Water-in-oil emulsifiers in the water-in-oil according to the invention Polymer dispersion may be included.

As oil-in-water emulsifiers (a4), the person skilled in the art can use them as inverters Reverse emulsifiers, or as activators of water-in-oil Compounds used in the polymer dispersions in the invention Water-in-oil polymer dispersion may be included. Ethoxylated are preferred Fatty alcohols, particularly preferably ethoxylated fatty alcohols, which consist of linear and / or branched fatty alcohols with an alkyl chain length of more than 11 Carbon atoms are made. Are also preferred Ethoxylation products of highly branched alcohols by oxosynthesis are accessible, such as preferably isotridecyl alcohol. Particularly preferred as Inverters are ethoxylation products of higher, once branched Alcohols available through Guerbet synthesis. As an oil-in-water Emulsifiers (a4) can also contain mixtures of different oil-in-water Emulsifiers in the water-in-oil polymer dispersion according to the invention be included.

As additives (a5) in the water-in-oil according to the invention Polymer dispersions preferably the compounds known to the person skilled in the art for complexing foreign ions, such as Versenex® 80 (Dow Chemical Corp.), and chain regulators such as formic acid his.

As auxiliaries (A2) are in the composition according to the invention preferably binders, adhesives, wetting agents, spreading agents, antifreeze agents, Dyes, antioxidants, fertilizers, nutrients, buffer compounds, Hormones, especially growth substances, as well as antibiotics, gelling agents, Contain UV stabilizers or adhesion promoters. Fertilizers can be organic and / or inorganic fertilizers, preferably commercially available fertilizers, particularly preferred commercially available water-soluble fertilizers, which in addition Carriers nitrogen, phosphorus, potassium and / or other macro and / or Micronutrients as individual or mixed components with other nutrients contain.

As water (A3) is preferred in the composition according to the invention Tap water included.

Possible fungal organisms or their constituents (A4) which are preferably present in the composition according to the invention are:
Alternaria spp. (e.g. angustievoidea, A. agripestis, A. cassiae) HB; Ampelomyces spp. (e.g. quisqualis FU); Ascochyta spp. (e.g. caulina) HB; Colletotrichum spp. (e.g. BC cocodes, C. orbicolare, C. gloeosporioides, C gloeosporioides f. sp. aeschnynomene, C. gloeosporioides f. sp. cuscutae, C. gloeosporioides f. sp. malva) HB, Cercospora spp. (e.g. BC rodmanii) HB; Drechslera spp. HB; Fusarium spp. FU, HB, IN (e.g. F oxysporum, F. oxysporum f. Sp. Orthoceras, F. vasinfectum, F. tumidum HB), Gliocladium catenulatum FU; Melampsora spp. (e.g. BM euphorbiae HB), Microphaeropsis spp. HB, Myrothecizum versucaria HB, Paecilomyces spp. (e.g. Paecilomyces lilacinus, NE), Phlebiopsis gigantea FU; Phomopsis spp .. (e.g. Phomopsis convolvulus HB), Phytophthora spp. (e.g. BP citrophthora, P. palmivora) HB; Pleiochaeta setosa HB, Prospodium tuberculatum HB, Puccinia spp. (e.g. BP chondrillinae, P. acroptili, P. canaliculata, P. centaureae, P. punctiformis, P. jaceae) HB, Rhizoctonia solani HB, Sclerotinia spp. (e.g. BS sclerotiorum) HB, Septoria spp. HB, Streptomyces griseoviridis FU; Trichoderma spp. (e.g. BT harzianum; T. polysporum; T. viride) FU; Verticilliuni spp. (e.g. Vb dahliae, Vb. lecanii) FU, IN.

The following fungal organisms (A4) are preferably used, among others:
Deuteromycetes, for example Acremonium spp. (e.g. Berkeleyanum, A. furcatum, A. psammosporum, A. roseum), Acrodontium spp. (e.g. A, crateriform, Akanthomyces gracilis, Aphanocladium album, Arthrobotrys spp. (e.g. BA amerospora, A. brochopaga, A. cladodes, A. conoides, A. dactyloides, A. musiformis, A. oligospora, A. oligospora, A. psychrophilum, A. superba, A. thaumasia), Aschersonia spp. (e.g. BA aleyrodis, A. goldiana, A. insperata, A. turbinata), Aspergillus (e.g. BA clavatus, A. flavus, A. niger, A. ochraceus, A. parasiticus, A. tamarii), Beauvaria spp. (e.g. amorpha, bassiana, brongniartii caledonica, tenella, velata, vermiconia), Calcarisporium spp. (e.g. BC ovalisporum), Candida spp. , Cladosporium spp., (E.g. BC cladosporioides), Culicinomyces spp. (E.g. BC bisporalis clavisporus), Dactylaria spp. (E.g. BD candida), Dactylella spp. (E.g. BD aphrobrocha, D. leptospora, D. lobata, D. oxyspora), Drechmeria spp. (E.g. BD coniospora), Duddingtonia spp. (E.g. BD flagrans), Engyodontium spp. (E.g. BE aranearum), Fusarium spp. (E.g. BF acuminatum, F. avenaceum, F. coccophilum, F. lateritium, F. moniliforme, F. moniliforme var. intermedium, F. nygamai, F. oxysporum, F. polyphialidicum, F. sambucinum, F. semitectum, F. solani, F. subglutinans), Geniculifera spp. (e.g. BG paucispora), Geotrichum spp., Gibellula spp. (e.g. BG clavulifera var. alba, G. pulchra), Gliocladium spp, (e.g. BG roseum), Harposporium spp. (e.g. BH anguillulae, H. arcuatum, H. cerberi, H. cycloides, H. helicoides, H. janus, H. leptospira, H. lilliputanum, H. subuliforme), Hirsutella spp. (e.g. BH bogoriensis, H. brownorum, H. citriformis, H. fusiformis, H. gigantea, H. gucyana, H. haptospora, H. illustris, H. kirchneri, H. nodulosa, H. radiata, H. repens, H. rhossiliensis, H. satumaensis, H. strigosa, H. subulata, H. thompsonii, H. thompsonii var. Synnematosa, H. versicolor, H verticilloides), Humicola spp., Hymenostilbe spp. (e.g. BH verrucosa), Mariannaea spp. (e.g. BM elegans [Teleomorph: Nectria mariannaeae], M. pruinosa), Metarhician spp. (e.g. BM album, M. anisopliae, M. anisopliae var. anisopliae, M. anisopliae var. frigidum, M. anisopliae vor. majus, M. flavoviride, M. flavoviride var. flavoviride, M. flavoviride var. minus, M . taii), Microhilum spp. (e.g. BM oncoperae), Monacrosporium spp. (e.g. BM doedycoide, M. elegans, M. ellipsosporum, M. eudematum, M. gephyropagum, M. parvicollis, M. thaumasium), Myriodontium spp. (e.g. BM keratinophilum), Nematoctonus spp. (e.g. BN concurrens, N. leiosporus, N. leptosporus), Nomuraea spp. (e.g. BN anemonoid, N. atypicola, N. rileyi), Ostracoderma spp., Paecilomyces spp. (e.g. BP amoenorosens, P. andoi, P. canadensis, P. farinosus, P. fumosoroseus, P. javanicccs, P. lilacinus, P. marquandii, P. reniformis, P. tenuipes, P. viridis), Penicillium spp. (e.g. BP thomii), Phialophora spp. (e.g. BP malorum), Phoma spp. (e.g. BP cava), Plesiospora spp. (e.g. BP globosa), Polycephalomyces spp. (e.g. BP formosus, P. tomentosus), Pseudogibellula spp. (e.g. BP formicarum), Rotiferophthora spp. (e.g. BR amamiensis, R. angustispora, R. japonica, R. lacrima, R. minutispora), Scopulariopsis spp., Sorosporella spp., (e.g. BS uvella), Sporothrix spp. (e.g. BS insectorum), Stachybotrys spp., Stilbella spp. (e.g. (S. buquetti), Syngliocladium spp., Synnematium spp. (e.g. BS jonesii), Tolypocladium spp. (e.g. BT cylindrosporum, T. extinguens, T. geodes, T. lignicola, T. microsporum, T. nubicola, T. parasiticum, T. tundrense), Trichoderma spp. (E.g. BT lignorum), Trichothecium spp. (E.g. BT roseum), Tritirachium spp. (E.g. BT isariae), Verticillium spp. (E.g. BV aranearum, V. bactrosporum, V. balanoides, V. cephalosporum, V. chlamydosporium, V. cinnamoneum, V. coccosporum, V. epiphytum, V. fungicola, V. fungicola var. flavidum, V. fusisporum, V. indicum, V insectorum, V. lamellicola, V. lecanii, V. pseudohemipterigenum, V. psalliotae), Zygomycetes, for example Basidiobolccs spp. (e.g. BB haptosporus, B. microsporus, B. ranarum), Batkoa spp. (e.g. BB apiculata, B. gigantea, B. major), Conidiobolus spp. (E.g. BC adiaeretus, C. bangalorensis, C. brefeldianus, C. coronatus, C. firmipilleus, C. lachnodes, C. lamprauges, C. obsczcrus [Synonym: Entomophthora thaxteriana ], C. osmodes, C. pseudapiculatus, C. pum ilus, C. rhysosporus, C. thromboides [synonyms: Entomophthora virulenta, E. pyriformis, E. destruens]), Entomophaga spp. (z. B. asiatica, E. aulicae, E. australiensis, E. calopteni, E. conglomerata, E. grylli, E. macleodii E. maimaiga, E. praxibuli, E. tabanivora, E. tenthredinis), Entomophthora spp. (e.g. chromaphidis, E. culicis, E. muscae, E. planchoniana, E. schizophorae), Erynia spp. (e.g. aquatica, E. conica, E. curvispora, E. ovispora, E. rhizospora, E. sciarae), Eryniopsis spp. (e.g. BE caroliniana, E. ptychopterae), Furia spp. (e.g. FF americana, F. crustosa, F. ithacensis, F. neopyralidartcm, F. pieris, F. virescens), Macrobiotophthora spp. (e.g. BM vermicola), Massospora spp. (e.g. BM cicadina, M. levispora), Mortierella spp. (e.g. BM claussenii, M. histoplasmatoides, M. hyalina), Neozygites spp. (e.g. BN floridana, N. fresenii, N. parvispora, N. tetranychi, N. turbinata), Pandora spp. (e.g. BP blunckii, P. bullata, P. delphacis, P. dipterigena, P. echinospora, P. kondolensis, P. neoaphidis, P. nouryi), Schizangiella spp. (e.g. BS serpentis), Smittium spp. (e.g. BS culicis, S. culisetae), Sporodiniella spp. (e.g. BS umbellata), Strongwellsea spp. (e.g. BS castrans), Zoophthora spp. (e.g. ZZ anglica, Z. aphidis, Z. lanceolata, Z. occidentalis, Z. phalloides, Z. phytonomi, Z. radicans), Oomycetes, for example Aphanomyces spp., Crypticola spp. (e.g. BC clavulifera), Lagenidium spp. (e.g. BL caudatum, L. giganteum), Leptolegnia spp., Saprolegnia spp., Pyrenomycetes, for example Atricordyceps spp. (e.g. harposporifera), Cordycepioideus spp. (e.g. BC bisporus); Cordyceps spp. (e.g. BC aphodii, C. militaris, C. ophioglossoides, C. roseostromata, C. variabilis), Torrubiella spp. (e.g. BT homopterorum, T. ratticaudata), Chytridiomycetes, for example Catenaria spp. (e.g. BC anguillulae), Coelomycidium spp. (e.g. C simulii), Plectomycetes, e.g. Ascosphaera spp. (e.g. BA aggregata, A. apis, A. atra, A. duoformis, A. flava, A. major, A. proliperda), Ascomycetes, for example Syspastospora spp. (e.g. BS parasitica), or Basidiomycetes, for example Filobasidiella spp. (e.g. arachnophila).

Each of the above-mentioned fungal organisms (A4) also contributes the other components (A1) to (A3) a preferred embodiment of the composition according to the invention.

Furthermore, each and every component of the fungus listed above Organisms (A4) with the other components (A1) to (A3) are preferred Embodiment of the composition according to the invention.

In a further embodiment of the invention, the Composition at least two, preferably different fungal Organisms or components of fungal organisms.

In another embodiment of the invention, the Composition at least three, preferably different fungal Organism or components of fungal organisms.

In a further embodiment of the invention, the Composition at least four, preferably different fungal Organisms or components of fungal silver organisms.

In a further, preferred embodiment, the invention includes Composition in addition to components (A1) to (A4) also from the fungal organism or its components (A4) various active ingredients (A5). These are preferably in an amount in a range of 0.0001 to 10% by weight, particularly preferably in a range from 0.001 to 5% by weight, each based on the total weight of the composition from (A1) to (A5), contain.

As from the fungal organism or its components (A4) various active ingredients (A5) are preferred acaricides (AC), algicides (AL), attractants (AT), bactericides (BA), fungicides (FU), herbicides (HB), Insecticides (IN), molluscicides (MO), nematicides (NE), pheromones (PH), Repellents (RE), resistance inductors (RI), rodenticides (RO), savener (SA), Sterilants (ST), synergies (SY), viricides (VI), growth regulators (PG) or at least two of them. These include HB, FU, IN, NE or PG preferred and FU, IN or PG particularly preferred.

According to a particularly preferred embodiment, the term different from the fungal organism or its components (A4) Active ingredients all active ingredients known and suitable to those skilled in the art without Tebuconazole, imidacloprid, thiacloprid, trifloxystrobin and iprovalicarb Roger that.

According to a particularly preferred embodiment, the term different from the fungal organism or its components (A4) Active ingredients all active ingredients known and suitable to those skilled in the art without Azoxystrobin, Fludioxonyl, Mefenoxam, and Thiamethoxam understood.

According to another preferred embodiment, the term different from the fungal organism or its components (A4) Active ingredients all active ingredients known and suitable to those skilled in the art without Methoprene, Bacillus thuringienis israeliensis and Bacillus subtilis understood.

According to a further preferred embodiment, the term different from the fungal organism or its components (A4) Active ingredients all active ingredients known and suitable to those skilled in the art without Acephate and Pyriproxifen understood.

Furthermore, in one embodiment of the invention under the term of fungal organism or its components (A4) various active ingredients all active substances known and suitable to the person skilled in the art without endothall Dipotassium salt understood.

According to another preferred embodiment, the term different from the fungal organism or its components (A4) Active ingredients all active ingredients known and suitable to those skilled in the art without Novaluron understood.

In another embodiment of the composition according to the invention this includes at least two, preferably different, of the fungal organism or its components (A4) various active ingredients (A5).

In another further embodiment of the invention The composition includes at least three, preferably different from the fungal organism or its components (A4) various active ingredients (A5).

In a further embodiment of the composition according to the invention this includes at least four, preferably different, of the fungal organism or its components (A4) various active ingredients (A5).

Below are some preferred classes of active ingredients or active ingredient compounds as active ingredients (A5) different from the fungal organism or its components (A4), together with their use or uses:
Abamectine AC, IN; AC 92553, HB; Acephate IN; AC 382042 FU; Aceqinocyl AC; Acetamiprid IN; Acetochlor HB; N-Acetylthiazolidin-4-carboxylic acids; Acetoprole AC; Acilflorfen-Na HB; Acibenzolar-S-methyl FU, RI; Acifluorfen HB; Aclonifen HB; Acridinic bases RE; Acrinathrin IN, AC; Alachlor HB; Alanycarb IN; Aldicarb AC, NE, IN; Aldimorph FU; Alkyldimethylbenzylammonium chloride HB; Alkyldimethylethylbenzylammonium chloride HB; Alkyltrimethylammonium chloride BA, FU; Alkyltrimethylbenzylammonium chloride HB; Allidochlor, HB; Alloxydim HB; Allyl alcohol HB; Alphacypermethrin (= □ -Cypermethrin); Alphamethrin (= □ -Cypermethrin) IN; Aluminum ammonium sulfate RE; Aluminum phosphide IN, RO; Aluminum sulphate MO, PG; Ametryn HB; Amicarbazone HB; Amidosulfuron HB; Amino acids PG, RI; 2-aminobutane FU; DL-3 aminobutyric acid (3-ABS) RI, Amitraz AC, IN; Amitroles (= aminotriazoles) HB; Ammonium carbonates FU; Ammonium hydroxide FU; Ammonium sulphamate HB; Ammonium sulphate HB; Ammonium thiocyanate HB; Amosulfuron HB; Ampropylfos FU; Ancymidol PG; Andoprim FU; Anilazine FU; Anilofos HB; Anthracene oil IN, AC, HB, RO; Anthraquinone RE; Arachidonic acid RI, arsenic anhydride; Asulam HB; Atrazine HB; Azaconazole IN, FU; Azadirachtin IN; Azafenidin FU, HB; Azamethiphos IN; Azinphos-methyl IN, AC; Aziprotryne HB; Azocyclotin AC; Azoxystrobin FU; Bacillus subtilis culture substrates RI, BAS500F; Barban HB; Barium fluosilicate IN; Barium nitrate RE; Barium polysulphide IN, FU; BAY MKH 6561 HB; Beflubutamide HB; Benfluamide HB; Benalaxyl FU; Benazolin (-ethyl) HB; Bendiocarb IN; Benefin HB; Benbiclon / benzobicyelon HB; Benfluralin HB; Benfuracarb IN, NE; Benfuresate HB; Benodanil FU; Benomyl FU; Bensulfuron (-methyl) HB; Bensulide HB; Bensultap IN; Bentalurun FU; Bentazone IIB; Benzalkonium chloride HB; Benzamacril FU; Benzene- (1,2,3) -thiadiazole-7-carbothioic acid-S-methyl ester (BTH) RI, benzothiadiazole RI, benzoximate AC; Benzoylprop (ethyl) HB; Benzthiazuron HB; 6-benzyladenine PG; Benzofenap HB; Benzofluor PG, HB; 2-benzyl-4-chlorophenol FU; Bialaphos HB, FU; Bifenazate AC, IN; Bifenox HB; Bifenthrin IN, AC; Biloxazole FU; Binapacryl AC, FU; Bioallethrin IN; Bioresmethrin IN; Biphenyl FU; Bistrifluron IN; Bitertanol 386 FU; Blasticidin-S FU; Bordeaux mixture = calcium copper sulphate FU; Boric acid IN; BPMC IN; Brandol FU; Brassinolide PG; Brodifacoum RO; Brofenprox = Halfenprox; Bromacil HB; Bromadiolones RO, RE; Bromethalin RO, RE; Bromobutide HB; Bromocycles AC, IN; Bromofenoxime HB; Bromophos IN; Bromophos-ethyl IN; Bromopropylate AC; Bromoxynil HB; Bromuconazole FU; Bronopol FU, BA; Buminafos PG, HB; Bupirimate FU; Buprofezin AC, IN; Burgundy mixture FU; Butachlor HB; Butam (= tebutam); Butenachlor HB, FU; Buthidiazo HB; Buthiobate FU; Butocarboxime IN; Butoxyearboxim IN, AC; Butralin HB, PG; Buturon HB; sec-butylamine FU, IN; Cadusafos IN, NE; Calciferol RO; Calcium carbide RE; Caleium cyanamide HB; Calcium chloride FU, PG; Calcium copper oxychloride FU; Calcium copper sulfate FU; Calcium cyanide (see cyanides) IN, RO; Calcium phosphate RO; Calcium phosphide RO; Caloxidim HB; Captan FU; Captafol FU; Carbaryl IN, PG; Carbatene (see Metiram); Carbendazim FU; Carbetamide HB; Carbofuran IN, NE, AC; Carbondioxides IN, RO; Carbon disulfide IN, NE; Carbophenothione IN, AC; Carbosulfan IN, NE; Carboxin FU; Cartap (hydrochloride) IN; Carpropamid FU; Carvone FU; Cetrimide HB; Quinomethionate AC, FU; Chlomethoxyfen HB; Chloral-semi-acylal HB; Chloralose RO; Chloramben HB; Chlorates HB; Chlorobenzthiazon FU; Chlorbromuron HB; Chlorobufam HB; Chloretazate PG; Chloroethoxyfos IN; Chlorfenapyr AC, IN; Chlorfenazole FU; Chlorfenprop (methyl) HB; Chlorofenson IN, AC; Chlorfena HB; Chlorfenvinphos AC, IN; Chlorfluazuron IN; Chlorflurenol (chlorflurecol) HB, PG; Chloridazon HB; Chlormephos IN; Chlormequat (chloride) PG; Chlorobenzilate AC; Chlorobufam HB; Chlorofenizon = chlorofenson; 4-chloro-3-methylphenol FU; Chloroneb FU; p-chloronitrobenzene IN; Chlorophacinon RO; Chlorophenprop-methyl HB; Chlorophylline FU, BA; Chloropicrin NE, IN, FU; Chloropropylate AC; Chlorothalonil FU; Chloroxuron HB; Chlorphonium chloride PG; Chlorpropham PG, IIB; Chlorpyrifos IN, AC; Chlorpyrifos-methyl IN, AC; Chlorsulfuron HB; Chlorothal-dimethyl HB; Chlorothiamide HB; Chlorothiamidine IN; Chlorothiophos IN; Chlortoluron HB; Chlozolinate FU; Cholecalciferol RO; Choline chloride RO; Chromafenozide IN; Cimetacarb ethyl (see trinexapac); Cimidon-ethyl HB; Cinmethylin HB; Cinidon-ethyl HB; Cinosulfuron HB; Cintofen PG; Citronellol IN, RE; Ciz-zeathin PG; Clefoxydim HB; Clethodim 508 HB; Clodinafop (-propargyl) HB; Clofencet PG; Clofentezine AC; Clomazone HB; Clomeprop HB; Clopoxydim HB; Clopyralid HB; Clozylacon FU; Codlemone (cf. 8,10-dodecadien-1-ol) AT; Copper acetate FU; Copper ammonium carbonate FU; Copper □ -cyclodextrine hydroxide FU; Copper carbonate basic FU; Copper hydroxide BA, FU; Copper naphtenate FU, RE; Copper oxychloride FU; Copper salts of fatty and rosin acids FU; Copper sulfate AL, FU; Copper sulfate tribasic AL, FU; Coumachlor RO; Coumafuryl RO; Coumaphen (see warfarin); Coumatetralyl RO; 4-CPA (4-chlorophenoxyacetic acid) PG; p-cresyl acetate RE; Cresylic acid ST, FU; Crimidine RO; Cubiet FU; Cufraneb FU; Cuprammonium FU; Cuprous oxide FU; Cyanamide PG, HB; Cyanazine HB; Cyanides IN, RO; Cycloate HB; Cycloxydim HB; Cycloheximide FU; Cycloprothrin IN; Cycluron HB; Cyflufenamid FU; Cyfluthrin IN, AC; □ -Cyfluthrin IN; □ -Cyhalothrin IN; Cyhexatin AC; Cymoxanil FU; Cyprazine HB; Cypermethrin IN, AC; □ -Cypermethrin IN; □ -Cypermethrin IN; Cyproconazole FU; Cyprodinil FU; Cyprofuram FU; Cyromazine IN; Cysteine PG; 2,4-D HB, PG; DADZ (zinc dimethylditiocarbamate) RE; Dalapon (sodium) HB; Daminozide PG; Daphneöl RE; Dazomet NE, FU, HB, IN, ST; 2,4-DB HB; DCPA HB; DD NE, FU, IN; Debacarb FU; 1-decanol PG; 5-decen-1-ol AT; 5-decen-1-ylacetate AT; Decanoncsäure; DEH 112 FU, HB; Deltamethrin IN; Demetone-S-methyl IN, AC; Demeton-S-methyl sulphone IN; Denathonium benzoate RE; Desmedipham HB; Desmetryn HB; Diafenthiuron IN, AC; Dialifos IN, AC; Di-allate HB; Diammonium phosphate AC; Diazinon IN, AC; Dicamba HB; Dichlobenil HB; Dichlofenthion NE, IN; Dichlofluanid FU; Dichlone FU; Dichloran FU; p-dichlorobenzene RO; Dichlorobenzoic acid methyl ester FU; Dichlorophene AL, BA, HB, FU; 2,6-dichloroisonicotinic acid (INA, DCINA) RI, 1,2-dichloropropane IN, FU, ST; 1,3-dichloropropene NE, HB; 1,3-dichloropropene (cis) NE, HB; Dichlorprop HB; 2,2-dichloro-3,3-dimethylcyclopropylcarboxylic acid RI, dichloroprop-P HB; Dichlorvos IN, AC; Diclobutrazole FU; Diclofop (methyl) HB; Diclocymet FU; Dicloran FU; Diclomezine FU; Dicofol AC; Dicrotophos IN, AC; Dicyclopentadienes RE, PG; Didecyldimethylammonium chloride FU; Dienochlor AC, diethatyl (ethyl) HB; Diethion (see ethion); Diethofencarb FU; Difenacoum RO; Difenamide = diphenamide; Difenoconazole FU; Difenoxuron HB; Difenzoquate (methyl sulfate) HB, FU; Difethialon RO; Diflubenzuron IN; Diflufenican HB; Diflufenzopyr HB; Diflumetorim FU; Dimefluazole FU; Dipotassium hydrogen phosphate RI, dikegulac (sodium) PG; Dimefox AC, IN; Dimefuron HB; Dimepiperate HB; Dimethyl-p-menthen PG; Dimethachlor HB; Dimethenamid HB; Dimethipin PG, HB; Dimethirimol FU; Dimethoate IN, AC; Dimethomorph FU; Dimeturon HB; 3,7-dimethyl-2,6-octadienal AT; 3,7-dimethyl-2,6-octadien-1-ol AT; Dimexano HB; Dimoxystrobin FU; Diniconazole FU; Dinitramine HB; Dinobuton AC, FU; Dinocap FU, AC; Dinosep acetate HB; Dinoterb HB; Dioctyldimethylammonium chloride FU, BA; Dioxacarb IN; 1,7-dioxaspiro-5,5-undecane AT; Dioxathione AT; Dioxohexahydro-1,3,5-triazine RI, diphacinone RO; Diphenamide HB; DNOC IN, AC, HB; Diphenylamine FU, PG; 1,3-diphenylurea PG; Diquat (dibromide) HB; (Disodium) -ethylene-diammetetra-acetate and its salts HB; Dipyrithion BA, FU; Disodium octaborate HB; Disulfoton AC, IN; Ditalimfos FU; Dithianon FU; 2- (dithiocyanomethylthio) benzothiazole FU; Diuron HB; DNOC 1 N, AC, FU, HB; (42-9Z) -7,9-dodecadien-1-ol AT; (E) 7- (Z) 9-dodecadienyl acetate AT; (Z) -8-dodecenol AT; (Z) -5-dodecen-1-ylacetate AT; (Z) -8-dodecenyl acetate AT; (E / Z) -8-dodecenyl acetate AT; (Z) -9-dodecenyl acetate 422 AT; (E) -10-dodecenyl acetate AT; trans-9-dodecyl acetate AT; Dodecyl alcohol AT; Dodemorph FU; Dodine FU; DPX IN, HB; Drazoxolon FU; Dymrone HB; Ebufos (see Cadusafos); Eglinazin-ethyl HB; Edifenphos FU; Emamectin benzoate IN; Endosulfan IN, AC; Endothal AL, PG, HB; EI endotoxin of Bacillus thuringiensis IN; Enilconazole (cf. Imazalil); Epocholeon PG; Epoxiconazole FU; 7,8-epoxy-2-methyl-octadecane AT; EPTC HB; Esfenvalerat IN; Esprocarb HB; Etacelasil PG; Etacazazole FU; Ethaboxam FU; Ethalfluralin HB; Ethanethiol RO; Ethanol MO; Ethephon PG; Ethidimuron HB; Ethiozin HB; Ethiofencarb IN; Ethion IN, AC; Ethoxyfen HB; Ethirimol FU; Ethoate-methyl AC, IN; Ethofumesate HB; Ethoprophos NE, IN; Ethoxyquin FU, PG; Ethyl hexanoate FU, BA; Ethyl oleate PG; Etofenprox IN; Etoxazole AC, IN; Etridiazole FU; Etrimfos IN, AC; Eucalyptus oil RE; Farnesol AT, Famoxadone FU; Fatty acid esters IN, PG; Sodium salts of the fatty acids HB, FU, IN; Fatty alcohols PG; Fenapanil FU; Fenamidon FU; Fenaminosulf FU; Fenamiphos NE; Fenarimol FU; Fenazaflor AC; Fenazaquin AC; Fenbuconazole FU; Fenbutatin oxide AC; Fenfuram FU; Fenhexamide FU; Fenitropan FU; Fenitrothion IN, AC; Fenizon = Fenson; Fenoprop PG, HB; Fenothiocarb IN, AC; Fenoxanil FU; Fenoxaprop (ethyl) HB; Fenoxaprop-P (ethyl) HB; Fenoxycarb IN; Fenpiclonil FU; Fenpropathrin IN, AC; Fenthiapropyl-ethyl HB; Fenpropidin FU; Fenpropimorph FU; Fenpyroximate AC; Fenridazone PG; Fenson AC; Fenthion IN; Fenthiosulf IN; Fentin AL, MO, FU; Fentin acetate FU, AL, MO, HB; Fentin hydroxide FU, AL, MO, HB; Fenuron HB; Fenvalerate IN, AC; Ferbam FU; Ferimzone FU; Fipronil IN; Flamprop (isopropyl) HB; Flamprop (methyl) HB; Flamprop-M (isopropyl) HB; Flazasulforon HB; Flocoumafen RO; Flonicamide IN; Fluacrypyrim AC; Fluazifop (-butyl) HB; Fluazifop-P (-butyl) HB; Fluazinam FU; Flubenzimine AC; Flucarbazone HB; Fluchloralin HB; Flucycloxuron IN, AC; Flucythrinate IN; Fludioxonyl FU; Flufenoxuron AC, IN; Flumequine BA; Flumetover FU; Flufenacet HB; Flufenerim IN, Flufenpyr HB; Flumethralin PG; Fluometuron HB; Flumioxazin HB; Flumipropyn HB; Flumicloralyl HB; Flumetsulam HB; Fluorobentranil HB; Fluoroacetamide RO; Fluorodifene HB; Fluoroglycofene (-ethyl) HB; Flupoxam HB; Fluproxyfen IN; Fluquinconazole FU; Flurenol (flurecol) HB; Fluridone HB; Flurochloridone HB; Fluoroimide FU; Fluroxypyr HB; Flurprimidole PG; Flurtramon HB; Flusilazole FU; Flusulfamide FU; Flutenzine IN; Flutolanil FU; Flutriafol FU; (Tau) fluvalinate AC, IN; Focus HB; Folic acid PG; Folpet FU; Fomesafen HB; Fonofos IN; Foramsulfuron HB; Formaldehyde FU, BA, ST; Formetanate IN, AC; Formic acid IN; Formothion IN, AC; Fosamine (ammonium) HB; Fosetyl (aluminum) FU; Fosthiazate NE, IN; Fosthietan IN, NE; Formamsulfuron HB; Fuberidazole FU; Furalaxyl FU; Furametpyr FU; Furacarbonil FU; Furathiocarb IN; Furconazole-cis FU; Furathiocarb IN; Furconazole FU; Furfural HB; Furmecyclox FU; Furyloxyfen HB; Galacturonic acid RI, gallic acids and their derivatives RI, gamma-aminobutyric acid (GABA) RI, gelatin IN; Gentianic violet BA; Gibberellic acid PG; Gibberellin PG; Glucuronic acid RI, glufosinate (ammonium) HB; Glutaraldehyde FU, BA; Glutaraldehyde (see glutaraldehyde); Glyphosate (including trimesium salt) HB; Glyphosate (trimesium) (cf. glyphosate); Guazatin FU, RE; Halfenprox AC; Halofenozide IN; Haloxyfop HB; Haloxyfop-R HB; Haloxyfop-P-methyl HB; Haloxyfopethoxyethyl HB; Halosulfone HB; Harpin RI, Hemimellitic Acid RI, Heptenophos IN; HW 52 HB; Hexachlorobenzene FU; Hexachlorophene FU; Hexaconazole FU; cis-7, trans-11-hexadecadienyl acetate AT; (Z) -11-hexadecanol AT; Z-9-Hexadecenal AT; (7Z-11Z) -7,11-hexadien-1-ylacetate AT; Hexaflumuron IN; Hexazinone HB; Hexythiazox AC, IN; Hydramethylnon IN; hydrolyzed proteins AT; m-hydroxybenzoic acid RI, p-hydroxybenzoic acid RI, hydroxyisoxazole FU; Hydroxy MCPA PG; Hydroxyphenyl salicylamide FU; 8-hydroxyquinoline sulfates BA, FU; Hymexazole FU; IKF-916 FU; ILIA 0051 HB; Imazalil FU; Imazamethabenz (methyl) HB; Imazapyr HB; Imazaquin HB, PG; Imazethabenz HB; Imazethapyr HB, PG; Imibenconazole FU; Imidacloprid IN; Iminoctadine FU; Indolylbutylic acid PG; Indolyl acetic acid PG; Indoxacarb IN; Iodocarb FU; Iodine furnace AC, IN; Iodosulfuron HB; Ioxynil HB; Ipconazole FU; Iprobefos FU; Iprovalicarb FU; Iprodione FU; Iron d1 sodium EDTA HB; Iron II Sulphate HB, MO; Iron III sulphate HB; Isazofos IN, NE, HB; Isocarbamide HB; Isofenphos IN; Isolan IN; Isoprocarb IN; Isopropalin HB; Isoprothiolane FU; Isoproturon HB; Isouron, HB; Isoval RO; Isovaledione FU; Isoxaben HB; Isoxathione IN; Isoxapyrifop HB; JC 940 HB; Jasmonic acid RI, carbutilate HB; Kasugamycin FU, BA; KH 218 HB; Kinoprene IN; Kitazin P FU; Kresoxim-methyl FU; KZ-165 FU; Lactic acid PG; Lactofen HB; Lambda cyhalothrin IN; Lauryldimethylbenzylammonium bromide FU, BA; Lauryldimethylbenzylammonium chloride HB; Lecithin FU; Lenacil 163 HB; Lime phosphate PG; Limesulfur 17 FU, IN, AC; Lindane IN, RO; Linuron HB; Lufenuron AC, IN; Magnesium phosphide IN, RO; Malathion IN, AC; Maleic hydrazide PG; ManKupfer ("Man" for Mn) FU; Mancozeb FU; Maneb FU; MCPA HB; MCPA thioethyl HB, MO; MCPB HB; Mecarbam IN, AC; Mecoprop HB; Mecoprop-P HB; MCPA HB; MCPB HB; Mefenacet HB; Mefenoxam FU; Meferimzone FU; Mefluidide PG, HB; Mefluoxafop HB, mepanipyrim FU; Mefluidide HB, PG; Mellitic acid RI, mephospholan IN; Mepronil FU; Merphos PG; Mesosulfuron HB; Metalaxyl FU; Metalaxyl-M FU; Metaldehyde MO; Metam (sodium) FU, IN, HB, NE; Metamifop HB, metamitron HB; Metazachlor HB; Metconazole FU; Methabenzthiazuron HB; Methacrifos AC, IN; Methamidophos IN, AC; Mcthasulfocarb PG, FU; Methazole HB; Metriftiroxam FU; Methidathione IN, AC; Methiocarb IN, AC, MO, RE; Methomyl AC, IN; Methoprene IN; Methoprothryne HB; Methoxychlor IN; Methoxyfenozide IN; Methylarsonic acid (see MSMA); Methyl bromide FU, IN, NE, HB; Methylenebisthiocyanate FU; 7-methyl-3-methylene-7-octene-1-yl AT; Methylnaphthylacetamide PG; Methylnaphthyl acetic acid PG; Methyl-trans-6-nonenoate AT; Methyl nonyl ketone RE; Methyl isothiocyanate FU, NE, HB, IN; Metiram FU; Metobromuron HB; Metolachlor HB; Metomeclam FU; Metominostrobin FU; Metometuron (see tribenuron); Metosulam HB; Metoxuron HB; Metrafenone FU, metribuzin HB; Metsulfovax FU; Metsulfuron (methyl) HB; Mevinphos IN, AC; Milbemectin AC, 1N; Molinate HB; Monalide HB; Monocarbamide dihydrogen sulfate PG, HB; Monocrotophos AC, IN; Monolinuron HB; Monuron HB; MSMA HB; MIT-466 IN; Myclobutanil FU; Myclozolin FU; Nabam FU, HB, AL; Naled IN, AC; Naphthalene RE; 1-naphthylacetamide PG; 1-naphthyl acetic acid PG; Naphthylacetic acid ethyl ester PG; Naphthylacetic acid hydrazide PG; 2-naphthyloxyacetamide PG, HB; 2-naphthyloxyacetic acid PG; Napropamide HB; Naptalam HB; Sodium thiocyanate (cf. sodium thiocyanate); Neburon HB; Neoasozin FU; Nerolidol (cf. 3,7-dimethyl-2,6-octadien-1-ol); Nickel dimethyldithiocarbamate BA, FU; Nicobifene FU, nicosulfuron HB; Nicotine IN; Nicotinic acid and its derivatives FU, IN, RI, nipyraclofen HB; Nitenpyram IN; Nitraline HB; Nitrofen HB; Nitrofuorfen HB; Nitrothal (isopropyl) FU; NNF-9850 FU; trans-6-non-1-ol AT; Nonylphenol ether polyoxyethylene glycol PG; Nonylphenol ethoxylate FU; Norflurazon HB; Noruron HB; Novaluron IN; Noviflumuron IN, NSK 850 HB; Nuarimol FU; (Z, Z) octadienylacetate AT; (Z) -13-octadecanols AT; Octhilinone BA, FU; Octyldecyldimethylammonium chloride FU, BA; Ofurace FU; Omethoate IN, AC; Orbencarb HB; Organo mercury compounds FU; Oryzalin HB; Oxadiazon HB; Oxadixyl FU; Oxamocarb FU; Oxasulfuron HB, FU; Oxamyl AC, IN, NE; Oxine copper FU; Oxycarboxin FU; Oxydemeton-methyl IN, AC; Oxyfluorfen HB; Oxyquinoline FU; Oxytetracycline BA; Paclobutrazole PG; Papaine RO; Paraffin oil HB, IN, AC; Paraformaldehyde IN; Paraquat HB; Parathion IN, AC; Parathion-methyl IN, RE; PCPA (see 4-CPA) Pebulate HB; Pefurazoate FU; Pelargonic acid HB, PG; Penconazole FU; Pencycuron FU; Pendimethalin HB; Penoxsulam HB; Pentachlorophenol IN, FU, HB; Pentanochlor HB; 4-t-pentylphenol BA; Pepper IN; Perfluidone HB; Permethrin IN; Petroleum oils FU, HB, IN, AC; Phenazine oxides FU; Phenamiphos (see Fenamiphos); Phenisopham HB; Phenmedipham HB; Phenols HB, ST; Phenothiol (see MCPA thioethyl); Phenothrin IN; Phenthoate AC, IN; 2-phenylphenol (including the sodium salts) FU; Pherodim AT; Phloroglucin RI, Phorate IN; Phosalones IN, AC; Phosametine HB; Phosdiphen FU; Phosmet AC, IN; Phosphamidon IN, AC; Phosphoric acid and phosphorous acid RI, phoxime IN; Phthalide FU; Phycarin RI, Picloram HB; Picoxystrobin FU; Picolinafen HB; Piperophos HB; Piperalin FU; Pimaricin FU; Pirimicarb IN; Pirimiphos-ethyl IN; Pirimiphos-methyl AC, IN; Primisulforon HB; Plant oils IN, AC, OT, FU, PG; Polybutenes IN; Polyoxin FU; Polyram FU; Pyridalyl IN; Potassium chlorate (see chlorates); Potassium permanganate FU, BA, MO; Potassium soap (cf. fatty acid salts of potassium); Potassium sorbate FU; Pretilachlor HB; Primisulfuron HB; Probenazole BA, FU; Prochloraz FU; Procyazin HB; Procymidone FU; Prodiamine HB; Profenofos AC, IN; Profluazole HB; Profluralin HB; Promecarb IN; Prometon HB; Prometryne HB; Pronamid HB; Pronumone AT; Propachlor HB; Propamocarb (- hydrochloride) FU; Propanil HB; Propham PG, HB; Propaphos IN; Propaquizafop HB; Propargite AC, AT; Propazine HB; Propetamphos AC, IN; Propham HB, PG; Propiconazole FU; Propineb FU; Propionic acid FU, BA; Propoxur IN; Propyl 3-t-butylphenoxyacetate PG; Propyzamide HB; Pyrazolate HB; Pyrazosulfuron-ethyl HB; Polyphenols RI, prosulfocarb HB; Prothiocarb FU; Prothiofos IN; Prothoate IN, AC; Protocatechic acids RI, pymetrozine IN; Pyraclofos IN, AC; Pyraclonil HB; Pyraflufen-ethyl; HB; Pyranocumann RO; Pyrazone (cf. chloridazon); Pyrazolynate HB; Pyrazophos FU; Pyrazoxyfen HB; Pyracarbolide FU; Pyrethrins AC, IN; Pyributicarb FU, HB; Pyridaben AC, IN; Pyridafenthion IN, Pyridalyl IN (formerly S 1812), AC; 2-pyridinecarboxaldehyde-4-nitrophenylhydrazone RI, pyriftalid HB; Pyridate HB; Pyrifenox FU; Pyrimethanil FU; Pyrimidifene AC, IN; Pyriproxyfen IN; Pyrnachlor HB; Pyrogallol RI, pyroquilone FU; Pyroxyfur FU; Quinconazole FU; Quassia IN, RE; Quinalphos AC, IN; Quinclorac HB; Quinmeral HB; Quinoclamine HB, AL; Quinoxyfen FU; Quintozene FU; Quinmerac HB; Quinomethionate (cf. quinomethionate); Quintozene FU; Quizalofop HB; Quizalofop-P HB; Rabenzazole FU; Rapeseed oil (cf. vegetable oils); Renriduron (cf. rimsulfuron); Resmethrin IN; Rcynutria extracts RI, RH-7281 FU; Rimilure-8L (see (Z, E) -11-tetradecadiene-lyl acetate); Resorcylic acids RI, rimsulfuron HB; Rotenone AC, IN; Salicylic acid and its derivatives RI, scilliroside RO; Seaweed extract PG; Sebacic acid RE; Sechumeton HB; Seconal OT; Serricornin AT; Sethoxydim HB; Siduron HB; Silafluofen IN; Silthiofam FU; Silver iodide RE; Silver nitrate PG, FU; Simazine HB; Simeconazole FU; Sodium pt-amylphenate FU, BA; Sodium pt-amylphenoxide FU; Sodium arsenite FU, IN; Sodium o-benzyl-p-chlorophenoxide FU; Sodium chlorate (see chlorates); Sodium chloride HB; Sodium cyanide (cf. cyanides); Sodium diacetone ketogulonate PG; Sodium dichlorophenate FU, BA; Sodium dimethylarsinate HB, RO; Sodium dimethyldithiocarbamate FU; Sodium dioctyl sulfosuccinate AC; Sodium fluorosilicate IN; Sodium hydrogen carbonate FU; Sodium hydroxide HB; Sodium hypochlorite BA; Sodium lauryl sulfate FU, BA; Sodium metabisulphite FU; Sodium monochloroacetate HB; Sodium o-nitrophenolate PG; Sodium bis-p-nitrophenolate PG; Sodium 5-nitroguaiacolate PG; Sodium pentaborate PG; Sodium 2-phenylphenate (see 2-phenylphenol); Sodium propionate FU; Sodium silver thiosulphate HB; Sodium tetraborate IN, HB, MO; Sodium tetrathiocarbamate NE; Sodium tetrathiocarbonate NE, FU; Sodium thiocyanate HB; Sodium p-toluenesulfonchloramide BA; Soybean oil, epoxylated IN; Silthiofam FU; Spinosad IN; Spinosyn IN; Spirodiclofen AC; Spiroxamine FU; SSF-126 FU; SSF-129 FU; Streptomycine BA; Strychnine RO; Sulcotrione HB; Sulfentranzone HB; Sulfodiazole (see ethidimuron); Sulfosates (see Glyphosate trimesium); Sulfotep IN, AC; Sulfur FU, AC, RE; Sulfuric acid HB; Sulprofos IN; 2,4,5-T HB; Tamagrowth (TS303) PG; Tarsic acid IN; Tar oils FU, IN, HB; 2,3,6-TBA HB; TCA HB; TCMTB FU; Tebuconazole FU; Tebufenozide IN; Tebufenpyrad AC; Tebupyrimiphos IN; Tebutam HB; Tebuthiuron HB; Tecloftalame BA, FU; Tecnazene FU, PG; Teflubenzuron IN; Tefluthrin IN; Temephos IN; Tepraloxydim HB; Terbacil HB; Terbucarb HB; Terbuchlor HB; Terbufos NE, IN; Terbumeton HB; Terbuthylazine HB; Terbutryn HB; Terrazole FU; Tefcyclasis FU; Tetrachlorvinphos AC, IN; Tetraconazole FU; (Z, E) -11-tetradecadien-1-yl acetate AT; (Z) -7-tetradecanols AT; (Z) -7- tetradecenal AT; (Z) -9-tetradecenyl acetate AT; (E) -11-tetradecenyl acetate AT; Tetradifon AC, IN; Tetramethrin IN; Tetrasul AC; TH 913 HB; Thallium sulphale RO; Thiabendazole FU; Thiacloprid IN; Thiamethoxam IN; Thiameturon see thifensulfuron; Thiazafluron HB; Thiazopyr HB; Thidiazuron PG; Thifensulfuron (methyl) HB; Thifluzamide FU; Thiobencarb HB; Thiocarb IN; Thiocyclam (hydrogen oxalate) IN; Thicyofen FU; Thiodicarb MO, IN; Thiofanox AC, IN; Thiometone IN, AC; Thionazine NE; Thiophanate-ethyl FU; Thiophanate methyl FU; Thiourea RO; Thiram FU; Tiadinil FU; Tioxymid FU; Tiocarbazil HB; Tolclofos-methyl FU; Tolylfluanid FU, AC; Tolylphthalam PG; Tralkoxydim HB; Tralomethrin IN; Transfluthrin IN; Triadimefon FU; Triadimenol FU; 2,4,5-triamino-6-hydroxypyrimidine RI, triapenthenol PG; Triasulfuron HB; Triazamate IN; Triazbutil FU; Triazofenamide HB; Triazophos NE, IN, AC; Triazoxide FU; Tribenuron (methyl) HB; S, S, S-tributyl phosphorotrithioate PG; Tributyl phosphorotrithioite (see Merphos); Tributyltin oxide FU; Tricalcium phosphate RO; Trichamid FU; Trichlorfon IN; Trichloronate IN; Triclopyr HB; Tricosene IN; Tricyclazole FU; (4E-7Z) -4,7-tridecadien-1-yl acetate AT; Tridemorph FU; Tridiphane HB; Trietazine HB; Trifenmorph MO; Trifloxystrobin FU; Trifloxysulfuron HB; Triflumizole FU; Triflumuron IN; Trifluralin HB; Triflusulfuron (-methyl) HB; Triforme FU, AC; Trimedlure AT; Trimellitic acid RI, trimesic acid RI, trimeturon HB; Trinexapac PG; Trioxymethylene FU; Tritazine HB; Triticonazole FU; Urea FU; Uniconazole PG, FU; Validamycin FU; Vamidothione IN, AC; Vapam IN, NE, FU; Vernolate HB; Vinclozolin FU; Warfarin RO; Wax RO; XRD-563 FU; Xylyl methyl carbamate IN; Xylachlor HB; Xylylcarb IN; Zarilamide FU; Zetacypermethrin (cf. zeta-cypermethrin) IN; Zinc phosphides IN, RO; Zineb FU; Zinebethylenethiuram disulphide adduct (cf. (Z) -9-dodecenylacetate); (Z) -11-tetradecen-1-yl acetate AT; Bitumen Pruning c, Bone Oil RE; IN greases; Quartz sand RE; Olfactory repellants RE; AD-67 Safener SA; Benoxacor Safener SA; Cloquintocet mexyl safener SA; N, N-diallyl-2,2-dichloroacetamide (R 25 788) safener SA; Extender syn. SY; Fenchlorazole (-ethyl) safener SA; Fenchlorim safener SA; Flurazole safener SA; Mefenpyr-diethyl safener SA; Piperonyl butoxide Syn. SY; Sulfaquinoxaline Syn SY.

In a preferred embodiment of the composition according to the invention this can be done at 20 ° C and a pressure of 1 bar through a sieve with a Mesh width of 150 µm without the crosslinked polymer containing Particles> 150 µm remain on the sieve.

In a further preferred embodiment of the invention The composition can be at 20 ° C and a pressure of 1 bar Pour a sieve with a mesh width of 90 µm without the cross-linked polymer containing particles> 90 µm remain on the sieve.

The invention also relates to a method for producing the Composition according to the invention, wherein the additive (A1) in the form of a Water-in-oil polymer dispersion (B1), which is a hydrophobic, organic phase and includes dispersed, swollen polymers and fungal organisms or their constituents (B2), water (B4) and optionally with an or several excipients (B3) and one or more, of the fungal Organisms or their components (B2) various active substances (B5) is mixed.

• 1. einem gequollenen Polymer in einer Menge in einem Bereich von 10 bis 79 Gew.-%, vorzugsweise in einem Bereich von 20 bis 50 Gew.-% und darüber hinaus bevorzugt in einem Bereich von 25 bis 35 Gew.-%, jeweils bezogen auf das Gesamtgewicht der Wasser-in-Öl-Polymerdispersion (B1);
• 2. einer hydrophoben, organischen Flüssigkeit in einer Menge im Bereich von 20 bis 80 Gew.-%, vorzugsweise in einem Bereich von 25 bis 50 -Gew.-% und besonders bevorzugt in einem Bereich von 30 bis 45 Gew.-%, jeweils bezogen auf das Gesamtgewicht der Wasser-in-Öl- Polymerdispersion (B1);
• 3. einem oder mehreren Wasser-in-Öl-Emulgatoren in einer Menge in einem Bereich von 0,5 bis 10 Gew.-%, bevorzugt in einem Bereich von 2 bis 8 -Gew.-% und besonders bevorzugt in einem Bereich von 2 bis 6 Gew.-%, jeweils bezogen auf das Gesamtgewicht der Wasser-in-Öl- Polymerdispcrsion (B1);
• 4. einem oder mehreren Öl-in-Wasser-Emulgatoren in einer Menge in einem Bereich von 0,5 bis 10 Gew.-%, bevorzugt in einem Bereich von 2 bis 8 -Gew.-% und besonders bevorzugt in einem Bereich von 2 bis 6 Gew.-%, jeweils bezogen auf das Gesamtgewicht der Wasser-in-Öl- Polymerdispersion (B1);
• 5. einem oder mehreren Zusatzstoffen in einer Menge in einem Bereich von 0 bis 20 Gew.-%, bevorzugt in einem Bereich von 0,01 bis 10 Gew.-% und besonders bevorzugt in einem Bereich von 0,1 bis 5 Gew.-%, jeweils bezogen auf das Gesamtgewicht der Wasser-in-Öl-Polymerdispersion (B1), und
• 6. auf einer solchen Menge Wasser, dass die Summe der Komponenten (b1) bis (b6) 100 Gew.-% beträgt.

In a preferred embodiment of the method according to the invention, the water-in-oil polymer dispersion (B1) is based on

• 1. a swollen polymer in an amount in a range from 10 to 79% by weight, preferably in a range from 20 to 50% by weight and moreover preferably in a range from 25 to 35% by weight, in each case based on the total weight of the water-in-oil polymer dispersion (B1);
• 2. a hydrophobic organic liquid in an amount in the range from 20 to 80% by weight, preferably in a range from 25 to 50% by weight and particularly preferably in a range from 30 to 45% by weight, in each case based on the total weight of the water-in-oil polymer dispersion (B1);
• 3. one or more water-in-oil emulsifiers in an amount in a range from 0.5 to 10% by weight, preferably in a range from 2 to 8% by weight and particularly preferably in a range from 2 up to 6% by weight, based in each case on the total weight of the water-in-oil polymer dispersion (B1);
• 4. one or more oil-in-water emulsifiers in an amount in a range from 0.5 to 10% by weight, preferably in a range from 2 to 8% by weight and particularly preferably in a range from 2 up to 6% by weight, based in each case on the total weight of the water-in-oil polymer dispersion (B1);
• 5. one or more additives in an amount in a range from 0 to 20% by weight, preferably in a range from 0.01 to 10% by weight and particularly preferably in a range from 0.1 to 5% by weight %, in each case based on the total weight of the water-in-oil polymer dispersion (B1), and
• 6. on an amount of water such that the sum of components (b1) to (b6) is 100% by weight.

In a preferred embodiment of the method according to the invention correspond to the fungal organisms or their components (B2) that Excipients (B3) derived from the fungal organisms or their components (B2) various active ingredients (B5), the swollen polymer (b1), the hydrophobic, organic liquid (b2), the water-in-oil emulsifier (b3), the oil-in-water Emulsifier (b4) and the additive (b5) in connection with the inventive fungal organisms or composition their components (A4), auxiliary substances (A2), from the fungal organisms or whose components (A4) various active ingredients (A5), swollen Polymers (a1), hydrophobic, organic liquids (a2), water-in-oil Emulsifiers (a3), oil-in-water emulsifiers (a4) or additives (a5). As Water (b6) of the water-in-oil polymer dispersion is preferred Deionized water is used while preferred as water (B4) Tap water is used.

The preparation of the water-in-oil used in the process according to the invention Polymer dispersion takes place according to the methods known to the person skilled in the art Emulsion polymerization, preferably by inverse Emulsion polymerization. The monomers (α1) and (α2) and optionally the crosslinker (α3) and the additives (b5) in water dissolved and then this solution in the hydrophobic, organic liquid (b2) Dispersed in the presence of one or more water-in-oil emulsifiers (b3). After stirring the monomer emulsion for about 1-2 hours with nitrogen is blown out, the polymerization is started by adding the Polymerization initiators. It is also possible to pre-polymerize the initiators the addition of the hydrophobic organic liquid (b2) in the aqueous phase to disperse a uniform distribution of the initiators in the aqueous Ensure phase.

Polymerization initiators can be dissolved or dispersed in a solution of monomers according to the invention. All radical-decomposing compounds known to those skilled in the art are suitable as initiators. These include in particular peroxides, hydroperoxides, hydrogen peroxide, persulfates, azo compounds and the so-called redox catalysts. The use of water-soluble catalysts is preferred. In some cases it is advantageous to use mixtures of different polymerization initiators. Among these mixtures, those of hydrogen peroxide and sodium or potassium peroxodisulfate are preferred, which can be used in any conceivable quantitative ratio. Suitable organic peroxides are preferably acetylacetone peroxide, methyl ethyl ketone peroxide, t-butyl hydroperoxide, cumene hydroperoxide, t-amylperpivate, t-butylperviate, t-butylperneohexonate, t-butylisobutyrate, t-butylper-2-ethylhexenoate, t-butylperzoate, t-butylperisononate, t-butylperisononate , t-butyl 3,5,5-tri-methyl hexanoate and amyl perneodecanoate. Further preferred polymerization initiators are:
Azo compounds such as 2,2'-azobis- (2-amidinopropane) dihydrochloride, azo-bisamidinopropane dihydrochloride, 2,2'-azobis- (N, N-dimethylene) isobutyramidine dihydrochloride, 2- (carbamoylazo) isobutyronitrile and 4, 4'-azobis (4-cyanovaleric acid). The compounds mentioned are used in customary amounts, preferably in a range from 0.01 to 5, preferably from 0.1 to 2 mol%, in each case based on the amount of the monomers to be polymerized.

The redox catalysts contain as oxidic component at least one of the above-mentioned per compounds and as reducing component preferably ascorbic acid, glucose, sorbose, manose, ammonium or alkali metal hydrogen sulfite, sulfate, thiosulfate, hyposulfite or sulfide, metal salts such as iron-II -ions or silver ions or sodium hydroxymethyl sulfoxylate. Ascorbic acid or sodium pyrosulfite is preferably used as the reducing component of the redox catalyst. Based on the amount of monomers used in the polymerization, 1.10 ^-5 to 1 mol% of the reducing component of the redox catalyst and 1.10 ^-5 to 5 mol% of the oxidizing component of the redox catalyst are used. Instead of or in addition to the oxidizing component of the redox catalyst, one or more, preferably water-soluble, azo compounds can be used.

According to the invention, a redox system consisting of is preferred Hydrogen peroxide, sodium peroxodisulfate and ascorbic acid are used. According to the invention, it is generally azo compounds as initiators preferred, with azo-bisamidinopropane dihydrochloride being particularly preferred. As a rule, the polymerization with the initiators in one Temperature range from 30 to 90 ° C initiated.

The polymerization can be isothermal, adiabatic or as a combination of one isothermal and adiabatic processes.

In isothermal polymerization, the polymerization process in a certain temperature started under reduced pressure, such as described in EP 228 397 B1, the disclosure of which is hereby incorporated by reference is introduced. The reduced pressure is set so that the resulting heat of polymerization volatile substances such as water and components distill off the organic phase and the temperature is almost constant can be held. The end of the polymerization is characterized by that no more distillate passes over.

In adiabatic polymerization, the polymerization process is carried out in a certain temperature in the range from 0 to 50 ° C, preferably 0 to 25 ° C, started. However, the polymerization is carried out at atmospheric pressure without external Heat input carried up by the heat of polymerization one of the content maximum dependent on the dispersion of polymerizable substance Final temperature of the dispersion is reached.

If the polymerization is a combination of an isothermal and adiabatic Process is carried out, the process is preferably initially isothermal guided. At a predetermined time, the apparatus is run with inert gas aerated and the polymerization up to a certain final temperature continued.

After the polymerization, the water-in-oil polymer dispersion is cooled. Finally, the water-in-oil polymer dispersion becomes the oil-in-water Emulsifiers (b4) added as activators or inverters.

According to another embodiment of the method for Preparation of the composition can be the components of fungal Organisms (B2) or those of the fungal organisms or their Ingredients (B2) different active ingredients (B5) or (B2) and (B5) before or added after the preparation of the water-in-oil polymer dispersion (B1).

According to a further embodiment of the method for producing the The composition of the components of fungal organisms (B2) according to the preparation of the water-in-oil polymer dispersion (B1) is added, before this with water (B4) and optionally with one or more Auxiliaries (B3) is mixed.

The water-in-oil used in the process according to the invention Polymer dispersion (B1) preferably has polymer particles with a size of less than 10 µm and preferably less than 2 µm.

• 1. (α) eine Viskosität von mindestens 5000 mPa.s, bevorzugt von mindestens 10 000 mPa.s und darüber hinaus bevorzugt von mindestens 15 000 mPa.s bei 4 Umdrehungen pro Minute,
• 2. (β) eine Viskosität von mindestens 500 mPa.s, bevorzugt von mindestens 1000 mPa.s und darüber hinaus bevorzugt von mindestens 2000 mPa.s bei 128 Umdrehungen pro Minute.

It is further preferred that the water-in-oil polymer dispersion (B1) used in the process according to the invention is in an aqueous mixture consisting of water and 2.75% by weight of the water-in-oil polymer dispersion (B1), based on the total weight of the aqueous mixture, the water-in-oil polymer dispersion (B1) containing 28% by weight of the crosslinked polymer (b1), based on the total weight of the water-in-oil polymer dispersion (B1), has at least one of the following properties:

• 1. (α) a viscosity of at least 5000 mPa.s, preferably of at least 10,000 mPa.s and moreover preferably of at least 15,000 mPa.s at 4 revolutions per minute,
• 2. (β) a viscosity of at least 500 mPa.s, preferably of at least 1000 mPa.s and more preferably of at least 2000 mPa.s at 128 revolutions per minute.

Those resulting from the above properties (α) to (β) Property combinations of two or more of these properties in each case preferred embodiments of the in the Process used water-in-oil polymer dispersions (B1). Furthermore water-in-oil polymer dispersions (B1) with the shown below as letters or combinations of letters Properties or combinations of properties: α, β, αβ.

Mixing the water-in-oil polymer dispersion (B1) as an additive Microorganisms (B2), water (B4) and, if applicable, auxiliary substances (B3) is done by simply combining and mixing the individual Components. Preferably, the water-in-oil Polymer dispersion with water and optionally one or more Auxiliary materials mixed. This mixture is then mixed with the Microorganisms mixed.

The water-in-oil polymer dispersion is preferably mixed with Water or with water containing the excipient by adding the aqueous phase the water-in-oil polymer dispersion against a shear body, preferably a static mixer. On this shear body the aqueous phase with the water-in-oil polymer dispersion at a pressure of greater than 1.1, preferably greater than 1.5 and particularly preferably greater than 2 bar, it is also preferred that the pressure does not exceed 10 bar.

In another embodiment of the method according to the invention, the Water-in-oil polymer dispersion (B1) before adding components (B2) to (B5) is mixed, diluted with a hydrophobic organic liquid, preferably in a mixture ratio of water-in-oil polymer dispersion organic phase from 1 to 0.1 to 1 to 10.

The invention further relates to a composition by The inventive method is available. It preferably has Composition the same properties as the one described at the beginning, composition according to the invention.

The invention also relates to a method for controlling organisms, which are different from the fungal organisms (A4), the organisms with the composition of the invention or with the brought into contact obtainable composition method according to the invention become.

In the case of organisms which have the composition according to the invention or the composition obtainable by the process according to the invention in Brought into contact, it is preferably harmful or annoying pro- or eukaryotic organisms or viruses.

The organisms are preferably located on or in a substrate. As Whole plants, parts of plants or harvested products such as are preferred Stems, branches, flowers, leaves, whole or split roots or tubers, Grains of seeds, seeds or fruit, smooth or rough surfaces such as walls or Soils, culture or soil substrates, liquid substrates, especially water, or gaseous substrates such as air.

The contacting of the invention preferably takes place Composition or with the method of the invention obtainable composition with the organisms by spreading, Immersion, pickling, incorporation into the substrate or spraying, the Spraying is particularly preferred.

The invention further relates to the use of the invention Composition or the obtainable by the inventive method Composition for controlling organisms other than the fungal organisms (A4).

The invention further relates to the use of the composition in the Agriculture, forestry, horticulture, fruit growing, Vector control, in plant breeding, in plant breeding, in generative and vegetative seeds, for seedlings, for non- agricultural applications to control or control Organisms, in the storage or processing of harvested products, fruits and crops or vegetable materials.

• 1. (β1) Erhöhung der Keimrate von Sporen oder Bakterien, vorzugsweise Pilzsporen,
• 2. (β2) Verbesserung der Lagerstabilität von pilzlichen Organismen oder deren Bestandteile,
• 3. (β3) Erhöhung der oviziden Wirkung von pilzlichen Organismen oder deren Bestandteile, oder zur
• 4. (β4) Erhöhung der larviziden Wirkung von pilzlichen Organismen oder deren Bestandteile.

The invention further relates to the use of the additive (A1) for

• 1. (β1) increase in the germination rate of spores or bacteria, preferably fungal spores,
• 2. (β2) improvement of the storage stability of fungal organisms or their components,
• 3. (β3) increase in the ovicidal activity of fungal organisms or their components, or for
• 4. (β4) increase in the larvicidal activity of fungal organisms or their components.

Spores are fungal spores, fungal organisms or their components of those fungal organisms or those fungal organisms or whose components (A4) are preferred, which are already in connection with the were called composition according to the invention.

The resulting from the above letters (β1) to (β4) Uses or combinations of two or more of these Letter-related uses of the additive (A1) represent each preferred embodiments of the use according to the invention. As Embodiments according to the invention are particularly preferred of the additive (A1), which can be derived from the following letters or Letter combinations result in: β1, β2, β3, β4, β1β2, β1β3, β1β4, β2β3, β2β4, β3β4, β1β2b3, β1β2β4, β1β3β4, β2β3β4, β1β2β3β4.

Increasing the germination rate of fungal spores (β1) is preferred Increasing the germination rate of fungal spores when the fungal spores come into contact with the additive (A1) under conditions that cause germination of the fungal spores allow compared to the germination rate of the same fungal spores that are among the the same conditions were not brought into contact with the additive (A1), Roger that.

Improving the storage stability of fungal organisms or their Ingredients (β2) is preferably used to improve storage stability Storage of the fungal organisms or their components in a mixture containing the fungal organisms or their components and the additive (A1) compared to the storage stability of the same fungal organisms or the components of which, in the absence of the additive (A1), are the same Conditions were stored understood.

Among the improvement in ovicidal activity (β3) is preferred Reduction of hatching of non-adult organisms from eggs after the Storage by adult organisms on or in a substrate with the fungal ones Organisms or with their components and the additive (A1) in contact were compared to the hatching of non-adult organisms the same eggs that are only with the fungal organisms or with their Components were brought into contact, the non-adult and the adult organisms are different from fungal organisms.

With the improvement of the larvicidal activity (β4) the Reducing the survival rate of non-adult organisms that result from untreated, deposited on or in a substrate by adult organisms Eggs hatched, or that were born of adult organisms and that then with the fungal organisms or with their components and the additive (A1) compared to the survival rate of non-adult organisms that are only associated with the fungal organisms or have been brought into contact with their constituents, the non-adult and the adult organisms are different from the fungal organisms.

As organisms and substrates in the use of the invention Additive preferred those organisms and substrates that are already in the Connection with the inventive method for combating Were called organisms.

Contacting this when using the additive according to the invention is preferably done in the same way that already in connection with the Processes according to the invention for controlling organisms described has been.

The invention further relates to the use of a combination of the Additive (A1) and the fungal organisms or their components Achieving a synergistic effect in the control of organisms, that are different from the fungal organisms (A4) with this one Combination (Colby, S.R. (1967): "Calculating Synergistic and Antagonistic Responses of Herbicide Combinations ", Weeds, 15: pp. 20-22).

The invention further relates to the use of a combination of the Additive (A1), at least one fungal organism or its components and at least one of the fungal organism or its components different active ingredient to achieve a synergistic effect in the Control of organisms by the fungal organisms (A4) are different with this combination (Colby, S.R. (1967): "Calculating Synergistic and Antagonistic Responses of Herbicide Combinations ", Weeds, 15: Pp. 20-22).

As fungal organisms or their components and from the fungal ones Organisms Different organisms are those fungal organisms or their constituents and organisms preferred which are related to the composition of the invention or in connection with the Processes according to the invention for controlling organisms have been mentioned.

• 1. ein Additiv in einer Menge in einem Bereich von 0,2 bis 80 Gew.-%, bevorzugt in einem Bereich von 1 bis 60 Gew.-% und besonders bevorzugt in einem Bereich von 10 bis 40 Gew.-%,
• 2. ein n oder mehrere Hilfsstoffen in einer Menge in einem Bereich von 0,1 bis 40 Gew.-%, bevorzugt in einem Bereich von 1 bis 30 Gew.-% und besonders bevorzugt in einem Bereich von 10 bis 20 Gew.-%,
• 3. Wasser in einer Menge von höchstens 50 Gew.-%, bevorzugt von höchstens 25 Gew.-% und besonders bevorzugt von höchstens 5 Gew.-%, wobei die Summe der Komponenten (C1) bis (C3) 100 Gew.-% beträgt, sowie
• 4. pilzliche Organismen in einer Menge in einem Bereich von 10⁴ bis 10¹², bevorzugt 10⁶ bis 10¹⁰ und besonders bevorzugt 10⁷ bis 10⁸ colony forming units (cfu) pro Gramm auf die Komponenten (C1) bis (C3) des Pflanzenschutz- oder Schädlingsbekämpfungsmittels oder Bestandteile von pilzlichen Organismen in einer Menge in einem Bereich von 10^-3 bis 9.10⁵ mg/kg Zusammensetzung, bevorzugt von 0,1 bis 9.10⁴ mg/kg Zusammensetzung und besonders bevorzugt von 5 bis 9.10³ mg/kg Zusammensetzung,

wobei das Additiv (C1) als Bestandteile beinhaltet:

• 1. ein vernetztes Polymer in einer Menge in einem Bereich von 10 bis 79 -Gew.-%, bevorzugt in einem Bereich von 20 bis 50 Gew.-% und darüber hinaus bevorzugt in einem Bereich von 25 bis 35 Gew.-%, jeweils bezogen auf das Gesamtgewicht des Additivs (C1),
• 2. eine hydrophobe, organische Flüssigkeit in einer Menge in einem Bereich von 20 bis 80 Gew.-%, bevorzugt in einem Bereich von 25 bis 50 Gew.-% und darüber hinaus bevorzugt in einem Bereich von 30 bis 40 Gew.-%, jeweils bezogen auf das Gesamtgewicht des Additivs (C1),
• 3. einen oder mehrere Wasser-in-Ol-Emulgatoren in einer Menge in einem Bereich von 0,5 bis 10 Gew.-%, bevorzugt in einem Bereich von 1 bis 8 -Gew.-% und darüber hinaus bevorzugt in einem Bereich von 2 bis 6 Gew.-%, jeweils bezogen auf das Gesamtgewicht des Additivs (C1),
• 4. einen oder mehrere Öl-in-Wasser-Emulgatoren in einer Menge in einem Bereich von 0,5 bis 10 Gew.-%, bevorzugt in einem Bereich von 1 bis 8 -Gew.-% und darüber hinaus bevorzugt in einem Bereich von 2 bis 6 Gew.-%, jeweils bezogen auf das Gesamtgewicht des Additivs (C1),
• 5. einen oder mehrere Zusatzstoffe in einer Menge in einem Bereich von 0 bis 20 Gew.-%, bevorzugt in einem Bereich von 0,01 bis 10 Gew.-% und darüber hinaus bevorzugt in einem Bereich von 0,1 bis 5 Gew.-%, jeweils bezogen auf das Gesamtgewicht des Additivs (C1),

wobei die Summe (c1) bis (c5) 100 Gew.-% beträgt. The invention also relates to a plant protection or pesticide comprising components

• 1. an additive in an amount in a range from 0.2 to 80% by weight, preferably in a range from 1 to 60% by weight and particularly preferably in a range from 10 to 40% by weight,
• 2. one or more auxiliary substances in an amount in a range from 0.1 to 40% by weight, preferably in a range from 1 to 30% by weight and particularly preferably in a range from 10 to 20% by weight .
• 3. Water in an amount of at most 50% by weight, preferably at most 25% by weight and particularly preferably at most 5% by weight, the sum of components (C1) to (C3) 100% by weight amounts, as well
• 4. fungal organisms in an amount in a range from 10 ⁴ to 10 ¹² , preferably 10 ⁶ to 10 ¹⁰ and particularly preferably 10 ⁷ to 10 ⁸ colony forming units (cfu) per gram to the components (C1) to (C3) of the Plant protection or pesticide or components of fungal organisms in an amount in a range from 10 ^-3 to 9.10 ⁵ mg / kg composition, preferably from 0.1 to 9.10 ⁴ mg / kg composition and particularly preferably from 5 to 9.10 ³ mg / kg Composition,

the additive (C1) contains as constituents:

• 1. a crosslinked polymer in an amount in a range from 10 to 79% by weight, preferably in a range from 20 to 50% by weight and moreover preferably in a range from 25 to 35% by weight, in each case based on the total weight of the additive (C1),
• 2. a hydrophobic organic liquid in an amount in a range from 20 to 80% by weight, preferably in a range from 25 to 50% by weight and moreover preferably in a range from 30 to 40% by weight, each based on the total weight of the additive (C1),
• 3. one or more water-in-oil emulsifiers in an amount in a range from 0.5 to 10% by weight, preferably in a range from 1 to 8% by weight and moreover preferably in a range from 2 to 6% by weight, based in each case on the total weight of the additive (C1),
• 4. one or more oil-in-water emulsifiers in an amount in a range from 0.5 to 10% by weight, preferably in a range from 1 to 8% by weight and more preferably in a range from 2 to 6% by weight, based in each case on the total weight of the additive (C1),
• 5. one or more additives in an amount in a range from 0 to 20% by weight, preferably in a range from 0.01 to 10% by weight and moreover preferably in a range from 0.1 to 5% by weight. -%, each based on the total weight of the additive (C1),

the sum (c1) to (c5) being 100% by weight.

The additive (C1) preferably originates from a water-in-oil Polymer dispersion.

The components (C1) to (C4) and (c1) to (c6) are preferably those components (A1) to (A4) or (a1) to (a6) already mentioned in connection with the composition according to the invention were.

In a preferred embodiment, the invention contains Pesticides or pesticides in addition to Components (C1) to (C4) one or more of the fungal ones Organisms or their components (C4) various active substances (C5). This preferably correspond to those active ingredients (A5) that are already in Were mentioned in connection with the composition of the invention. The crop protection or Pesticides contain these active ingredients (C5) in one quantity Range from 0.0001 to 90% by weight, particularly preferably from 0.001 to 50% by weight and moreover preferably from 0.01 to 25% by weight, in each case based on the Total weight of the crop protection or pesticide.

The invention also relates to a method for producing the invention Phytosanitary or pesticide, the fungal Organisms or their components (C4) with water (C3), with the additive (C1) and optionally with the auxiliary substances (C2) and one or more of those fungal organisms or their components (C4) various active ingredients (C5) are mixed and then the composition thus obtained is dried.

The composition is preferably dried by Freeze-drying.

The invention also relates to a method according to the invention Available crop protection or pesticide.

The invention further relates to the use of an inventive Plant protection or pesticide for controlling Organisms that are different from the fungal organisms (C4).

The invention is now based on test methods and not limitative Examples explained in more detail.

TEST METHODS Reduction of the flow rate

A pipette is used to place 1.0 g of the composition at a height of 20 cm in the middle of the plate (8 cm from the side edge) on a smooth plexiglass plate (length 46 cm, width 16 cm). The table top is placed at an angle on a table top so that the angle between the flat table top and the plastic top is 20 °. It is tracked which distance the mixture has covered. The flow rate is given in cm / sec and results from the following equation:

Extends the time for water to evaporate

The extension of the time that passes to 100% by weight of the water in the Composition evaporated at 22 ° C and a pressure of 1 bar determined that 10 g of the composition in a crystallizing dish of Weighed in diameter 9 cm and evenly distributed on the bottom of the bowl were. The dishes were opened in the room at a temperature of 22 ° C and left at a pressure of 1 bar. The weight loss was once determined every hour. Evaporation of 100% of the water is achieved when the weight of the crystallizing dish does not change over a period of 10 hours more changes. If necessary, to determine the time at which 100% by weight of the water has evaporated, are extrapolated.

Determination of the viscosity of the water-in-oil polymer dispersion

The viscosity of the water-in-oil polymer dispersion was determined using a Haake® RV 20 Rotovisco viscometer with an M5 measuring head at 22 ° C. 972.5 g of water with a hardness of 20-25 ° dH are placed in a 2 L plastic beaker and then 27.5 g of product are added with a disposable syringe. The mixture is stirred with the Multifix record stirrer at 3200 revolutions per minute for 5 minutes and left to rest for 10 minutes. The Haake® measuring cup is filled with the prepared solution so that the top marking in the cup is covered by the solution. Now the measuring cup is inserted into the Haake viscometer, which was previously calibrated to zero and fitted with the measuring body. The measurement is carried out at switch levels 3 and 8. The displayed scale value is multiplied by the corresponding factor for each switch level, as shown in the table below.

Determination of the droplet size of the water-in-oil polymer dispersion

10 µl of the water-in-oil polymer dispersion are placed on a slide pipetted and covered with a cover slip. The size of the polymer pots is under the light microscope as the average of the size of 100 polymer droplets educated.

Determination of the increase in the germination rate of fungal spores (β1)

The improvement in the germination rate in the emulsion polymers was shown compared to the standard suspension in a Tween® 80 emulsion using the Abbott formula (Abbott, WS 1925: "A method for computing the effectiveness of an insecticide". Journal of Economic Entomology 18 : 265-267):

Tween® 80 is used as a standard or control because it is a widespread and commonly used in spore preparations Wetting agent (surfactant) that makes it possible that the hydrophobic spores are dispersible in water.

Determination of the improvement in the storage stability of fungal spores (β2)

A spore suspension containing fungal spores and the water-in-oil polymer dispersion (or Tween® 80 as a control) was produced. The mushroom was incubated on rice grains and sporulated. The mushroom colony was then washed off with a dilute, aqueous mixture containing the water-in-oil polymer dispersion or Tween® 80. The spore suspensions thus obtained were then dried under the vaccination bench for 48 h and then stored in Eppendorf tubes at 25 ° C. in the dark for 130 days. Then a sample of the substances was stirred into water and the spore concentration was adjusted to 10 ⁶ cfu / ml (cfu colony forming units). Finally, the suspension was inoculated on water agar (1.5%), incubated for 24 h at 25 ° C. in the dark and the germination rate as defined above was determined. The storage stability is improved if the germination rate of the fungal spores treated with the water-in-oil polymer dispersion after 130 days is greater than the storage stability of the fungal spores treated with Tween® 80.

Determination of the increase in ovicidal activity (β3)

"Leaf cages" with adult white flies (Bemisia argentifolii, 30 white flies per "cage") were attached to cotton in the 4-leaf stage. After 48 hours, the cages and whiteflies were removed and the number of eggs laid was determined (mean value of the treatment or the control at time 0). The eggs laid by the whitefly on the cotton were then spore-suspended, which was obtained by washing a mushroom colony sporulating on rice with a dilute, aqueous mixture containing the water-in-oil polymer dispersion (or containing Tween® 80 for the control Treatment) was sprayed. 8 days after the treatment, the extent of the hatching (β2) was determined by determining the number of nymphs in the first nymph stage (mean value of the treatment or control at time T). The hatching and thus the ovicidal effect of the suspension is expressed by the yuotient (number of nymphs still alive at time T / number of eggs present at time 0). Since the eggs laid before and live nymphs were counted after the treatment, the increase in the ovicidal effect of the water-in-oil polymer dispersion compared to the Tween® 80 control was determined using the Henderson-Tilton formula (Henderson, CF; Tilton, EW 1955: "Tests with acaricides against brown wheat mite". Journal of Economic Entomology 48: 157-161) determined (E =% reduction in survivors, MW = mean).

Determination of the increase in larvicidal activity (β4)

On cotton in the 4-leaf stage, "leaf cages" with adult whites were used Flies (Bemisia argentifolii 30 white flies per "cage") attached. After 48 Hours the cages and whiteflies were removed and the number of laid eggs determined (mean of treatment or control at Time 0). The eggs hatched 13 days after the eggs had been laid Nymphs with a spore suspension by washing one off on rice sporulating mushroom colony with a dilute, watery mixture containing the water-in-oil polymer dispersion (or containing Tween® 80 as Control treatment) was sprayed. After the treatment the number of surviving nymphs was determined (mean of treatment or control at time T). The larvicidal effect of the suspension will by the quotient (number of nymphs still alive at time T / number of eggs present at time 0). The increase in larvicides Effect of the water-in-oil polymer dispersion compared to the Tween® 80- Control was determined using the Henderson-Tilton formula above.

EXAMPLES

The water-in-oil used in Examples 1 and 2 below Polymer dispersion is the Firesorb® MF product from Stockhausen GmbH & Co. KG.

example 1 Determination of the reduction in evaporation through the additive

The water-in-oil polymer dispersion (W / Ö-PD) is mixed with water in the amounts given in Table 1 below. Pure tap water serves as a control. Table 1

Table 1 shows that the addition of the water-in-oil Polymer dispersion in the amounts given in Table 1 in one aqueous mixture the time that passes, up to 100 wt .-% of the water evaporated, extended.

Example 2 Determination of the decrease in the flow rate of the composition through the water-in-oil polymer dispersion

The water-in-oil polymer dispersion (W / Ö-PD) is mixed with water in the amounts given in Table 2 below. Pure tap water serves as a control. Table 2

Table 2 shows that the addition of water-in-oil Polymer dispersion in the amounts given in Table 2 in an aqueous Mixture reduces the flow rate.

In the following examples, the water-in-oil polymer dispersion was either the product Firesorb® MF from Stockhausen GmbH & Co. KG or that Sarpifan® FS product from Stockhausen GmbH & Co. KG.

Example 3 Increase in the germination rate of fungal spores (β1) with reduced water activity (= Dry conditions)

The germination rate was determined in the manner described above. A spore colony of Metarhizin anisopliae (isolate No. 97) was treated with highly dilute, aqueous Firesorb® MF emulsions (0.5 and 1% by weight) or with a 0.05% surfactant emulsion (Tween® 80) washed off and diluted with water to a spore density of 10 ⁷ cfu / ml. After the inoculation on glycerol-containing dextrose agar, the germination rate was determined after 24 h with a water availability of 94% in the medium. The water availability in the nutrient medium is adjusted using clyccrol (Dallyn, H .; Fox, A. 1980: "Spoi / agc of matcrials of reduced water activity by xerophilic fungi." In: Gould, GH, Corry, JEL (eds.): Microbial growth and survibval in extremes of environment. Technical Series No. 15, Academic Press, London, 129-139.). Table 3

Table 3 shows that the addition of the Firesorb® MF emulsion in increasing concentrations compared to the untreated control (germination rate 0%) and with Tween® 80 in regular application rate also below Dry conditions the germination rate of Metarhizin anisopliae spores clearly elevated.

Example 4 Increase in the germination rate of fungal spores (β1) with reduced water activity (= Dry conditions)

The germination rate was determined in the manner described above. A spore colony of Metarhiziarn anisopliae (isolate No. 43) was treated with highly dilute, aqueous Firesorb® MF emulsions (0.5 and 1% by weight) or with a 0.05% surfactant emulsion (Tween® 80) washed off and diluted with water to a spore density of 10 ⁷ cfu / ml. This fungal isolate is much more sensitive, germinates worse and usually no longer germinates under dry conditions. Therefore, germination and the improved germination at 100% and 98% humidity are shown here. Table 4

Table 4 shows that the addition of the Firesorb® MF emulsion in increasing concentrations compared to the untreated control (germination rate 0%) and with Tween® 80 in a regular application rate the germination rate of Metarhitic anisopliae spores both under dry conditions (98% moisture) as well as at a humidity of 100%.

Example 5 Sarpifan® FS increases the germination rate of fungal spores (β1) with reduced Water activity (= dry conditions)

The germination rate was determined in the manner described above. A spore colony of Metarhizin anisopliae (isolate No. 43) was washed off with highly dilute, aqueous emulsions Sarpifan® FS (0.5 and 1% by weight) or with a 0.05% surfactant emulsion (Tween® 80) and diluted with water to a spore density of 10 ⁷ cfu / ml. After inoculation on glycerol-containing dextrose agar as described in Example 3, the increase in the germination rate was determined after 24 h at 98 and 100% water availability: Table 5

Table 5 shows that the addition of Sarpifan® FS is increasing Concentrations compared to the untreated control (germination rate 0%) and to Tween® 80 in regular application rate the germination rate of metarhilic anisopliae- Spores both in dry conditions (98% moisture) and in one Humidity increased by 100%.

Example 6 Improvement of storage stability (β2)

The storage stability was determined in the manner described above. A metarhizizem anisopliae colony sporulating on rice grains (isolate 43) was treated with a dilute, aqueous mixture containing the Firesorb® MF or Sarpifan® FS in quantities of 0.5 or 1.0% by weight and a Tween® 80 solution Control washed off. The spore suspensions thus obtained were then dried under the vaccination bench for 48 h and then stored in Eppendorf tubes at 25 ° C. in the dark for 130 days. A sample of the substances was then stirred into water and the spore concentration was adjusted to 10 ⁶ cfu / ml. Finally, the suspension was inoculated on water agar (1.5%), incubated for 24 h at 25 ° C. in the dark and the germination rate was determined (the germination rate of the controls, i.e. those spores that were only treated with a Tween® 80 solution, was 0% after 130 days): Table 6

Table 6 shows that the germination rate of the fungal spores of the fungus Metarhician anisopliae after storage for a period of 130 days Presence of the water-in-oil polymer dispersions compared to those in Absence of the additive stored mushroom spores clearly and thus the Storage stability is significantly improved.

Example 7 Increasing the ovicidal effects of fungi (β3)

The increase in the ovicidal activity of fungi (β3) was determined in the manner described above. The eggs on the cotton in the 4-leaf stage were treated with 20 ml of a spore suspension (Metarhician anisopliae, isolate 97) containing Firesorb® MF in an amount of 1% by weight 9 days after the number of eggs laid had been determined. with a spore suspension containing Tween® 80 in an amount of 0.05% by weight, with an aqueous mixture containing exclusively Firesorb® MF in an amount of 1% by weight or with an aqueous mixture containing exclusively the surfactant Tween® 80 in sprayed an amount of 0.05 wt .-%. Eight days after treatment, the number of surviving nymphs in the first nymph stage was determined. Since the eggs laid before and live nymphs were counted after the treatment, the effectiveness of the treatment by Tween® 80 and various concentrations of emulsion polymers on egg hatching and the development of the Bemisia argentifolii nymphs were determined using the Henderson-Tilton formula (E =% improved ovicidal activity by polymer treatment compared to standard treatment) determined (MW = mean).


Table 7

Table 7 shows that the addition of the Firesorb® MF emulsion in The ovicidal effect of the Mushroom increased significantly.

Example 8 Increasing the larvicidal or non-adult stage killing effect of fungi (β4)

The increase in the larvicidal or non-adult stage-killing effect of fungi (β4) was determined in the manner described above. The eggs on the cotton in the 4-leaf stage were treated 13 days after the number of eggs laid with 20 ml of a spore suspension (metarhician anisopliae, isolate 97) containing the product Firesorb® MF in an amount of 1% by weight. %, with a spore suspension containing Tween® 80 in an amount of 0.05% by weight, with an aqueous mixture containing exclusively the product Firesorb® MF in an amount of 1% by weight or with an aqueous mixture containing exclusively the surfactant Tween® 80 sprayed in an amount of 0.05% by weight. Five days after treatment, the number of surviving nymphs in the 1st and 2nd stage of the nymph was determined. The results are shown in Table 7: Table 8

Table 8 shows that the addition of a 1% Firesorb® MF- Emulsion compared to Tween® 80 in a regular application rate the larvicides or the non-adult stage-killing effect of the fungus is significantly increased.

Example 9 Increasing the larvicidal or non-adult stages of killing effect Mushrooms (β4)

The increase in the larvicidal or non-adult stage-killing effect of fungi (β4) was determined in the manner described above. The eggs on the cotton in the 4-leaf stage were treated 13 days after the number of eggs laid with 20 ml of a spore suspension (Paecilomyces fumosoroseus) containing Sarpifan® FS in an amount of 0.5% by weight a spore suspension containing Tween® 80 in an amount of 0.05% by weight, with an aqueous mixture containing only Sarpifan® FS in an amount of 0.5% by weight or with an aqueous mixture containing exclusively the surfactant Tween® 80 sprayed in an amount of 0.05% by weight. Five days after treatment, the number of surviving nymphs in the 1st or 2nd nymph stage was determined. The results are shown in Table 9: Table 9

Table 9 shows that, according to Henderson-Tilton, the mushroom P. fumosorosens in Tween® 80, like Tween® 80 itself has hardly any killing effect. The emulsion polymer (Sarpifan® FS) used in this example has it all even killing 28.1% of the damaging nymphs alone is 22.5% better than without the polymer dispersion. A dramatically improved The kill rate of 79.5% was surprisingly achieved by the Combination of the mushroom with the emulsion polymer.

Since this effect is higher than the additive effect of the fungus alone and the emulsion polymer alone, synergy can be assumed, as claimed in this document and as set out here:
Richer (Richer, DL 1987: "Synergism-a Patent View". Pesticide Science 19: 309-315) describes methods and procedures to demonstrate synergy. Accordingly, in the simplest case, the purely additive expected effect E _{e can} be explained by:

E _e = X + Y (1)

where X represents the observed percent control by active principle A alone and Y represents the observed percent control by active principle B alone, both in the application rate and in the combination. If the observed effect E _o exceeds the value for E _e , there is synergy. This clearly applies here, because 81.0 is significantly more than 3.7 + 28.1 = 31.8.

Claims (21)

1. Including a composition 1. an additive in an amount ranging from 0.001 to 2.0% by weight 2. one or more auxiliary substances in an amount in a range from 0 to 20% by weight, 3. such an amount of water that the sum of the components (A1) to (A3) is 100% by weight, and 4. fungal organisms in an amount in a range from 10 ⁰ to 10 ¹⁰ colony forming units (cfu) per gram from (A1) to (A3) of the composition or components of fungal organisms in an amount in a range from 10 ^-3 to 5.10 ⁵ mg / kg composition, the additive (A1) 1. a crosslinked polymer in an amount in a range from 10 to 80% by weight, based on the total weight of the additive (A1), 2. a hydrophobic, organic liquid in an amount in a range from 20 to 80% by weight, based on the total weight of the additive (A1), 3. one or more water-in-oil emulsifiers in an amount in a range from 0.5 to 10% by weight, based on the total weight of the additive (A1), 4. one or more oil-in-water emulsifiers in an amount in a range from 0.5 to 10% by weight, based on the total weight of the additive (A1), 5. one or more additives in an amount in a range from 0 to 20 wt .-%, based on the total weight of the additive (A1), and 6. based on such an amount of water that the sum (a1) to (a6) is 100% by weight. 2. The composition of claim 1, wherein the composition in addition to components (A1) to (A4) one or more of the fungal organisms or their components (A4) various Active substances (A5) contains. 3. The composition of claim 1 or 2, wherein the Composition at 20 ° C and a pressure of 1 bar through a sieve with a mesh width of 150 µm without the cross-linked polymer containing particles> 150 µm remain on the sieve. 4. Composition according to one of claims 1 to 3, wherein the additive 1. in a composition consisting of water and the additive in an amount of 1.5% by weight, based on the total weight of the composition, has at least one of the following properties: 1. Reduced flow rate of the composition by at least 75% compared to the flow rate of water; 2. Extended period of time that passes until the water contained in 10 g of the composition has evaporated at 22 ° C. and a pressure of 1 bar compared to the period of time that elapses before the same amount of water without the additive is used under the same conditions evaporated to at least 2 hours. 5. Composition according to one of claims 1 to 4, wherein the polymer (a1) 1. (α1) 0.1 to 99.999% by weight of polymerized, ethylenically unsaturated, acid group-containing monomers or their salts or polymerized, ethylenically unsaturated monomers containing a protonated or quaternized nitrogen, or a mixture of at least two thereof, 2. (α2) 0 to 70% by weight of polymerized, ethylenically unsaturated monomers which can be copolymerized with (α1), 3. (α3) 0.001 to 10% by weight of one or more crosslinking agents, and 4. (α4) 0 to 20% by weight of one or more adjuvants, the sum of the amounts by weight (α1) to (α4) being 100% by weight. 6. A process for the preparation of the composition according to the invention, the additive (A1) being in the form of a water-in-oil polymer dispersion (B1) which comprises a hydrophobic organic phase and swollen polymers distributed therein 1. a swollen polymer in an amount in a range of 10 to 80 wt .-%, based on the total weight of the water-in-oil polymer dispersion (B1); 2. a hydrophobic organic liquid in an amount in the range from 20 to 80% by weight, based on the total weight of the water-in-oil polymer dispersion (B1); 3. one or more water-in-oil emulsifiers in an amount in a range from 0.5 to 10% by weight, based on the total weight of the water-in-oil polymer dispersion (B1); 4. one or more oil-in-water emulsifiers in an amount in a range from 0.5 to 10% by weight, based on the total weight of the water-in-oil polymer dispersion (B1); 5. one or more additives in an amount in a range of 0 to 20 wt .-%, based on the total weight of the water-in-oil polymer dispersion (B 1), and 6. is based on such an amount of water that the sum of components (b1) to (b6) is 100% by weight, is mixed with fungal organisms or their constituents (B2), water (B4) and optionally with one or more auxiliary substances (B3) and one or more active substances (B5) different from the fungal organisms or their constituents (B2). 7. A composition obtainable by a process according to claim 6. 8. A method of controlling organisms other than the fungal organisms (A4), the organisms with the A composition according to any one of claims 1 to 5 or 7 in contact to be brought. 9. The method of claim 8, wherein the organisms are harmful or troublesome are pro- or eukaryotic organisms or viruses. 10. The method of claim 8 or 9, wherein the contacting by Spraying or dipping takes place. 11. Use of a composition according to any one of claims 1 to 5 or 7 to control organisms that are different from the fungal organisms (A4). 12. Use of a composition according to any one of claims 1 to 5 or 7 in agriculture, forestry, horticulture, Fruit growing, vector control, plant growing, Plant breeding, with generative and vegetative seeds, with seedlings, with non-agricultural control or control applications of organisms, in the storage or processing of harvested products, Fruits and crops or vegetable materials. 13. Use of a composition according to any one of claims 1 to 5 or 7 for seed dressing. 14. Use of an additive as defined in one of claims 1 to 6 for 1. (β1) increase in the germination rate of spores or bacteria, preferably fungal spores, 2. (β2) improvement of the storage stability of fungal organisms or their components, 3. (β3) increase in the ovicidal activity of fungal organisms or their components, or for 4. (β4) increase in the larvicidal activity of fungal organisms or their components. 15. Use of a combination of an additive as in one of the Claims 1 to 6 defines and fungal organisms or their Components for achieving a synergistic effect in the Fight organisms by fungal organisms are different with this combination. 16. Use a combination of the additive as in one of the Claims 1 to 6 defined, at least one fungal organism or its components and at least one of the fungal organism or its components different active ingredient to achieve a synergistic effect in the control of organisms by the fungal organisms are different with this combination. 17. A pesticide or pesticide containing as components 1. an additive in an amount in a range from 0.2 to 80% by weight, 2. one or more auxiliary substances in an amount in a range from 0.1 to 40% by weight, 3. Water in an amount of at most 50% by weight, the sum (C1) to (C3) being 100% by weight, and 4. fungal organisms in an amount in a range from 10 ⁴ to 10 ¹² colony forming units (cfu) per gram of components (C1) to (C3) of the plant protection or pesticide or components of fungal organisms in an amount of 10 ^-3 up to 5.10 ⁵ mg / kg composition, the additive (C1) contains as constituents: 1. a crosslinked polymer in an amount in a range from 10 to 79% by weight, based on the total weight of the additive (C1), 2. a hydrophobic organic liquid in an amount in a range from 20 to 80% by weight, based on the total weight of the additive (C1), 3. one or more water-in-oil emulsifiers in an amount in a range from 0.5 to 10% by weight, based on the total weight of the additive (C1), 4. one or more oil-in-water emulsifiers in an amount in a range from 0.5 to 10% by weight, based on the total weight of the additive (C1), 5. one or more additives in an amount in a range from 0 to 20% by weight, based on the total weight of the additive (C1), the sum (c1) to (c5) being 100% by weight. 18. plant protection or pesticide composition according to claim 17, the crop protection or pesticide in addition to components (C1) to (C4) one or more of the fungal ones Organisms or their components (C4) various active substances (C5) contains. 19. A process for making crop protection or Pest control agent according to claim 17 or 18, wherein the fungal microorganisms or their components (C4) with water (C3), a water-in-oil polymer dispersion as defined in claim 6 and optionally with the auxiliary substances (C2) and one or more, of which fungal organisms or their components (C4) various Active ingredients (C5) are mixed and then the so obtained Composition is dried. 20. A plant protection or pesticide available through the Method according to claim 19. 21. Use of a plant protection or pesticide according to one of claims 17, 18 or 20 for combating organisms, that are different from the fungal organisms (C4).