DE202004010572U1 - Water dispenser comprises electrolysis unit mounted between mains or bottled water supply and tap which consists of one or two electrolysis cells, reaction chamber and catalysis chamber - Google Patents

Water dispenser comprises electrolysis unit mounted between mains or bottled water supply and tap which consists of one or two electrolysis cells, reaction chamber and catalysis chamber Download PDF

Info

Publication number
DE202004010572U1
DE202004010572U1 DE202004010572U DE202004010572U DE202004010572U1 DE 202004010572 U1 DE202004010572 U1 DE 202004010572U1 DE 202004010572 U DE202004010572 U DE 202004010572U DE 202004010572 U DE202004010572 U DE 202004010572U DE 202004010572 U1 DE202004010572 U1 DE 202004010572U1
Authority
DE
Germany
Prior art keywords
water
tap
electrolysis
chamber
water dispenser
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Expired - Lifetime
Application number
DE202004010572U
Other languages
German (de)
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Kaehn Kurt Dr
Original Assignee
Kaehn Kurt Dr
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Kaehn Kurt Dr filed Critical Kaehn Kurt Dr
Priority to DE202004010572U priority Critical patent/DE202004010572U1/en
Publication of DE202004010572U1 publication Critical patent/DE202004010572U1/en
Anticipated expiration legal-status Critical
Expired - Lifetime legal-status Critical Current

Links

Classifications

    • AHUMAN NECESSITIES
    • A61MEDICAL OR VETERINARY SCIENCE; HYGIENE
    • A61LMETHODS OR APPARATUS FOR STERILISING MATERIALS OR OBJECTS IN GENERAL; DISINFECTION, STERILISATION OR DEODORISATION OF AIR; CHEMICAL ASPECTS OF BANDAGES, DRESSINGS, ABSORBENT PADS OR SURGICAL ARTICLES; MATERIALS FOR BANDAGES, DRESSINGS, ABSORBENT PADS OR SURGICAL ARTICLES
    • A61L2/00Methods or apparatus for disinfecting or sterilising materials or objects other than foodstuffs or contact lenses; Accessories therefor
    • A61L2/02Methods or apparatus for disinfecting or sterilising materials or objects other than foodstuffs or contact lenses; Accessories therefor using physical phenomena
    • A61L2/03Electric current
    • A61L2/035Electrolysis
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B67OPENING, CLOSING OR CLEANING BOTTLES, JARS OR SIMILAR CONTAINERS; LIQUID HANDLING
    • B67DDISPENSING, DELIVERING OR TRANSFERRING LIQUIDS, NOT OTHERWISE PROVIDED FOR
    • B67D1/00Apparatus or devices for dispensing beverages on draught
    • B67D1/0042Details of specific parts of the dispensers
    • B67D1/0057Carbonators
    • B67D1/006Conventional carbonators
    • CCHEMISTRY; METALLURGY
    • C02TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
    • C02FTREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
    • C02F1/00Treatment of water, waste water, or sewage
    • C02F1/46Treatment of water, waste water, or sewage by electrochemical methods
    • C02F1/461Treatment of water, waste water, or sewage by electrochemical methods by electrolysis
    • C02F1/467Treatment of water, waste water, or sewage by electrochemical methods by electrolysis by electrochemical disinfection; by electrooxydation or by electroreduction
    • C02F1/4672Treatment of water, waste water, or sewage by electrochemical methods by electrolysis by electrochemical disinfection; by electrooxydation or by electroreduction by electrooxydation
    • CCHEMISTRY; METALLURGY
    • C02TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
    • C02FTREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
    • C02F9/00Multistage treatment of water, waste water or sewage
    • C02F9/20Portable or detachable small-scale multistage treatment devices, e.g. point of use or laboratory water purification systems
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B67OPENING, CLOSING OR CLEANING BOTTLES, JARS OR SIMILAR CONTAINERS; LIQUID HANDLING
    • B67DDISPENSING, DELIVERING OR TRANSFERRING LIQUIDS, NOT OTHERWISE PROVIDED FOR
    • B67D2210/00Indexing scheme relating to aspects and details of apparatus or devices for dispensing beverages on draught or for controlling flow of liquids under gravity from storage containers for dispensing purposes
    • B67D2210/00002Purifying means
    • B67D2210/00013Sterilising means
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B67OPENING, CLOSING OR CLEANING BOTTLES, JARS OR SIMILAR CONTAINERS; LIQUID HANDLING
    • B67DDISPENSING, DELIVERING OR TRANSFERRING LIQUIDS, NOT OTHERWISE PROVIDED FOR
    • B67D2210/00Indexing scheme relating to aspects and details of apparatus or devices for dispensing beverages on draught or for controlling flow of liquids under gravity from storage containers for dispensing purposes
    • B67D2210/00002Purifying means
    • B67D2210/00013Sterilising means
    • B67D2210/00018Membranes
    • CCHEMISTRY; METALLURGY
    • C02TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
    • C02FTREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
    • C02F1/00Treatment of water, waste water, or sewage
    • C02F1/46Treatment of water, waste water, or sewage by electrochemical methods
    • C02F1/461Treatment of water, waste water, or sewage by electrochemical methods by electrolysis
    • C02F1/463Treatment of water, waste water, or sewage by electrochemical methods by electrolysis by electrocoagulation
    • CCHEMISTRY; METALLURGY
    • C02TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
    • C02FTREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
    • C02F1/00Treatment of water, waste water, or sewage
    • C02F1/72Treatment of water, waste water, or sewage by oxidation
    • C02F1/725Treatment of water, waste water, or sewage by oxidation by catalytic oxidation
    • CCHEMISTRY; METALLURGY
    • C02TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
    • C02FTREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
    • C02F1/00Treatment of water, waste water, or sewage
    • C02F1/46Treatment of water, waste water, or sewage by electrochemical methods
    • C02F1/461Treatment of water, waste water, or sewage by electrochemical methods by electrolysis
    • C02F1/46104Devices therefor; Their operating or servicing
    • C02F1/46109Electrodes
    • C02F2001/46133Electrodes characterised by the material
    • C02F2001/46138Electrodes comprising a substrate and a coating
    • CCHEMISTRY; METALLURGY
    • C02TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
    • C02FTREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
    • C02F2201/00Apparatus for treatment of water, waste water or sewage
    • C02F2201/002Construction details of the apparatus
    • C02F2201/003Coaxial constructions, e.g. a cartridge located coaxially within another
    • CCHEMISTRY; METALLURGY
    • C02TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
    • C02FTREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
    • C02F2201/00Apparatus for treatment of water, waste water or sewage
    • C02F2201/46Apparatus for electrochemical processes
    • C02F2201/461Electrolysis apparatus
    • C02F2201/46105Details relating to the electrolytic devices
    • C02F2201/46115Electrolytic cell with membranes or diaphragms
    • CCHEMISTRY; METALLURGY
    • C02TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
    • C02FTREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
    • C02F2201/00Apparatus for treatment of water, waste water or sewage
    • C02F2201/46Apparatus for electrochemical processes
    • C02F2201/461Electrolysis apparatus
    • C02F2201/46105Details relating to the electrolytic devices
    • C02F2201/4612Controlling or monitoring
    • C02F2201/46125Electrical variables
    • CCHEMISTRY; METALLURGY
    • C02TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
    • C02FTREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
    • C02F2201/00Apparatus for treatment of water, waste water or sewage
    • C02F2201/46Apparatus for electrochemical processes
    • C02F2201/461Electrolysis apparatus
    • C02F2201/46105Details relating to the electrolytic devices
    • C02F2201/4612Controlling or monitoring
    • C02F2201/46145Fluid flow

Abstract

Water dispenser comprises an electrolysis unit which is mounted between a mains or bottled water supply and the tap. This consists of one or two electrolysis cells, a reaction chamber and a catalysis chamber. Each cell has a tubular anode (a) and a central cathode (c) which are separated by a coaxial ion-selective diaphragm (b). The electrodes are made from metal oxide coated titanium and the diaphragm is made from a ceramic mixture of metal oxides.

Description

Wasserspender verschiedener Bauart haben Probleme mit der mikrobiologischen Qualität des gezapften Trinkwassers; es entspncht häufig nicht den Anforderungen der am 1.1.2003 in Kraft getretenen Trinkwasserverordnung 2001. Im Sinne dieser Verordnung sind Wasserspender Anlagen, aus denen Trinkwasser entnommen oder abgegeben wird. Das Wasser muß zum Zeitpunkt der Abgabe den mikrobiologischen Anforderungen an Wasser für den menschlichen Gebrauch entsprechen (§4 Absatz 2 und §5 Absatz 1 und 2). Das heißt konkret: Krankheitserreger dürfen nicht nachweisbar und die in keimbildenden Einheiten (KBE) gemessene Gesamtkeimbelastung muß kleiner 100 KBE pro Milliliter sein.water dispenser different designs have problems with the microbiological quality of the tapped drinking water; it often corresponds not the requirements of the Drinking Water Ordinance that came into force on 1.1.2003 2001. For the purposes of this regulation, water dispenser systems are out from which drinking water is taken or released. The water must be at the time the release of the microbiological requirements for water for human Correspond to use (§4 Paragraph 2 and §5 Paragraphs 1 and 2). This means specifically: pathogens may undetectable and those measured in nucleating units (CFU) Total bacterial load must be less 100 CFU per milliliter.

In den Zapfstellen von Wasserspendern bleibt nach jeder Betätigung Feuchtigkeit zurück. Keime (Bakterien, Sporen von Einzellern, Pilzen und Bakterien), die über die Luft oder bei Berührung über die Hände dort eindringen, finden ideale Lebensbedingungen und vermehren sich rasch. Sie dringen von der Zapfstelle aus weiter in die wasserführenden Leitungen vor (retrograde Verkeimung) und bilden einen festsitzenden Biofilm. Diese Vorgänge werden durch regelmäßige Stagnationszeiten (z.B. Nichtgebrauch über Nacht oder über das Wochenende) stark befördert. Der Biofilm gibt Keime in das Wasser ab, das dadurch mikrobiologisch kontaminiert wird.In The water dispenser taps remain moist after each operation back. Germs (bacteria, spores from unicellular organisms, fungi and bacteria), the above the air or when touched over the Hands there penetrate, find ideal living conditions and multiply quickly. They penetrate further into the water-carrying pipes from the tap before (retrograde contamination) and form a stuck biofilm. These processes are caused by regular stagnation times (e.g. not used over Night or over the weekend). The biofilm releases germs into the water, making it microbiological is contaminated.

Keime gelangen aber auch mit dem Wasser, mit dem der Wasserspender beschickt wird, in die wasserführenden Bauteile. Wasser, das der Hausinstallation entnommen oder als Quellwasser etc. in großen Flaschen (sogenannten Ballons) angeliefert wird, ist nicht steril (keimfrei). Wenn sich die vorhandenen Keime ablagern, können auch sie einen Biofilm in den wasserführenden Teilen des Wasserspenders ausbilden.germs but also get with the water that the water dispenser loads will, in the water-bearing Components. Water taken from the house installation or as spring water etc. in large Bottles (called balloons) are not sterile (Germ-free). If the existing germs are deposited, they can too a biofilm in the aquifer Train parts of the water dispenser.

Gesundheitseinrichtungen sind besonders verpflichtet, die Qualität des Trinkwassers zu überwachen. Nachdem die mikrobiologische Problematik der Wasserspender in Fachkreisen diskutiert wird, werden auch zunehmend vorhandene Wasserspender in die Untersuchungen mit einbezogen. In einigen Einrichtungen wurden daraufhin alle Wasserspender entfernt.health facilities are particularly obliged to monitor the quality of the drinking water. After the microbiological problem of water dispensers in specialist circles water dispensers are also increasingly being discussed included in the investigations. In some facilities then all water dispensers removed.

Stand der TechnikState of the art

Die Hersteller von Wasserspendern haben auf die Situation unterschiedlich reagiert – im folgenden eine Auswahl von Maßnahmen (können auch kombiniert vorkommen):The Manufacturers of water dispensers have different on the situation reacted - in following a selection of measures (can also occur in combination):

  • – Es werden weiterhin keine besonderen Reinigungsmaßnahmen empfohlen.- It special cleaning measures are still not recommended.
  • – Es wird eine tägliche Reinigung der Zapfstelle empfohlen.- It becomes a daily Cleaning of the tap is recommended.
  • – Es wird eine tägliche Sprühdesinfektion der Zapfstelle empfohlen.- It becomes a daily spray recommended at the tap.
  • – Es wird gefordert, die Zapfstelle morgens und abends zu desinfizieren und zusätzlich die regelmäßige Reinigung nach den Technischen Regeln für Getränkeschankanlagen (TRSK 501 §11) vorzunehmen.- It is required to disinfect the tap in the morning and evening and additionally regular cleaning according to the technical rules for Getränkeschankanlagen (TRSK 501 §11) make.
  • – Es wird eine turnusmäßige Hygiene-Inspektion durch Fachpersonal angeboten.- It a regular hygiene inspection is carried out Specialists offered.
  • – Der Raum um die Zapfstelle wird mit UV-Licht bestrahlt.- The Space around the tap is irradiated with UV light.
  • – Es werden im Gerät Bakterienfilter oder UV-Strahler verwendet.- It are in the device Bacterial filter or UV lamp used.

Für die Lösung desselben Problems werden also sehr unterschiedliche Maßnahmen vorgeschlagen, die sich stark in ihrer Wirksamkeit unterscheiden. Die einzelnen Reinigungsschritte sind hinsichtlich ihrer hygienischen Relevanz oft wenig spezifiziert. Im Gerät vor der Zapfstelle eingebaute Bakterienfilter und UV-Strahler können nicht die Keime erfassen, die über die Zapfstelle von außen eindringen und Biofilm in der auslaufnahen Wasserleitung bilden. Die UV-Bestrahlung der Zapfstelle erfaßt nicht die Keime, die über den Wasserzulauf eindringen.For the solution of the same So very different measures are proposed to the problem differ greatly in their effectiveness. The individual cleaning steps are often not specified in terms of their hygienic relevance. In the device Bacterial filters and UV lamps installed in front of the tap cannot capture the germs that over the tap from the outside penetrate and form biofilm in the water pipe near the outlet. The UV radiation at the tap does not detect the germs that pass through the Penetrate water inlet.

Insgesamt erschwert die baulich-konstruktive Ausführung der Wasserspender hygienische Reinigungsmaßnahmen.All in all complicates the structural and constructive execution of the water dispenser hygienic Cleaning measures.

Die Keimbelastung ist auch abhängig vom Standort (Büro, Artpraxis, Baumarkt etc.) und der Befolgung und Kontrolle der Hygiene- und Reinigungsanweisungen des Betreibers. In der Regel existieren hier keinerlei Vorgaben.The Germ load is also dependent from the location (office, Art practice, hardware store etc.) and compliance and control of hygiene and cleaning instructions from the operator. Usually exist here no requirements.

Erläuterung zur Ausführung „Hygienischer Wasserspender"Explanation of the execution "Hygienic Water dispenser "

Unter den Begriff „Wasserspender" im Sinne dieses Antrages fallen Trinkbrunnen, Trinkwasserbrunnen, Trinkwasseranlagen, Tafelwasseranlagen, Water Cooler etc., aus denen gekühltes und/oder ungekühltes und/oder erhitztes Wasser in Form von stillem Wasser und/oder kohlensäurehaltigem Wasser und/oder sauerstoffhaltigem Wasser für den menschlichen Gebrauch entnommen oder abgegeben wird.Under the term "water dispenser" in the sense of this Applications include drinking fountains, drinking water fountains, drinking water systems, Bottled water systems, water coolers etc., from which cooled and / or uncooled and / or heated water in the form of still water and / or carbonated Water and / or oxygenated water for human use is removed or delivered.

Der Einbauort und die Anzahl der notwendigen Elektrolyseeinheiten wird von der Art des Wasserspenders bestimmt (gekühltes / erhitztes / stilles / kohlensäurehaltiges / sauerstoffangereichertes Wasser). Ein einfaches Ausführungsbeispiel zeigt die 1 (Wasserspender für gekühltes stilles und kohlensäurehaltiges Wasser mit Anschluß an die Hausinstallation).The installation location and the number of necessary electrolysis units is determined by the type of water dispenser (cooled / heated / still / carbonated / oxygenated water). A simple embodiment shows the 1 (Water dispenser for chilled still and carbonated water with connection to the house installation).

Der im Schutzanspruch 1 angegebenen Erfindung liegt das Problem zugrunde, die mikrobiologische Qualität des Wassers aus Wasserspendern entsprechend den Anforderungen der Trinkwasserverordnung 2001 sicherzustellen. Dieses Problem wird mit den in Schutzanspruch 1 aufgeführten Merkmalen gelöst.The specified in protection claim 1 The problem underlying the invention is to ensure the microbiological quality of the water from water dispensers in accordance with the requirements of the Drinking Water Ordinance 2001. This problem is solved with the features listed in protection claim 1.

Mit der Erfindung wird erreicht, daß aus dem Wasserspender stets Wasser von Trinkwasserqualität entnommen werden kann – unabhängig von der Keimbelastung der Umgebung, des zulaufenden Wassers und der Wasserzuleitungen und unabhängig von der strikten Einhaltung von Reinigungsintervallen und kurzen Stagnationszeiten (Wochenenden). Im Anodenraum (2: 1) entstehen starke Oxidantien, die Keime abtöten und im Wasser ein positives Redoxpotenzial erzeugen. Die Einwirkzeit der Oxidantien wird in einer Reaktionskammer (3A und 3B: 3) verlängert. Ein Durchflußsensor schaltet den elektrischen Strom ein und aus, so daß nur strömendes Wasser elektrolytisch behandelt wird. Abhängig von der Qualität des zulaufenden Wassers wird eine Elektrolyseeinheit gemäß 3A oder 3B verwendet.With the invention it is achieved that water of drinking water quality can always be withdrawn from the water dispenser - regardless of the microbial load in the environment, the incoming water and the water supply lines and regardless of the strict adherence to cleaning intervals and short stagnation times (weekends). In the anode compartment ( 2 : 1 ) strong oxidants are created which kill germs and produce a positive redox potential in the water. The exposure time of the oxidants is recorded in a reaction chamber ( 3A and 3B : 3 ) extended. A flow sensor switches the electrical current on and off, so that only flowing water is treated electrolytically. Depending on the quality of the incoming water, an electrolysis unit is installed 3A or 3B used.

Die Elektrolysezelle zeichnet sich durch eine Membran (Diaphragma) aus, die den Elektrodenraum in Anoden- und Kathodenraum trennt (2: b) und eine Durchmischung der beiden Wasserteilströme verhindert. Aus der ersten Elektrolysezelle gelangt nur der Wasserteilstrom aus dem Anodenraum zur Zapfstelle, der Wasserteilstrom aus dem Kathodenraum wird verworfen (3A und 3B: c). Die Zelle läßt sich so ansteuern, daß der Keimgehalt des Wassers immer den Anforderungen der Trinkwasserverordnung entspricht. Bei Durchströmung des Anodenraumes erhält das Wasser ein positives Redoxpotenzial von bis zu + 800 mV. Dieses Redoxpotenzial ist auch bei Stagnation (Nichtbetrieb) ausreichend stabil, um über einige Tage alle Anflug- und Hautkeime an der Zapfstelle sicher abzutöten. Dadurch wird eine retrograde Kontamination des Wasserspenders über die Zapfstelle und die Bildung von Biofilm verhütet.The electrolysis cell is characterized by a membrane (diaphragm) that separates the electrode space into the anode and cathode spaces ( 2 : b) and a mixing of the two partial water flows prevented. From the first electrolytic cell, only the partial water flow from the anode compartment reaches the tap, the partial water stream from the cathode compartment is discarded ( 3A and 3B : c). The cell can be controlled so that the microbial content of the water always meets the requirements of the Drinking Water Ordinance. When flowing through the anode compartment, the water receives a positive redox potential of up to + 800 mV. This redox potential is sufficiently stable even in the event of stagnation (non-operation) to safely kill all approach and skin germs at the tap over a few days. This prevents retrograde contamination of the water dispenser via the tap and the formation of biofilm.

Mit der Elektrolyseeinheit werden nicht nur Keime, sondern auch Giftstoffe aus dem Wasser entfernt:With The electrolysis unit not only releases germs, but also toxins removed from the water:

  • – Die im Schutzanspruch 2 aufgeführte Katalysekammer mit Katalysator-Granulat steigert und vervollständigt den durch die Oxidantien initiierten Abbau organisch-chemischer Verbindungen. Dadurch werden beispielsweise Rückstände von Arzneimitteln oder von Pestiziden zerstört. Der Katalysator wird dabei nicht verbraucht und muß nicht regeneriert oder ausgetaucht werden.- The listed in claim 2 Catalyst chamber with catalyst granulate increases and completes the degradation of organic chemical compounds initiated by the oxidants. This means, for example, residues of pharmaceuticals or destroyed by pesticides. The catalyst is not consumed and does not have to be regenerated or replaced.
  • – Durch das im Schutzanspruch 4 aufgeführte ionenselektive Diaphragma lassen sich giftige Schwermetalle im Kathodenraum sammeln, ausfällen und schließlich abführen. Im Kathodenraum entstehen starke Reduktionsmittel, die Metallionen entweder als Metallhydroxide oder als neutralisierte Metallatome ausfällen. Das ionenselektive Diaphragma (2: b) sorgt dafür, daß giftige Metalle im Kathodenraum konzentriert und Mineralstoffe im Anodenraum zurückgehalten werden. Der Wasserteilstrom aus dem Kathodenraum der ersten Elektrolysezelle wird verworfen (Drainage, siehe 1: b und 3A und 3B: c) und giftige Metalle somit entfernt.- Due to the ion-selective diaphragm listed in protection claim 4, toxic heavy metals can be collected in the cathode compartment, precipitated and finally removed. Strong reducing agents are generated in the cathode compartment, which precipitate metal ions either as metal hydroxides or as neutralized metal atoms. The ion-selective diaphragm ( 2 : b) ensures that toxic metals are concentrated in the cathode compartment and minerals are retained in the anode compartment. The partial water flow from the cathode compartment of the first electrolytic cell is discarded (drainage, see 1 : Federation 3A and 3B : c) and thus toxic metals removed.

Das im Schutzanspruch 3 aufgeführte sauerstoffreiche Wasser entsteht aus dem Zusammenwirken mehrerer Faktoren. Der Sauerstoff entsteht vorwiegend im Anodenraum der ersten Elektrolysezelle. Unter der Vielzahl der dort gebildeten Oxidantien ist der Sauerstoff relativ stabil und reaktionsträge. Er wird bei den oxidativen Prozessen in der Reaktions- und Katalysekammer nicht verbraucht und reichert sich daher im Wasser an.The listed in protection claim 3 oxygen-rich water arises from the interaction of several Factors. The oxygen mainly arises in the anode compartment of the first Electrolysis cell. Among the multitude of oxidants formed there the oxygen is relatively stable and inert. He will in the oxidative processes in the reaction and catalysis chamber not consumed and therefore accumulates in the water.

Die im Schutzanspruch 5 aufgeführte Restrukturierung des Wassers ist ein Kombinationseffekt aus starkem elektromagnetischen Feld und starken Scherkräften in den Elektrolysezellen. Flüssiges Wasser hat eine Struktur, die durch den Dipolcharakter (ungleiche Ladungsverteilung) und die asymmetrische Form der Wassermoleküle bedingt ist. Bis zu über hundert Wassermoleküle bilden dabei käfigartige Moleküle (Cluster). Diese werden aufgebrochen und ordnen sich neu, wobei vorwiegend kleinere Wassermolekül-Cluster entstehen, was die Transportfähigkeit der Wassers für kleine Moleküle wie z.B. Gase erhöht.The listed in claim 5 Restructuring the water is a combination effect of strong electromagnetic field and strong shear forces in the electrolysis cells. Liquid water has a structure that is characterized by the dipole character (uneven charge distribution) and the asymmetrical shape of the water molecules is due. Up to over a hundred water molecules form cage-like molecules (Cluster). These are broken up and rearranged, whereby predominantly smaller water molecule clusters arise what the portability the water for small molecules such as. Gases increased.

Die Vorteile der Kombination Wasserspender plus ElektrolyseeinheitThe advantages the combination of water dispenser plus electrolysis unit

  • – Die mikrobiologische Qualität des gezapften Wassers entspricht stets der Trinkwasserverordnung 2001.- The microbiological quality of the tap water always corresponds to the drinking water ordinance 2,001th
  • – Die keimabtötende Wirkung des Redoxpotenzials macht die regelmäßige Desinfektion der Zapfstelle überflüssig.- The germicidal The effect of the redox potential makes regular disinfection of the tap unnecessary.
  • – Der Unterhaltsaufwand zur Trinkwasserhygiene durch den Betreiber ist gering.- The Maintenance costs for drinking water hygiene by the operator low.
  • – Hoher hygienischer Sicherheitsstandard wird mit wenig Aufwand hergestellt.- Higher hygienic safety standards are produced with little effort.
  • – Das Wasser wird zusätzlich mit Sauerstoff angereichert.- The Water is added enriched with oxygen.
  • – Organische Schadstoffe wie Halogenmethane, polyzyklische aromatische Kohlenwasserstoffe, Arzneimittel, Pestizide und andere werden zerstört.- Organic Pollutants such as halomethanes, polycyclic aromatic hydrocarbons, pharmaceuticals, Pesticides and others are destroyed.
  • – Giftige Schwermetallionen wie Blei oder Cadmium werden entfernt.- Toxic Heavy metal ions such as lead or cadmium are removed.
  • – Die Transportkapazität des Wassers (z.B. für Sauerstoff) wird durch Änderung der Clusterstruktur erhöht.- The transport capacity of water (e.g. for oxygen) is through change the cluster structure increased.

Abbildung 1illustration 1

Anordnung von Bauelementen in einem Wasserspender für stilles und kohlensäurehaltiges Wasser mit Anschluß an die Hausinstallation und Elektrolyseeinheit nach dem Wassereingang.arrangement of components in a water dispenser for still and carbonated water with connection to the house installation and electrolysis unit after the water inlet.

aa
Wasserzulaufwater supply
bb
Drainagedrainage
cc
Zapfstelle für kohlensäurehaltiges Wassertap for carbonated water
dd
Zapfstelle für stilles Wassertap for silent water
ee
Zugang KohlendioxidAccess carbon dioxide
11
Elektrolyseeinheit mit elektronischer Steuerung und Durchflußsensor, wahlweiseelectrolysis unit with electronic control and flow sensor, optional
kombiniert mit Druckminderer und Wassermangelsicherungcombined with pressure reducer and low water protection
22
Pumpepump
33
Karbonatortopf mit NiveaureglerKarbonatortopf with level control
44
Kühlschlangencooling coils
55
Ablaßventildrain valve
66
Rückschlagventilcheck valve
77
Gasventil mit Druckminderergas valve with pressure reducer

Abbildung 2Figure 2

Querschnitt durch eine Elektrolysekammercross-section through an electrolysis chamber

aa
Anodeanode
bb
Diaphragmadiaphragm
cc
Kathodecathode
11
Anodenraumanode chamber
22
Kathodenraumcathode space

Abbildung 3A und 3BFigures 3A and 3B

Aufbau einer Elektrolyseeinheit – wassertührende Teile 3A mit zwei Elektrolysezellen, 3B mit einer ElektrolysezelleConstruction of an electrolysis unit - water-carrying parts 3A with two electrolytic cells, 3B with an electrolytic cell

aa
Wasserzulaufwater supply
bb
gereinigtes Wasserpurified water
cc
Drainage (Wasserverwurf)drainage (Water supply litter)
11
Elektrolysezelle 1 electrolysis cell 1
22
Elektrolysezelle 2 electrolysis cell 2
33
Reaktionskammerreaction chamber
44
Katalysekammer mit Katalysator-Granulatcatalytic chamber with catalyst granules
55
regelbares Durchflußventilcontrollable flow valve

Claims (5)

Hygienischer Wasserspender mit Entkeimung des zulaufenden Wassers und Verkeimungsschutz der wasserführenden Teile, dadurch gekennzeichnet, daß zwischen dem geräteseitigen Wasseranschluß (Hausinstallation oder die Wasserflasche) und der Zapfstelle / den Zapfstellen des Wasserspenders eine Elektrolyseeinheit installiert ist. Die Elektrolyseeinheit besteht aus einer oder zwei speziellen Elektrolysezellen, einer Reaktionskammer und einer Katalysekammer. Die Elektrolysezellen bestehen aus zylindrischen, coaxial angeordneten Elektroden und einem ionenselektiven Diaphragma (2: a–c), das den Raum zwischen den Elektroden in einen Anodenraum (2: 1) und einen Kathodenraum (2: 2) unterteilt. Die Elektroden sind aus Titan gefertigt und mit Metalloxiden beschichtet, das Diaphragma besteht aus einem keramischen Gemisch von Metalloxiden. Anoden- und Kathodenraum verfügen je über einen Wasserein- und -auslaß. Bei Wasserfluß wird ein elektrischer Strom von größer 1 Ampere zugeschaltet und durch eine Steuerelektronik konstant gehalten. Dem Anodenraum der ersten Elektrolysezelle ist die Reaktionskammer nachgeschaltet, dahinter folgt die Katalysekammer (3A und 3B: 3, 4). Der zulaufende Wasserstrom wird nach Durchströmung des Anodenraums der ersten Elektrolysezelle durch ein regelbares Durchflußventil (3A und 3B: 5) aufgeteilt in einen Drainagestrom (Verwurf) und einen Trinkwasserstrom zur Zapfstelle.Hygienic water dispenser with disinfection of the incoming water and protection against contamination of the water-carrying parts, characterized in that an electrolysis unit is installed between the water connection on the device (house installation or the water bottle) and the tap / taps of the water dispenser. The electrolysis unit consists of one or two special electrolysis cells, a reaction chamber and a catalytic chamber. The electrolytic cells consist of cylindrical, coaxially arranged electrodes and an ion-selective diaphragm ( 2 : a – c) which separates the space between the electrodes into an anode space ( 2 : 1 ) and a cathode compartment ( 2 : 2 ) divided. The electrodes are made of titanium and coated with metal oxides, the diaphragm consists of a ceramic mixture of metal oxides. Anode and cathode compartments each have a water inlet and outlet. When water flows, an electrical current of greater than 1 ampere is switched on and kept constant by control electronics. The reaction chamber is connected downstream of the anode compartment of the first electrolytic cell, followed by the catalytic chamber ( 3A and 3B : 3 . 4 ). After flowing through the anode compartment of the first electrolytic cell, the incoming water flow is controlled by a controllable flow valve ( 3A and 3B : 5 ) divided into a drainage stream (discard) and a drinking water stream to the tap. Hygienischer Wasserspender nach Anspruch 1, dadurch gekennzeichnet, daß organisch-chemische Verunreinigungen des Wassers durch elektrolytisch erzeugte Oxidantien zerstört werden. Die Effektivität dieser Prozesse wird durch eine Katalysekammer mit Katalysator-Granulat (3A und 3B: 4) potenziert, die der Reaktionskammer nachgeschaltet ist.Hygienic water dispenser according to claim 1, characterized in that organic chemical contaminations of the water are destroyed by electrolytically generated oxidants. The effectiveness of these processes is determined by a catalyst chamber with catalyst granules ( 3A and 3B : 4 ) potentiated, which is downstream of the reaction chamber. Hygienischer Wasserspender nach einem der vorhergehenden Ansprüche, dadurch gekennzeichnet, daß das Wasser durch Elektrolyse zusätzlich mit Sauerstoff angereichert wird. Die Sauerstoffbildung erfolgt hauptsächlich im Anodenraum (2: 1) der ersten Elektrolysezelle (3A und 3B: 1).Hygienic water dispenser according to one of the preceding claims, characterized in that the water is additionally enriched with oxygen by electrolysis. Oxygen formation mainly occurs in the anode compartment ( 2 : 1 ) of the first electrolytic cell ( 3A and 3B : 1 ). Hygienischer Wasserspender nach einem der vorhergehenden Ansprüche, dadurch gekennzeichnet, daß Schwermetallionen durch das ionenselektive Diaphragma in den Kathodenraum (2: 2) der ersten Elektrolysezelle überführt werden (3A und 3B: 1) und somit in den Drainagestrom gelangen.Hygienic water dispenser according to one of the preceding claims, characterized in that heavy metal ions pass through the ion-selective diaphragm into the cathode compartment ( 2 : 2 ) are transferred to the first electrolytic cell ( 3A and 3B : 1 ) and thus get into the drainage stream. Hygienischer Wasserspender nach einem der vorhergehenden Ansprüche, dadurch gekennzeichnet, daß die Struktur des Wassers (Größenverteilung der Wassermolekül-Cluster) in den beiden Elektrolysezellen (3A und 3B: 1,2) elektrolytisch verändert wird.Hygienic water dispenser according to one of the preceding claims, characterized in that the structure of the water (size distribution of the water molecule clusters) in the two electrolysis cells ( 3A and 3B : 1 . 2 ) is changed electrolytically.
DE202004010572U 2004-07-09 2004-07-09 Water dispenser comprises electrolysis unit mounted between mains or bottled water supply and tap which consists of one or two electrolysis cells, reaction chamber and catalysis chamber Expired - Lifetime DE202004010572U1 (en)

Priority Applications (1)

Application Number Priority Date Filing Date Title
DE202004010572U DE202004010572U1 (en) 2004-07-09 2004-07-09 Water dispenser comprises electrolysis unit mounted between mains or bottled water supply and tap which consists of one or two electrolysis cells, reaction chamber and catalysis chamber

Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
DE202004010572U DE202004010572U1 (en) 2004-07-09 2004-07-09 Water dispenser comprises electrolysis unit mounted between mains or bottled water supply and tap which consists of one or two electrolysis cells, reaction chamber and catalysis chamber

Publications (1)

Publication Number Publication Date
DE202004010572U1 true DE202004010572U1 (en) 2004-11-18

Family

ID=33483341

Family Applications (1)

Application Number Title Priority Date Filing Date
DE202004010572U Expired - Lifetime DE202004010572U1 (en) 2004-07-09 2004-07-09 Water dispenser comprises electrolysis unit mounted between mains or bottled water supply and tap which consists of one or two electrolysis cells, reaction chamber and catalysis chamber

Country Status (1)

Country Link
DE (1) DE202004010572U1 (en)

Cited By (20)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US7836543B2 (en) 2006-02-10 2010-11-23 Tennant Company Method and apparatus for producing humanly-perceptable indicator of electrochemical properties of an output cleaning liquid
US7891046B2 (en) 2006-02-10 2011-02-22 Tennant Company Apparatus for generating sparged, electrochemically activated liquid
DE202010015529U1 (en) 2009-11-19 2011-03-17 Aqora Gmbh Liquid dispenser
DE202009018113U1 (en) 2009-11-09 2011-03-24 Aqora Gmbh donation fitting
US8007654B2 (en) 2006-02-10 2011-08-30 Tennant Company Electrochemically activated anolyte and catholyte liquid
US8012339B2 (en) 2006-02-10 2011-09-06 Tennant Company Hand-held spray bottle having an electrolyzer and method therefor
US8012340B2 (en) 2006-02-10 2011-09-06 Tennant Company Method for generating electrochemically activated cleaning liquid
US8016996B2 (en) 2006-02-10 2011-09-13 Tennant Company Method of producing a sparged cleaning liquid onboard a mobile surface cleaner
US8025786B2 (en) 2006-02-10 2011-09-27 Tennant Company Method of generating sparged, electrochemically activated liquid
US8025787B2 (en) 2006-02-10 2011-09-27 Tennant Company Method and apparatus for generating, applying and neutralizing an electrochemically activated liquid
US8046867B2 (en) 2006-02-10 2011-11-01 Tennant Company Mobile surface cleaner having a sparging device
US8062499B2 (en) 2008-05-05 2011-11-22 Tennant Compnay Charge movement detector for electrochemically activated liquids
US8236147B2 (en) 2008-06-19 2012-08-07 Tennant Company Tubular electrolysis cell and corresponding method
US8319654B2 (en) 2008-06-19 2012-11-27 Tennant Company Apparatus having electrolysis cell and indicator light illuminating through liquid
US8337690B2 (en) 2007-10-04 2012-12-25 Tennant Company Method and apparatus for neutralizing electrochemically activated liquids
US8371315B2 (en) 2008-12-17 2013-02-12 Tennant Company Washing systems incorporating charged activated liquids
WO2013067032A1 (en) * 2011-11-01 2013-05-10 Indrani Deo Dispensing machine sanitization using electrochemically activated liquid
US8485140B2 (en) 2008-06-05 2013-07-16 Global Patent Investment Group, LLC Fuel combustion method and system
EP2706042A1 (en) 2012-09-07 2014-03-12 OxyTherm GmbH Point-of-use water dispenser and method for using said water dispenser
WO2019018576A1 (en) * 2017-07-18 2019-01-24 Linares Reinerio Water activator transducer

Cited By (28)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US8156608B2 (en) 2006-02-10 2012-04-17 Tennant Company Cleaning apparatus having a functional generator for producing electrochemically activated cleaning liquid
US8025787B2 (en) 2006-02-10 2011-09-27 Tennant Company Method and apparatus for generating, applying and neutralizing an electrochemically activated liquid
US8603320B2 (en) 2006-02-10 2013-12-10 Tennant Company Mobile surface cleaner and method for generating and applying an electrochemically activated sanitizing liquid having O3 molecules
US7836543B2 (en) 2006-02-10 2010-11-23 Tennant Company Method and apparatus for producing humanly-perceptable indicator of electrochemical properties of an output cleaning liquid
US7891046B2 (en) 2006-02-10 2011-02-22 Tennant Company Apparatus for generating sparged, electrochemically activated liquid
US8046867B2 (en) 2006-02-10 2011-11-01 Tennant Company Mobile surface cleaner having a sparging device
US8007654B2 (en) 2006-02-10 2011-08-30 Tennant Company Electrochemically activated anolyte and catholyte liquid
US8012339B2 (en) 2006-02-10 2011-09-06 Tennant Company Hand-held spray bottle having an electrolyzer and method therefor
US8012340B2 (en) 2006-02-10 2011-09-06 Tennant Company Method for generating electrochemically activated cleaning liquid
US8016996B2 (en) 2006-02-10 2011-09-13 Tennant Company Method of producing a sparged cleaning liquid onboard a mobile surface cleaner
US8025786B2 (en) 2006-02-10 2011-09-27 Tennant Company Method of generating sparged, electrochemically activated liquid
US8719999B2 (en) 2006-02-10 2014-05-13 Tennant Company Method and apparatus for cleaning surfaces with high pressure electrolyzed fluid
US8337690B2 (en) 2007-10-04 2012-12-25 Tennant Company Method and apparatus for neutralizing electrochemically activated liquids
US8062499B2 (en) 2008-05-05 2011-11-22 Tennant Compnay Charge movement detector for electrochemically activated liquids
US8485140B2 (en) 2008-06-05 2013-07-16 Global Patent Investment Group, LLC Fuel combustion method and system
US8236147B2 (en) 2008-06-19 2012-08-07 Tennant Company Tubular electrolysis cell and corresponding method
US8319654B2 (en) 2008-06-19 2012-11-27 Tennant Company Apparatus having electrolysis cell and indicator light illuminating through liquid
US8371315B2 (en) 2008-12-17 2013-02-12 Tennant Company Washing systems incorporating charged activated liquids
DE102009052273A1 (en) 2009-11-09 2011-07-07 AQORA GmbH, 91301 donation fitting
EP2336090A2 (en) 2009-11-09 2011-06-22 Aqora GmbH Liquid dispensing device
DE202009018113U1 (en) 2009-11-09 2011-03-24 Aqora Gmbh donation fitting
DE202010015529U1 (en) 2009-11-19 2011-03-17 Aqora Gmbh Liquid dispenser
US9144346B2 (en) 2011-11-01 2015-09-29 Pepsico, Inc. Dispensing machine sanitization using electrochemically activated liquid
WO2013067032A1 (en) * 2011-11-01 2013-05-10 Indrani Deo Dispensing machine sanitization using electrochemically activated liquid
US10308495B2 (en) 2011-11-01 2019-06-04 Pepsico, Inc. Dispensing machine sanitization using electro-chemically activated liquid
DE102012215936A1 (en) 2012-09-07 2014-03-13 Oxymount Technology GmbH Conducted water dispenser and method of operating a wired water dispenser
EP2706042A1 (en) 2012-09-07 2014-03-12 OxyTherm GmbH Point-of-use water dispenser and method for using said water dispenser
WO2019018576A1 (en) * 2017-07-18 2019-01-24 Linares Reinerio Water activator transducer

Similar Documents

Publication Publication Date Title
DE202004010572U1 (en) Water dispenser comprises electrolysis unit mounted between mains or bottled water supply and tap which consists of one or two electrolysis cells, reaction chamber and catalysis chamber
EP2527303B1 (en) Reverse osmosis assembly
US9688560B2 (en) Water purification system engineered for Legionella control in industrial and commercial water systems
US5401399A (en) Water purification system
US9056145B2 (en) Self-contained, self-cleaning aqueous liquid sterilizer
KR101697155B1 (en) Simple water purification appratus having central management and control system
US20080105620A1 (en) Water purification system
EP2706042B1 (en) Point-of-use water dispenser and method for using said water dispenser
US10669180B2 (en) Adaptive catalytic technology water treatment system
US20110042322A1 (en) Apparatus and methods for variably sterilizing aqueous liquids
EP2464396B1 (en) Coupling and switching element for lines for transporting fluids
CA2910853A1 (en) Apparatus and method for electrodisinfection
DE102010044733B4 (en) Water treatment device for medical purposes
US20090071883A1 (en) Electrolytic system for obtaining a disinfectant
CN102824109A (en) Water dispenser
EP2464447B1 (en) Device for adding gas to fluids
DE102008004663A1 (en) Method for sanitization and germ reduction from biologically cleaned sewage, comprises conducting the sewage or sewage partial flow to a clarification plant through electrolysis cell and subsequently supplying to industrial water container
EP3412637A1 (en) Ultraviolet light water treatment unit for closed recirculation systems
Allen et al. Water quality and water delivery systems
DE102011115507A1 (en) Device for disinfection of aquiferous plants i.e. house installations, and power mains of medical devices, has interchangeable sodium chloride reservoir and/or water reservoir connected to external compressor under pressure
KR101685929B1 (en) Simple water purification appratus having near field communication function for water quality measuring and confirmation
Miguel et al. Enterococcus sp. Inactivation by Ozonation in Natural Water: Influence of H2O2 and TiO2 and Inactivation Kinetics Modeling
US20120181238A1 (en) Water treatment system
CN211972023U (en) Water filtering and sterilizing device
EP2336090B1 (en) Liquid dispensing device

Legal Events

Date Code Title Description
R086 Non-binding declaration of licensing interest
R207 Utility model specification

Effective date: 20041223

R156 Lapse of ip right after 3 years

Effective date: 20080201