DE2402730A1 - CLEANING ITEMS FOR USE IN THE BATHROOM OR UNDER THE SHOWER - Google Patents

Description

Attorney File 24 746 'January 21, 1974

Cleaning supplies for use in the bathroom or shower

The present invention relates to a cleaning article made of a nonwoven fabric for single use in the bath or in the shower, which contains at least one cleaning agent and, if desired, additional agents such as skin protection agents and / or contains perfume and its nonwoven * fibers by means of a water-insoluble binder are connected to each other.

In British Patent 1288641 a cleaning fleece is already described that the bactericidal solution containing with an aqueous, at least 15 wt. "L- aqueous ethanol or isopropanol, impregnated and sealed in an impermeable sachet.

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However, such a fleece is not dried after impregnation and remains moist or even moist to the touch wet, and it cannot be used as a washcloth in the bath or even in the shower because of the high content of impregnated wet residue of gradually volatilizing alcohol as well as its low content of Surfactants do not allow a satisfactorily dense foam to be developed, anyway not under the running water of the shower.

From the German Offenlegungsschrift 2 119 -819 is furthermore an impregnated cotton wool for cosmetic purposes is known. Such cotton wool, which in the form of multilayered Disks, balls of cotton wool or the like. Is present and is possibly covered with non-woven (non-woven) fleece, is with fat-dissolving substances such as isopropyl myristate or paraffin oil and optionally impregnated with a perfume and is intended for skin cleansing or make-up removal in the absence of water. Such impregnated cotton swabs However, they are not suitable as washcloths for use in the bathroom or shower because of their consistency as well as lose their mechanical strength in water and does not contain any foaming agent.

The present invention relates to a cleaning article of the type described in the opening paragraph with a Detergent-releasing non-woven fabric, the fibers of which pass through

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a water-insoluble binder are linked together. At least part of the fleece practically adheres evenly distributed and a cosmetically acceptable foam-forming cleaning agent when dry.

The cleaning article is expediently manufactured in such a way that that the fiber material of the fleece with an aqueous preparation of a cosmetically acceptable foam-forming Impregnated detergent and then it dries. The nonwoven fabric of a cleaning article obtained in this way contains i.e. the dryness of an aqueous impregnation preparation from at least one cosmetically acceptable one foam-forming detergents.

The aqueous impregnation preparation can be present as a solution, emulsion, coacervate or aqueous gel and still contain other additives that are at least partially retained in the dry air, such as skin protection agents, foam reinforcing agents, Preservatives, antioxidants.

The cleaning article according to the invention advantageously has the shape of a rectangular one that can be used as a glove Bag, which consists of a rectangular, in the middle folded piece of fleece, which on the edge of two of its Pages glued, sewn or welded together.

The fleece consists of non-woven material, its fibers by means of a water-insoluble binder

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connected to one another, preferably glued, and which shows the usual appearance of a non-woven material.

The nonwovens which can be used according to the invention can contain natural, artificial and synthetic fibers, e.g. fibers made from native or regenerated cellulose, such as Viscose rayon, fibers made of synthetic polyamide, polyester, acrylonitrile or mixtures of two or more such fiber types.

The water-insoluble binder holding the fibers of the fleece together can be a synthetic rubber or a synthetic resin suitable for this purpose, such as acrylic acid ester resin.

The fleece preferably consists of

(a) 50 to 90 parts by weight viscose rayon fibers, which with 10 to 50 parts by weight of a synthetic Rubbers are connected to each other, or

(b) from 50 to 90 parts by weight of a mixture of viscose rayon fibers on the one hand and synthetic polyamide on the other and / or polyester fibers, in the weight ratio of the viscose plastic fibers to the polyamide and / or polyester fibers from 1: 5 to 1:15, including as a binder, e.g. acrylic acid ester resin, preferably 10 to 50 parts by weight are added.

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In general, it is desired that the rewetted nonwoven impregnated according to the invention have one has a smooth, soft handle. In any case, there should be none when rubbing the skin with the moist cleaning article Skin irritation may occur.

Nonwovens that can be used are described, for example, in DT-AS 1 036 804, DT-AS 1 093 321 and FR-PS 1 124 968. That used Fleece should also have a relatively high tensile strength in warm shower and bath water, too when rubbed into the wet state. It should also have good absorbency and high retention capacity for water-based impregnation preparations and must be such that the preparations are absorbed immediately and spread quickly and evenly in it.

The aqueous preparation (impregnation preparation) used to impregnate the fleece can be an aqueous one Be a solution, an aqueous emulsion or suspension, or a liquid aqueous gel. It contains at least one cosmetically acceptable foaming agents, and possibly skin protection agents and other cosmetically acceptable additives, e.g. perfumes.

The pH of the above-mentioned preparation should be between 2.5 and 8, preferably 6.5 and 7.5. That to manufacture of the cleaning article according to the invention

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dete aqueous impregnation preparation contains appropriately at least 5% by weight and at most 80% by weight of cosmetically acceptable foaming agent, based on the total weight of the preparation. The foaming agent content is preferably 5-60% by weight of the preparation, which is particularly preferred but those impregnation preparations which contain 10 to 50% by weight of foaming agent.

Various surface-active substances (surfactants) can be used as foaming agents, e.g. anionic, cationic, ampholytic and non-ionic surfactants or mixtures of two or more of these compatible with one another Surfactants. Although such a surfactant shows a high foaming power, it is one for a skin cleansing agent only moderate cleaning power, so you can also use a suitable cleaning agent, that only wants to produce insufficient foam on its own.

The anion-active surfactants that can be used as foaming agents are e.g. soaps, saponins, sarcosinates, N-acylsarcosinates, sulfated monoglycerides, primary and secondary alkyl sulfates, alkyl hydrogen carboxylic acids, primary and secondary alkylarylsulfonates, alkali and amine salts of the half esters, preferably the lower alkyl half esters, the SuIfosuccinic acid, alkali and amine salts of fatty acids (lower) alkanolamide sulfates, fatty acid methyl taurides,

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Acid condensates, alkyl polyglycol ether sulfates, such as sodium lauryl sulfate, triethanolammonium myristyl sulfate, Sodium dodecylphenolsulfonate, sodium N-lauroyl sarcosinate, Sodium diglycol ether sulfate, sodium lauryl polyethylene glycol sulfate, Sodium N-methyl-N-alkyl tauride (aminoethane sulfonate), sodium N-coconut fatty acid N-methyl tauride, Sodium N-methyl-N-oleyl tauride.

Cationic ones are also suitable for use as foaming agents in the impregnation preparations mentioned Surfactants e.g. those from the following classes: quaternary ammonium salts, e.g. bis-quaternary ammonium salts, amines, Amine salts, long-chain imidazolines, imidazolium salts, Pyridinium, morpholinium, quinolinium salts, as well as their ethoxylated derivatives.

Such cationic surfactants are in particular the alkyltrimethyl, dialkyldimethyl and alkyldimethylbenzylammonium salts, the alkyl groups of which contain 8 to 22, preferably 12 to 18, hydrocarbon atoms, such as: Tetradecyl-trimethylammonium bromide, hexadecyltrlmethylammonium bromide, Cetyltrimethylammonium chloride, octadecyltrimethylammonium chloride, an alkyltrimethylammonium chloride, the alkyl radicals of which correspond to the alkyl radicals of coconut fatty acid; Ethyl-dodecyl-dimethylammonium bromide, distearyldimethylammonium chloride; Lauryldimethylbenzylammonium chloride; Hexadecyltrimethylamine; Octadecylpyridinium chloride,

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Tetradecylpyridinium iodide; polyethoxylated stearylamines; Diethanolammonium chloride, cetylethylmorpholinium ethosulfate.

Ampholytic surfactants, long-chain N-alkylated β-aminopropionic acids are also suitable as foaming agents, Glycines, betaines, sulfated imidazoline derivatives and condensates of sulfosuccinic acid esters with taurine.

These ampholytic compounds include, for example Sodium salt of N-coconut fatty acid-ß-aminopropionic acid, N-lauryl-ß-aminopropionic acid, N-lauryl myristyl-ß-aminopropionic acid and the triethanoamine salt of N-laurylmyristylß-aminopropionic acid as well as their glycines and betaines.

Nonionic surfactants from the following classes are also found in the impregnation preparations as foaming agents the invention uses: alkyl polyglycol ethers, alkylaryl polyglycol ethers, Polyethylene glycols, polypropylene glycols, higher alkyl mercaptan condensates with alkylene oxide, condensates of polyethylene glycols with polypropylene oxide, ethylene oxide condensates of fatty acylalkylolamides, oxyethylated sorbitan fatty acid esters, Oxethylated pentaerythritol fatty acid esters.

Condensates of polyols with polybasic, water-soluble acids such as: polyethylene glycol monocetyl ester, in particular the monococoates, monolaurates, monomyristates, monoricinoleates as well as sorbitan esters such as sorbitan monooleate, Sorbitan soybean oil fatty acid ester, sorbitan stearate

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and -sorbit of tert-dodecylthioether.

The foaming agent can also consist of a mixture of surfactants of a single or different types (anionic, cationic, ampholytic and / or nonionic) exist, provided that they are compatible with one another are.

The HLB value (hydrophilic / lipophilic balance according to GRIFFIN) of the foaming agent (if the impregnation preparation contains only one foaming agent) or the Foaming agent mixtures (cumulative HLB value) is e.g. 7 to 40, preferably more for the individual foaming agent than 10, or more than 13 for a mixture.

Because of their high HLB values, which are mostly between and 40, are used for the cleaning article according to the invention the anionic foaming agents, optionally mixed with cationic, ampholytic and / or nonionic foaming agents, are particularly preferred. \

Insofar as the cumulative HLB value of a foaming agent mixture is high enough to give the cleaning article according to the invention a good foaming power, there can be Foam concentrates also contain surfactants with a lower HLB value.

The aqueous impregnation preparation used to produce the cleaning article according to the invention preferably contains one or more skin protectants. Under skin

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Protective agents are understood as substances of different compositions that protect the skin against harmful Skin environmental effects or against adverse effects the soaps, surfactants, etc. protect.

Skin protection agents are e.g. substances that can reduce irritation caused by odorous substances such as E.g. guaiacols, or substances which, by re-oiling the skin, lead to the disadvantageous, excessive degreasing of the skin Soaps and surfactants counteract this, such as the fatty acid esters and certain fatty acid alkylolamides. The skin protection products should also cut the skin from fat-dissolving substances.

The skin protection substances, humectants represent or contain, which protect the skin against excessive drying out.

Suitable skin protection agents are in particular lanolin, constituents of lanolin or derivatives of such constituents. parts such as fatty acid alkylamides, lecithins, wool fatty alcohols and wool wax derivatives, hydrogenated fats and herbal drugs. Particularly suitable among these are lauric acid isopropanolamide, coconut fatty acid diethanolamide, Stearic acid monoethanolamide, myristic acid monoethanolamide, Oleic acid monoethanolamide, undecylic acid monoethanolamide, coconut fat, palm oil, castor oil, sesame oil, soybean oil, sun

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flower oil, sebum and chamomile, conifer and algae extracts.

The following should also be mentioned as advantageous skin protection agents or humectants that can be used in such: Sodium lactate, glycerine, propylene glycol, butanediol, Hexylene glycol, honey, invert sugar solutions, sorbitol solutions, silicones, alkali salts of 2-pyrrolidone-5-carboxylic acid, Polysaccharides, polyethylene glycols and polyglycerols of low molecular weight, which are not among the foaming agents belong.

The content of skin protection agent is preferably 0.1 to 20%, and even better 0.1 to 10%, based on the Weight of the impregnation preparation. The latter can further contain a cosmetically acceptable perfume.

The impregnation preparation can be in the form of a transparent Solution, emulsion, dispersion or gel for Soaking the fleece can be used.

Often times, the foaming agent tends to form a gel in the presence of water. This tendency can be increased by adding increased by salts such as sodium chloride.

However, the impregnation preparation preferably contains a hydrophilic thickener as a further additive. Such Thickeners are e.g .: natural hydrocolloids (pentoses, methylpentoses, hexoses, carageenates, karaya gum, Tragacanth, alginates, gum arabic) and synthetic

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Hydrocolloids (esters and ethers of cellulose such as methyl cellulose, Methyl ethyl cellulose, methyl hydroxypropyl cellulose, carboxymethyl cellulose); Polyvinylpyrrolidones, Polyvinyl alcohols, carboxy vinyl polymers, polymethacrylic acids, Polyethylene oxide waxes).

Such a thickener acts as an adhesive for the foaming agent and for the skin protection agent, their release into the water, especially when using the cleaning article in the bath or under the jet of the Shower that is slowed down.

The amount of thickener used should not be higher than a good, even one and rapid impregnation of the fleece is possible.

The impregnation preparation can contain further additives, which are suitable for the in the invention Dry residue contained in cleaning articles are suitable.

Such additives are, for example: sequestering agents, preservatives, anti-oxidants, foam reinforcing agents and water-soluble dyes.

The sequestering agents (complexing substances, Chelating agents) are used to remove the hardness of the water and the often harmful trace metals. Suitable Agents are e.g. sodium salts of nitrilotriacetic acid and ethylenediaminetetraacetic acid, as well as alkali phosphates

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or polyphosphates.

Preservatives cut the dry residue in the cleaning articles according to the invention against microbes caused adverse changes. The sodium salts of benzoic acid of p-alkoxybenzoic acids, the dehydracetic acid and sorbic acid, as well as chloroacetamide, phenylethyl alcohol and 8-hydroxyquinoline are particularly useful as preservatives.

The antioxidants slit the dryness of the Cleaning article according to the invention against chemical decomposition, which occurs through oxidation in the air can. Suitable antioxidants are e.g. butylhydroxytoluene, butylhydroxyanisole, methyl, ethyl, propyl, Lauryl gallate, nordihydroguajaretic acid (NDGA), tocopherols, 2,2'-methylene-bis- (4-ethyl-6-tert.) - butylphenol, citric acid, Ascorbic acid.

Suitable foam reinforcing agents or foam stabilizers are in particular fatty acid amides, fatty acid alkyl oil amides e.g. methylenedistearamide and coconut fatty acid diethanolamide as well as the amino oxides such as cetyldimethylaminooxide, Lauryldimethylaminooxide, stearyldimethylaminooxide, myristylcetyl-dimethylaminooxide.

The total content of additives is generally 0.1 to 60%, preferably 0.1 to 20% by weight

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of the impregnation preparation.

Of the further additives mentioned, the following amounts are preferably used: 0.001 to 2% by weight of preservatives and / or antioxidants; 0.01 to 1% by weight of dye, 0.1 to 5% sequestering agent and 0.1 to 5% perfume, all of the above percentages being based on the weight of the impregnating preparation.

During the impregnation, the fleece can usually contain 50% to 1000% of its own weight in impregnation preparation take up. However, it is preferred to take up the preparation in amounts of 100 to 500% of the weight of the fleece.

The residue remaining on the impregnated fleece after the impregnation preparation has dried is approximately 10 to 200%, preferably up to 100%, of the weight of the fleece.

The cleaning article according to the invention can on can be made in different ways. The as yet non-impregnated fleece can follow, but preferably before "its" Processing into a bag with the impregnation preparation soaked, sprayed or padded and then to be dried.

The processing of the fleece into a pocket that can be used as a glove is carried out by cutting out and folding a rectangular piece of fleece once and, if necessary, by gluing or total heating (thermal welding)

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while pressing or by sewing along two of the three free edges of the circumference. The cleaning article can be impregnated by design of the wet Fleece can be dried at room temperature or in a drying cabinet.

In the following examples, the quantities given are parts by weight, unless otherwise noted.

Examples 1 to 3

There are three nonwovens made of viscose-rayon fibers connected by synthetic rubber (based on isoprene) (consisting of 75% by weight viscose silk and 25% by weight rubber)

2
each of which has 1 m surface, padded with 300 g of one of the emulsions 1, 2 and 3 and dried. These fleeces have a thickness of 0.14 (examples 1 and 2) or 0.23 mm (example 3), a nominal weight of 32 or

40 g / m and a tensile strength of 130 g to 145 g.

Such materials are currently being used by Bonded under the quality designations V.lOONF and V.130NF Fiber Fabrics Ltd., Bridgewater. Somerset, England, manufactured and sold).

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TABLE I.

Impregnation preparation 1 50 - 10 2 55 - 10 3 37 Sodium polyethoxylaurium sulfate
(277oig in water: MG-384) 0.4 0.4 0.3 Coconut fatty acid diethanolamide - Glycerin 5 Sodium hexametaphosphate 5 2.4 Sodium chloride 0.2 0.2 - aqueous chamomile extract (cone.) 0.04 0.04 watery linden blossom
extract (cone.) 1.2 1.6 0.3 p ~ meth.oxybenzoic acid sodium 38.16 22.76 - water soluble dye 0.3 Perfume 59.7 Deionized water

After impregnation and drying in a heating cabinet at 40 ^° C., each of the impregnated nonwovens is cut into rectangular parts, each 31 cm × 21.3 cm, folded in the middle and glued along two adjacent edges. The cleaning articles obtained according to these examples have the shape of a glove of 15.5 cm × 21.3 cm, weigh about 2 g and are each intended for single use.

Each inventive cleaning article obtained in this way contains between 2.5 and 3 g of dry residue.

When using them, even under running water,

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becomes a pleasant, strong foam with good skin cleansing properties and creates skin care effect.

Similar results are obtained if, instead of the above-mentioned nonwovens, the ones given below are used Quality designations used by the same company placed on the market; namely:

TABLE II

quality thickness
mm weight
g / m ² Fiber type Binder- Salary* Γ 100
XLB 45
XMR 60 BL
MX 201
KLB 33 0.15
0.24
0.38
0.28
0.17 34
45
60
52
34 Viscose art
silk / nylon
(Weight adj
ratio 55:45)
like examples
4-6
Nylon-poly
ester / viscose
rayon
90:10
Nylon-poly
ester / viscose
rayon Type 35
35
35
35 Polyacrylic
ester resin
Polyacrylic
ester resin
Polyacrylic
ester resin
Polyacrylic
ester resin

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Examples 4 to 6

There are three fleeces, each 1 m in size and 34 g Weight, consisting of a mixture of nylon / polyester fibers (weight ratio 1: 1) bonded by a polyacrylic acid resin, with viscose rayon fibers, the Content of viscose silk 10% of the pure fiber weight and the content of binder 35%, based on the weight of the not yet impregnated fleece, padded with 300 g of one of the following emulsions and at room temperature dried.

TABLE III

Impregnation preparation 4th 5 6th Sodium lauryl ether sulfate (28%) 50.00 47.5 47.5 Foaming agent (a) 17.5 17.5 Coconut fatty acid diethanolamide 3.00 - - Oleic acid diethanolamide 5.0 - Foaming agent (b) (41%) 10.00 - - superfatting agent (c) 3.00 - - Superfatting agent (d) - - 5.0 Methyl parahydroxybenzoate 0.10 - - Water soluble dye 0.05 - - Perfume 1.00 - - Deionized water 32.85 30.00 30.00

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(a) Foaming agent of the formula

CH ₃

R-CO-NH- (CH ₂ ) ₃ -N © _CH ₂ -COo

CH ₃

where R-CO is a mixture of lauric and stearic acid residues in a weight ratio of 3: 7 means (available from Chem. Factory Th. Goldschmidt AG., Essen, Germany; TEGOBETAIN®).

(b) foaming agent consisting of a mixture of

C, ₂ to C, ο fatty alcohol ether sulfates with ethylene glycol stearate as a pearlescent substance (as
41% aqueous paste available from Henkel & Cie GmbH, Düsseldorf, Germany: DEHYKONT PK 776®).

(c) Superfatting agent, consisting of a glycerol ester of coconut fatty acid, pH of the 5% aqueous Solution: about 6.3

^d 20 ^{= 1> 5}

η _β 20 = about 1.5

Viscosity at 20 ^° C.: about 200 cP

Saponification number: about 90

Iodine number: <5

(available from Deutsche Hydrierwerke, Düsseldorf: CETIOL HI

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(d) Skin protection substance (plasticizer) oxyethylated, liquid portion of the lanolin obtained by selective solvents.
Acid number: max 2.0
Saponification number: 10-20
Hydroxyl number: 10-25
Iodine number: 9-16
(available from Malmstrom Chemical Corp .: LANTROL AWS

Examples 7 and 8

There are 3 non-woven fleece pieces from the same Material as in Examples 4 to 6, padded in the following emulsions:

TABLE III

Components 7th 8th Foaming agent (a) 20.00 Foam reinforcement agent (s) 20.00 Cetyltrimethylammonium chloride 4.90 Triethanolamine salt des 20.00 Lauryl ether sulfate Sucrose monolaurate 5.0 Superfatting agent 4.9 Perfume 0.1 0.1 deionized water 55.00 55.00

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(e) Oxethylated hydrogenated tall oil amide with thoroughly " an average of 50 ethylene oxide units per molecule, (available from ARMOR INDUSTRIAL CHEMICAL COMPANY, Chicago, U.S.A .: ETHOMID HT / 60 ©).

(f) Oxethylated sorbitol-lanolin derivative having an HLB of 16 (available from ATLAS POWDER Company, Wilmington U.S.A. ': ATLAS G-1471®).

Example 9

Under the same conditions as in the previous examples, a nonwoven fabric is made into a gel of the following composition padded.

TABLE IV

Components 9 Sodium lauryl sulfate 88% 10.00 Thickener (g) 1.50 Sequestering agent (h) 0.15 Methyl parahydroxy benzoate 0.10 Triethanolamine 1.40 deionized water 86.85

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(g) thickener adhesive; high molecular weight carboxyvinyl polymer,

Viscosity of a 0.5% gel: approx. 8.9 cP (available from B.F. GOODRICH CHEMICAL COMP., Cleveland, U.S.A .: CARBOPOL 941®).

(h) sequestrants; Ethyleiidiaruintetraacetic acid disodium salt.

The cleaning article according to the invention obtained with this impregnated fleece is particularly suitable for use in the bath.

Examples 10 to 12

Six nonwovens measuring 1 m × 0.25 m, which are described in the examples in TABLE II at the last point under the designation XLB 33, are produced by means of two rollers, between which a pressure of 0.7 bar or 1 , 4 bar prevails, each padded with one of the following compositions. Before padding, each piece of fleece weighs 8.5 g.

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TABLE V

Comp ons 10 - 11 - 12th Sodium Lauryl Ether Sulphate (25%) 97 - 40 - 47.5 Foaming agent (a) (see example 5,6) - 1.5 20.0 Skin protection substance (d) - 0.1 5.0 Thickener (g) (see example) 2.5 - - Sequestering agent (h) (see example) 0.5 1.0 - Dye (blue) - 57.45 - Perfume up to pH 7 1.0 deionized water 26.5 Triethanolamine -

After spinning and drying at room temperature each piece of fleece weighed. The weight gain corresponds the weight of the dry residue.

TABLE VI

IMPREGNATION CONDITIONS DRY RESIDUE 11 12th Padding with 0.7 bar pressure
Padding with 14 bar pressure lo 1.95 g
1.25 g 6.8 g
5.0 g 3.5 g
2.8 g

In these examples the dry residue is up to 927o of the weight of the unimpregnated fleece.

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Claims (21)

_ 24 - claims 1.) Clean your items with a detergent donating fiber fleece, the fibers of which are connected to one another by a water-insoluble binder, thereby characterized in that a cosmetically acceptable, foam-forming cleaning agent in at least part of the Fleece adheres to the fiber material in an even distribution and when dry. 2. Cleaning article according to claim 1, characterized in that that the fleece is the dry residue of an aqueous impregnation preparation from at least one Contains cosmetically acceptable foam-forming detergents. 3. Cleaning article according to claim 1, characterized in that it has the shape of a pocket. 4. Cleaning article according to claim 1 or 2, characterized characterized in that the fiber material is made from native or regenerated cellulose, from synthetic polyamide Polyester, polyacrylonitrile or mixtures of two or more such fibers. 5. Cleaning article according to one of claims 1 to 3, characterized in that the fiber binder is a synthetic rubber or a resin suitable for this purpose. 509827/0143 6. "Cleaning article according to claim 4, characterized in that the fleece 50 to 90 parts viscose rayon fibers which are associated with 10 to 50 parts of a synthetic rubber. 7. Cleaning article according to claim 4, characterized in that the fleece, based on its total weight, 5o to 90% of a mixture of fibers made of viscose rayon on the one hand and on the other hand synthetic polyamide and / or polyester fibers in a weight ratio of 1: 5 to 1:15 and, also based on the total weight of the fleece, contains 10 to 50% of an acrylic acid ester resin as a fiber binder. 8. Cleaning article according to one of claims 2 to 7, characterized in that the pH of the impregnation preparation is between 2.5 and 8. 9. Cleaning article according to claim 8, characterized in that the pH of the impregnation preparation is between 6.5 and 7.5. 10. Cleaning article according to claim 7, characterized in that the amount of foaming agent is at least 5%, based on on the weight of the impregnation preparation. 11. Cleaning article according to claim 10, characterized in that the amount of foaming agent 5 to 807o, based on the weight of the impregnation preparation. '· 5 0 9827/0143 12. Cleaning article according to claim 11, characterized in that that the foaming agent 10 to 50 wt.%, Based on the weight of the impregnation preparation. 13. Cleaning article according to one of claims 1 to 12, characterized in that the foaming agent contains at least one anionic foaming agent. 14. Cleaning article according to one of claims 1 to 13, characterized in that the foaming agent has an HLB value between 7 and 40. 15. Cleaning article according to claim 14, characterized in that the foaming agent has an HLB value between 10 and 40 has. 16. Cleaning article according to one of claims 1 to 14, characterized in that it contains a skin protection agent and / or a humectant. 17. Cleaning article according to claim 16, characterized in that that it uses a fatty acid alkylolamide as a skin protection agent, a lecithin, a wool fatty alcohol, a wool fat derivative, a hydrogenated fat, a herbal drug Contains silicone oil, and / or a hydrophilic polyol. 18. Cleaning article according to one of claims 2 to 17, characterized in that the impregnation preparation contains a hydrophilic thickener. 509827/0143 19. Cleaning article according to one of claims 2 to 18, characterized in that the dry residue 10 to Makes up 200% of the weight of the fleece. 20. Cleaning article according to claim 19, characterized in that the dry residue is 10 to 100% of the weight of the fleece matters. 21. A method of manufacturing a cleaning article of in claim 1 specified composition with a Detergent-releasing fiber fleece, the fibers of which are connected by a water-insoluble binder, thereby characterized in that the fiber material with an aqueous preparation of a cosmetically acceptable foam-forming Impregnated detergent and then it dries. 509827/0143