DE29624395U1 - Substrat mit photokalytischer Beschichtung - Google Patents
Substrat mit photokalytischer BeschichtungInfo
- Publication number
- DE29624395U1 DE29624395U1 DE1996224395 DE29624395U DE29624395U1 DE 29624395 U1 DE29624395 U1 DE 29624395U1 DE 1996224395 DE1996224395 DE 1996224395 DE 29624395 U DE29624395 U DE 29624395U DE 29624395 U1 DE29624395 U1 DE 29624395U1
- Authority
- DE
- Germany
- Prior art keywords
- coating
- substrate according
- substrate
- way
- titanium
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Expired - Lifetime
Links
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- C—CHEMISTRY; METALLURGY
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- C04B—LIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
- C04B41/00—After-treatment of mortars, concrete, artificial stone or ceramics; Treatment of natural stone
- C04B41/009—After-treatment of mortars, concrete, artificial stone or ceramics; Treatment of natural stone characterised by the material treated
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- C—CHEMISTRY; METALLURGY
- C03—GLASS; MINERAL OR SLAG WOOL
- C03C—CHEMICAL COMPOSITION OF GLASSES, GLAZES OR VITREOUS ENAMELS; SURFACE TREATMENT OF GLASS; SURFACE TREATMENT OF FIBRES OR FILAMENTS MADE FROM GLASS, MINERALS OR SLAGS; JOINING GLASS TO GLASS OR OTHER MATERIALS
- C03C17/00—Surface treatment of glass, not in the form of fibres or filaments, by coating
- C03C17/001—General methods for coating; Devices therefor
- C03C17/002—General methods for coating; Devices therefor for flat glass, e.g. float glass
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- C—CHEMISTRY; METALLURGY
- C03—GLASS; MINERAL OR SLAG WOOL
- C03C—CHEMICAL COMPOSITION OF GLASSES, GLAZES OR VITREOUS ENAMELS; SURFACE TREATMENT OF GLASS; SURFACE TREATMENT OF FIBRES OR FILAMENTS MADE FROM GLASS, MINERALS OR SLAGS; JOINING GLASS TO GLASS OR OTHER MATERIALS
- C03C17/00—Surface treatment of glass, not in the form of fibres or filaments, by coating
- C03C17/006—Surface treatment of glass, not in the form of fibres or filaments, by coating with materials of composite character
- C03C17/007—Surface treatment of glass, not in the form of fibres or filaments, by coating with materials of composite character containing a dispersed phase, e.g. particles, fibres or flakes, in a continuous phase
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- C—CHEMISTRY; METALLURGY
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- C03C17/00—Surface treatment of glass, not in the form of fibres or filaments, by coating
- C03C17/22—Surface treatment of glass, not in the form of fibres or filaments, by coating with other inorganic material
- C03C17/23—Oxides
- C03C17/25—Oxides by deposition from the liquid phase
- C03C17/256—Coating containing TiO2
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- C03C—CHEMICAL COMPOSITION OF GLASSES, GLAZES OR VITREOUS ENAMELS; SURFACE TREATMENT OF GLASS; SURFACE TREATMENT OF FIBRES OR FILAMENTS MADE FROM GLASS, MINERALS OR SLAGS; JOINING GLASS TO GLASS OR OTHER MATERIALS
- C03C17/00—Surface treatment of glass, not in the form of fibres or filaments, by coating
- C03C17/34—Surface treatment of glass, not in the form of fibres or filaments, by coating with at least two coatings having different compositions
- C03C17/3411—Surface treatment of glass, not in the form of fibres or filaments, by coating with at least two coatings having different compositions with at least two coatings of inorganic materials
- C03C17/3417—Surface treatment of glass, not in the form of fibres or filaments, by coating with at least two coatings having different compositions with at least two coatings of inorganic materials all coatings being oxide coatings
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- C03—GLASS; MINERAL OR SLAG WOOL
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- C03C17/00—Surface treatment of glass, not in the form of fibres or filaments, by coating
- C03C17/34—Surface treatment of glass, not in the form of fibres or filaments, by coating with at least two coatings having different compositions
- C03C17/3411—Surface treatment of glass, not in the form of fibres or filaments, by coating with at least two coatings having different compositions with at least two coatings of inorganic materials
- C03C17/3429—Surface treatment of glass, not in the form of fibres or filaments, by coating with at least two coatings having different compositions with at least two coatings of inorganic materials at least one of the coatings being a non-oxide coating
- C03C17/3441—Surface treatment of glass, not in the form of fibres or filaments, by coating with at least two coatings having different compositions with at least two coatings of inorganic materials at least one of the coatings being a non-oxide coating comprising carbon, a carbide or oxycarbide
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- C04B41/4505—Coating or impregnating, e.g. injection in masonry, partial coating of green or fired ceramics, organic coating compositions for adhering together two concrete elements characterised by the method of application
- C04B41/4562—Photographic methods, e.g. making use of photo-sensitive materials
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- C04B41/45—Coating or impregnating, e.g. injection in masonry, partial coating of green or fired ceramics, organic coating compositions for adhering together two concrete elements
- C04B41/52—Multiple coating or impregnating multiple coating or impregnating with the same composition or with compositions only differing in the concentration of the constituents, is classified as single coating or impregnation
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- C04B41/00—After-treatment of mortars, concrete, artificial stone or ceramics; Treatment of natural stone
- C04B41/80—After-treatment of mortars, concrete, artificial stone or ceramics; Treatment of natural stone of only ceramics
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- G02F1/00—Devices or arrangements for the control of the intensity, colour, phase, polarisation or direction of light arriving from an independent light source, e.g. switching, gating or modulating; Non-linear optics
- G02F1/01—Devices or arrangements for the control of the intensity, colour, phase, polarisation or direction of light arriving from an independent light source, e.g. switching, gating or modulating; Non-linear optics for the control of the intensity, phase, polarisation or colour
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- G02F1/133—Constructional arrangements; Operation of liquid crystal cells; Circuit arrangements
- G02F1/1333—Constructional arrangements; Manufacturing methods
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- C03C—CHEMICAL COMPOSITION OF GLASSES, GLAZES OR VITREOUS ENAMELS; SURFACE TREATMENT OF GLASS; SURFACE TREATMENT OF FIBRES OR FILAMENTS MADE FROM GLASS, MINERALS OR SLAGS; JOINING GLASS TO GLASS OR OTHER MATERIALS
- C03C2217/00—Coatings on glass
- C03C2217/20—Materials for coating a single layer on glass
- C03C2217/21—Oxides
- C03C2217/211—SnO2
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- C—CHEMISTRY; METALLURGY
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- C03C2217/00—Coatings on glass
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- C03C2217/212—TiO2
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- C03C2217/00—Coatings on glass
- C03C2217/20—Materials for coating a single layer on glass
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- C03C2217/213—SiO2
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- C—CHEMISTRY; METALLURGY
- C03—GLASS; MINERAL OR SLAG WOOL
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- C03C2217/00—Coatings on glass
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- C03C2217/214—Al2O3
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- C—CHEMISTRY; METALLURGY
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- C03C2217/00—Coatings on glass
- C03C2217/20—Materials for coating a single layer on glass
- C03C2217/21—Oxides
- C03C2217/22—ZrO2
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- C—CHEMISTRY; METALLURGY
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- C03C2217/24—Doped oxides
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- C03C2217/00—Coatings on glass
- C03C2217/40—Coatings comprising at least one inhomogeneous layer
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- Y10T428/252—Glass or ceramic [i.e., fired or glazed clay, cement, etc.] [porcelain, quartz, etc.]
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- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y10—TECHNICAL SUBJECTS COVERED BY FORMER USPC
- Y10T—TECHNICAL SUBJECTS COVERED BY FORMER US CLASSIFICATION
- Y10T428/00—Stock material or miscellaneous articles
- Y10T428/25—Web or sheet containing structurally defined element or component and including a second component containing structurally defined particles
- Y10T428/256—Heavy metal or aluminum or compound thereof
-
- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y10—TECHNICAL SUBJECTS COVERED BY FORMER USPC
- Y10T—TECHNICAL SUBJECTS COVERED BY FORMER US CLASSIFICATION
- Y10T428/00—Stock material or miscellaneous articles
- Y10T428/26—Web or sheet containing structurally defined element or component, the element or component having a specified physical dimension
- Y10T428/263—Coating layer not in excess of 5 mils thick or equivalent
- Y10T428/264—Up to 3 mils
- Y10T428/265—1 mil or less
-
- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y10—TECHNICAL SUBJECTS COVERED BY FORMER USPC
- Y10T—TECHNICAL SUBJECTS COVERED BY FORMER US CLASSIFICATION
- Y10T428/00—Stock material or miscellaneous articles
- Y10T428/31504—Composite [nonstructural laminate]
- Y10T428/31826—Of natural rubber
- Y10T428/31841—Next to cellulosic
-
- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y10—TECHNICAL SUBJECTS COVERED BY FORMER USPC
- Y10T—TECHNICAL SUBJECTS COVERED BY FORMER US CLASSIFICATION
- Y10T428/00—Stock material or miscellaneous articles
- Y10T428/31504—Composite [nonstructural laminate]
- Y10T428/31855—Of addition polymer from unsaturated monomers
- Y10T428/31938—Polymer of monoethylenically unsaturated hydrocarbon
Description
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Claims (17)
1. Substrat (1) auf der Basis von Glas, Keramik oder Glaskeramik das zumindest an ei
nem Teil mindestens einer seiner Seiten eine Beschichtung (3) aufweist, welche zu
mindest teilweise kristallisiertes Titanoxyd umfasst, wobei das Substrat mit der Be
schichtung so hergerichtet ist, dass organische Verbindungen, die auf der TiO2 Be
schichtung abgeschieden werden, durch einen photokatalytischen Effekt unter der
Einwirkung von natürlichem Licht oder UVA-Strahlung zerstört werden.
2. Substrat nach Anspruch 1, dadurch gekennzeichnet, dass die Beschichtung so ausge
bildet ist, dass organische Verschmutzungen, die in Form von Organosilanschichten,
insbesondere Oktadecyltrichlorsilan (OTS) in einer Dicke von zumindest 0,05 nm auf
der Beschichtung aufgebracht sind, bei einer UVA-Bestrahlung mit 0,6 W/m2 in einer
Stunde verschwinden.
3. Substrat nach Anspruch 1, dadurch gekennzeichnet, dass die Beschichtung so aus
gebildet ist, dass organische Verschmutzungen, die in Form von Organosilanschich
ten, insbesondere Oktadecyltrichlorsilan (OTS) in einer Dicke von zumindest 4 nm
auf der Beschichtung aufgebracht sind, bei einer UVA-Bestrahlung mit 0,6 W/m2 in
einer Stunde verschwinden.
4. Substrat nach Anspruch 1, dadurch gekennzeichnet, dass die Beschichtung so aus
gebildet ist, dass organische Verschmutzungen, in Form von Organosilanschichten,
insbesondere Oktadecyltrichlorsilan (OTS) in einer Dicke von zumindest 9 nm auf der
Beschichtung aufgebracht sind, bei einer UVA-Bestrahlung mit 0,6 W/m2 in einer
Stunde verschwinden.
5. Substrat nach Anspruch 1, dadurch gekennzeichnet, dass die Beschichtung so aus
gebildet ist, dass organische Verschmutzungen, die in Form von Organosilanschichten
Oktadecyltrichlorsilan (OTS) in einer Dicke von zumindest 19,5 nm auf der Be
schichtung aufgebracht sind, bei einer UVA-Bestrahlung mit 0,6 W/m2 in einer Stunde
verschwinden.
6. Substrat nach einem der hervor gehenden Ansprüche, dadurch gekennzeichnet, dass
das kristallisierte Titanoxyd in Anatase, Rutil oder in einer Mischung aus Anatase-
Rutil vorliegt.
7. Substrat nach einem der hervor gehenden Ansprüche, dadurch gekennzeichnet, dass
das Titanoxyd mit einem Krisallisationsgrad von zumindest 25%, insbesondere zwi
schen 30 und 80%, kristallisiert ist.
8. Substrat nach einem der hervor gehenden Ansprüche, dadurch gekennzeichnet, dass
das kristallisierte Titanoxyd in Form von Kristalliten mit einer mittleren Größe von
0,5 bis 60 nm, vorzugsweise 1 bis 50 nm und insbesondere 10 bis 40 nm vorliegt.
9. Substrat nach einem der hervor gehenden Ansprüche, dadurch gekennzeichnet, dass
die Oberfläche der Beschichtung (3) oleophil oder hydrophil ist, insbesondere
hydrophil in der Weise, dass insbesondere ein Kontaktwinkel mit Wasser nachfolgend
einer Lichtbestrahlung < 20° beträgt.
10. Substrat nach einem der Ansprüche 1 bis 8, dadurch gekennzeichnet, dass die Ober
fläche der Beschichtung (3) oleophil oder hydrophil ist, insbesondere hydrophil in der
Weise, dass insbesondere ein Kontaktwinkel mit Wasser nachfolgend einer Lichtbe
strahlung < 5° beträgt.
11. Substrat nach einem der vorhergehenden Ansprüche, dadurch gekennzeichnet, dass
die Dicke der Beschichtung (3) zwischen 5 nm und 1 µm, insbesondere zwischen 5
und 100 nm, vorzugsweise 10 bis 80 nm und höchst vorzugsweise 20 bis 50 nm be
trägt.
12. Substrat nach einem der vorhergehenden Ansprüche, dadurch gekennzeichnet, dass
die RMS-Rauhigkeit der Beschichtung (3) zwischen 2 und 20 nm, insbesondere zwi
schen 5 und 20 nm beträgt.
13. Substrat nach einem der vorhergehenden Ansprüche, dadurch gekennzeichnet, dass
unter der Beschichtung (3) mit den photokatalytischen Eigenschaften zumindest ein
dünner Film (2) angeordnet ist, der eine antistatische, thermische oder optische Funk
tion aufweist oder als Barriere gegen die Migration des aus dem Substrat stammenden
Alkalis dient.
14. Substrat nach Anspruch 13, dadurch gekennzeichnet, dass der dünne Film (2), der
eine Barriere gegenüber den Alkalien bereitstellt, auf Siliziumoxyd, Nitrid, Oxinitrid
oder Oxikarbid, Al2O3:F oder Aluminiumnitrid basiert.
15. Substrat nach Anspruch 13, dadurch gekennzeichnet, dass der dünne Film (2), der
eine optische Funktion aufweist, auf einem Oxyd oder einer Mischung aus Oxyden
basiert, deren Brechungsindex zwischen dem der Beschichtung und dem des Substrats
liegt, insbesondere aus einem der nachfolgenden Oxyde gewählt ist: Al2O3, SnO2,
In2O3, Siliziumoxikarbid oder Oxinitrid.
16. Substrat nach einem der vorhergehenden Ansprüche, dadurch gekennzeichnet, dass
die Beschichtung (3) die Endschicht eines Stapels von Antireflexionsschichten bildet.
17. Verglasung, die schmutzabweisend ist, und/oder eine Antibeschlagverglasung, die
monolithisch aufgebaut oder eine Mehrfachverglasung vom Typ Doppelverglasung
bzw. Verbundverglasung, in welche das Substrat (1) nach einem der vorhergehenden
Ansprüche eingebaut ist.
Applications Claiming Priority (2)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
FR9510839A FR2738813B1 (fr) | 1995-09-15 | 1995-09-15 | Substrat a revetement photo-catalytique |
EP96931839A EP0850204B1 (de) | 1995-09-15 | 1996-09-13 | Substrat mit photokatalytischer beschichtung |
Publications (1)
Publication Number | Publication Date |
---|---|
DE29624395U1 true DE29624395U1 (de) | 2003-01-16 |
Family
ID=9482590
Family Applications (4)
Application Number | Title | Priority Date | Filing Date |
---|---|---|---|
DE1996224395 Expired - Lifetime DE29624395U1 (de) | 1995-09-15 | 1996-09-13 | Substrat mit photokalytischer Beschichtung |
DE1996224343 Expired - Lifetime DE29624343U1 (de) | 1995-09-15 | 1996-09-13 | Substrat mit photokatalytischer Beschichtung |
DE1996617705 Revoked DE69617705T2 (de) | 1995-09-15 | 1996-09-13 | Substrat mit photokatalytischer beschichtung |
DE1996634178 Expired - Lifetime DE69634178T2 (de) | 1995-09-15 | 1996-09-13 | Substrat mit photokatalytischer Beschichtung |
Family Applications After (3)
Application Number | Title | Priority Date | Filing Date |
---|---|---|---|
DE1996224343 Expired - Lifetime DE29624343U1 (de) | 1995-09-15 | 1996-09-13 | Substrat mit photokatalytischer Beschichtung |
DE1996617705 Revoked DE69617705T2 (de) | 1995-09-15 | 1996-09-13 | Substrat mit photokatalytischer beschichtung |
DE1996634178 Expired - Lifetime DE69634178T2 (de) | 1995-09-15 | 1996-09-13 | Substrat mit photokatalytischer Beschichtung |
Country Status (16)
Country | Link |
---|---|
US (11) | US6103363A (de) |
EP (3) | EP1132351B1 (de) |
JP (6) | JP4485606B2 (de) |
KR (1) | KR100475355B1 (de) |
AT (2) | ATE286858T1 (de) |
AU (1) | AU7087596A (de) |
BR (1) | BR9610604A (de) |
CZ (1) | CZ299321B6 (de) |
DE (4) | DE29624395U1 (de) |
DK (2) | DK0850204T3 (de) |
ES (2) | ES2168506T3 (de) |
FR (1) | FR2738813B1 (de) |
PL (1) | PL192392B1 (de) |
PT (2) | PT1132351E (de) |
TR (1) | TR199800459T1 (de) |
WO (1) | WO1997010186A1 (de) |
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1995
- 1995-09-15 FR FR9510839A patent/FR2738813B1/fr not_active Expired - Lifetime
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1996
- 1996-09-13 PT PT01106093T patent/PT1132351E/pt unknown
- 1996-09-13 CZ CZ0078498A patent/CZ299321B6/cs not_active IP Right Cessation
- 1996-09-13 BR BR9610604A patent/BR9610604A/pt not_active IP Right Cessation
- 1996-09-13 TR TR1998/00459T patent/TR199800459T1/xx unknown
- 1996-09-13 PT PT96931839T patent/PT850204E/pt unknown
- 1996-09-13 AT AT01106093T patent/ATE286858T1/de active
- 1996-09-13 KR KR10-1998-0701868A patent/KR100475355B1/ko not_active IP Right Cessation
- 1996-09-13 AU AU70875/96A patent/AU7087596A/en not_active Abandoned
- 1996-09-13 EP EP20010106093 patent/EP1132351B1/de not_active Revoked
- 1996-09-13 US US09/029,855 patent/US6103363A/en not_active Expired - Lifetime
- 1996-09-13 DK DK96931839T patent/DK0850204T3/da active
- 1996-09-13 DE DE1996224395 patent/DE29624395U1/de not_active Expired - Lifetime
- 1996-09-13 DE DE1996224343 patent/DE29624343U1/de not_active Expired - Lifetime
- 1996-09-13 PL PL325527A patent/PL192392B1/pl unknown
- 1996-09-13 EP EP96931839A patent/EP0850204B1/de not_active Revoked
- 1996-09-13 WO PCT/FR1996/001421 patent/WO1997010186A1/fr not_active Application Discontinuation
- 1996-09-13 JP JP51172297A patent/JP4485606B2/ja not_active Expired - Lifetime
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- 2005-03-14 JP JP2005071728A patent/JP2005213142A/ja active Pending
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Cited By (1)
Publication number | Priority date | Publication date | Assignee | Title |
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DE10325768A1 (de) * | 2003-06-05 | 2004-12-23 | Chemetall Gmbh | Beschichtungssystem für Glasoberflächen, Verfahren zu dessen Herstellung und dessen Anwendung |
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