DE3260105D1 - Catalytic hydrogenation of di-(4-aminophenyl) methane - Google Patents
Catalytic hydrogenation of di-(4-aminophenyl) methaneInfo
- Publication number
- DE3260105D1 DE3260105D1 DE8282104441T DE3260105T DE3260105D1 DE 3260105 D1 DE3260105 D1 DE 3260105D1 DE 8282104441 T DE8282104441 T DE 8282104441T DE 3260105 T DE3260105 T DE 3260105T DE 3260105 D1 DE3260105 D1 DE 3260105D1
- Authority
- DE
- Germany
- Prior art keywords
- aminophenyl
- methane
- catalytic hydrogenation
- hydrogenation
- catalytic
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Expired
Links
Classifications
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
- C07C209/00—Preparation of compounds containing amino groups bound to a carbon skeleton
- C07C209/68—Preparation of compounds containing amino groups bound to a carbon skeleton from amines, by reactions not involving amino groups, e.g. reduction of unsaturated amines, aromatisation, or substitution of the carbon skeleton
- C07C209/70—Preparation of compounds containing amino groups bound to a carbon skeleton from amines, by reactions not involving amino groups, e.g. reduction of unsaturated amines, aromatisation, or substitution of the carbon skeleton by reduction of unsaturated amines
- C07C209/72—Preparation of compounds containing amino groups bound to a carbon skeleton from amines, by reactions not involving amino groups, e.g. reduction of unsaturated amines, aromatisation, or substitution of the carbon skeleton by reduction of unsaturated amines by reduction of six-membered aromatic rings
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
- C07C2601/00—Systems containing only non-condensed rings
- C07C2601/12—Systems containing only non-condensed rings with a six-membered ring
- C07C2601/14—The ring being saturated
Applications Claiming Priority (1)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
US06/269,200 US4394523A (en) | 1981-06-01 | 1981-06-01 | Catalytic hydrogenation of di (4-aminophenyl) methane |
Publications (1)
Publication Number | Publication Date |
---|---|
DE3260105D1 true DE3260105D1 (de) | 1984-05-17 |
Family
ID=23026227
Family Applications (1)
Application Number | Title | Priority Date | Filing Date |
---|---|---|---|
DE8282104441T Expired DE3260105D1 (de) | 1981-06-01 | 1982-05-21 | Catalytic hydrogenation of di-(4-aminophenyl) methane |
Country Status (5)
Country | Link |
---|---|
US (1) | US4394523A (de) |
EP (1) | EP0066210B1 (de) |
JP (1) | JPS57203043A (de) |
CA (1) | CA1190565A (de) |
DE (1) | DE3260105D1 (de) |
Families Citing this family (15)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
US4448995A (en) * | 1982-12-13 | 1984-05-15 | Mobay Chemical Corporation | Catalytic hydrogenation of di(4-aminophenyl)methane |
US4754070A (en) * | 1986-01-23 | 1988-06-28 | Air Products And Chemicals, Inc. | Hydrogenation of methylenedianiline to produce bis(para-aminocyclohexyl)methane |
US5196594A (en) * | 1988-01-14 | 1993-03-23 | Miles, Inc. | Process for the production of 4,4'-diamino-dicyclohexylmethane with a low trans-trans isomer content by the catalytic hydrogenation of 4,4'-diamino-diphenylmethane |
US4960941A (en) * | 1988-03-30 | 1990-10-02 | Air Products And Chemicals, Inc. | Hydrogenation of aromatic amines to produce their ring hydrogenated counterparts |
US5245082A (en) * | 1990-09-06 | 1993-09-14 | Bayer Aktiengesellschaft | Process for the production of di-(4-aminocyclohexyl)-methane containing 15 to 25% by weight of the trans-trans isomer |
US5214212A (en) * | 1992-02-27 | 1993-05-25 | Olin Corporation | Promoters for hydrogenation of aromatic amines |
US5550294A (en) * | 1992-02-05 | 1996-08-27 | Olin Corporation | Method of increasing hydrogenation rate of aromatic amines |
US5364971A (en) * | 1993-08-25 | 1994-11-15 | Texaco Chemical Inc. | Decolorization of polyethylene polyamines using ruthenium |
DE19533718A1 (de) * | 1995-09-12 | 1997-03-13 | Basf Ag | Verfahren zur Hydrierung von aromatischen Verbindungen, in denen mindestens eine Aminogruppe an einen aromatischen Kern gebunden ist |
DE10119136A1 (de) * | 2001-04-19 | 2002-11-14 | Bayer Ag | Ruthenium-Katalysator für die Hydrierung von Diaminodiphenylmethan zu Diaminodicyclohexylmethan |
US7049273B2 (en) * | 2002-07-17 | 2006-05-23 | Afton Chemical Intangibles Llc | Hybridized olefin copolymer additives |
US7743738B2 (en) * | 2007-03-01 | 2010-06-29 | Afton Chemical Corporation | Scavenging phosphorus, sulfur, and lead from combustion exhaust using tungsten compounds and lubricant |
US7794512B2 (en) * | 2007-03-16 | 2010-09-14 | Afton Chemical Corporation | Supplying tungsten to a combustion system or combustion system exhaust stream containing iron |
CN102093227B (zh) | 2011-01-07 | 2013-08-07 | 烟台万华聚氨酯股份有限公司 | 生产低的反-反异构体含量的4,4’-二氨基二环己基甲烷的方法 |
TWI534131B (zh) | 2014-11-27 | 2016-05-21 | 財團法人工業技術研究院 | 氫化4,4’-二胺基二苯甲烷的觸媒與方法 |
Family Cites Families (26)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
US2494563A (en) * | 1947-01-08 | 1950-01-17 | Du Pont | Bis (4-aminocyclohexyl) methane |
US2606928A (en) * | 1947-11-18 | 1952-08-12 | Du Pont | Preparation of amino alicyclic compounds |
US2606924A (en) * | 1949-06-09 | 1952-08-12 | Du Pont | Bis (4-aminocyclohexyl)-methane |
US2606925A (en) * | 1949-12-15 | 1952-08-12 | Du Pont | Ruthenium catalyzed hydrogenation process for obtaining aminocyclohexyl compounds |
US3155724A (en) * | 1961-12-29 | 1964-11-03 | Du Pont | Process for bringing stereoisomeric mixture of bis-(4-aminocyclohexane) methane close to the equilibrium concentration |
US3153088A (en) * | 1961-12-29 | 1964-10-13 | Du Pont | Selective alteration of the ratios of mixtures of bis-(4-aminocyclohexyl) methane isomers |
US3347917A (en) * | 1961-12-29 | 1967-10-17 | Du Pont | Process for the preparation of di (paraaminocyclohexyl) methane |
US3361814A (en) * | 1964-09-18 | 1968-01-02 | Mobay Chemical Corp | Cycloaliphatic tetraamines |
US3330850A (en) * | 1964-09-18 | 1967-07-11 | Mobay Chemical Corp | Cycloaliphatic tetraisocyanates |
US3393236A (en) * | 1965-06-09 | 1968-07-16 | Du Pont | Stereoisomeric preparation of bis(p-aminocyclohexyl) methane |
CH515882A (de) * | 1965-12-23 | 1971-11-30 | Du Pont | Verfahren zur Herstellung von 4,4'-Methylen-di-(cyclohexylamin) |
US3636108A (en) * | 1965-12-23 | 1972-01-18 | Du Pont | Catalytic hydrogenation of aromatic nitrogen containing compounds over alkali moderated ruthenium |
US3590002A (en) * | 1967-07-21 | 1971-06-29 | Mobay Chemical Corp | Mixtures of 2,4'-diisocyanato dicyclohexylmethane with lower aliphatic and cycloaliphatic polyisocyanates |
US3557180A (en) * | 1968-07-02 | 1971-01-19 | Du Pont | 2,4-bis(isocyanatocyclohexylmethyl) cyclohexyl isocyanate |
US3644522A (en) * | 1969-04-04 | 1972-02-22 | Du Pont | Catalytic hydrogenation of nitrogen containing compounds over supported ruthenium catalysts |
JPS4939994B1 (de) * | 1969-10-16 | 1974-10-30 | ||
US3825586A (en) * | 1969-11-21 | 1974-07-23 | Du Pont | Process for enriching trans-trans salts of bis(4-aminocyclohexyl)methane and 1,12-dodecanedioic acid |
US3711550A (en) * | 1970-02-16 | 1973-01-16 | Du Pont | Isomerization of 4,4'-methylenedi (cyclohexylamine) over moderated ruthenium catalyst |
US3676495A (en) * | 1970-09-16 | 1972-07-11 | Du Pont | 2,4-bis(4-aminocyclohexylmethyl)cyclohexylamine |
US3743677A (en) * | 1971-08-03 | 1973-07-03 | Basf Ag | Continuous manufacture of bis(aminocyclohexyl)-alkanes or bis(aminocyclohexyl)ethers |
US3766272A (en) * | 1972-08-25 | 1973-10-16 | Du Pont | 4,4'-methylenedi(cyclohexylamine)isomerization over a supported catalyst |
US3856862A (en) * | 1973-06-25 | 1974-12-24 | Upjohn Co | Process for hydrogenation of di(4-aminophenyl)methane with a rhodium catalyst |
US3914307A (en) * | 1973-12-27 | 1975-10-21 | Universal Oil Prod Co | Hydrogenation of aromatic amines |
US3959374A (en) * | 1974-05-30 | 1976-05-25 | Jefferson Chemical Company, Inc. | Process for the preparation of mixed isomeric methylene-bridged polycyclohexylpolyamines |
US4161492A (en) * | 1975-01-24 | 1979-07-17 | Bayer Aktiengesellschaft | Cycloaliphatic amines and process for preparing same |
US4226737A (en) * | 1977-11-10 | 1980-10-07 | Milliken Research Corporation | Polycycloaliphatic polyamines |
-
1981
- 1981-06-01 US US06/269,200 patent/US4394523A/en not_active Expired - Lifetime
-
1982
- 1982-04-13 CA CA000400847A patent/CA1190565A/en not_active Expired
- 1982-05-21 DE DE8282104441T patent/DE3260105D1/de not_active Expired
- 1982-05-21 EP EP82104441A patent/EP0066210B1/de not_active Expired
- 1982-05-28 JP JP57090053A patent/JPS57203043A/ja active Pending
Also Published As
Publication number | Publication date |
---|---|
JPS57203043A (en) | 1982-12-13 |
US4394523A (en) | 1983-07-19 |
CA1190565A (en) | 1985-07-16 |
EP0066210B1 (de) | 1984-04-11 |
EP0066210A1 (de) | 1982-12-08 |
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Legal Events
Date | Code | Title | Description |
---|---|---|---|
8339 | Ceased/non-payment of the annual fee |