DE60023011D1 - Niederwertige frühübergangsmetallkatalysatoren für die polymerisation von olefinen enthaltend eine cyclopentadienylgruppe - Google Patents
Niederwertige frühübergangsmetallkatalysatoren für die polymerisation von olefinen enthaltend eine cyclopentadienylgruppeInfo
- Publication number
- DE60023011D1 DE60023011D1 DE60023011T DE60023011T DE60023011D1 DE 60023011 D1 DE60023011 D1 DE 60023011D1 DE 60023011 T DE60023011 T DE 60023011T DE 60023011 T DE60023011 T DE 60023011T DE 60023011 D1 DE60023011 D1 DE 60023011D1
- Authority
- DE
- Germany
- Prior art keywords
- sub
- sup
- line
- formulae
- hydrocarbyl
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Expired - Fee Related
Links
Classifications
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
- C08F220/00—Copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and only one being terminated by only one carboxyl radical or a salt, anhydride ester, amide, imide or nitrile thereof
- C08F220/02—Monocarboxylic acids having less than ten carbon atoms; Derivatives thereof
- C08F220/10—Esters
- C08F220/12—Esters of monohydric alcohols or phenols
- C08F220/14—Methyl esters, e.g. methyl (meth)acrylate
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J31/00—Catalysts comprising hydrides, coordination complexes or organic compounds
- B01J31/16—Catalysts comprising hydrides, coordination complexes or organic compounds containing coordination complexes
- B01J31/22—Organic complexes
- B01J31/2282—Unsaturated compounds used as ligands
- B01J31/2295—Cyclic compounds, e.g. cyclopentadienyls
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
- C08F10/00—Homopolymers and copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
- C08F12/00—Homopolymers and copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and at least one being terminated by an aromatic carbocyclic ring
- C08F12/02—Monomers containing only one unsaturated aliphatic radical
- C08F12/04—Monomers containing only one unsaturated aliphatic radical containing one ring
- C08F12/06—Hydrocarbons
- C08F12/08—Styrene
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
- C08F212/00—Copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and at least one being terminated by an aromatic carbocyclic ring
- C08F212/02—Monomers containing only one unsaturated aliphatic radical
- C08F212/04—Monomers containing only one unsaturated aliphatic radical containing one ring
- C08F212/06—Hydrocarbons
- C08F212/08—Styrene
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
- C08F4/00—Polymerisation catalysts
- C08F4/42—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors
- C08F4/44—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides
- C08F4/60—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides together with refractory metals, iron group metals, platinum group metals, manganese, rhenium technetium or compounds thereof
- C08F4/619—Component covered by group C08F4/60 containing a transition metal-carbon bond
- C08F4/6192—Component covered by group C08F4/60 containing a transition metal-carbon bond containing at least one cyclopentadienyl ring, condensed or not, e.g. an indenyl or a fluorenyl ring
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J2231/00—Catalytic reactions performed with catalysts classified in B01J31/00
- B01J2231/10—Polymerisation reactions involving at least dual use catalysts, e.g. for both oligomerisation and polymerisation
- B01J2231/12—Olefin polymerisation or copolymerisation
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J2531/00—Additional information regarding catalytic systems classified in B01J31/00
- B01J2531/40—Complexes comprising metals of Group IV (IVA or IVB) as the central metal
- B01J2531/46—Titanium
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
- C08F4/00—Polymerisation catalysts
- C08F4/42—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors
- C08F4/44—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides
- C08F4/60—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides together with refractory metals, iron group metals, platinum group metals, manganese, rhenium technetium or compounds thereof
- C08F4/62—Refractory metals or compounds thereof
- C08F4/64—Titanium, zirconium, hafnium or compounds thereof
- C08F4/659—Component covered by group C08F4/64 containing a transition metal-carbon bond
- C08F4/65908—Component covered by group C08F4/64 containing a transition metal-carbon bond in combination with an ionising compound other than alumoxane, e.g. (C6F5)4B-X+
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
- C08F4/00—Polymerisation catalysts
- C08F4/42—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors
- C08F4/44—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides
- C08F4/60—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides together with refractory metals, iron group metals, platinum group metals, manganese, rhenium technetium or compounds thereof
- C08F4/62—Refractory metals or compounds thereof
- C08F4/64—Titanium, zirconium, hafnium or compounds thereof
- C08F4/659—Component covered by group C08F4/64 containing a transition metal-carbon bond
- C08F4/6592—Component covered by group C08F4/64 containing a transition metal-carbon bond containing at least one cyclopentadienyl ring, condensed or not, e.g. an indenyl or a fluorenyl ring
-
- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y10—TECHNICAL SUBJECTS COVERED BY FORMER USPC
- Y10S—TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y10S526/00—Synthetic resins or natural rubbers -- part of the class 520 series
- Y10S526/943—Polymerization with metallocene catalysts
Applications Claiming Priority (5)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
US14232999P | 1999-07-03 | 1999-07-03 | |
US142329P | 1999-07-03 | ||
US608855 | 2000-06-30 | ||
US09/608,855 US6670299B1 (en) | 1999-07-03 | 2000-06-30 | Cyclopentadienyl-containing low-valent early transition metal olefin polymerization catalysts |
PCT/US2000/018336 WO2001002445A1 (en) | 1999-07-03 | 2000-07-03 | Cyclopentadienyl-containing low-valent early transition metal olefin polymerization catalysts |
Publications (2)
Publication Number | Publication Date |
---|---|
DE60023011D1 true DE60023011D1 (de) | 2006-02-16 |
DE60023011T2 DE60023011T2 (de) | 2006-07-13 |
Family
ID=26839992
Family Applications (1)
Application Number | Title | Priority Date | Filing Date |
---|---|---|---|
DE60023011T Expired - Fee Related DE60023011T2 (de) | 1999-07-03 | 2000-07-03 | Niederwertige frühübergangsmetallkatalysatoren für die polymerisation von olefinen enthaltend eine cyclopentadienylgruppe |
Country Status (6)
Country | Link |
---|---|
US (6) | US6670299B1 (de) |
EP (1) | EP1200486B1 (de) |
AT (1) | ATE305945T1 (de) |
AU (1) | AU5912200A (de) |
DE (1) | DE60023011T2 (de) |
WO (1) | WO2001002445A1 (de) |
Families Citing this family (27)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
US6670299B1 (en) * | 1999-07-03 | 2003-12-30 | Northwestern University | Cyclopentadienyl-containing low-valent early transition metal olefin polymerization catalysts |
KR100366424B1 (ko) * | 2000-08-14 | 2003-01-09 | 삼성종합화학주식회사 | 내충격특성이 우수한 신디오탁틱 폴리스티렌의 리액터얼로이 |
AU2001296670A1 (en) * | 2000-10-06 | 2002-04-15 | Carnegie-Mellon University | A catalyst system for controlled polymerization |
PL1638933T3 (pl) * | 2003-06-17 | 2008-10-31 | Pfizer | Pochodne n-pirolidyn-3-yloamidu jako inhibitory wychwytu zwrotnego serotoniny i noradrenaliny |
JP5171248B2 (ja) | 2004-03-05 | 2013-03-27 | カーネギー−メロン ユニバーシティ | 原子移動ラジカル重合法 |
US8273823B2 (en) | 2005-08-23 | 2012-09-25 | Carnegie Mellon University | Atom transfer radical polymerization in microemulsion and true emulsion polymerization processes |
EP1943278B1 (de) | 2005-08-26 | 2010-10-06 | Carnegie Mellon University | Polymerisationsverfahren mit katalysatorreaktivierung |
CA2632880A1 (en) * | 2005-12-16 | 2007-07-05 | Dow Global Technologies Inc. | Polydentate heteroatom ligand containing metal complexes, catalysts and methods of making and using the same |
FR2903988B1 (fr) * | 2006-07-18 | 2008-09-05 | Arkema France | Procede de preparation de polymeres (meth)acryliques |
WO2008057163A2 (en) | 2006-10-09 | 2008-05-15 | Carnegie Mellon University | Preparation of functional gel particles with a dual crosslink network |
WO2009023353A1 (en) | 2007-05-23 | 2009-02-19 | Carnegie Mellon University | Hybrid particle composite structures with reduced scattering |
GB2463199B (en) | 2007-05-23 | 2012-09-26 | Univ Carnegie Mellon | Atom transfer dispersion polymerization |
US7863210B2 (en) | 2007-12-28 | 2011-01-04 | Chevron Phillips Chemical Company Lp | Nano-linked metallocene catalyst compositions and their polymer products |
US8080681B2 (en) | 2007-12-28 | 2011-12-20 | Chevron Phillips Chemical Company Lp | Nano-linked metallocene catalyst compositions and their polymer products |
US8012900B2 (en) * | 2007-12-28 | 2011-09-06 | Chevron Phillips Chemical Company, L.P. | Nano-linked metallocene catalyst compositions and their polymer products |
WO2010111708A1 (en) | 2009-03-27 | 2010-09-30 | Carnegie Mellon University | Preparation of functional star macromolecules |
US7919639B2 (en) * | 2009-06-23 | 2011-04-05 | Chevron Phillips Chemical Company Lp | Nano-linked heteronuclear metallocene catalyst compositions and their polymer products |
WO2012038969A1 (en) | 2010-09-03 | 2012-03-29 | Ganapati Dadasaheb Yadav | Process for converting fructose into 5-hydroxymethylfurfural using a mesoporous silica based catalyst impregnated with rare earth metals |
WO2012091965A1 (en) | 2010-12-17 | 2012-07-05 | Carnegie Mellon University | Electrochemically mediated atom transfer radical polymerization |
EP2747753B1 (de) | 2011-08-22 | 2023-03-29 | Carnegie Mellon University | Radikalische atomtransfer-polymerisation unter biologisch verträglichen bedingungen |
WO2013126745A2 (en) | 2012-02-23 | 2013-08-29 | Carnegie Mellon University | Ligands designed to provide highly active catalyst complexes |
US9718898B1 (en) | 2012-11-20 | 2017-08-01 | Lion Copolymer Geismar, Llc | Homogeneous polymerization catalyst for alpha olefins |
US9574030B1 (en) | 2012-11-20 | 2017-02-21 | Lion Copolymer Geismar, Llc | Process for the polymerization of alpha olefins and non-conjugated dienes using a toluene free homogenous co-catalyst system with metallocene pro-catalysts |
US20140142261A1 (en) * | 2012-11-20 | 2014-05-22 | Lion Copolymer, Inc | Process for the polymerization of alpha olefins and non-conjugated dienes using a toluene free homogenous co-catalyst system with metallocene pro-catalysts |
US9718897B1 (en) | 2012-11-20 | 2017-08-01 | Lion Copolymer Geismar, Llc | Process for the polymerization or copolymerization of an alpha olefin |
US9982070B2 (en) | 2015-01-12 | 2018-05-29 | Carnegie Mellon University | Aqueous ATRP in the presence of an activator regenerator |
US11174325B2 (en) | 2017-01-12 | 2021-11-16 | Carnegie Mellon University | Surfactant assisted formation of a catalyst complex for emulsion atom transfer radical polymerization processes |
Family Cites Families (10)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
JPS56142216A (en) | 1980-02-19 | 1981-11-06 | Daicel Chem Ind Ltd | Optical resolution of racemate by optically active polymer |
ATE154367T1 (de) | 1991-03-27 | 1997-06-15 | Idemitsu Kosan Co | Verfahren zur herstellung eines styrolpolymerisats |
JPH04366109A (ja) * | 1991-06-12 | 1992-12-18 | Idemitsu Kosan Co Ltd | スチレン系重合体の製造方法及びその触媒 |
DE69433089T2 (de) * | 1993-06-24 | 2004-06-17 | American National Can Co., Chicago | Mehrschichtige strukturen aus single-site katalysierten polymeren |
CN1141635A (zh) | 1994-01-18 | 1997-01-29 | 陶氏化学公司 | 低氧化态金属钛配合物的制备方法 |
US5543480A (en) * | 1994-06-28 | 1996-08-06 | The Dow Chemical Company | Polymerization process using diene containing catalysts |
JP3511321B2 (ja) * | 1994-11-29 | 2004-03-29 | 出光興産株式会社 | スチレン系重合体の分子量制御方法 |
US5856256A (en) * | 1996-02-20 | 1999-01-05 | Northwestern University | Organo-Lewis acid as cocatalyst for cationic homogeneous Ziegler-Natta olefin polymerizations |
EP0927201B1 (de) | 1996-09-06 | 2004-04-14 | Hyundai Petrochemical Co., Ltd. | Katalysatorsystem für die (co)polymerisierung von olefinen und verfahren zur herstellung von olefin-(co)polymeren unter verwendung des katalysatorsystems |
US6670299B1 (en) * | 1999-07-03 | 2003-12-30 | Northwestern University | Cyclopentadienyl-containing low-valent early transition metal olefin polymerization catalysts |
-
2000
- 2000-06-30 US US09/608,855 patent/US6670299B1/en not_active Expired - Lifetime
- 2000-07-03 WO PCT/US2000/018336 patent/WO2001002445A1/en active IP Right Grant
- 2000-07-03 DE DE60023011T patent/DE60023011T2/de not_active Expired - Fee Related
- 2000-07-03 AT AT00945137T patent/ATE305945T1/de not_active IP Right Cessation
- 2000-07-03 AU AU59122/00A patent/AU5912200A/en not_active Abandoned
- 2000-07-03 EP EP00945137A patent/EP1200486B1/de not_active Expired - Lifetime
-
2002
- 2002-07-18 US US10/198,241 patent/US6544922B1/en not_active Expired - Fee Related
- 2002-12-19 US US10/324,734 patent/US6747112B2/en not_active Expired - Fee Related
- 2002-12-19 US US10/325,330 patent/US20030134995A1/en not_active Abandoned
-
2004
- 2004-05-10 US US10/842,725 patent/US7119158B2/en not_active Expired - Fee Related
-
2005
- 2005-05-04 US US11/121,775 patent/US7160965B2/en not_active Expired - Fee Related
Also Published As
Publication number | Publication date |
---|---|
US20030134994A1 (en) | 2003-07-17 |
EP1200486A1 (de) | 2002-05-02 |
ATE305945T1 (de) | 2005-10-15 |
US20030134995A1 (en) | 2003-07-17 |
US7119158B2 (en) | 2006-10-10 |
AU5912200A (en) | 2001-01-22 |
WO2001002445A1 (en) | 2001-01-11 |
US6670299B1 (en) | 2003-12-30 |
EP1200486B1 (de) | 2005-10-05 |
US20050209417A1 (en) | 2005-09-22 |
US7160965B2 (en) | 2007-01-09 |
US6544922B1 (en) | 2003-04-08 |
US20040225089A1 (en) | 2004-11-11 |
DE60023011T2 (de) | 2006-07-13 |
US6747112B2 (en) | 2004-06-08 |
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Legal Events
Date | Code | Title | Description |
---|---|---|---|
8364 | No opposition during term of opposition | ||
8339 | Ceased/non-payment of the annual fee |