DE60236653D1 - Verfahren zur herstellung von geträgerten übergangsmetallpolymerisationskatalysatoren und daraus gebildete zusammensetzungen - Google Patents

Verfahren zur herstellung von geträgerten übergangsmetallpolymerisationskatalysatoren und daraus gebildete zusammensetzungen

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Publication number
DE60236653D1
DE60236653D1 DE60236653T DE60236653T DE60236653D1 DE 60236653 D1 DE60236653 D1 DE 60236653D1 DE 60236653 T DE60236653 T DE 60236653T DE 60236653 T DE60236653 T DE 60236653T DE 60236653 D1 DE60236653 D1 DE 60236653D1
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DE
Germany
Prior art keywords
transition metal
polymerization catalysts
compositions made
supported transition
metal polymerization
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Expired - Lifetime
Application number
DE60236653T
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English (en)
Inventor
Keng-Yu Shih
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
WR Grace and Co Conn
WR Grace and Co
Original Assignee
WR Grace and Co Conn
WR Grace and Co
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Publication date
Application filed by WR Grace and Co Conn, WR Grace and Co filed Critical WR Grace and Co Conn
Application granted granted Critical
Publication of DE60236653D1 publication Critical patent/DE60236653D1/de
Anticipated expiration legal-status Critical
Expired - Lifetime legal-status Critical Current

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    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F4/00—Polymerisation catalysts
    • C08F4/02—Carriers therefor
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F110/00—Homopolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond
    • C08F110/02—Ethene
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F10/00—Homopolymers and copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond
DE60236653T 2001-04-30 2002-04-10 Verfahren zur herstellung von geträgerten übergangsmetallpolymerisationskatalysatoren und daraus gebildete zusammensetzungen Expired - Lifetime DE60236653D1 (de)

Applications Claiming Priority (2)

Application Number Priority Date Filing Date Title
US28760701P 2001-04-30 2001-04-30
PCT/US2002/011369 WO2002088198A1 (en) 2001-04-30 2002-04-10 Method of making supported transition metal polymerization catalysts and compositions formed therefrom

Publications (1)

Publication Number Publication Date
DE60236653D1 true DE60236653D1 (de) 2010-07-22

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Family Applications (1)

Application Number Title Priority Date Filing Date
DE60236653T Expired - Lifetime DE60236653D1 (de) 2001-04-30 2002-04-10 Verfahren zur herstellung von geträgerten übergangsmetallpolymerisationskatalysatoren und daraus gebildete zusammensetzungen

Country Status (6)

Country Link
US (1) US6927261B2 (de)
EP (1) EP1401889B1 (de)
KR (1) KR100540049B1 (de)
AT (1) ATE470682T1 (de)
DE (1) DE60236653D1 (de)
WO (1) WO2002088198A1 (de)

Families Citing this family (26)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US6656866B2 (en) * 2000-12-04 2003-12-02 Univation Technologies, Llc Catalyst preparation method
PT1401890E (pt) 2001-04-30 2011-03-11 Grace W R & Co Catalisadores de polimerização de metal de transiçãoaglomerado- suporte de crómio e processos para utilização dos mesmos
US20040118035A1 (en) * 2001-05-15 2004-06-24 Saleem Al-Ahmad Olefin polymerization catalyst and process and polymer, polymer derivatives, lubricants and fuels thereof
DE102004006113A1 (de) * 2004-02-06 2005-08-25 Basell Polyolefine Gmbh Verfahren zur Herstellung von Trägern für Katalysatoren
DE102004006104A1 (de) * 2004-02-06 2005-08-25 Basell Polyolefine Gmbh Verfahren zur Herstellung von geträgerten Katalysatoren für die Polymerisation
EP1749842A1 (de) * 2005-08-03 2007-02-07 Total Petrochemicals Research Feluy Übergangsnetalkomplex geträgert auf einem Fluorierten aktivierten Träger
EP2045014B8 (de) * 2006-07-25 2014-02-26 National University Corporation Hokkaido University Polymergestützter metalkomplexkatalysator
EP1925623A1 (de) * 2006-11-24 2008-05-28 Total Petrochemicals Research Feluy Polymerisation von Alpha-Olefinen mit Pyrrol-Iminophenolkomplexen
KR101338042B1 (ko) * 2011-11-15 2013-12-09 한국과학기술연구원 다공성 지지체에 분산된 금속 나노 입자, 그 제조 방법 및 이를 이용한 촉매
US10618988B2 (en) 2015-08-31 2020-04-14 Exxonmobil Chemical Patents Inc. Branched propylene polymers produced via use of vinyl transfer agents and processes for production thereof
CN107921424A (zh) 2015-08-31 2018-04-17 埃克森美孚化学专利公司 粘土上的具有悬垂烯烃的烷基铝
US11041029B2 (en) 2015-08-31 2021-06-22 Exxonmobil Chemical Patents Inc. Aluminum alkyls with pendant olefins for polyolefin reactions
US9982067B2 (en) 2015-09-24 2018-05-29 Exxonmobil Chemical Patents Inc. Polymerization process using pyridyldiamido compounds supported on organoaluminum treated layered silicate supports
US9994657B2 (en) 2015-10-02 2018-06-12 Exxonmobil Chemical Patents Inc. Polymerization process using bis phenolate compounds supported on organoaluminum treated layered silicate supports
US9994658B2 (en) 2015-10-02 2018-06-12 Exxonmobil Chemical Patents Inc. Polymerization process using bis phenolate compounds supported on organoaluminum treated layered silicate supports
US9975973B2 (en) 2015-10-02 2018-05-22 Exxonmobil Chemical Patents Inc. Asymmetric fluorenyl-substituted salan catalysts
US9982076B2 (en) 2015-10-02 2018-05-29 Exxonmobil Chemical Patents Inc. Supported bis phenolate transition metals complexes, production and use thereof
US10414887B2 (en) 2015-10-02 2019-09-17 Exxonmobil Chemical Patents Inc. Supported catalyst systems and methods of using same
US10000593B2 (en) 2015-10-02 2018-06-19 Exxonmobil Chemical Patents Inc. Supported Salan catalysts
US10562987B2 (en) 2016-06-30 2020-02-18 Exxonmobil Chemical Patents Inc. Polymers produced via use of quinolinyldiamido transition metal complexes and vinyl transfer agents
US20200369803A1 (en) 2016-12-29 2020-11-26 Chevron Phillips Chemical Company Lp Methods of Preparing a Catalyst
US10654953B2 (en) 2016-12-29 2020-05-19 Chevron Phillips Chemical Company Lp Methods of preparing a catalyst
US11267914B2 (en) 2016-12-29 2022-03-08 Chevron Phillips Chemical Company Lp Methods of preparing a catalyst
US10626200B2 (en) 2017-02-28 2020-04-21 Exxonmobil Chemical Patents Inc. Branched EPDM polymers produced via use of vinyl transfer agents and processes for production thereof
WO2018160278A1 (en) 2017-03-01 2018-09-07 Exxonmobil Chemical Patents Inc. Branched ethylene copolymers produced via use of vinyl transfer agents and processes for production thereof
WO2023239560A1 (en) 2022-06-09 2023-12-14 Formosa Plastics Corporaton, U.S.A. Clay composite support-activators and catalyst compositions

Family Cites Families (71)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
IT513721A (de) 1953-01-27 1900-01-01
US4176090A (en) 1975-11-18 1979-11-27 W. R. Grace & Co. Pillared interlayered clay materials useful as catalysts and sorbents
SE423721B (sv) 1976-03-17 1982-05-24 Stora Kopparbergs Bergslags Ab Sett for framstellning av rastal genom direktreduktion
IL50548A (en) 1976-09-23 1979-10-31 Yissum Res Dev Co Process for preparation of molecular sieves
US4238364A (en) 1979-04-03 1980-12-09 University Of Utah Class of cracking catalysts acidic forms of cross-linked smectities
US4271043A (en) 1979-09-04 1981-06-02 W. R. Grace & Co. Pillared interlayered clay products
US4248739A (en) 1979-09-04 1981-02-03 W. R. Grace & Co. Stabilized pillared interlayered clays
US4375406A (en) 1981-01-21 1983-03-01 Chevron Research Company Fibrous clay compositions containing precalcined oxides
US4367163A (en) 1981-04-15 1983-01-04 Research Corporation Silica-clay complexes
US4629712A (en) 1984-08-17 1986-12-16 Michigan State University Delaminated clay materials
US4637992A (en) 1984-12-17 1987-01-20 Shell Oil Company Intercalated clay compositions
US4859648A (en) 1984-12-28 1989-08-22 Mobil Oil Corporation Layered metal chalcogenides containing interspathic polymeric chalcogenides
US4761391A (en) 1986-06-30 1988-08-02 Union Oil Company Of California Delaminated clays and their use in hydrocarbon conversion processes
US5153157A (en) 1987-01-30 1992-10-06 Exxon Chemical Patents Inc. Catalyst system of enhanced productivity
US5241025A (en) 1987-01-30 1993-08-31 Exxon Chemical Patents Inc. Catalyst system of enhanced productivity
US4995964A (en) 1987-03-05 1991-02-26 Uop Midbarrel hydrocracking process employing rare earth pillared clays
US5225500A (en) 1988-07-15 1993-07-06 Fina Technology, Inc. Process and catalyst for producing syndiotactic polyolefins
US5243002A (en) 1988-07-15 1993-09-07 Fina Technology, Inc. Process and catalyst for producing syndiotactic polymers
JPH0278663A (ja) 1988-09-14 1990-03-19 N O K Sogo Gijutsu Kenkyusho:Kk ２，６―エチリデンニトリロフェニルピリジン、その製造法ならびに金属塩錯体
US4981825A (en) 1989-09-12 1991-01-01 Board Of Trustees Operating Michigan State University Dried metal oxide and clay particle compositions and method for the preparation thereof
US5064802A (en) 1989-09-14 1991-11-12 The Dow Chemical Company Metal complex compounds
ATE137247T1 (de) 1989-10-30 1996-05-15 Fina Technology Addition von alkylaluminium zum verbessern eines metallocenkatalysators
DE69018376T3 (de) 1989-10-30 2002-05-16 Fina Technology Herstellung von Metallocenkatalysatoren für Olefinpolymerisation.
EP0670334A3 (de) 1990-06-22 1995-09-13 Exxon Chemical Patents Inc. Aluminiumfreie Monocyclopentadienyl-Metallocenkatalysatoren für Olefinpolymerisation
JP2545006B2 (ja) 1990-07-03 1996-10-16 ザ ダウ ケミカル カンパニー 付加重合触媒
US5128291A (en) 1990-12-11 1992-07-07 Wax Michael J Porous titania or zirconia spheres
US5250277A (en) 1991-01-11 1993-10-05 Mobil Oil Corp. Crystalline oxide material
TW218884B (de) 1991-05-01 1994-01-11 Mitsubishi Kakoki Kk
US5399636A (en) 1993-06-11 1995-03-21 Phillips Petroleum Company Metallocenes and processes therefor and therewith
CA2124187C (en) 1991-11-25 2001-08-07 Howard William Turner Polyonic transition metal catalyst composition
JPH05170429A (ja) 1991-12-18 1993-07-09 Mitsubishi Materials Corp 粘土架橋多孔体及びその製造方法
US5238892A (en) 1992-06-15 1993-08-24 Exxon Chemical Patents Inc. Supported catalyst for 1-olefin(s) (co)polymerization
US5362825A (en) 1992-07-13 1994-11-08 Phillips Petroleum Company Catalysts for polymerizing olefins and methods
US5395808A (en) 1992-12-21 1995-03-07 W. R. Grace & Co.-Conn. Inorganic supports for bioremediation
US5403809A (en) 1992-12-21 1995-04-04 W. R. Grace & Co.-Conn. Composite inorganic supports containing carbon for bioremediation
US5403799A (en) 1992-12-21 1995-04-04 W. R. Grace & Co.-Conn. Process upset-resistant inorganic supports for bioremediation
EP0816386B1 (de) 1993-03-23 1998-12-16 Asahi Kasei Kogyo Kabushiki Kaisha Olefinpolymerisationskatalysator mit mehrzähnigem Ligand
ATE147748T1 (de) 1993-06-24 1997-02-15 Dow Chemical Co Titan-und zirkoniumkomplexe und diese enthaltende polymerisationskatalysatoren
DE69412047T2 (de) 1993-12-17 1999-04-15 Tosoh Corp Olefinpolymerisationkatalysator und Verfahren zur Olefinpolymerisation
DE69525679T2 (de) 1994-05-18 2002-11-07 Mitsubishi Chem Corp Katalysator zur Polymerisation eines Olefins und Verfahren zum Polymerisieren des Olefins
US5541272A (en) 1994-06-03 1996-07-30 Phillips Petroleum Company High activity ethylene selective metallocenes
US5643847A (en) 1994-08-03 1997-07-01 Exxon Chemical Patents Inc. Supported ionic catalyst composition
US5661097A (en) 1994-08-12 1997-08-26 The Dow Chemical Company Supported olefin polymerization catalyst
US5714424A (en) 1995-01-09 1998-02-03 W. R. Grace & Co.-Conn. Multi-component polyolefin catalysts
JP3847783B2 (ja) 1995-01-24 2006-11-22 イー・アイ・デュポン・ドゥ・ヌムール・アンド・カンパニー オレフィンの重合方法
US5880241A (en) 1995-01-24 1999-03-09 E. I. Du Pont De Nemours And Company Olefin polymers
DE69611554T2 (de) 1995-02-20 2001-07-05 Tosoh Corp Katalysator für die Polymerisation von Olefinen und Verfahren zur Herstellung von Olefinpolymerisaten
HUP9902066A3 (en) 1995-11-27 1999-11-29 Grace W R & Co Supported catalyst containing tethered cation forming activator
DE69701909T2 (de) 1996-02-23 2000-08-17 Tosoh Corp Olefinpolymerisationskatalysator auf Basis von organometallischen Komplexen und Verfahren zur Herstellung von Polyolefinen mit diesem Katalysator
DE69717441T2 (de) * 1996-06-21 2003-10-02 Grace W R & Co Zerbrechlicher sprühgetrockneter agglomeratträger, verfahren zur herstellung solcher träger und darauf angebrachte olefinpolymerisationskatalysatoren
IL129929A0 (en) 1996-12-17 2000-02-29 Du Pont Polymerization of ethylene with specific iron or cobalt complexes novel pyridinebis (imines) and novel complexes of pyridinebis(imines) with iron and cobalt
US6110858A (en) 1996-12-18 2000-08-29 Tosoh Corporation Olefin polymerization catalysts and process for producing olefin polymers
US5906955A (en) 1996-12-20 1999-05-25 Tosoh Corporation Catalyst for polymerization of an olefin, and method for producing an olefin polymer
KR20000070067A (ko) 1997-01-13 2000-11-25 메리 이. 보울러 프로필렌의 중합 방법
US5807800A (en) 1997-02-11 1998-09-15 Fina Technology, Inc. Process for producing stereospecific polymers
US6048817A (en) 1997-04-25 2000-04-11 Mitsubishi Chemical Corporation Polymerization of olefins
JP3458656B2 (ja) 1997-05-27 2003-10-20 東ソー株式会社 オレフィン重合用触媒およびオレフィン重合体の製造方法
JPH10338516A (ja) 1997-06-04 1998-12-22 Nikki Kagaku Kk 粘土鉱物にインターカレートした金属酸化物の製造方法
JPH1140664A (ja) 1997-07-17 1999-02-12 Mitsubishi Electric Corp 半導体装置の製造方法
US6174976B1 (en) 1998-02-24 2001-01-16 Eastman Chemical Company Neutral nickel complexes for olefin polymerization
AU2738599A (en) 1998-03-12 1999-09-27 Bp Chemicals Limited Polymerisation catalysts
ID27209A (id) 1998-03-12 2001-03-08 Bp Chem Int Ltd Katalis-katalis polimerisasi
DZ2737A1 (fr) 1998-03-12 2003-09-01 Bp Chem Int Ltd Catalyseurs de polymérisation.
JPH11292912A (ja) 1998-04-08 1999-10-26 Idemitsu Petrochem Co Ltd オレフィン重合用触媒及びポリオレフィンの製造方法
JP2000086672A (ja) 1998-09-14 2000-03-28 Idemitsu Petrochem Co Ltd アルミノキサン、オレフィン類重合用触媒及びオレフィン系重合体の製造方法
US6184171B1 (en) 1998-10-05 2001-02-06 W.R. Grace & Co. -Conn Supported bidentate and tridentate catalyst compositions and olefin polymerization using same
WO2001030864A2 (en) 1999-10-07 2001-05-03 The Dow Chemical Company Nanocomposite polymers
US6399535B1 (en) * 1999-11-01 2002-06-04 W. R. Grace & Co.-Conn. Coordination catalyst systems employing agglomerated metal oxide/clay support-activator and method of their preparation
US6559090B1 (en) * 1999-11-01 2003-05-06 W. R. Grace & Co.-Conn. Metallocene and constrained geometry catalyst systems employing agglomerated metal oxide/clay support-activator and method of their preparation
WO2001042320A1 (en) * 1999-12-10 2001-06-14 The Dow Chemical Company Treated clay compositions and olefin polymerization catalysts comprising the same
US6632894B1 (en) 1999-12-30 2003-10-14 Phillips Petroleum Company Organometal catalyst compositions

Also Published As

Publication number Publication date
EP1401889A1 (de) 2004-03-31
WO2002088198A1 (en) 2002-11-07
KR20040089445A (ko) 2004-10-21
KR100540049B1 (ko) 2006-01-20
US20030203808A1 (en) 2003-10-30
EP1401889B1 (de) 2010-06-09
US6927261B2 (en) 2005-08-09
ATE470682T1 (de) 2010-06-15

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