DE60304342D1 - Verfahren zur verabreichung von katalysatoren für popylenpolymerisation - Google Patents

Verfahren zur verabreichung von katalysatoren für popylenpolymerisation

Info

Publication number
DE60304342D1
DE60304342D1 DE60304342T DE60304342T DE60304342D1 DE 60304342 D1 DE60304342 D1 DE 60304342D1 DE 60304342 T DE60304342 T DE 60304342T DE 60304342 T DE60304342 T DE 60304342T DE 60304342 D1 DE60304342 D1 DE 60304342D1
Authority
DE
Germany
Prior art keywords
polymerization
catalyst
popylene
catalysts
administration
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Revoked
Application number
DE60304342T
Other languages
English (en)
Other versions
DE60304342T2 (de
Inventor
C Smith
C Vizzini
A Powell
J Burkhardt
N Speca
Shiaw Ju
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
ExxonMobil Chemical Patents Inc
Original Assignee
ExxonMobil Chemical Patents Inc
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Family has litigation
First worldwide family litigation filed litigation Critical https://patents.darts-ip.com/?family=32093991&utm_source=google_patent&utm_medium=platform_link&utm_campaign=public_patent_search&patent=DE60304342(D1) "Global patent litigation dataset” by Darts-ip is licensed under a Creative Commons Attribution 4.0 International License.
Application filed by ExxonMobil Chemical Patents Inc filed Critical ExxonMobil Chemical Patents Inc
Publication of DE60304342D1 publication Critical patent/DE60304342D1/de
Application granted granted Critical
Publication of DE60304342T2 publication Critical patent/DE60304342T2/de
Anticipated expiration legal-status Critical
Revoked legal-status Critical Current

Links

Classifications

    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08FMACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F110/00Homopolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond
    • C08F110/04Monomers containing three or four carbon atoms
    • C08F110/06Propene
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B01PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01JCHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J8/00Chemical or physical processes in general, conducted in the presence of fluids and solid particles; Apparatus for such processes
    • B01J8/0015Feeding of the particles in the reactor; Evacuation of the particles out of the reactor
    • B01J8/0035Periodical feeding or evacuation
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B01PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01JCHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J8/00Chemical or physical processes in general, conducted in the presence of fluids and solid particles; Apparatus for such processes
    • B01J8/18Chemical or physical processes in general, conducted in the presence of fluids and solid particles; Apparatus for such processes with fluidised particles
    • B01J8/1818Feeding of the fluidising gas
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B01PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01JCHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J8/00Chemical or physical processes in general, conducted in the presence of fluids and solid particles; Apparatus for such processes
    • B01J8/18Chemical or physical processes in general, conducted in the presence of fluids and solid particles; Apparatus for such processes with fluidised particles
    • B01J8/1872Details of the fluidised bed reactor
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B01PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01JCHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J8/00Chemical or physical processes in general, conducted in the presence of fluids and solid particles; Apparatus for such processes
    • B01J8/18Chemical or physical processes in general, conducted in the presence of fluids and solid particles; Apparatus for such processes with fluidised particles
    • B01J8/20Chemical or physical processes in general, conducted in the presence of fluids and solid particles; Apparatus for such processes with fluidised particles with liquid as a fluidising medium
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08FMACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F10/00Homopolymers and copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08FMACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F10/00Homopolymers and copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond
    • C08F10/04Monomers containing three or four carbon atoms
    • C08F10/06Propene
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B01PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01JCHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J2208/00Processes carried out in the presence of solid particles; Reactors therefor
    • B01J2208/00008Controlling the process
    • B01J2208/00017Controlling the temperature
    • B01J2208/00106Controlling the temperature by indirect heat exchange
    • B01J2208/00265Part of all of the reactants being heated or cooled outside the reactor while recycling
    • B01J2208/00292Part of all of the reactants being heated or cooled outside the reactor while recycling involving reactant solids
    • B01J2208/003Part of all of the reactants being heated or cooled outside the reactor while recycling involving reactant solids involving reactant slurries
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B01PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01JCHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J2208/00Processes carried out in the presence of solid particles; Reactors therefor
    • B01J2208/00743Feeding or discharging of solids
    • B01J2208/00752Feeding
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08FMACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F4/00Polymerisation catalysts
    • C08F4/42Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors
    • C08F4/44Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides
    • C08F4/60Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides together with refractory metals, iron group metals, platinum group metals, manganese, rhenium technetium or compounds thereof
    • C08F4/62Refractory metals or compounds thereof
    • C08F4/64Titanium, zirconium, hafnium or compounds thereof
    • C08F4/659Component covered by group C08F4/64 containing a transition metal-carbon bond
    • C08F4/6592Component covered by group C08F4/64 containing a transition metal-carbon bond containing at least one cyclopentadienyl ring, condensed or not, e.g. an indenyl or a fluorenyl ring
    • C08F4/65922Component covered by group C08F4/64 containing a transition metal-carbon bond containing at least one cyclopentadienyl ring, condensed or not, e.g. an indenyl or a fluorenyl ring containing at least two cyclopentadienyl rings, fused or not
    • C08F4/65927Component covered by group C08F4/64 containing a transition metal-carbon bond containing at least one cyclopentadienyl ring, condensed or not, e.g. an indenyl or a fluorenyl ring containing at least two cyclopentadienyl rings, fused or not two cyclopentadienyl rings being mutually bridged
    • YGENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y10TECHNICAL SUBJECTS COVERED BY FORMER USPC
    • Y10STECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y10S526/00Synthetic resins or natural rubbers -- part of the class 520 series
    • Y10S526/919Catalyst injection technique in addition polymerization processes
    • YGENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y10TECHNICAL SUBJECTS COVERED BY FORMER USPC
    • Y10STECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y10S526/00Synthetic resins or natural rubbers -- part of the class 520 series
    • Y10S526/943Polymerization with metallocene catalysts
DE60304342T 2002-10-09 2003-09-22 Verfahren zur verabreichung von katalysatoren für popylenpolymerisation Revoked DE60304342T2 (de)

Applications Claiming Priority (3)

Application Number Priority Date Filing Date Title
US41725402P 2002-10-09 2002-10-09
US417254P 2002-10-09
PCT/US2003/029584 WO2004033506A1 (en) 2002-10-09 2003-09-22 Methods of delivering catalyst systems for propylene polymerization

Publications (2)

Publication Number Publication Date
DE60304342D1 true DE60304342D1 (de) 2006-05-18
DE60304342T2 DE60304342T2 (de) 2006-11-09

Family

ID=32093991

Family Applications (1)

Application Number Title Priority Date Filing Date
DE60304342T Revoked DE60304342T2 (de) 2002-10-09 2003-09-22 Verfahren zur verabreichung von katalysatoren für popylenpolymerisation

Country Status (6)

Country Link
US (2) US7232868B2 (de)
EP (1) EP1556422B1 (de)
AT (1) ATE321791T1 (de)
AU (1) AU2003270801A1 (de)
DE (1) DE60304342T2 (de)
WO (1) WO2004033506A1 (de)

Families Citing this family (4)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CA2749835C (en) 2011-08-23 2018-08-21 Nova Chemicals Corporation Feeding highly active phosphinimine catalysts to a gas phase reactor
DE102011112862A1 (de) 2011-09-07 2013-03-07 Volkswagen Aktiengesellschaft Brennkraftmaschine, Maskierungsmodul und Strömungskörper
CN109563189B (zh) * 2016-08-10 2021-06-18 埃克森美孚化学专利公司 向溶液聚合反应器供应固体催化剂的方法
US10544246B2 (en) 2016-08-10 2020-01-28 Exxonmobil Chemical Patents Inc. Methods for supplying solid catalysts to a solution polymerization reactor

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US2508744A (en) * 1947-12-30 1950-05-23 Standard Oil Dev Co Propylene polymerization
US2852501A (en) * 1954-10-05 1958-09-16 Monsanto Chemicals Polymerization of ethylene
NL121075C (de) * 1955-11-08
US2917465A (en) * 1956-04-27 1959-12-15 Phillips Petroleum Co Polymerization catalyst feed control
US2956995A (en) * 1956-06-28 1960-10-18 Nat Distillers Chem Corp Continuous process for the production of aliphatic monoolefin polymers
US3004086A (en) * 1956-08-27 1961-10-10 Phillips Petroleum Co Method and apparatus for providing a solids slurry
US3257363A (en) * 1961-05-22 1966-06-21 Phillips Petroleum Co Control of the composition of a reaction mixture
AT255852B (de) 1963-01-11 1967-07-25 Julius Dopslaff Einstellventil
US3440238A (en) * 1965-09-08 1969-04-22 Mobil Oil Corp Polymerization of olefins in a gravitating bed
US3687920A (en) * 1971-01-25 1972-08-29 Union Carbide Corp Polymerization of olefins with silane modified catalyst system
US3726845A (en) * 1971-03-22 1973-04-10 Exxon Research Engineering Co Supplying catalyst to a reaction zone
US3779712A (en) * 1971-11-26 1973-12-18 Union Carbide Corp Particulate solids injector apparatus
US4011383A (en) * 1974-05-20 1977-03-08 E. I. Du Pont De Nemours And Company Tetra(neophyl) zirconium and its use in process for the polymerization of olefins
US4123601A (en) * 1977-04-20 1978-10-31 Gulf Oil Corporation Catalyst feeding apparatus
US4232138A (en) * 1977-12-19 1980-11-04 Standard Oil Company (Indiana) Olefin polymerization catalyst
US4268017A (en) * 1979-12-28 1981-05-19 Exxon Research & Engineering Co. Reactor with extractable feed nozzle
US5326855A (en) * 1983-10-06 1994-07-05 Henry Kahn Process for the manufacture of elastomers in particulate form
US4610574A (en) * 1984-05-30 1986-09-09 Amoco Corporation Catalyst feeding system
US4585644A (en) * 1984-06-04 1986-04-29 Phillips Petroleum Company Changing oil tubes in a carbon black reactor
WO1989000584A1 (en) * 1987-07-10 1989-01-26 Quantum Chemical Corporation Propylene polymerization catalyst and method
GB9103527D0 (en) * 1991-02-20 1991-04-10 Exxon Chemical Patents Inc Hp catalyst killer
US5317036A (en) * 1992-10-16 1994-05-31 Union Carbide Chemicals & Plastics Technology Corporation Gas phase polymerization reactions utilizing soluble unsupported catalysts
SG49620A1 (en) 1992-11-30 1998-06-15 Sumitomo Chemical Co Powder supply
US5859159A (en) * 1992-12-17 1999-01-12 Exxon Chemical Patents Inc. Dilute process for the polymerization of non-ethylene α-olefin homopolymers and copolymers using metallocene catalyst systems
US5643846A (en) 1993-04-28 1997-07-01 Fina Technology, Inc. Process for a isotactic/syndiotactic polymer blend in a single reactor
NZ264288A (en) 1993-09-30 1996-08-27 Boc Group Inc Preparation of ethylene and propylene polymers from mixtures of ethylene/ethane and propylene/propane, respectively, with either pre-polymerisation or post-polmerisation adsorption of the unsaturated component and recycling of at least part of the unreacted monomer
US6239058B1 (en) * 1995-07-18 2001-05-29 Fina Technology, Inc. Process for activating a metallocene catalyst supported on silica
FR2741549B1 (fr) 1995-11-29 1998-01-02 Bp Chemicals Snc Procede d'introduction d'un catalyseur dans un reacteur de polymerisation d'olefine en phase gazeuse
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Also Published As

Publication number Publication date
EP1556422B1 (de) 2006-03-29
AU2003270801A1 (en) 2004-05-04
EP1556422A1 (de) 2005-07-27
US20060257294A1 (en) 2006-11-16
DE60304342T2 (de) 2006-11-09
US20040097667A1 (en) 2004-05-20
US7494626B2 (en) 2009-02-24
US7232868B2 (en) 2007-06-19
ATE321791T1 (de) 2006-04-15
WO2004033506A1 (en) 2004-04-22

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Legal Events

Date Code Title Description
8363 Opposition against the patent
8331 Complete revocation