DE69216117T2 - Verfahren zur Polymerisation und Kopolymerisation von Olefine - Google Patents
Verfahren zur Polymerisation und Kopolymerisation von OlefineInfo
- Publication number
- DE69216117T2 DE69216117T2 DE69216117T DE69216117T DE69216117T2 DE 69216117 T2 DE69216117 T2 DE 69216117T2 DE 69216117 T DE69216117 T DE 69216117T DE 69216117 T DE69216117 T DE 69216117T DE 69216117 T2 DE69216117 T2 DE 69216117T2
- Authority
- DE
- Germany
- Prior art keywords
- polymerisation
- mol
- catalyst system
- contg
- pref
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Revoked
Links
Classifications
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
- C08F110/00—Homopolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond
- C08F110/04—Monomers containing three or four carbon atoms
- C08F110/06—Propene
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
- C08F297/00—Macromolecular compounds obtained by successively polymerising different monomer systems using a catalyst of the ionic or coordination type without deactivating the intermediate polymer
- C08F297/06—Macromolecular compounds obtained by successively polymerising different monomer systems using a catalyst of the ionic or coordination type without deactivating the intermediate polymer using a catalyst of the coordination type
- C08F297/08—Macromolecular compounds obtained by successively polymerising different monomer systems using a catalyst of the ionic or coordination type without deactivating the intermediate polymer using a catalyst of the coordination type polymerising mono-olefins
- C08F297/083—Macromolecular compounds obtained by successively polymerising different monomer systems using a catalyst of the ionic or coordination type without deactivating the intermediate polymer using a catalyst of the coordination type polymerising mono-olefins the monomers being ethylene or propylene
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
- C08F10/00—Homopolymers and copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond
- C08F10/04—Monomers containing three or four carbon atoms
- C08F10/06—Propene
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
- C08F210/00—Copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond
- C08F210/04—Monomers containing three or four carbon atoms
- C08F210/06—Propene
Landscapes
- Chemical & Material Sciences (AREA)
- Health & Medical Sciences (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Medicinal Chemistry (AREA)
- Polymers & Plastics (AREA)
- Organic Chemistry (AREA)
- Inorganic Chemistry (AREA)
- Transition And Organic Metals Composition Catalysts For Addition Polymerization (AREA)
- Addition Polymer Or Copolymer, Post-Treatments, Or Chemical Modifications (AREA)
- Polymerisation Methods In General (AREA)
- Dental Preparations (AREA)
- Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)
Applications Claiming Priority (2)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
US65044391A | 1991-02-04 | 1991-02-04 | |
US07/793,821 US5218052A (en) | 1991-02-04 | 1991-11-18 | Olefin polymerization and copolymerization process |
Publications (2)
Publication Number | Publication Date |
---|---|
DE69216117D1 DE69216117D1 (de) | 1997-02-06 |
DE69216117T2 true DE69216117T2 (de) | 1997-07-17 |
Family
ID=27095865
Family Applications (1)
Application Number | Title | Priority Date | Filing Date |
---|---|---|---|
DE69216117T Revoked DE69216117T2 (de) | 1991-02-04 | 1992-02-03 | Verfahren zur Polymerisation und Kopolymerisation von Olefine |
Country Status (9)
Country | Link |
---|---|
US (1) | US5218052A (de) |
EP (2) | EP0736552A3 (de) |
JP (1) | JPH05105722A (de) |
KR (1) | KR100263263B1 (de) |
AT (1) | ATE146806T1 (de) |
CA (1) | CA2059838C (de) |
CZ (1) | CZ287574B6 (de) |
DE (1) | DE69216117T2 (de) |
SK (1) | SK280948B6 (de) |
Families Citing this family (67)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
IT1260497B (it) * | 1992-05-29 | 1996-04-09 | Himont Inc | Polimeri cristallini del propilene aventi migliorata processabilita' allo stato e processo per la loro preparazione |
US7074871B2 (en) * | 1992-05-29 | 2006-07-11 | Basell Poliolefine Italia S.R.L. | Crystalline polymers of propylene having improved processability in the molten state and process for their preparation |
TW300235B (de) † | 1992-12-04 | 1997-03-11 | Mitsui Petroleum Chemicals Ind | |
EP0841370B1 (de) * | 1993-01-11 | 2003-05-02 | Mitsui Chemicals, Inc. | Zusammensetzung von Propylen-Polymeren |
JPH07173214A (ja) * | 1993-10-27 | 1995-07-11 | Nippon Oil Co Ltd | オレフィン類重合用触媒成分 |
US5409992A (en) * | 1994-02-28 | 1995-04-25 | Himont Incorporated | Calenderable blends containing broad molecular weight distribution propylene polymer material |
WO1996002381A1 (fr) * | 1994-07-15 | 1996-02-01 | Idemitsu Petrochemical Co., Ltd. | Resine de polypropylene tres rigide et produit d'extrusion-soufflage obtenu a partir de celle-ci |
KR100341040B1 (ko) * | 1994-08-18 | 2002-11-23 | 칫소가부시키가이샤 | 고강성프로필렌-에틸렌블록공중합체조성물및이의제조방법 |
FI944761A0 (fi) * | 1994-10-11 | 1994-10-11 | Borealis Holding As | Ny polypropylenkomposition med vid molekylvikt distribution |
AU700153B2 (en) * | 1994-10-12 | 1998-12-24 | Kimberly-Clark Worldwide, Inc. | Melt-extrudable thermoplastic polypropylene composition and nonwoven web prepared therefrom |
JPH10510832A (ja) * | 1994-12-20 | 1998-10-20 | エンゲルハード・コーポレーシヨン | 芳香族ポリカルボン酸の改良精製方法 |
USH1722H (en) * | 1995-05-05 | 1998-04-07 | Goode; Mark Gregory | Process for producing polypropylene impact block copolymers |
WO1997011775A2 (de) * | 1995-09-28 | 1997-04-03 | Targor Gmbh | Geträgertes katalysatorsystem, verfahren zu seiner herstellung und seine verwendung zur polymerisation von olefinen |
US5738745A (en) * | 1995-11-27 | 1998-04-14 | Kimberly-Clark Worldwide, Inc. | Method of improving the photostability of polypropylene compositions |
DE19606510A1 (de) * | 1996-02-22 | 1997-08-28 | Hoechst Ag | Hochmolekulares Polypropylen mit breiter Molmassenverteilung |
DE19621022B4 (de) † | 1996-05-24 | 2014-12-31 | Basell Polyolefine Gmbh | Hochmolekulares Ethylen/Propylen-Reaktorblend mit breiter Molmassenverteilung |
US6576306B2 (en) | 1996-09-04 | 2003-06-10 | Exxonmobil Chemical Patents Inc. | Propylene polymers for films |
US6583227B2 (en) | 1996-09-04 | 2003-06-24 | Exxonmobil Chemical Patents Inc. | Propylene polymers for films |
ES2174278T3 (es) * | 1996-09-04 | 2002-11-01 | Exxonmobil Chem Patents Inc | Polimeros de propileno mejorados para peliculas orientadas. |
US6100351A (en) * | 1997-01-07 | 2000-08-08 | Huntsman Polymers Corporation | Olefin polymerization process and products thereof |
US5948720A (en) * | 1997-01-07 | 1999-09-07 | Huntsman Polymers Corporation | Catalyst for the production of flexible polyolefin compositions, methods for making and using same, and products thereof |
US6057407A (en) * | 1997-01-08 | 2000-05-02 | Bp Amoco Corporation | High melt flow propylene polymer produced by gas-phase polymerization |
US6080818A (en) * | 1997-03-24 | 2000-06-27 | Huntsman Polymers Corporation | Polyolefin blends used for non-woven applications |
DE69820399T2 (de) * | 1997-05-30 | 2004-10-07 | Mitsui Chemicals Inc | Polypropylenharz-Zusammensetzung und spritzgegossener Gegenstand |
KR100503136B1 (ko) | 1997-08-05 | 2005-07-25 | 미쓰이 가가쿠 가부시키가이샤 | 폴리프로필렌 수지 조성물 및 그 용도 |
FI973816A0 (fi) | 1997-09-26 | 1997-09-26 | Borealis As | Polypropen med hoeg smaeltstyrka |
SG71878A1 (en) * | 1997-12-11 | 2000-04-18 | Sumitomo Chemical Co | Propylene-based polymer composition and foamed article thereof |
EP1078009B1 (de) | 1998-05-13 | 2004-06-16 | ExxonMobil Chemical Patents Inc. | Propylenhomopolymere und herstellungsverfahren |
US6306960B1 (en) | 1998-05-13 | 2001-10-23 | Exxonmobil Chemical Patents Inc. | Articles formed from foamable polypropylene polymer |
US6784269B2 (en) | 1998-05-13 | 2004-08-31 | Exxonmobil Chemical Patents Inc. | Polypropylene compositions methods of making the same |
US7354880B2 (en) * | 1998-07-10 | 2008-04-08 | Univation Technologies, Llc | Catalyst composition and methods for its preparation and use in a polymerization process |
KR100565151B1 (ko) | 1999-02-04 | 2006-03-30 | 미쓰이 가가쿠 가부시키가이샤 | 폴리프로필렌 블록 공중합체 수지 및 제조 방법 |
US6174930B1 (en) | 1999-04-16 | 2001-01-16 | Exxon Chemical Patents, Inc. | Foamable polypropylene polymer |
KR100546499B1 (ko) * | 1999-05-27 | 2006-01-26 | 삼성토탈 주식회사 | 에틸렌 중합 및 공중합용 촉매 |
KR100524293B1 (ko) | 1999-05-27 | 2005-10-26 | 삼성토탈 주식회사 | 에틸렌 중합 및 공중합용 촉매 |
JP2003514049A (ja) * | 1999-11-04 | 2003-04-15 | エクソンモービル・ケミカル・パテンツ・インク | 発泡性ポリプロピレンポリマー及びそれらの用途 |
KR100389476B1 (ko) * | 2000-11-09 | 2003-06-27 | 삼성종합화학주식회사 | 에틸렌 중합체 및 공중합체 제조방법 |
KR100389475B1 (ko) * | 2000-11-09 | 2003-06-27 | 삼성종합화학주식회사 | 에틸렌 중합 또는 공중합용 촉매의 제조 방법 |
KR100389962B1 (ko) * | 2000-11-10 | 2003-07-02 | 삼성종합화학주식회사 | 에틸렌 중합 또는 공중합용 촉매의 제조 방법 |
KR100421551B1 (ko) * | 2000-12-16 | 2004-03-09 | 삼성아토피나주식회사 | 올레핀 전중합 촉매 및 이를 이용한 올레핀 중합방법 |
US6566294B2 (en) | 2000-12-21 | 2003-05-20 | Exxonmobil Chemical Patents Inc. | Multi-donor catalyst system for the polymerization of olefins |
US20040072936A1 (en) * | 2000-12-22 | 2004-04-15 | Sok-Won Kim | Polyolefin resin composition |
US7067576B2 (en) * | 2000-12-22 | 2006-06-27 | Samsung Atofina, Co., Ltd. | Flame retardant polypropylene resin composition |
EP1362079B1 (de) * | 2000-12-22 | 2005-06-08 | Samsung General Chemicals Co., Ltd. | Polypropylenharzzusammensetzung mit verbesserter oberflächenhärte und kratzfestigkeit |
WO2002051882A1 (en) * | 2000-12-22 | 2002-07-04 | Samsung General Chemicals Co., Ltd. | Chelate catalyst for olefin polymerization and olefin polymerization method using the same |
KR100530794B1 (ko) * | 2001-06-21 | 2005-11-23 | 삼성토탈 주식회사 | 에틸렌 중합 및 공중합용 촉매 |
EP1461368B1 (de) * | 2002-01-03 | 2006-08-16 | Innovene USA LLC | Gasphasen olefin polymerisationsverfahren mit der benutzung von einem dual donor ziegler-natta katalysator |
CN100389148C (zh) * | 2002-09-06 | 2008-05-21 | 丁少忠 | 一种可生物降解的餐具及其制备方法 |
EP1668046B8 (de) | 2003-09-23 | 2021-04-21 | W.R. Grace & CO. - CONN. | Selbstlimitierende katalysatorzusammensetzung und propylenpolymerisationsverfahren |
KR101146472B1 (ko) * | 2003-09-23 | 2012-05-21 | 유니온 카바이드 케미칼즈 앤드 플라스틱스 테크날러지 엘엘씨 | 모노카르복실산 에스테르 내부 공여체를 갖는 자가-소멸촉매 조성물 및 프로필렌 중합 방법 |
EP1670833A1 (de) * | 2003-09-23 | 2006-06-21 | Union Carbide Chemicals & Plastics Technology Corporation | Katalysatorzusammensetzung mit gemischtem sca und propylenpolymerisationsverfahren |
EP1726603A1 (de) * | 2005-05-27 | 2006-11-29 | Borealis Technology Oy | Hochkristallines Polypropylen |
EP1726602A1 (de) * | 2005-05-27 | 2006-11-29 | Borealis Technology Oy | Hochkristallines Polypropylen |
RU2008103837A (ru) * | 2005-07-01 | 2009-08-10 | Базелль Полиолефин Италия С.Р.Л. (It) | Пропиленовые полимеры с широким молекулярно-массовым распределением |
CN101754996B (zh) * | 2007-07-18 | 2013-01-02 | 住友化学株式会社 | 热塑性弹性体组合物及复合成型体 |
US10647788B2 (en) * | 2007-08-24 | 2020-05-12 | W. R. Grace & Co-.Conn. | Self-limiting catalyst system with controlled aluminum to SCA ratio and method |
KR101787927B1 (ko) | 2007-12-21 | 2017-10-18 | 더블유.알. 그레이스 앤드 캄파니-콘. | 두자리 내부 공여체를 가진 자기-제한성 촉매 조성물 |
RU2487897C2 (ru) * | 2008-08-21 | 2013-07-20 | ДАУ ГЛОБАЛ ТЕКНОЛОДЖИЗ ЭлЭлСи | Ударопрочный пропиленовый сополимер с высокой скоростью течения расплава и способ его получения |
EP2315789B1 (de) * | 2008-08-21 | 2015-09-02 | W.R. Grace & CO. - CONN. | Katalysatorzusammensetzung mit gemischtem selektivitätssteuerungsmittel und polymerisationsverfahren unter verwendung davon |
CN102159638B (zh) * | 2008-10-01 | 2015-04-15 | 博里利斯股份公司 | 具有改善性能的污水管材料 |
US8604118B2 (en) * | 2008-12-26 | 2013-12-10 | Dow Global Technologies Llc | Antifoulant for impact copolymers and method |
WO2010096033A1 (en) * | 2009-02-20 | 2010-08-26 | Ineos Usa Llc | Broadening the molecular weight distribution of polyolefins materials made in a horizontal stirred gas phase reactor |
CN102812056B (zh) * | 2009-12-21 | 2015-04-29 | 陶氏环球技术有限责任公司 | 具有多个流动型态的气相聚合方法 |
US9272965B2 (en) * | 2009-12-22 | 2016-03-01 | Catalytic Distillation Technologies | Process for the conversion of alcohols to olefins |
US10647790B2 (en) | 2011-06-30 | 2020-05-12 | W. R. Grace & Co.-Conn. | Process for gas-phase polymerization having high bed bulk density |
JP5785809B2 (ja) * | 2011-07-28 | 2015-09-30 | 東邦チタニウム株式会社 | オレフィン類重合用固体触媒成分、その製造方法、オレフィン類重合触媒およびオレフィン類重合体の製造方法 |
WO2019155393A1 (en) * | 2018-02-07 | 2019-08-15 | Relianceindustries Limited | A ziegler-natta catalyst system with self-extinguishing properties suitable for olefin polymerization |
Family Cites Families (14)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
JPS5847402B2 (ja) * | 1976-02-13 | 1983-10-22 | 三井化学株式会社 | 成形用重合体組成物およびその製法 |
GB2055388B (en) * | 1979-07-27 | 1983-02-23 | El Paso Polyolefins | Block copolymerization process and product |
JPS5661415A (en) * | 1979-10-24 | 1981-05-26 | Mitsubishi Chem Ind Ltd | Preparation of propylene-ethylene block copolymer |
US4284738A (en) * | 1980-08-11 | 1981-08-18 | El Paso Polyolefins Company | Ethylene-propylene block copolymerization process and product |
JPS5883016A (ja) * | 1981-11-13 | 1983-05-18 | Mitsui Petrochem Ind Ltd | プロピレンブロツク共重合体の製法 |
JPS58201806A (ja) * | 1982-05-19 | 1983-11-24 | Chisso Corp | 後加工シ−ト用および吹込成形用高溶融粘弾性ポリプロピレンとその製造法 |
JPS58219207A (ja) * | 1982-06-15 | 1983-12-20 | Chisso Corp | 高剛性高溶融粘弾性ポリプロピレンとその製造法 |
JPS59122506A (ja) * | 1982-12-28 | 1984-07-16 | Sumitomo Chem Co Ltd | 軟質プロピレン重合体 |
US4866022A (en) * | 1984-03-23 | 1989-09-12 | Amoco Corporation | Olefin polymerization catalyst |
US4612299A (en) * | 1984-07-09 | 1986-09-16 | Amoco Corporation | Magnesium carboxylate supports |
US4829038A (en) * | 1986-06-17 | 1989-05-09 | Amoco Corporation | Alpha-olefin polymerization catalyst system including an advantageous modifier component |
DE3640924A1 (de) * | 1986-11-29 | 1988-06-01 | Hoechst Ag | 1-olefin-stereoblockpolymer und verfahren zu seiner herstellung |
CA2018829C (en) * | 1989-06-19 | 1996-06-11 | Jun Saito | Process for producing a high-stiffness polypropylene and a highly stereoregular polypropylene |
US4990478A (en) * | 1989-09-21 | 1991-02-05 | Amoco Corporation | Silane-modified supported polyolefin catalyst to produce a broadened molecular weight distribution product |
-
1991
- 1991-11-18 US US07/793,821 patent/US5218052A/en not_active Expired - Lifetime
-
1992
- 1992-01-22 CA CA002059838A patent/CA2059838C/en not_active Expired - Lifetime
- 1992-01-31 KR KR1019920001519A patent/KR100263263B1/ko not_active IP Right Cessation
- 1992-02-03 DE DE69216117T patent/DE69216117T2/de not_active Revoked
- 1992-02-03 EP EP96109556A patent/EP0736552A3/de not_active Withdrawn
- 1992-02-03 JP JP4017667A patent/JPH05105722A/ja active Pending
- 1992-02-03 EP EP92300907A patent/EP0498603B1/de not_active Revoked
- 1992-02-03 AT AT92300907T patent/ATE146806T1/de not_active IP Right Cessation
- 1992-02-04 SK SK307-92A patent/SK280948B6/sk not_active IP Right Cessation
- 1992-02-04 CZ CS1992307A patent/CZ287574B6/cs not_active IP Right Cessation
Also Published As
Publication number | Publication date |
---|---|
EP0498603A2 (de) | 1992-08-12 |
CA2059838C (en) | 2002-05-28 |
EP0498603A3 (en) | 1992-09-02 |
KR920016478A (ko) | 1992-09-24 |
ATE146806T1 (de) | 1997-01-15 |
EP0736552A2 (de) | 1996-10-09 |
CA2059838A1 (en) | 1992-08-05 |
JPH05105722A (ja) | 1993-04-27 |
US5218052A (en) | 1993-06-08 |
CZ287574B6 (cs) | 2000-12-13 |
CS30792A3 (en) | 1992-08-12 |
EP0498603B1 (de) | 1996-12-27 |
KR100263263B1 (ko) | 2000-08-01 |
EP0736552A3 (de) | 1997-03-26 |
SK280948B6 (sk) | 2000-09-12 |
DE69216117D1 (de) | 1997-02-06 |
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Legal Events
Date | Code | Title | Description |
---|---|---|---|
8363 | Opposition against the patent | ||
8331 | Complete revocation |