DE69304004T2 - Katalysatorfeststoffzusammensetzung und Olefinpolymerisationsverfahren unter Anwendung derselben - Google Patents

Katalysatorfeststoffzusammensetzung und Olefinpolymerisationsverfahren unter Anwendung derselben

Info

Publication number
DE69304004T2
DE69304004T2 DE69304004T DE69304004T DE69304004T2 DE 69304004 T2 DE69304004 T2 DE 69304004T2 DE 69304004 T DE69304004 T DE 69304004T DE 69304004 T DE69304004 T DE 69304004T DE 69304004 T2 DE69304004 T2 DE 69304004T2
Authority
DE
Germany
Prior art keywords
same
polymerization process
olefin polymerization
solid composition
catalyst solid
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Expired - Fee Related
Application number
DE69304004T
Other languages
English (en)
Other versions
DE69304004D1 (de
Inventor
Tadashi Takahashi
Kazuhiro Yamamoto
Katsumi Hirakawa
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Mitsubishi Chemical Corp
Original Assignee
Mitsubishi Chemical Corp
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Mitsubishi Chemical Corp filed Critical Mitsubishi Chemical Corp
Application granted granted Critical
Publication of DE69304004D1 publication Critical patent/DE69304004D1/de
Publication of DE69304004T2 publication Critical patent/DE69304004T2/de
Anticipated expiration legal-status Critical
Expired - Fee Related legal-status Critical Current

Links

Classifications

    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F10/00—Homopolymers and copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F4/00—Polymerisation catalysts
    • C08F4/42—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors
    • C08F4/44—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides
    • C08F4/60—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides together with refractory metals, iron group metals, platinum group metals, manganese, rhenium technetium or compounds thereof
    • C08F4/62—Refractory metals or compounds thereof
    • C08F4/64—Titanium, zirconium, hafnium or compounds thereof
    • C08F4/659—Component covered by group C08F4/64 containing a transition metal-carbon bond
    • C08F4/65908—Component covered by group C08F4/64 containing a transition metal-carbon bond in combination with an ionising compound other than alumoxane, e.g. (C6F5)4B-X+
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F4/00—Polymerisation catalysts
    • C08F4/42—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors
    • C08F4/44—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides
    • C08F4/60—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides together with refractory metals, iron group metals, platinum group metals, manganese, rhenium technetium or compounds thereof
    • C08F4/62—Refractory metals or compounds thereof
    • C08F4/64—Titanium, zirconium, hafnium or compounds thereof
    • C08F4/659—Component covered by group C08F4/64 containing a transition metal-carbon bond
    • C08F4/65912—Component covered by group C08F4/64 containing a transition metal-carbon bond in combination with an organoaluminium compound
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F4/00—Polymerisation catalysts
    • C08F4/42—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors
    • C08F4/44—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides
    • C08F4/60—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides together with refractory metals, iron group metals, platinum group metals, manganese, rhenium technetium or compounds thereof
    • C08F4/62—Refractory metals or compounds thereof
    • C08F4/64—Titanium, zirconium, hafnium or compounds thereof
    • C08F4/659—Component covered by group C08F4/64 containing a transition metal-carbon bond
    • C08F4/65916—Component covered by group C08F4/64 containing a transition metal-carbon bond supported on a carrier, e.g. silica, MgCl2, polymer
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F4/00—Polymerisation catalysts
    • C08F4/42—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors
    • C08F4/44—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides
    • C08F4/60—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides together with refractory metals, iron group metals, platinum group metals, manganese, rhenium technetium or compounds thereof
    • C08F4/62—Refractory metals or compounds thereof
    • C08F4/64—Titanium, zirconium, hafnium or compounds thereof
    • C08F4/659—Component covered by group C08F4/64 containing a transition metal-carbon bond
    • C08F4/6592—Component covered by group C08F4/64 containing a transition metal-carbon bond containing at least one cyclopentadienyl ring, condensed or not, e.g. an indenyl or a fluorenyl ring
DE69304004T 1992-09-22 1993-09-17 Katalysatorfeststoffzusammensetzung und Olefinpolymerisationsverfahren unter Anwendung derselben Expired - Fee Related DE69304004T2 (de)

Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
JP25305392A JP3202349B2 (ja) 1992-09-22 1992-09-22 触媒組成物およびそれを用いるオレフィンの重合法

Publications (2)

Publication Number Publication Date
DE69304004D1 DE69304004D1 (de) 1996-09-19
DE69304004T2 true DE69304004T2 (de) 1997-01-23

Family

ID=17245832

Family Applications (1)

Application Number Title Priority Date Filing Date
DE69304004T Expired - Fee Related DE69304004T2 (de) 1992-09-22 1993-09-17 Katalysatorfeststoffzusammensetzung und Olefinpolymerisationsverfahren unter Anwendung derselben

Country Status (4)

Country Link
US (1) US5474962A (de)
EP (1) EP0589638B1 (de)
JP (1) JP3202349B2 (de)
DE (1) DE69304004T2 (de)

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DE69426648T3 (de) * 1993-06-15 2005-02-03 Idemitsu Kosan Co. Ltd. Verfahren zur herstellung von olefinpolymeren und katalysator zur olefinpolymerisation
FI96866C (fi) * 1993-11-05 1996-09-10 Borealis As Tuettu olefiinipolymerointikatalyytti, sen valmistus ja käyttö
DE4344688A1 (de) * 1993-12-27 1995-06-29 Hoechst Ag Metallocenverbindung
ATE207085T1 (de) * 1994-06-24 2001-11-15 Exxonmobil Chem Patents Inc Polymerisationskatalysatorsystem, ihre herstellung und verwendung
PL182074B1 (en) * 1994-06-24 2001-11-30 Exxon Chemical Patents Inc Catalytic systems for polymerisation processes, their production and application
TW454020B (en) * 1994-08-09 2001-09-11 Mitsui Chemicals Inc Olefin polymerization catalyst
US5625015A (en) * 1994-11-23 1997-04-29 Exxon Chemical Patents Inc. Method for making supported catalyst systems and catalyst systems therefrom
ES2116188B1 (es) * 1994-12-30 1999-04-01 Repsol Quimica Sa Proceso de obtencion de poliolefinas con distribuciones de pesos moleculares anchas, bimodales o multimodales.
EP0728773B1 (de) * 1995-02-21 1998-11-04 Mitsubishi Chemical Corporation Katalysatoren für Olefinpolymerisation und Verfahren zur Herstellung von damit erhaltenen Olefinpolymeren
DE19606165A1 (de) 1996-02-20 1997-08-21 Basf Ag Verfahren zur Herstellung von Polymerisaten von Alkenen durch Gasphasenpolymerisation
DE19606166A1 (de) * 1996-02-20 1997-08-21 Basf Ag Verfahren zur Herstellung von Polymerisaten von Alkenen durch Suspensionspolymerisation
DE19606167A1 (de) * 1996-02-20 1997-08-21 Basf Ag Geträgerte Katalysatorsysteme
WO1997035892A1 (en) * 1996-03-27 1997-10-02 The Dow Chemical Company Solution polymerization process with dispersed catalyst activator
ATE212647T1 (de) 1996-06-26 2002-02-15 Bp Chem Int Ltd Verfahren zur ethylenpolymerisation in der gasphase
EP0816394B1 (de) * 1996-06-26 2002-01-30 BP Chemicals S.N.C. Verfahren zur Ethylenpolymerisation in der Gasphase
DE19757563A1 (de) 1997-03-07 1999-07-08 Targor Gmbh Geträgertes Katalysatorsystem, Verfahren zur Herstellung und seine Verwendung zur Polymerisation von Olefinen
EP0878483B1 (de) * 1997-03-27 2008-03-12 Council of Scientific and Industrial Research Verfahren zur Polymerisation und Copolymerisation von Olefinen
EP0878485B1 (de) * 1997-05-14 2006-04-26 Council of Scientific and Industrial Research Verfahren zur Polymerisation von Olefinen
US6030918A (en) * 1997-06-25 2000-02-29 The Regents Of The University Of California Gallium based low-interaction anions
EP0996649A1 (de) * 1997-07-08 2000-05-03 BP Chemicals Limited Geträgerter polymerisationskatalysator
US6154501A (en) * 1998-02-04 2000-11-28 Friedman; Robert F. Method and apparatus for combining transponders on multiple satellites into virtual channels
US6559091B1 (en) 1999-02-22 2003-05-06 Eastman Chemical Company Catalysts containing N-pyrrolyl substituted nitrogen donors
US6545108B1 (en) 1999-02-22 2003-04-08 Eastman Chemical Company Catalysts containing N-pyrrolyl substituted nitrogen donors
US6288181B1 (en) 1999-03-30 2001-09-11 Eastman Chemical Company Process for producing polyolefins
US6313236B1 (en) 1999-03-30 2001-11-06 Eastman Chemical Company Process for producing polyolefins
US6417298B1 (en) 1999-06-07 2002-07-09 Eastman Chemical Company Process for producing ethylene/olefin interpolymers
US6417299B1 (en) 1999-06-07 2002-07-09 Eastman Chemical Company Process for producing ethylene/olefin interpolymers
US6417301B1 (en) 1999-06-07 2002-07-09 Eastman Chemical Company Process for producing ethylene/olefin interpolymers
BR9917469B1 (pt) 1999-08-31 2008-11-18 processo para polimerizar uma olefina e/ou uma olefina e pelo menos uma ou mais outras olefinas, filme, e, artigo.
US6187879B1 (en) 1999-08-31 2001-02-13 Eastman Chemical Company Process for producing polyolefins
ATE395368T1 (de) 1999-12-20 2008-05-15 Exxonmobil Chem Patents Inc Verfahren zur herstellung von polyolefinen mittels verträgter ionischer katalysatoren
US6579823B2 (en) 2000-02-18 2003-06-17 Eastman Chemical Company Catalysts containing per-ortho aryl substituted aryl or heteroaryl substituted nitrogen donors
US7056996B2 (en) * 2000-02-18 2006-06-06 E. I. Du Pont De Nemours And Company Productivity catalysts and microstructure control
US20040127658A1 (en) * 2000-02-18 2004-07-01 Eastman Chemical Company Productivity catalysts and microstructure control
US6605677B2 (en) 2000-02-18 2003-08-12 Eastman Chemical Company Olefin polymerization processes using supported catalysts
CA2417412A1 (en) 2000-08-02 2002-02-07 Xinmin Yang Method for producing highly productive supported ionic catalyst for gas phase polymerization
US6706891B2 (en) 2000-11-06 2004-03-16 Eastman Chemical Company Process for the preparation of ligands for olefin polymerization catalysts
EP1636245B1 (de) * 2003-05-28 2009-02-25 Basell Polyolefine GmbH Bisindenyl-zirconium-komplexe zur olefinpolymerisation
WO2006137818A1 (en) * 2005-01-04 2006-12-28 Fina Technology, Inc. Catalyst components and their use in the polymerization of olefins
EP1693388A1 (de) * 2005-02-21 2006-08-23 Innovene Europe Limited Polymerisationskatalysatoren
WO2018067121A1 (en) 2016-10-04 2018-04-12 Halliburton Energy Services, Inc. Telemetry system using frequency combs

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Publication number Priority date Publication date Assignee Title
FR1332778A (fr) * 1962-06-25 1963-07-19 Cabot Corp Compositions polymérisées perfectionnées obtenues notamment à partir d'alpha-monooléfines
US4508843A (en) * 1983-08-08 1985-04-02 Exxon Research & Engineering Co. Supported polyolefin catalyst for the polymerization of ethylene under high temperatures
US4808561A (en) * 1985-06-21 1989-02-28 Exxon Chemical Patents Inc. Supported polymerization catalyst
JP2538595B2 (ja) * 1987-05-13 1996-09-25 三井石油化学工業株式会社 オレフイン重合用固体触媒
JP2573613B2 (ja) * 1987-08-14 1997-01-22 三菱化学株式会社 エチレンの重合法
US5026797A (en) * 1987-10-22 1991-06-25 Mitsubishi Petrochemical Co., Ltd. Process for producing ethylene copolymers
US5155080A (en) * 1988-07-15 1992-10-13 Fina Technology, Inc. Process and catalyst for producing syndiotactic polyolefins
US4935397A (en) * 1988-09-28 1990-06-19 Exxon Chemical Patents Inc. Supported metallocene-alumoxane catalyst for high pressure polymerization of olefins and a method of preparing and using the same
EP0380241B1 (de) * 1989-01-21 1996-03-20 Mitsubishi Chemical Corporation Verfahren zur Herstellung von Ethylencopolymeren
JP2999274B2 (ja) * 1991-01-28 2000-01-17 三菱化学株式会社 エチレン重合体の製造法
TW218884B (de) * 1991-05-01 1994-01-11 Mitsubishi Kakoki Kk

Also Published As

Publication number Publication date
US5474962A (en) 1995-12-12
EP0589638A2 (de) 1994-03-30
JPH06100622A (ja) 1994-04-12
EP0589638B1 (de) 1996-08-14
JP3202349B2 (ja) 2001-08-27
DE69304004D1 (de) 1996-09-19
EP0589638A3 (en) 1994-08-24

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