DE69321879T2 - Kationische Metallocenkatalysatoren auf Basis von Triphenylcarbeniumaluminium - Google Patents
Kationische Metallocenkatalysatoren auf Basis von TriphenylcarbeniumaluminiumInfo
- Publication number
- DE69321879T2 DE69321879T2 DE69321879T DE69321879T DE69321879T2 DE 69321879 T2 DE69321879 T2 DE 69321879T2 DE 69321879 T DE69321879 T DE 69321879T DE 69321879 T DE69321879 T DE 69321879T DE 69321879 T2 DE69321879 T2 DE 69321879T2
- Authority
- DE
- Germany
- Prior art keywords
- triphenylcarbenium
- aluminum
- metallocene catalysts
- catalysts based
- cationic metallocene
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Expired - Lifetime
Links
- XSBGAUUCJDMBSO-UHFFFAOYSA-N aluminum diphenylmethylbenzene Chemical compound [Al+3].c1ccc(cc1)[C+](c1ccccc1)c1ccccc1 XSBGAUUCJDMBSO-UHFFFAOYSA-N 0.000 title 1
- 125000002091 cationic group Chemical group 0.000 title 1
- 239000012968 metallocene catalyst Substances 0.000 title 1
Classifications
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07F—ACYCLIC, CARBOCYCLIC OR HETEROCYCLIC COMPOUNDS CONTAINING ELEMENTS OTHER THAN CARBON, HYDROGEN, HALOGEN, OXYGEN, NITROGEN, SULFUR, SELENIUM OR TELLURIUM
- C07F17/00—Metallocenes
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
- C08F10/00—Homopolymers and copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
- C08F10/00—Homopolymers and copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond
- C08F10/04—Monomers containing three or four carbon atoms
- C08F10/06—Propene
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
- C08F4/00—Polymerisation catalysts
- C08F4/42—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors
- C08F4/44—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides
- C08F4/60—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides together with refractory metals, iron group metals, platinum group metals, manganese, rhenium technetium or compounds thereof
- C08F4/619—Component covered by group C08F4/60 containing a transition metal-carbon bond
- C08F4/61908—Component covered by group C08F4/60 containing a transition metal-carbon bond in combination with an ionising compound other than alumoxane, e.g. (C6F5)4B-X+
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
- C08F4/00—Polymerisation catalysts
- C08F4/42—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors
- C08F4/44—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides
- C08F4/60—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides together with refractory metals, iron group metals, platinum group metals, manganese, rhenium technetium or compounds thereof
- C08F4/619—Component covered by group C08F4/60 containing a transition metal-carbon bond
- C08F4/61912—Component covered by group C08F4/60 containing a transition metal-carbon bond in combination with an organoaluminium compound
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
- C08F4/00—Polymerisation catalysts
- C08F4/42—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors
- C08F4/44—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides
- C08F4/60—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides together with refractory metals, iron group metals, platinum group metals, manganese, rhenium technetium or compounds thereof
- C08F4/619—Component covered by group C08F4/60 containing a transition metal-carbon bond
- C08F4/6192—Component covered by group C08F4/60 containing a transition metal-carbon bond containing at least one cyclopentadienyl ring, condensed or not, e.g. an indenyl or a fluorenyl ring
- C08F4/61922—Component covered by group C08F4/60 containing a transition metal-carbon bond containing at least one cyclopentadienyl ring, condensed or not, e.g. an indenyl or a fluorenyl ring containing at least two cyclopentadienyl rings, fused or not
- C08F4/61927—Component covered by group C08F4/60 containing a transition metal-carbon bond containing at least one cyclopentadienyl ring, condensed or not, e.g. an indenyl or a fluorenyl ring containing at least two cyclopentadienyl rings, fused or not two cyclopentadienyl rings being mutually bridged
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
- C08F4/00—Polymerisation catalysts
- C08F4/42—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors
- C08F4/44—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides
- C08F4/60—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides together with refractory metals, iron group metals, platinum group metals, manganese, rhenium technetium or compounds thereof
- C08F4/62—Refractory metals or compounds thereof
- C08F4/639—Component covered by group C08F4/62 containing a transition metal-carbon bond
- C08F4/63908—Component covered by group C08F4/62 containing a transition metal-carbon bond in combination with an ionising compound other than alumoxane, e.g. (C6F5)4B-X+
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
- C08F4/00—Polymerisation catalysts
- C08F4/42—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors
- C08F4/44—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides
- C08F4/60—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides together with refractory metals, iron group metals, platinum group metals, manganese, rhenium technetium or compounds thereof
- C08F4/62—Refractory metals or compounds thereof
- C08F4/639—Component covered by group C08F4/62 containing a transition metal-carbon bond
- C08F4/63912—Component covered by group C08F4/62 containing a transition metal-carbon bond in combination with an organoaluminium compound
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
- C08F4/00—Polymerisation catalysts
- C08F4/42—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors
- C08F4/44—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides
- C08F4/60—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides together with refractory metals, iron group metals, platinum group metals, manganese, rhenium technetium or compounds thereof
- C08F4/62—Refractory metals or compounds thereof
- C08F4/639—Component covered by group C08F4/62 containing a transition metal-carbon bond
- C08F4/6392—Component covered by group C08F4/62 containing a transition metal-carbon bond containing at least one cyclopentadienyl ring, condensed or not, e.g. an indenyl or a fluorenyl ring
- C08F4/63922—Component covered by group C08F4/62 containing a transition metal-carbon bond containing at least one cyclopentadienyl ring, condensed or not, e.g. an indenyl or a fluorenyl ring containing at least two cyclopentadienyl rings, fused or not
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
- C08F4/00—Polymerisation catalysts
- C08F4/42—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors
- C08F4/44—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides
- C08F4/60—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides together with refractory metals, iron group metals, platinum group metals, manganese, rhenium technetium or compounds thereof
- C08F4/62—Refractory metals or compounds thereof
- C08F4/64—Titanium, zirconium, hafnium or compounds thereof
- C08F4/659—Component covered by group C08F4/64 containing a transition metal-carbon bond
- C08F4/65908—Component covered by group C08F4/64 containing a transition metal-carbon bond in combination with an ionising compound other than alumoxane, e.g. (C6F5)4B-X+
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
- C08F4/00—Polymerisation catalysts
- C08F4/42—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors
- C08F4/44—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides
- C08F4/60—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides together with refractory metals, iron group metals, platinum group metals, manganese, rhenium technetium or compounds thereof
- C08F4/62—Refractory metals or compounds thereof
- C08F4/64—Titanium, zirconium, hafnium or compounds thereof
- C08F4/659—Component covered by group C08F4/64 containing a transition metal-carbon bond
- C08F4/6592—Component covered by group C08F4/64 containing a transition metal-carbon bond containing at least one cyclopentadienyl ring, condensed or not, e.g. an indenyl or a fluorenyl ring
- C08F4/65922—Component covered by group C08F4/64 containing a transition metal-carbon bond containing at least one cyclopentadienyl ring, condensed or not, e.g. an indenyl or a fluorenyl ring containing at least two cyclopentadienyl rings, fused or not
- C08F4/65927—Component covered by group C08F4/64 containing a transition metal-carbon bond containing at least one cyclopentadienyl ring, condensed or not, e.g. an indenyl or a fluorenyl ring containing at least two cyclopentadienyl rings, fused or not two cyclopentadienyl rings being mutually bridged
Applications Claiming Priority (1)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
US07/893,522 US5763549A (en) | 1989-10-10 | 1992-06-04 | Cationic metallocene catalysts based on organoaluminum anions |
Publications (2)
Publication Number | Publication Date |
---|---|
DE69321879D1 DE69321879D1 (de) | 1998-12-10 |
DE69321879T2 true DE69321879T2 (de) | 1999-06-10 |
Family
ID=25401710
Family Applications (1)
Application Number | Title | Priority Date | Filing Date |
---|---|---|---|
DE69321879T Expired - Lifetime DE69321879T2 (de) | 1992-06-04 | 1993-06-04 | Kationische Metallocenkatalysatoren auf Basis von Triphenylcarbeniumaluminium |
Country Status (5)
Country | Link |
---|---|
US (2) | US5763549A (de) |
EP (1) | EP0573403B1 (de) |
JP (1) | JP3446059B2 (de) |
DE (1) | DE69321879T2 (de) |
ES (1) | ES2124777T3 (de) |
Families Citing this family (153)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
US5384299A (en) * | 1987-01-30 | 1995-01-24 | Exxon Chemical Patents Inc. | Ionic metallocene catalyst compositions |
US6008307A (en) * | 1994-04-28 | 1999-12-28 | Exxon Chemical Patents Inc | Process for producing olefin polymers using cationic catalysts |
US6291389B1 (en) | 1994-04-28 | 2001-09-18 | Exxonmobil Chemical Patents Inc. | Cationic polymerization catalysts |
US6143686A (en) * | 1994-08-03 | 2000-11-07 | Exxon Chemical Patents, Inc. | Supported ionic catalyst compositions |
ATE208404T1 (de) * | 1994-08-03 | 2001-11-15 | Exxonmobil Chem Patents Inc | Ionische katalysatorzusammensetzung auf träger |
US5856256A (en) * | 1996-02-20 | 1999-01-05 | Northwestern University | Organo-Lewis acid as cocatalyst for cationic homogeneous Ziegler-Natta olefin polymerizations |
US6274752B1 (en) | 1996-02-20 | 2001-08-14 | Northwestern University | Organo-Lewis acid as cocatalyst for cationic homogeneous Ziegler-Natta olefin polymerizations |
US6291695B1 (en) | 1996-02-20 | 2001-09-18 | Northwestern University | Organo-Lewis acids of enhanced utility, uses thereof, and products based thereon |
US5786291A (en) * | 1996-02-23 | 1998-07-28 | Exxon Chemical Patents, Inc. | Engineered catalyst systems and methods for their production and use |
US6066603A (en) * | 1996-06-17 | 2000-05-23 | Exxon Chemical Patents Inc. | Polar monomer containing copolymers derived from olefins useful as lubricant and useful as lubricant and fuel oil additivies process for preparation of such copolymers and additives and use thereof |
EP0906343B1 (de) | 1996-06-17 | 2001-04-18 | Exxon Chemical Patents Inc. | Olefinpolymerisationkatalysatorsysteme von gemischten übergangsmetalen |
US5811379A (en) | 1996-06-17 | 1998-09-22 | Exxon Chemical Patents Inc. | Polymers derived from olefins useful as lubricant and fuel oil additives, processes for preparation of such polymers and additives and use thereof (PT-1267) |
US5854166A (en) * | 1996-08-19 | 1998-12-29 | Northwestern University | Synthesis and use of (perfluoroaryl) fluoro-aluminate anion |
US6130302A (en) | 1996-08-19 | 2000-10-10 | Northwestern University | Synthesis and use of (polyfluoroaryl)fluoroanions of aluminum, gallium and indium |
US6262200B1 (en) | 1996-08-19 | 2001-07-17 | Northwestern University | (Polyfluoroaryl)fluoroanions of aluminum, gallium, and indium of enhanced utility, uses thereof, and products based thereon |
US6180736B1 (en) | 1996-12-20 | 2001-01-30 | Exxon Chemical Patents Inc | High activity metallocene polymerization process |
DE19703478A1 (de) | 1997-01-31 | 1998-08-06 | Hoechst Ag | Verfahren zur Herstellung eines Matallocen-Katalysatorsystems |
KR100564500B1 (ko) | 1997-02-07 | 2006-03-29 | 엑손모빌 케미칼 패턴츠 인코포레이티드 | 폴리에틸렌 마크로머를 혼입한 프로필렌 중합체 |
JP2001511214A (ja) | 1997-02-07 | 2001-08-07 | エクソン・ケミカル・パテンツ・インク | ビニル含有マクロマーの調製 |
US5895771A (en) * | 1997-06-05 | 1999-04-20 | Akzo Nobel Nv | Fluorinated alkoxy and/or aryloxy aluminates as cocatalysts for metallocene-catalyzed olefin polymerizations |
US6172015B1 (en) | 1997-07-21 | 2001-01-09 | Exxon Chemical Patents, Inc | Polar monomer containing copolymers derived from olefins useful as lubricant and fuel oil additives, processes for preparation of such copolymers and additives and use thereof |
US6635715B1 (en) | 1997-08-12 | 2003-10-21 | Sudhin Datta | Thermoplastic polymer blends of isotactic polypropylene and alpha-olefin/propylene copolymers |
US7026404B2 (en) | 1997-08-12 | 2006-04-11 | Exxonmobil Chemical Patents Inc. | Articles made from blends made from propylene ethylene polymers |
US6921794B2 (en) | 1997-08-12 | 2005-07-26 | Exxonmobil Chemical Patents Inc. | Blends made from propylene ethylene polymers |
US6100224A (en) * | 1997-10-01 | 2000-08-08 | Exxon Chemical Patents Inc | Copolymers of ethylene α-olefin macromers and dicarboxylic monomers and derivatives thereof, useful as additives in lubricating oils and in fuels |
US6197910B1 (en) | 1997-12-10 | 2001-03-06 | Exxon Chemical Patents, Inc. | Propylene polymers incorporating macromers |
US6184327B1 (en) | 1997-12-10 | 2001-02-06 | Exxon Chemical Patents, Inc. | Elastomeric propylene polymers |
US6117962A (en) * | 1997-12-10 | 2000-09-12 | Exxon Chemical Patents Inc. | Vinyl-containing stereospecific polypropylene macromers |
CN1130392C (zh) | 1998-05-13 | 2003-12-10 | 埃克森美孚化学专利公司 | 丙烯均聚物及其制备方法 |
US6784269B2 (en) | 1998-05-13 | 2004-08-31 | Exxonmobil Chemical Patents Inc. | Polypropylene compositions methods of making the same |
DE69916834T2 (de) | 1998-06-12 | 2004-09-30 | Univation Technologies, LLC, Houston | Verfahren zur polymerisation von olefinen unter verwendung von aktivierten lewis säure-base komplexen |
JP2002519497A (ja) | 1998-07-01 | 2002-07-02 | エクソンモービル・ケミカル・パテンツ・インク | 結晶性プロピレンポリマーと結晶化可能プロピレンポリマーとを含んでなる弾性ブレンド |
BR9912124A (pt) | 1998-07-16 | 2001-09-25 | Univation Tech Llc | Co-catalisadores de ácido de lewis à base de alumìnio para a polimerização de olefina |
EP1104426B1 (de) * | 1998-08-11 | 2002-08-14 | The Dow Chemical Company | Katalysatoraktivatorverbindung |
EP1104430B1 (de) * | 1998-08-11 | 2002-12-18 | Dow Global Technologies Inc. | Ansa gruppe-4-metall bis(.mu.-aluminium) -substituierte metallocene |
JP2002522551A (ja) * | 1998-08-11 | 2002-07-23 | ザ ダウ ケミカル カンパニー | アンサ−基−4−金属ビス(μ−置換)アルミニウム錯体 |
EP1115761B1 (de) | 1998-08-26 | 2013-09-18 | ExxonMobil Chemical Patents Inc. | Verzweigte polypropylenzusammensetzungen |
US6403773B1 (en) | 1998-09-30 | 2002-06-11 | Exxon Mobil Chemical Patents Inc. | Cationic group 3 catalyst system |
IT1304181B1 (it) * | 1998-12-17 | 2001-03-08 | Enichem Spa | Composizione attivante di complessi metallocenici nella catalisi deiprocessi di (co)polimerizzazione delle olefine. |
JP2000351813A (ja) | 1999-04-09 | 2000-12-19 | Mitsui Chemicals Inc | エチレン・α−オレフィン共重合体およびその製造方法ならびにその用途 |
US6174930B1 (en) | 1999-04-16 | 2001-01-16 | Exxon Chemical Patents, Inc. | Foamable polypropylene polymer |
US6339134B1 (en) | 1999-05-06 | 2002-01-15 | Univation Technologies, Llc | Polymerization process for producing easier processing polymers |
US6479598B1 (en) | 1999-07-20 | 2002-11-12 | Exxonmobil Chemical Patents Inc. | Petroleum resins and their production with BF3 catalyst |
DE19935592A1 (de) | 1999-08-02 | 2001-02-08 | Elenac Gmbh | Imidochromverbindungen in Katalysatorsystemen für die Olefinpolymerisation |
CA2381723C (en) | 1999-08-13 | 2007-10-30 | Basell Polyolefine Gmbh | Copolymers of ethylene with c3-c12 .alpha. olefins |
US6403743B1 (en) | 1999-09-14 | 2002-06-11 | Exxonmobil Chemical Patents Inc. | Petroleum resins and their production with supported catalyst |
US6300439B1 (en) | 1999-11-08 | 2001-10-09 | Univation Technologies, Llc | Group 15 containing transition metal catalyst compounds, catalyst systems and their use in a polymerization process |
US6274684B1 (en) * | 1999-10-22 | 2001-08-14 | Univation Technologies, Llc | Catalyst composition, method of polymerization, and polymer therefrom |
DE60006146T2 (de) | 1999-11-04 | 2004-09-30 | Exxonmobil Chemical Patents Inc., Baytown | Propylencopolymerschäume und deren verwendung |
US6667274B1 (en) * | 1999-12-30 | 2003-12-23 | Phillips Petroleum Company | Polymerization catalysts |
DE10022497A1 (de) | 2000-05-09 | 2001-11-15 | Bayer Ag | Copolymerisation konjugierter Diene mit nichtkonjugierten Olefinen mittels Katalysatoren der Seltenen Erden |
JP2004504420A (ja) * | 2000-07-17 | 2004-02-12 | ユニベーション・テクノロジーズ・エルエルシー | 触媒系及びその重合方法への使用 |
US6495484B1 (en) | 2000-08-28 | 2002-12-17 | Univation Technologies, Llc | Catalyst system and its use in a polymerization process |
GC0000293A (en) * | 2000-10-10 | 2006-11-01 | Saudi Basic Ind Corp | Catalyst composition and process for olfin polymerization and copolymerization using supported metallocene catalyst systems |
CA2332203A1 (en) * | 2001-01-24 | 2002-07-24 | Bayer Inc. | Process for making high molecular weight isobutylene polymers |
JP5156167B2 (ja) | 2001-04-12 | 2013-03-06 | エクソンモービル・ケミカル・パテンツ・インク | プロピレン−エチレンポリマー及び製造法 |
DE10127926A1 (de) | 2001-06-08 | 2002-12-12 | Bayer Ag | 1,3-disubstituierte Indenkomplexe |
US6660679B2 (en) | 2001-06-18 | 2003-12-09 | Univation Technologies, Llc | Catalyst system and its use in a polymerization process |
JP2005522406A (ja) | 2001-06-29 | 2005-07-28 | エクソンモービル・ケミカル・パテンツ・インク | メタロセン及び該メタロセン由来の触媒組成物 |
US6916892B2 (en) | 2001-12-03 | 2005-07-12 | Fina Technology, Inc. | Method for transitioning between Ziegler-Natta and metallocene catalysts in a bulk loop reactor for the production of polypropylene |
CA2368724C (en) * | 2002-01-21 | 2011-06-14 | Bayer Inc. | Process for preparing isobutylene-based polymers |
US7943700B2 (en) | 2002-10-01 | 2011-05-17 | Exxonmobil Chemical Patents Inc. | Enhanced ESCR of HDPE resins |
US7223822B2 (en) | 2002-10-15 | 2007-05-29 | Exxonmobil Chemical Patents Inc. | Multiple catalyst and reactor system for olefin polymerization and polymers produced therefrom |
KR101113341B1 (ko) | 2002-10-15 | 2012-09-27 | 엑손모빌 케미칼 패턴츠 인코포레이티드 | 올레핀 중합용 다중 촉매 시스템 및 이로부터 제조된중합체 |
US7700707B2 (en) | 2002-10-15 | 2010-04-20 | Exxonmobil Chemical Patents Inc. | Polyolefin adhesive compositions and articles made therefrom |
US20040102311A1 (en) | 2002-11-21 | 2004-05-27 | Abbas Razavi | Bridged metallocene catalyst component, method of making, polyolefin catalyst having C1, C2, or Cs symmetry, methods of making, methods of polymerizing, olefins and products made thereof |
US7195806B2 (en) | 2003-01-17 | 2007-03-27 | Fina Technology, Inc. | High gloss polyethylene articles |
US6953764B2 (en) | 2003-05-02 | 2005-10-11 | Dow Global Technologies Inc. | High activity olefin polymerization catalyst and process |
US8779053B2 (en) | 2003-08-25 | 2014-07-15 | Dow Global Technologies Llc | Coating compositions |
US7947776B2 (en) | 2003-08-25 | 2011-05-24 | Dow Global Technologies Llc | Aqueous dispersion, its production method, and its use |
US7763676B2 (en) | 2003-08-25 | 2010-07-27 | Dow Global Technologies Inc. | Aqueous polymer dispersions and products from those dispersions |
TW200517426A (en) | 2003-08-25 | 2005-06-01 | Dow Global Technologies Inc | Aqueous dispersion, its production method, and its use |
US7803865B2 (en) | 2003-08-25 | 2010-09-28 | Dow Global Technologies Inc. | Aqueous dispersion, its production method, and its use |
US8158711B2 (en) | 2003-08-25 | 2012-04-17 | Dow Global Technologies Llc | Aqueous dispersion, its production method, and its use |
US8357749B2 (en) | 2003-08-25 | 2013-01-22 | Dow Global Technologies Llc | Coating composition and articles made therefrom |
US8946329B2 (en) | 2003-08-25 | 2015-02-03 | Dow Global Technologies Llc | Coating compositions |
US8722787B2 (en) | 2003-08-25 | 2014-05-13 | Dow Global Technologies Llc | Coating composition and articles made therefrom |
US9169406B2 (en) | 2003-08-25 | 2015-10-27 | Dow Global Technologies Llc | Coating compositions |
US8349929B2 (en) | 2003-08-25 | 2013-01-08 | Dow Global Technologies Llc | Coating composition and articles made therefrom |
US7034157B2 (en) * | 2003-10-23 | 2006-04-25 | Fina Technology, Inc. | Catalyst components, process for their preparation and their use as catalyst components in polymerization of olefins |
WO2005063829A1 (en) * | 2003-12-23 | 2005-07-14 | Basell Polyolefine Gmbh | Catalyst system for olefin polymerization |
US7211536B2 (en) * | 2004-10-22 | 2007-05-01 | Fina Technology, Inc. | Supported metallocene catalysts and their use in producing stereospecific polymers |
US8093341B2 (en) | 2004-10-28 | 2012-01-10 | Dow Global Technologies Llc | Method of controlling a polymerization reactor |
WO2006049699A1 (en) | 2004-10-29 | 2006-05-11 | Exxonmobil Chemical Patents Inc | Catalyst compound containing divalent tridentate ligand |
US7588706B2 (en) | 2004-12-16 | 2009-09-15 | Exxonmobil Chemical Patents Inc. | Multi-layer films with improved properties |
CA2590871A1 (en) | 2004-12-21 | 2006-06-29 | Dow Global Technologies Inc. | Polypropylene-based adhesive compositions |
US7053163B1 (en) | 2005-02-22 | 2006-05-30 | Fina Technology, Inc. | Controlled comonomer distribution along a reactor for copolymer production |
US20070225423A1 (en) * | 2005-10-07 | 2007-09-27 | Mitsui Chemicals, Inc. | Process for producing blow molded product by blow molding |
US20070080483A1 (en) * | 2005-10-07 | 2007-04-12 | Mitsui Chemicals, Inc. | Process for producing injection molded product |
US7605208B2 (en) | 2005-10-31 | 2009-10-20 | Mitsui Chemicals, Inc. | Process for producing thermoplastic resin composition |
EP1803747A1 (de) | 2005-12-30 | 2007-07-04 | Borealis Technology Oy | Oberflächemodifizierte Polymerisationskatalysatoren zur Herstellung von Polyolefinfilmen mit niedrigem Gelgehalt |
JP5666129B2 (ja) | 2006-05-17 | 2015-02-12 | ダウ グローバル テクノロジーズ エルエルシー | ポリオレフィン溶液重合方法及びポリマー |
US7985804B2 (en) | 2006-11-06 | 2011-07-26 | Exxonmobil Chemical Patents Inc. | Rubber toughened compositions, articles, films, and methods of making the same |
US8143352B2 (en) | 2006-12-20 | 2012-03-27 | Exxonmobil Research And Engineering Company | Process for fluid phase in-line blending of polymers |
US8362163B2 (en) | 2007-03-07 | 2013-01-29 | Dow Global Technologies, Llc | Tethered supported transition metal complex |
TW200932762A (en) | 2007-10-22 | 2009-08-01 | Univation Tech Llc | Polyethylene compositions having improved properties |
US7906588B2 (en) | 2007-10-26 | 2011-03-15 | Exxonmobil Chemical Patents Inc. | Soft heterogeneous isotactic polypropylene compositions |
TW200936619A (en) | 2007-11-15 | 2009-09-01 | Univation Tech Llc | Polymerization catalysts, methods of making, methods of using, and polyolefin products made therefrom |
WO2009067337A1 (en) | 2007-11-19 | 2009-05-28 | Dow Global Technologies Inc. | Long chain branched propylene-alpha-olefin copolymers |
US9938400B2 (en) | 2008-04-23 | 2018-04-10 | Exxonmobil Chemical Patents Inc. | Propylene copolymers in soft thermoplastic blends |
US8242198B2 (en) | 2008-06-09 | 2012-08-14 | Exxonmobil Chemical Patents Inc. | Polyolefin adhesive compositions |
US9168718B2 (en) | 2009-04-21 | 2015-10-27 | Exxonmobil Chemical Patents Inc. | Method for producing temperature resistant nonwovens |
US8664129B2 (en) | 2008-11-14 | 2014-03-04 | Exxonmobil Chemical Patents Inc. | Extensible nonwoven facing layer for elastic multilayer fabrics |
US9498932B2 (en) | 2008-09-30 | 2016-11-22 | Exxonmobil Chemical Patents Inc. | Multi-layered meltblown composite and methods for making same |
US10161063B2 (en) | 2008-09-30 | 2018-12-25 | Exxonmobil Chemical Patents Inc. | Polyolefin-based elastic meltblown fabrics |
ES2432965T3 (es) | 2008-12-15 | 2013-12-05 | Exxonmobil Chemical Patents Inc. | Composiciones de olefinas termoplásticas |
CN102333644B (zh) | 2009-02-27 | 2015-07-22 | 埃克森美孚化学专利公司 | 多层非织造原位层压体及其制备方法 |
US8378042B2 (en) | 2009-04-28 | 2013-02-19 | Exxonmobil Chemical Patents Inc. | Finishing process for amorphous polymers |
US9127151B2 (en) | 2009-04-28 | 2015-09-08 | Exxonmobil Chemical Patents Inc. | Polymer compositions having improved properties as viscosity index improvers and use thereof in lubricating oils |
US20120028865A1 (en) | 2010-07-28 | 2012-02-02 | Sudhin Datta | Viscosity Modifiers Comprising Blends of Ethylene-Based Copolymers |
KR20120050501A (ko) | 2009-10-02 | 2012-05-18 | 엑손모빌 케미칼 패턴츠 인코포레이티드 | 다층 용융취입 복합체 및 이의 제조 방법 |
CA2777230C (en) | 2009-10-19 | 2015-12-22 | Sasol Technology (Pty) Limited | Oligomerisation of olefinic compounds with reduced polymer formation |
US8668975B2 (en) | 2009-11-24 | 2014-03-11 | Exxonmobil Chemical Patents Inc. | Fabric with discrete elastic and plastic regions and method for making same |
CN102741303B (zh) | 2010-01-22 | 2015-05-06 | 埃克森美孚化学专利公司 | 润滑油组合物及其制造方法 |
CN102725319B (zh) | 2010-01-27 | 2014-10-15 | 埃克森美孚化学专利公司 | 共聚物、其组合物及制造它们的方法 |
EP2545215B1 (de) | 2010-03-12 | 2014-08-27 | ExxonMobil Chemical Patents Inc. | Verfahren zur herstellung von temperaturbeständigen faservliesen |
SG186166A1 (en) | 2010-07-28 | 2013-01-30 | Exxonmobil Chem Patents Inc | Viscosity modifiers comprising blends of ethylene-based copolymers |
WO2012015572A1 (en) | 2010-07-28 | 2012-02-02 | Exxonmobil Chemical Patents Inc. | Viscosity modifiers comprising blends of ethylene-based copolymers |
EP2598572B1 (de) | 2010-07-28 | 2020-03-18 | ExxonMobil Chemical Patents Inc. | Copolymerzusammensetzungen auf ethylenbasis als viskositätsmodifikatoren und verfahren zu ihrer herstellung |
WO2012134721A2 (en) | 2011-03-25 | 2012-10-04 | Exxonmobil Chemical Patents Inc. | Vinyl terminated higher olefin polymers and methods to produce thereof |
CN103443136B (zh) | 2011-03-25 | 2016-03-30 | 埃克森美孚化学专利公司 | 通过烯烃易位制备的两亲性嵌段聚合物 |
US8658556B2 (en) | 2011-06-08 | 2014-02-25 | Exxonmobil Chemical Patents Inc. | Catalyst systems comprising multiple non-coordinating anion activators and methods for polymerization therewith |
US9139794B2 (en) | 2012-02-03 | 2015-09-22 | Exxonmobil Chemical Patents Inc. | Process for the production of polymeric compositions useful as oil modifiers |
WO2013115912A1 (en) | 2012-02-03 | 2013-08-08 | Exxonmobil Chemical Patents Inc. | Process for the production of polymeric compositions useful as oil modifiers |
US10316176B2 (en) | 2012-02-03 | 2019-06-11 | Exxonmobil Chemical Patents Inc. | Polymer compositions and methods of making them |
US9938413B2 (en) | 2012-12-28 | 2018-04-10 | Dow Global Technologies Llc | Coating composition and articles made therefrom |
EP2922925B1 (de) | 2012-12-28 | 2019-12-04 | Dow Global Technologies LLC | Beschichtungszusammensetzungen |
KR102038178B1 (ko) | 2013-01-18 | 2019-10-29 | 다우 글로벌 테크놀로지스 엘엘씨 | 고분자량 폴리올레핀을 위한 중합 방법 |
US10548367B2 (en) | 2013-01-29 | 2020-02-04 | Exxonmobil Chemical Patents Inc. | Footwear sole comprising a propylene-based elastomer, footwear comprising said sole, and methods of making them |
JP6161716B2 (ja) | 2013-10-18 | 2017-07-12 | 三井化学株式会社 | エチレン・α−オレフィン共重合体を含有する接着剤 |
EP3106475B1 (de) | 2014-02-13 | 2019-08-28 | Mitsui Chemicals, Inc. | Verfahren zur herstellung von ethylen-/alpha-olefin-copolymeren |
WO2015129414A1 (ja) | 2014-02-28 | 2015-09-03 | 三井化学株式会社 | 架橋体とその製造方法および用途、ならびにエチレン系共重合体 |
CN106133006B (zh) | 2014-03-28 | 2018-04-03 | 三井化学株式会社 | 乙烯/α‑烯烃共聚物及润滑油 |
JP6253765B2 (ja) | 2014-03-28 | 2017-12-27 | 三井化学株式会社 | オレフィン系樹脂およびその製造方法 |
WO2016039295A1 (ja) | 2014-09-10 | 2016-03-17 | 三井化学株式会社 | 潤滑油組成物 |
US9944728B2 (en) | 2014-09-11 | 2018-04-17 | Mitsui Chemicals, Inc. | Production method of olefin (co)polymer containing constituent unit derived from 1-butene |
EP3218426B1 (de) | 2014-11-12 | 2022-03-30 | ExxonMobil Chemical Patents Inc. | Reinigung eines weichmachers und verwendung davon in polymerherstellungsverfahren und -anlage |
WO2016093266A1 (ja) | 2014-12-09 | 2016-06-16 | 三井化学株式会社 | プロピレン系樹脂組成物 |
EP3272790B1 (de) | 2015-03-20 | 2023-07-05 | Mitsui Chemicals, Inc. | Thermoplastische elastomerzusammensetzung, verwendung davon, verfahren zur herstellung davon, ethylen/-olefin/nichtkonjugiertes polyencopolymer und verwendung davon |
US10647626B2 (en) | 2016-07-12 | 2020-05-12 | Chevron Phillips Chemical Company Lp | Decene oligomers |
US11162050B2 (en) | 2016-12-27 | 2021-11-02 | Mitsui Chemicals, Inc. | Lubricating oil composition, viscosity modifier for lubricating oil, and additive composition for lubricating oil |
KR102208021B1 (ko) | 2017-01-16 | 2021-01-26 | 미쓰이 가가쿠 가부시키가이샤 | 자동차 기어용 윤활유 조성물 |
WO2019027524A1 (en) | 2017-08-02 | 2019-02-07 | Exxonmobil Chemical Patents Inc. | MULTILAYER FILMS AND METHODS OF MANUFACTURE |
CN111868116B (zh) | 2018-03-20 | 2022-12-09 | 三井化学株式会社 | 乙烯-α-烯烃-非共轭多烯共聚物、其制造方法及用途 |
BR112020019547B1 (pt) | 2018-03-30 | 2023-11-28 | Dow Global Technologies Llc | Processo para polimerizar olefinas |
EP3774941B1 (de) | 2018-03-30 | 2022-11-02 | Dow Global Technologies LLC | Binukleare olefinpolymerisierungsaktivatoren |
KR20200138271A (ko) | 2018-03-30 | 2020-12-09 | 다우 글로벌 테크놀로지스 엘엘씨 | 올레핀 중합 활성화제 |
KR20200142513A (ko) | 2018-03-30 | 2020-12-22 | 다우 글로벌 테크놀로지스 엘엘씨 | 올레핀 중합을 위한 공-촉매로서 고도 가용성 알킬 치환된 카르베늄 보레이트 |
WO2019240899A1 (en) | 2018-06-13 | 2019-12-19 | Exxonmobil Chemical Patents Inc. | Polyolefin blend compositions |
US20200087495A1 (en) | 2018-09-14 | 2020-03-19 | Fina Technology, Inc. | Polyethylene and controlled rheology polypropylene polymer blends and methods of use |
MX2021006769A (es) | 2019-02-20 | 2021-07-15 | Fina Technology | Composiciones de polimero con baja distorsion. |
US11873462B2 (en) | 2019-08-29 | 2024-01-16 | Mitsui Chemicals, Inc. | Lubricating oil composition |
WO2022232123A1 (en) | 2021-04-26 | 2022-11-03 | Fina Technology, Inc. | Thin single-site catalyzed polymer sheets |
Family Cites Families (15)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
PL276385A1 (en) * | 1987-01-30 | 1989-07-24 | Exxon Chemical Patents Inc | Method for polymerization of olefines,diolefins and acetylene unsaturated compounds |
US5198401A (en) * | 1987-01-30 | 1993-03-30 | Exxon Chemical Patents Inc. | Ionic metallocene catalyst compositions |
IL85097A (en) * | 1987-01-30 | 1992-02-16 | Exxon Chemical Patents Inc | Catalysts based on derivatives of a bis(cyclopentadienyl)group ivb metal compound,their preparation and their use in polymerization processes |
US4794096A (en) * | 1987-04-03 | 1988-12-27 | Fina Technology, Inc. | Hafnium metallocene catalyst for the polymerization of olefins |
US4975403A (en) * | 1987-09-11 | 1990-12-04 | Fina Technology, Inc. | Catalyst systems for producing polyolefins having a broad molecular weight distribution |
US5162278A (en) * | 1988-07-15 | 1992-11-10 | Fina Technology, Inc. | Non-bridged syndiospecific metallocene catalysts and polymerization process |
US5155080A (en) * | 1988-07-15 | 1992-10-13 | Fina Technology, Inc. | Process and catalyst for producing syndiotactic polyolefins |
US4892851A (en) * | 1988-07-15 | 1990-01-09 | Fina Technology, Inc. | Process and catalyst for producing syndiotactic polyolefins |
EP0423100A3 (en) * | 1989-10-10 | 1991-08-07 | Fina Technology, Inc. | Process and catalyst for producing syndiotactic polymers |
DE69018376T3 (de) * | 1989-10-30 | 2002-05-16 | Fina Technology | Herstellung von Metallocenkatalysatoren für Olefinpolymerisation. |
WO1992001723A1 (en) * | 1990-07-24 | 1992-02-06 | Mitsui Toatsu Chemicals, Incorporated | CATALYST FOR α-OLEFIN POLYMERIZATION AND PRODUCTION OF POLY-α-OLEFIN THEREWITH |
WO1992009640A1 (en) * | 1990-11-30 | 1992-06-11 | Idemitsu Kosan Co., Ltd. | Process for producing olefinic polymer |
JP2888648B2 (ja) * | 1990-12-28 | 1999-05-10 | 出光興産株式会社 | スチレン系重合体の製造方法及びその触媒 |
JP3194438B2 (ja) * | 1992-01-08 | 2001-07-30 | 出光興産株式会社 | スチレン系重合体の製造方法及びその触媒 |
KR100292158B1 (ko) * | 1992-08-04 | 2001-06-01 | 가지와라 야스시 | 올레핀중합용 촉매 및 올레핀의 중합방법 |
-
1992
- 1992-06-04 US US07/893,522 patent/US5763549A/en not_active Expired - Lifetime
-
1993
- 1993-06-04 JP JP16032593A patent/JP3446059B2/ja not_active Expired - Lifetime
- 1993-06-04 ES ES93870096T patent/ES2124777T3/es not_active Expired - Lifetime
- 1993-06-04 EP EP93870096A patent/EP0573403B1/de not_active Expired - Lifetime
- 1993-06-04 DE DE69321879T patent/DE69321879T2/de not_active Expired - Lifetime
-
1995
- 1995-06-02 US US08/456,639 patent/US5807939A/en not_active Expired - Lifetime
Also Published As
Publication number | Publication date |
---|---|
DE69321879D1 (de) | 1998-12-10 |
EP0573403A2 (de) | 1993-12-08 |
US5763549A (en) | 1998-06-09 |
JPH06220119A (ja) | 1994-08-09 |
US5807939A (en) | 1998-09-15 |
EP0573403B1 (de) | 1998-11-04 |
ES2124777T3 (es) | 1999-02-16 |
EP0573403A3 (en) | 1994-08-17 |
JP3446059B2 (ja) | 2003-09-16 |
Similar Documents
Publication | Publication Date | Title |
---|---|---|
DE69321879T2 (de) | Kationische Metallocenkatalysatoren auf Basis von Triphenylcarbeniumaluminium | |
DE69326463D1 (de) | Olefinpolymerisationskatalysatoren auf basis von uebergangsmetallen | |
DE69503070D1 (de) | Auf borabenzol basierter olefinpolymerisationskatalysator | |
BR9510288A (pt) | Catalisadores de polimerização de azametaloceno | |
DE59409647D1 (de) | Trägerkatalysatoren | |
DE69735068D1 (de) | Heterocyclische Metallocne und Polymerisationskatalysatoren | |
DE9404954U1 (de) | Katalysator | |
DE69518324D1 (de) | Hochaktive polyäthylenkatalysatoren | |
DE69534409D1 (de) | Derivate auf Basis von Polyvinylpyridin | |
DE69514803T2 (de) | Olefinpolymerisationskatalysator | |
NO933427L (no) | Etylenpolymerisasjonsprosess | |
DE69326256T2 (de) | Hochaktive polyethylenkatalysatoren | |
NO891345D0 (no) | Ziegler-natta-katalysator. | |
DE69301547T2 (de) | Elektrisch heizbarer katalytischer Umwandler | |
DE59501207D1 (de) | Geträgerte Metallocen-Katalysatorsysteme | |
DE59506210D1 (de) | Geträgerte Metallocen-Katalysatorsysteme | |
DE69520449T2 (de) | Olefinpolymerisationskatalysator | |
DE9313593U1 (de) | Katalysatoranordnung | |
DE59804442D1 (de) | Katalysatoren auf basis von fulven-metallkomplexen | |
DE59304643D1 (de) | Kationische Triazatrimethinfarbstoffe | |
DE69306117T2 (de) | Epoxydierungskatalysator | |
DE59807157D1 (de) | Katalysatorsystem auf Basis von Monoazadien-Metallkomplexen | |
DK0665985T3 (da) | Platin-rhodium-jern-katalysator | |
DE69325857D1 (de) | Olefinpolymerisation, Katalysator und Vorprodukt | |
DE69309967D1 (de) | Diarylcarbinol metathesekatalysatoren |
Legal Events
Date | Code | Title | Description |
---|---|---|---|
8364 | No opposition during term of opposition | ||
8328 | Change in the person/name/address of the agent |
Representative=s name: ACKMANN MENGES PATENT- UND RECHTSANWAELTE, 80469 M |
|
R082 | Change of representative |
Ref document number: 573403 Country of ref document: EP Representative=s name: SCHUMACHER & WILLSAU PATENTANWALTSGESELLSCHAFT, DE |