DE69507522T2 - Blockcopolymere aus monovinylaromatischem Monomer und konjugiertem Dien - Google Patents

Blockcopolymere aus monovinylaromatischem Monomer und konjugiertem Dien

Info

Publication number
DE69507522T2
DE69507522T2 DE69507522T DE69507522T DE69507522T2 DE 69507522 T2 DE69507522 T2 DE 69507522T2 DE 69507522 T DE69507522 T DE 69507522T DE 69507522 T DE69507522 T DE 69507522T DE 69507522 T2 DE69507522 T2 DE 69507522T2
Authority
DE
Germany
Prior art keywords
conjugated diene
initiator
block copolymers
aromatic monomer
monovinyl aromatic
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Expired - Fee Related
Application number
DE69507522T
Other languages
English (en)
Other versions
DE69507522D1 (de
Inventor
Craig D Deporter
Ralph C Farrar
Nathan A Stacy
George A Moczygemba
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Phillips Petroleum Co
Original Assignee
Phillips Petroleum Co
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Phillips Petroleum Co filed Critical Phillips Petroleum Co
Publication of DE69507522D1 publication Critical patent/DE69507522D1/de
Application granted granted Critical
Publication of DE69507522T2 publication Critical patent/DE69507522T2/de
Anticipated expiration legal-status Critical
Expired - Fee Related legal-status Critical Current

Links

Classifications

    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F297/00—Macromolecular compounds obtained by successively polymerising different monomer systems using a catalyst of the ionic or coordination type without deactivating the intermediate polymer
    • C08F297/02—Macromolecular compounds obtained by successively polymerising different monomer systems using a catalyst of the ionic or coordination type without deactivating the intermediate polymer using a catalyst of the anionic type
    • C08F297/04—Macromolecular compounds obtained by successively polymerising different monomer systems using a catalyst of the ionic or coordination type without deactivating the intermediate polymer using a catalyst of the anionic type polymerising vinyl aromatic monomers and conjugated dienes
    • C08F297/044—Macromolecular compounds obtained by successively polymerising different monomer systems using a catalyst of the ionic or coordination type without deactivating the intermediate polymer using a catalyst of the anionic type polymerising vinyl aromatic monomers and conjugated dienes using a coupling agent
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F297/00—Macromolecular compounds obtained by successively polymerising different monomer systems using a catalyst of the ionic or coordination type without deactivating the intermediate polymer
    • C08F297/02—Macromolecular compounds obtained by successively polymerising different monomer systems using a catalyst of the ionic or coordination type without deactivating the intermediate polymer using a catalyst of the anionic type
    • C08F297/04—Macromolecular compounds obtained by successively polymerising different monomer systems using a catalyst of the ionic or coordination type without deactivating the intermediate polymer using a catalyst of the anionic type polymerising vinyl aromatic monomers and conjugated dienes
DE69507522T 1994-03-23 1995-03-22 Blockcopolymere aus monovinylaromatischem Monomer und konjugiertem Dien Expired - Fee Related DE69507522T2 (de)

Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
US08/216,725 US5438103A (en) 1994-03-23 1994-03-23 Block copolymers of monovinylaromatic and conjugated diene monomers

Publications (2)

Publication Number Publication Date
DE69507522D1 DE69507522D1 (de) 1999-03-11
DE69507522T2 true DE69507522T2 (de) 1999-06-24

Family

ID=22808262

Family Applications (1)

Application Number Title Priority Date Filing Date
DE69507522T Expired - Fee Related DE69507522T2 (de) 1994-03-23 1995-03-22 Blockcopolymere aus monovinylaromatischem Monomer und konjugiertem Dien

Country Status (9)

Country Link
US (1) US5438103A (de)
EP (1) EP0673953B1 (de)
JP (1) JPH08143636A (de)
KR (1) KR100373544B1 (de)
AT (1) ATE176251T1 (de)
CA (1) CA2143598C (de)
DE (1) DE69507522T2 (de)
ES (1) ES2127957T3 (de)
TW (1) TW382633B (de)

Families Citing this family (52)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CA2134026C (en) * 1993-11-15 1998-06-09 William J. Trepka Tapered block copolymers of monovinylarenes and conjugated dienes
CN1036346C (zh) * 1995-08-04 1997-11-05 中国石油化工总公司 丁苯嵌段共聚物热塑弹性体及制法
CN1037848C (zh) * 1995-08-04 1998-03-25 北京燕山石油化工公司研究院 丁苯嵌段共聚物的制造方法
US6835778B2 (en) * 1995-08-29 2004-12-28 Chevron Phillips Chemical Company Lp Conjugated diene/monovinylarene block copolymers blends
US6096828A (en) * 1995-08-29 2000-08-01 Phillips Petroleum Company Conjugated diene/monovinylarene block copolymers, methods for preparing same, and polymer blends
US6143832A (en) * 1997-05-22 2000-11-07 Nippon Zeon Co., Ltd. Aromatic vinyl-conjugated diene block copolymer and production process thereof
US6359075B1 (en) * 2001-01-09 2002-03-19 Bridgestone/Firestone, Inc. Means of producing high diblock content thermoplastic elastomers via chain transfer
US6956084B2 (en) * 2001-10-04 2005-10-18 Bridgestone Corporation Nano-particle preparation and applications
KR100452813B1 (ko) * 2002-05-15 2004-10-14 금호석유화학 주식회사 2조성 선형 블락 공중합체， 그 제조방법 및 용도
KR100458169B1 (ko) * 2002-07-26 2004-11-20 금호석유화학 주식회사 비대칭 다중블록 ｓｂｓ 중합체 및 이의 제조 방법
US20040115381A1 (en) * 2002-12-12 2004-06-17 Chevron Phillips Chemical Company, Lp Method for manufacturing articles with materials containing tapered polymers
US7576155B2 (en) 2002-12-18 2009-08-18 Bridgestone Corporation Method for clay exfoliation, compositions therefore, and modified rubber containing same
US6875818B2 (en) 2003-01-16 2005-04-05 Bridgestone Corporation Polymer nano-strings
CN100386353C (zh) * 2003-03-19 2008-05-07 电气化学工业株式会社 含有支链状嵌段共聚物的嵌段共聚物混合物
US7205370B2 (en) 2004-01-12 2007-04-17 Bridgestone Corporation Polymeric nano-particles of flower-like structure and applications
DK1711558T3 (da) * 2004-01-30 2008-09-22 Renolit Ag Syndiotaktisk polypropylensammensætning omfattende en termoplastisk elastomer
US20050166551A1 (en) * 2004-02-02 2005-08-04 Keane J. A. Multilayer high clarity shrink film comprising monovinylarene-conjugated diene copolymer
US7718737B2 (en) 2004-03-02 2010-05-18 Bridgestone Corporation Rubber composition containing functionalized polymer nanoparticles
US7112369B2 (en) * 2004-03-02 2006-09-26 Bridgestone Corporation Nano-sized polymer-metal composites
US8063142B2 (en) 2004-03-02 2011-11-22 Bridgestone Corporation Method of making nano-particles of selected size distribution
US20050282956A1 (en) 2004-06-21 2005-12-22 Xiaorong Wang Reversible polymer/metal nano-composites and method for manufacturing same
US7998554B2 (en) 2004-07-06 2011-08-16 Bridgestone Corporation Hydrophobic surfaces with nanoparticles
US7572855B2 (en) 2005-01-28 2009-08-11 Bridgestone Corporation Nano-composite and compositions manufactured thereof
US7579398B2 (en) 2005-02-02 2009-08-25 Bridgestone Corporation Nano-composite and compositions therefrom
US7659342B2 (en) 2005-02-03 2010-02-09 Bridgestone Corporation Polymer nano-particle with polar core and method for manufacturing same
US7538159B2 (en) 2005-12-16 2009-05-26 Bridgestone Corporation Nanoparticles with controlled architecture and method thereof
US9061900B2 (en) 2005-12-16 2015-06-23 Bridgestone Corporation Combined use of liquid polymer and polymeric nanoparticles for rubber applications
US7884160B2 (en) 2005-12-19 2011-02-08 Bridgestone Corporation Non-spherical nanoparticles made from living triblock polymer chains
US8288473B2 (en) 2005-12-19 2012-10-16 Bridgestone Corporation Disk-like nanoparticles
US7560510B2 (en) 2005-12-20 2009-07-14 Bridgestone Corporation Nano-sized inorganic metal particles, preparation thereof, and application thereof in improving rubber properties
US7601772B2 (en) 2005-12-20 2009-10-13 Bridgestone Corporation Nano-composite and method thereof
US8877250B2 (en) 2005-12-20 2014-11-04 Bridgestone Corporation Hollow nano-particles and method thereof
US8697775B2 (en) 2005-12-20 2014-04-15 Bridgestone Corporation Vulcanizable nanoparticles having a core with a high glass transition temperature
US7935184B2 (en) 2006-06-19 2011-05-03 Bridgestone Corporation Method of preparing imidazolium surfactants
WO2008014464A2 (en) 2006-07-28 2008-01-31 Bridgestone Corporation Polymeric core-shell nanoparticles with interphase region
US7597959B2 (en) 2006-12-19 2009-10-06 Bridgestone Corporation Core-shell fluorescent nanoparticles
US7649049B2 (en) 2006-12-20 2010-01-19 Bridgestone Corporation Rubber composition containing a polymer nanoparticle
US7829624B2 (en) 2007-06-29 2010-11-09 Bridgestone Corporation One-pot synthesis of nanoparticles and liquid polymer for rubber applications
KR101116750B1 (ko) * 2008-10-31 2012-02-22 금호석유화학 주식회사 비대칭 스타 폴리머의 제조 방법
US8846819B2 (en) 2008-12-31 2014-09-30 Bridgestone Corporation Core-first nanoparticle formation process, nanoparticle, and composition
US9062144B2 (en) 2009-04-03 2015-06-23 Bridgestone Corporation Hairy polymeric nanoparticles with first and second shell block polymer arms
US20100272975A1 (en) * 2009-04-23 2010-10-28 Chevron Phillips Chemical Company Lp System and method for the production and use of lamination films
US9115222B2 (en) 2009-12-29 2015-08-25 Bridgestone Corporation Well defined, highly crosslinked nanoparticles and method for making same
US9428604B1 (en) 2011-12-30 2016-08-30 Bridgestone Corporation Nanoparticle fillers and methods of mixing into elastomers
JP6099637B2 (ja) 2012-05-08 2017-03-22 デンカ株式会社 ブロック共重合体組成物、およびシート
US9441090B1 (en) * 2015-03-12 2016-09-13 Chevron Phillips Chemical Company Lp Methods for controlling hardness of styrene-butadiene block copolymers
US9598524B1 (en) 2015-09-18 2017-03-21 Chevron Phillips Chemical Company Lp Styrene-butadiene block copolymers with a terminal butadiene block for tubing applications
US9540475B2 (en) 2015-03-12 2017-01-10 Chevron Phillips Chemical Company Lp Styrene-butadiene block copolymers for tubing applications
US9738781B2 (en) 2015-09-03 2017-08-22 Ineos Styrolution Group Gmbh Blends of styrene-butadiene block copolymer with styrenic thermoplastic elastomers for tubing applications
US9828455B2 (en) 2016-02-24 2017-11-28 Ineos Styrolution Group Gmbh Styrene-butadiene block copolymers with an internal butadiene block for tubing applications
US10023676B2 (en) 2016-02-24 2018-07-17 Ineos Styrolution Group Gmbh Styrene-butadiene block copolymers with an internal butadiene block for tubing applications
GB201905379D0 (en) 2019-04-16 2019-05-29 Univ Durham Method of epoxidation

Family Cites Families (14)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US3670054A (en) * 1969-10-29 1972-06-13 Shell Oil Co Block copolymers having reduced solvent sensitivity
US3725368A (en) * 1970-01-19 1973-04-03 Lithium Corp Preparation of polymers
US4004070A (en) * 1970-09-28 1977-01-18 Phillips Petroleum Company Viscosity reduction of organopolylithium-initiated polymer solutions
US3937760A (en) * 1974-04-29 1976-02-10 The Firestone Tire & Rubber Company Process for producing multiblock copolymer and products produced thereby
US4133845A (en) * 1974-12-05 1979-01-09 Bayer Aktiengesellschaft Polysegment copolymers
US4248982A (en) * 1979-04-30 1981-02-03 Arco Polymers, Inc. Clear impact resistant thermoplastic star-block copolymers
US4285751A (en) * 1979-05-10 1981-08-25 W. R. Grace & Co. Method of forming an improved battery separator
US4297451A (en) * 1979-07-10 1981-10-27 Phillips Petroleum Company Dienyllithium initiated polymers
US4584346A (en) * 1984-02-29 1986-04-22 Phillips Petroleum Company Craze-resistant transparent resinous polymodal block copolymers
IT1196517B (it) * 1986-07-17 1988-11-16 Montedipe Spa Copolimeri a blocco radiali e bimodali aventi ottime proprieta' ottiche e reistenza agli urti e processo per la loro preparazione
CA2028410C (en) * 1990-01-02 1996-09-17 William J. Trepka Tapered block styrene/butadiene copolymers
US5319033A (en) * 1990-01-02 1994-06-07 Phillips Petroleum Company Tapered block monovinyl aromatic/conjugated diene copolymer
US5256736A (en) * 1991-05-08 1993-10-26 Phillips Petroleum Company Tapered block copolymers of conjugated dienes and monovinylarenes
US5290875A (en) * 1992-11-30 1994-03-01 Phillips Petroleum Company Conjugated diene/monovinylarene block copolymers with multiple tapered blocks

Also Published As

Publication number Publication date
JPH08143636A (ja) 1996-06-04
DE69507522D1 (de) 1999-03-11
KR950032340A (ko) 1995-12-20
TW382633B (en) 2000-02-21
EP0673953A1 (de) 1995-09-27
CA2143598C (en) 2000-01-11
ATE176251T1 (de) 1999-02-15
KR100373544B1 (ko) 2003-04-26
ES2127957T3 (es) 1999-05-01
CA2143598A1 (en) 1995-09-24
US5438103A (en) 1995-08-01
EP0673953B1 (de) 1999-01-27

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Legal Events

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8339 Ceased/non-payment of the annual fee