DE69528781T2 - Biscyclopentadienyl-Dien Komplexe, ihre Herstellung und diese enthaltende Katalysatorzusammensetzungen - Google Patents

Biscyclopentadienyl-Dien Komplexe, ihre Herstellung und diese enthaltende Katalysatorzusammensetzungen

Info

Publication number
DE69528781T2
DE69528781T2 DE69528781T DE69528781T DE69528781T2 DE 69528781 T2 DE69528781 T2 DE 69528781T2 DE 69528781 T DE69528781 T DE 69528781T DE 69528781 T DE69528781 T DE 69528781T DE 69528781 T2 DE69528781 T2 DE 69528781T2
Authority
DE
Germany
Prior art keywords
biscyclopentadienyl
preparation
compositions containing
catalyst compositions
diene complexes
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Expired - Lifetime
Application number
DE69528781T
Other languages
English (en)
Other versions
DE69528781D1 (de
Inventor
Francis J Timmers
David D Devore
James C Stevens
Robert K Rosen
Jasson T Patton
David R Neithamer
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Dow Global Technologies LLC
Original Assignee
Dow Global Technologies LLC
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Family has litigation
First worldwide family litigation filed litigation Critical https://patents.darts-ip.com/?family=26962891&utm_source=google_patent&utm_medium=platform_link&utm_campaign=public_patent_search&patent=DE69528781(T2) "Global patent litigation dataset” by Darts-ip is licensed under a Creative Commons Attribution 4.0 International License.
Priority claimed from US08/481,791 external-priority patent/US6465384B1/en
Application filed by Dow Global Technologies LLC filed Critical Dow Global Technologies LLC
Publication of DE69528781D1 publication Critical patent/DE69528781D1/de
Application granted granted Critical
Publication of DE69528781T2 publication Critical patent/DE69528781T2/de
Anticipated expiration legal-status Critical
Expired - Lifetime legal-status Critical Current

Links

Classifications

    • CCHEMISTRY; METALLURGY
    • C07ORGANIC CHEMISTRY
    • C07FACYCLIC, CARBOCYCLIC OR HETEROCYCLIC COMPOUNDS CONTAINING ELEMENTS OTHER THAN CARBON, HYDROGEN, HALOGEN, OXYGEN, NITROGEN, SULFUR, SELENIUM OR TELLURIUM
    • C07F17/00Metallocenes
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08FMACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F10/00Homopolymers and copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08FMACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F4/00Polymerisation catalysts
    • C08F4/42Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors
    • C08F4/44Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides
    • C08F4/60Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides together with refractory metals, iron group metals, platinum group metals, manganese, rhenium technetium or compounds thereof
    • C08F4/62Refractory metals or compounds thereof
    • C08F4/64Titanium, zirconium, hafnium or compounds thereof
    • C08F4/659Component covered by group C08F4/64 containing a transition metal-carbon bond
    • C08F4/65908Component covered by group C08F4/64 containing a transition metal-carbon bond in combination with an ionising compound other than alumoxane, e.g. (C6F5)4B-X+
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08FMACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F4/00Polymerisation catalysts
    • C08F4/42Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors
    • C08F4/44Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides
    • C08F4/60Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides together with refractory metals, iron group metals, platinum group metals, manganese, rhenium technetium or compounds thereof
    • C08F4/62Refractory metals or compounds thereof
    • C08F4/64Titanium, zirconium, hafnium or compounds thereof
    • C08F4/659Component covered by group C08F4/64 containing a transition metal-carbon bond
    • C08F4/65912Component covered by group C08F4/64 containing a transition metal-carbon bond in combination with an organoaluminium compound
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08FMACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F4/00Polymerisation catalysts
    • C08F4/42Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors
    • C08F4/44Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides
    • C08F4/60Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides together with refractory metals, iron group metals, platinum group metals, manganese, rhenium technetium or compounds thereof
    • C08F4/62Refractory metals or compounds thereof
    • C08F4/64Titanium, zirconium, hafnium or compounds thereof
    • C08F4/659Component covered by group C08F4/64 containing a transition metal-carbon bond
    • C08F4/65916Component covered by group C08F4/64 containing a transition metal-carbon bond supported on a carrier, e.g. silica, MgCl2, polymer
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08FMACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F4/00Polymerisation catalysts
    • C08F4/42Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors
    • C08F4/44Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides
    • C08F4/60Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides together with refractory metals, iron group metals, platinum group metals, manganese, rhenium technetium or compounds thereof
    • C08F4/62Refractory metals or compounds thereof
    • C08F4/64Titanium, zirconium, hafnium or compounds thereof
    • C08F4/659Component covered by group C08F4/64 containing a transition metal-carbon bond
    • C08F4/6592Component covered by group C08F4/64 containing a transition metal-carbon bond containing at least one cyclopentadienyl ring, condensed or not, e.g. an indenyl or a fluorenyl ring
    • C08F4/65922Component covered by group C08F4/64 containing a transition metal-carbon bond containing at least one cyclopentadienyl ring, condensed or not, e.g. an indenyl or a fluorenyl ring containing at least two cyclopentadienyl rings, fused or not
    • YGENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y10TECHNICAL SUBJECTS COVERED BY FORMER USPC
    • Y10STECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y10S526/00Synthetic resins or natural rubbers -- part of the class 520 series
    • Y10S526/901Monomer polymerized in vapor state in presence of transition metal containing catalyst
    • YGENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y10TECHNICAL SUBJECTS COVERED BY FORMER USPC
    • Y10STECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y10S526/00Synthetic resins or natural rubbers -- part of the class 520 series
    • Y10S526/943Polymerization with metallocene catalysts
DE69528781T 1994-08-02 1995-07-14 Biscyclopentadienyl-Dien Komplexe, ihre Herstellung und diese enthaltende Katalysatorzusammensetzungen Expired - Lifetime DE69528781T2 (de)

Applications Claiming Priority (2)

Application Number Priority Date Filing Date Title
US28492594A 1994-08-02 1994-08-02
US08/481,791 US6465384B1 (en) 1994-08-02 1995-06-07 Biscyclopentadienyl diene complexes

Publications (2)

Publication Number Publication Date
DE69528781D1 DE69528781D1 (de) 2002-12-12
DE69528781T2 true DE69528781T2 (de) 2003-07-03

Family

ID=26962891

Family Applications (2)

Application Number Title Priority Date Filing Date
DE69511707T Expired - Lifetime DE69511707T3 (de) 1994-08-02 1995-07-14 Biscyclopentodienyl-dien komplexe
DE69528781T Expired - Lifetime DE69528781T2 (de) 1994-08-02 1995-07-14 Biscyclopentadienyl-Dien Komplexe, ihre Herstellung und diese enthaltende Katalysatorzusammensetzungen

Family Applications Before (1)

Application Number Title Priority Date Filing Date
DE69511707T Expired - Lifetime DE69511707T3 (de) 1994-08-02 1995-07-14 Biscyclopentodienyl-dien komplexe

Country Status (21)

Country Link
US (3) US5972822A (de)
EP (1) EP0775148B2 (de)
JP (1) JP3996184B2 (de)
CN (3) CN1058015C (de)
AT (2) ATE183748T1 (de)
AU (1) AU693578B2 (de)
BR (1) BR9508889A (de)
CA (1) CA2195789C (de)
CZ (1) CZ31697A3 (de)
DE (2) DE69511707T3 (de)
ES (2) ES2182403T3 (de)
FI (1) FI970429A0 (de)
HU (1) HU225300B1 (de)
IL (1) IL114790A (de)
MY (1) MY113182A (de)
NO (1) NO970441L (de)
NZ (1) NZ290066A (de)
PL (1) PL184500B1 (de)
RU (1) RU2135508C1 (de)
TW (1) TW449604B (de)
WO (1) WO1996004290A1 (de)

Families Citing this family (140)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
DE4420456A1 (de) * 1994-06-13 1995-12-14 Hoechst Ag Übergangsmetallverbindung
ATE411343T1 (de) * 1994-06-13 2008-10-15 Basell Polyolefine Gmbh Uebergangsmetallverbindung
US5972822A (en) * 1994-08-02 1999-10-26 The Dow Chemical Company Biscyclopentadienyldiene complex containing addition polymerization catalysts
WO1996016094A1 (en) * 1994-11-23 1996-05-30 The Dow Chemical Company Preparation of syndiotactic polyolefins from prochiral olefins
DE4442166A1 (de) * 1994-11-26 1996-05-30 Basf Ag Verfahren zur Herstellung von Polyolefinen mit geringen extrahierbaren Anteilen
US6787618B1 (en) 1995-12-01 2004-09-07 Basell Polypropylen Gmbh Metallocene compound and high molecular weight copolymers of propylene and olefins having two or four to thirty-two carbon atoms
US5854362A (en) * 1995-12-11 1998-12-29 The Dow Chemical Company Supported biscyclopentadienyl metal complexes
US5679816A (en) * 1996-01-03 1997-10-21 The Dow Chemical Company Preparation of biscyclopentadienyl diene complexes
DE19602543A1 (de) * 1996-01-25 1997-07-31 Basf Ag Verfahren zur Herstellung von Polymerisaten von C¶2¶- bis C¶1¶¶0¶-Alkenen in Gegenwart von Metallocenkomplexen mit kationisch funktionalisierten Cyclopentadienylliganden
DE19711339B4 (de) * 1996-03-19 2008-09-11 Denki Kagaku Kogyo K.K. Copolymer aus Ethylen und aromatischer Vinylverbindung, Verfahren zu dessen Herstellung, Formkörper daraus sowie Zusammensetzung umfassend das Copolymer
WO1997035867A1 (en) * 1996-03-27 1997-10-02 The Dow Chemical Company Heterocyclic metal complexes and olefin polymerization process
DE19615953A1 (de) * 1996-04-22 1997-10-23 Basf Ag Verfahren zur Herstellung von Polymerisaten von Alk-1-enen in Gegenwart eines geträgerten Metallocenkatalysatorsystems und eines Antistatikums
EP0854155A4 (de) * 1996-07-31 2002-01-02 Japan Polyolefins Co Ltd Hochkristallines polypropylen
US6140448A (en) * 1996-08-29 2000-10-31 Director-General Of Agency Of Industrial Science And Technology Process for preparing polysilane by catalytic dehydrogenative condensation of organosilane and metal complex catalyst therefor
TW473503B (en) * 1996-09-04 2002-01-21 Dow Chemical Co Substantially random interpolymer comprising Α-olefin/vinyl aromatic monomer and/or hindered aliphatic or cycloaliphatic vinyl or vinylidene monomers, ethylene/styrene copolymer, and process for preparing Α-olefin/vinyl aromatic monomer interpoly
EP0853091A1 (de) 1997-01-13 1998-07-15 Bp Chemicals S.N.C. Verfahren zur Polymerisation
US6252019B1 (en) * 1997-05-13 2001-06-26 Montell Technology Company Bv Process for polymerizing tactioselective polyolefins in condensed phase using hafnocenes
GB9713279D0 (en) * 1997-06-25 1997-08-27 Dow Corning Process for making silyl endblocked polymers
GB9713741D0 (en) * 1997-06-27 1997-09-03 Bp Chem Int Ltd Polymerisation catalysts
DE19728126A1 (de) * 1997-07-02 1999-01-07 Bayer Ag Katalysatorsystem auf Basis von Monoazadien-Metallkomplexen
US7232871B2 (en) * 1997-08-12 2007-06-19 Exxonmobil Chemical Patents Inc. Propylene ethylene polymers and production process
US6921794B2 (en) * 1997-08-12 2005-07-26 Exxonmobil Chemical Patents Inc. Blends made from propylene ethylene polymers
US6635715B1 (en) * 1997-08-12 2003-10-21 Sudhin Datta Thermoplastic polymer blends of isotactic polypropylene and alpha-olefin/propylene copolymers
US6696379B1 (en) 1997-09-19 2004-02-24 The Dow Chemical Company Supported modified alumoxane catalyst activator
GB9800245D0 (en) * 1998-01-07 1998-03-04 Bp Chem Int Ltd Novel polymers
US6017586A (en) * 1998-02-19 2000-01-25 Catalyst Group, Inc. Polymer material and method of making same utilizing inert atmosphere
AR015731A1 (es) * 1998-03-11 2001-05-16 Dow Global Technologies Inc Procedimiento para preparar complejos de metales de formula (l-a-l)md o de los aductos de las bases de lewis de los mismos; complejos de metales de formulamx2d o bases de lewis de los mismos, de aplicacion de dicho procedimiento, y procedimiento para preparar los complejos de dichos compuestos mx2d.
JP2002516358A (ja) * 1998-05-23 2002-06-04 バーゼル、ポリプロピレン、ゲゼルシャフト、ミット、ベシュレンクテル、ハフツング 触媒組成物およびプロピレン重合のためのその使用
KR100581789B1 (ko) * 1998-07-01 2006-05-23 엑손모빌 케미칼 패턴츠 인코포레이티드 프로필렌의 결정성 중합체 및 결정화가능한 중합체를포함하는 탄성 블렌드 조성물
WO2000009515A1 (en) 1998-08-11 2000-02-24 The Dow Chemical Company Catalyst activator composition
JP4435420B2 (ja) 1998-08-17 2010-03-17 ダウ グローバル テクノロジーズ インコーポレーテッド 3配位アルミニウム触媒活性剤組成物
AU3551499A (en) 1998-08-18 2000-03-14 Dow Chemical Company, The Metalloid salt catalyst/activators
CN1240726C (zh) 1998-09-16 2006-02-08 陶氏环球技术公司 淤浆聚合法及聚合物组合物
US6291614B1 (en) 1998-09-16 2001-09-18 The Dow Chemical Company Dinuclear fluoroaryl aluminum alkyl complexes
US6403773B1 (en) 1998-09-30 2002-06-11 Exxon Mobil Chemical Patents Inc. Cationic group 3 catalyst system
CN1134467C (zh) 1998-11-02 2004-01-14 杜邦唐弹性体公司 剪切稀化的乙烯/α-烯烃共聚体及它们的制备
US6479424B1 (en) 1998-12-14 2002-11-12 Bp Corporation North America Inc. Fluxional catalysts and related ligands containing bulky substituents
GB9918668D0 (en) * 1999-08-06 1999-10-13 Bp Chem Int Ltd Polymerisation catalysts
US6313230B1 (en) * 1999-09-21 2001-11-06 Industrial Technology Research Institute Catalyst composition for hydrogenation of conjugated diene based synthetic rubbers
US6673735B1 (en) 1999-11-24 2004-01-06 Dow Global Technologies Inc. Preparation of catalyst compositions
US20020013224A1 (en) * 2000-02-08 2002-01-31 Diamond Gary M. Catalysts, metal complexes, compositions and arrays containing erbium
ATE409192T1 (de) * 2000-03-01 2008-10-15 Shell Int Research Selektive, katalytische und thermische funktionalisierung von sekundären oder aromatischen c-h bindungen in zyklischen kohlenwasserstoffen
US6451937B1 (en) 2000-03-01 2002-09-17 Shell Oil Company Selective, catalytic, thermal functionalization of primary C-H hydrocarbon bonds
WO2001092348A2 (en) * 2000-05-31 2001-12-06 E.I. Du Pont De Nemours And Company Polymerization of olefins
US7078164B1 (en) 2000-06-19 2006-07-18 Symyx Technologies, Inc. High throughput screen for identifying polymerization catalysts from potential catalysts
DE60117198T2 (de) * 2000-06-27 2006-07-27 Saudi Basic Industries Corp. (Sabic) Verfahren für die Herstellung von Olefinen durch oxidative Dehydrierung
US6380330B1 (en) 2000-06-30 2002-04-30 Exxonmobil Chemical Patents Inc. Metallocene compositions
US6376412B1 (en) 2000-06-30 2002-04-23 Exxonmobil Chemical Patents Inc. Metallocene compositions
US6376408B1 (en) 2000-06-30 2002-04-23 Exxonmobil Chemical Patents Inc. Metallocene compositions
US6376413B1 (en) 2000-06-30 2002-04-23 Exxonmobil Chemical Patents Inc. Metallocene compositions
US6376627B1 (en) 2000-06-30 2002-04-23 Exxonmobil Chemical Patents Inc. Metallocene compositions
US6376409B1 (en) 2000-06-30 2002-04-23 Exxonmobil Chemical Patents Inc. Metallocene compositions
US6380120B1 (en) 2000-06-30 2002-04-30 Exxonmobil Chemical Patents Inc. Metallocene compositions
US6376411B1 (en) 2000-06-30 2002-04-23 Exxonmobil Chemical Patents Inc. Metallocene compositions
US7122498B2 (en) 2000-06-30 2006-10-17 Exxonmobil Chemical Patents Inc. Metallocenes and catalyst compositions derived therefrom
US6380124B1 (en) 2000-06-30 2002-04-30 Exxonmobil Chemical Patents Inc. Metallocene compositions
US6399723B1 (en) 2000-06-30 2002-06-04 Exxonmobil Chemical Patents Inc. Metallocene compositions
US6380334B1 (en) 2000-06-30 2002-04-30 Exxonmobil Chemical Patents Inc. Metallocene compositions
US6870016B1 (en) 2000-06-30 2005-03-22 Exxonmobil Chemical Patents Inc. Polymerization process and polymer composition
US6376410B1 (en) 2000-06-30 2002-04-23 Exxonmobil Chemical Patents Inc. Metallocene compositions
US6380121B1 (en) 2000-06-30 2002-04-30 Exxonmobil Chemical Patents Inc. Metallocene compositions
US6380122B1 (en) 2000-06-30 2002-04-30 Exxonmobil Chemical Patents Inc. Metallocene compositions
US6376407B1 (en) 2000-06-30 2002-04-23 Exxonmobil Chemical Patents Inc. Metallocene compositions
US6414095B1 (en) 2000-06-30 2002-07-02 Exxon Mobil Chemical Patents Inc. Metallocene compositions
US6380331B1 (en) 2000-06-30 2002-04-30 Exxonmobil Chemical Patents Inc. Metallocene compositions
US6380123B1 (en) 2000-06-30 2002-04-30 Exxonmobil Chemical Patents Inc. Metallocene compositions
GB0023662D0 (en) 2000-09-27 2000-11-08 Borealis Tech Oy Supported catalyst
US6943133B2 (en) * 2000-10-20 2005-09-13 Univation Technologies, Llc Diene functionalized catalyst supports and supported catalyst compositions
US6900321B2 (en) 2000-11-07 2005-05-31 Symyx Technologies, Inc. Substituted pyridyl amine complexes, and catalysts
ATE485319T1 (de) 2001-04-12 2010-11-15 Exxonmobil Chem Patents Inc Verfahren zur polymerisation von propylen und ethylen in lösung
US6979530B2 (en) * 2001-05-21 2005-12-27 Applera Corporation Peptide conjugates and fluorescence detection methods for intracellular caspase assay
ATE384086T1 (de) * 2001-06-15 2008-02-15 Dow Global Technologies Inc Verzweigte polymere auf alpha-olefin basis
KR100440482B1 (ko) * 2001-07-11 2004-07-14 주식회사 엘지화학 새로운 다중핵 반쪽 메탈로센 촉매
US6906160B2 (en) 2001-11-06 2005-06-14 Dow Global Technologies Inc. Isotactic propylene copolymer fibers, their preparation and use
US6943215B2 (en) * 2001-11-06 2005-09-13 Dow Global Technologies Inc. Impact resistant polymer blends of crystalline polypropylene and partially crystalline, low molecular weight impact modifiers
US7122689B2 (en) * 2001-11-06 2006-10-17 Symyx Technologies, Inc. Titanium substituted pyridyl amine complexes, catalysts and processes for polymerizing ethylene and stryene
US6927256B2 (en) 2001-11-06 2005-08-09 Dow Global Technologies Inc. Crystallization of polypropylene using a semi-crystalline, branched or coupled nucleating agent
EP1444276A1 (de) * 2001-11-06 2004-08-11 Dow Global Technologies, Inc. Isotaktische propylencopolymere, ihre herstellung und ihre verwendung
US6960635B2 (en) * 2001-11-06 2005-11-01 Dow Global Technologies Inc. Isotactic propylene copolymers, their preparation and use
US6794514B2 (en) * 2002-04-12 2004-09-21 Symyx Technologies, Inc. Ethylene-styrene copolymers and phenol-triazole type complexes, catalysts, and processes for polymerizing
DE60335459D1 (de) * 2002-04-24 2011-02-03 Symyx Solutions Inc Verbrückte bi-aromatische liganden, komplexe, katalysatoren, verfahren zur polymerisierung und entstehende polymere
US7091292B2 (en) * 2002-04-24 2006-08-15 Symyx Technologies, Inc. Bridged bi-aromatic catalysts, complexes, and methods of using the same
US7060848B2 (en) * 2002-04-24 2006-06-13 Symyx Technologies, Inc. Bridged bi-aromatic catalysts, complexes, and methods of using the same
EP1357152A1 (de) 2002-04-26 2003-10-29 Solvay Polyolefins Europe-Belgium (Société Anonyme) Polymer für Kraftstofftanks
EP1554320B2 (de) * 2002-10-02 2011-07-13 Dow Global Technologies LLC Flüssige und gelartige niedermolekulare ethylenpolymere
ES2394304T3 (es) 2002-10-15 2013-01-30 Exxonmobil Chemical Patents, Inc. Sistema de múltiples catalizadores para la polimerización de olefinas y polímeros producidos a partir de éstos
US7223822B2 (en) 2002-10-15 2007-05-29 Exxonmobil Chemical Patents Inc. Multiple catalyst and reactor system for olefin polymerization and polymers produced therefrom
EP1964884A1 (de) 2002-10-17 2008-09-03 Dow Global Technologies Inc. Hoch gefüllte Polymerzusammensetzungen
US7579407B2 (en) * 2002-11-05 2009-08-25 Dow Global Technologies Inc. Thermoplastic elastomer compositions
US7459500B2 (en) * 2002-11-05 2008-12-02 Dow Global Technologies Inc. Thermoplastic elastomer compositions
KR100497172B1 (ko) * 2002-11-11 2005-06-28 주식회사 엘지화학 양쪽 메탈로센 유도체 화합물을 리간드로 가진 다중핵반쪽 메탈로센 촉매 및 이를 이용한 스티렌 중합체의제조방법
DE60313362T2 (de) * 2002-12-17 2007-08-16 Ineos Europe Ltd., Lyndhurst Geträgerter olefin polymerisationskatalysator
CA2536339C (en) 2003-08-19 2013-01-08 Dow Global Technologies Inc. Interpolymers suitable for use in hot melt adhesives and processes to prepare same
DE602005026514D1 (de) * 2004-04-30 2011-04-07 Dow Global Technologies Inc Verbesserter vliesstoff und verbesserte fasern
GB0411742D0 (en) 2004-05-26 2004-06-30 Exxonmobil Chem Patents Inc Transition metal compounds for olefin polymerization and oligomerization
CN102321201B (zh) 2004-06-16 2013-06-26 陶氏环球技术有限责任公司 选择聚合改性剂的方法
DE102004039911A1 (de) * 2004-08-18 2006-02-23 Goldschmidt Gmbh Katalytisches System für die dehydrogenative Kondensation von Polyorganosiloxanen mit Alkoholen und ein Verfahren zur Herstellung von organisch modifizierten Polyorganosiloxanen
US7256296B2 (en) * 2004-09-22 2007-08-14 Symyx Technologies, Inc. Heterocycle-amine ligands, compositions, complexes, and catalysts
US7387980B2 (en) * 2004-09-22 2008-06-17 Symyx Technologies, Inc. Methods of using heterocycle-amine ligands, compositions, complexes, and catalysts
EP1805229A1 (de) 2004-10-28 2007-07-11 Dow Gloval Technologies Inc. Verfahren zur steuerung eines polymerisierungsreaktors
WO2006066126A2 (en) * 2004-12-16 2006-06-22 Symyx Technologies, Inc. Phenol-heterocyclic ligands, metal complexes, and their uses as catalysts
KR20070087670A (ko) * 2004-12-21 2007-08-28 다우 글로벌 테크놀로지스 인크. 폴리프로필렌-기재의 접착제 조성물
EP1731536A1 (de) 2005-06-09 2006-12-13 Innovene Manufacturing France SAS Unterstützte Polymerisationskatalysatoren
RU2008121721A (ru) * 2005-10-31 2009-12-10 Дау Глобал Текнолоджиз Инк. (Us) Эластомерная композиция на основе пропилена
WO2007070041A1 (en) 2005-12-14 2007-06-21 Exxonmobil Chemical Patents Inc. Halogen substituted metallocene compounds for olefin polymerization
AU2006329980A1 (en) 2005-12-16 2007-07-05 Dow Global Technologies Inc. Polydentate heteroatom ligand containing metal complexes, catalysts and methods of making and using the same
EP1820820A1 (de) 2006-02-15 2007-08-22 INEOS Manufacturing Belgium NV Polyethylenzusammensetzung
GB0610667D0 (en) 2006-05-30 2006-07-05 Nova Chem Int Sa Supported polymerization catalysts
EP2041193B1 (de) * 2006-07-05 2010-12-29 Solvay SA Verfahren zur herstellung eines latex eines vinylchloridpolymers
US8281332B2 (en) * 2007-05-02 2012-10-02 Google Inc. Animated video overlays
US7943711B2 (en) * 2007-05-14 2011-05-17 Exxonmobil Chemical Patents Inc. Ethylene elastomer compositions
EP2112173A1 (de) 2008-04-16 2009-10-28 ExxonMobil Chemical Patents Inc. Katalysatorverbindungen und ihre Verwendung
EP2103634A1 (de) 2008-03-20 2009-09-23 ExxonMobil Chemical Patents Inc. Herstellung propylen-basierter polymere
US20090286944A1 (en) * 2008-05-15 2009-11-19 Symyx Technologies, Inc. Select phenol-heterocycle ligands, metal complexes formed therefrom, and their uses as catalysts
EP2196481A1 (de) 2008-12-12 2010-06-16 Total Petrochemicals Research Feluy Herstellung von langkettigem, verzweigtem, isotaktischem Polypropylen
JP5575267B2 (ja) 2009-12-24 2014-08-20 エクソンモービル・ケミカル・パテンツ・インク 新規合成ベースストックの製造方法
US8058461B2 (en) 2010-03-01 2011-11-15 Exxonmobil Chemical Patents Inc. Mono-indenyl transition metal compounds and polymerization therewith
CN102958959B (zh) 2010-07-06 2015-11-25 提克纳有限公司 产生高分子量聚乙烯的方法
EP2591021A2 (de) 2010-07-06 2013-05-15 Ticona GmbH Polyethylen von ultrahohem molekulargewicht sowie seine herstellung und verwendung
KR20130124170A (ko) 2010-07-06 2013-11-13 티코나 게엠베하 고 분자량 폴리에틸렌의 제조 방법
US20130090400A1 (en) 2010-07-06 2013-04-11 Ticona Gmbh Process for producing high molecular weight polyethylene
CN102958960A (zh) 2010-07-06 2013-03-06 提克纳有限公司 成形的高分子量聚乙烯制品、其产生和用途
US8993704B2 (en) 2010-07-06 2015-03-31 Ticona Gmbh High molecular weight polyethylene fibers and membranes, their production and use
US8722819B2 (en) 2010-07-06 2014-05-13 Ticona Gmbh Process for producing high molecular weight polyethylene
EP2813545A1 (de) * 2010-12-03 2014-12-17 Dow Global Technologies LLC Verfahren zur Herstellung von Ethylenpolymerzusammensetzungen
EP2465876A1 (de) 2010-12-15 2012-06-20 INEOS Manufacturing Belgium NV Aktivierung von Trägern
CN103370344A (zh) 2011-01-20 2013-10-23 英尼奥斯商业服务英国有限公司 活化载体
WO2012136644A1 (en) 2011-04-08 2012-10-11 Ineos Europe Ag Laminate comprising a polyolefin layer adhered to a base layer
BR112014014119A2 (pt) 2011-12-14 2017-06-13 Ineos Europe Ag novos polímeros
WO2013093540A1 (en) 2011-12-19 2013-06-27 Ticona Gmbh Process for producing high molecular weight polyethylene
WO2013158225A1 (en) 2012-04-18 2013-10-24 Exxonmobil Chemical Patents Inc. Polyolefin compositions and methods of production thereof
EP2935297B1 (de) 2012-12-21 2019-03-20 ExxonMobil Chemical Patents Inc. Brückenmetallocenverbindungen sowie katalysatorsysteme und polymerisierungsverfahren damit
WO2016006404A1 (ja) * 2014-07-07 2016-01-14 富士フイルム株式会社 非水二次電池用電解液および非水二次電池、これらに用いられる添加剤
US20160236340A1 (en) 2015-02-17 2016-08-18 Snap-On Incorporated Remote Wrench Handle and Accessories
US10647626B2 (en) 2016-07-12 2020-05-12 Chevron Phillips Chemical Company Lp Decene oligomers
US10815255B2 (en) 2017-01-06 2020-10-27 Univation Technologies, Llc Synthesis of benzyloxyphenoxy phenol ligands
BR112019013171B1 (pt) 2017-01-06 2023-03-28 Univation Technologies, Llc Processo de síntese de ligantes de benzilanilinil fenil fenol
US11926802B2 (en) 2021-11-05 2024-03-12 Exxonmobil Chemical Patents Inc. Lubricating oil composition with viscosity modifier based on syndiotactic propylene-based ethylene- propylene copolymers with improved properties
WO2023081010A1 (en) 2021-11-05 2023-05-11 Exxonmobil Chemical Patents Inc. Polypropylene viscosity modifiers and lubricating oils thereof
US20230148328A1 (en) 2021-11-05 2023-05-11 Exxonmobil Chemical Patents Inc. Syndiotactic propylene-based ethylene- propylene copolymers

Family Cites Families (25)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US3242099A (en) * 1964-03-27 1966-03-22 Union Carbide Corp Olefin polymerization catalysts
US4808561A (en) * 1985-06-21 1989-02-28 Exxon Chemical Patents Inc. Supported polymerization catalyst
US5084534A (en) * 1987-06-04 1992-01-28 Exxon Chemical Patents, Inc. High pressure, high temperature polymerization of ethylene
CA1338046C (en) * 1986-09-19 1996-02-06 Howard Curtis Welborn Jr. High pressure high temperature polymerization of ethylene
PL276385A1 (en) * 1987-01-30 1989-07-24 Exxon Chemical Patents Inc Method for polymerization of olefines,diolefins and acetylene unsaturated compounds
US5153157A (en) * 1987-01-30 1992-10-06 Exxon Chemical Patents Inc. Catalyst system of enhanced productivity
US5198401A (en) * 1987-01-30 1993-03-30 Exxon Chemical Patents Inc. Ionic metallocene catalyst compositions
US4912075A (en) * 1987-12-17 1990-03-27 Exxon Chemical Patents Inc. Method for preparing a supported metallocene-alumoxane catalyst for gas phase polymerization
DE3742934A1 (de) * 1987-12-18 1989-06-29 Hoechst Ag Verfahren zur herstellung einer chiralen, stereorigiden metallocen-verbindung
US5008228A (en) * 1988-03-29 1991-04-16 Exxon Chemical Patents Inc. Method for preparing a silica gel supported metallocene-alumoxane catalyst
US5086025A (en) * 1988-03-29 1992-02-04 Exxon Chemical Patents Inc. Method for preparing a silica gel supported metallocene-alumoxane catalyst
US4914253A (en) * 1988-11-04 1990-04-03 Exxon Chemical Patents Inc. Method for preparing polyethylene wax by gas phase polymerization
US5064802A (en) * 1989-09-14 1991-11-12 The Dow Chemical Company Metal complex compounds
JP2545006B2 (ja) * 1990-07-03 1996-10-16 ザ ダウ ケミカル カンパニー 付加重合触媒
US5272236A (en) * 1991-10-15 1993-12-21 The Dow Chemical Company Elastic substantially linear olefin polymers
US5721185A (en) * 1991-06-24 1998-02-24 The Dow Chemical Company Homogeneous olefin polymerization catalyst by abstraction with lewis acids
US5374696A (en) * 1992-03-26 1994-12-20 The Dow Chemical Company Addition polymerization process using stabilized reduced metal catalysts
US5350723A (en) * 1992-05-15 1994-09-27 The Dow Chemical Company Process for preparation of monocyclopentadienyl metal complex compounds and method of use
WO1994000500A1 (en) * 1992-06-26 1994-01-06 Exxon Chemical Patents Inc. Solution phase polymerization process utilizing metallocene catalyst with production of olefin polymers
JP2936189B2 (ja) * 1992-09-09 1999-08-23 東ソー株式会社 有機遷移金属錯体
US5372682A (en) * 1993-06-24 1994-12-13 The Dow Chemical Company Electrochemical preparation of addition polymerization catalysts
US5470993A (en) * 1993-06-24 1995-11-28 The Dow Chemical Company Titanium(II) or zirconium(II) complexes and addition polymerization catalysts therefrom
DE4420456A1 (de) * 1994-06-13 1995-12-14 Hoechst Ag Übergangsmetallverbindung
US5486632A (en) * 1994-06-28 1996-01-23 The Dow Chemical Company Group 4 metal diene complexes and addition polymerization catalysts therefrom
US5972822A (en) * 1994-08-02 1999-10-26 The Dow Chemical Company Biscyclopentadienyldiene complex containing addition polymerization catalysts

Also Published As

Publication number Publication date
RU2135508C1 (ru) 1999-08-27
MX9700816A (es) 1997-09-30
DE69528781D1 (de) 2002-12-12
CN1156997A (zh) 1997-08-13
EP0775148B2 (de) 2003-01-02
MY113182A (en) 2001-12-31
US5972822A (en) 1999-10-26
CN1263894A (zh) 2000-08-23
CN1260350A (zh) 2000-07-19
JPH10503517A (ja) 1998-03-31
US5616664A (en) 1997-04-01
NO970441D0 (no) 1997-01-31
US5527929A (en) 1996-06-18
HUT77589A (hu) 1998-06-29
DE69511707T2 (de) 1999-12-16
IL114790A0 (en) 1995-11-27
ES2137532T3 (es) 1999-12-16
CN1176093C (zh) 2004-11-17
PL318434A1 (en) 1997-06-09
NO970441L (no) 1997-03-26
DE69511707T3 (de) 2003-10-16
PL184500B1 (pl) 2002-11-29
ATE227300T1 (de) 2002-11-15
WO1996004290A1 (en) 1996-02-15
BR9508889A (pt) 1997-09-30
ES2182403T3 (es) 2003-03-01
CA2195789A1 (en) 1996-02-15
FI970429A (fi) 1997-01-31
CZ31697A3 (en) 1997-05-14
FI970429A0 (fi) 1997-01-31
CN1154668C (zh) 2004-06-23
DE69511707D1 (de) 1999-09-30
EP0775148B1 (de) 1999-08-25
AU3009095A (en) 1996-03-04
IL114790A (en) 2002-05-23
ATE183748T1 (de) 1999-09-15
JP3996184B2 (ja) 2007-10-24
AU693578B2 (en) 1998-07-02
TW449604B (en) 2001-08-11
EP0775148A1 (de) 1997-05-28
ES2137532T5 (es) 2003-07-01
NZ290066A (en) 1998-02-26
HU225300B1 (en) 2006-09-28
CN1058015C (zh) 2000-11-01
CA2195789C (en) 2007-03-20

Similar Documents

Publication Publication Date Title
ATE227300T1 (de) Biscyclopentadienyl-dien komplexe, ihre herstellung und diese enthaltende katalysatorzusammensetzungen
CA2192825A1 (en) Group 4 metal diene complexes and addition polymerization catalysts therefrom
MY114551A (en) Metallocenes preparation and use
HU9503780D0 (en) Titanium(ii) or zirconium(ii) complexes and addition polymerization catalysts therefrom
CA2105555A1 (en) Improved catalyst composition
WO1997017380A3 (en) Polymerizable compositions comprising alpha-olefin hydrocarbon monomers and methods of use therefor
WO1994007944A1 (en) Compositions, articles and methods for scavenging oxygen which have improved physical properties
CA2313215A1 (en) Polymerization catalyst systems, their use, their products and articles thereof
MXPA04003409A (es) Composiciones de complejo metalico y su uso como catalizadores para producir polidienos.
CA2229608A1 (en) Substituted indenyl containing metal complexes and olefin polymerization process
ATE211478T1 (de) Nichtaromatische anionische dienylgruppe enthaltende metall (iii) komplexe und diese enthaltende additionspolymerizationskatalysatoren
RU92016286A (ru) Способ получения селективно гидрированных полимеров сопряженных диолефинов
EP0915098A3 (de) Biscyclopentadienyl-Dien Komplexe, ihre Herstellung und diese enthaltende Katalysatorzusammensetzungen
WO1999006448A8 (de) Katalysatoren auf basis von fulven-metallkomplexen
ES2153198T3 (es) Complejos metalicos que contienen itrio y procedimiento de polimerizacion de olefinas.
WO2002020629A3 (de) Katalysatorsystem zur polymerisation von dienen
RU1789519C (ru) Способ изготовлени цветных силикатных изделий
PL358179A1 (en) Use of stannylenes and germylenes as polymerisation catalysts for heterocycles

Legal Events

Date Code Title Description
8364 No opposition during term of opposition