DE69620871T2 - Geträgerter katalysatoraktivator - Google Patents

Geträgerter katalysatoraktivator

Info

Publication number
DE69620871T2
DE69620871T2 DE69620871T DE69620871T DE69620871T2 DE 69620871 T2 DE69620871 T2 DE 69620871T2 DE 69620871 T DE69620871 T DE 69620871T DE 69620871 T DE69620871 T DE 69620871T DE 69620871 T2 DE69620871 T2 DE 69620871T2
Authority
DE
Germany
Prior art keywords
supported catalyst
catalyst activator
activator
supported
catalyst
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Expired - Lifetime
Application number
DE69620871T
Other languages
English (en)
Other versions
DE69620871D1 (de
Inventor
George Ward
Malott Carnahan
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
WR Grace and Co Conn
WR Grace and Co
Original Assignee
WR Grace and Co Conn
WR Grace and Co
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by WR Grace and Co Conn, WR Grace and Co filed Critical WR Grace and Co Conn
Publication of DE69620871D1 publication Critical patent/DE69620871D1/de
Application granted granted Critical
Publication of DE69620871T2 publication Critical patent/DE69620871T2/de
Anticipated expiration legal-status Critical
Expired - Lifetime legal-status Critical Current

Links

Classifications

    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F10/00—Homopolymers and copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F4/00—Polymerisation catalysts
    • C08F4/42—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors
    • C08F4/44—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides
    • C08F4/60—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides together with refractory metals, iron group metals, platinum group metals, manganese, rhenium technetium or compounds thereof
    • C08F4/619—Component covered by group C08F4/60 containing a transition metal-carbon bond
    • C08F4/61908—Component covered by group C08F4/60 containing a transition metal-carbon bond in combination with an ionising compound other than alumoxane, e.g. (C6F5)4B-X+
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F4/00—Polymerisation catalysts
    • C08F4/42—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors
    • C08F4/44—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides
    • C08F4/60—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides together with refractory metals, iron group metals, platinum group metals, manganese, rhenium technetium or compounds thereof
    • C08F4/619—Component covered by group C08F4/60 containing a transition metal-carbon bond
    • C08F4/61916—Component covered by group C08F4/60 containing a transition metal-carbon bond supported on a carrier, e.g. silica, MgCl2, polymer
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F4/00—Polymerisation catalysts
    • C08F4/42—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors
    • C08F4/44—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides
    • C08F4/60—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides together with refractory metals, iron group metals, platinum group metals, manganese, rhenium technetium or compounds thereof
    • C08F4/62—Refractory metals or compounds thereof
    • C08F4/64—Titanium, zirconium, hafnium or compounds thereof
    • C08F4/659—Component covered by group C08F4/64 containing a transition metal-carbon bond
    • C08F4/6592—Component covered by group C08F4/64 containing a transition metal-carbon bond containing at least one cyclopentadienyl ring, condensed or not, e.g. an indenyl or a fluorenyl ring
    • C08F4/65922—Component covered by group C08F4/64 containing a transition metal-carbon bond containing at least one cyclopentadienyl ring, condensed or not, e.g. an indenyl or a fluorenyl ring containing at least two cyclopentadienyl rings, fused or not
    • C08F4/65925—Component covered by group C08F4/64 containing a transition metal-carbon bond containing at least one cyclopentadienyl ring, condensed or not, e.g. an indenyl or a fluorenyl ring containing at least two cyclopentadienyl rings, fused or not two cyclopentadienyl rings being mutually non-bridged
    • Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y10—TECHNICAL SUBJECTS COVERED BY FORMER USPC
    • Y10S—TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y10S526/00—Synthetic resins or natural rubbers -- part of the class 520 series
    • Y10S526/943—Polymerization with metallocene catalysts
DE69620871T 1995-01-25 1996-01-02 Geträgerter katalysatoraktivator Expired - Lifetime DE69620871T2 (de)

Applications Claiming Priority (3)

Application Number Priority Date Filing Date Title
US37820295A 1995-01-25 1995-01-25
US08/544,051 US5939347A (en) 1995-01-25 1995-10-17 Supported catalytic activator
PCT/US1996/000644 WO1996023005A1 (en) 1995-01-25 1996-01-02 A supported catalytic activator

Publications (2)

Publication Number Publication Date
DE69620871D1 DE69620871D1 (de) 2002-05-29
DE69620871T2 true DE69620871T2 (de) 2002-12-12

Family

ID=27008110

Family Applications (1)

Application Number Title Priority Date Filing Date
DE69620871T Expired - Lifetime DE69620871T2 (de) 1995-01-25 1996-01-02 Geträgerter katalysatoraktivator

Country Status (5)

Country Link
US (1) US5939347A (de)
EP (1) EP0805824B1 (de)
AU (1) AU4701796A (de)
DE (1) DE69620871T2 (de)
WO (1) WO1996023005A1 (de)

Families Citing this family (49)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US5384299A (en) * 1987-01-30 1995-01-24 Exxon Chemical Patents Inc. Ionic metallocene catalyst compositions
US6143686A (en) * 1994-08-03 2000-11-07 Exxon Chemical Patents, Inc. Supported ionic catalyst compositions
US7153909B2 (en) 1994-11-17 2006-12-26 Dow Global Technologies Inc. High density ethylene homopolymers and blend compositions
US5885924A (en) * 1995-06-07 1999-03-23 W. R. Grace & Co.-Conn. Halogenated supports and supported activators
PT863919E (pt) * 1995-11-27 2001-04-30 Grace W R & Co Catalisador sobre suporte contendo um activador imobilizado que forma catioes
JP2000517349A (ja) * 1996-03-27 2000-12-26 ザ ダウ ケミカル カンパニー 分散した触媒活性剤による溶液重合法
DE19622207A1 (de) 1996-06-03 1997-12-04 Hoechst Ag Chemische Verbindung
ATE202365T1 (de) * 1996-08-13 2001-07-15 Basell Polyolefine Gmbh Geträgertes katalysatorsystem, verfahren zu seiner herstellung und seine verwendung zur polymerisation von olefinen
ATE325821T1 (de) 1996-08-13 2006-06-15 Basell Polyolefine Gmbh Geträgerte chemische verbindung
US6262200B1 (en) * 1996-08-19 2001-07-17 Northwestern University (Polyfluoroaryl)fluoroanions of aluminum, gallium, and indium of enhanced utility, uses thereof, and products based thereon
US6130302A (en) * 1996-08-19 2000-10-10 Northwestern University Synthesis and use of (polyfluoroaryl)fluoroanions of aluminum, gallium and indium
US6184319B1 (en) * 1996-12-20 2001-02-06 Sumitomo Chemical Company, Limited Olefin polymer, films or sheets made therefrom, and process for the production of olefin polymer
EP0931099A1 (de) * 1997-03-07 1999-07-28 Basell Polyolefine GmbH Verfahren zur herstellung von olefinpolymerisaten mit erhöhtem schmelzpunkt
US6426313B2 (en) * 1997-06-05 2002-07-30 Exxon Mobil Chemical Patents Inc. Polymeric supported catalysts for olefin polymerization
US6228795B1 (en) * 1997-06-05 2001-05-08 Exxon Chemical Patents, Inc. Polymeric supported catalysts
FR2769245B1 (fr) 1997-10-02 1999-10-29 Atochem Elf Sa Support solide activateur des catalyseurs metallocenes en polymerisation des olefines, son procede de preparation, systeme catalytique et procede de polymerisation correspondants
DE19757540A1 (de) * 1997-12-23 1999-06-24 Hoechst Ag Geträgertes Katalysatorsystem zur Polymerisation von Olefinen
US6177375B1 (en) * 1998-03-09 2001-01-23 Pq Corporation High activity olefin polymerization catalysts
US6211312B1 (en) 1998-06-12 2001-04-03 Univation Technologies Olefin polymerization process using activated lewis acid-base complexes
ATE355308T1 (de) * 1998-07-16 2006-03-15 Univation Tech Llc Lewis-säure cokatalysatoren auf aluminium-basis für die olefinpolymerisation
US6368999B1 (en) 1998-08-26 2002-04-09 Exxon Mobil Chemical Patents Inc. Highly active supported catalyst compositions
WO2000015671A1 (en) * 1998-09-16 2000-03-23 The Dow Chemical Company Slurry polymerization process and polymer compositions
US6184171B1 (en) * 1998-10-05 2001-02-06 W.R. Grace & Co. -Conn Supported bidentate and tridentate catalyst compositions and olefin polymerization using same
US6486088B1 (en) 1998-10-23 2002-11-26 Exxonmobil Chemical Patents Inc. High activity carbenium-activated polymerization catalysts
US6239060B1 (en) * 1998-12-31 2001-05-29 Phillips Petroleum Company Supported metallocene catalyst system and method for polymerizing olefins
US6194343B1 (en) * 1999-03-11 2001-02-27 University Of Waterloo Bridged “tethered” metallocenes
DE19917985A1 (de) 1999-04-21 2000-10-26 Targor Gmbh Katalysatorsystem
CA2379917A1 (en) * 1999-07-15 2001-01-25 The Dow Chemical Company High density ethylene homopolymers and blend compositions
US6476164B1 (en) 1999-10-22 2002-11-05 Exxonmobil Chemical Patents Inc. Carbenium cationic complexes suitable for polymerization catalysts
US6475946B1 (en) * 1999-10-22 2002-11-05 Exxonmobil Chemical Patents Inc. Olefin polymerization catalysis with aryl substituted carbenium cationic complexes
US6395847B2 (en) * 1999-11-19 2002-05-28 Exxonmobil Chemical Patents Inc. Supported organometallic catalysts and their use in olefin polymerization
ATE337344T1 (de) * 1999-11-19 2006-09-15 Exxonmobil Chem Patents Inc Vorbereitung eines geträgerten katalysatorsystems zur polymerisation von olefinen
US6822057B2 (en) * 1999-12-09 2004-11-23 Exxon Mobil Chemical Patents Inc. Olefin polymerization catalysts derived from Group-15 cationic compounds and processes using them
US6489480B2 (en) 1999-12-09 2002-12-03 Exxonmobil Chemical Patents Inc. Group-15 cationic compounds for olefin polymerization catalysts
ATE395368T1 (de) * 1999-12-20 2008-05-15 Exxonmobil Chem Patents Inc Verfahren zur herstellung von polyolefinen mittels verträgter ionischer katalysatoren
DE19962814A1 (de) 1999-12-23 2001-06-28 Targor Gmbh Neues Katalysatorsystem und dessen Verwendung
DE19962910A1 (de) 1999-12-23 2001-07-05 Targor Gmbh Chemische Verbindung, Verfahren zu deren Herstellung und deren Verwendung in Katalysatorsystemen zur Herstellung von Polyolefinen
SG83828A1 (en) 1999-12-27 2001-10-16 Sumitomo Chemical Co Catalyst for addition polymerization, and process for producing addition polymer with the same
US6495484B1 (en) * 2000-08-28 2002-12-17 Univation Technologies, Llc Catalyst system and its use in a polymerization process
JP2004510037A (ja) * 2000-09-26 2004-04-02 ビーピー　ケミカルズ　リミテッド 支持触媒系
US6632770B2 (en) * 2000-12-22 2003-10-14 Univation Technologies, Llc Catalyst system and its use in a polymerization process
JP2003128720A (ja) * 2001-10-19 2003-05-08 Sunallomer Ltd オレフィン重合用固体助触媒成分、オレフィン重合用触媒およびイオン含有化合物
JP2005538245A (ja) 2002-07-15 2005-12-15 バーゼル、ポリオレフィン、ゲゼルシャフト、ミット、ベシュレンクテル、ハフツング 担体を有する触媒組成物の製造方法
US20050209096A1 (en) * 2002-08-20 2005-09-22 Jacobsen Grant B Supported polymerisation catalysts
US7309677B2 (en) * 2002-08-20 2007-12-18 B.P. Chemicals Limited Supported polymerisation catalysts
CA2405241C (en) * 2002-09-24 2011-07-26 Nova Chemicals Corporation Olefin polymerization catalyst system
BRPI0418117B1 (pt) 2003-12-23 2015-10-13 Basell Polyolefine Gmbh preparação de cocatalisadores suportados
US7217676B2 (en) * 2004-01-16 2007-05-15 Exxon Mobil Chemical Patents Inc. Hydrophobization and silica for supported catalyst
CN101687188A (zh) * 2007-07-13 2010-03-31 埃克森美孚化学专利公司 制备负载的甲硅烷基封闭的二氧化硅结合的阴离子活化剂及相关催化剂的方法

Family Cites Families (16)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US5198401A (en) * 1987-01-30 1993-03-30 Exxon Chemical Patents Inc. Ionic metallocene catalyst compositions
US5241025A (en) * 1987-01-30 1993-08-31 Exxon Chemical Patents Inc. Catalyst system of enhanced productivity
US5202398A (en) * 1987-06-05 1993-04-13 Hoechst Aktiengesellschaft Process for the preparation of a 1-olefin polymer
US5057475A (en) * 1989-09-13 1991-10-15 Exxon Chemical Patents Inc. Mono-Cp heteroatom containing group IVB transition metal complexes with MAO: supported catalyst for olefin polymerization
WO1991009882A1 (en) * 1990-01-02 1991-07-11 Exxon Chemical Patents Inc. Supported ionic metallocene catalysts for olefin polymerization
PL166690B1 (pl) * 1990-06-04 1995-06-30 Exxon Chemical Patents Inc Sposób wytwarzania polimerów olefin PL
US5079205A (en) * 1990-07-13 1992-01-07 Exxon Chemical Patents Inc. Group ivb, vb and vib metal hydrocarbyloxides, with alumoxane for olefin polymerization
ES2085000T3 (es) * 1990-12-27 1996-05-16 Exxon Chemical Patents Inc Un compuesto de amido-metal de transicion y un sistema catalitico para la produccion de polipropileno isotactico.
ES2108861T3 (es) * 1991-11-25 1998-01-01 Exxon Chemical Patents Inc Composiciones cataliticas polionicas de metales de transicion.
DE69334188T2 (de) * 1992-08-05 2008-10-23 Exxonmobil Chemical Patents Inc., Baytown Verfahren zur Herstellung von einem geträgertem Aktivatorkomponenten
EP0586167B1 (de) * 1992-09-04 2000-07-12 BP Chemicals Limited Katalysatorzusammensetzung und Verfahren zur Herstellung von Polyolefinen
US5276199A (en) * 1993-02-11 1994-01-04 Ethyl Corporation Process for preparing cyclopentenones
US5498582A (en) * 1993-12-06 1996-03-12 Mobil Oil Corporation Supported metallocene catalysts for the production of polyolefins
WO1996004319A1 (en) * 1994-08-03 1996-02-15 Exxon Chemical Patents Inc. Supported ionic catalyst composition
US5643847A (en) * 1994-08-03 1997-07-01 Exxon Chemical Patents Inc. Supported ionic catalyst composition
KR100420432B1 (ko) * 1995-03-10 2004-07-23 다우 글로벌 테크놀로지스 인크. 지지된촉매및이를이용한중합방법

Also Published As

Publication number Publication date
WO1996023005A1 (en) 1996-08-01
US5939347A (en) 1999-08-17
AU4701796A (en) 1996-08-14
EP0805824B1 (de) 2002-04-24
DE69620871D1 (de) 2002-05-29
EP0805824A1 (de) 1997-11-12

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Legal Events

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