DE69721305D1 - Retroreflektierender gegenstand mit waschfestem bindemittel für kügelchen - Google Patents

Retroreflektierender gegenstand mit waschfestem bindemittel für kügelchen

Info

Publication number
DE69721305D1
DE69721305D1 DE69721305T DE69721305T DE69721305D1 DE 69721305 D1 DE69721305 D1 DE 69721305D1 DE 69721305 T DE69721305 T DE 69721305T DE 69721305 T DE69721305 T DE 69721305T DE 69721305 D1 DE69721305 D1 DE 69721305D1
Authority
DE
Germany
Prior art keywords
retrore
wash
reflective object
resistant ball
ball agent
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Expired - Lifetime
Application number
DE69721305T
Other languages
English (en)
Other versions
DE69721305T2 (de
Inventor
J Fleming
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
3M Co
Original Assignee
Minnesota Mining and Manufacturing Co
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Minnesota Mining and Manufacturing Co filed Critical Minnesota Mining and Manufacturing Co
Publication of DE69721305D1 publication Critical patent/DE69721305D1/de
Application granted granted Critical
Publication of DE69721305T2 publication Critical patent/DE69721305T2/de
Anticipated expiration legal-status Critical
Expired - Lifetime legal-status Critical Current

Links

Classifications

    • G—PHYSICS
    • G02—OPTICS
    • G02B—OPTICAL ELEMENTS, SYSTEMS OR APPARATUS
    • G02B5/00—Optical elements other than lenses
    • G02B5/12—Reflex reflectors
    • G02B5/126—Reflex reflectors including curved refracting surface
    • G02B5/128—Reflex reflectors including curved refracting surface transparent spheres being embedded in matrix
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
    • C08G18/00—Polymeric products of isocyanates or isothiocyanates
    • C08G18/06—Polymeric products of isocyanates or isothiocyanates with compounds having active hydrogen
    • C08G18/28—Polymeric products of isocyanates or isothiocyanates with compounds having active hydrogen characterised by the compounds used containing active hydrogen
    • C08G18/40—High-molecular-weight compounds
    • C08G18/61—Polysiloxanes
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
    • C08G18/00—Polymeric products of isocyanates or isothiocyanates
    • C08G18/06—Polymeric products of isocyanates or isothiocyanates with compounds having active hydrogen
    • C08G18/70—Polymeric products of isocyanates or isothiocyanates with compounds having active hydrogen characterised by the isocyanates or isothiocyanates used
    • C08G18/71—Monoisocyanates or monoisothiocyanates
    • C08G18/718—Monoisocyanates or monoisothiocyanates containing silicon
    • Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y10—TECHNICAL SUBJECTS COVERED BY FORMER USPC
    • Y10S—TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y10S428/00—Stock material or miscellaneous articles
    • Y10S428/913—Material designed to be responsive to temperature, light, moisture
    • Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y10—TECHNICAL SUBJECTS COVERED BY FORMER USPC
    • Y10T—TECHNICAL SUBJECTS COVERED BY FORMER US CLASSIFICATION
    • Y10T428/00—Stock material or miscellaneous articles
    • Y10T428/24—Structurally defined web or sheet [e.g., overall dimension, etc.]
    • Y10T428/24355—Continuous and nonuniform or irregular surface on layer or component [e.g., roofing, etc.]
    • Y10T428/24372—Particulate matter
    • Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y10—TECHNICAL SUBJECTS COVERED BY FORMER USPC
    • Y10T—TECHNICAL SUBJECTS COVERED BY FORMER US CLASSIFICATION
    • Y10T428/00—Stock material or miscellaneous articles
    • Y10T428/25—Web or sheet containing structurally defined element or component and including a second component containing structurally defined particles
    • Y10T428/252—Glass or ceramic [i.e., fired or glazed clay, cement, etc.] [porcelain, quartz, etc.]
    • Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y10—TECHNICAL SUBJECTS COVERED BY FORMER USPC
    • Y10T—TECHNICAL SUBJECTS COVERED BY FORMER US CLASSIFICATION
    • Y10T428/00—Stock material or miscellaneous articles
    • Y10T428/31504—Composite [nonstructural laminate]
    • Y10T428/31551—Of polyamidoester [polyurethane, polyisocyanate, polycarbamate, etc.]
    • Y10T428/31598—Next to silicon-containing [silicone, cement, etc.] layer
    • Y10T428/31601—Quartz or glass
DE1997621305 1996-12-20 1997-12-04 Retroreflektierender gegenstand mit waschfestem bindemittel für kügelchen Expired - Lifetime DE69721305T2 (de)

Applications Claiming Priority (3)

Application Number Priority Date Filing Date Title
US08/777,718 US5976669A (en) 1996-12-20 1996-12-20 Retroreflective article having launderably durable bead-bond
US777718 1996-12-20
PCT/US1997/023040 WO1998028642A1 (en) 1996-12-20 1997-12-04 Retroreflective article having launderably durable bead-bond

Publications (2)

Publication Number Publication Date
DE69721305D1 true DE69721305D1 (de) 2003-05-28
DE69721305T2 DE69721305T2 (de) 2004-02-12

Family

ID=25111044

Family Applications (1)

Application Number Title Priority Date Filing Date
DE1997621305 Expired - Lifetime DE69721305T2 (de) 1996-12-20 1997-12-04 Retroreflektierender gegenstand mit waschfestem bindemittel für kügelchen

Country Status (10)

Country Link
US (1) US5976669A (de)
EP (1) EP0946889B1 (de)
JP (1) JP4344865B2 (de)
KR (1) KR100519884B1 (de)
CN (1) CN1113252C (de)
CA (1) CA2274541C (de)
DE (1) DE69721305T2 (de)
HK (1) HK1023408A1 (de)
TW (1) TW386092B (de)
WO (1) WO1998028642A1 (de)

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US6159537A (en) * 1997-08-01 2000-12-12 3M Innovative Properties Company Method of making a retroreflective article that has a binder layer containing an epoxy resin and silicone crosslinked polymer
ES2273663T3 (es) 1999-01-14 2007-05-16 Reflec Plc Tintas retrorreflectantes.
GB2347366A (en) * 1999-03-05 2000-09-06 Reflective Technology Ind Ltd Reflective tape
EP1185893B1 (de) 1999-06-17 2004-12-22 3M Innovative Properties Company Retroreflektierender gegenstand mit einer farbigen schicht, die reflektierende blättchen und einen kovalent an ein polymer gebundenen farbstoff enthält
US6361850B1 (en) 1999-06-17 2002-03-26 3M Innovative Properties Company Retroreflective article having a colored layer containing a dye covalently bonded to a polymer
FR2803724B1 (fr) * 2000-01-18 2002-04-12 T 2 S Materiau complexe retroreflechissant la lumiere et/ou fluorescent
US6676754B1 (en) * 2000-06-30 2004-01-13 3M Innovative Properties Company Coating apparatus and methods of applying a polymer coating
US6723433B2 (en) * 2001-03-02 2004-04-20 3M Innovative Properties Company Printable film and coating composition exhibiting stain resistance
US6953624B2 (en) * 2001-03-02 2005-10-11 3M Innovative Properties Company Printable film and coating composition exhibiting stain resistance
ITMO20010126A1 (it) * 2001-06-21 2002-12-21 Autoadesivi S R L Tessuto o termoadesivo rinfrangente o retroriflettente
US6820280B1 (en) * 2002-06-18 2004-11-23 Blaver Manufacturing Company, Inc. Rip-off, high-visibility, safety vest
DE10355318A1 (de) * 2003-11-27 2005-06-23 Wacker-Chemie Gmbh Verfahren zur Herstellung von organyloxysilylterminierten Polymeren
BRPI0418341A (pt) * 2003-12-30 2007-05-02 3M Innovative Properties Co artigo retrorreflexivo com variação de cor e método para produzir um artigo retrorreflexivo com variação de cor
JP4750559B2 (ja) * 2004-01-30 2011-08-17 株式会社カネカ 粘着剤組成物
US9198156B2 (en) * 2004-08-23 2015-11-24 Telefonaktiebolaget L M Ericsson (Publ) Paging mobile stations in a hybrid network
US20080097068A1 (en) * 2004-10-15 2008-04-24 Thiede Verena M Isocyanate-Terminated Prepolymer Composition and a Polyurethane or Polyurea Elastomer Produced Therefrom
US8232362B2 (en) * 2005-09-15 2012-07-31 Momentive Performance Materials Inc. Preparation of amino-silane terminated polymer by using organic bismuth catalyst and cured polymer therefrom by using non-tin catalyst
US9248470B2 (en) * 2006-07-31 2016-02-02 Safe Reflections, Inc. Colorized retroreflective material and method
DE102006055739A1 (de) * 2006-11-25 2008-05-29 Bayer Materialscience Ag Abformmassen
US8292539B2 (en) * 2007-04-10 2012-10-23 Stoncor Group, Inc. Agglomerated retroreflective beads for highway marking and methods for fabrication and use thereof
US9207373B2 (en) 2007-04-10 2015-12-08 Stoncor Group, Inc. Methods for fabrication and highway marking usage of agglomerated retroreflective beads
CN101971061B (zh) * 2008-01-10 2014-04-16 可隆工业株式会社 光学片
JP2010131817A (ja) * 2008-12-03 2010-06-17 Ito Kosan Kk 再帰反射性シート
CN102893188B (zh) 2010-05-25 2016-11-02 3M创新有限公司 外露透镜逆反射制品
TW201315598A (zh) * 2012-10-18 2013-04-16 Cing Wai Kung Mau Company 反光物品製程
CN103792604B (zh) 2012-10-26 2016-12-21 3M创新有限公司 回归反射制品和附饰物
CN103792603B (zh) 2012-10-26 2016-07-06 3M创新有限公司 回归反射材料及制品
WO2015030770A1 (en) 2013-08-29 2015-03-05 Safe Reflections, Inc. Colorized retroreflective material and method of formation
CN105940325A (zh) 2014-01-31 2016-09-14 3M创新有限公司 彩色回射制品
KR20160123330A (ko) 2014-02-13 2016-10-25 쓰리엠 이노베이티브 프로퍼티즈 컴파니 고온 안정성을 갖는 가요성 미소구체 물품
KR102300849B1 (ko) 2014-02-13 2021-09-13 쓰리엠 이노베이티브 프로퍼티즈 컴파니 이중 경화 내오염성 미소구체 물품
WO2015171405A1 (en) * 2014-05-09 2015-11-12 3M Innovative Properties Company Retroreflective articles
US10261222B2 (en) * 2014-06-16 2019-04-16 3M Innovative Properties Company Retroreflective articles with wash durable bead bond layers
JP6454096B2 (ja) * 2014-06-27 2019-01-16 株式会社松井色素化学工業所 画像形成方法及び布状繊維製品
KR20170065591A (ko) 2014-09-30 2017-06-13 쓰리엠 이노베이티브 프로퍼티즈 캄파니 착색된 재귀반사성 물품
CN104354352A (zh) * 2014-10-14 2015-02-18 陈国顺 一种带彩色印花型反光织物及制作方法
US10345495B2 (en) 2014-12-30 2019-07-09 3M Innovative Properties Company Stain resistant retroreflective articles
WO2016130172A1 (en) 2015-02-13 2016-08-18 3M Innovative Properties Company Flexible microsphere articles having high temperature stability
EP3436259A4 (de) 2016-03-30 2020-02-05 3M Innovative Properties Company Artikel mit einem vorbestimmten muster von zufällig verteilten mikrokugeln und verfahren zur herstellung davon
ITUA20164500A1 (it) * 2016-06-20 2017-12-20 Giorgio Corradi Inserto retro riflettente
US20180055124A1 (en) * 2016-08-26 2018-03-01 Chieh-Yu Chen Hat
CN111344606A (zh) 2017-10-27 2020-06-26 3M创新有限公司 包括含有主反射层和次反射层的回射元件的回射制品
EP3701300A4 (de) 2017-10-27 2021-08-25 3M Innovative Properties Company Rückstrahlender gegenstand mit eingebetteten reflektierenden schichten
US11366252B2 (en) 2017-10-27 2022-06-21 3M Innovative Properties Company Retroreflective article comprising locally-laminated reflective layers
US20220216616A1 (en) * 2019-05-24 2022-07-07 3M Innovative Properties Company Radar retroreflective article
US20230099542A1 (en) * 2021-09-29 2023-03-30 Douglas Bradshaw Traffic Control Safety Gloves

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US3758192A (en) * 1970-08-20 1973-09-11 Minnesota Mining & Mfg Reflex-reflective structures including fabric and transfer foils
US3700305A (en) * 1970-12-14 1972-10-24 Minnesota Mining & Mfg Retroreflective microspheres having a dielectric mirror on a portion of their surface and retroreflective constructions containing such microspheres
US3979344A (en) * 1974-11-19 1976-09-07 Inmont Corporation Vulcanizable silicon terminated polyurethane polymer composition having improved cure speed
US4576850A (en) * 1978-07-20 1986-03-18 Minnesota Mining And Manufacturing Company Shaped plastic articles having replicated microstructure surfaces
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US4533592A (en) * 1984-08-02 1985-08-06 Minnesota Mining And Manufacturing Company Thermally stable flame retardant reflective and retroreflective trim
US4763985A (en) * 1986-08-01 1988-08-16 Minnesota Mining And Manufacturing Company Retroreflective sheet with enhanced brightness
US4916199A (en) * 1988-07-14 1990-04-10 The B. F. Goodrich Company Polyurethanes made from blends of polypropyleneoxide polyol and organic-silicone block copolymer based polyol intermediates
US4889903A (en) * 1988-08-03 1989-12-26 Basf Corporation Fast-cure polyurethane sealant composition containing titanium ester accelerators
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US5128804A (en) * 1991-02-06 1992-07-07 Minnesota Mining And Manufacturing Company Permeable retroreflective sheeting
CA2066503A1 (en) * 1991-04-22 1992-10-23 Joseph S. Sollers Polyurethane foam based on combination of polyester resin and polyether polyol
CA2061708C (en) * 1991-05-08 2002-04-23 Wu-Shyong Li Launderable retroreflective applique with colorant
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US5200262A (en) * 1992-04-01 1993-04-06 Minnesota Mining And Manufacturing Company Launderable retroreflective applique with improved retention of retroreflective elements
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Also Published As

Publication number Publication date
EP0946889A1 (de) 1999-10-06
WO1998028642A1 (en) 1998-07-02
JP2001507138A (ja) 2001-05-29
CN1113252C (zh) 2003-07-02
HK1023408A1 (en) 2000-09-08
TW386092B (en) 2000-04-01
DE69721305T2 (de) 2004-02-12
CN1240516A (zh) 2000-01-05
CA2274541A1 (en) 1998-07-02
KR100519884B1 (ko) 2005-10-12
JP4344865B2 (ja) 2009-10-14
KR20000062254A (ko) 2000-10-25
EP0946889B1 (de) 2003-04-23
CA2274541C (en) 2007-02-06
US5976669A (en) 1999-11-02

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Legal Events

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