DE69730718D1 - Metallkomplexe enthaltend ein an position 3 substituierte cyclopentadienylgruppe und ein olefinpolymerisationsverfahren - Google Patents
Metallkomplexe enthaltend ein an position 3 substituierte cyclopentadienylgruppe und ein olefinpolymerisationsverfahrenInfo
- Publication number
- DE69730718D1 DE69730718D1 DE69730718T DE69730718T DE69730718D1 DE 69730718 D1 DE69730718 D1 DE 69730718D1 DE 69730718 T DE69730718 T DE 69730718T DE 69730718 T DE69730718 T DE 69730718T DE 69730718 D1 DE69730718 D1 DE 69730718D1
- Authority
- DE
- Germany
- Prior art keywords
- group substituted
- polymerization method
- metal complexes
- olefin polymerization
- cyclopentadienyl group
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Expired - Lifetime
Links
Classifications
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- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07F—ACYCLIC, CARBOCYCLIC OR HETEROCYCLIC COMPOUNDS CONTAINING ELEMENTS OTHER THAN CARBON, HYDROGEN, HALOGEN, OXYGEN, NITROGEN, SULFUR, SELENIUM OR TELLURIUM
- C07F17/00—Metallocenes
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07F—ACYCLIC, CARBOCYCLIC OR HETEROCYCLIC COMPOUNDS CONTAINING ELEMENTS OTHER THAN CARBON, HYDROGEN, HALOGEN, OXYGEN, NITROGEN, SULFUR, SELENIUM OR TELLURIUM
- C07F7/00—Compounds containing elements of Groups 4 or 14 of the Periodic System
- C07F7/02—Silicon compounds
- C07F7/08—Compounds having one or more C—Si linkages
- C07F7/10—Compounds having one or more C—Si linkages containing nitrogen having a Si-N linkage
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
- C08F10/00—Homopolymers and copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
- C08F210/00—Copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond
- C08F210/16—Copolymers of ethene with alpha-alkenes, e.g. EP rubbers
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
- C08F2420/00—Metallocene catalysts
- C08F2420/02—Cp or analog bridged to a non-Cp X anionic donor
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
- C08F4/00—Polymerisation catalysts
- C08F4/42—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors
- C08F4/44—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides
- C08F4/60—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides together with refractory metals, iron group metals, platinum group metals, manganese, rhenium technetium or compounds thereof
- C08F4/62—Refractory metals or compounds thereof
- C08F4/64—Titanium, zirconium, hafnium or compounds thereof
- C08F4/659—Component covered by group C08F4/64 containing a transition metal-carbon bond
- C08F4/65908—Component covered by group C08F4/64 containing a transition metal-carbon bond in combination with an ionising compound other than alumoxane, e.g. (C6F5)4B-X+
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
- C08F4/00—Polymerisation catalysts
- C08F4/42—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors
- C08F4/44—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides
- C08F4/60—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides together with refractory metals, iron group metals, platinum group metals, manganese, rhenium technetium or compounds thereof
- C08F4/62—Refractory metals or compounds thereof
- C08F4/64—Titanium, zirconium, hafnium or compounds thereof
- C08F4/659—Component covered by group C08F4/64 containing a transition metal-carbon bond
- C08F4/65912—Component covered by group C08F4/64 containing a transition metal-carbon bond in combination with an organoaluminium compound
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
- C08F4/00—Polymerisation catalysts
- C08F4/42—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors
- C08F4/44—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides
- C08F4/60—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides together with refractory metals, iron group metals, platinum group metals, manganese, rhenium technetium or compounds thereof
- C08F4/62—Refractory metals or compounds thereof
- C08F4/64—Titanium, zirconium, hafnium or compounds thereof
- C08F4/659—Component covered by group C08F4/64 containing a transition metal-carbon bond
- C08F4/65916—Component covered by group C08F4/64 containing a transition metal-carbon bond supported on a carrier, e.g. silica, MgCl2, polymer
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
- C08F4/00—Polymerisation catalysts
- C08F4/42—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors
- C08F4/44—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides
- C08F4/60—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides together with refractory metals, iron group metals, platinum group metals, manganese, rhenium technetium or compounds thereof
- C08F4/62—Refractory metals or compounds thereof
- C08F4/64—Titanium, zirconium, hafnium or compounds thereof
- C08F4/659—Component covered by group C08F4/64 containing a transition metal-carbon bond
- C08F4/6592—Component covered by group C08F4/64 containing a transition metal-carbon bond containing at least one cyclopentadienyl ring, condensed or not, e.g. an indenyl or a fluorenyl ring
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- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y10—TECHNICAL SUBJECTS COVERED BY FORMER USPC
- Y10S—TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y10S526/00—Synthetic resins or natural rubbers -- part of the class 520 series
- Y10S526/943—Polymerization with metallocene catalysts
Applications Claiming Priority (5)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
US2376896P | 1996-08-08 | 1996-08-08 | |
US23768P | 1996-08-08 | ||
US3481996P | 1996-12-19 | 1996-12-19 | |
US34819P | 1996-12-19 | ||
PCT/US1997/013170 WO1998006727A1 (en) | 1996-08-08 | 1997-07-28 | 3-heteroatom substituted cyclopentadienyl-containing metal complexes and olefin polymerization process |
Publications (2)
Publication Number | Publication Date |
---|---|
DE69730718D1 true DE69730718D1 (de) | 2004-10-21 |
DE69730718T2 DE69730718T2 (de) | 2005-09-22 |
Family
ID=26697575
Family Applications (1)
Application Number | Title | Priority Date | Filing Date |
---|---|---|---|
DE69730718T Expired - Lifetime DE69730718T2 (de) | 1996-08-08 | 1997-07-28 | Metallkomplexe enthaltend ein an position 3 substituierte cyclopentadienylgruppe und ein olefinpolymerisationsverfahren |
Country Status (24)
Country | Link |
---|---|
US (1) | US6268444B1 (de) |
EP (1) | EP0923589B1 (de) |
JP (1) | JP3407074B2 (de) |
KR (1) | KR100528754B1 (de) |
CN (1) | CN1114609C (de) |
AR (1) | AR009035A1 (de) |
AT (1) | ATE276263T1 (de) |
AU (1) | AU719500B2 (de) |
BR (1) | BR9711124A (de) |
CA (1) | CA2262910C (de) |
CO (1) | CO4870708A1 (de) |
CZ (1) | CZ42399A3 (de) |
DE (1) | DE69730718T2 (de) |
EG (1) | EG21365A (de) |
ES (1) | ES2224266T3 (de) |
HU (1) | HUP9902581A3 (de) |
ID (1) | ID18004A (de) |
MY (1) | MY132554A (de) |
NO (1) | NO326005B1 (de) |
NZ (1) | NZ333878A (de) |
SK (1) | SK15399A3 (de) |
TR (1) | TR199900487T2 (de) |
TW (1) | TW455595B (de) |
WO (1) | WO1998006727A1 (de) |
Families Citing this family (141)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
US5968337A (en) * | 1996-04-18 | 1999-10-19 | Battelle Memorial Institute | Apparatus and method for constant flow oxidizing of organic materials |
DE69935815T2 (de) | 1998-07-01 | 2007-12-27 | Exxonmobil Chemical Patents Inc., Baytown | Elastische Mischung mit Kristallpolymeren und kristallisierbaren Polymeren des Propens |
BR9915199B1 (pt) | 1998-11-02 | 2010-09-08 | interpolìmero de etileno/alfa-olefina de cisalhamento fino, processo de preparação de interpolìmero de etileno/alfa-olefina, artigo manufaturado, composição de mistura de polìmeros e composição vulcanizada termoplástica. | |
US6326493B1 (en) * | 1999-01-25 | 2001-12-04 | Chisso Corporation | Metallocene compounds, processes for the preparation thereof, catalyst components for olefin polymerization, and processes for the production of olefin polymers |
EP1070072A4 (de) * | 1999-02-05 | 2002-09-25 | Boulder Scient Co | Herstellung silylierter und n-silylierter verbindungen |
CN1357012A (zh) * | 1999-04-20 | 2002-07-03 | 英国石油化学品有限公司 | 延迟活性载体上的烯烃聚合催化剂组合物及其制备和使用方法 |
WO2000066596A1 (en) | 1999-04-29 | 2000-11-09 | The Dow Chemical Company | Bis(n,n-dihydrocarbylamino)- substituted cyclopentadienes and metal complexes thereof |
CA2368010A1 (en) | 1999-05-13 | 2000-11-23 | Dow Global Technologies Inc. | Metal complexes containing bridging heteroatom for olefin-polymerization process |
JP2002544282A (ja) | 1999-05-13 | 2002-12-24 | ザ ダウ ケミカル カンパニー | ジ−及びトリ−ヘテロ原子置換インデニル金属錯体 |
EP1194431B1 (de) | 1999-06-04 | 2005-06-22 | Dow Global Technologies Inc. | Borsubstituierte cyclopentadiene und metallkomplexe dieser liganden |
JP2003501436A (ja) | 1999-06-04 | 2003-01-14 | バセル テクノロジー カンパニー ビー.ブイ. | チタン錯体の製造法 |
DE19927766A1 (de) * | 1999-06-17 | 2000-12-21 | Basf Ag | Trägerkatalysator zur Olefinpolymerisation |
EP1253158A1 (de) * | 1999-12-10 | 2002-10-30 | Dow Global Technologies Inc. | Substituierte Gruppe 4-Metallkomplexe, Katalysatoren und Verfahren zur Olefinpolymerisation |
US6825295B2 (en) | 1999-12-10 | 2004-11-30 | Dow Global Technologies Inc. | Alkaryl-substituted group 4 metal complexes, catalysts and olefin polymerization process |
CN1409729A (zh) * | 1999-12-10 | 2003-04-09 | 陶氏环球技术公司 | 取代的第4族金属配合物,催化剂和烯烃聚合方法 |
ES2239665T3 (es) | 2000-01-18 | 2005-10-01 | Basell Polyolefine Gmbh | Procedimiento para producir polimeros aa base de propileno, substancialmente amorfos. |
DE60238049D1 (de) | 2001-04-12 | 2010-12-02 | Exxonmobil Chem Patents Inc | Verfahren zur Polymerisation von Propylen und Ethylen in Lösung |
US6943215B2 (en) * | 2001-11-06 | 2005-09-13 | Dow Global Technologies Inc. | Impact resistant polymer blends of crystalline polypropylene and partially crystalline, low molecular weight impact modifiers |
US6927256B2 (en) | 2001-11-06 | 2005-08-09 | Dow Global Technologies Inc. | Crystallization of polypropylene using a semi-crystalline, branched or coupled nucleating agent |
US6906160B2 (en) * | 2001-11-06 | 2005-06-14 | Dow Global Technologies Inc. | Isotactic propylene copolymer fibers, their preparation and use |
EP1444276A1 (de) | 2001-11-06 | 2004-08-11 | Dow Global Technologies, Inc. | Isotaktische propylencopolymere, ihre herstellung und ihre verwendung |
JP4062929B2 (ja) | 2002-02-08 | 2008-03-19 | 住友化学株式会社 | 遷移金属錯体、配位子、オレフィン重合用触媒およびオレフィン重合体の製造方法 |
WO2003078480A2 (en) * | 2002-03-14 | 2003-09-25 | Dow Global Technologies Inc. | Polycyclic, fused heteroring compounds, metal complexes and polymerization process |
US8008412B2 (en) | 2002-09-20 | 2011-08-30 | Exxonmobil Chemical Patents Inc. | Polymer production at supersolution conditions |
BR0314562B1 (pt) * | 2002-10-17 | 2013-11-19 | Composição polimérica. | |
US7459500B2 (en) * | 2002-11-05 | 2008-12-02 | Dow Global Technologies Inc. | Thermoplastic elastomer compositions |
US7579407B2 (en) * | 2002-11-05 | 2009-08-25 | Dow Global Technologies Inc. | Thermoplastic elastomer compositions |
US6927264B2 (en) * | 2003-05-28 | 2005-08-09 | Dow Global Technologies Inc. | Metal complexes and polymerization process using same |
US7737205B2 (en) * | 2003-07-28 | 2010-06-15 | Dow Global Technologies Inc | Thermoplastic vulcanizates and process to prepare them |
ES2397751T3 (es) | 2003-08-19 | 2013-03-11 | Dow Global Technologies Inc. | Interpolímeros adecuados para usar en colas termoplásticas |
WO2005092503A1 (en) * | 2004-03-16 | 2005-10-06 | Union Carbide Chemicals & Plastics Technology Corporation | Aluminum phosphate-supported group 6 metal amide catalysts for oligomerization of ethylene |
US8273826B2 (en) * | 2006-03-15 | 2012-09-25 | Dow Global Technologies Llc | Impact modification of thermoplastics with ethylene/α-olefin interpolymers |
TW200604224A (en) | 2004-03-17 | 2006-02-01 | Dow Global Technologies Inc | Catalyst composition comprising shuttling agent for ethylene copolymer formation |
JP4879882B2 (ja) | 2004-03-17 | 2012-02-22 | ダウ グローバル テクノロジーズ エルエルシー | より高次のオレフィンマルチブロックコポリマーを形成するためのシャトリング剤を含む触媒組成物 |
CA2558251A1 (en) | 2004-03-17 | 2005-09-29 | Dow Global Technologies Inc. | Catalyst composition comprising shuttling agent for ethylene copolymer formation |
CN102321201B (zh) | 2004-06-16 | 2013-06-26 | 陶氏环球技术有限责任公司 | 选择聚合改性剂的方法 |
DE602005010255D1 (de) * | 2004-07-08 | 2008-11-20 | Exxonmobil Chem Patents Inc | Katalysator system für die olefinpolymerisation und verfahren zu seiner verwendung |
EP1805229A1 (de) | 2004-10-28 | 2007-07-11 | Dow Gloval Technologies Inc. | Verfahren zur steuerung eines polymerisierungsreaktors |
EP1845101A4 (de) | 2005-01-28 | 2010-02-24 | Sumitomo Chemical Co | Verfahren zur herstellung eines alkoxytitankomplexes |
ZA200707866B (en) | 2005-03-17 | 2008-12-31 | Dow Global Technologies Inc | Viscosity index improver for lubricant compositions |
US9410009B2 (en) | 2005-03-17 | 2016-08-09 | Dow Global Technologies Llc | Catalyst composition comprising shuttling agent for tactic/ atactic multi-block copolymer formation |
CA2600140A1 (en) | 2005-03-17 | 2006-09-28 | Dow Global Technologies Inc. | Catalyst composition comprising shuttling agent for tactic/ atactic multi-block copolymer formation |
WO2006101595A1 (en) | 2005-03-17 | 2006-09-28 | Dow Global Technologies Inc. | Catalyst composition comprising shuttling agent for regio-irregular multi-block copolymer formation |
US8287949B2 (en) * | 2005-07-07 | 2012-10-16 | Dow Global Technologies Inc. | Aqueous dispersions |
TW200722441A (en) | 2005-09-15 | 2007-06-16 | Dow Global Technologies Inc | Catalytic olefin block copolymers via polymerizable shuttling agent |
CA2622599A1 (en) * | 2005-09-15 | 2007-03-29 | Dow Global Technolgies Inc. | Control of polymer architecture and molecular weight distribution via multi-centered shuttling agent |
JP2009513396A (ja) * | 2005-10-26 | 2009-04-02 | ダウ グローバル テクノロジーズ インコーポレイティド | 多層弾性物品 |
US8785531B2 (en) * | 2006-07-06 | 2014-07-22 | Dow Global Technologies Llc | Dispersions of olefin block copolymers |
WO2008030980A1 (en) * | 2006-09-06 | 2008-03-13 | Dow Global Technologies Inc. | Knit fabrics comprising olefin block interpolymers |
US8476326B2 (en) * | 2006-09-22 | 2013-07-02 | Dow Global Technologies Llc | Fibrillated polyolefin foam |
TW200835737A (en) * | 2006-11-01 | 2008-09-01 | Dow Global Technologies Inc | Polyurethane compositions and articles prepared therefrom, and methods for making the same |
WO2008067538A2 (en) * | 2006-11-30 | 2008-06-05 | Dow Global Technologies Inc. | Stretch fabrics with wrinkle resistance and garment |
EP2087155B1 (de) * | 2006-11-30 | 2017-04-26 | Dow Global Technologies LLC | Textiles flächengebilde mit elastofasern aus vernetztem ethylenpolymer |
EP2084313A1 (de) * | 2006-11-30 | 2009-08-05 | Dow Global Technologies Inc. | Olefinblockzusammensetzungen für schwere stretch-waren |
US8242237B2 (en) | 2006-12-20 | 2012-08-14 | Exxonmobil Chemical Patents Inc. | Phase separator and monomer recycle for supercritical polymerization process |
KR101455425B1 (ko) * | 2006-12-21 | 2014-10-27 | 다우 글로벌 테크놀로지스 엘엘씨 | 폴리올레핀 조성물 및 그로부터 제조된 물품 및 그의 제조 방법 |
JP2010516910A (ja) | 2007-01-16 | 2010-05-20 | ダウ グローバル テクノロジーズ インコーポレイティド | オレフィンブロック組成物のコーン染色糸 |
BRPI0806226A2 (pt) * | 2007-01-16 | 2011-09-06 | Dow Global Technologies Inc | tecido tingido e processo para produzir um tecido tingido |
JP2010516908A (ja) * | 2007-01-16 | 2010-05-20 | ダウ グローバル テクノロジーズ インコーポレイティド | オレフィンブロックポリマーの伸縮性布帛および衣類 |
BRPI0809743B1 (pt) * | 2007-04-24 | 2019-02-26 | Dow Global Technologies Inc. | Composição de polímero e artigo moldado termoformado |
ITMI20070878A1 (it) * | 2007-05-02 | 2008-11-03 | Dow Global Technologies Inc | Processo per la polimerizzazine di polimeri tattici con l'uso di catalizzatori chirali |
ITMI20070877A1 (it) | 2007-05-02 | 2008-11-03 | Dow Global Technologies Inc | Processo per la produzione di copolimeri a blocchi multipli con l'utilizzo di solventi polari |
EP2160419B1 (de) | 2007-06-04 | 2013-11-13 | ExxonMobil Chemical Patents Inc. | Homogene propylenpolymerisation unter superlösungsbedingungen |
JP2010533246A (ja) * | 2007-07-09 | 2010-10-21 | ダウ グローバル テクノロジーズ インコーポレイティド | 繊維に適するオレフィンブロックインターポリマー組成物 |
US8486878B2 (en) * | 2007-07-13 | 2013-07-16 | Dow Global Technologies, Llc | Viscosity index improver for lubricant compositions |
BRPI0812643B1 (pt) * | 2007-07-13 | 2019-01-15 | Dow Global Technologies Inc | interpolímero de etileno/a-olefina |
US8492322B2 (en) * | 2007-07-13 | 2013-07-23 | Dow Global Technologies, Llc | Viscosity index improver for lubricant compositions |
US8569422B2 (en) * | 2007-07-13 | 2013-10-29 | Dow Global Technologies, Llc | Catalytic olefin block copolymers with controlled block sequence distribution and at least one low crystallinity hard block |
US7981517B2 (en) * | 2007-08-28 | 2011-07-19 | Dow Global Technologies Inc. | Bituminous compositions and methods of making and using same |
EP2203512A1 (de) * | 2007-09-28 | 2010-07-07 | Dow Global Technologies Inc. | Thermoplastische olefinzusammensetzung mit verbesserter wärmeformbeständigkeit |
WO2009072503A1 (ja) * | 2007-12-05 | 2009-06-11 | Mitsui Chemicals, Inc. | 共重合体ゴム、ゴム組成物およびゴム成形体 |
US8318875B2 (en) | 2008-01-18 | 2012-11-27 | Exxonmobil Chemical Patents Inc. | Super-solution homogeneous propylene polymerization and polypropylenes made therefrom |
JP5330414B2 (ja) | 2008-02-29 | 2013-10-30 | ダウ グローバル テクノロジーズ エルエルシー | エチレン/α−オレフィンブロックインターポリマーを含む配向フィルム |
SG10201805188YA (en) | 2008-06-18 | 2018-07-30 | Dow Global Technologies Inc | Processes to control fouling and improve compositions |
US8114946B2 (en) | 2008-12-18 | 2012-02-14 | Chevron Phillips Chemical Company Lp | Process for producing broader molecular weight distribution polymers with a reverse comonomer distribution and low levels of long chain branches |
WO2010098932A1 (en) | 2009-02-25 | 2010-09-02 | Dow Global Technologies Inc. | PHYLON PROCESSES OF MAKING FOAM ARTICLES COMPRISING ETHYLENE/α-OLEFINS BLOCK INTERPOLYMERS |
US8318874B2 (en) * | 2009-06-26 | 2012-11-27 | Dow Global Technologies Llc | Process of selectively polymerizing ethylene and catalyst therefor |
US8957167B2 (en) | 2009-07-28 | 2015-02-17 | Univation Technologies, Llc | Polymerization process using a supported constrained geometry catalyst |
ES2858349T3 (es) | 2009-07-29 | 2021-09-30 | Dow Global Technologies Llc | Agentes de transporte de cadena de múltiples cabezas y su uso para la preparación de copolímeros de bloques |
US8324416B2 (en) | 2009-07-29 | 2012-12-04 | Dow Global Technologies, Llc | Multifunctional chain shuttling agents |
ES2638913T3 (es) | 2009-08-31 | 2017-10-24 | Dow Global Technologies Llc | Catalizador y procedimiento para polimerizar una olefina y poliolefina preparada mediante el mismo |
US8679639B2 (en) | 2009-11-24 | 2014-03-25 | Dow Global Technologies Llc | Extrusion coating composition |
US8784996B2 (en) | 2009-11-24 | 2014-07-22 | Dow Global Technologies Llc | Extrusion coating composition |
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WO2012103080A1 (en) | 2011-01-26 | 2012-08-02 | Dow Global Technologies Llc | Process for making a polyolefin-polysiloxane block copolymer |
WO2012155022A1 (en) | 2011-05-12 | 2012-11-15 | Dow Global Technologies Llc | Non-cyclopentadienyl-based chromium catalysts for olefin polymerization |
JP5600219B2 (ja) | 2011-10-24 | 2014-10-01 | 三菱化学株式会社 | 熱可塑性エラストマー組成物及びその製造方法 |
US9045568B2 (en) | 2012-08-03 | 2015-06-02 | Exxonmobil Chemical Patents Inc. | Vinyl terminated polyethylene with long chain branching |
US8952114B2 (en) | 2012-08-03 | 2015-02-10 | Exxonmobil Chemical Patents Inc. | Halogenated catalysts comprising Salan ligands |
EP2880006B1 (de) | 2012-08-03 | 2017-12-20 | ExxonMobil Chemical Patents Inc. | Unsymmetrische katalysatoren mit salan-liganden |
US9382349B2 (en) | 2012-08-03 | 2016-07-05 | Exxonmobil Chemical Patents Inc. | Polyalphaolefins prepared using modified Salan catalyst compounds |
WO2014022008A1 (en) | 2012-08-03 | 2014-02-06 | Exxonmobil Chemical Patents Inc. | Catalysts comprising salan ligands |
EP2880096B1 (de) | 2012-08-03 | 2018-01-03 | ExxonMobil Chemical Patents Inc. | Verfahren zur herstellung von polyalphaolefinen unter verwendung von modifizierten salankatalysatorverbindungen und damit hergestellte polyalphaolefine |
US9120879B2 (en) | 2012-11-02 | 2015-09-01 | Exxonmobil Chemical Patents Inc. | Supported Salan catalysts |
US8937137B2 (en) | 2013-03-13 | 2015-01-20 | Exxonmobil Chemical Patents Inc. | Diphenylamine salan catalyst |
US9150676B2 (en) | 2013-06-20 | 2015-10-06 | Exxonmobil Chemical Patents Inc. | Thio-salalen catalyst |
US9200100B2 (en) | 2013-06-20 | 2015-12-01 | Exxonmobil Chemical Patents Inc. | Long-bridged salen catalyst |
US9200099B2 (en) | 2013-06-20 | 2015-12-01 | Exxonmobil Chemical Patents Inc. | Salenol catalyst |
KR101774615B1 (ko) | 2013-12-02 | 2017-09-04 | 주식회사 엘지화학 | 인덴기를 갖는 메탈로센형 촉매 및 이를 이용한 올레핀 중합체의 제조방법 |
US9290589B2 (en) | 2013-12-13 | 2016-03-22 | Exxonmobil Chemical Patents Inc. | Cyclopentadienyl-substituted salan catalysts |
WO2015094513A1 (en) | 2013-12-19 | 2015-06-25 | Dow Global Technologies Llc | Metal-ligand complex, olefin polymerization catalyst derived therefrom, and olefin polymerization method utilizing the catalyst |
US9193813B2 (en) | 2014-03-31 | 2015-11-24 | Exxonmobil Chemical Patents Inc. | Phenylene-bridged salalen catalysts |
CN107001764B (zh) | 2014-12-23 | 2020-10-09 | 陶氏环球技术有限责任公司 | 包括嵌段复合物的热塑性硫化橡胶 |
SG11201705218XA (en) | 2014-12-23 | 2017-07-28 | Dow Global Technologies Llc | Thermoplastic Vulcanizate Including Rubber Block Interpolymer |
EP3492532A1 (de) | 2015-01-06 | 2019-06-05 | Scg Chemicals Co. Ltd. | Sio2-geschichtete doppelhydroxidmikrokügelchen und verfahren zur herstellung davon |
US9796795B2 (en) | 2015-01-14 | 2017-10-24 | Exxonmobil Chemical Patents Inc. | Tetrahydroindacenyl catalyst composition, catalyst system, and processes for use thereof |
EP3274380B1 (de) | 2015-04-20 | 2020-08-19 | ExxonMobil Chemical Patents Inc. | Katalysatorzusammensetzung mit fluoridiertem träger und verfahren zur verwendung davon |
CN107636028A (zh) | 2015-04-20 | 2018-01-26 | 埃克森美孚化学专利公司 | 包含氟化物化的载体的催化剂组合物及其使用方法 |
BR112017025509B1 (pt) * | 2015-05-29 | 2022-05-10 | Dow Global Technologies Llc | Processo para produzir uma pololefina |
WO2017004462A1 (en) | 2015-06-30 | 2017-01-05 | Dow Global Technologies Llc | A polymerization process for producing ethylene based polymers |
EP3356374A1 (de) | 2015-09-30 | 2018-08-08 | Dow Global Technologies LLC | Mehr- oder doppelköpfige zusammensetzungen für kettenübertragung und verfahren zur herstellung davon |
BR112018011907A2 (pt) | 2015-12-15 | 2018-11-27 | Dow Global Technologies Llc | espumas reticuladas feitas de interpolímeros de etileno/alfa-olefinas |
EP3452521B1 (de) | 2016-05-03 | 2023-07-12 | ExxonMobil Chemical Patents Inc. | Tetrahydroindacenylkatalysatorzusammensetzung und verfahren zur verwendung davon |
GB201608384D0 (en) | 2016-05-12 | 2016-06-29 | Scg Chemicals Co Ltd | Unsymmetrical metallocene catalysts and uses thereof |
GB201610457D0 (en) * | 2016-06-15 | 2016-07-27 | Scg Chemicals Co Ltd | Catalysts |
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ES2954446T3 (es) | 2017-03-15 | 2023-11-22 | Dow Global Technologies Llc | Sistema de catalizador parala formación de copolímero multibloque |
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SG11201908414YA (en) | 2017-03-15 | 2019-10-30 | Dow Global Technologies Llc | Catalyst system for multi-block copolymer formation |
WO2018170056A1 (en) | 2017-03-15 | 2018-09-20 | Dow Global Technologies Llc | Catalyst system for multi-block copolymer formation |
US11208502B2 (en) | 2017-03-15 | 2021-12-28 | Dow Global Technologies Llc | Catalyst system for multi-block coploymer formation |
KR102643986B1 (ko) * | 2017-09-29 | 2024-03-07 | 사빅 에스케이 넥슬렌 컴퍼니 피티이 엘티디 | 신규한 인덴계 전이금속 화합물, 이를 포함하는 전이금속 촉매 조성물, 및 이를 이용한 에틸렌 단독중합체 또는 에틸렌과 α-올레핀의 공중합체의 제조방법 |
WO2019064247A1 (ko) * | 2017-09-29 | 2019-04-04 | 사빅 에스케이 넥슬렌 컴퍼니 피티이 엘티디 | 신규한 인덴계 전이금속 화합물, 이를 포함하는 전이금속 촉매 조성물, 및 이를 이용한 에틸렌 단독중합체 또는 에틸렌과 α-올레핀의 공중합체의 제조방법 |
US10703838B2 (en) | 2017-10-31 | 2020-07-07 | Exxonmobil Chemical Patents Inc. | Mixed catalyst systems with four metallocenes on a single support |
SG11202009138QA (en) | 2018-03-19 | 2020-10-29 | Dow Global Technologies Llc | Silicon-terminated organo-metal compounds and processes for preparing the same |
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WO2020174346A1 (ko) * | 2019-02-28 | 2020-09-03 | 사빅 에스케이 넥슬렌 컴퍼니 피티이 엘티디 | 신규한 테트라아릴보레이트 화합물, 이를 포함하는 촉매 조성물, 및 이를 이용한 에틸렌 단독중합체 또는 에틸렌과 α-올레핀의 공중합체의 제조방법 |
KR20200105409A (ko) * | 2019-02-28 | 2020-09-07 | 사빅 에스케이 넥슬렌 컴퍼니 피티이 엘티디 | 신규한 테트라아릴보레이트 화합물, 이를 포함하는 촉매 조성물, 및 이를 이용한 에틸렌 단독중합체 또는 에틸렌과 α-올레핀의 공중합체의 제조방법 |
EP4004071A1 (de) | 2019-07-31 | 2022-06-01 | Dow Global Technologies LLC | Polymerisation von ethylen in lösungsverfahren unter verwendung eines ziegler-natta-katalysators und eines hydrierungsprokatalysators |
BR112023000641A2 (pt) | 2020-07-17 | 2023-01-31 | Dow Global Technologies Llc | Processo de polimerização de monômeros de olefina |
CN113264963A (zh) * | 2021-05-19 | 2021-08-17 | 青岛科技大学 | 一种耐高温高活性限定几何构型催化剂的制备与应用 |
CN115894573A (zh) * | 2022-11-11 | 2023-04-04 | 天津科技大学 | 一种限制几何构型含氮侧臂茂茚金属衍生物及其合成方法 |
Family Cites Families (20)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
US5055438A (en) | 1989-09-13 | 1991-10-08 | Exxon Chemical Patents, Inc. | Olefin polymerization catalysts |
US5621126A (en) | 1987-01-30 | 1997-04-15 | Exxon Chemical Patents Inc. | Monocyclopentadienyl metal compounds for ethylene-α-olefin-copolymer production catalysts |
NZ235032A (en) | 1989-08-31 | 1993-04-28 | Dow Chemical Co | Constrained geometry complexes of titanium, zirconium or hafnium comprising a substituted cyclopentadiene ligand; use as olefin polymerisation catalyst component |
US5057475A (en) | 1989-09-13 | 1991-10-15 | Exxon Chemical Patents Inc. | Mono-Cp heteroatom containing group IVB transition metal complexes with MAO: supported catalyst for olefin polymerization |
US5064802A (en) | 1989-09-14 | 1991-11-12 | The Dow Chemical Company | Metal complex compounds |
PL166690B1 (pl) * | 1990-06-04 | 1995-06-30 | Exxon Chemical Patents Inc | Sposób wytwarzania polimerów olefin PL |
JP2545006B2 (ja) | 1990-07-03 | 1996-10-16 | ザ ダウ ケミカル カンパニー | 付加重合触媒 |
JP3275211B2 (ja) | 1991-05-20 | 2002-04-15 | ザ ダウ ケミカル カンパニー | 付加重合触媒の製造方法 |
ES2155492T3 (es) | 1991-05-27 | 2001-05-16 | Basell Polyolefine Gmbh | Procedimiento para la obtencion de poliolefinas con una amplia distribucion de pesos moleculares. |
US5721185A (en) | 1991-06-24 | 1998-02-24 | The Dow Chemical Company | Homogeneous olefin polymerization catalyst by abstraction with lewis acids |
ATE286918T1 (de) | 1991-10-15 | 2005-01-15 | Basell Polyolefine Gmbh | Verfahren zur herstellung eines olefinpolymers unter verwendung von metallocenen mit speziell substituierten indenylliganden |
US5374696A (en) | 1992-03-26 | 1994-12-20 | The Dow Chemical Company | Addition polymerization process using stabilized reduced metal catalysts |
US5710222A (en) | 1992-06-22 | 1998-01-20 | Fina Technology, Inc. | Method for controlling the melting points and molecular weights of syndiotactic polyolefins using metallocene catalyst systems |
ES2153368T3 (es) * | 1992-08-03 | 2001-03-01 | Targor Gmbh | Procedimiento para la obtencion de un polimero de olefina bajo empleo de metalocenos especiales. |
JP2736938B2 (ja) | 1993-06-24 | 1998-04-08 | ザ ダウ ケミカル カンパニー | チタン(▲ii▼)またはジルコニウム(▲ii▼)錯体およびそれからなる付加重合触媒 |
EP0719289B1 (de) | 1993-09-17 | 1999-12-29 | The Dow Chemical Company | Olefinpolymerisation in der gasphase |
WO1995014024A1 (fr) | 1993-11-18 | 1995-05-26 | Idemitsu Kosan Co., Ltd. | Compose de metal de transition, catalyseur de polymerisation d'olefines et procede pour produire un polymere d'olefines en utilisant ce catalyseur |
DE4406963A1 (de) * | 1994-03-03 | 1995-09-07 | Basf Ag | Metallocenkomplexe mit heterofunktionellen Gruppen am Cyclopentadienylsystem |
ATE164858T1 (de) | 1994-10-31 | 1998-04-15 | Dsm Nv | Katalytische zusammensetzung und verfahren zur olefinpolymerisation |
DE19517851A1 (de) * | 1995-05-16 | 1996-11-21 | Hoechst Ag | Organometallverbindung |
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1997
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- 1997-07-28 AU AU41456/97A patent/AU719500B2/en not_active Ceased
- 1997-07-28 HU HU9902581A patent/HUP9902581A3/hu unknown
- 1997-07-28 TR TR1999/00487T patent/TR199900487T2/xx unknown
- 1997-07-28 KR KR1019997000985A patent/KR100528754B1/ko not_active IP Right Cessation
- 1997-07-28 EP EP97939348A patent/EP0923589B1/de not_active Expired - Lifetime
- 1997-07-28 CZ CZ99423A patent/CZ42399A3/cs unknown
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- 1997-07-28 WO PCT/US1997/013170 patent/WO1998006727A1/en active IP Right Grant
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- 1997-08-08 AR ARP970103617A patent/AR009035A1/es not_active Application Discontinuation
- 1997-08-09 EG EG77997A patent/EG21365A/xx active
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WO1998006727A1 (en) | 1998-02-19 |
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CA2262910C (en) | 2006-04-11 |
AR009035A1 (es) | 2000-03-08 |
ID18004A (id) | 1998-02-19 |
AU719500B2 (en) | 2000-05-11 |
EP0923589B1 (de) | 2004-09-15 |
EP0923589A1 (de) | 1999-06-23 |
MY132554A (en) | 2007-10-31 |
ES2224266T3 (es) | 2005-03-01 |
AU4145697A (en) | 1998-03-06 |
TR199900487T2 (xx) | 1999-06-21 |
JP2000516228A (ja) | 2000-12-05 |
NO326005B1 (no) | 2008-09-01 |
HUP9902581A2 (hu) | 1999-11-29 |
SK15399A3 (en) | 2000-04-10 |
CO4870708A1 (es) | 1999-12-27 |
CN1114609C (zh) | 2003-07-16 |
NO990545D0 (no) | 1999-02-05 |
HUP9902581A3 (en) | 2004-03-01 |
TW455595B (en) | 2001-09-21 |
CA2262910A1 (en) | 1998-02-19 |
KR20000029833A (ko) | 2000-05-25 |
EG21365A (en) | 2001-09-30 |
JP3407074B2 (ja) | 2003-05-19 |
BR9711124A (pt) | 1999-09-28 |
CN1230190A (zh) | 1999-09-29 |
NO990545L (no) | 1999-03-26 |
CZ42399A3 (cs) | 1999-07-14 |
DE69730718T2 (de) | 2005-09-22 |
ATE276263T1 (de) | 2004-10-15 |
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