DE69822746D1 - Herstellung von Polyäthylen mit einer breiten Molekulargewichtsverteilung - Google Patents

Herstellung von Polyäthylen mit einer breiten Molekulargewichtsverteilung

Info

Publication number
DE69822746D1
DE69822746D1 DE69822746T DE69822746T DE69822746D1 DE 69822746 D1 DE69822746 D1 DE 69822746D1 DE 69822746 T DE69822746 T DE 69822746T DE 69822746 T DE69822746 T DE 69822746T DE 69822746 D1 DE69822746 D1 DE 69822746D1
Authority
DE
Germany
Prior art keywords
reactor
polyethylene
ethylene
manufacture
molecular weight
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Expired - Lifetime
Application number
DE69822746T
Other languages
English (en)
Other versions
DE69822746T2 (de
Inventor
Guy Debras
Michel Messiaen
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Total Research and Technology Feluy SA
Original Assignee
Atofina Research SA
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Atofina Research SA filed Critical Atofina Research SA
Application granted granted Critical
Publication of DE69822746D1 publication Critical patent/DE69822746D1/de
Publication of DE69822746T2 publication Critical patent/DE69822746T2/de
Anticipated expiration legal-status Critical
Expired - Lifetime legal-status Critical Current

Links

Classifications

    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F297/00—Macromolecular compounds obtained by successively polymerising different monomer systems using a catalyst of the ionic or coordination type without deactivating the intermediate polymer
    • C08F297/06—Macromolecular compounds obtained by successively polymerising different monomer systems using a catalyst of the ionic or coordination type without deactivating the intermediate polymer using a catalyst of the coordination type
    • C08F297/08—Macromolecular compounds obtained by successively polymerising different monomer systems using a catalyst of the ionic or coordination type without deactivating the intermediate polymer using a catalyst of the coordination type polymerising mono-olefins
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F10/00—Homopolymers and copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond
    • C08F10/02—Ethene
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F210/00—Copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond
    • C08F210/04—Monomers containing three or four carbon atoms
    • C08F210/06—Propene
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F210/00—Copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond
    • C08F210/16—Copolymers of ethene with alpha-alkenes, e.g. EP rubbers
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F2410/00—Features related to the catalyst preparation, the catalyst use or to the deactivation of the catalyst
    • C08F2410/01—Additive used together with the catalyst, excluding compounds containing Al or B
    • Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y10—TECHNICAL SUBJECTS COVERED BY FORMER USPC
    • Y10S—TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y10S526/00—Synthetic resins or natural rubbers -- part of the class 520 series
    • Y10S526/943—Polymerization with metallocene catalysts

Landscapes

  • Chemical & Material Sciences (AREA)
  • Health & Medical Sciences (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Medicinal Chemistry (AREA)
  • Polymers & Plastics (AREA)
  • Organic Chemistry (AREA)
  • Inorganic Chemistry (AREA)
  • Addition Polymer Or Copolymer, Post-Treatments, Or Chemical Modifications (AREA)
  • Polymerisation Methods In General (AREA)
  • Transition And Organic Metals Composition Catalysts For Addition Polymerization (AREA)
DE69822746T 1997-09-27 1998-09-25 Herstellung von Polyäthylen mit einer breiten Molekulargewichtsverteilung Expired - Lifetime DE69822746T2 (de)

Applications Claiming Priority (2)

Application Number Priority Date Filing Date Title
EP97202971 1997-09-27
EP97202971A EP0905151A1 (de) 1997-09-27 1997-09-27 Herstellung von Polyäthylen mit einer breiten Molekulargewichtsverteilung

Publications (2)

Publication Number Publication Date
DE69822746D1 true DE69822746D1 (de) 2004-05-06
DE69822746T2 DE69822746T2 (de) 2005-03-10

Family

ID=8228763

Family Applications (1)

Application Number Title Priority Date Filing Date
DE69822746T Expired - Lifetime DE69822746T2 (de) 1997-09-27 1998-09-25 Herstellung von Polyäthylen mit einer breiten Molekulargewichtsverteilung

Country Status (6)

Country Link
US (1) US6221982B1 (de)
EP (1) EP0905151A1 (de)
JP (1) JP4373508B2 (de)
AT (1) ATE263196T1 (de)
DE (1) DE69822746T2 (de)
ES (1) ES2217474T3 (de)

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EP1041090A1 (de) * 1999-03-29 2000-10-04 Fina Research S.A. Herstellung von Polyethylen mit breiter Molekulargewichtsverteilung
GB9919718D0 (en) * 1999-08-19 1999-10-20 Borealis As Process
DE19945980A1 (de) * 1999-09-24 2001-03-29 Elenac Gmbh Polyethylen Formmasse mit verbesserter ESCR-Steifigkeitsrelation und Schwellrate, Verfahren zu ihrer Herstellung und daraus hergestellte Hohlkörper
FI111954B (fi) * 2000-02-21 2003-10-15 Borealis Tech Oy Menetelmä polyeteenipäällysteen valmistamiseksi substraatille
FR2807439B1 (fr) 2000-04-07 2003-06-13 Atofina Polymeres multimodaux par polymerisation radicalaire controlee en presence d'alcoxyamines
EP1146077B1 (de) * 2000-04-13 2006-06-07 Borealis Technology Oy HDPE Polymerzusammensetzung
US6486270B1 (en) * 2000-08-25 2002-11-26 Equistar Chemicals, Lp High molecular weight, medium density polyethylene
BR0211959A (pt) 2001-08-17 2004-09-21 Dow Global Technologies Inc Composição de polietileno bimodal e artigos fabricados da mesma
US6924340B2 (en) 2002-04-04 2005-08-02 Equistar Chemicals L.P. Process for removal of intermediate hydrogen from cascaded polyolefin slurry reactors
US6716936B1 (en) 2002-12-16 2004-04-06 Equistar Chemicals L.P. Cascaded boiling pool slurry reactors for producing bimodal low to medium density polyethylene polymers
WO2004056921A1 (en) 2002-12-19 2004-07-08 Basell Polyolefine Gmbh Polyethylene blow molding composition for producing small containers
US6921804B2 (en) * 2003-03-25 2005-07-26 Equistar Chemicals L.P. Cascaded polyolefin slurry polymerization employing disengagement vessel between reactors
BRPI0411178A (pt) * 2003-05-15 2006-07-18 Du Pont composição, processo para a fabricação de uma composição, peça aparente, automóvel, processos de revestimento de substratos, substratos revestidos e veìculo
RU2337925C2 (ru) * 2003-08-20 2008-11-10 Базелль Полиолефин Италия С.Р.Л. Способ и устройство для полимеризации этилена
JP4790627B2 (ja) * 2003-12-19 2011-10-12 バーゼル・ポリオレフィン・ゲーエムベーハー エチレン（コ）ポリマーの製造方法
KR101168444B1 (ko) 2004-02-13 2012-07-25 토탈 페트로케미칼스 리서치 펠루이 올레핀 중합을 위한 복수개의 루프 반응기
US8440125B2 (en) 2004-06-28 2013-05-14 Equistar Chemicals, Lp Polyethylene films having high resistance to deformation or elongation
DE102004055587A1 (de) 2004-11-18 2006-05-24 Basell Polyolefine Gmbh Polyethylen Formmasse für die äußere Ummantelung von Elektrokabeln
DE102004055588A1 (de) 2004-11-18 2006-05-24 Basell Polyolefine Gmbh Polyethylen Formmasse für die Beschichtung von Stahlrohren
EP1846498B1 (de) * 2005-01-31 2013-08-14 ExxonMobil Chemical Patents Inc. Polymermischungen und -granulat sowie deren herstellungsverfahren
DE102005009896A1 (de) 2005-03-01 2006-09-07 Basell Polyolefine Gmbh Polyethylen Formmasse zum Herstellen von Blasfolien mit verbesserten mechanischen Eigenschaften
DE102005009916A1 (de) 2005-03-01 2006-09-07 Basell Polyolefine Gmbh Polyethylen Formmasse zum Herstellen von Blasfolien mit verbesserten mechanischen Eigenschaften
DE102005030941A1 (de) 2005-06-30 2007-01-11 Basell Polyolefine Gmbh Polyethylen Formmasse zur Herstellung von spritzgegossenen Fertigteilen
DE102005040390A1 (de) 2005-08-25 2007-03-01 Basell Polyolefine Gmbh Multimodale Polyethylen Formmasse zur Herstellung von Rohren mit verbesserten mechanischen Eigenschaften
US7786203B2 (en) * 2005-09-16 2010-08-31 Milliken & Company Polymer compositions comprising nucleating or clarifying agents and articles made using such compositions
CN101273445B (zh) * 2005-09-28 2012-07-25 大见忠弘 可控气氛的接合装置、接合方法及电子装置
EP1840140A1 (de) * 2006-03-30 2007-10-03 Total Petrochemicals Research Feluy Verfahren zum Wechseln zwischen Polymertypen
CN100424105C (zh) * 2006-08-03 2008-10-08 中国石化扬子石油化工有限公司 一种高密度聚乙烯通信电缆绝缘料的制备方法
US7601787B2 (en) * 2006-11-30 2009-10-13 Equistar Chemicals, IP Ethylene polymerization process
CN101481433B (zh) * 2008-01-08 2011-04-20 李长荣化学工业股份有限公司 共轭二烯类聚合物的加氢反应系统
US20110174413A1 (en) * 2010-01-20 2011-07-21 Fina Technology, Inc. Modification of Polyethylene Pipe to Improve Sag Resistance
US9108147B2 (en) 2010-10-15 2015-08-18 Chevron Phillips Chemical Company Lp Component separations in polymerization
US9180405B2 (en) 2010-10-15 2015-11-10 Chevron Phillips Chemical Company Lp Ethylene recovery by absorption
US8410329B2 (en) 2010-10-15 2013-04-02 Chevron Phillips Chemical Company Lp Ethylene separation
CA2869960A1 (en) 2012-04-13 2013-10-17 Chevron Phillips Chemical Company Lp Component separations in polymerization
US9000106B2 (en) * 2012-05-02 2015-04-07 Exxonmobil Chemical Patents Inc. Copolymer production system and process
KR20150068438A (ko) * 2012-10-22 2015-06-19 바젤 폴리올레핀 게엠베하 우수한 기계적 성질을 가진 폴리에틸렌 조성물
US8987390B2 (en) 2012-12-18 2015-03-24 Chevron Phillips Chemical Company, Lp Chain transfer agent removal between polyolefin polymerization reactors
US8822608B1 (en) 2013-03-12 2014-09-02 Chevron Phillips Chemical Co. LP. Polyolefin production with different diluents in multiple polymerization reactors
WO2016063205A2 (en) 2014-10-21 2016-04-28 Nova Chemicals (International) S.A. Dilution index
CA2868640C (en) 2014-10-21 2021-10-26 Nova Chemicals Corporation Solution polymerization process
US10544237B2 (en) * 2015-08-26 2020-01-28 Exxonmobil Chemical Patents Inc. Method of regulating hydrogen to a polymerization reactor
EP3504250A1 (de) 2016-08-23 2019-07-03 ExxonMobil Chemical Patents Inc. Olefinpolymerisierungsverfahren
WO2018038796A1 (en) 2016-08-23 2018-03-01 Exxonmobil Chemical Patents Inc. Olefin polymerization processes
US10329412B2 (en) 2017-02-16 2019-06-25 Nova Chemicals (International) S.A. Caps and closures
US10442920B2 (en) 2017-04-19 2019-10-15 Nova Chemicals (International) S.A. Means for increasing the molecular weight and decreasing the density of ethylene interpolymers employing homogeneous and heterogeneous catalyst formulations
WO2019096745A1 (en) * 2017-11-17 2019-05-23 Total Research & Technology Feluy Polyethylene resin and caps or closures made therefrom
RU2761055C1 (ru) * 2018-06-21 2021-12-02 Базелл Полиолефин Гмбх Суспензионный способ получения сополимеров этилена в каскаде реакторов
US10882987B2 (en) 2019-01-09 2021-01-05 Nova Chemicals (International) S.A. Ethylene interpolymer products having intermediate branching
US11046843B2 (en) 2019-07-29 2021-06-29 Nova Chemicals (International) S.A. Ethylene copolymers and films with excellent sealing properties
KR102526767B1 (ko) * 2019-09-30 2023-04-27 주식회사 엘지화학 장기 물성 및 가공성이 우수한 에틸렌/1-헥센 공중합체

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US4851488A (en) * 1987-04-23 1989-07-25 Shell Oil Company Process for altering hydrogenated polymer compositions from high melt flow to low melt flow
US5276115A (en) * 1992-12-14 1994-01-04 Phillips Petroleum Company Mono-1-olefin polymerization in the presence of hydrogen and a cyclopentadienyl compound
IT1273660B (it) * 1994-07-20 1997-07-09 Spherilene Srl Procedimento per la preparazione di polimeri amorfi del propilene
FI96216C (fi) * 1994-12-16 1996-05-27 Borealis Polymers Oy Prosessi polyeteenin valmistamiseksi

Also Published As

Publication number Publication date
DE69822746T2 (de) 2005-03-10
EP0905151A1 (de) 1999-03-31
ES2217474T3 (es) 2004-11-01
US6221982B1 (en) 2001-04-24
JP4373508B2 (ja) 2009-11-25
JPH11189605A (ja) 1999-07-13
ATE263196T1 (de) 2004-04-15

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