EP0059043A1 - Surface active compositions - Google Patents
Surface active compositions Download PDFInfo
- Publication number
- EP0059043A1 EP0059043A1 EP82300640A EP82300640A EP0059043A1 EP 0059043 A1 EP0059043 A1 EP 0059043A1 EP 82300640 A EP82300640 A EP 82300640A EP 82300640 A EP82300640 A EP 82300640A EP 0059043 A1 EP0059043 A1 EP 0059043A1
- Authority
- EP
- European Patent Office
- Prior art keywords
- compound
- salt
- sulphate
- composition
- carbon atoms
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Granted
Links
Classifications
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D3/00—Other compounding ingredients of detergent compositions covered in group C11D1/00
- C11D3/16—Organic compounds
- C11D3/37—Polymers
- C11D3/3703—Macromolecular compounds obtained otherwise than by reactions only involving carbon-to-carbon unsaturated bonds
- C11D3/3707—Polyethers, e.g. polyalkyleneoxides
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D1/00—Detergent compositions based essentially on surface-active compounds; Use of these compounds as a detergent
- C11D1/02—Anionic compounds
- C11D1/12—Sulfonic acids or sulfuric acid esters; Salts thereof
- C11D1/29—Sulfates of polyoxyalkylene ethers
Definitions
- THIS INVENTION relates to surface active compositions.
- sulphating agents for example H 2 S0 4 , S0 3 or SO 2 Cl 2 and neutralising with an amine for example a C l to C 5 mono alkyl amine or ammonia or with an alkali or alkaline earth base or ammonium compound to give the salt which is normally produced as a concentrate containing for example 65 to 75% by weight of the salt and a minor amount of water which includes any water of neutralisation and any introduced as solvent for the neutralising agent.
- Such concentrates are normally viscous liquids, but if free inorganic sulphates, for example sodium sulphate, or the unsulphated alcohol ethoxylate is present the concentrate may become an elastic gell which is difficult to handle.
- the alcohol-ether sulphate salts are normally transported as concentrates and then diluted with water and optionally other materials to produce the product ultimately used by the consumer. On dilution of the concentrate another gell of a particularly troublesome type is encountered when a composition of about 55% of the alcohol ether sulphate salt and 45% of water is reached. Frequently ethanol is added to break the gells and allow dilution, but this represents a considerable expense and becuase of its volatility, a fire hazard.
- a compound other than a sulphate or sulphate salt
- average molecular weight 500 to 10,000 preferably 500 to 6,000 and more preferably 1,000 to 3,000
- the compound comprising a total of at least two ether linkages per seven carbon atoms, for example a polyethylene glycol of average molecular weight 500 to 6,000 reduces the problem of dilution with water.
- the said compounds are of low volatility, and the quantities required are small.
- the invention comprises a composition comprising a salt of an alcohol ether sulphate of formula [RO(C 2 H 4 O) n SO 3 ] - m M m+ where R and n are as previously defined, M is an ammonium, substituted ammcnium, alkali or alkaline earth metal ion and m is the valency of M, and a gel inhibiting quantity of a compound (other than a sulphate or sulphate salt) of average molecular weight 500 to 10,000, preferably 500 to 6,000 and more preferably 1,000 to 3,000, which comprises at least one polyalkylene glycol chain, the compound comprising a total of at least two ether linkages per seven carbon atoms, for example a polyethylene glycol.
- the compound may be a polyalkylene or mixed polyalkylene glycol, for example polyethylene glycol or a mixed polyethylene/polypropylene glycol, a compound comprising a polyalkylene glycol chain linked to a phenol or alcohol for example an alkyl phenol (suitably having 4 to 12 carbon atoms in its alkyl group or groups) or alcohol (suitably having 1 to 16 and preferably 10 to 16 carbon atoms)/ethylene oxide condensate or with two or more polyalkylene glycol chains linked to a residue of a compound having two or more active hydrogen atoms, for example, glycerol or butane 1,4 diol.
- the compound is very suitably a polyethylene glycol.
- a gel inhibiting quantity is meant an amount sufficient to reduce the maximum elasticity of any gel encountered during dilution with water to at most 4 x 10 -4 Newtons per sq mm and preferably at most 1 x 10 -4 Newtons. In general 0.5 to 5% by weight of polyethylene glycol is used.
- Compositions according to the invention tend to be thixotropic; they are readily pumpable in suitable conventional equipment.
- the salt is suitably a sodium, potassium, magnesium or ammonium salt, and may be produced by neutralising the acid with a hydroxide, carbonate or bicarbonate of the cation. Direct neutralisation with ammonia or an amine may be carried out.
- the invention also comprises a process in which the alcohol ether sulphate salt is mixed with a gel inhibiting amount of a compound (other than a sulphate or sulphate salt) of average molecular weight 500 to 10,000, preferably 500 to 6,000 and more preferably 1,000 to 3,000, which comprises at least one polyalkylene glycol chain, the compound comprising a total of at least two ether linkages per seven carbon atoms, for example a polyethylene glycol,and then diluted with water.
- a compound other than a sulphate or sulphate salt of average molecular weight 500 to 10,000, preferably 500 to 6,000 and more preferably 1,000 to 3,000, which comprises at least one polyalkylene glycol chain, the compound comprising a total of at least two ether linkages per seven carbon atoms, for example a polyethylene glycol,and then diluted with water.
- the compound has at least two ether linkages per five carbon atoms.
- a sodium salt of a mixed C 13 and C 15 alcohol (7 to 3 by molar ratio) ethoxylated with an average of 3 mole C 2 H 4 O per mole of alcohol, sulphated with S0 3 and neutralised with NaOH solution to produce a 70% mixture by weight of the salt with water (hereinafter referred to as material A) was tested in an oscillating can rheometer to determine its dynamic viscosity and elasticity at a frequency of oscillation of 9.8 cycles per second. Material A with the specified additives was also tested in the same way.
- Material A with 2.5% w/w of polyethylene glycol (800 mol wt) added had a dynamic viscosity under the same conditions of 37 poise at low shear and an elasticity of 3.2 x 10 -4 N mm -2 .
- Material A with 1% w/w polyethylene glycol (1,COO mol wt) added had a dynamic viscosity under the same conditions of 34 poise at low shear and an elasticity of 4.1 x 10 -4 N mm -2 .
- Material A with 21 ⁇ 2 w/w polyethylene glycol (1,000 mol wt) added had a dynamic viscosity under the same conditions of 36 poise at low shear and an elasticity of 2.1 x 10 -4 N mm -2 .
- Synperonic TLE is a commercial product produced by alkoxylating methanol. It contains 28 ether links per 63 carbon atoms and has a molecular weight of 1,400.
- “Synperonic”A50 is a commercial product produced by condensing a mixed C l3 and C 15 alcohol (7 to 3 by molar ratio) with c. 50 moles of ethylene oxide per mole.
- Synperonic OP40 is a product of condensing octyl phenol with c. 40 moles of ethylene oxide per mole.
- M.W. means molecular weight
Abstract
Description
- THIS INVENTION relates to surface active compositions.
- Alcohol ether sulphate salts of which the anion has the formula [RO(C2H4O)nSO3]- where R is an alkyl group having 10 to 20 and preferably 12 to 16 carbon atoms and n is an integer in the range 1 to 7 and preferably 1 to 4 are known surface active agents which are used'in, for example shampoos, liquid dishwashing liquids etc.
- They are normally produced by ethoxylating an appropriate alcohol, reacting the product with a sulphating agent for example H2S04, S03 or SO2Cl2 and neutralising with an amine for example a Cl to C5 mono alkyl amine or ammonia or with an alkali or alkaline earth base or ammonium compound to give the salt which is normally produced as a concentrate containing for example 65 to 75% by weight of the salt and a minor amount of water which includes any water of neutralisation and any introduced as solvent for the neutralising agent. Such concentrates are normally viscous liquids, but if free inorganic sulphates, for example sodium sulphate, or the unsulphated alcohol ethoxylate is present the concentrate may become an elastic gell which is difficult to handle.
- The alcohol-ether sulphate salts are normally transported as concentrates and then diluted with water and optionally other materials to produce the product ultimately used by the consumer. On dilution of the concentrate another gell of a particularly troublesome type is encountered when a composition of about 55% of the alcohol ether sulphate salt and 45% of water is reached. Frequently ethanol is added to break the gells and allow dilution, but this represents a considerable expense and becuase of its volatility, a fire hazard.
- We have found that the addition of a compound (other than a sulphate or sulphate salt) of average molecular weight 500 to 10,000, preferably 500 to 6,000 and more preferably 1,000 to 3,000, which comprises at least one polyalkylene glycol chain, the compound comprising a total of at least two ether linkages per seven carbon atoms, for example a polyethylene glycol of average molecular weight 500 to 6,000 reduces the problem of dilution with water. The said compounds are of low volatility, and the quantities required are small.
- The invention comprises a composition comprising a salt of an alcohol ether sulphate of formula [RO(C2H4O)nSO3] -mMm+ where R and n are as previously defined, M is an ammonium, substituted ammcnium, alkali or alkaline earth metal ion and m is the valency of M, and a gel inhibiting quantity of a compound (other than a sulphate or sulphate salt) of average molecular weight 500 to 10,000, preferably 500 to 6,000 and more preferably 1,000 to 3,000, which comprises at least one polyalkylene glycol chain, the compound comprising a total of at least two ether linkages per seven carbon atoms, for example a polyethylene glycol.
- The compound may be a polyalkylene or mixed polyalkylene glycol, for example polyethylene glycol or a mixed polyethylene/polypropylene glycol, a compound comprising a polyalkylene glycol chain linked to a phenol or alcohol for example an alkyl phenol (suitably having 4 to 12 carbon atoms in its alkyl group or groups) or alcohol (suitably having 1 to 16 and preferably 10 to 16 carbon atoms)/ethylene oxide condensate or with two or more polyalkylene glycol chains linked to a residue of a compound having two or more active hydrogen atoms, for example, glycerol or butane 1,4 diol. The compound is very suitably a polyethylene glycol.
- By a gel inhibiting quantity is meant an amount sufficient to reduce the maximum elasticity of any gel encountered during dilution with water to at most 4 x 10-4 Newtons per sq mm and preferably at most 1 x 10-4 Newtons. In general 0.5 to 5% by weight of polyethylene glycol is used.. Compositions according to the invention tend to be thixotropic; they are readily pumpable in suitable conventional equipment.
- The salt is suitably a sodium, potassium, magnesium or ammonium salt, and may be produced by neutralising the acid with a hydroxide, carbonate or bicarbonate of the cation. Direct neutralisation with ammonia or an amine may be carried out.
- The invention also comprises a process in which the alcohol ether sulphate salt is mixed with a gel inhibiting amount of a compound (other than a sulphate or sulphate salt) of average molecular weight 500 to 10,000, preferably 500 to 6,000 and more preferably 1,000 to 3,000, which comprises at least one polyalkylene glycol chain, the compound comprising a total of at least two ether linkages per seven carbon atoms, for example a polyethylene glycol,and then diluted with water.
- Preferably the compound has at least two ether linkages per five carbon atoms.
- A sodium salt of a mixed C13 and C15 alcohol (7 to 3 by molar ratio) ethoxylated with an average of 3 mole C2H4O per mole of alcohol, sulphated with S03 and neutralised with NaOH solution to produce a 70% mixture by weight of the salt with water (hereinafter referred to as material A) was tested in an oscillating can rheometer to determine its dynamic viscosity and elasticity at a frequency of oscillation of 9.8 cycles per second. Material A with the specified additives was also tested in the same way.
- The elasticity of Material A was.745 Nm-2 and its dynamic viscosity at 25°C at low shear was 39.5 poise.
- Material A with 2.5% w/w of polyethylene glycol (800 mol wt) added had a dynamic viscosity under the same conditions of 37 poise at low shear and an elasticity of 3.2 x 10-4 N mm-2.
- Material A with 1% w/w polyethylene glycol (1,COO mol wt) added had a dynamic viscosity under the same conditions of 34 poise at low shear and an elasticity of 4.1 x 10-4 N mm-2.
- Material A with 2½ w/w polyethylene glycol (1,000 mol wt) added had a dynamic viscosity under the same conditions of 36 poise at low shear and an elasticity of 2.1 x 10-4 N mm-2.
-
- "Synperonic"A50 is a commercial product produced by condensing a mixed Cl3 and C15 alcohol (7 to 3 by molar ratio) with c. 50 moles of ethylene oxide per mole.
- "Synperonic" OP40 is a product of condensing octyl phenol with c. 40 moles of ethylene oxide per mole.
- M.W. means molecular weight.
- Materials with the additives all diluted much more readily with water than the pure material. The time required for comparable dilutions was substantially less, for example one tenth, and no problems were encountered with gel formation during dilution.
Claims (7)
Applications Claiming Priority (2)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
GB8105257 | 1981-02-19 | ||
GB8105257 | 1981-02-19 |
Publications (2)
Publication Number | Publication Date |
---|---|
EP0059043A1 true EP0059043A1 (en) | 1982-09-01 |
EP0059043B1 EP0059043B1 (en) | 1985-08-21 |
Family
ID=10519822
Family Applications (1)
Application Number | Title | Priority Date | Filing Date |
---|---|---|---|
EP82300640A Expired EP0059043B1 (en) | 1981-02-19 | 1982-02-09 | Surface active compositions |
Country Status (10)
Country | Link |
---|---|
EP (1) | EP0059043B1 (en) |
JP (1) | JPS57155298A (en) |
AR (1) | AR228638A1 (en) |
AU (1) | AU555929B2 (en) |
BR (1) | BR8200899A (en) |
CA (1) | CA1165660A (en) |
DE (1) | DE3265500D1 (en) |
ES (1) | ES9000010A1 (en) |
NO (1) | NO158565C (en) |
ZA (1) | ZA821048B (en) |
Cited By (4)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
EP0402051A2 (en) * | 1989-06-05 | 1990-12-12 | Mobil Oil Corporation | Processes for the preparation of saturated alcohol derivatives and their use in detergent: plasticizer: and synthetic lubricant formulations |
EP0816479A1 (en) * | 1996-06-28 | 1998-01-07 | The Procter & Gamble Company | Dishwashing compositions with improved resistance to gelling |
WO2002000580A1 (en) * | 2000-06-26 | 2002-01-03 | Basf Aktiengesellschaft | Alcohol mixtures having 13 and 15 carbon atoms and the use thereof in the preparation of surface-active substances |
WO2002077143A1 (en) * | 2001-03-21 | 2002-10-03 | The Procter & Gamble Company | Hand dishwashing composition |
Families Citing this family (1)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
JPH07274346A (en) * | 1994-03-29 | 1995-10-20 | Mirai Ind Co Ltd | Dust-proof packing for box |
Citations (5)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
FR2198992A1 (en) * | 1972-09-11 | 1974-04-05 | Procter & Gamble Europ | |
FR2216346A1 (en) * | 1973-02-05 | 1974-08-30 | Colgate Palmolive Co | Detergent soap soln contg alkyl polyethoxy sulphate - and a detergent salt to reduce soap stains on clothes washed in hard water |
US3963649A (en) * | 1972-09-11 | 1976-06-15 | The Procter & Gamble Company | Liquid detergent composition |
GB2054635A (en) * | 1979-06-29 | 1981-02-18 | Kao Corp | Detergent composition |
US4304680A (en) * | 1973-02-05 | 1981-12-08 | Colgate-Palmolive Company | Laundry soap |
Family Cites Families (5)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
JPS50116383A (en) * | 1973-10-29 | 1975-09-11 | ||
JPS5335711A (en) * | 1976-09-14 | 1978-04-03 | Kao Corp | Neutral liquid detergent composition |
JPS5916598B2 (en) * | 1978-12-05 | 1984-04-16 | ライオン株式会社 | Enzyme-containing cleaning composition |
DE3066054D1 (en) * | 1979-09-01 | 1984-02-09 | Henkel Kgaa | Watery tenside concentrates and process for the improvement of the flowing property of difficultly movable watery tenside concentrates |
DE3166233D1 (en) * | 1980-02-05 | 1984-10-31 | Procter & Gamble | Liquid detergent composition |
-
1982
- 1982-02-09 EP EP82300640A patent/EP0059043B1/en not_active Expired
- 1982-02-09 DE DE8282300640T patent/DE3265500D1/en not_active Expired
- 1982-02-15 AU AU80485/82A patent/AU555929B2/en not_active Expired
- 1982-02-17 CA CA000396422A patent/CA1165660A/en not_active Expired
- 1982-02-17 ZA ZA821048A patent/ZA821048B/en unknown
- 1982-02-18 BR BR8200899A patent/BR8200899A/en not_active IP Right Cessation
- 1982-02-18 JP JP57025240A patent/JPS57155298A/en active Granted
- 1982-02-18 NO NO820510A patent/NO158565C/en not_active IP Right Cessation
- 1982-02-18 ES ES509713A patent/ES9000010A1/en not_active Expired
- 1982-02-19 AR AR288480A patent/AR228638A1/en active
Patent Citations (5)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
FR2198992A1 (en) * | 1972-09-11 | 1974-04-05 | Procter & Gamble Europ | |
US3963649A (en) * | 1972-09-11 | 1976-06-15 | The Procter & Gamble Company | Liquid detergent composition |
FR2216346A1 (en) * | 1973-02-05 | 1974-08-30 | Colgate Palmolive Co | Detergent soap soln contg alkyl polyethoxy sulphate - and a detergent salt to reduce soap stains on clothes washed in hard water |
US4304680A (en) * | 1973-02-05 | 1981-12-08 | Colgate-Palmolive Company | Laundry soap |
GB2054635A (en) * | 1979-06-29 | 1981-02-18 | Kao Corp | Detergent composition |
Cited By (7)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
EP0402051A2 (en) * | 1989-06-05 | 1990-12-12 | Mobil Oil Corporation | Processes for the preparation of saturated alcohol derivatives and their use in detergent: plasticizer: and synthetic lubricant formulations |
EP0402051A3 (en) * | 1989-06-05 | 1992-03-25 | Mobil Oil Corporation | Processes for the preparation of saturated alcohol derivatives and their use in detergent: plasticizer: and synthetic lubricant formulations |
EP0816479A1 (en) * | 1996-06-28 | 1998-01-07 | The Procter & Gamble Company | Dishwashing compositions with improved resistance to gelling |
WO2002000580A1 (en) * | 2000-06-26 | 2002-01-03 | Basf Aktiengesellschaft | Alcohol mixtures having 13 and 15 carbon atoms and the use thereof in the preparation of surface-active substances |
US7183446B2 (en) | 2000-06-26 | 2007-02-27 | Basf Aktiengesellschaft | Alcohol mixtures having 13 and 15 carbon atoms and the use thereof in the preparation of surface-active substances |
WO2002077143A1 (en) * | 2001-03-21 | 2002-10-03 | The Procter & Gamble Company | Hand dishwashing composition |
US6790818B2 (en) | 2001-03-21 | 2004-09-14 | Procter & Gamble Company | Hand dishwashing composition |
Also Published As
Publication number | Publication date |
---|---|
DE3265500D1 (en) | 1985-09-26 |
NO158565C (en) | 1988-10-05 |
NO820510L (en) | 1982-08-20 |
ZA821048B (en) | 1982-10-27 |
NO158565B (en) | 1988-06-27 |
EP0059043B1 (en) | 1985-08-21 |
ES9000010A1 (en) | 1989-10-16 |
JPH0525920B2 (en) | 1993-04-14 |
AR228638A1 (en) | 1983-03-30 |
JPS57155298A (en) | 1982-09-25 |
CA1165660A (en) | 1984-04-17 |
AU555929B2 (en) | 1986-10-16 |
AU8048582A (en) | 1982-08-26 |
BR8200899A (en) | 1982-12-28 |
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