EP0291869A3 - Phosphatfreies Waschmittel mit reduzierter Inkrustierungstendenz - Google Patents

Phosphatfreies Waschmittel mit reduzierter Inkrustierungstendenz Download PDF

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Publication number
EP0291869A3
EP0291869A3 EP88107689A EP88107689A EP0291869A3 EP 0291869 A3 EP0291869 A3 EP 0291869A3 EP 88107689 A EP88107689 A EP 88107689A EP 88107689 A EP88107689 A EP 88107689A EP 0291869 A3 EP0291869 A3 EP 0291869A3
Authority
EP
European Patent Office
Prior art keywords
phosphate
acid
free detergent
alkali metal
tendency
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Withdrawn
Application number
EP88107689A
Other languages
English (en)
French (fr)
Other versions
EP0291869A2 (de
Inventor
Günther Dr. Vogt
Hans Dr. Andree
Gertrud Nienhaus
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Henkel AG and Co KGaA
Original Assignee
Henkel AG and Co KGaA
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Henkel AG and Co KGaA filed Critical Henkel AG and Co KGaA
Publication of EP0291869A2 publication Critical patent/EP0291869A2/de
Publication of EP0291869A3 publication Critical patent/EP0291869A3/de
Withdrawn legal-status Critical Current

Links

Classifications

    • C—CHEMISTRY; METALLURGY
    • C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
    • C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
    • C11D3/00—Other compounding ingredients of detergent compositions covered in group C11D1/00
    • C11D3/16—Organic compounds
    • C11D3/36—Organic compounds containing phosphorus
    • C11D3/364—Organic compounds containing phosphorus containing nitrogen
    • C—CHEMISTRY; METALLURGY
    • C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
    • C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
    • C11D3/00—Other compounding ingredients of detergent compositions covered in group C11D1/00
    • C11D3/02—Inorganic compounds ; Elemental compounds
    • C11D3/12—Water-insoluble compounds
    • C11D3/124—Silicon containing, e.g. silica, silex, quartz or glass beads
    • C11D3/1246—Silicates, e.g. diatomaceous earth
    • C11D3/128—Aluminium silicates, e.g. zeolites
    • C—CHEMISTRY; METALLURGY
    • C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
    • C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
    • C11D3/00—Other compounding ingredients of detergent compositions covered in group C11D1/00
    • C11D3/16—Organic compounds
    • C11D3/36—Organic compounds containing phosphorus
    • C11D3/361—Phosphonates, phosphinates or phosphonites
    • C—CHEMISTRY; METALLURGY
    • C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
    • C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
    • C11D3/00—Other compounding ingredients of detergent compositions covered in group C11D1/00
    • C11D3/16—Organic compounds
    • C11D3/37—Polymers
    • C11D3/3746—Macromolecular compounds obtained by reactions only involving carbon-to-carbon unsaturated bonds
    • C11D3/3757—(Co)polymerised carboxylic acids, -anhydrides, -esters in solid and liquid compositions
    • C11D3/3761—(Co)polymerised carboxylic acids, -anhydrides, -esters in solid and liquid compositions in solid compositions

Abstract

Waschmittel mit einem Gehalt an (a) 5 bis 35 % an üblichen Tensi­ den, (b) 10 bis 40 % feinkristallinem Zeolith, (c) 4 bis 20 % an Alkalimetallsilikaten bzw. -carbonaten und 0,1 bis 5 % an (d1) Aminoalkanphosphonaten und/oder (d2) Copolymeren aus (Meth-) Acrylsäure und Maleinsäure sowie (e) 5 - 80 % an sonstigen Wasch­ mittelbestandteilen, werden hinsichtlich ihrer Inkrustations-ver­ hütenden Eigenschaften wesentlich verbessert, wenn sie zusätzlich (f) 0,05 bis 1 % (bezogen auf freie Säure) 1-Hydroxyethan-1,1-di­ phosphonsäure in Form der Alkalimetallsalze enthalten. Das Verhältnis von (d1) = (f) beträgt 3 : 1 bis 1 : 6 und von (d2) : (f) 40 : 1 bis 2 : 1.
EP88107689A 1987-05-21 1988-05-13 Phosphatfreies Waschmittel mit reduzierter Inkrustierungstendenz Withdrawn EP0291869A3 (de)

Applications Claiming Priority (2)

Application Number Priority Date Filing Date Title
DE19873717227 DE3717227A1 (de) 1987-05-21 1987-05-21 Phosphatfreies waschmittel mit reduzierter inkrustierungstendenz
DE3717227 1987-05-21

Publications (2)

Publication Number Publication Date
EP0291869A2 EP0291869A2 (de) 1988-11-23
EP0291869A3 true EP0291869A3 (de) 1990-07-18

Family

ID=6328146

Family Applications (1)

Application Number Title Priority Date Filing Date
EP88107689A Withdrawn EP0291869A3 (de) 1987-05-21 1988-05-13 Phosphatfreies Waschmittel mit reduzierter Inkrustierungstendenz

Country Status (4)

Country Link
US (1) US4919845A (de)
EP (1) EP0291869A3 (de)
DE (1) DE3717227A1 (de)
DK (1) DK279888A (de)

Families Citing this family (39)

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DE3900207A1 (de) * 1989-01-05 1990-07-12 Basf Ag Verwendung von copolymerisaten aus 1,2-di-alkoxyethylenen und monoethylenisch ungesaettigten dicarbonsaeureanhydriden in waschmitteln und waschmittel, die diese copolymerisate enthalten
CH679311A5 (de) * 1989-01-07 1992-01-31 Sandoz Ag
US5244988A (en) * 1989-05-17 1993-09-14 Rohm And Haas Company Maleate polymerization process
US5030380A (en) * 1989-06-27 1991-07-09 Lever Brothers Company, Division Of Conopco, Inc. Polymeric electrolyte-hydrogen peroxide adducts
DE4034131C2 (de) * 1990-10-26 1999-08-26 Henkel Kgaa Gerüststoff für Waschmittel
NZ239112A (en) 1991-01-29 1994-12-22 Ecolab Inc Solid alkaline compositions containing the reaction product in water of alkali metal hydroxide and alkali metal silicate; process of manufacture
DK167363B1 (da) * 1991-04-12 1993-10-18 Cleantabs As Toejvaskemiddel
US5474699A (en) * 1991-05-31 1995-12-12 Colgate-Palmolive Co. Phosphate containing powered automatic dishwashing composition with enzymes
US5693602A (en) * 1991-05-31 1997-12-02 Colgate-Palmolive Co. Spray dried powered automatic dishwashing composition containing enzymes
US5433885A (en) * 1991-07-17 1995-07-18 Church & Dwight Co., Inc. Stabilization of silicate solutions
US5281351A (en) * 1991-12-06 1994-01-25 Lever Brothers Company, Division Of Conopco, Inc. Processes for incorporating anti-scalants in powdered detergent compositions
DE4303320C2 (de) * 1993-02-05 1995-12-21 Degussa Waschmittelzusammensetzung mit verbessertem Schmutztragevermögen, Verfahren zu dessen Herstellung und Verwendung eines geeigneten Polycarboxylats hierfür
US5352376A (en) * 1993-02-19 1994-10-04 Ecolab Inc. Thermoplastic compatible conveyor lubricant
US5376300A (en) * 1993-06-29 1994-12-27 Church & Dwight Co., Inc. Carbonate built laundry detergent composition
GB2285053A (en) * 1993-12-23 1995-06-28 Procter & Gamble Rinse aid composition
GB2285051A (en) * 1993-12-23 1995-06-28 Procter & Gamble Rinse aid composition
GB2285052A (en) * 1993-12-23 1995-06-28 Procter & Gamble Detergent composition
WO1996008552A1 (en) † 1994-09-13 1996-03-21 Kao Corporation Washing method and clothes detergent composition
KR100322629B1 (ko) * 1994-12-06 2002-08-13 제일제당주식회사 액체세제조성물
US5925609A (en) * 1995-03-11 1999-07-20 Procter & Gamble Company Detergent composition comprising source of hydrogen peroxide and protease enzyme
EP0815192A4 (de) * 1995-03-11 1999-09-22 Procter & Gamble Waschmittelzusammensetzung mit einer polymeren polycarboxylverbindung, einem komplexbildner und einer amylase
US5929018A (en) * 1995-03-11 1999-07-27 Procter & Gamble Co. Detergent composition comprising a polymeric polycarboxylic compound, a chelant, and an amylase enzyme
FR2732355B1 (fr) * 1995-03-29 1997-04-30 Rhone Poulenc Chimie Formulation detergente compacte en poudre pour lavage du linge
DE19520101A1 (de) * 1995-06-01 1996-12-05 Henkel Kgaa Vergrauungsinhibitorsystem auf enzymatischer Basis
GB2303635A (en) * 1995-07-25 1997-02-26 Procter & Gamble Detergent compositions in compacted solid form
US6063747A (en) * 1995-07-25 2000-05-16 The Procter & Gamble Company Detergent compositions in compacted solid form
DE19528059A1 (de) * 1995-07-31 1997-02-06 Bayer Ag Wasch- und Reinigungsmittel mit Iminodisuccinaten
DE19538028A1 (de) * 1995-10-12 1997-04-17 Sued Chemie Ag Waschmittelzusatz
US5876514A (en) * 1997-01-23 1999-03-02 Ecolab Inc. Warewashing system containing nonionic surfactant that performs both a cleaning and sheeting function and a method of warewashing
US6407050B1 (en) 2000-01-11 2002-06-18 Huish Detergents, Inc. α-sulfofatty acid methyl ester laundry detergent composition with reduced builder deposits
MY129053A (en) 2001-06-06 2007-03-30 Thermphos Trading Gmbh Composition for inhibiting calcium salt scale
MY138251A (en) * 2001-06-06 2009-05-29 Thermphos Trading Gmbh Method for inhibiting calcium salt scale
AR034363A1 (es) * 2001-06-06 2004-02-18 Solutia Inc Composiciones y metodo de fabricacion de pulpa mejorada.
US7485613B2 (en) * 2004-12-01 2009-02-03 Venus Laboratories, Inc. Low foaming carpet-cleaning detergent concentrate comprised of ethylene oxide adduct and without phosphates
US7459420B2 (en) * 2004-12-01 2008-12-02 Vlahakis E Van Automatic dishwashing detergent comprised of ethylene oxide adduct and without phosphates
US7699905B1 (en) 2006-05-08 2010-04-20 Iowa State University Research Foundation, Inc. Dispersoid reinforced alloy powder and method of making
EP2090646A1 (de) * 2008-01-22 2009-08-19 Thermphos Trading GmbH Oberflächenbehandlungszusammensetzung mit Phosphonsäureverbindungen
US8883035B2 (en) 2009-07-27 2014-11-11 Ecolab Usa Inc. Formulation of a ware washing solid controlling hardness
JP2017503061A (ja) * 2013-11-11 2017-01-26 エコラボ ユーエスエー インコーポレイティド 多目的酵素洗剤及び使用溶液を安定化する方法

Citations (3)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
FR2388044A1 (fr) * 1977-04-22 1978-11-17 Henkel Kgaa Produit de lavage pour textiles exempt de phosphates et convenant en particulier pour les lavages a temperature elevee
EP0001853A1 (de) * 1977-11-07 1979-05-16 THE PROCTER & GAMBLE COMPANY Reinigungsmittelmischungen mit verbesserter Bleichwirkung
EP0114308A1 (de) * 1982-12-24 1984-08-01 Henkel Kommanditgesellschaft auf Aktien Sprühgetrocknetes Mehrkomponenten-Waschmittel

Family Cites Families (15)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
ZA661932B (de) * 1965-04-01
DE1767454C2 (de) * 1968-05-11 1983-01-27 Henkel KGaA, 4000 Düsseldorf Verfahren zum Korrosions- und Versteinungsschutz in Warm- und Heißwassersystemen
DE2224837C3 (de) * 1972-05-20 1986-05-07 Agfa-Gevaert Ag, 5090 Leverkusen Direktpositives photographisches Aufzeichnungsmaterial
DE2325829C2 (de) * 1973-05-22 1982-04-01 Henkel KGaA, 4000 Düsseldorf Sequestrierungsmittel
GB1455873A (en) * 1973-08-24 1976-11-17 Procter & Gamble Textile-softening detergent compositions
US3959167A (en) * 1973-12-10 1976-05-25 Chemed Corporation Method and composition of inhibiting scale
US4146495A (en) * 1977-08-22 1979-03-27 Monsanto Company Detergent compositions comprising polyacetal carboxylates
US4144226A (en) * 1977-08-22 1979-03-13 Monsanto Company Polymeric acetal carboxylates
EP0026529B2 (de) * 1979-09-29 1992-08-19 THE PROCTER & GAMBLE COMPANY Reinigungsmittelzusammensetzungen
US4265777A (en) * 1980-04-17 1981-05-05 The Procter & Gamble Company Detergent compositions containing an aluminosilicate detergency builder and an unsaturated fatty acid soap
AU549000B2 (en) * 1981-02-26 1986-01-09 Colgate-Palmolive Pty. Ltd. Base beads for detergent compositions
EP0124913B1 (de) * 1983-04-08 1986-06-18 THE PROCTER & GAMBLE COMPANY Granulierte Detergenszusammensetzungen, welche ein gemischtes Polymerzusatzsystem enthalten
GB8414407D0 (en) * 1984-06-06 1984-07-11 Monsanto Europe Sa Detergent compositions
DE3444960A1 (de) * 1984-12-10 1986-06-12 Henkel KGaA, 4000 Düsseldorf Koerniges adsorptionsmittel
DE3526405A1 (de) * 1985-07-24 1987-02-05 Henkel Kgaa Schichtsilikate mit beschraenktem quellvermoegen, verfahren zu ihrer herstellung und ihre verwendung in wasch- und reinigungsmitteln

Patent Citations (3)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
FR2388044A1 (fr) * 1977-04-22 1978-11-17 Henkel Kgaa Produit de lavage pour textiles exempt de phosphates et convenant en particulier pour les lavages a temperature elevee
EP0001853A1 (de) * 1977-11-07 1979-05-16 THE PROCTER & GAMBLE COMPANY Reinigungsmittelmischungen mit verbesserter Bleichwirkung
EP0114308A1 (de) * 1982-12-24 1984-08-01 Henkel Kommanditgesellschaft auf Aktien Sprühgetrocknetes Mehrkomponenten-Waschmittel

Also Published As

Publication number Publication date
DE3717227A1 (de) 1988-12-01
EP0291869A2 (de) 1988-11-23
DK279888A (da) 1988-11-22
DK279888D0 (da) 1988-05-20
US4919845A (en) 1990-04-24

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