EP0298604A2 - Decorative objects with multicolor effects - Google Patents
Decorative objects with multicolor effects Download PDFInfo
- Publication number
- EP0298604A2 EP0298604A2 EP88305170A EP88305170A EP0298604A2 EP 0298604 A2 EP0298604 A2 EP 0298604A2 EP 88305170 A EP88305170 A EP 88305170A EP 88305170 A EP88305170 A EP 88305170A EP 0298604 A2 EP0298604 A2 EP 0298604A2
- Authority
- EP
- European Patent Office
- Prior art keywords
- color
- pigment
- absorption
- interference
- colorant
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
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Classifications
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- B—PERFORMING OPERATIONS; TRANSPORTING
- B05—SPRAYING OR ATOMISING IN GENERAL; APPLYING FLUENT MATERIALS TO SURFACES, IN GENERAL
- B05D—PROCESSES FOR APPLYING FLUENT MATERIALS TO SURFACES, IN GENERAL
- B05D5/00—Processes for applying liquids or other fluent materials to surfaces to obtain special surface effects, finishes or structures
- B05D5/06—Processes for applying liquids or other fluent materials to surfaces to obtain special surface effects, finishes or structures to obtain multicolour or other optical effects
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B44—DECORATIVE ARTS
- B44F—SPECIAL DESIGNS OR PICTURES
- B44F1/00—Designs or pictures characterised by special or unusual light effects
- B44F1/08—Designs or pictures characterised by special or unusual light effects characterised by colour effects
Definitions
- interference pigments are an outgrowth of nacreous pigments, that is, pigments which simulate the effect of natural pearls.
- the pigments are composed of thin platelets which are transparent in the visible region of the spectrum. The platelets are very smooth and part of the light which strikes the platelets is reflected and part is transmitted through the platelet. That part of the light which is transmitted is subsequently reflected by other layers of platelets. The result is that there are multiple reflections from many layers and it is this which gives rise to a depth of sheen since the eye cannot focus on one particular layer.
- the reflection which takes place is specular in that the angle of incidence equals the angle of reflection.
- the amount of light reflected at non-specular angles is small and the amount of light reflected diminishes very quickly as the specular angle is passed.
- the result is that nacreous pigments are extremely sensitive to the angle of viewing.
- the platelets In order for the maximum amount of light to be reflected, the platelets must be extremely smooth. Any surface roughness causes light to be scattered in a non-specular manner and diminishes the lustrous effect.
- the platelets must be aligned parallel to each other and to the substrate for maximum reflectivity. If not so aligned, light will be reflected randomly and again, luster will diminish. The amount of light which is reflected depends on the index of refraction of the platelets. The greater the index of refraction, the greater the amount of light reflected. Since in most cases, the platelets are imbedded in film forming mediums which have an index of refraction of approximately 1.5, it is necessary that the index of refraction of the platelets be considerably greater than 1.5.
- the layers of reflecting material are composed of calcium carbonate interspersed between layers of an organic material.
- Synthetic nacreous pigments have been made by growing crystals of basic lead carbonate and bismuth oxychloride. Both of these substances can be grown into crystals which are extremely smooth and flat.
- titanium dioxide which per se has not been grown into flat crystals has been coated on thin smooth platelets of mica which act as a carrier.
- the mica platelets are ideally from 5 to 50 microns in length.
- the coatings of titanium dioxide which are applied generally range from 60 nanometers to 160 nanometers in thickness.
- titanium dioxide can be used as the coating on mica. These include ZrO2, SnO2, ZnO, Fe2O3, Cr2O3, V2O5 and the hydrous forms thereof.
- the oxides can be present in various crystalline forms.
- TiO2 can be anatase or rutile or mixtures of the two.
- Combinations of oxides of two or more metals can be used as can their different crystalline forms.
- Interference pigments if composed of the correct thickness, can reflect any color of the visible spectrum. These colors can range from a yellow to a red to a blue and a green. Shadings between these are also possible. Because the reflected colors are produced by an interference effect, the complementary colors are produced by transmission. Thus if a red color is produced by reflection from an interference pigment, a green color will be seen if the pigment is viewed in transmission.
- interference pigments are incorporated into film formers and coated on white backgrounds, then two colors can be seen depending on the angle of viewing. At near specular angles, the reflected color can be observed. At other angles, the transmission color can be observed.
- absorption pigments In order to enhance the reflection color, absorption pigments have been added to interference pigments. In most cases, the absorption pigments have been precipitated onto the interference pigments so that they form an integral part of the platelets. Thus, for example, if Fe2O3 which has a yellow to red color depending on its particle size is precipitated upon a yellow interference color, an enhancement of the yellow color will be produced. The yellow of the Fe2O3 adds to the yellow of the interference color producing a rich lustrous yellow color. Those pigments which have an absorption pigment added to an interference pigment resulting in enhanced color intensity are called combination pigments.
- a colored oxide is used for the coating on mica, that color will combine with the added colorant and will modify the final absorption color. If a colorless oxide is used for the coating on mica, the absorption color will not be modified.
- the concentration of the absorption pigments is adjusted so that the color intensity produced is of the same order of magnitude as the interference colors. If the concentration of the colorants is too great, the absorption colorant will obscure the interference color and no enhancement will take place. In order for this enhancement to take place, the colorants are added at a concentration between about 2% and 5% in the case of TiO2 coated mica pigments, based upon the weight of titanium dioxide coated mica.
- the absorption pigment of the same color as the interference color can be added but difversferent absorption colorants can be added to different interferences colors.
- it is possible to add a red absorption pigment (carmine) to a blue interference pigment.
- the combination pigments When the combination pigments are dispersed in a film-forming medium and coated over a white background, two distinct colors can be observed depending on the angle of viewing. At the normal angle of viewing, the reflection color of the interference pigment is seen. At the diffuse angle or the grazing angle, the reflection color of the interference pigment is no longer observed and the color of the absorption pigment is now seen. Thus by changing the angle of viewing from the normal to a grazing angle, the color changes from the reflection color of the interference to the color of the absorption pigment. Very beautiful and esthetically pleasing color effects can be seen.
- Combination pigments have been used in applications such as coating on white, grey or black substrates or incorporating them into formulations used for cosmetic applications such as eye shadow, etc. where such color changes would be desirable.
- interference pigments made from titanium dioxide coated mica were used as base substrates.
- Four interference colors were used. They were yellow, red, blue and green.
- the absorption pigments which were used were a yellow (Fe2O3), a red (carmine), a blue (iron blue) and a green (Cr2O3).
- Each of the absorption colorants was precipitated upon the interference pigments forming a total of 16 samples.
- the concentration of the colorants ranged between 2% and 5%. Other colorants may be used in place of the colorants specified in these examples.
- the combination pigments were incorporated at 3% concentration into a nitrocellulose lacquer having a solids content of 9.5%.
- Films of the combination pigments dispersed in the nitrocellulose lacquer were formed on glass slides using a Bird Film Applicator. This formed a wet film of approximately 0.003 inch. The films were allowed to dry so that the platelets were aligned parallel to the film.
- the dried films were viewed visually in daylight by observing the specular reflection color at normal incidence, by observing the color at a diffuse or grazing angle and finally by observing the color by transmission.
- the observer stood with daylight at his back and the slide held so that the light struck the surface and was specularly reflected back to the observer.
- the slide was held toward the light so that the light fell upon the surface at a grazing angle and then was reflected to the observer.
- For transmission the slides were held to the light.
- the colors which were observed were recorded and the results of these observations are shown in Table I.
- Table I For comparison, the observations made on the interference pigments which contained no absorption pigments are also set forth. The combinations which exhibited the most distinct three-color effects are indicated by an asterisk.
- the combination pigments which have been used in the Table to demonstrate third color effects had the absorption pigments precipitated directly on the surfaces. Similar results can be achieved by dispersing the absorption colorants and the interference pigments separately in the film former. In this case, the absorption colorant is dispersed throughout the film rather than being concentrated upon each platelet. Similar, though not exactly equivalent, results are produced. As can be expected, different concentrations of colorant will be needed and these can be easily determined by a few routine experiments.
- any object which is transparent or semi-transparent and which will allow some of the light to pass through and which can be coated with the combination pigments or have them incorporated therein can be used.
- a combination pigment of a yellow absorption colorant and a red interference pigment was dispersed in a water base acrylic polymer emulsion.
- the dispersion was made by taking 3.0 g of the combination pigment, adding approximately 3 g of the emulsion and stirring in thoroughly. Then 94 g of the emulsion was slowly added with stirring to form a 3% concentration of the combination pigment in the emulsion.
- This pigmented emulsion was then applied by brush to a clear transparent acrylic sheet, one quarter inch in thickness, and the emulsion allowed to dry. Small sections were then cut from this sheet. Each of the sections when viewed at the specular angle showed a red interference color, a yellow color at the glancing angle and by transmission, a yellow-green color.
- a combination pigment of a red absorption colorant on a blue interference pigment was dispersed in a clear thermosetting acrylic enamel (AT56 Rohm & Haas Co.) and diluted in a ratio of 2:1 with xylene.
- the dispersion was made by taking 3.0 g of the combination pigment and adding approximately 3 g of the thermosetting acrylic which was stirred in thoroughly. Then 94 g of the acrylic enamel was added with stirring.
- the pigmented acrylic enamel was applied to a large transparent glass bowl approximately 24 inches in diameter.
- the coating was applied using a conventional air spray gun. Two layers were applied. The coating was then cured in an oven at 120°C for 30 minutes. Viewing the bowl directly a blue reflection color was seen. The sides of the bowl displayed a red absorption color and the rear of the bowl where the transmission color could be seen displayed an orange color.
- the colors blended one into the other and a pleasing artistic effect was produced which was a delight to the eye.
- the components of the combination pigment of Example 2 were introduced separately into the acrylic lacquer of that example.
- the red colorant was first dispersed followed by the blue interference pigment.
- the color play in the coated bowl was similar to that seen in Example 2.
- a combination pigment of a red absorption pigment on a yellow interference pigment was dispersed in a nitrocellulose lacquer.
- the dispersion was made by mixing 3.0 g of the pigment with 3 g of a nitrocellulose lacquer having a solids content of 9.5%. After thorough mixing, an additional 94 g of the nitrocellulose lacquer was added with stirring. Films of the dispersed particles in the nitrocellulose lacquer were formed on glass slides by using a Bird Film Applicator. This formed a wet film of approximately 0.003 inch. The films were allowed to air dry. The glass slides were then cut into rectangular sections, 2 inches by 3 inches, and provision made so the slides could be hung by a wire or string.
- a combination pigment of a blue colorant and green interference pigment was dispersed in a low density polyethylene. 950 g of Tenite 1925F made by Eastman Chemicals was put into a Banbury Mixer. The plastic was mixed until melted. 50 g of the combination pigment were then added slowly to the melted plastic and mixing was continued for 10 minutes. After the mixing cycle was complete, the pigmented plastic was dumped into a pan and taken immediately to a Boling Steward hot roll machine where the pigmented plastic was pressed between the 2 hot rolls to form a slab 1 ⁇ 4 to 1 ⁇ 2 inch in thickness and 10 inches wide. It was scored with a razor knife, allowed to cool, and broken into small pieces.
- the combination pigments can be applied to a substrate by methods which are known in the art.
- the coating methods include brush, roll, knife, pressure-roll, engraving roll, dipping, air blade, air spray, electrostatic spray, airless spray, fluidized bed and other similar methods.
- the pigmented plastics can also be molded by any of the known processes which include compression molding, injection molding, extrusion, or blow molding. They may also be cast by various processes.
- thermoplastics which can be used include cellulose acetate, cellulose acetate butyrate, polycarbonate, polyethylene, polypropylene, polystyrene, and similar materials.
- thermosetting plastics include epoxy resins, phenol-formaldehyde acrylic, polyesters, polystyrene, polyurethanes and similar products.
Abstract
Description
- Historically, interference pigments are an outgrowth of nacreous pigments, that is, pigments which simulate the effect of natural pearls. The pigments are composed of thin platelets which are transparent in the visible region of the spectrum. The platelets are very smooth and part of the light which strikes the platelets is reflected and part is transmitted through the platelet. That part of the light which is transmitted is subsequently reflected by other layers of platelets. The result is that there are multiple reflections from many layers and it is this which gives rise to a depth of sheen since the eye cannot focus on one particular layer.
- The reflection which takes place is specular in that the angle of incidence equals the angle of reflection. The amount of light reflected at non-specular angles is small and the amount of light reflected diminishes very quickly as the specular angle is passed. The result is that nacreous pigments are extremely sensitive to the angle of viewing. In order for the maximum amount of light to be reflected, the platelets must be extremely smooth. Any surface roughness causes light to be scattered in a non-specular manner and diminishes the lustrous effect.
- The platelets must be aligned parallel to each other and to the substrate for maximum reflectivity. If not so aligned, light will be reflected randomly and again, luster will diminish. The amount of light which is reflected depends on the index of refraction of the platelets. The greater the index of refraction, the greater the amount of light reflected. Since in most cases, the platelets are imbedded in film forming mediums which have an index of refraction of approximately 1.5, it is necessary that the index of refraction of the platelets be considerably greater than 1.5.
- In the case of the natural pearl, the layers of reflecting material are composed of calcium carbonate interspersed between layers of an organic material. Synthetic nacreous pigments have been made by growing crystals of basic lead carbonate and bismuth oxychloride. Both of these substances can be grown into crystals which are extremely smooth and flat. More recently, titanium dioxide, which per se has not been grown into flat crystals has been coated on thin smooth platelets of mica which act as a carrier. The mica platelets are ideally from 5 to 50 microns in length. The coatings of titanium dioxide which are applied generally range from 60 nanometers to 160 nanometers in thickness.
- It is found that with a coating of 60 nanometers of titanium dioxide on mica, a pearl or white lustrous pigment results. As the thickness of the titanium dioxide is increased, interference of light results and the colors of the rainbow are produced. Thus, it is possible to produce color using only a transparent layer of titanium dioxide. The colors seen from an oil slick or from a soap bubble are examples of interference colors. The colors from an oil slick or from a soap bubble disappear when the soap bubble collapses or the oil slick disappears. The colors from the interference pigments, however, are permanent and can be incorporated into film-forming mediums to impart color. Interference pigments not only impart color but because of their constitution, also impart luster.
- Other substances besides titanium dioxide can be used as the coating on mica. These include ZrO₂, SnO₂, ZnO, Fe₂O₃, Cr₂O₃, V₂O₅ and the hydrous forms thereof. The oxides can be present in various crystalline forms. For example, TiO₂ can be anatase or rutile or mixtures of the two. Combinations of oxides of two or more metals can be used as can their different crystalline forms.
- Interference pigments, if composed of the correct thickness, can reflect any color of the visible spectrum. These colors can range from a yellow to a red to a blue and a green. Shadings between these are also possible. Because the reflected colors are produced by an interference effect, the complementary colors are produced by transmission. Thus if a red color is produced by reflection from an interference pigment, a green color will be seen if the pigment is viewed in transmission.
- If interference pigments are incorporated into film formers and coated on white backgrounds, then two colors can be seen depending on the angle of viewing. At near specular angles, the reflected color can be observed. At other angles, the transmission color can be observed.
- In order to enhance the reflection color, absorption pigments have been added to interference pigments. In most cases, the absorption pigments have been precipitated onto the interference pigments so that they form an integral part of the platelets. Thus, for example, if Fe₂O₃ which has a yellow to red color depending on its particle size is precipitated upon a yellow interference color, an enhancement of the yellow color will be produced. The yellow of the Fe₂O₃ adds to the yellow of the interference color producing a rich lustrous yellow color. Those pigments which have an absorption pigment added to an interference pigment resulting in enhanced color intensity are called combination pigments.
- Other colorants besides Fe₂O₃ have been used. In order to enhance the red interference color, carmine, an organic red colorant, is added to a red interference pigment. In order to enhance the blue, iron blue is added, and in order to enhance the green, Cr₂O₃ is added.
- If a colored oxide is used for the coating on mica, that color will combine with the added colorant and will modify the final absorption color. If a colorless oxide is used for the coating on mica, the absorption color will not be modified.
- The concentration of the absorption pigments is adjusted so that the color intensity produced is of the same order of magnitude as the interference colors. If the concentration of the colorants is too great, the absorption colorant will obscure the interference color and no enhancement will take place. In order for this enhancement to take place, the colorants are added at a concentration between about 2% and 5% in the case of TiO₂ coated mica pigments, based upon the weight of titanium dioxide coated mica.
- Not only can the absorption pigment of the same color as the interference color be added but different absorption colorants can be added to different interferences colors. Thus, for example, it is possible to add a red absorption pigment (carmine) to a blue interference pigment.
- When absorption colorants differ in color from the interference color, interesting color effects are produced depending on the background and the angle of viewing. Since the concentration of the colorants is quite low, when the combination pigments are displayed over a black background, the black absorbs the color of the colorant and only the reflection color of the interference is observed. This is true whether the pigments are observed at the normal angle or the grazing angle.
- When the combination pigments are dispersed in a film-forming medium and coated over a white background, two distinct colors can be observed depending on the angle of viewing. At the normal angle of viewing, the reflection color of the interference pigment is seen. At the diffuse angle or the grazing angle, the reflection color of the interference pigment is no longer observed and the color of the absorption pigment is now seen. Thus by changing the angle of viewing from the normal to a grazing angle, the color changes from the reflection color of the interference to the color of the absorption pigment. Very beautiful and esthetically pleasing color effects can be seen.
- Combination pigments have been used in applications such as coating on white, grey or black substrates or incorporating them into formulations used for cosmetic applications such as eye shadow, etc. where such color changes would be desirable.
- It has now been discovered that there is a third color which is formed and that is the subject of this invention. If the known combination pigments are incorporated into a transparent film-forming medium and coated on a transparent substrate such as glass, acrylic sheet etc. a third color can be seen. This third color is different in color from both the reflection color and the color of the absorption pigment. The third color is formed from the mixing of the transmis sion color of the interference pigment with the color of the absorption pigment. These third colors have, heretofore, not been seen because combination pigments are not used on transparent substrates.
- In order to demonstrate the colors which are formed, interference pigments made from titanium dioxide coated mica were used as base substrates. Four interference colors were used. They were yellow, red, blue and green. The absorption pigments which were used were a yellow (Fe₂O₃), a red (carmine), a blue (iron blue) and a green (Cr₂O₃). Each of the absorption colorants was precipitated upon the interference pigments forming a total of 16 samples. The concentration of the colorants ranged between 2% and 5%. Other colorants may be used in place of the colorants specified in these examples.
- After appropriate processing, the combination pigments were incorporated at 3% concentration into a nitrocellulose lacquer having a solids content of 9.5%. Films of the combination pigments dispersed in the nitrocellulose lacquer were formed on glass slides using a Bird Film Applicator. This formed a wet film of approximately 0.003 inch. The films were allowed to dry so that the platelets were aligned parallel to the film.
- The dried films were viewed visually in daylight by observing the specular reflection color at normal incidence, by observing the color at a diffuse or grazing angle and finally by observing the color by transmission. The observer stood with daylight at his back and the slide held so that the light struck the surface and was specularly reflected back to the observer. For diffuse reflection, the slide was held toward the light so that the light fell upon the surface at a grazing angle and then was reflected to the observer. For transmission, the slides were held to the light. The colors which were observed were recorded and the results of these observations are shown in Table I. For comparison, the observations made on the interference pigments which contained no absorption pigments are also set forth. The combinations which exhibited the most distinct three-color effects are indicated by an asterisk.
- These examples demonstrate that when the color of the absorption pigment is different from the reflecting color of the interference pigment or its complement (the transmission color), a new color is formed. Thus, a red colorant precipitated on a yellow interference pigment (transmission color blue) formed a third color, purple, by transmission. A green colorant on the same yellow interference pigment formed a blue-green color by transmission.
- From the foregoing, it can be seen that various shades are possible depending on the identity and concentration of absorption colorant used. A greater concentration of colorant will tend to shade the color in the direction of the colorant. If too great a concentration of colorant is used, the transmission color will be masked and obscured and only the absorption colorant will be seen. The concentration of the absorption colorant is therefore determined by the intensity of the transmission color. For the commercially available interference pigments, a concentration of absorption pigment varying between 2% and 5% has been found to produce interesting third colors.
- The combination pigments which have been used in the Table to demonstrate third color effects had the absorption pigments precipitated directly on the surfaces. Similar results can be achieved by dispersing the absorption colorants and the interference pigments separately in the film former. In this case, the absorption colorant is dispersed throughout the film rather than being concentrated upon each platelet. Similar, though not exactly equivalent, results are produced. As can be expected, different concentrations of colorant will be needed and these can be easily determined by a few routine experiments.
- Any object which is transparent or semi-transparent and which will allow some of the light to pass through and which can be coated with the combination pigments or have them incorporated therein can be used. This includes glass bottles, glass sheets, sheets of transparent acrylic, polyester, etc.
- A combination pigment of a yellow absorption colorant and a red interference pigment was dispersed in a water base acrylic polymer emulsion. The dispersion was made by taking 3.0 g of the combination pigment, adding approximately 3 g of the emulsion and stirring in thoroughly. Then 94 g of the emulsion was slowly added with stirring to form a 3% concentration of the combination pigment in the emulsion. This pigmented emulsion was then applied by brush to a clear transparent acrylic sheet, one quarter inch in thickness, and the emulsion allowed to dry. Small sections were then cut from this sheet. Each of the sections when viewed at the specular angle showed a red interference color, a yellow color at the glancing angle and by transmission, a yellow-green color.
- Similar sections were made using different combination pigments. The sections were mounted on a large acrylic panel to simulate a stained glass effect depicting various scenes.
- A combination pigment of a red absorption colorant on a blue interference pigment was dispersed in a clear thermosetting acrylic enamel (AT56 Rohm & Haas Co.) and diluted in a ratio of 2:1 with xylene. The dispersion was made by taking 3.0 g of the combination pigment and adding approximately 3 g of the thermosetting acrylic which was stirred in thoroughly. Then 94 g of the acrylic enamel was added with stirring. The pigmented acrylic enamel was applied to a large transparent glass bowl approximately 24 inches in diameter. The coating was applied using a conventional air spray gun. Two layers were applied. The coating was then cured in an oven at 120°C for 30 minutes. Viewing the bowl directly a blue reflection color was seen. The sides of the bowl displayed a red absorption color and the rear of the bowl where the transmission color could be seen displayed an orange color. The colors blended one into the other and a pleasing artistic effect was produced which was a delight to the eye.
- The components of the combination pigment of Example 2 were introduced separately into the acrylic lacquer of that example. The red colorant was first dispersed followed by the blue interference pigment. The color play in the coated bowl was similar to that seen in Example 2.
- A combination pigment of a red absorption pigment on a yellow interference pigment was dispersed in a nitrocellulose lacquer. The dispersion was made by mixing 3.0 g of the pigment with 3 g of a nitrocellulose lacquer having a solids content of 9.5%. After thorough mixing, an additional 94 g of the nitrocellulose lacquer was added with stirring. Films of the dispersed particles in the nitrocellulose lacquer were formed on glass slides by using a Bird Film Applicator. This formed a wet film of approximately 0.003 inch. The films were allowed to air dry. The glass slides were then cut into rectangular sections, 2 inches by 3 inches, and provision made so the slides could be hung by a wire or string.
- Similar slides were made using the combination pigment of a red colorant on a yellow interference pigment and the combination pigment of a yellow colorant on a red interference pigment. The slides were then hung from strings as in a mobile and beautiful color effects could be seen as each slide, revolving slowly by air currents, alternately showed various colors by reflection and transmission.
- A combination pigment of a blue colorant and green interference pigment was dispersed in a low density polyethylene. 950 g of Tenite 1925F made by Eastman Chemicals was put into a Banbury Mixer. The plastic was mixed until melted. 50 g of the combination pigment were then added slowly to the melted plastic and mixing was continued for 10 minutes. After the mixing cycle was complete, the pigmented plastic was dumped into a pan and taken immediately to a Boling Steward hot roll machine where the pigmented plastic was pressed between the 2 hot rolls to form a slab ¼ to ½ inch in thickness and 10 inches wide. It was scored with a razor knife, allowed to cool, and broken into small pieces. It was then granulated in a Cumberland Granulator. After granulation, the material was taken to a Killian Extruder where it was extruded from a sheeting die forming a sheet approximately 4 mils in thickness. A green color was observed at the specular angle, a blue color at a glancing angle and by transmission, a purple color was seen. Similar sheets could be made using different combination pigments and all could be cut into different patterns and suitably mounted on a clear substrate (for example between 2 pieces of glass) to form an art work which had a myriad of colors.
- From the examples set forth hereinbefore, it can be seen that the combination pigments can be applied to a substrate by methods which are known in the art. The coating methods include brush, roll, knife, pressure-roll, engraving roll, dipping, air blade, air spray, electrostatic spray, airless spray, fluidized bed and other similar methods. The pigmented plastics can also be molded by any of the known processes which include compression molding, injection molding, extrusion, or blow molding. They may also be cast by various processes.
- The thermoplastics which can be used include cellulose acetate, cellulose acetate butyrate, polycarbonate, polyethylene, polypropylene, polystyrene, and similar materials. The thermosetting plastics include epoxy resins, phenol-formaldehyde acrylic, polyesters, polystyrene, polyurethanes and similar products.
TABLE I VISUAL OBSERVATIONS OF COATED GLASS SLIDES Color Reflection Color at Normal Incidence Color at Diffuse Angle, Appx.-15/60 Transmission Color Interference Gold (IY) Yellow White Blue IY & Yellow Colorant Yellow Yellow Neutral IY & Red Colorant Yellow Red Purple* IY & Blue Colorant Yellow Blue Blue IY & Green Colorant Yellow Green Blue-Green Interference Red (IR) Red White Green IR & Yellow Colorant Red Yellow Yellow-Green* IR & Red Colorant Red Red Neutral IR & Blue Colorant Red Blue Blue-Green* IR & Green Colorant Red Green Green Interference Blue (IB) Blue Sl.Yellow Yellow IB & Yellow Colorant Blue Yellow Yellow IB & Red Colorant Blue Red Orange* IB & Blue Colorant Blue Blue Blue-Green IB & Green Colorant Blue Green Yellow-Green* Interference Green (IG) Green White Purple IG & Yellow Colorant Yel-Green Yellow Orange* IG & Red Colorant Green Red Red IG & Blue Colorant Green Blue Blue-Purple* IG & Green Colorant Green Green Orange
Claims (19)
Applications Claiming Priority (2)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
US7002287A | 1987-07-06 | 1987-07-06 | |
US70022 | 1987-07-06 |
Publications (3)
Publication Number | Publication Date |
---|---|
EP0298604A2 true EP0298604A2 (en) | 1989-01-11 |
EP0298604A3 EP0298604A3 (en) | 1990-10-10 |
EP0298604B1 EP0298604B1 (en) | 1994-05-18 |
Family
ID=22092636
Family Applications (1)
Application Number | Title | Priority Date | Filing Date |
---|---|---|---|
EP88305170A Expired - Lifetime EP0298604B1 (en) | 1987-07-06 | 1988-06-07 | Decorative objects with multicolor effects |
Country Status (6)
Country | Link |
---|---|
EP (1) | EP0298604B1 (en) |
JP (1) | JPH0777840B2 (en) |
AT (1) | ATE105787T1 (en) |
CA (1) | CA1324241C (en) |
DE (1) | DE3889592T2 (en) |
ES (1) | ES2051849T3 (en) |
Cited By (6)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
GB2249974A (en) * | 1990-11-20 | 1992-05-27 | Swintex | Coloured material |
EP1200250A1 (en) * | 1999-06-14 | 2002-05-02 | CPFilms, Inc. | Light-stable colored transparent composite films |
EP1047371B1 (en) * | 1998-06-24 | 2006-03-29 | Color Access, Inc. | Natural look cosmetic compositions |
US7064897B2 (en) * | 2002-12-31 | 2006-06-20 | 3M Innovative Properties Company | Optical polarizing films with designed color shifts |
US20110118384A1 (en) * | 2008-05-09 | 2011-05-19 | Basf Se | Pearlescent pigments coated with a metal oxide/hydroxide layer and an acrylic copolymer |
KR102123940B1 (en) * | 2019-10-16 | 2020-06-17 | 이윤정 | Decoration Panel Using Lacquer Screen Printing and Mother-of-pearl and Manufacturing Method Thereof |
Citations (5)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
US3087828A (en) * | 1961-06-28 | 1963-04-30 | Du Pont | Nacreous pigment compositions |
GB1141981A (en) * | 1966-01-21 | 1969-02-05 | Dow Chemical Co | Iridescent bodies and coating compositions and composite structures comprising them |
DE2313331A1 (en) * | 1973-03-17 | 1974-09-19 | Merck Patent Gmbh | FERROUS MICA SCALE PIGMENTS |
EP0075755A2 (en) * | 1981-09-23 | 1983-04-06 | MERCK PATENT GmbH | Light-stable nacreous pigments, process for their manufacture and their use |
EP0211351B1 (en) * | 1985-08-07 | 1990-10-24 | MERCK PATENT GmbH | Nacreous pigments coated with iron oxide |
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1988
- 1988-06-06 JP JP63139202A patent/JPH0777840B2/en not_active Expired - Lifetime
- 1988-06-07 ES ES88305170T patent/ES2051849T3/en not_active Expired - Lifetime
- 1988-06-07 AT AT88305170T patent/ATE105787T1/en not_active IP Right Cessation
- 1988-06-07 DE DE3889592T patent/DE3889592T2/en not_active Expired - Lifetime
- 1988-06-07 EP EP88305170A patent/EP0298604B1/en not_active Expired - Lifetime
- 1988-07-05 CA CA000571179A patent/CA1324241C/en not_active Expired - Fee Related
Patent Citations (5)
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US3087828A (en) * | 1961-06-28 | 1963-04-30 | Du Pont | Nacreous pigment compositions |
GB1141981A (en) * | 1966-01-21 | 1969-02-05 | Dow Chemical Co | Iridescent bodies and coating compositions and composite structures comprising them |
DE2313331A1 (en) * | 1973-03-17 | 1974-09-19 | Merck Patent Gmbh | FERROUS MICA SCALE PIGMENTS |
EP0075755A2 (en) * | 1981-09-23 | 1983-04-06 | MERCK PATENT GmbH | Light-stable nacreous pigments, process for their manufacture and their use |
EP0211351B1 (en) * | 1985-08-07 | 1990-10-24 | MERCK PATENT GmbH | Nacreous pigments coated with iron oxide |
Cited By (12)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
GB2249974A (en) * | 1990-11-20 | 1992-05-27 | Swintex | Coloured material |
GB2249974B (en) * | 1990-11-20 | 1994-10-12 | Swintex | Coloured material |
EP1047371B1 (en) * | 1998-06-24 | 2006-03-29 | Color Access, Inc. | Natural look cosmetic compositions |
EP1200250A1 (en) * | 1999-06-14 | 2002-05-02 | CPFilms, Inc. | Light-stable colored transparent composite films |
EP1200250A4 (en) * | 1999-06-14 | 2005-05-25 | Cpfilms Inc | Light-stable colored transparent composite films |
US7229684B2 (en) | 1999-06-14 | 2007-06-12 | Cpfilms, Inc. | Light-stable colored transparent composite films |
US7064897B2 (en) * | 2002-12-31 | 2006-06-20 | 3M Innovative Properties Company | Optical polarizing films with designed color shifts |
US7256936B2 (en) | 2002-12-31 | 2007-08-14 | 3M Innovative Properties Company | Optical polarizing films with designed color shifts |
US7744987B2 (en) | 2002-12-31 | 2010-06-29 | 3M Innovative Properties Company | Optical polarizing films |
US20110118384A1 (en) * | 2008-05-09 | 2011-05-19 | Basf Se | Pearlescent pigments coated with a metal oxide/hydroxide layer and an acrylic copolymer |
US8772371B2 (en) * | 2008-05-09 | 2014-07-08 | Basf Se | Pearlescent pigments coated with a metal oxide/hydroxide layer and an acrylic copolymer |
KR102123940B1 (en) * | 2019-10-16 | 2020-06-17 | 이윤정 | Decoration Panel Using Lacquer Screen Printing and Mother-of-pearl and Manufacturing Method Thereof |
Also Published As
Publication number | Publication date |
---|---|
JPH0777840B2 (en) | 1995-08-23 |
DE3889592D1 (en) | 1994-06-23 |
DE3889592T2 (en) | 1994-09-01 |
JPS6424800A (en) | 1989-01-26 |
EP0298604B1 (en) | 1994-05-18 |
CA1324241C (en) | 1993-11-16 |
ATE105787T1 (en) | 1994-06-15 |
EP0298604A3 (en) | 1990-10-10 |
ES2051849T3 (en) | 1994-07-01 |
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