EP0404011A2 - A kneaded moldable resin composition - Google Patents

A kneaded moldable resin composition Download PDF

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Publication number
EP0404011A2
EP0404011A2 EP90111443A EP90111443A EP0404011A2 EP 0404011 A2 EP0404011 A2 EP 0404011A2 EP 90111443 A EP90111443 A EP 90111443A EP 90111443 A EP90111443 A EP 90111443A EP 0404011 A2 EP0404011 A2 EP 0404011A2
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EP
European Patent Office
Prior art keywords
kneaded
weight parts
resin composition
formula
ethylene
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Withdrawn
Application number
EP90111443A
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German (de)
French (fr)
Other versions
EP0404011A3 (en
Inventor
Akitaka Senume
Kiroku Tsukada
Isoa Noda
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
NUC Corp
Original Assignee
Nippon Unicar Co Ltd
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Publication date
Application filed by Nippon Unicar Co Ltd filed Critical Nippon Unicar Co Ltd
Publication of EP0404011A2 publication Critical patent/EP0404011A2/en
Publication of EP0404011A3 publication Critical patent/EP0404011A3/en
Withdrawn legal-status Critical Current

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    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
    • C08L23/00—Compositions of homopolymers or copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond; Compositions of derivatives of such polymers
    • C08L23/02—Compositions of homopolymers or copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond; Compositions of derivatives of such polymers not modified by chemical after-treatment
    • C08L23/04—Homopolymers or copolymers of ethene
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
    • C08K5/00—Use of organic ingredients
    • C08K5/01—Hydrocarbons
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
    • C08L23/00—Compositions of homopolymers or copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond; Compositions of derivatives of such polymers
    • C08L23/02—Compositions of homopolymers or copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond; Compositions of derivatives of such polymers not modified by chemical after-treatment
    • C08L23/04—Homopolymers or copolymers of ethene
    • C08L23/08—Copolymers of ethene
    • C08L23/0807—Copolymers of ethene with unsaturated hydrocarbons only containing more than three carbon atoms
    • C08L23/0815—Copolymers of ethene with aliphatic 1-olefins
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
    • C08L23/00—Compositions of homopolymers or copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond; Compositions of derivatives of such polymers
    • C08L23/02—Compositions of homopolymers or copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond; Compositions of derivatives of such polymers not modified by chemical after-treatment
    • C08L23/04—Homopolymers or copolymers of ethene
    • C08L23/08—Copolymers of ethene
    • C08L23/0846—Copolymers of ethene with unsaturated hydrocarbons containing other atoms than carbon or hydrogen atoms
    • C08L23/0853—Vinylacetate
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
    • C08L25/00—Compositions of, homopolymers or copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and at least one being terminated by an aromatic carbocyclic ring; Compositions of derivatives of such polymers
    • C08L25/02—Homopolymers or copolymers of hydrocarbons
    • C08L25/04—Homopolymers or copolymers of styrene
    • C08L25/06—Polystyrene
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
    • C08L83/00—Compositions of macromolecular compounds obtained by reactions forming in the main chain of the macromolecule a linkage containing silicon with or without sulfur, nitrogen, oxygen or carbon only; Compositions of derivatives of such polymers
    • C08L83/04—Polysiloxanes
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
    • C08G77/00—Macromolecular compounds obtained by reactions forming a linkage containing silicon with or without sulfur, nitrogen, oxygen or carbon in the main chain of the macromolecule
    • C08G77/04—Polysiloxanes
    • C08G77/20—Polysiloxanes containing silicon bound to unsaturated aliphatic groups

Definitions

  • This invention relates to a kneaded moldable resin composition which can be molded into films and tubes. Specifically this invention relates to a kneaded moldable resin composition comprising polyethylene resin, a polysiloxane polymer, and a compound having unsaturated groups on both ends thereof.
  • Silicone has been widely used because of its good characteristics, such as slipping properties, mold release properties, oxygen permeability, water repellency, electric insulativeness, etc. But its low mechanical strength, the difficulty of being formed into film, and poor moldability are drawbacks of silicone.
  • An object of this invention is to provide a resin which improves the drawbacks of low mechanical strength, poor film forming property, poor moldability, etc. inherent to silicone.
  • the kneaded composition according to this invention is moldable into films, sheets, tubes, etc., and the resultant moldings exhibit properties inherent to silicone.
  • the composition is applicable to medical parts, industrial parts, electric parts, etc.
  • the composition is usable as a modifier for improving the moldability and impact strength of the engineering plastics.
  • the inventors have studied to prepare a kneaded moldable resin which will improve the disadvantages inherent to silicone of low mechanical strength, film moldability and moldability, etc. and have successfully made this invention.
  • This invention provides a kneaded moldable composition
  • the kneaded resin composition according to this invention is moldable into films, tubes, etc.
  • the moldings of the kneaded resin composition have an ethylene polymer and an organosilicon compound mixed not in insufficiently macro-distributed states but homogeneously.
  • the kneaded resin composition according to this invention can be mixed with, e.g., polystyrene, nylon, polyester, polycarbonate or others so as to improve the moldability and impact resistance of the latter.
  • the ethylene polymer used in the composition according to this invention contains ethylene as the main component and is exemplified by high-pressure process polyethylene, linear low-density polyethylene (LLDPE), ethylene- ⁇ -olefin copolymer, ethylene-vinyl acetate copolymer, ethylene-acrylic acid copolymer, ethylene-methacrylic acid copolymer, ethylene-methyl acrylate copolymer, ethylene-methyl methacrylate copolymer, ethylene-ethyl acrylate copolymer, ethylene-ethyl methacrylate, ethylene-vinyl alcohol copolymer, ethylene-propylene-diene terpolymer, etc.
  • LLDPE linear low-density polyethylene
  • ethylene- ⁇ -olefin copolymer ethylene-vinyl acetate copolymer
  • ethylene-acrylic acid copolymer ethylene-methacrylic acid copolymer
  • the R1 group is exemplified by vinyl group, acryl group, methacryl group, etc.; and the R2 group is exemplified by alkyl group, such as methyl, acryl, methacryl and others, by aryl group, such as phenyl, tryl and others, b cycloalkyl group such as cyclohexyl, cyclobutyl and others, and by groups having hydrogen groups bonding with carbon atoms of the above-listed hydrocarbon groups partially substituted with halogen atoms, cyano groups, mercapto groups and others, the R2 being combinations of the same kind groups or different kind groups.
  • a is larger than 0 and smaller than 1 exclusive of 1.
  • a is 0, unpreferably the ethylenepolymer and the hydrocarbon compound expressed by Formula (B) do not react with each other.
  • a is 1 or larger than 1, unpreferably the molding produced from the composition according to this invention is too hard.
  • a is 0.0004 - 0.06.
  • b is larger than 0.5 inclusive of 0.5 and smaller than 3 exclusive of 3.
  • b is smaller than 0.5 inclusive of 0.5, the composition according to this invention cannot be kneaded readily and has poor moldability.
  • b is larger than 3 inclusive of 3, unpreferably the molding produced from the comnposition according to this invention is too hard.
  • b is 1 - 2.
  • the organopolysiloxane used in this invention may have a chain molecular structure, branched chain molecular structure, cyclic molecular structure, recticular molecular structure, stereorecticular molecular structure, etc.
  • the polymerization ratio of the organopolysiloxane used in this invention is not specifically limited by a suitable polymerization ratio which does not bother its kneading with the ethylene polymer.
  • the polymerization ratio is above 250.
  • the hydrocarbon compound expressed by Formula (B) used in this invention is exemplified by 1,4-pentadiene, 1,5 hexadiene, 1,6-heptadiene, 1,7-octadiene, 1,8-nonadiene, 1,9-decadiene, 1,10-undecadiene, 1,11-dodecadiene, 1,12-tridecadiene, 1,13-tetradecadiene, or others.
  • the organopolysiloxane expressed by Formula (A) used in this invention is added by more 0.01 weight parts, preferably 0.05 - 300 weight parts, to 100 weight parts of the ethylene polymer.
  • the organopolysiloxane is added by less than 0.01 weight parts, the resultant resin does not exhibit properties inherent to silicone readily.
  • the resultant resin cannot be molded into film easily.
  • the hydrocarbon expressed by Formula (B) used in this invention is added by more than 0.01 weight parts.
  • a numbers of masses of the crosslinked silicone are created.
  • the kneaded resin composition according to this invention may contain oxidation stabilizers, UV stabilizers, inorganic fillers, pigments, flame retarders, rubbers, etc.
  • the kneaded resin composition according to this invention can be molded by the injection molding, blow molding, etxtrusion molding, etc.
  • the composition is heat-kneaded by usual kneaders, such as Banbury mixers, twin-screw extruders, etc.
  • the heating temperature is as low as possible.
  • a temperature lower than 170 °C is preferable. If it is heated at a tempe­rature higher than 170 °C, the decomposition odor will beco­me stronger.
  • the heating period of time is more than 30 minutes.
  • This sheet had little decomposition odor and no inhomogeneous portions.
  • the resultant kneaded composition had a melt index of 0.2 g/10 mins., a tensile strength of 60 kg/cm2 and an elongation of 500 %.
  • the resultant sheet had no exudation of the silicone on the surfaces.
  • This sheet was pelletized, and the pellets could be extruded into a tape at 160 °C by the extruder of a Brabender Plastograph.
  • Example 2 In the same was as in Example 1, the components except the 1,9-decadiene were kneaded to be formed into a sheet.
  • the sheet partially had masses of crosslinked organosilicone compound having diameters of 0.1 - 0.5 mm, and the resultant sheet was not homogeneous.
  • the resultant kneaded composition had a melt index of 0.1 g/10 mins., a tensile strength of 70 kg/cm2, an elongation of 300 %.
  • the resultant sheet had no exudation of the silicone. This sheet was formed in to pellets, and the pellets could be formed into a tape at 160 °C°Cby the extruder of a Brabender Plastograph.
  • IRGANOX 1010 an antioxidant made by CibaGaigy
  • the resultant kneaded composition had a melt index of 0.2 g/10 mins., a tensile strength of 50 kg/cm2 and an elongation of 600 %.
  • the resultant sheet had substantially no exudation of the silicone. This sheet was formed into pellets, and the pellets were formed into a tape at 160 °C by the extrduer of a Brabender Plastograph.

Abstract

A kneaded moldable resin composition comprising 100 weight parts of an ethylene polymer; 0.01 - 300 weight parts of an organopolysiloxane expressed by the formula
Figure imga0001
 (where R¹ is an aliphatic unsaturated group, R² is a substituted or unsubstituted monovalent hydrocarbon group containing no aliphatic unsaturated group, 0<a<1, 0.5<b<3, and 1<a+b<3); 0.01 - 30 weight parts of a hydrocarbon compound expressed by the formula
CH₂ = CH(CH₂)cCH = CH₂      (B)
(where c is an integer of 1 - 30) which are heat-kneaded with each other.

Description

    BACKGROUND OF THE INVENTION Field of Industrial Uses
  • This invention relates to a kneaded moldable resin composition which can be molded into films and tubes. Specifically this invention relates to a kneaded moldable resin composition comprising polyethylene resin, a polysiloxane polymer, and a compound having unsaturated groups on both ends thereof.
    • Prior Art
  • Silicone has been widely used because of its good characteristics, such as slipping properties, mold release properties, oxygen permeability, water repellency, electric insulativeness, etc. But its low mechanical strength, the difficulty of being formed into film, and poor moldability are drawbacks of silicone.
    • OBJECTIVES
  • An object of this invention is to provide a resin which improves the drawbacks of low mechanical strength, poor film forming property, poor moldability, etc. inherent to silicone.
    • SUMMARY
  • The kneaded composition according to this invention is moldable into films, sheets, tubes, etc., and the resultant moldings exhibit properties inherent to silicone. The composition is applicable to medical parts, industrial parts, electric parts, etc. Besides, the composition is usable as a modifier for improving the moldability and impact strength of the engineering plastics.
    • DETAILED DESCRIPTION
  • The inventors have studied to prepare a kneaded moldable resin which will improve the disadvantages inherent to silicone of low mechanical strength, film moldability and moldability, etc. and have successfully made this invention.
  • This invention provides a kneaded moldable composition comprising 100 weight parts of an organopolysiloxane expressed by the formula
    Figure imgb0001
     (wherein R¹ is an aliphatic unsaturated group, R² is a substituted or unsubstituted monovalent hydrocarbon group containing no aliphatic unsaturated group, 0<a<1, 0.5<b<3, and 1<a+b<3); and 0.01 - 30 weight parts of a hydrocarbon compound expressed by the formula
    CH₂=CH(CH₂)cCH=CH₂      (B)
    (where c is an integer of 1 - 30)which are heat-kneaded, and moldings of the kneaded resin composition.
  • The kneaded resin composition according to this invention is moldable into films, tubes, etc. The moldings of the kneaded resin composition have an ethylene polymer and an organosilicon compound mixed not in insufficiently macro-distributed states but homogeneously.
  • When an ethylene polymer, and an organopolysiloxane expressed by Formula (A) are kneaded by a Banbury mixer, the mixer slips, and they are difficult to be kneaded, and even if they are kneaded, the reaction do not take place readily. But, when an organic peroxide is added, the torque increases in a short period of time, and the reaction starts. The ehtylene polymer and the organopolysiloxane compound are combined. But a number of masses of the crosslinked silicone are created, and a homogeneous resin cannot be produced readily.
  • In order to overcome this phenomenon, the inventors have studied and found that the addition of a hydrocarbon compound expressed by Formula (B) enables a resultant resin to be homogeneous with almost no masses of crosslinked silicone. The kneaded resin composition of this invention is moldable into films and tubes by the usual molding machines for molding polyethylene, etc. The resultant films and tubes are homogeneous with substantially no masses of crosslinked silicone.
  • The kneaded resin composition according to this invention can be mixed with, e.g., polystyrene, nylon, polyester, polycarbonate or others so as to improve the moldability and impact resistance of the latter.
  • The ethylene polymer used in the composition according to this invention contains ethylene as the main component and is exemplified by high-pressure process polyethylene, linear low-density polyethylene (LLDPE), ethylene-α-olefin copolymer, ethylene-vinyl acetate copolymer, ethylene-acrylic acid copolymer, ethylene-methacrylic acid copolymer, ethylene-methyl acrylate copolymer, ethylene-methyl methacrylate copolymer, ethylene-ethyl acrylate copolymer, ethylene-ethyl methacrylate, ethylene-vinyl alcohol copolymer, ethylene-propylene-diene terpolymer, etc.
  • In the organopolysiloxane expressed by Formula (A) which is used in this invention, the R¹ group is exemplified by vinyl group, acryl group, methacryl group, etc.; and the R² group is exemplified by alkyl group, such as methyl, acryl, methacryl and others, by aryl group, such as phenyl, tryl and others, b cycloalkyl group such as cyclohexyl, cyclobutyl and others, and by groups having hydrogen groups bonding with carbon atoms of the above-listed hydrocarbon groups partially substituted with halogen atoms, cyano groups, mercapto groups and others, the R² being combinations of the same kind groups or different kind groups.
  • a is larger than 0 and smaller than 1 exclusive of 1. When a is 0, unpreferably the ethylenepolymer and the hydrocarbon compound expressed by Formula (B) do not react with each other. When a is 1 or larger than 1, unpreferably the molding produced from the composition according to this invention is too hard. Preferably a is 0.0004 - 0.06. It is preferable that b is larger than 0.5 inclusive of 0.5 and smaller than 3 exclusive of 3. When b is smaller than 0.5 inclusive of 0.5, the composition according to this invention cannot be kneaded readily and has poor moldability. When b is larger than 3 inclusive of 3, unpreferably the molding produced from the comnposition according to this invention is too hard. Preferably b is 1 - 2.
  • The organopolysiloxane used in this invention may have a chain molecular structure, branched chain molecular structure, cyclic molecular structure, recticular molecular structure, stereorecticular molecular structure, etc.
  • The polymerization ratio of the organopolysiloxane used in this invention is not specifically limited by a suitable polymerization ratio which does not bother its kneading with the ethylene polymer. Preferably the polymerization ratio is above 250.
  • The hydrocarbon compound expressed by Formula (B) used in this invention is exemplified by 1,4-pentadiene, 1,5 hexadiene, 1,6-heptadiene, 1,7-octadiene, 1,8-nonadiene, 1,9-decadiene, 1,10-undecadiene, 1,11-dodecadiene, 1,12-tridecadiene, 1,13-tetradecadiene, or others.
  • The organopolysiloxane expressed by Formula (A) used in this invention is added by more 0.01 weight parts, preferably 0.05 - 300 weight parts, to 100 weight parts of the ethylene polymer. When the organopolysiloxane is added by less than 0.01 weight parts, the resultant resin does not exhibit properties inherent to silicone readily. When it is added by more than 300 weight parts, the resultant resin cannot be molded into film easily.
  • The hydrocarbon expressed by Formula (B) used in this invention is added by more than 0.01 weight parts. When the hydrocarbon is added by less than 0.01 weight parts, a numbers of masses of the crosslinked silicone are created.
  • The kneaded resin composition according to this invention may contain oxidation stabilizers, UV stabilizers, inorganic fillers, pigments, flame retarders, rubbers, etc.
  • The kneaded resin composition according to this invention can be molded by the injection molding, blow molding, etxtrusion molding, etc. The composition is heat-kneaded by usual kneaders, such as Banbury mixers, twin-screw extruders, etc.
  • It is preferable that the heating temperature is as low as possible. For example, when ethylene-vinyl acetate copolymer is chose as the ethylene polymer, a temperature lower than 170 °C is preferable. If it is heated at a tempe­rature higher than 170 °C, the decomposition odor will beco­me stronger. Preferably the heating period of time is more than 30 minutes.
    • EXAMPLES Example 1
  • One hundred (100) weight parts of ethylene-vinyl acetate copolymer (made by Nippon Unicar) having a melt index of 2.5 g/10 mins. (190 °C, 2160 g) and 18 wt% of vinyl acetate content, 100 weight parts of silicone gum stock (made by Nippon Unicar) having a viscosity of 300,000 CS at 23 °C and a 1:0 % of methyl vinylsilicone, 1 part of 1,9-decadiene, and 0.1 parts of IRGANOX 1010 (an antioxidant made by Ciba Gaigy) were kneaded at 100 °C for 10 minutes and at 165 °C for 70 minutes to be formed by the compression molding into a 1 mm-thick sheet. This sheet had little decomposition odor and no inhomogeneous portions. The resultant kneaded composition had a melt index of 0.2 g/10 mins., a tensile strength of 60 kg/cm² and an elongation of 500 %. The resultant sheet had no exudation of the silicone on the surfaces. This sheet was pelletized, and the pellets could be extruded into a tape at 160 °C by the extruder of a Brabender Plastograph.
    • Control 1
  • In the same was as in Example 1, the components except the 1,9-decadiene were kneaded to be formed into a sheet. The sheet partially had masses of crosslinked organosilicone compound having diameters of 0.1 - 0.5 mm, and the resultant sheet was not homogeneous.
    • Example 2
  • One hundred (100) weight parts of ethylene-vinyl acetate copolymer (made by Nippon Unicar) having a melt index of 1.5 g/10 mins. and a vinyl acetate content of 15 weight%, 100 weight parts of silicone gum stock (made by Nippon Unicar) having a viscosity of 300,000 CS at 23 °C and a methyl vinylsilicone content of 5.0 %, 2 parts of 1,9-decadiene, and 0.1 parts of IRGANOX 1010 (an antioxidant made by Ciba Gaigy) were kneaded at 100 °C for 10 minutes by a Brabender Plastograph and at 165 °C for 40 minutes to be formed into a 1-mm thick sheet by the compression molding. The resultant kneaded composition had a melt index of 0.1 g/10 mins., a tensile strength of 70 kg/cm², an elongation of 300 %. The resultant sheet had no exudation of the silicone. This sheet was formed in to pellets, and the pellets could be formed into a tape at 160 °C°Cby the extruder of a Brabender Plastograph.
    • Example 3
  • One hundred (100) weight parts of ethylene-butene-1 copolymer (made by Union Carbide) having a melt index of 4.7 g/10 mins. and a density of 0.900, 100 parts of silicon gum stock having a viscosity of 300,000 CS at 23 °C and a methyl vinylsilicone of 5.0 %, 2 weight parts of 1,9-decadiene, and 0.1 parts of IRGANOX 1010 (an antioxidant made by CibaGaigy) were kneaded for 10 minutes at 100 °C and for 70 minutes at 165 °C to be formed into a 1-mm thick sheet by the compression molding. The resultant kneaded composition had a melt index of 0.2 g/10 mins., a tensile strength of 50 kg/cm² and an elongation of 600 %. The resultant sheet had substantially no exudation of the silicone. This sheet was formed into pellets, and the pellets were formed into a tape at 160 °C by the extrduer of a Brabender Plastograph.
    • Example 4
  • One hundred (100) weight parts of polystyrene having a melt flow index (200 °C, 5,000 g) and an Izod impact strength of 1.3 kg.cm/cm (with a notch) at 10.0 g/10 mins., and 10 parts of the pellets prepared in Example 1 were kneaded at 200 °C for 10 minutes by a Brabender Plastograph and then was taken out to be formed into a sheet. The resultant sheet had an Izod impact strength of 3.0 kg.cm/cm.

Claims (2)

1. A kneaded moldable resin composition comprising 100 weight parts of an ethylene polymer; 0.01 - 300 weight parts of an organopolysiloxane expressed by the formula
Figure imgb0002
 (where R¹ is an aliphatic unsaturated group, R² is a substituted or unsubstituted monovalent hydrocarbon group containing no aliphatic unsaturated group, 0<a<1, 0.5<b<3, and 1<a+b<3); 0.01 - 30 weight parts of a hydrocarbon compound expressed by the formula
CH₂ = CH(CH₂)cCH = CH₂      (B)
(where c is an integer of 1 - 30) which are heat-kneaded with each other.
2. A molding produced from a kneaded moldable resin composition accoring to claim 1.
EP19900111443 1989-06-19 1990-06-18 A kneaded moldable resin composition Withdrawn EP0404011A3 (en)

Applications Claiming Priority (2)

Application Number Priority Date Filing Date Title
JP154699/89 1989-06-19
JP1154699A JPH0321611A (en) 1989-06-19 1989-06-19 Formable kneaded resin mixture

Publications (2)

Publication Number Publication Date
EP0404011A2 true EP0404011A2 (en) 1990-12-27
EP0404011A3 EP0404011A3 (en) 1991-10-16

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EP (1) EP0404011A3 (en)
JP (1) JPH0321611A (en)
KR (1) KR910000896A (en)
CN (1) CN1048714A (en)
AU (1) AU5753090A (en)
BR (1) BR9002890A (en)
CA (1) CA2019244A1 (en)
HU (1) HUT55432A (en)

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WO2006083540A1 (en) * 2005-02-02 2006-08-10 Exxonmobil Chemical Patents Inc. Modified polyethylene compositions
US7795366B2 (en) 2002-08-12 2010-09-14 Exxonmobil Chemical Patents Inc. Modified polyethylene compositions

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US5690755A (en) * 1992-08-31 1997-11-25 Nippon Steel Corporation Cold-rolled steel sheet and hot-dip galvanized cold-rolled steel sheet having excellent bake hardenability, non-aging properties at room temperature and good formability and process for producing the same
US6030255A (en) * 1995-01-31 2000-02-29 Nippon Zeon Co., Ltd. Insulator and high frequency connector
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US8192813B2 (en) 2003-08-12 2012-06-05 Exxonmobil Chemical Patents, Inc. Crosslinked polyethylene articles and processes to produce same
US8389615B2 (en) 2004-12-17 2013-03-05 Exxonmobil Chemical Patents Inc. Elastomeric compositions comprising vinylaromatic block copolymer, polypropylene, plastomer, and low molecular weight polyolefin
WO2007011541A1 (en) 2005-07-15 2007-01-25 Exxonmobil Chemical Patents Inc. Elastomeric compositions
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Patent Citations (1)

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US2924584A (en) * 1956-06-20 1960-02-09 Du Pont Composition comprising polyethylene and an ethylenically unsaturated aliphatic hydrocarbon of 20-35 carbon atoms and article thereof

Cited By (7)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
EP0600166A1 (en) * 1992-09-08 1994-06-08 Tokuyama Corporation Resin compositions, production process thereof, and products using the resin compositions
US5492970A (en) * 1992-09-08 1996-02-20 Tokuyama Corporation Resin compositions, production process thereof, and products using the resin compositions
US5543189A (en) * 1992-09-08 1996-08-06 Tokuyama Corporation Resin compositions, production process thereof, and products using the resin compositions
SG83634A1 (en) * 1992-09-08 2001-10-16 Tokuyama Corp Resin compositions, production process thereof, and products using the resin compositions
US7795366B2 (en) 2002-08-12 2010-09-14 Exxonmobil Chemical Patents Inc. Modified polyethylene compositions
WO2006083540A1 (en) * 2005-02-02 2006-08-10 Exxonmobil Chemical Patents Inc. Modified polyethylene compositions
CN101137708B (en) * 2005-02-02 2012-03-28 埃克森美孚化学专利公司 Modified polyethylene compositions

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EP0404011A3 (en) 1991-10-16
CN1048714A (en) 1991-01-23
CA2019244A1 (en) 1990-12-19
JPH0321611A (en) 1991-01-30
BR9002890A (en) 1991-08-20
HU903884D0 (en) 1990-11-28
HUT55432A (en) 1991-05-28
AU5753090A (en) 1990-12-20
KR910000896A (en) 1991-01-30

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