EP0604908A2 - Metallocene compounds having ligands of fluorenylic type - Google Patents
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- EP0604908A2 EP0604908A2 EP93120798A EP93120798A EP0604908A2 EP 0604908 A2 EP0604908 A2 EP 0604908A2 EP 93120798 A EP93120798 A EP 93120798A EP 93120798 A EP93120798 A EP 93120798A EP 0604908 A2 EP0604908 A2 EP 0604908A2
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- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07F—ACYCLIC, CARBOCYCLIC OR HETEROCYCLIC COMPOUNDS CONTAINING ELEMENTS OTHER THAN CARBON, HYDROGEN, HALOGEN, OXYGEN, NITROGEN, SULFUR, SELENIUM OR TELLURIUM
- C07F17/00—Metallocenes
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- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
- C08F10/00—Homopolymers and copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond
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- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
- C08F4/00—Polymerisation catalysts
- C08F4/42—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors
- C08F4/44—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides
- C08F4/60—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides together with refractory metals, iron group metals, platinum group metals, manganese, rhenium technetium or compounds thereof
- C08F4/62—Refractory metals or compounds thereof
- C08F4/64—Titanium, zirconium, hafnium or compounds thereof
- C08F4/659—Component covered by group C08F4/64 containing a transition metal-carbon bond
- C08F4/65908—Component covered by group C08F4/64 containing a transition metal-carbon bond in combination with an ionising compound other than alumoxane, e.g. (C6F5)4B-X+
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- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
- C08F4/00—Polymerisation catalysts
- C08F4/42—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors
- C08F4/44—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides
- C08F4/60—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides together with refractory metals, iron group metals, platinum group metals, manganese, rhenium technetium or compounds thereof
- C08F4/62—Refractory metals or compounds thereof
- C08F4/64—Titanium, zirconium, hafnium or compounds thereof
- C08F4/659—Component covered by group C08F4/64 containing a transition metal-carbon bond
- C08F4/65912—Component covered by group C08F4/64 containing a transition metal-carbon bond in combination with an organoaluminium compound
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- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
- C08F4/00—Polymerisation catalysts
- C08F4/42—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors
- C08F4/44—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides
- C08F4/60—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides together with refractory metals, iron group metals, platinum group metals, manganese, rhenium technetium or compounds thereof
- C08F4/62—Refractory metals or compounds thereof
- C08F4/64—Titanium, zirconium, hafnium or compounds thereof
- C08F4/659—Component covered by group C08F4/64 containing a transition metal-carbon bond
- C08F4/6592—Component covered by group C08F4/64 containing a transition metal-carbon bond containing at least one cyclopentadienyl ring, condensed or not, e.g. an indenyl or a fluorenyl ring
- C08F4/65922—Component covered by group C08F4/64 containing a transition metal-carbon bond containing at least one cyclopentadienyl ring, condensed or not, e.g. an indenyl or a fluorenyl ring containing at least two cyclopentadienyl rings, fused or not
- C08F4/65927—Component covered by group C08F4/64 containing a transition metal-carbon bond containing at least one cyclopentadienyl ring, condensed or not, e.g. an indenyl or a fluorenyl ring containing at least two cyclopentadienyl rings, fused or not two cyclopentadienyl rings being mutually bridged
Definitions
- the present invention relates to a class of metallocenes, to the process for the preparation thereof and to their use as catalyst components in processes for the polymerization of olefins.
- U.S. Patent 4,542,199 describes a catalytic system for the polymerization of olefins comprising a bis(cyclopentadienyl)zirconium and an alumoxane. From the polymerization reaction of propylene carried out in the presence of this catalyst, low molecular weight atactic polypropylene is obtained.
- European Patent 283,739 describes a catalytic systems for the polymerization of oleins comprising a bis(cyclopentadienyl)zirconium partially substituted and an alumoxane. From the polymerization of propylene carried out in the presence of this catalyst a low molecular weight atactic polypropylene is obtained.
- New metallocenes having two fluorenyl rings bridge-linked which can be advantageously used as catalytic components for the polymerization of olefins and, expecially, for the preparation of high molecular weight atactic polypropylene, have been surprisingly found.
- an object of the present invention is a metallocene of the formula (I) wherein substituents R1, the same or different from each other, are hydrogen atoms, C1-C20 alkyl radicals, C3-C20 cycloalkyl radicals, C2-C20 alkenyl radicals, C6-C20 aryl radicals, C7-C20 alkylaryl radicals, or C7-C20 arylalkyl radicals, optionally two adjacent substituents R1 can form a cycle comprising from 5 to 8 carbon atoms and, furthermore, substituents R1 can contain Si or Ge atoms; M is Ti, Zr or Hf; substituents R2, the same or different from each other, are halogen atoms, -OH, -SH, R1, -OR1, -SR1, -NR12 or PR12, wherein R1 is defined as above; the group R3 is selected from >CR12, >SiR12, >GeR12, >NR1 or >PR1,
- Preferred substituents R1 are hydrogen, C1-C10 alkyl radicals, more preferably C1-C3; C3-C10 cycloalkyl radicals, more preferably C3-C6; C2-C10 alkenyl radicals, more preferably C2-C3, C6-C10 aryl radicals, C7-C10 alkylaryl radicals or C7-C10 arylalkyl radicals.
- Alkyl radicals can be linear or brancehd, in addition to cyclic.
- Substituents R2 are preferably halogen atoms or groups R1. More preferably, they are chlorine or methyl radicals.
- the group R3 is preferably a group >SiR12. More preferably it is a group >Si(CH3)2.
- Non limitative examples of metallocenes of formula (I) according to the invention are: dimethylsilandiylbis(fluorenyl)titanium dichloride, dimethylsilandiylbis(fluorenyl)zirconium dichloride, dimethylsilandiylbis(fluorenyl)hafnium dichloride, dimethylsilandiylbis(fluorenyl)titanium dichloride, dimethylsilandiylbis(fluorenyl)zirconium dimethyl, dimethylsilandiylbis(fluorenyl)hafnium dimethyl, dimethylsilandiylbis(fluorenyl)titanium dichloride, dimethylsilandiylbis(fluorenyl)zirconium dichloride, dimethylsilandiylbis(fluorenyl)hafnium dichloride, dimethylsilandiylbis(fluorenyl)titan
- Another object of the present invention is a process for the preparation of metallocenes of formula (I), comprising:
- Non limitative examples of compounds able to form anionic compounds of formula (III) and (V) are methyllithium, n-butyllithium, potassium hydride, metallic sodium or potassium.
- Non limitative examples of compounds of formula R3X2 are dimethyldichlorosilane, diphenyldichlorosilane, dimethyldichlorogermanium, 2,2-dichloropropane. Dimethyldichlorosilane is particularly interesting.
- Non limitative examples of compounds of formula MX4 are titanium tetrachloride, zirconium tetrachloride, hafnium tetrachloride. Particularly interesting is zirconium tetrachloride.
- substitution reaction of substituents X in the compound of formula (VI) with substituents R2 different from halogen is carried out by generally used methods.
- substituents R2 are alkyl groups
- the compound of formula (VI) can be reacted with alkylmagnesium halides (Grignard reagents) or with lithioalkyl compounds.
- the synthesis of the ligand of formula (IV) is suitably performed by adding a solution of an organic lithium compound in an aprotic solvent to a solution of the compound (II) in an aprotic solvent.
- a solution containing the compound (II) in the anionic form is obtained and this is added to a solution of the compound of formula R3X2 in an aprotic solvent.
- the ligand of formula (IV) is separated by generally used methods. This is dissolved in an aprotic polar solvent, and to this solution a solution of an organic lithium compound in an aprotic solvent is added. The ligand (IV) is thus obtained and is separated, dissolved in an aprotic polar solvent and thereafter added to a suspension of the compound MX4 in an apolar solvent. At the end of the reaction the solid product obtained is separated from the reaction mixture by generally used techniques.
- the temperature is kept between -180°C and 80°C and, preferably, between -20°C and 40°C.
- hydrocarbon solvents such as pentane, hexane, benzene and the like can be suitably used.
- Non limitative examples of aprotic polar solvents are tetrahydrofurane, dimethoxyethane, diethylether, toluene, dichloromethane and the like.
- Another object of the present invention is a compound of formula (IV) wherein substituents R1 and the group R3 are defined as above and, when R3 is a group >Si(CH3)2, at least one substituent R1 is different from hydrogen.
- Non limitative example of compounds of formula (IV) according to the invention are diphenylbis(fluorenyl)silane, 2,2-bis(fluorenyl)propane, dimethylbis(fluorenyl)germanium, dimethylbis(1-methylfluorenyl)silane.
- Another object of the present invention is a catalyst for the polymerization of olefins, comprising the product of the reaction between:
- the alumoxane used as component (B) can be obtained by reaction between water and an organometallic compound of aluminium of formula AlR3 or Al2R46, wherein substituents R4, the same or different from each other, are defined as above, with the provision that at least one R4 is different from halogen. In that case, these are reacted in molar ratios Al/water comprised between about 1:1 and 100:1.
- the molar ratio between aluminium and the metal of the metallocene is comprised between about 10:1 and about 5000:1, and preferably between 100:1 and 4000:1.
- the alumoxane used in the catalyst according to the invention is a linear, branched or cyclic compound, containing at least one group of the type: wherein substituents R5, the same or different from each other, are R1 or a group -0-Al(R5)2, and optionally some R5 can be halogen or hydrogen atoms.
- alumoxanes of formula in the case of linear compounds, wherein n is 0 or an integer comprised between 1 and 40, or alumoxanes of formula: in the case of cyclic compounds, wherein n is an integer comprised between 2 and 40.
- Radicals R1 are preferably methyl, ethyl or isobutyl.
- alumoxanes suitable for the use according to the present invention are methylalumoxane (MAO) and isobutylalumoxane (TIBAO).
- trimethylaluminium and triisobutylaluminium are preferred.
- Non limitative examples of compounds able to form a metallocene alkyl cation are compounds of formula Y+Z ⁇ , wherein Y+ is a Bronsted acid, able to give a proton and to react irreversibly with a substituent R2 of the metallocene of formula (I), and Z ⁇ is a compatible anion, which does not coordinate, which is able to stabilize the active catalytic species which originates from the reaction of the two compounds and which is sufficiently labile to be able to be removed from an olefinic substrate.
- the anion Z ⁇ comprises one or more boron atoms.
- the anion Z ⁇ is an anion of the formula BAr (-) 4, wherein substituents Ar, the same or different from each other, are aryl radicals such as phenyl, pentafluorophenyl, bis(trifluoromethyl)phenyl. Particularly preferred is the tetrakis-pentafluorophenyl borate. Furthermore, compounds of formula BAr3 can be suitably used.
- the catalysts used in the process of the present invention can be also used on inert supports. This is obtained by depositing the metallocene (A), or the product of the reaction of the same with the component (B), or the component (B) and thereafter the metallocene (A), on inert supports such as for example silica, alumina, styrene-divinylbenzene copolymers or polyethylene.
- Catalysts of the present invention are useable in the polymerization reaction of olefins.
- a further object of the present invention is a process for the polymerization of olefins comprising the polymerization reaction of an olefinic monomer in the presence of a catalyst as above described.
- catalysts according to the invention can be suitably used in the homopolymerization reaction of alphaolefins such as ethylene, propylene or 1-butene.
- alphaolefins such as ethylene, propylene or 1-butene.
- Another use of interest of the catalysts of the invention is in the copolymerization reactions of ethylene with alpha-olefins such as propylene and 1-butene.
- Polymerization processes which use the catalysts of the invention can be carried out either in liquid phase, in the presence or not of an inert aliphatic or aromatic hydrocarbon solvent, such as hexane or toluene, or in gas phase.
- an inert aliphatic or aromatic hydrocarbon solvent such as hexane or toluene
- the polymerization temperature in processes for the ethylene or propylene homopolymerization is generally comprised between -50°C and 250°C, in particular between 40°C and 90°C.
- the molecular weight of the polymers can be varied merely by varying the polymerization temperature, the type or the concentration of the catalytic components or by using molecular weight regulators such as, for example, hydrogen.
- the molecular weight distribution can be changed using mixtures of different metallocenes, or carrying out the polymerization in more steps differing as to polymeri-zation temperatures and/or concentrations of the molecular weight regulator.
- Polymerization yields depend on the purity of the metallocene component of the catalyst. Therefore, metallocenes obtained from the process of the invention can be used either as such or subjected to purification treatments.
- the components of the catalyst can be contacted among them before the polymerization.
- the contact time is generally comprised between 1 and 60 minutes, preferably between 5 and 20 minutes.
- Fig. 1 reports the 1H-NMR spectrum of the dimethylbisfluorenylsilane ligand of the Example 1(A).
- Fig. 2 reports the 1H-NMR spectrum of the dimethylsilandylbis(fluorenyl)zirconium dichloride of the Example 1(B).
- the intrinsic viscosity [ ⁇ ] was measured in tetrahydronaphtalene at 135°C.
- the molecular weight distribution was determined by GPC analysis carried out by an apparatus WATERS 150 in orthodichlorobenzene at 135°C.
- DSC Differential Scanning Calorimetry
- the resulting solution was then added dropwise to a stirring solution obtained by dissolving 19.4 g (0.15 mol) of dimethyldichlorosilane in 100 ml of THF, maintained at 0°C during the addition. After the addition was complete, the solution was warmed to room temperature and stirring was continued for 14 hours.
- the catalyst solution was prepared as follows: 12.1 mg of the metallocene prepared in example 1(B) and 112.3 mg of MAO were dissolved in 10 ml of toluene. 0.2 ml of this solution was transferred in 10 ml of toluene containing 98 mg of MAO and this solution was injected into the autoclave at 50°C under ethylene stream. The autoclave was pressurized at 4 bar-a with ethylene and the polymerization was carried out for 1 hour. 9 g of polyethylene having intrinsic viscosity 10.56 dl/g were separated.
- the catalyst solution was prepared as follows: 8 mg of the metallocene prepared in example 1(B) were suspended in 5 ml of the cyclohexane solution of TIBAO. 0.14 ml of this suspension was transferred in 10 ml of toluene containing 1.16 ml of the same TIBAO in cyclohexane.
- the resulting solution was then injected into the autoclave at 50°C under ethylene stream.
- the autoclave was pressurized at 4 bar-a with ethylene and the polymerization was carried out for 1 hour. 7.5 g of polyethylene having intrinsic viscosity 10.10 dl/g were separated.
- the polymerizations were carried out with the procedure described in Example 4.
- the amount of Me2SiFlu2ZrCl2 used was 4 mg.
- the amounts of MAO and of toluene used, the polymerization yields and the intrinsic viscosities of the obtained polymers are reported in Table 1.
- Example 4 The polymerization was carried out as in Example 4, but using 3.4 mL of an M-MAO solution containing 2 mg of MeSiFlu2ZrMe2 prepared as described in example 1(C). 80 g of a solid, transparent, amorphous polypropylene were obtained. This product has an intrinsic viscosity of 2.1 dL/g.
- the polymerization was carried out as in Example 4, but the catalyst was prepared by dissolving Me2SiFlu2ZrCl2 in a toluene solution of MAO, such as the Al/Zr ratio was 550 molar, then removing the solvent in vacuo until a free-flowing light geen-blue powder was obtained. 186 mg of this powder were charged in the autoclave before the monomer was added. The polymerization was carried out for 120 min at 50°C, 183 g of solid, transparent, amorphous polypropylene were obtained, having an intrinsic viscosity of 2.65 dL/g.
- Example 12 The polymerisation was carried out as in Example 12, but in the gas phase, using 64 g of NaCl as the disperdant. 196 mg of the same catalyst powder used in Example 12 were charged in the autoclave before the monomer was pressurized in at 13 bar. The polymerization was carried out for 240 min at 50°C. 100 g of solid, transparent, amorphous polypropylene were obtained, having an intrinsic viscosity of 2.26 dL/g.
- the whole was pressurized at 4 bar-a with propylene and was allowed to polymerize for 1 hr. After having interrupted the experiment by addition of methanol, the polymer was coagulated with methanol in excess, filtered, dried in vacuum, extracted with hot chloroformium and dried again.
- the catalyst solution was prepared as follows: 15.8 mg of the metallocene prepared in Example 1(B) and 229.3 mg of MAO were dissolved in 10 ml of toluene. 3.8 ml of this solution were transferred in 20 ml of toluene containing 1.043 mg of MAO and this solution was injected into the autoclave under propylene stream. The autoclave was pressurized at 4 bar-a with propylene and the polymerization was carried out for 90 minutes.
- Example 1(B) Into a 1.35 liter steel autoclave, degassed warm under propylene stream, 480 g of propylene at 40°C were fed. By propylene overpressure, 11.5 ml of a toluene solution containing 174 mg of MAO and 3.7 mg of the metallocene prepared in Example 1(B), were injected. The temperature was brought to 50°C and the polymerization reaction was carried out for 1 hour.
- the catalyst solution was prepared as follows: 8 mg of the metallocene prepared in Example 1(B) and 846 mg of MAO were dissolved in 15 ml of toluene. This solution was injected into the autoclave by means of nitrogen pressure through the stainless-steel vial. The polymerization was carried out for 1 hour. Then, the reaction was stopped by adding 600 cc of CO. After degasing the residual monomers, the product was collected and dryed at 60°C under a reduced nitrogen pressure.
Abstract
wherein substituents R¹ are, for example, hydrogen atoms or alkyl groups, M is Ti, Zr or Hf, substituents R² are, for example, halogens or alkyl groups, the bridging group R³ is, for example, a dialkylsilandiyl divalent radical. These metallocenes are useful as catalyst components for the polymerization of olefins and, expecially, for the preparation of high molecular weight atactic polypropylene.
Description
- The present invention relates to a class of metallocenes, to the process for the preparation thereof and to their use as catalyst components in processes for the polymerization of olefins.
- U.S. Patent 4,542,199 describes a catalytic system for the polymerization of olefins comprising a bis(cyclopentadienyl)zirconium and an alumoxane. From the polymerization reaction of propylene carried out in the presence of this catalyst, low molecular weight atactic polypropylene is obtained.
- European Patent 283,739 describes a catalytic systems for the polymerization of oleins comprising a bis(cyclopentadienyl)zirconium partially substituted and an alumoxane. From the polymerization of propylene carried out in the presence of this catalyst a low molecular weight atactic polypropylene is obtained.
- In U.S. Patent 4,931,417 catalysts for the polymerization of olefins comprising a metallocene wherein two cyclopentadienyl rings are linked through a radical containing a silicon or germanium atom are described. The polymerization reaction of propylene carried out in the presence of the above mentioned compounds partially substituted on the cyclopentadienyl rings gives raise to isotactic polypropylene, whereas with dimethylsilandiylbis(cyclopentadienyl)zirconium dichloride, low molecular weight atactic polypropylene is obtained.
- In Japanese Patent Application Publication No. 1 249 782, the preparation of the potassium sal of the bis(fluorenyl)dimethylsilane to be used for preparing organo-lantanide hydrides is described. These are useable as catalysts for the hydrogenation of olefins of every type and for the polymerization of ethylene.
- New metallocenes having two fluorenyl rings bridge-linked which can be advantageously used as catalytic components for the polymerization of olefins and, expecially, for the preparation of high molecular weight atactic polypropylene, have been surprisingly found.
- Therefore, an object of the present invention is a metallocene of the formula (I)
wherein substituents R¹, the same or different from each other, are hydrogen atoms, C₁-C₂₀ alkyl radicals, C₃-C₂₀ cycloalkyl radicals, C₂-C₂₀ alkenyl radicals, C₆-C₂₀ aryl radicals, C₇-C₂₀ alkylaryl radicals, or C₇-C₂₀ arylalkyl radicals, optionally two adjacent substituents R¹ can form a cycle comprising from 5 to 8 carbon atoms and, furthermore, substituents R¹ can contain Si or Ge atoms;
M is Ti, Zr or Hf;
substituents R², the same or different from each other, are halogen atoms, -OH, -SH, R¹, -OR¹, -SR¹, -NR¹₂ or PR¹₂, wherein R¹ is defined as above;
the group R³ is selected from >CR¹₂, >SiR¹₂, >GeR¹₂, >NR¹ or >PR¹, wherein R¹ is defined as above and optionally, when R³ is >CR¹₂, >SiR¹₂ or >GeR¹₂, both substituents R¹ can form a cycle comprising from 3 to 8 atoms. - Preferred substituents R¹ are hydrogen, C₁-C₁₀ alkyl radicals, more preferably C₁-C₃; C₃-C₁₀ cycloalkyl radicals, more preferably C₃-C₆; C₂-C₁₀ alkenyl radicals, more preferably C₂-C₃, C₆-C₁₀ aryl radicals, C₇-C₁₀ alkylaryl radicals or C₇-C₁₀ arylalkyl radicals. Alkyl radicals can be linear or brancehd, in addition to cyclic.
- Substituents R² are preferably halogen atoms or groups R¹. More preferably, they are chlorine or methyl radicals.
- The group R³ is preferably a group >SiR¹₂. More preferably it is a group >Si(CH₃)₂.
- Non limitative examples of metallocenes of formula (I) according to the invention are:
dimethylsilandiylbis(fluorenyl)titanium dichloride,
dimethylsilandiylbis(fluorenyl)zirconium dichloride,
dimethylsilandiylbis(fluorenyl)hafnium dichloride,
dimethylsilandiylbis(fluorenyl)titanium dichloride,
dimethylsilandiylbis(fluorenyl)zirconium dimethyl,
dimethylsilandiylbis(fluorenyl)hafnium dimethyl,
dimethylsilandiylbis(fluorenyl)titanium dichloride,
dimethylsilandiylbis(fluorenyl)zirconium dichloride,
dimethylsilandiylbis(fluorenyl)hafnium dichloride,
dimethylsilandiylbis(fluorenyl)titanium dimethyl,
dimethylsilandiylbis(fluorenyl)zirconium dimethyl,
dimethylsilandiylbis(fluorenyl)hafnium dimethyl,
isopropylidenbis(fluorenyl)titanium dichloride,
isopropylidenbis(fluorenyl)zirconium dichloride,
isopropylidenbis(fluorenyl)hafnium dichloride,
isopropylidenbis(fluorenyl)titanium dimethyl,
isopropylidenbis(fluorenyl)zirconium dimethyl,
isopropylidenbis(fluorenyl)hafnium dimethyl,
dimethylgermandiylbis(fluorenyl)titanium dichloride,
dimethylgermandiylbis(fluorenyl)zirconium dichloride,
dimethylgermandiylbis(fluorenyl)hafnium dichloride,
dimethylgermandiylbis(fluorenyl)titanium dimethyl,
dimethylgermandiylbis(fluorenyl)zirconium dimethyl,
dimethylgermandiylbis(fluorenyl)hafnium dimethyl,
dimethylsilandiylbis(1-methylfluorenyl)titanium dichloride,
dimethylsilandiylbis(1-methylfluorenyl)zirconium dichloride,
dimethylsilandiylbis(1-methylfluorenyl)hafnium dichloride,
dimethylsilandiylbis(1-methylfluorenyl)titanium dimethyl,
dimethylsilandiylbis(1-methylfluorenyl)zirconium dimethyl,
dimethylsilandiylbis(1-methylfluorenyl)hafnium dimethyl. - Furthermore, another object of the present invention is a process for the preparation of metallocenes of formula (I), comprising:
- (a) the reaction of a compound of formula (II)
- (b) the subsequent reaction of the compound of formula (IV) obtained at point (a) with a compound able to form the dianion of formula (V)
- (c) in the case at least one R² in the metallocene of formula (I) to be prepared is different from halogen, the substitution of at least one substituent X in the compound of formula (VI) with at least one R² different from halogen.
- Non limitative examples of compounds able to form anionic compounds of formula (III) and (V) are methyllithium, n-butyllithium, potassium hydride, metallic sodium or potassium.
- Non limitative examples of compounds of formula R³X₂ are dimethyldichlorosilane, diphenyldichlorosilane, dimethyldichlorogermanium, 2,2-dichloropropane. Dimethyldichlorosilane is particularly interesting.
- Non limitative examples of compounds of formula MX₄ are titanium tetrachloride, zirconium tetrachloride, hafnium tetrachloride. Particularly interesting is zirconium tetrachloride.
- The substitution reaction of substituents X in the compound of formula (VI) with substituents R² different from halogen is carried out by generally used methods. For example, when substituents R² are alkyl groups, the compound of formula (VI) can be reacted with alkylmagnesium halides (Grignard reagents) or with lithioalkyl compounds.
- According to an embodiment of the process according to the invention, the synthesis of the ligand of formula (IV) is suitably performed by adding a solution of an organic lithium compound in an aprotic solvent to a solution of the compound (II) in an aprotic solvent. Thus, a solution containing the compound (II) in the anionic form is obtained and this is added to a solution of the compound of formula R³X₂ in an aprotic solvent.
- From the solution obtained by working as above described, the ligand of formula (IV) is separated by generally used methods. This is dissolved in an aprotic polar solvent, and to this solution a solution of an organic lithium compound in an aprotic solvent is added. The ligand (IV) is thus obtained and is separated, dissolved in an aprotic polar solvent and thereafter added to a suspension of the compound MX₄ in an apolar solvent. At the end of the reaction the solid product obtained is separated from the reaction mixture by generally used techniques.
- During the whole process, the temperature is kept between -180°C and 80°C and, preferably, between -20°C and 40°C.
- As apolar solvents hydrocarbon solvents such as pentane, hexane, benzene and the like can be suitably used.
- Non limitative examples of aprotic polar solvents are tetrahydrofurane, dimethoxyethane, diethylether, toluene, dichloromethane and the like.
-
- The above mentioned compounds of formula (IV) are intermediate ligands which can be used for preparing metallocenes of formula (I).
- Non limitative example of compounds of formula (IV) according to the invention are diphenylbis(fluorenyl)silane, 2,2-bis(fluorenyl)propane, dimethylbis(fluorenyl)germanium, dimethylbis(1-methylfluorenyl)silane.
- Furthermore, another object of the present invention is a catalyst for the polymerization of olefins, comprising the product of the reaction between:
- (A) a metallocene of formula (I), optionally as reaction product with an aluminium organo-metallic compound of formula AlR⁴₃ or Al₂R⁴₆, wherein substituents R⁴, the same or different from each other, are R¹ or halogen, and
- (B) an alumoxane, optionally mixed with an aluminium organometallic compound of formula AlR⁴₃ or Al₂R⁴₆, wherein substituents R⁴, the same or different from each other, are defined as above, or one or more compounds able to give a metallocene alkyl cation.
- The alumoxane used as component (B) can be obtained by reaction between water and an organometallic compound of aluminium of formula AlR₃ or Al₂R⁴₆, wherein substituents R⁴, the same or different from each other, are defined as above, with the provision that at least one R⁴ is different from halogen. In that case, these are reacted in molar ratios Al/water comprised between about 1:1 and 100:1.
- The molar ratio between aluminium and the metal of the metallocene is comprised between about 10:1 and about 5000:1, and preferably between 100:1 and 4000:1.
- Metallocenes of formula (I) particularly suitable are those wherein M=Zr, substituents R¹ are hydrogen atoms, substituents R² are chlorine or methyl groups, and the group R³ is a radical >Si(CH₃)₂ such as, for example, dimethylsilandiylbis(fluorenyl)zirconium dichloride.
-
-
- Radicals R¹ are preferably methyl, ethyl or isobutyl. Examples of alumoxanes suitable for the use according to the present invention are methylalumoxane (MAO) and isobutylalumoxane (TIBAO).
- Non limitative examples of aluminium compounds of formula AlR₃ or Al₂R⁴₆ are:
Al(Me)₃, Al(Et)₃, AlH(Et)₂, Al(iBu)₃, AlH(iBu)₂, Al(iHex)₃, Al(C₆H₅)₃, Al(CH₂C₆H₅)₃, Al(CH₂CMe₃)₃, Al(CH₂SiMe₃)₃, Al(Me)₂iBu, Al(Me)₂Et, AlMe(Et)₂, AlMe(iBu)₂, Al(Me)₂iBu, Al(Me)₂Cl, Al(Et)₂Cl, AlEtCl₂, Al₂(Et)₃Cl₃,
wherein Me=methyl, Et=ethyl, iBu=isobutyl, iHex=isohexyl. - Among the above mentioned aluminium compounds, trimethylaluminium and triisobutylaluminium are preferred.
- Non limitative examples of compounds able to form a metallocene alkyl cation are compounds of formula Y⁺Z⁻, wherein Y⁺ is a Bronsted acid, able to give a proton and to react irreversibly with a substituent R² of the metallocene of formula (I), and Z⁻ is a compatible anion, which does not coordinate, which is able to stabilize the active catalytic species which originates from the reaction of the two compounds and which is sufficiently labile to be able to be removed from an olefinic substrate. Preferably, the anion Z⁻ comprises one or more boron atoms. More preferably, the anion Z⁻ is an anion of the formula BAr(-)₄, wherein substituents Ar, the same or different from each other, are aryl radicals such as phenyl, pentafluorophenyl, bis(trifluoromethyl)phenyl. Particularly preferred is the tetrakis-pentafluorophenyl borate. Furthermore, compounds of formula BAr₃ can be suitably used.
- The catalysts used in the process of the present invention can be also used on inert supports. This is obtained by depositing the metallocene (A), or the product of the reaction of the same with the component (B), or the component (B) and thereafter the metallocene (A), on inert supports such as for example silica, alumina, styrene-divinylbenzene copolymers or polyethylene.
- The solid compound thus obtained, combined with a further addition of alkylaluminium compound either as such or prereacted with water, if necessary, is usefully used in the gas phase polymerization.
- Catalysts of the present invention are useable in the polymerization reaction of olefins.
- Therefore, a further object of the present invention is a process for the polymerization of olefins comprising the polymerization reaction of an olefinic monomer in the presence of a catalyst as above described.
- In particular, catalysts according to the invention can be suitably used in the homopolymerization reaction of alphaolefins such as ethylene, propylene or 1-butene. Another use of interest of the catalysts of the invention is in the copolymerization reactions of ethylene with alpha-olefins such as propylene and 1-butene.
- Polymerization processes which use the catalysts of the invention can be carried out either in liquid phase, in the presence or not of an inert aliphatic or aromatic hydrocarbon solvent, such as hexane or toluene, or in gas phase.
- The polymerization temperature in processes for the ethylene or propylene homopolymerization is generally comprised between -50°C and 250°C, in particular between 40°C and 90°C.
- The molecular weight of the polymers can be varied merely by varying the polymerization temperature, the type or the concentration of the catalytic components or by using molecular weight regulators such as, for example, hydrogen.
- The molecular weight distribution can be changed using mixtures of different metallocenes, or carrying out the polymerization in more steps differing as to polymeri-zation temperatures and/or concentrations of the molecular weight regulator.
- Polymerization yields depend on the purity of the metallocene component of the catalyst. Therefore, metallocenes obtained from the process of the invention can be used either as such or subjected to purification treatments.
- The components of the catalyst can be contacted among them before the polymerization. The contact time is generally comprised between 1 and 60 minutes, preferably between 5 and 20 minutes.
- Fig. 1 reports the ¹H-NMR spectrum of the dimethylbisfluorenylsilane ligand of the Example 1(A).
- Fig. 2 reports the ¹H-NMR spectrum of the dimethylsilandylbis(fluorenyl)zirconium dichloride of the Example 1(B).
- The following examples are given to illustrate and not to limit the invention.
- The intrinsic viscosity [η] was measured in tetrahydronaphtalene at 135°C.
- The molecular weight distribution was determined by GPC analysis carried out by an apparatus WATERS 150 in orthodichlorobenzene at 135°C.
- The Differential Scanning Calorimetry (DSC) measurements were carried out on an apparatus DSC-7 of Perkin-Elmer Co. Ltd. according to the following procedure. About 10 mg of sample were heated at 200°C with a scanning speed equal to 20°C/minute; the sample was kept at 200°C for 5 minutes and thereafter was cooled with a scanning speed equal to 20°C/minute. Thereafter a second scanning equal to 20°C/min was carried out according to the same modalities of the first one. The values reported are those obtained in the second scanning.
- To a solution obtained by dissolving 50 g (300 mmol) of fluorene in 350 ml of tetrahydrofuran (THF), kept under stirring at the temperature of 0°C, 120 ml of a 2.5 M hexane solution of n-butyllithium were added dropwise, whili maintaining the temperature at 0°C. After the addition was complete, the solution was warmed to room temperature and stirring was continued for 5 hours after gas evolution had ceased.
- The resulting solution was then added dropwise to a stirring solution obtained by dissolving 19.4 g (0.15 mol) of dimethyldichlorosilane in 100 ml of THF, maintained at 0°C during the addition. After the addition was complete, the solution was warmed to room temperature and stirring was continued for 14 hours.
- The reaction was quenched with water and the organic phase collected and dried over MgSO₄. Solvents were removed in vacuo and the solids collected were recrystallized from hexane, yielding 37 g (63%) of dimethylbis(9-fluorenyl)silane, whose structure and chemical purity have been confirmed by GC-MS and ¹H-NMR (Fig. 1).
- To a solution prepared by dissolving 8.5 g (21.9 mmol) of (CH₃)₂Si(Flu)₂ obtained under (A) in 150 ml of diethylether (Et₂O), kept under rapid stirring at the temperature of 0°C, 32.5 ml of a 1.4M solution of methyllithium in Et₂O were added. After the addition was complete, the mixture was warmed to room temperature and stirring was continued for 5 hours after gas evolution had ceased. The resulting suspension was cooled to -78°C and then added to a rapidly stirring slurry of 5.1 g of ZrCl₄ (21.9 mmol) in 150 ml of pentane, also kept at -78°C. After the addition was complete, the reaction mixture was slowly warmed to room temperature and stirring was continued for 17 hours. Solvents were then removed by filtration and the solids collected were washed with Et₂O and then pentane. The bright red complex was dried to free-flowing powder under vacuum at room temperature, yielding 13.1 g of Me₂SiFlu₂ZrCl₂, whose structure and chemical purity have been confirmed by GC-MS and ¹H-NMR (Fig. 2).
- 6.0 g of dimethylsilanediylbis(9-fluorenyl)zirconium dichloride obtained under (B) were suspended in 50 mL Et₂O. 7.29 mL of a 3.0 M solution of methylmagnesium bromide in Et₂O were added dropwise to the rapidly stirring slurry, which was maintained at 0°C during the addition.
- After the addition was complete, the mixture was allowed to warm to room temperature and stirring continued for additional 17 hours. The solids were collected by filtration, washed with Et₂O and pentane and finally dried under vacuum. 6.5 g of Me₂SiFlu₂ZrMe₂ were obtained, whose structure and chemical purity have been confirmed by GC-MS and ¹H-NMR.
- 8.5 g (21.9 mmol) of dimethylbis(9-fluorenyl)silane obtained under (A) were dissolved in 150 mL of Et₂O. 32.5 ml of a 1.4 M solution of methyllithium in Et₂O were added dropwise to the rapidly stirring solution, which was maintained at 0°C during the addition. After the addition was complete, the solution was warmed to room temperature and stirring was continued for 17 hours.
- The solids were collected by filtration, washed with Et₂O and resuspended in Et₂O. The resulting slurry was then cannulated dropwise into a rapidly stirring suspension of 7.01 g of HfCl₄ (21.8 mmol) in 100 ml of pentane at -78°C. After the additions was complete, the reaction mixture was slowly warmed to room temperature and stirring was continued for 17 hours. Solvents were then removed by filtration and the solids collected were washed with Et₂O and then pentane. The bright orange complex was dried to a free-flowing powder under vacuum at room temperature. Yield 13.1 g.
- 4.0 g of dimethylsilanediylbis(9-fluorenyl)hafnium dichloride obtained under (D) were suspended in 50 mL Et₂O. 4.19 mL of a 3.0 M solution of methylmagnesium bromide in Et₂O were added dropwise to the rapidly stirring slurry, which was maintained at 0°C during the addition.
- After the addition was complete, the mixture was allowed to warm to room temperature and stirring continued for additional 17 hours. The solids were collected by filtration, washed with Et₂O and pentane and finally dried under vacuum. 3.9 g of an orange product were obtained. The structure and chemical purity of Me₂SiFlu₂HfMe₂ have been confirmed by GC-MS and ¹H-NMR.
- A commercial (Witco, MW 1400) 30% toluene solution of MAO was dried in vacuo until a solid, glassy material was obtained which was finely crushed and further treated in vacuo until all volatiles were removed (4-6 hours, 0.1 mmHg, 40-50°C) to leave a white, free-flowing powder.
- The commercial (Witco) 30% cyclohexane solution was used as received.
- The commercial (Ethyl) isopar C solution (62 g Al/L) was used as received.
- Was prepared as described in Massey, A.G, Park, A.J., J. Organomet. Chem. 1964, 2, 245.
- 12.8 mL of bromopentafluorobenzene were dissolved in 430 ml of pentane and cooled to -78°C. To this solution, 64.2 mL of butyllithium (1.6 M in hexane) were slowly added while keeping the temperature at -78°C. After the addition was complete, 33 mL of a 1.0 M solution of BCl₃ in hexane previously cooled to -50°C were quick added to the reaction mixture, which was then stirred for 15 min and finally allowed to warm to room temperature. A precipitate formed. Stirring was continued for 16 hours, then the solution was filtered and the volatiles removed in vacuo. 11.31 g of a white, crystalline product were obtained.
- Into a 1 liter glass Büchi autoclave, provided with jacket, screw stirrer and thermoresistance, and joined with a thermostat for controlling the temperature, washed with a hexane solution of triisobutylaluminium (AliBu₃) and dried warm under nitrogen stream, 0.4 liter of n-hexane (purified by passing on alumina columns) were fed under nitrogen atmosphere and the temperature was brought to 50°C.
- The catalyst solution was prepared as follows: 12.1 mg of the metallocene prepared in example 1(B) and 112.3 mg of MAO were dissolved in 10 ml of toluene. 0.2 ml of this solution was transferred in 10 ml of toluene containing 98 mg of MAO and this solution was injected into the autoclave at 50°C under ethylene stream. The autoclave was pressurized at 4 bar-a with ethylene and the polymerization was carried out for 1 hour. 9 g of polyethylene having intrinsic viscosity 10.56 dl/g were separated.
- It was worked as in the preceding example, but the catalyst solution was prepared as follows: 8 mg of the metallocene prepared in example 1(B) were suspended in 5 ml of the cyclohexane solution of TIBAO. 0.14 ml of this suspension was transferred in 10 ml of toluene containing 1.16 ml of the same TIBAO in cyclohexane.
- The resulting solution was then injected into the autoclave at 50°C under ethylene stream. The autoclave was pressurized at 4 bar-a with ethylene and the polymerization was carried out for 1 hour. 7.5 g of polyethylene having intrinsic viscosity 10.10 dl/g were separated.
- 480 g of propylene were charged in a 1.4-L jacketed stainless-steel autoclave, equipped with magnetically driven stirrer, 35-mL stainless-steel vial and thermoresitance, connected to a thermostat for temperature control, previously dried at 70°C in a stream of propylene. The autoclave was then thermostatted at 40°C. 11.5 mL of a toluene solution containing 1.5 mg of Me2SiFlu₂ZrCl₂ prepared as described in example 1(B) and 326 mg of MAO were stirred 5 min at room temperature and then injected in the autoclave by means of propylene pressure through the stainless-steel vial, the temperature rapidly raised to 50°C and the polymerization carried out at constant temperature for 1 hour. 21 g of solid, transparent, amorphous polypropylene were obtained. This product has an intrinsic viscosity of 2.28 dL/g and is completely soluble in warm CHCl₃. The GPC analysis gives Mw=377,000 and Mw/Mn= 2.64.
- The polymerizations were carried out with the procedure described in Example 4. The amount of Me2SiFlu₂ZrCl₂ used was 4 mg. The amounts of MAO and of toluene used, the polymerization yields and the intrinsic viscosities of the obtained polymers are reported in Table 1.
-
- 1 L of hexane and 270 g of propylene were charged in a 2.3-L jacketed stainless-steel autoclave, equipped with magnetically driven stirrer, 35-mL stainless-steel vial and thermoresistance, connected to a thermostat for temperature control, previously dried at 70°C in a stream of propylene. The autoclave was then thermostatted at 40°C. 14.3 mL of a toluene solution containing 8 mg of Me₂SiFlu₂Cl₂ prepared as described in example 1(B) and 211 mg of MAO were stirred 5 min at room temperature and then injected in the autoclave by means of propylene pressure through the stainless-steel vial, the temperature rapidly raised to 50°C and the polymerization carried out at constant temperature for 1 hour. The polymerisation was quenched by adding a small amount of methanol. The clear, viscous hexane solution was evaporated and the solid residue further essiccated in vacuo at 60°C. 46 g of solid, transparent, amorphous polypropylene were obtained. This product has an intrinsic viscosity of 1.96 dL/g.
- The polymerization was carried out as in Example 4, but using 3.4 mL of an M-MAO solution containing 2 mg of MeSiFlu₂ZrMe₂ prepared as described in example 1(C). 80 g of a solid, transparent, amorphous polypropylene were obtained. This product has an intrinsic viscosity of 2.1 dL/g.
- In a Büchi 1-L jacketed glass autoclave, equipped with a helical stirrer and a thermoresistance, connected to a thermostat for temperature control, previously washed with a solution of AliBu₃ in hexane and then dried at 60°C under a nitrogen stream, were charged 0.4 L of hexane (purified by passing through an activated alumina column) and 0.224 mmol of AliBu₃ (0.2 M solution in hexane). The autoclave was then thermostatted at 50°C. 6.1 mL of a solution prepared by adding 1.1 ml of a 0.021 M solution of B(C₆F₅)₃ in hexane to 5 mL toluene containing 0.0488 mmol AliBu₃ and 5.7 mg of Me₂SiFlu₂ZrMe₂ prepared as described in example 1(C) were injected in the autoclave at 50°C. Propylene was pressurized in until the pressure reached 4 bar, and the polymerization carried out at constant pressure for 1 hour. The polymerization was quenched by adding a small amount of methanol. The clear, viscous hexane solution was evaporated and the solid residue further essiccated in vacuo at 60°C. 27.5 g of solid, transparent, amorphous polypropylene were obtained. This product has an intrinsic viscosity of 1.64 dL/g.
- The polymerization was carried out as in Example 4, but the catalyst was prepared by dissolving Me₂SiFlu₂ZrCl₂ in a toluene solution of MAO, such as the Al/Zr ratio was 550 molar, then removing the solvent in vacuo until a free-flowing light geen-blue powder was obtained. 186 mg of this powder were charged in the autoclave before the monomer was added. The polymerization was carried out for 120 min at 50°C, 183 g of solid, transparent, amorphous polypropylene were obtained, having an intrinsic viscosity of 2.65 dL/g.
- The polymerisation was carried out as in Example 12, but in the gas phase, using 64 g of NaCl as the disperdant. 196 mg of the same catalyst powder used in Example 12 were charged in the autoclave before the monomer was pressurized in at 13 bar. The polymerization was carried out for 240 min at 50°C. 100 g of solid, transparent, amorphous polypropylene were obtained, having an intrinsic viscosity of 2.26 dL/g.
- 17.1 mg of the metallocene obtained in example 1(B) and 348.5 mg of MAO were dissolved in 10 ml of toluene. 0.8 ml of this solution were transferred in 10 ml of toluene solution containing 241.4 mg of MAO and the resulting solution was injected under propylene atmosphere into a glass Büchi autoclave containing 90 ml of toluene, heated at 50°C and stirred by a magnetic bar.
- The whole was pressurized at 4 bar-a with propylene and was allowed to polymerize for 1 hr. After having interrupted the experiment by addition of methanol, the polymer was coagulated with methanol in excess, filtered, dried in vacuum, extracted with hot chloroformium and dried again.
- 4.85 g of solid, transparent polypropylene were obtained, having intrinsic viscosity of 1.06 dl/g, which at the DSC do not show any melting point. The GPC analysis gave the following values: Mw = 122,000; Mw/Mn = 3.7.
- Into a 1 liter glass Büchi autoclave, provided with jacket, screw stirrer and thermoresistance, and joined to a thermostat for controlling the temperature, degassed with an hexane solution of AliBu₃ and dried in vacuum under nitrogen stream, 0.4 liter of n-hexane (purified by passing it on alumina columns) were fed and the temperature was breought to 50°C.
- The catalyst solution was prepared as follows: 15.8 mg of the metallocene prepared in Example 1(B) and 229.3 mg of MAO were dissolved in 10 ml of toluene. 3.8 ml of this solution were transferred in 20 ml of toluene containing 1.043 mg of MAO and this solution was injected into the autoclave under propylene stream. The autoclave was pressurized at 4 bar-a with propylene and the polymerization was carried out for 90 minutes.
- After coagulation in methanol and drying, 49 g of solid and transparent polypropylene, having intrinsic viscosity 1.41 dl/g, were separated. The GPC analysis gave the following values: Mw = 200,000; Mw/mn = 3.5.
- Into a 1.35 liter steel autoclave, degassed warm under propylene stream, 480 g of propylene at 40°C were fed. By propylene overpressure, 11.5 ml of a toluene solution containing 174 mg of MAO and 3.7 mg of the metallocene prepared in Example 1(B), were injected. The temperature was brought to 50°C and the polymerization reaction was carried out for 1 hour.
- After removing the unreacted monomer and drying the product, 53 g of solid, transparent polymer, soluble in warm chloroform, having intrinsic viscosity of 2.08 dl/g, were separated.
- Into a 1.34 liter steel autoclave, degassed warm under propylene stream, 560 g of 1-butene were fed at a temperature of 50°C. By nitrogen overpressure, 5 ml of a toluene solution containing 350 mg of MAO were injected; then, 10 ml of a toluene solution containing 350 mg of MAO and 8.8 mg of the metallocene prepared in Example 1(B) were injected. The polymerization reaction was carried out at 50°C for 2 hours.
- After removing the unreacted monomer and drying the product, 28 g of solid, transparent poly-1-butene were separated, which is completely amorphous, soluble in warm chloroform, and has intrinsic viscosity of 1.29 dl/g.
- Into a 1.4-l jacketed stainless-steel autoclave, equipped with magnetically driven stirrer, 35-ml stainless-steel vial and thermoresistance, previously dried in a propylene stream at 70°C, 275 g of propylene and 330 g of 1-butene were fed at a temperature of 50°C.
- The catalyst solution was prepared as follows: 8 mg of the metallocene prepared in Example 1(B) and 846 mg of MAO were dissolved in 15 ml of toluene. This solution was injected into the autoclave by means of nitrogen pressure through the stainless-steel vial. The polymerization was carried out for 1 hour. Then, the reaction was stopped by adding 600 cc of CO. After degasing the residual monomers, the product was collected and dryed at 60°C under a reduced nitrogen pressure.
- 105 g of an amorphous copolymer, having 39% by weight of 1-butene units, Tg = -9.5 and intrinsic viscosity of 2.37 dl/g, were obtained.
- It was worked as in Example 18, but the quantity of propylene which was fet into the autoclave was 120 g and, instead of the 1-butene, 200 g of 1-hexene were fed into the autoclave.
- 67 g of an amorphous copolymer, having 55.6% by weight of 1-hexene units, Tg = -15.8 and intrinsic viscosity of 1.65 dl/g, were obtained.
- It was worked as in Example 18, but the quantity of propylene which was fet into the autoclave was 130 g and, instead of the 1-butene, 270 g of 1-octene were fed into the autoclave.
- 75 g of an amorphous copolymer, having 66.3% by weight of 1-octene units, Tg = -32.3 and intrinsic viscosity of 1.71 dl/g, were obtained.
- It was worked as in Example 20, but the quantity of propylene which was fet into the autoclave was 200 g, and the quantity of 1-octene was 150 g.
- 6.2 g of an amorphous copolymer, having 39.4% by weight of 1-octene units, Tg = -16.3 and intrinsic viscosity of 2.15 dl/g, were obtained.
- It was worked as in Example 20, but the quantity of propylene which was fet into the autoclave was 270 g, and the quantity of 1-octene was 45 g.
-
Claims (12)
- A metallocene of the formula (I)
M is Ti, Zr or Hf;
substituents R², the same or different from each other, are halogen atoms, -OH, -SH, R¹, -OR¹, -SR¹, -NR¹₂ or PR¹₂, wherein R¹ is defined as above;
the group R³ is selected from >CR¹₂, >SiR¹₂, >GeR¹₂, >NR¹ or >PR¹, wherein R¹ is defined as above and optionally, when R³ is >CR¹₂, >SiR¹₂ or >GeR¹₂, both substituents R¹ can form a cycle comprising from 3 to 8 atoms. - The metallocene according to claim 1, wherein substituents R¹ are hydrogen atoms, substituents R² are chlorine or methyl groups, and the group R³ is a radical >Si(CH₃)₂.
- Dimethylsilandiylbis(fluorenyl)zirconium dichloride.
- A process for the preparation of a metallocene of formula (I) as claimed in claim 1, comprising:(a) the reaction of a compound of formula (II)(b) the subsequent reaction of the compound of formula (IV) obtained at point (a) with a compound able to form the dianion of formula (V)(c) in the case at least one R² in the metallocene of formula (I) to be prepared is different from halogen, the substitution of at least one substituent X in the compound of formula (VI) with at least one R² different from halogen.
- The process according to claim 4, wherein MX₄ is zirconium tetrachloride.
- The compound according to claim 6, wherein the group R³ is a radical >Si(CH₃)₂.
- A catalyst for the polymerization of olefins comprising the product of the reaction between:(A) a metallocene of formula (I) as claimed in claim 1, optionally as reaction product with an aluminium organo-metallic compound of formula AlR⁴₃ or Al₂R⁴₆, wherein substituents R⁴, the same or different from each other, are R¹ or halogen, and(B) an alumoxane, optionally mixed with an aluminium organo-metallic compound of formula AlR⁴₃ or Al₂R⁴₆, wherein substituents R⁴, the same or different from each other, are defined as above, or one or more compounds able to give a metallocene alkyl cation.
- The catalyst according to claim 8, wherein the compound able to form a metallocene alkyl cation is a compound of formula Y⁺Z⁻, wherein Y⁺ is a Bronsted acid, able to give a proton and to react irreversibly with a substituent R² of the metallocene of formula (I) and Z⁻ is a compatible anion, which does not coordinate, which is able to stabilize the active catalytic species originating from the reaction of the two compounds, and which is sufficiently labile to be able to be removed from an olefinic substrate.
- The catalyst according to claim 9, wherein the anion Y⁺ comprises one or more boron atoms.
- The catalyst according to claim 8, comprising the product of the reaction between dimethylsilandiylbis(fluorenyl)zirconium dichloride and a compound selected from methylalumoxane and isobutylalumoxane.
- A process for the polymerization of olefins comprising the polymerization reaction of an olefinic monomer in the presence of a catalyst as claimed in claim 8.
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JP4592848B2 (en) * | 1998-10-21 | 2010-12-08 | 三井化学株式会社 | Soft transparent syndiotactic polypropylene composition |
KR101154507B1 (en) | 2009-07-31 | 2012-06-13 | 주식회사 엘지화학 | Metallocene compounds, catalyst composition comprising the same, and method for preparation of olefin-based polymer using the same |
CN106459278B (en) * | 2014-04-17 | 2020-11-06 | 博里利斯股份公司 | Improved catalyst system for the preparation of polyethylene copolymers in a high temperature solution polymerization process |
WO2019139355A1 (en) * | 2018-01-11 | 2019-07-18 | 주식회사 엘지화학 | Method for preparing polyolefin by using supported hybrid metallocene catalyst |
KR102363189B1 (en) * | 2018-01-11 | 2022-02-15 | 주식회사 엘지화학 | Preparation method of polyolefin using a supported hybrid metallocene catalyst |
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JPH01249782A (en) * | 1988-03-30 | 1989-10-05 | Mitsubishi Metal Corp | Potassium salt of organic silicon compound for catalyst having high activity and production thereof |
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NL9101502A (en) * | 1991-09-06 | 1993-04-01 | Dsm Nv | A METHOD FOR PREPARING A BRIDGED METALLOCENE COMPOUND, A CATALYST COMPONENT AND A METHOD FOR THE POLYMERIZATION OF OLEFINS. |
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W.SPALECK ET AL: "Stereorigid Metallocenes: Correlations Between Structure and Behaviour in Homopolymerizations of Propylene", NEW JOURNAL OF CHEMISTRY, vol. 14, no. 6, July 1990 (1990-07-01), pages 69 - 73 |
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Also Published As
Publication number | Publication date |
---|---|
ES2162802T3 (en) | 2002-01-16 |
RU2169152C2 (en) | 2001-06-20 |
IT1256259B (en) | 1995-11-29 |
ITMI922988A0 (en) | 1992-12-30 |
DE69330780D1 (en) | 2001-10-25 |
EP0604908B1 (en) | 2001-09-19 |
CA2112598A1 (en) | 1994-07-01 |
JPH06256369A (en) | 1994-09-13 |
ITMI922988A1 (en) | 1994-06-30 |
DE69330780T2 (en) | 2002-07-04 |
KR940014423A (en) | 1994-07-18 |
FI935913A (en) | 1994-07-01 |
EP0604908A3 (en) | 1994-08-24 |
FI935913A0 (en) | 1993-12-29 |
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