EP1138090A1 - Organic solar cell or light-emitting diode - Google Patents
Organic solar cell or light-emitting diodeInfo
- Publication number
- EP1138090A1 EP1138090A1 EP99962081A EP99962081A EP1138090A1 EP 1138090 A1 EP1138090 A1 EP 1138090A1 EP 99962081 A EP99962081 A EP 99962081A EP 99962081 A EP99962081 A EP 99962081A EP 1138090 A1 EP1138090 A1 EP 1138090A1
- Authority
- EP
- European Patent Office
- Prior art keywords
- substance
- layer
- component according
- intermediate layer
- component
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Withdrawn
Links
Classifications
-
- H—ELECTRICITY
- H10—SEMICONDUCTOR DEVICES; ELECTRIC SOLID-STATE DEVICES NOT OTHERWISE PROVIDED FOR
- H10K—ORGANIC ELECTRIC SOLID-STATE DEVICES
- H10K50/00—Organic light-emitting devices
- H10K50/10—OLEDs or polymer light-emitting diodes [PLED]
- H10K50/11—OLEDs or polymer light-emitting diodes [PLED] characterised by the electroluminescent [EL] layers
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B82—NANOTECHNOLOGY
- B82Y—SPECIFIC USES OR APPLICATIONS OF NANOSTRUCTURES; MEASUREMENT OR ANALYSIS OF NANOSTRUCTURES; MANUFACTURE OR TREATMENT OF NANOSTRUCTURES
- B82Y10/00—Nanotechnology for information processing, storage or transmission, e.g. quantum computing or single electron logic
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B82—NANOTECHNOLOGY
- B82Y—SPECIFIC USES OR APPLICATIONS OF NANOSTRUCTURES; MEASUREMENT OR ANALYSIS OF NANOSTRUCTURES; MANUFACTURE OR TREATMENT OF NANOSTRUCTURES
- B82Y20/00—Nanooptics, e.g. quantum optics or photonic crystals
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B82—NANOTECHNOLOGY
- B82Y—SPECIFIC USES OR APPLICATIONS OF NANOSTRUCTURES; MEASUREMENT OR ANALYSIS OF NANOSTRUCTURES; MANUFACTURE OR TREATMENT OF NANOSTRUCTURES
- B82Y30/00—Nanotechnology for materials or surface science, e.g. nanocomposites
-
- H—ELECTRICITY
- H10—SEMICONDUCTOR DEVICES; ELECTRIC SOLID-STATE DEVICES NOT OTHERWISE PROVIDED FOR
- H10K—ORGANIC ELECTRIC SOLID-STATE DEVICES
- H10K30/00—Organic devices sensitive to infrared radiation, light, electromagnetic radiation of shorter wavelength or corpuscular radiation
- H10K30/10—Organic devices sensitive to infrared radiation, light, electromagnetic radiation of shorter wavelength or corpuscular radiation comprising heterojunctions between organic semiconductors and inorganic semiconductors
-
- H—ELECTRICITY
- H10—SEMICONDUCTOR DEVICES; ELECTRIC SOLID-STATE DEVICES NOT OTHERWISE PROVIDED FOR
- H10K—ORGANIC ELECTRIC SOLID-STATE DEVICES
- H10K30/00—Organic devices sensitive to infrared radiation, light, electromagnetic radiation of shorter wavelength or corpuscular radiation
- H10K30/10—Organic devices sensitive to infrared radiation, light, electromagnetic radiation of shorter wavelength or corpuscular radiation comprising heterojunctions between organic semiconductors and inorganic semiconductors
- H10K30/15—Sensitised wide-bandgap semiconductor devices, e.g. dye-sensitised TiO2
- H10K30/151—Sensitised wide-bandgap semiconductor devices, e.g. dye-sensitised TiO2 the wide bandgap semiconductor comprising titanium oxide, e.g. TiO2
-
- H—ELECTRICITY
- H10—SEMICONDUCTOR DEVICES; ELECTRIC SOLID-STATE DEVICES NOT OTHERWISE PROVIDED FOR
- H10K—ORGANIC ELECTRIC SOLID-STATE DEVICES
- H10K30/00—Organic devices sensitive to infrared radiation, light, electromagnetic radiation of shorter wavelength or corpuscular radiation
- H10K30/20—Organic devices sensitive to infrared radiation, light, electromagnetic radiation of shorter wavelength or corpuscular radiation comprising organic-organic junctions, e.g. donor-acceptor junctions
- H10K30/211—Organic devices sensitive to infrared radiation, light, electromagnetic radiation of shorter wavelength or corpuscular radiation comprising organic-organic junctions, e.g. donor-acceptor junctions comprising multiple junctions, e.g. double heterojunctions
-
- H—ELECTRICITY
- H10—SEMICONDUCTOR DEVICES; ELECTRIC SOLID-STATE DEVICES NOT OTHERWISE PROVIDED FOR
- H10K—ORGANIC ELECTRIC SOLID-STATE DEVICES
- H10K30/00—Organic devices sensitive to infrared radiation, light, electromagnetic radiation of shorter wavelength or corpuscular radiation
- H10K30/30—Organic devices sensitive to infrared radiation, light, electromagnetic radiation of shorter wavelength or corpuscular radiation comprising bulk heterojunctions, e.g. interpenetrating networks of donor and acceptor material domains
-
- H—ELECTRICITY
- H10—SEMICONDUCTOR DEVICES; ELECTRIC SOLID-STATE DEVICES NOT OTHERWISE PROVIDED FOR
- H10K—ORGANIC ELECTRIC SOLID-STATE DEVICES
- H10K30/00—Organic devices sensitive to infrared radiation, light, electromagnetic radiation of shorter wavelength or corpuscular radiation
- H10K30/30—Organic devices sensitive to infrared radiation, light, electromagnetic radiation of shorter wavelength or corpuscular radiation comprising bulk heterojunctions, e.g. interpenetrating networks of donor and acceptor material domains
- H10K30/35—Organic devices sensitive to infrared radiation, light, electromagnetic radiation of shorter wavelength or corpuscular radiation comprising bulk heterojunctions, e.g. interpenetrating networks of donor and acceptor material domains comprising inorganic nanostructures, e.g. CdSe nanoparticles
-
- H—ELECTRICITY
- H10—SEMICONDUCTOR DEVICES; ELECTRIC SOLID-STATE DEVICES NOT OTHERWISE PROVIDED FOR
- H10K—ORGANIC ELECTRIC SOLID-STATE DEVICES
- H10K85/00—Organic materials used in the body or electrodes of devices covered by this subclass
- H10K85/20—Carbon compounds, e.g. carbon nanotubes or fullerenes
- H10K85/211—Fullerenes, e.g. C60
-
- H—ELECTRICITY
- H10—SEMICONDUCTOR DEVICES; ELECTRIC SOLID-STATE DEVICES NOT OTHERWISE PROVIDED FOR
- H10K—ORGANIC ELECTRIC SOLID-STATE DEVICES
- H10K85/00—Organic materials used in the body or electrodes of devices covered by this subclass
- H10K85/30—Coordination compounds
- H10K85/311—Phthalocyanine
-
- H—ELECTRICITY
- H10—SEMICONDUCTOR DEVICES; ELECTRIC SOLID-STATE DEVICES NOT OTHERWISE PROVIDED FOR
- H10K—ORGANIC ELECTRIC SOLID-STATE DEVICES
- H10K85/00—Organic materials used in the body or electrodes of devices covered by this subclass
- H10K85/60—Organic compounds having low molecular weight
- H10K85/615—Polycyclic condensed aromatic hydrocarbons, e.g. anthracene
- H10K85/621—Aromatic anhydride or imide compounds, e.g. perylene tetra-carboxylic dianhydride or perylene tetracarboxylic di-imide
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- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y02—TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
- Y02E—REDUCTION OF GREENHOUSE GAS [GHG] EMISSIONS, RELATED TO ENERGY GENERATION, TRANSMISSION OR DISTRIBUTION
- Y02E10/00—Energy generation through renewable energy sources
- Y02E10/50—Photovoltaic [PV] energy
- Y02E10/549—Organic PV cells
-
- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y10—TECHNICAL SUBJECTS COVERED BY FORMER USPC
- Y10S—TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y10S362/00—Illumination
- Y10S362/80—Light emitting diode
Definitions
- the invention relates to a component with a first layer which essentially consists of a first material, a second layer essentially consisting of a second material and at least one intermediate layer located between the first layer and the second layer.
- a generic component is known from US-PS 5698048. There is an intermediate layer between the two layers, which contains a polymer, but not one of the two materials of the layers.
- a diode is known from US Pat. No. 5,454,880 in which a layer made of a polymer and a further layer containing fullerenes are adjacent to one another.
- the polymer is designed so that it acts as a donor, while the fullerenes act as acceptors for charge carriers.
- the invention has for its object to provide a generic component which has the highest possible efficiency for the transmission and / or reception of electromagnetic radiation, in particular light.
- the invention is intended to create a solar cell with the highest possible efficiency.
- this object is achieved in that a generic component is designed such that the intermediate layer contains the first material and / or the second material and that at least one substance is colloidally solved in the intermediate layer and that the substance is another Has conductivity than the first material or the second material.
- the invention therefore provides to create a component which has at least two layers of two materials with different conductivities and at least one intermediate layer located between them.
- the intermediate layer contains at least one of the two materials and a colloidally dissolved substance.
- Colloidally dissolved here means that the substance consists of particles or forms them by chemical reaction or agglomeration and that these particles are in the material.
- the particles preferably have a size of 1 nm to 1 ⁇ m.
- the particles are preferably in the material in such a way that they form a network over which
- Charge carriers can flow, for example in a percolation mechanism. It is advantageous, but not necessary, that charge carriers can flow in the material.
- the colloidally dissolved substance has a conductivity that is different both from the conductivity of the first material and from the conductivity of the second material. It is less a question of an absolute high level of conductivity than the way in which charge carriers are transported.
- a first expedient embodiment of the component is characterized in that it contains exactly one intermediate layer.
- the intermediate layer consists here, for example, of the first material and substance dissolved therein or of the second material and substance dissolved therein or of one
- Another, equally advantageous embodiment of the component is characterized by the fact that between the first layer and the second layer have a first intermediate layer and a second intermediate layer that the first intermediate layer lies against the first layer and that the second intermediate layer lies against the second layer.
- the intermediate layers can differ, for example, in that the first intermediate layer essentially contains the first material and the substance colloidally dissolved therein and that the second intermediate layer essentially consists of the second material and the substance colloidally dissolved therein.
- a first substance is colloidally dissolved in the first intermediate layer and that a second substance is colloidally dissolved in the second intermediate layer.
- first and / or second material is a semiconductor.
- the first material and / or the second material is an organic semiconductor.
- the first material and / or the second material are advantageous for use of the component as a solar cell or as part of a solar cell.
- the organic semiconductor expediently contains substituted perylene pigments. It is particularly expedient for the perylene pigments to be substituted perylene carboxylic acid imides.
- the second material contains an organic complex compound, in particular an organometallic complex compound.
- This is preferably a phthalocyanine compound.
- hydrogen phthalocyanine or metal phthalocyanines, in particular zinc phthalocyanine is particularly advantageous.
- a preferred embodiment of the component according to the invention is characterized in that the substance consists of a semiconductor material.
- semiconductor material encompasses all substances known from semiconductor technology as semiconductor materials. However, the term semiconductor material is not limited to materials generally referred to as semiconductors, but rather encompasses all of them
- the conductivity of particles of the substance can differ from the macroscopic conductivity.
- Electrical conduction is expedient for the invention to the extent that charge carriers of a conductivity type can be removed in a targeted manner.
- An increase in the conductivity by means of a suitable nanostructure by means of which, for example, a substance which macroscopically forms a semiconductor acts as a metal in the layer according to the invention, is therefore included. This also applies to macroscopic metallic materials that become semiconductors as small particles.
- a preferred embodiment of the component is characterized in that the substance consists of an organic semiconductor material.
- the substance contains a carbon modification
- Carbon modification has a band gap such as C 6O ⁇ C 70 or graphene.
- a particularly effective transport of the charge while avoiding electrical short circuits is achieved in that the substance is essentially in the form of particles.
- the particles are, for example, individual molecules, in particular individual fullerene molecules, or clusters of several molecules.
- the particles preferably have a size of 1 nm to 1 ⁇ m, an upper particle size of 200 nm being preferred.
- a significant increase in charge transport is achieved because the particles have a concentration that is so high that percolation occurs.
- a further increase in the efficiency when emitting and / or receiving electromagnetic radiation can be achieved by the fact that the concentration of the substance varies spatially.
- This variant of the invention therefore provides to create a component which has an intermediate layer within which a concentration of a colloidally dissolved substance varies spatially.
- the intermediate layer is located between the first layer and the second layer, it being possible for these layers to be located within a common carrier material.
- the first and second layers can differ little from each other or can consist of completely different materials.
- the first and the second material preferably differ only in that they are doped differently.
- An expedient embodiment of the component is characterized in that the concentration of the substance varies within the intermediate layer.
- the component prefferably be designed such that there are at least two substances in the intermediate layer.
- one of the substances has a concentration that varies spatially differently than a concentration of the other substance.
- a useful embodiment of the component is characterized in that the first substance has a Fermi level that differs by at least 20 meV from a Fermi level of the second substance.
- the first substance has a different conductivity type than the other substance.
- An expedient embodiment of the component is characterized in that one substance has a different band gap than the other substance.
- the band gap of the first substance differs from the band gap of the second substance by at least 20 meV.
- FIG. 1 shows a cross section through a first embodiment of a component according to the invention
- Fig. 2 shows an external quantum yield as the ratio of a current flow to incident photons (Incident Photon To Current Efficiency - IPCE) in
- FIG. 3 shows a cross section through a second embodiment of a component according to the invention
- Fig. 4 shows a cross section through another
- the component shown in FIG. 1 is, for example, a solar cell or an organic light-emitting diode.
- the component contains a layer system applied to a substrate 10, for example glass, in particular silicate glass, comprising a transparent contact layer 20, a first layer 30, a second layer 60, an intermediate layer 50 and a contacting layer 70.
- a contact 80 is applied to a lateral area of the transparent contact layer 20.
- Another contact 90 is located on the upper contacting layer 70.
- the transparent contact layer 20 has a thickness between 5 nm and 1 ⁇ m, preferably 10 nm to 200 nm. The thickness of the contact layer 20 can be chosen variably.
- the first layer 30 is located on the transparent contact layer. It is possible that the first layer 30 also extends in sections onto the substrate 10, for example in areas in which the transparent contact layer 20 was previously etched away. For the achievement of the border surface effects between the transparent contact layer 20 and the first layer 30, however, this is not necessary.
- the first layer 30 projects beyond the transparent contact layer 20, because a short circuit between the contact 90 and the transparent contact layer 20 is thus avoided.
- the first layer 30 has a thickness between 5 nm and 1000 nm, preferably 10 nm to 200 nm.
- the thickness of the layer 30 can be chosen variably because the dimensions of the layers 30, 60 are not important in order to achieve the interface effects between the layers 30 and 60.
- the contact layer 20 preferably consists of a transparent material, which is in particular a transparent conductive oxide.
- the transparent properties are necessary when used as a solar cell or as a light-emitting diode with light that penetrates through the substrate 10, so that light rays penetrating through the substrate 10 are not absorbed by the contact layer 20.
- the translucent design of the contact layer 20 is not necessary.
- the first layer 30 is preferably made of an organic semiconducting material of a first conductivity type.
- it is an n-conducting material, preferably perylene-3, 4, 9, 10-tetracarboxylic acid-N, N'-dimethylimide (MPP).
- the second layer 60 is preferably made of a second semiconducting material. This is, in particular, a material with an opposite conductivity type, preferably zinc phthaiocyanine (ZnPc).
- a Contacting layer 70 serves for an electrical connection of layer 60
- Contacting layer 70 made of gold has the particular advantage that it combines high electrical conductivity with high chemical resistance.
- the intermediate layer 50 contains the same material as the layer 60, but is enriched with a fullerene or a semiconductor oxide such as T ⁇ 0 2 .
- the enrichment is preferably a maximum of 60% when the component is used as a solar cell. If the component is used as a light-emitting diode, the enrichment can be even higher.
- the component shown in FIG. 1 is, for example, a solar cell or an organic light-emitting diode.
- the component contains a layer system applied to a substrate 10, for example glass, in particular silicate glass, comprising a transparent contact layer 20, a first layer 30, a second layer 60, a first intermediate layer 40, a second Intermediate layer 50 and a contacting layer 70.
- a substrate 10 for example glass, in particular silicate glass, comprising a transparent contact layer 20, a first layer 30, a second layer 60, a first intermediate layer 40, a second Intermediate layer 50 and a contacting layer 70.
- a contact 80 is applied to a lateral area of the transparent contact layer 20.
- Another contact 90 is located on the upper contacting layer 70.
- the transparent contact layer 20 has a thickness between 5 nm and 1000 nm, preferably 10 nm to 200 nm. The thickness of the layer can be chosen variably.
- the first layer 30 is located on the transparent contact layer. It is possible that the first layer 30 also extends in sections onto the substrate 10, for example in areas in which the transparent contact layer 20 was previously etched away.
- the first layer 30 projects beyond the transparent contact layer 20, because a short circuit between the contact 90 and the transparent contact layer 20 is thus avoided.
- the first layer 30 has a thickness between 5 nm and 1000 nm, preferably 10 nm to 200 nm.
- the thickness of the layer can be chosen variably because the dimensions of the layers are not important in order to achieve the interface effects.
- the contact layer 20 consists of a transparent material, which is in particular a transparent conductive oxide.
- the first layer 30 preferably consists of a organic semiconducting material of a first conductivity type.
- a first conductivity type preferably perylene-3, 4, 9, 10-tetracarboxylic acid N, '-dimethylimide (MPP).
- the second layer 60 is preferably made of a second semiconducting material. This is, in particular, a material with an opposite conductivity type, preferably zinc phthalocyanine (ZnPc).
- a contacting layer 70 serves for an electrical connection of the layer 60
- Contacting layer 70 made of gold has the particular advantage that it combines high electrical conductivity with high chemical resistance.
- the first intermediate layer 40 contains the material contained in the first layer 30 and possibly also the material contained in the second layer 60, preferably at least one organic semiconductor. MPP or ZnPc are particularly suitable. Furthermore, the intermediate layer 40 is enriched with a fullerene or another semiconductor material such as Ti0 2 . The enrichment is preferably a maximum of 60% when the component is used as a solar cell. If the component is used as a light-emitting diode, the enrichment can be even higher.
- the second intermediate layer 50 contains the same material as the layer 60, but is enriched with a different fullerene or a semiconductor material such as Ti0 2 .
- Enrichment is preferably a maximum of 60% when the component is used as a solar cell. If the component is used as a light-emitting diode, the enrichment can be even higher.
- the component shown in FIG. 4 is, for example, a solar cell or an organic light-emitting diode.
- the component contains a layer system applied to a substrate 10, for example glass, in particular silicate glass, comprising a transparent contact layer 20, a multiple layer and a contacting layer 70.
- the multiple layer preferably consists of a first layer 30, a second layer 60 and an intermediate layer 40.
- a contact 80 is applied to a lateral area of the transparent contact layer 20.
- Another contact 90 is located on the upper contacting layer 70.
- the transparent contact layer 20 has a thickness between 5 nm and 1 ⁇ m, preferably 10 nm to 200 nm. The thickness of the contact layer 20 can be chosen variably.
- the first layer 30 is located on the transparent contact layer. It is possible that the first layer 30 also extends in sections onto the substrate 10, for example in areas in which the transparent contact layer 20 was previously etched away. However, this is not necessary in order to achieve the interface effects between the transparent contact layer 20 and the first layer 30.
- the first layer 30 projects beyond the transparent contact layer 20, because a short circuit between the contact 90 and the transparent contact layer 20 is avoided in this way.
- the first layer 30 has a thickness between 5 nm and 1000 nm, preferably 10 nm to 200 nm.
- the thickness of the layer 30 can be chosen variably because it is not to achieve the interface effects between the layers 30 and 60 the dimensions of the layers 30, 60 are important.
- the contact layer 20 preferably consists of a transparent material, which is in particular a transparent conductive oxide.
- the layer 30 essentially consists of a matrix material and a semiconductor colloidally dissolved therein.
- the semiconductor preferably has a first conductivity type.
- it is an n-type material, preferably cadmium sulfide (CdS), n-doped gallium arsenide (GaAs), n-doped silicon, n-doped cadmium tellurite (CdTe) or em-substituted perylene pigment, in particular em-methylene-substituted perylene pigment, especially perylene-3, 4, 9, 10-tetracarboxylic acid-N, N'-dimethylimide (MPP).
- CdS cadmium sulfide
- GaAs gallium arsenide
- CdTe n-doped silicon
- CdTe n-doped cadmium tellurite
- em-substituted perylene pigment in particular em-
- the second layer 60 preferably consists of one
- the second semiconducting material is in particular a material with a conductivity type opposite to the first semiconducting material, for example p-doped zinc phthalocyanine (ZnPc), p-doped gallium arsenide (GaAs) or p-doped silicon.
- ZnPc zinc phthalocyanine
- GaAs gallium arsenide
- silicon p-doped silicon
- a contacting layer 70 serves for an electrical connection of the layer 60 Contact layer 70 to achieve high electrical conductivity and high chemical resistance made of gold.
- At least one intermediate layer 40 is located between the first layer 30 and the second layer 60.
- the intermediate layer 40 contains a suitable matrix material. If the layer 30 has the same matrix material as the layer 60, it is expedient that the intermediate layer 40 also consists of this matrix material. If, as is also possible, the layer 30 has a different matrix material than the layer 60, it is preferred that the intermediate layer 40 consists of a mixture or a solution of the matrix materials with one or more substances colloidally dissolved therein.
- the multilayer is produced by alternately immersing it in differently concentrated solutions. As a result, the layers which form the multiple layer are deposited in succession.
- a layer system is deposited on the substrate 10 as follows: wetting, in particular a dip coating, for example of indium-zinc oxide (ITO), takes place with a colloidal, in particular aqueous solution of particles, for example initially CdTe particles, the substrate 10 being immersed in succession in differently concentrated solutions. Immersion times and pulling speeds are varied so that first only CdTe particles, then mixtures with variable composition, then pure CdS particles build up the layer.
- ITO indium-zinc oxide
- the colloidal solution from which the layers are deposited by dip-coating can be a stabilizer included, but this is not necessary.
- a preferred stabilizer is polysulfate, which forms a shell around the particles in the solution that prevents the particles from growing together. When the layers are deposited, the stabilizer forms a matrix material in which the particles are embedded.
- colloidal solution does not contain a stabilizer, there is a space charge zone around the particles - ionic layer - with charges that prevent the
- the concentration of a first dopant decreases largely linearly in a range of approximately 100 ⁇ m.
- FIG. 6 shows a concentration of a second dopant as a function of its distance from the region of the first layer 30.
- the second dopant is, for example, CdS.
- the concentration of the second dopant increases largely linearly in a range of approximately 100 ⁇ m.
- the second dopant lies in the about 100 ⁇ m wide range also a substantially constant concentration gradient.
- the concentration gradients of the dopants differ only by their sign.
- concentration profile is preferred, the preferred exemplary embodiments of the invention with a changing concentration are in no way limited to linear concentration changes.
Abstract
Description
Claims
Applications Claiming Priority (5)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
DE19854938 | 1998-11-27 | ||
DE19854938A DE19854938A1 (en) | 1998-11-27 | 1998-11-27 | Component used as a solar cell or LED, has layers separated by an interlayer containing one or both layer materials and a different conductivity material colloid |
DE19905694 | 1999-02-11 | ||
DE19905694A DE19905694A1 (en) | 1998-11-27 | 1999-02-11 | Component |
PCT/DE1999/003759 WO2000033396A1 (en) | 1998-11-27 | 1999-11-26 | Organic solar cell or light-emitting diode |
Publications (1)
Publication Number | Publication Date |
---|---|
EP1138090A1 true EP1138090A1 (en) | 2001-10-04 |
Family
ID=26050436
Family Applications (1)
Application Number | Title | Priority Date | Filing Date |
---|---|---|---|
EP99962081A Withdrawn EP1138090A1 (en) | 1998-11-27 | 1999-11-26 | Organic solar cell or light-emitting diode |
Country Status (6)
Country | Link |
---|---|
US (1) | US6559375B1 (en) |
EP (1) | EP1138090A1 (en) |
JP (1) | JP4467805B2 (en) |
DE (1) | DE19905694A1 (en) |
HK (1) | HK1042589A1 (en) |
WO (1) | WO2000033396A1 (en) |
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SE0103740D0 (en) * | 2001-11-08 | 2001-11-08 | Forskarpatent I Vaest Ab | Photovoltaic element and production methods |
DE10059498A1 (en) | 2000-11-30 | 2002-06-13 | Infineon Technologies Ag | Substrate with a semiconducting layer, electronic component with this substrate, electronic circuit with at least one such electronic component, printable composition and method for producing a substrate |
JP4461656B2 (en) | 2000-12-07 | 2010-05-12 | セイコーエプソン株式会社 | Photoelectric conversion element |
JP4162116B2 (en) * | 2000-12-08 | 2008-10-08 | 富士フイルム株式会社 | Photoelectric conversion element and photoelectrochemical cell |
SG2009086778A (en) | 2000-12-28 | 2016-11-29 | Semiconductor Energy Lab Co Ltd | Luminescent device |
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WO2003043934A1 (en) * | 2001-11-20 | 2003-05-30 | Wm. Marsh Rice University | Coated fullerenes, composites and dielectrics made therefrom |
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WO2004083958A2 (en) * | 2003-03-19 | 2004-09-30 | Technische Universität Dresden | Photoactive component comprising organic layers |
KR101036539B1 (en) * | 2003-03-24 | 2011-05-24 | 코나르카 테크놀로지, 인코포레이티드 | Photovoltaic cell with mesh electrode |
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JP4862252B2 (en) * | 2003-08-22 | 2012-01-25 | 株式会社日本触媒 | Manufacturing method of organic solar cell |
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WO2005029592A1 (en) * | 2003-09-16 | 2005-03-31 | Midwest Research Intstitute | Organic photovoltaic cells with an electric field integrally-formed at the heterojunction interface |
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JP2002531958A (en) | 2002-09-24 |
JP4467805B2 (en) | 2010-05-26 |
WO2000033396A1 (en) | 2000-06-08 |
HK1042589A1 (en) | 2002-08-16 |
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