EP1322728A4 - The use of hydrogen to regenerate metal oxide hydrogen sulfide sorbents - Google Patents

The use of hydrogen to regenerate metal oxide hydrogen sulfide sorbents

Info

Publication number: EP1322728A4
Authority: EP; European Patent Office
Prior art keywords: hydrogen; metal oxide; hydrogen sulfide; sulfide sorbents; regenerate metal
Prior art date: 2000-07-21
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.): Withdrawn

Application number

EP01952851A

Other languages

German (de)

French (fr)

Other versions

EP1322728A1 (en

Inventor

Jingguang G Chen

Leo Dale Brown

William Chalmers Baird Jr

Gary Brice Mcvicker

Edward Stanley Ellis

Michele Sue Touvelle

Darryl Patrick Klein

David Evan William Vaughan

Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)

ExxonMobil Technology and Engineering Co

Original Assignee

ExxonMobil Research and Engineering Co

Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)

2000-07-21

Filing date

2001-07-19

Publication date

2004-10-06

2001-07-19 Application filed by ExxonMobil Research and Engineering Co filed Critical ExxonMobil Research and Engineering Co

2003-07-02 Publication of EP1322728A1 publication Critical patent/EP1322728A1/en

2004-10-06 Publication of EP1322728A4 publication Critical patent/EP1322728A4/en

Status Withdrawn legal-status Critical Current

Links

Classifications

- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J20/00—Solid sorbent compositions or filter aid compositions; Sorbents for chromatography; Processes for preparing, regenerating or reactivating thereof
- B01J20/30—Processes for preparing, regenerating, or reactivating
- B01J20/34—Regenerating or reactivating
- B01J20/345—Regenerating or reactivating using a particular desorbing compound or mixture
- B01J20/3458—Regenerating or reactivating using a particular desorbing compound or mixture in the gas phase
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J20/00—Solid sorbent compositions or filter aid compositions; Sorbents for chromatography; Processes for preparing, regenerating or reactivating thereof
- B01J20/02—Solid sorbent compositions or filter aid compositions; Sorbents for chromatography; Processes for preparing, regenerating or reactivating thereof comprising inorganic material
- B01J20/0203—Solid sorbent compositions or filter aid compositions; Sorbents for chromatography; Processes for preparing, regenerating or reactivating thereof comprising inorganic material comprising compounds of metals not provided for in B01J20/04
- B01J20/0225—Compounds of Fe, Ru, Os, Co, Rh, Ir, Ni, Pd, Pt
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J20/00—Solid sorbent compositions or filter aid compositions; Sorbents for chromatography; Processes for preparing, regenerating or reactivating thereof
- B01J20/02—Solid sorbent compositions or filter aid compositions; Sorbents for chromatography; Processes for preparing, regenerating or reactivating thereof comprising inorganic material
- B01J20/06—Solid sorbent compositions or filter aid compositions; Sorbents for chromatography; Processes for preparing, regenerating or reactivating thereof comprising inorganic material comprising oxides or hydroxides of metals not provided for in group B01J20/04
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J20/00—Solid sorbent compositions or filter aid compositions; Sorbents for chromatography; Processes for preparing, regenerating or reactivating thereof
- B01J20/02—Solid sorbent compositions or filter aid compositions; Sorbents for chromatography; Processes for preparing, regenerating or reactivating thereof comprising inorganic material
- B01J20/06—Solid sorbent compositions or filter aid compositions; Sorbents for chromatography; Processes for preparing, regenerating or reactivating thereof comprising inorganic material comprising oxides or hydroxides of metals not provided for in group B01J20/04
- B01J20/08—Solid sorbent compositions or filter aid compositions; Sorbents for chromatography; Processes for preparing, regenerating or reactivating thereof comprising inorganic material comprising oxides or hydroxides of metals not provided for in group B01J20/04 comprising aluminium oxide or hydroxide; comprising bauxite
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J20/00—Solid sorbent compositions or filter aid compositions; Sorbents for chromatography; Processes for preparing, regenerating or reactivating thereof
- B01J20/02—Solid sorbent compositions or filter aid compositions; Sorbents for chromatography; Processes for preparing, regenerating or reactivating thereof comprising inorganic material
- B01J20/10—Solid sorbent compositions or filter aid compositions; Sorbents for chromatography; Processes for preparing, regenerating or reactivating thereof comprising inorganic material comprising silica or silicate
- B01J20/103—Solid sorbent compositions or filter aid compositions; Sorbents for chromatography; Processes for preparing, regenerating or reactivating thereof comprising inorganic material comprising silica or silicate comprising silica
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J20/00—Solid sorbent compositions or filter aid compositions; Sorbents for chromatography; Processes for preparing, regenerating or reactivating thereof
- B01J20/30—Processes for preparing, regenerating, or reactivating
- B01J20/32—Impregnating or coating ; Solid sorbent compositions obtained from processes involving impregnating or coating
- B01J20/3202—Impregnating or coating ; Solid sorbent compositions obtained from processes involving impregnating or coating characterised by the carrier, support or substrate used for impregnation or coating
- B01J20/3204—Inorganic carriers, supports or substrates
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J20/00—Solid sorbent compositions or filter aid compositions; Sorbents for chromatography; Processes for preparing, regenerating or reactivating thereof
- B01J20/30—Processes for preparing, regenerating, or reactivating
- B01J20/32—Impregnating or coating ; Solid sorbent compositions obtained from processes involving impregnating or coating
- B01J20/3231—Impregnating or coating ; Solid sorbent compositions obtained from processes involving impregnating or coating characterised by the coating or impregnating layer
- B01J20/3234—Inorganic material layers
- B01J20/3236—Inorganic material layers containing metal, other than zeolites, e.g. oxides, hydroxides, sulphides or salts
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J20/00—Solid sorbent compositions or filter aid compositions; Sorbents for chromatography; Processes for preparing, regenerating or reactivating thereof
- B01J20/30—Processes for preparing, regenerating, or reactivating
- B01J20/34—Regenerating or reactivating
- B01J20/3433—Regenerating or reactivating of sorbents or filter aids other than those covered by B01J20/3408 - B01J20/3425
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J23/00—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00
- B01J23/70—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of the iron group metals or copper
- B01J23/89—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of the iron group metals or copper combined with noble metals
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J23/00—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00
- B01J23/90—Regeneration or reactivation
- B01J23/94—Regeneration or reactivation of catalysts comprising metals, oxides or hydroxides of the iron group metals or copper
- C—CHEMISTRY; METALLURGY
- C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
- C10G—CRACKING HYDROCARBON OILS; PRODUCTION OF LIQUID HYDROCARBON MIXTURES, e.g. BY DESTRUCTIVE HYDROGENATION, OLIGOMERISATION, POLYMERISATION; RECOVERY OF HYDROCARBON OILS FROM OIL-SHALE, OIL-SAND, OR GASES; REFINING MIXTURES MAINLY CONSISTING OF HYDROCARBONS; REFORMING OF NAPHTHA; MINERAL WAXES
- C10G25/00—Refining of hydrocarbon oils in the absence of hydrogen, with solid sorbents
- C10G25/003—Specific sorbent material, not covered by C10G25/02 or C10G25/03
- C—CHEMISTRY; METALLURGY
- C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
- C10G—CRACKING HYDROCARBON OILS; PRODUCTION OF LIQUID HYDROCARBON MIXTURES, e.g. BY DESTRUCTIVE HYDROGENATION, OLIGOMERISATION, POLYMERISATION; RECOVERY OF HYDROCARBON OILS FROM OIL-SHALE, OIL-SAND, OR GASES; REFINING MIXTURES MAINLY CONSISTING OF HYDROCARBONS; REFORMING OF NAPHTHA; MINERAL WAXES
- C10G45/00—Refining of hydrocarbon oils using hydrogen or hydrogen-generating compounds
- C10G45/02—Refining of hydrocarbon oils using hydrogen or hydrogen-generating compounds to eliminate hetero atoms without changing the skeleton of the hydrocarbon involved and without cracking into lower boiling hydrocarbons; Hydrofinishing
- C10G45/04—Refining of hydrocarbon oils using hydrogen or hydrogen-generating compounds to eliminate hetero atoms without changing the skeleton of the hydrocarbon involved and without cracking into lower boiling hydrocarbons; Hydrofinishing characterised by the catalyst used
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J2220/00—Aspects relating to sorbent materials
- B01J2220/50—Aspects relating to the use of sorbent or filter aid materials
- B01J2220/56—Use in the form of a bed

EP01952851A 2000-07-21 2001-07-19 The use of hydrogen to regenerate metal oxide hydrogen sulfide sorbents Withdrawn EP1322728A4 (en)

Applications Claiming Priority (3)

Application Number	Priority Date	Filing Date	Title
US62086400A	2000-07-21	2000-07-21
US620864		2000-07-21
PCT/US2001/022734 WO2002008361A1 (en)	2000-07-21	2001-07-19	The use of hydrogen to regenerate metal oxide hydrogen sulfide sorbents

Publications (2)

Publication Number	Publication Date
EP1322728A1 EP1322728A1 (en)	2003-07-02
EP1322728A4 true EP1322728A4 (en)	2004-10-06

Family

ID=24487726

Family Applications (1)

Application Number	Title	Priority Date	Filing Date
EP01952851A Withdrawn EP1322728A4 (en)	2000-07-21	2001-07-19	The use of hydrogen to regenerate metal oxide hydrogen sulfide sorbents

Country Status (6)

Country	Link
EP (1)	EP1322728A4 (en)
JP (1)	JP2004504478A (en)
AU (1)	AU2001273566A1 (en)
CA (1)	CA2416236A1 (en)
NO (1)	NO20030283L (en)
WO (1)	WO2002008361A1 (en)

Families Citing this family (4)

* Cited by examiner, † Cited by third party
Publication number	Priority date	Publication date	Assignee	Title
EP1345693B1 (en) *	2000-12-22	2007-03-28	Eurecat S.A.	Regeneration method of heterogeneous catalysts and adsorbents
GB0115850D0 (en)	2001-06-28	2001-08-22	Isis Innovations Ltd	Catalyst
US7074324B2 (en) *	2002-06-05	2006-07-11	Exxonmobil Research And Engineering Company	Process to remove sulfur contaminants from hydrocarbon streams
WO2008156524A1 (en)	2007-06-14	2008-12-24	Exxonmobil Upstream Research Company	Process for purification of hydrocarbons

Citations (6)

* Cited by examiner, † Cited by third party
Publication number	Priority date	Publication date	Assignee	Title
EP0244243A1 (en) *	1986-05-01	1987-11-04	Exxon Research And Engineering Company	removal of sulfur from process streams
US4729889A (en) *	1985-03-29	1988-03-08	California Institute Of Technology	High temperature regenerative H2 S sorbents
US5925239A (en) *	1996-08-23	1999-07-20	Exxon Research And Engineering Co.	Desulfurization and aromatic saturation of feedstreams containing refractory organosulfur heterocycles and aromatics
US5928498A (en) *	1996-08-23	1999-07-27	Exxon Research And Engineering Co.	Desulfurization and ring opening of petroleum streams
US5935420A (en) *	1996-08-23	1999-08-10	Exxon Research And Engineering Co.	Desulfurization process for refractory organosulfur heterocycles
WO2001044407A1 (en) *	1999-12-14	2001-06-21	Philips Petroleum Company	Desulfurization process and novel bimetallic sorbent systems for same

Family Cites Families (3)

* Cited by examiner, † Cited by third party
Publication number	Priority date	Publication date	Assignee	Title
US5439583A (en) *	1984-10-31	1995-08-08	Chevron Research And Technology Company	Sulfur removal systems for protection of reforming crystals
US5045175A (en) *	1989-12-28	1991-09-03	Uop	Separation system for C4 hydrotreater effluent having reduced hydrocarbon loss
GB9421705D0 (en) *	1994-10-27	1994-12-14	Ici Plc	Purification process

2001
- 2001-07-19 JP JP2002514251A patent/JP2004504478A/en active Pending
- 2001-07-19 AU AU2001273566A patent/AU2001273566A1/en not_active Abandoned
- 2001-07-19 EP EP01952851A patent/EP1322728A4/en not_active Withdrawn
- 2001-07-19 WO PCT/US2001/022734 patent/WO2002008361A1/en not_active Application Discontinuation
- 2001-07-19 CA CA002416236A patent/CA2416236A1/en not_active Abandoned
2003
- 2003-01-20 NO NO20030283A patent/NO20030283L/en not_active Application Discontinuation

Patent Citations (6)

* Cited by examiner, † Cited by third party
Publication number	Priority date	Publication date	Assignee	Title
US4729889A (en) *	1985-03-29	1988-03-08	California Institute Of Technology	High temperature regenerative H2 S sorbents
EP0244243A1 (en) *	1986-05-01	1987-11-04	Exxon Research And Engineering Company	removal of sulfur from process streams
US5925239A (en) *	1996-08-23	1999-07-20	Exxon Research And Engineering Co.	Desulfurization and aromatic saturation of feedstreams containing refractory organosulfur heterocycles and aromatics
US5928498A (en) *	1996-08-23	1999-07-27	Exxon Research And Engineering Co.	Desulfurization and ring opening of petroleum streams
US5935420A (en) *	1996-08-23	1999-08-10	Exxon Research And Engineering Co.	Desulfurization process for refractory organosulfur heterocycles
WO2001044407A1 (en) *	1999-12-14	2001-06-21	Philips Petroleum Company	Desulfurization process and novel bimetallic sorbent systems for same

Non-Patent Citations (1)

* Cited by examiner, † Cited by third party
Title
See also references of WO0208361A1 *

Also Published As

Publication number	Publication date
CA2416236A1 (en)	2002-01-31
WO2002008361A1 (en)	2002-01-31
AU2001273566A1 (en)	2002-02-05
NO20030283L (en)	2003-03-18
JP2004504478A (en)	2004-02-12
NO20030283D0 (en)	2003-01-20
EP1322728A1 (en)	2003-07-02

Legal Events

Date	Code	Title	Description
2003-05-16	PUAI	Public reference made under article 153(3) epc to a published international application that has entered the european phase	Free format text: ORIGINAL CODE: 0009012
2003-07-02	17P	Request for examination filed	Effective date: 20030212
2003-07-02	AK	Designated contracting states	Designated state(s): AT BE CH CY DE DK ES FI FR GB GR IE IT LI LU MC NL PT SE TR
2003-07-02	AX	Request for extension of the european patent	Extension state: AL LT LV MK RO SI
2003-08-06	RIN1	Information on inventor provided before grant (corrected)	Inventor name: VAUGHAN, DAVID, EVAN, WILLIAM Inventor name: KLEIN, DARRYL, PATRICK Inventor name: TOUVELLE, MICHELE, SUE Inventor name: ELLIS, EDWARD, STANLEY Inventor name: MCVICKER, GARY, BRICE Inventor name: BAIRD, WILLIAM, CHALMERS, JR. Inventor name: BROWN, LEO, DALE Inventor name: CHEN, JINGGUANG, G.
2004-10-06	A4	Supplementary search report drawn up and despatched	Effective date: 20040823
2004-10-06	RIC1	Information provided on ipc code assigned before grant	Ipc: 7C 07C 7/00 B Ipc: 7C 10G 45/00 B Ipc: 7B 01J 20/00 B Ipc: 7C 10G 45/10 B Ipc: 7C 10G 45/08 B Ipc: 7C 10G 45/06 B Ipc: 7C 10G 45/04 B Ipc: 7B 01J 38/12 B Ipc: 7B 01J 38/10 B Ipc: 7B 01J 38/04 B Ipc: 7B 01J 20/34 B Ipc: 7C 07C 7/12 A
2005-04-01	STAA	Information on the status of an ep patent application or granted ep patent	Free format text: STATUS: THE APPLICATION IS DEEMED TO BE WITHDRAWN
2005-05-18	18D	Application deemed to be withdrawn	Effective date: 20041207

Publication	Publication Date	Title
EP1223095A4 (en)	2004-11-17	Body structure
IL154534A0 (en)	2003-09-17	Cathartic composition
GB2359564B (en)	2004-09-29	Improvements in the electrolytic reduction of metal oxides
NO20030289D0 (en)	2003-01-20	Regeneration of hydrogen sulfide sorbents
GB0021885D0 (en)	2000-10-18	New use
EP1465966A4 (en)	2006-02-01	Desulfurization with improved sorbent regeneration background of the invention
NO20030284D0 (en)	2003-01-20	Regeneration of iron-based hydrogen sulfide sorbents
EP1322728A4 (en)	2004-10-06	The use of hydrogen to regenerate metal oxide hydrogen sulfide sorbents
AU3860101A (en)	2001-09-03	Utility lighter
PL360945A1 (en)	2004-09-20	Compressed metal oxide composition
AU141436S (en)	2000-08-14	Pencil case
GB0006864D0 (en)	2000-05-10	New use
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GB0121137D0 (en)	2001-10-24	Improvements to motorbility vehicles
AU1046702A (en)	2002-03-22	New use
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GB0004183D0 (en)	2000-04-12	New use
GB0018248D0 (en)	2000-09-13	New use
GB0004155D0 (en)	2000-04-12	Metal reduction
TW444669U (en)	2001-07-01	Pen structure
CA92372S (en)	2001-05-18	Utility lighter
GB0109595D0 (en)	2001-06-06	Hydro exhaust filter
GB0022677D0 (en)	2000-11-01	Porous refractory body
GB0015380D0 (en)	2000-08-16	Particulate metal oxide
GB0021760D0 (en)	2000-10-18	Recovery of metals