US1475396A - Method of treating water - Google Patents

Method of treating water Download PDF

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Publication number
US1475396A
US1475396A US461925A US46192521A US1475396A US 1475396 A US1475396 A US 1475396A US 461925 A US461925 A US 461925A US 46192521 A US46192521 A US 46192521A US 1475396 A US1475396 A US 1475396A
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US
United States
Prior art keywords
iron
manganese
treating water
oxygen
water
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Expired - Lifetime
Application number
US461925A
Inventor
Kestner Paul
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Individual
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Individual
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Filing date
Publication date
Priority to FR516710A priority Critical patent/FR516710A/en
Priority to GB227521A priority patent/GB164712A/en
Application filed by Individual filed Critical Individual
Priority to US461925A priority patent/US1475396A/en
Application granted granted Critical
Publication of US1475396A publication Critical patent/US1475396A/en
Anticipated expiration legal-status Critical
Expired - Lifetime legal-status Critical Current

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Classifications

    • CCHEMISTRY; METALLURGY
    • C02TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
    • C02FTREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
    • C02F1/00Treatment of water, waste water, or sewage
    • C02F1/20Treatment of water, waste water, or sewage by degassing, i.e. liberation of dissolved gases

Definitions

  • This invention consists in improved metallic media for the fixation of the oxygen of water in apparatus for abstracting gases from li uids. g
  • the xation of the oxygen dimolved in water is brought about in apparatus for ab- 2 stracting gases from liquids by the chemical combination of this oxygen with iron filings and turnings, and is represented by the to lowing chemical reactions:
  • he manganese acts as a catalyst in the oxidation and combines instantaneously with the oxygen, yielding oxide of iron and protoxide of manganese, MnO, capable of oxidizing in turn into dioxide and sesquioxide, which can be reduced again by the iron.
  • MnO protoxide of manganese
  • the proportion of manganese most favourable for'the catalysis is over 5% of the weight of the metal and below 6% of the weight of the iron.
  • the speed of reaction [0 is proportional to the quantity of man, ganese employed and inversely proportional to the quantity of-carbon in t e metal.

Description

, Patented Nov. 27, 1923.
PATENT OFFICE.
PAUL KESTNEB, OF BOULOGNE-SUR-SEINE, FRANCE.
(No Drawing.
' To all whom it may concern:
Be it known that I PAUL Knsrnnn, engineer, citizen of the l rench'Republic, residing at Boulog'ne-sur-Seine, Department 6 of the Seine, in France, and having P. 0. address 113 Boulevard de Strasbourg, in the said city, have invented certain new and useful Improvements in Methods of Treating Water; and I do hereby declare the following to be a full, clear, and exact description of the invention, such as will enableothers skilled in the art to which it appertains to make and use they same.
This invention consists in improved metallic media for the fixation of the oxygen of water in apparatus for abstracting gases from li uids. g The xation of the oxygen dimolved in water is brought about in apparatus for ab- 2 stracting gases from liquids by the chemical combination of this oxygen with iron filings and turnings, and is represented by the to lowing chemical reactions:
2Fe+30=Fe,O,. This oxidation is not immediate but reand quires a certain time to give aquantitative res In. accordance with the invention a small un'rnon or rnmrme wn'rnn.
application lied April 16, 1921. Serial No. 461,925.
quantity of manganese is added to the iron.
he manganese acts as a catalyst in the oxidation and combines instantaneously with the oxygen, yielding oxide of iron and protoxide of manganese, MnO, capable of oxidizing in turn into dioxide and sesquioxide, which can be reduced again by the iron. The successive reactions which are brought about are as follows:
g fii fga 'iggb kxidatlon of the manganese.
Reduction of the oxidized man see and ggfgn gfi gfig o! the iron to the state iil protoxfllnor+3Fe=Fe o4+4Mno f g 'gfgggggma figfigg iiiiaoii 25%;: oxidized manganese lzpggiiagsglgpdgi the iron to the state In0+0-=)l.n0, )Oxidatlon oi the protcxide of manganese into 3MnQ+0-Mu;0 dloxnieand saline oxide.
All these reactions taking place in the water likewise take place between the same oxides in a hydrated state, and constitute a closed cycle, the protoxide of manganese absorbing oxygen continuously and giving it up to the iron until the iron is completely 65 saturated.
The proportion of manganese most favourable for'the catalysis is over 5% of the weight of the metal and below 6% of the weight of the iron. The speed of reaction [0 is proportional to the quantity of man, ganese employed and inversely proportional to the quantity of-carbon in t e metal.
Claim:
A method of treating water to de- (8 oxidize it, employing iron or steel filings or turning's containing from 5 to 6 per cent of manganese, the manganese acting as a catalyst'in the oxidationof the iron and increasing considerabl the speed of the reaction which takes p 00.
PAUL KESTNEB.
US461925A 1920-06-09 1921-04-16 Method of treating water Expired - Lifetime US1475396A (en)

Priority Applications (3)

Application Number Priority Date Filing Date Title
FR516710A FR516710A (en) 1920-06-09 1920-06-09 Special irons and steels for fixing oxygen in water in degassers
GB227521A GB164712A (en) 1920-06-09 1921-01-17
US461925A US1475396A (en) 1920-06-09 1921-04-16 Method of treating water

Applications Claiming Priority (2)

Application Number Priority Date Filing Date Title
FR516710T 1920-06-09
US461925A US1475396A (en) 1920-06-09 1921-04-16 Method of treating water

Publications (1)

Publication Number Publication Date
US1475396A true US1475396A (en) 1923-11-27

Family

ID=23834483

Family Applications (1)

Application Number Title Priority Date Filing Date
US461925A Expired - Lifetime US1475396A (en) 1920-06-09 1921-04-16 Method of treating water

Country Status (3)

Country Link
US (1) US1475396A (en)
FR (1) FR516710A (en)
GB (1) GB164712A (en)

Cited By (6)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US5811142A (en) * 1996-04-03 1998-09-22 Tenneo Packaging Modified atmosphere package for cut of raw meat
US5928560A (en) * 1996-08-08 1999-07-27 Tenneco Packaging Inc. Oxygen scavenger accelerator
US6054153A (en) * 1998-04-03 2000-04-25 Tenneco Packaging Inc. Modified atmosphere package with accelerated reduction of oxygen level in meat compartment
US6321509B1 (en) 1999-06-11 2001-11-27 Pactiv Corporation Method and apparatus for inserting an oxygen scavenger into a modified atmosphere package
US6395195B1 (en) 1996-08-08 2002-05-28 Pactiv Corporation Oxygen scavenger accelerator
US6926846B1 (en) 1996-08-08 2005-08-09 Pactiv Corporation Methods of using an oxygen scavenger

Cited By (14)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US5948457A (en) * 1996-04-03 1999-09-07 Tenneco Packaging Inc. Modified atmosphere package
US5811142A (en) * 1996-04-03 1998-09-22 Tenneo Packaging Modified atmosphere package for cut of raw meat
US6183790B1 (en) 1996-04-03 2001-02-06 Pactiv Corporation Modified atmosphere package
US6508955B1 (en) 1996-08-08 2003-01-21 Pactiv Corporation Oxygen scavenger accelerator
US5928560A (en) * 1996-08-08 1999-07-27 Tenneco Packaging Inc. Oxygen scavenger accelerator
US7147799B2 (en) 1996-08-08 2006-12-12 Pactiv Corporation Methods of using an oxygen scavenger
US6315921B1 (en) 1996-08-08 2001-11-13 Pactiv Corporation Oxygen scavenger accelerator
US6926846B1 (en) 1996-08-08 2005-08-09 Pactiv Corporation Methods of using an oxygen scavenger
US6395195B1 (en) 1996-08-08 2002-05-28 Pactiv Corporation Oxygen scavenger accelerator
US6666988B2 (en) 1996-08-08 2003-12-23 Pactiv Corporation Methods of using an oxygen scavenger
US6054153A (en) * 1998-04-03 2000-04-25 Tenneco Packaging Inc. Modified atmosphere package with accelerated reduction of oxygen level in meat compartment
US6132781A (en) * 1998-04-03 2000-10-17 Pactiv Corporation Modified atmosphere package with accelerated reduction of oxygen level in meat compartment
US6494023B2 (en) 1999-06-11 2002-12-17 Pactiv Corporation Apparatus for inserting an oxygen scavenger into a modified atmosphere package
US6321509B1 (en) 1999-06-11 2001-11-27 Pactiv Corporation Method and apparatus for inserting an oxygen scavenger into a modified atmosphere package

Also Published As

Publication number Publication date
GB164712A (en) 1922-04-13
FR516710A (en) 1921-04-25

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