US20030215609A1 - Damp-proofing with wind-proofing for buildings - Google Patents

Damp-proofing with wind-proofing for buildings Download PDF

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Publication number
US20030215609A1
US20030215609A1 US10/439,218 US43921803A US2003215609A1 US 20030215609 A1 US20030215609 A1 US 20030215609A1 US 43921803 A US43921803 A US 43921803A US 2003215609 A1 US2003215609 A1 US 2003215609A1
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Prior art keywords
moisture
vapour
film
barrier film
adaptive
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US10/439,218
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Candid Burkart
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    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08JWORKING-UP; GENERAL PROCESSES OF COMPOUNDING; AFTER-TREATMENT NOT COVERED BY SUBCLASSES C08B, C08C, C08F, C08G or C08H
    • C08J5/00Manufacture of articles or shaped materials containing macromolecular substances
    • C08J5/18Manufacture of films or sheets
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B32LAYERED PRODUCTS
    • B32BLAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
    • B32B27/00Layered products comprising a layer of synthetic resin
    • B32B27/06Layered products comprising a layer of synthetic resin as the main or only constituent of a layer, which is next to another layer of the same or of a different material
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08LCOMPOSITIONS OF MACROMOLECULAR COMPOUNDS
    • C08L23/00Compositions of homopolymers or copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond; Compositions of derivatives of such polymers
    • C08L23/02Compositions of homopolymers or copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond; Compositions of derivatives of such polymers not modified by chemical after-treatment
    • C08L23/04Homopolymers or copolymers of ethene
    • EFIXED CONSTRUCTIONS
    • E04BUILDING
    • E04DROOF COVERINGS; SKY-LIGHTS; GUTTERS; ROOF-WORKING TOOLS
    • E04D12/00Non-structural supports for roofing materials, e.g. battens, boards
    • E04D12/002Sheets of flexible material, e.g. roofing tile underlay
    • EFIXED CONSTRUCTIONS
    • E04BUILDING
    • E04DROOF COVERINGS; SKY-LIGHTS; GUTTERS; ROOF-WORKING TOOLS
    • E04D13/00Special arrangements or devices in connection with roof coverings; Protection against birds; Roof drainage; Sky-lights
    • E04D13/16Insulating devices or arrangements in so far as the roof covering is concerned, e.g. characterised by the material or composition of the roof insulating material or its integration in the roof structure
    • E04D13/1606Insulation of the roof covering characterised by its integration in the roof structure
    • E04D13/1612Insulation of the roof covering characterised by its integration in the roof structure the roof structure comprising a supporting framework of roof purlins or rafters
    • E04D13/1625Insulation of the roof covering characterised by its integration in the roof structure the roof structure comprising a supporting framework of roof purlins or rafters with means for supporting the insulating material between the purlins or rafters
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08JWORKING-UP; GENERAL PROCESSES OF COMPOUNDING; AFTER-TREATMENT NOT COVERED BY SUBCLASSES C08B, C08C, C08F, C08G or C08H
    • C08J2323/00Characterised by the use of homopolymers or copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond; Derivatives of such polymers
    • C08J2323/02Characterised by the use of homopolymers or copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond; Derivatives of such polymers not modified by chemical after treatment
    • C08J2323/04Homopolymers or copolymers of ethene
    • C08J2323/08Copolymers of ethene
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08LCOMPOSITIONS OF MACROMOLECULAR COMPOUNDS
    • C08L23/00Compositions of homopolymers or copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond; Compositions of derivatives of such polymers
    • C08L23/02Compositions of homopolymers or copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond; Compositions of derivatives of such polymers not modified by chemical after-treatment
    • C08L23/04Homopolymers or copolymers of ethene
    • C08L23/08Copolymers of ethene
    • C08L23/0846Copolymers of ethene with unsaturated hydrocarbons containing other atoms than carbon or hydrogen atoms
    • C08L23/0869Acids or derivatives thereof
    • EFIXED CONSTRUCTIONS
    • E04BUILDING
    • E04BGENERAL BUILDING CONSTRUCTIONS; WALLS, e.g. PARTITIONS; ROOFS; FLOORS; CEILINGS; INSULATION OR OTHER PROTECTION OF BUILDINGS
    • E04B1/00Constructions in general; Structures which are not restricted either to walls, e.g. partitions, or floors or ceilings or roofs
    • E04B1/62Insulation or other protection; Elements or use of specified material therefor
    • E04B1/625Sheets or foils allowing passage of water vapor but impervious to liquid water; house wraps
    • YGENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y10TECHNICAL SUBJECTS COVERED BY FORMER USPC
    • Y10TTECHNICAL SUBJECTS COVERED BY FORMER US CLASSIFICATION
    • Y10T428/00Stock material or miscellaneous articles
    • Y10T428/24Structurally defined web or sheet [e.g., overall dimension, etc.]
    • Y10T428/24355Continuous and nonuniform or irregular surface on layer or component [e.g., roofing, etc.]
    • YGENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y10TECHNICAL SUBJECTS COVERED BY FORMER USPC
    • Y10TTECHNICAL SUBJECTS COVERED BY FORMER US CLASSIFICATION
    • Y10T428/00Stock material or miscellaneous articles
    • Y10T428/24Structurally defined web or sheet [e.g., overall dimension, etc.]
    • Y10T428/24355Continuous and nonuniform or irregular surface on layer or component [e.g., roofing, etc.]
    • Y10T428/24364Continuous and nonuniform or irregular surface on layer or component [e.g., roofing, etc.] with transparent or protective coating

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  • Engineering & Computer Science (AREA)
  • Chemical & Material Sciences (AREA)
  • Architecture (AREA)
  • Medicinal Chemistry (AREA)
  • Health & Medical Sciences (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Polymers & Plastics (AREA)
  • Organic Chemistry (AREA)
  • Manufacturing & Machinery (AREA)
  • Civil Engineering (AREA)
  • Structural Engineering (AREA)
  • Materials Engineering (AREA)
  • Building Environments (AREA)
  • Outer Garments And Coats (AREA)

Abstract

A moisture-adaptive vapour-barrier film consisting of polyethylene and acrylic ester is proposed for the full insulation of buildings, which adapts its diffusion resistance to environmental conditions in such a way that it blocks its pores in the winter and opens its pores in the summer and the vapour-diffusion resistance of which can be changed and adjusted as a function of the proportion of the acrylic ester so as to correspond to a diffusion equivalence from 0.5 m to 100 m air-layer thickness.

Description

    FIELD OF THE INVENTION
  • The invention relates to the damp-proofing and wind-proofing of buildings with the aid of a plastic film which, particularly with a view to lasting protection of the wooden construction of the roofs and of the prefabricated construction consisting of porous building materials, serves to enhance the heat insulation and consequently to improve the thermal energy balance of buildings. [0001]
  • BACKGROUND OF THE INVENTION
  • Buildings are erected for the purpose of protecting the interior from wind and weather. For a long time the cubic volume delimited by the walls and the ceiling was regarded as the utility space of a building. The attic, by which is meant the space between the ceiling and the roof, was considered by the owner of a building as a necessary evil of protection against the weather, for—except for drying the laundry—abiding occupancy was prohibited on account of misgivings on the part of the fire-regulation authorities. Since around the time of the oil crisis of the seventies, a harmonisation of the economic and ecological interests of the individual with the community has come about in the building and construction industry thanks to technical feasibility. Evidence of this radical change are enclosed new buildings defying the wind and the weather and an increasing proportion of the old structural fabric which has been renovated in accordance with these features, in which utilisation of the reconstructed space is permitted in unrestricted manner. [0002]
  • From document DE 195 14 420 a “moisture-adaptive vapour barrier” is known which in the form of film preferably consists of [0003] polyamide 6 or 3, 4 and which together with the water-vapour diffusion resistance, which is dependent on the ambient humidity, also exhibits sufficient tensile strength and tearing strength. Because the film alters its physical properties in such a way, depending on moisture loading, that it acts as a vapour barrier against the penetration of moisture and, on the other hand, thanks to its adaptability in a cold climate, allows the constructional elements to dry out, it is also called a “climate membrane”.
  • As a matter of fact, the film changes its molecular structure in such a way that the constructional elements protected by it through the heating-period of the winter and also in the humidity of the summer can attain and retain the optimal dry condition. Hence the film prevents the penetration of moisture in the winter with the increase in its diffusion resistance, and in the summer it becomes vapour-permeable as a consequence of the increased humidity, so that the parts of a new building that are damp with trapped moisture and covered by the film are able to dry out ideally. [0004]
  • The disadvantage of the state of the art is that the use of the known film, particularly in connection with the full insulation of rafters in roofs, is criticised and, where possible, boycotted by manual workers. The reasons for this are: [0005]
  • 1. loud noises in the course of laying, [0006]
  • 2. low tearing strength, so that cracks arise in the course of laying which have to be repaired by bonding, [0007]
  • 3. deficient suppleness, which in the case of penetration by a pipe and with local complexity of trajectory is manifested by wrinkling and warping, [0008]
  • 4. only 2 m sheet width and roll width (cf. http://www.isover.ch/de/prod-vario.html), which, in connection with the speedy covering of relatively large areas, is restrictively narrow, [0009]
  • and, last but not least, [0010]
  • 5. according to the manufacturer's instructions it must not be stretched, not even in plane-parallel manner, but must be laid exclusively with sagging, e.g. in the case of an average rafter span with about 60 cm clearance, with sagging of about 3 cm (cf. http://www.isover.ch/de/prod-vario.html), since it otherwise tears. [0011]
  • For prefabricated construction the consequence of the disadvantage specified in [0012] point 5 is dramatic, for, on account of the sagging, the use of the vapour-barrier film pertaining to the state of the art on prefabricated panels is abandoned. This is because, for the handling and logistics of panels, the risk of an injury from sagging films is too extreme . . . .
  • It is here that the invention intends to provide a remedy. The invention as characterised in the Claims solves the task without the above disadvantages (1-5), in that a polymer of ethylene which is compounded with carboxyl-containing monomers is proposed and used. [0013]
  • The film having the protected trade name AIRPASS, which is manufactured by the applicant, stems from the group constituted by the thermoplastic copolymers of ethylene with carboxyl-containing monomers, in particular the ethylene/acrylic copolymers with acrylic acid. In the course of copolymerisation the linear structure of the methylene chain is interrupted, and hence the crystallinity is reduced in such a way that the melting-temperature is lowered. The crucial point is that, in comparison with the PA6 films pertaining to the state of the art, the AIRPASS film has a higher tensile strength, by which is meant the maximum tension that a film is able to tolerate before ultimate tearing, and has a clearly higher extension at rupture, i.e. the value by which the film is stretched until it tears, so that the AIRPASS film can be stretched substantially more until tearing than the PA6 film pertaining to the state of the art. By reason of the higher stretchability and the excellent stress-cracking resistance of the polyethylene copolymer, the AIRPASS film can be blow-extruded and in this connection can be stretched excellently when hot. In comparison with the PA6 films these properties are significant, for they signify a more rational production process, more generous product design (i.e. substantially larger sheet widths) and, not least, a proverbially higher flexibility for the consumer in the course of working. This is because the films pertaining to the state of the art (PA6) can only be produced with slit dies and, for this reason, only “statically” and only in limited width (2 m) which, in comparison with the sheet width of the “dynamic” blowing process of up to 4 m, is rather modest. The proposed AIRPASS film can be produced with higher productivity, and, because on account of its elastically supple behaviour it does not rustle or tear, it can also be laid out better. Laying is additionally favoured by the broader sheet width, because this substantially reduces the installation effort. Finally and lastly, the outstanding properties of permeability and the low transmission-rate of the gas permeability of the AIRPASS film should be mentioned. In this connection the permeability in respect of water vapour indicates how many grams of water a film lets through per day, relative to its area, and the transmission-rate indicates the gas permeability: what volume of gas the film of defined thickness, area and also ambient pressure lets through per day at zero per cent relative atmospheric humidity and temperatures. The AIRPASS film can be manufactured in thicknesses from 20 μm to [0014] 200 μm and, depending on the mixing-ratio of the components polyethylene and acrylic ester, its water-vapour diffusion resistance (sd value) may vary from 0.5 m to 100 m of diffusion-equivalent air-layer thickness. The AIRPASS film can be applied on the most diverse base materials, such as tiles, reinforced and unreinforced papers, fabrics consisting of metals and also domestic and industrial textile fibres, and can be coated over its full area or partially with coupling agents and adhesives. With the AIRPASS film it is possible for prefabricated panels consisting of porous building materials to be coated or covered without sag.
  • The AIRPASS film fulfils the valve function for buildings in ideal manner, inasmuch as it restricts the penetration of moisture from outside but permits the escape of moisture from inside.[0015]
  • BRIEF DESCRIPTION OF THE DRAWINGS
  • The use of the invention is shown below on the basis of embodiment variants by way of example as follows: [0016]
  • FIG. 1 the use of AIRPASS in the case of a gable roof with full insulation of intermediate rafters, [0017]
  • FIG. 2 section A-A through the roof of FIG. 1[0018]
  • DETAILED DESCRIPTION OF THE PREFERRED EMBODIMENT
  • FIGS. 1 and 2 show the typical structure of a gable roof in traditional timber construction, with collar-beam floor and with the supporting elements of the [0019] beams 12, rafters 6 (which are also called counterlaths), roof battens 5 and with the roof tiles 8 with pantiles resting on the roof battens 5.
  • Corresponding to section A-A (FIG. 2) and the state of the art, however, there is situated between the [0020] beams 12 and the rafters 6 a surface-covering layer 5 supported by the boarding 4 and consisting of water-repellent, diffusion-open material and the moisture-adaptive vapour-barrier film AIRPASS 1′, which at the same time envelops the surfaces of the roof beams 12, with the exception of their surfaces facing towards the inside, and in this way forms closed quadrangular spaces for acceptance of the insulating boards 2′ with the aid of the installation fillets 1′ (of FIG. 1). The great advantage of the AIRPASS film 1, 1′—that it may be installed without sagging, i.e. “tightly”—already becomes evident from FIG. 1, where its fastening and mounting with insulating strips 3′ on the beams 12 and on the installation laths 11 take place. For, in contrast with the state of the art, the AIRPASS film 1, 1′ may be laid tightly, i.e. without any sagging with the installation laths 11, so that it can fit snugly against the insulating mats 3 which are held by the boarding 4′ or by the layer of plaster. Corresponding to the arrangement shown, no interspaces are present for any sagging of the AIRPASS film, thus simplifying installation work.
  • Corresponding to the panels of prefabricated construction, the AIRPASS film with the layers of the [0021] insulating material 2 and the insulating mats 3 could be structured in the manner of a sandwich and, depending on requirements, could be laminated with further finishes, for example metallic lathing, to counter electrosmog.

Claims (10)

What is claimed:
1) A moisture-adaptive vapour-barrier film for full insulation of buildings, which adapts its diffusion resistance to environmental conditions in such a way that it blocks its pores in the winter and opens its pores in the summer, characterised in that it consists of a mixture of polyethylene and acrylic ester.
2) Moisture-adaptive vapour-barrier film according to claim 1, characterised in that the vapour-diffusion resistance of the film can be changed and adjusted as a function of the proportion of the acrylic ester in the polyethylene, corresponding to a diffusion equivalence from 0.5 m to 100 m air-layer thickness and a relative atmospheric humidity from 60% to 80%.
3) Moisture-adaptive vapour-barrier film according to claims 1 and 2, characterised in that the film has a thickness from 20 μm to 200 μm.
4) Moisture-adaptive vapour-barrier film according to claims 1 to 3, characterised in that the film is preferably used for the full insulation of the rafters of a roof.
5) Moisture-adaptive vapour-barrier film according to claims 1 to 3, characterised in that the film is used for the coating of building boards such as panels which consist of open-pore building materials.
6) Moisture-adaptive vapour-barrier film according to claims 1 to 3, characterised in that the film serves for the coating of insulating mats.
7) Moisture-adaptive vapour-barrier film according to claims 1 to 6, characterised in that the film forms a laminate with a base material consisting of paper.
8) Moisture-adaptive vapour-barrier film according to claims 1 to 5, characterised in that the film forms a laminate with a base material consisting of tiles.
9) Moisture-adaptive vapour-barrier film according to claims 1 to 8, characterised in that the film is manufactured from recycled material.
10) Moisture-adaptive vapour-barrier film according to claims 1 to 9, characterised in that the film is preferably manufactured by the extrusion blowing process.
US10/439,218 2002-05-14 2003-05-14 Damp-proofing with wind-proofing for buildings Abandoned US20030215609A1 (en)

Applications Claiming Priority (2)

Application Number Priority Date Filing Date Title
EP02076924A EP1362694B1 (en) 2002-05-14 2002-05-14 Windproof moisture barrier for buildings
EP02076924.6 2002-05-14

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EP (1) EP1362694B1 (en)
AT (1) ATE273793T1 (en)
DE (1) DE50200867D1 (en)

Cited By (18)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US20070094966A1 (en) * 2004-11-23 2007-05-03 Certainteed Corporation Insulation Batt Having Integral Baffle Vent
US20070193215A1 (en) * 2004-09-01 2007-08-23 Marcus Jablonka Multi-layered building wall
US20070283652A1 (en) * 2006-06-13 2007-12-13 John Chu Chen Variable vapor barrier for moisture control in buildings
US20080160280A1 (en) * 2006-12-29 2008-07-03 E. I. Du Pont De Nemours And Company Variable vapor barrier for humidity Control
US20090202852A1 (en) * 2008-02-11 2009-08-13 John Chu Chen Compositions and Structures Having Tailored Water Vapor Transmission
US20090301016A1 (en) * 2004-12-10 2009-12-10 Jorn Schroer Vapor barrier for use in buildings
US20100041290A1 (en) * 2008-08-15 2010-02-18 E. I. Du Pont De Nemours And Company Selectively permeable protective structure and methods for use
US20100107550A1 (en) * 2007-03-30 2010-05-06 Certainteed Corporation Attic and wall insulation with desiccant
US20100273380A1 (en) * 2009-04-23 2010-10-28 E.I. Du Pont De Nemours And Company Selectively permeable protective structure and articles therefrom
US20100273379A1 (en) * 2009-04-23 2010-10-28 E. I. Du Pont De Nemours And Company Selectively permeable protective structure and methods for use
US20120055110A1 (en) * 2009-03-28 2012-03-08 Ewald Doerken Ag Method for Producing a Functional Layer of a Building Shell, and Building Shell and Functional Layer
US20130244518A1 (en) * 2007-09-26 2013-09-19 Ewald Dorken Ag Film for construction and film combination
US9115498B2 (en) 2012-03-30 2015-08-25 Certainteed Corporation Roofing composite including dessicant and method of thermal energy management of a roof by reversible sorption and desorption of moisture
US9476204B2 (en) 2014-02-03 2016-10-25 Owens Corning Intellectual Capital, Llc Boxed netting insulation system for roof deck
US9920516B2 (en) 2014-02-03 2018-03-20 Owens Corning Intellectual Capital, Llc Roof insulation systems
US9926702B2 (en) 2014-02-03 2018-03-27 Owens Corning Intellectual Property, LLC Roof insulation systems
US10435550B2 (en) 2013-12-20 2019-10-08 Performance Materials Na, Inc. Variable vapor barrier for humidity control
US11708692B2 (en) 2018-12-27 2023-07-25 Gold Bond Building Products, Llc Cementitious panels with swellable materials and methods of providing a moisture or water barrier in cementitious panels using swellable materials

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DE102006047834A1 (en) * 2006-10-10 2008-04-17 Borgolte, Bernhard, Dipl.-Ing. Air-tight connection for wooden roofs, has retractable plastic channels of rafter-purlin-collar beam construction article, which are made of polyethylene and are provided with pressure sensitive adhesive strips
FR2921945A1 (en) * 2007-10-04 2009-04-10 Mireille Barthalais Roof panel for e.g. constructing individual home in mountain, has vapor barrier layer arranged between insulating material and ceiling plate and covering lateral walls of caisson, and phonic/thermal insulating layer arranged against walls
FR2966179A1 (en) * 2010-10-19 2012-04-20 Saint Gobain Isover USE OF A MEMBRANE AND MEMBRANE
DE202012013028U1 (en) * 2012-11-05 2014-09-08 Werner Wille Device for producing a ventilated roof

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Cited By (30)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US20070193215A1 (en) * 2004-09-01 2007-08-23 Marcus Jablonka Multi-layered building wall
US8365486B2 (en) * 2004-09-01 2013-02-05 Ewald Dorken Ag Multi-layered building wall
US20070094966A1 (en) * 2004-11-23 2007-05-03 Certainteed Corporation Insulation Batt Having Integral Baffle Vent
US20090301016A1 (en) * 2004-12-10 2009-12-10 Jorn Schroer Vapor barrier for use in buildings
WO2007146391A3 (en) * 2006-06-13 2008-04-10 Du Pont Variable vapor barrier for moisture control in buildings
US20070283652A1 (en) * 2006-06-13 2007-12-13 John Chu Chen Variable vapor barrier for moisture control in buildings
US7838123B2 (en) 2006-06-13 2010-11-23 E. I. Du Pont De Nemours And Company Variable vapor barrier for moisture control in buildings
US20080160280A1 (en) * 2006-12-29 2008-07-03 E. I. Du Pont De Nemours And Company Variable vapor barrier for humidity Control
US7838104B2 (en) 2006-12-29 2010-11-23 E. I. Du Pont De Nemours And Company Variable vapor barrier for humidity control
US20100107550A1 (en) * 2007-03-30 2010-05-06 Certainteed Corporation Attic and wall insulation with desiccant
US8820028B2 (en) * 2007-03-30 2014-09-02 Certainteed Corporation Attic and wall insulation with desiccant
US20130244518A1 (en) * 2007-09-26 2013-09-19 Ewald Dorken Ag Film for construction and film combination
US20090202852A1 (en) * 2008-02-11 2009-08-13 John Chu Chen Compositions and Structures Having Tailored Water Vapor Transmission
US8852749B2 (en) 2008-02-11 2014-10-07 E I Du Pont De Nemours And Company Compositions and structures having tailored water vapor transmission
US20100041290A1 (en) * 2008-08-15 2010-02-18 E. I. Du Pont De Nemours And Company Selectively permeable protective structure and methods for use
US8733054B2 (en) * 2009-03-28 2014-05-27 Ewald Doerken Ag Method for producing a functional layer of a building shell, and building shell and functional layer
US20120055110A1 (en) * 2009-03-28 2012-03-08 Ewald Doerken Ag Method for Producing a Functional Layer of a Building Shell, and Building Shell and Functional Layer
US8763338B2 (en) * 2009-03-28 2014-07-01 Ewald Dörken Ag Method for producing a functional layer of a building shell, and building shell and functional layer
US20100273380A1 (en) * 2009-04-23 2010-10-28 E.I. Du Pont De Nemours And Company Selectively permeable protective structure and articles therefrom
US20100273379A1 (en) * 2009-04-23 2010-10-28 E. I. Du Pont De Nemours And Company Selectively permeable protective structure and methods for use
US20100272898A1 (en) * 2009-04-23 2010-10-28 E. I. Du Pont De Nemours And Company Method for preparing a selectively permeable protective structure
US8420176B2 (en) 2009-04-23 2013-04-16 E I Du Pont De Nemours And Company Method for preparing a selectively permeable protective structure
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EP1362694B1 (en) 2004-08-18
EP1362694A1 (en) 2003-11-19
ATE273793T1 (en) 2004-09-15
DE50200867D1 (en) 2004-09-23

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