US20040177580A1 - Reinforced foam articles - Google Patents

Reinforced foam articles Download PDF

Info

Publication number
US20040177580A1
US20040177580A1 US10/385,070 US38507003A US2004177580A1 US 20040177580 A1 US20040177580 A1 US 20040177580A1 US 38507003 A US38507003 A US 38507003A US 2004177580 A1 US2004177580 A1 US 2004177580A1
Authority
US
United States
Prior art keywords
openwork
foam
reinforcing member
beads
foam beads
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Abandoned
Application number
US10/385,070
Inventor
Tim Tremelling
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
INNOVATIVE CONSTRUCTION TECHNOLOGIES Inc
Innovative Construction Tech Corp
Original Assignee
Innovative Construction Tech Corp
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Innovative Construction Tech Corp filed Critical Innovative Construction Tech Corp
Priority to US10/385,070 priority Critical patent/US20040177580A1/en
Assigned to INNOVATIVE CONSTRUCTION TECHNOLOGIES, INC. reassignment INNOVATIVE CONSTRUCTION TECHNOLOGIES, INC. ASSIGNMENT OF ASSIGNORS INTEREST (SEE DOCUMENT FOR DETAILS). Assignors: TREMELLING, TIM
Publication of US20040177580A1 publication Critical patent/US20040177580A1/en
Abandoned legal-status Critical Current

Links

Images

Classifications

    • EFIXED CONSTRUCTIONS
    • E04BUILDING
    • E04BGENERAL BUILDING CONSTRUCTIONS; WALLS, e.g. PARTITIONS; ROOFS; FLOORS; CEILINGS; INSULATION OR OTHER PROTECTION OF BUILDINGS
    • E04B2/00Walls, e.g. partitions, for buildings; Wall construction with regard to insulation; Connections specially adapted to walls
    • E04B2/84Walls made by casting, pouring, or tamping in situ
    • E04B2/86Walls made by casting, pouring, or tamping in situ made in permanent forms
    • E04B2/8611Walls made by casting, pouring, or tamping in situ made in permanent forms with spacers being embedded in at least one form leaf
    • E04B2/8617Walls made by casting, pouring, or tamping in situ made in permanent forms with spacers being embedded in at least one form leaf with spacers being embedded in both form leaves
    • EFIXED CONSTRUCTIONS
    • E04BUILDING
    • E04BGENERAL BUILDING CONSTRUCTIONS; WALLS, e.g. PARTITIONS; ROOFS; FLOORS; CEILINGS; INSULATION OR OTHER PROTECTION OF BUILDINGS
    • E04B2/00Walls, e.g. partitions, for buildings; Wall construction with regard to insulation; Connections specially adapted to walls
    • E04B2/84Walls made by casting, pouring, or tamping in situ
    • E04B2/86Walls made by casting, pouring, or tamping in situ made in permanent forms
    • E04B2/8635Walls made by casting, pouring, or tamping in situ made in permanent forms with ties attached to the inner faces of the forms
    • EFIXED CONSTRUCTIONS
    • E04BUILDING
    • E04CSTRUCTURAL ELEMENTS; BUILDING MATERIALS
    • E04C1/00Building elements of block or other shape for the construction of parts of buildings
    • E04C1/40Building elements of block or other shape for the construction of parts of buildings built-up from parts of different materials, e.g. composed of layers of different materials or stones with filling material or with insulating inserts
    • EFIXED CONSTRUCTIONS
    • E04BUILDING
    • E04BGENERAL BUILDING CONSTRUCTIONS; WALLS, e.g. PARTITIONS; ROOFS; FLOORS; CEILINGS; INSULATION OR OTHER PROTECTION OF BUILDINGS
    • E04B2/00Walls, e.g. partitions, for buildings; Wall construction with regard to insulation; Connections specially adapted to walls
    • E04B2/02Walls, e.g. partitions, for buildings; Wall construction with regard to insulation; Connections specially adapted to walls built-up from layers of building elements
    • E04B2002/0202Details of connections
    • E04B2002/0204Non-undercut connections, e.g. tongue and groove connections
    • E04B2002/0206Non-undercut connections, e.g. tongue and groove connections of rectangular shape
    • EFIXED CONSTRUCTIONS
    • E04BUILDING
    • E04BGENERAL BUILDING CONSTRUCTIONS; WALLS, e.g. PARTITIONS; ROOFS; FLOORS; CEILINGS; INSULATION OR OTHER PROTECTION OF BUILDINGS
    • E04B2/00Walls, e.g. partitions, for buildings; Wall construction with regard to insulation; Connections specially adapted to walls
    • E04B2/02Walls, e.g. partitions, for buildings; Wall construction with regard to insulation; Connections specially adapted to walls built-up from layers of building elements
    • E04B2002/0202Details of connections
    • E04B2002/0204Non-undercut connections, e.g. tongue and groove connections
    • E04B2002/0226Non-undercut connections, e.g. tongue and groove connections with tongues and grooves next to each other on the end surface

Definitions

  • the present invention pertains to reinforced foam articles and in particular to articles made with dry expandable flowable foam beads.
  • foam matrices formed from a so-called wet foaming process in which a liquid resin is flowed in place along with an expanding gas component or other blowing agent which reduces the density of the liquid resin to a desired level.
  • the blowing agent may be incorporated in the liquid resin composition or may be introduced as the liquid resin composition is injected into the mold.
  • the blowing agent may be liberated from solid or liquid components added to the liquid resin composition during mixing, or may comprise a gas, such as nitrogen or carbon dioxide, which is injected directly into the liquid resin composition.
  • One advantage of wet foaming processes is that the resin, being provided in a liquid form, has a prolonged wetting time in a liquid phase, and internal reinforcing components disposed within the core of the foamed articles are subjected to the expanding liquid resin over an extended time. This promotes intimate contact between the resin and the surfaces of the internal reinforcing members. During this time, the liquid resin conforms or flows around the outer surfaces of exposed internal reinforcing members. In addition to such conformance aspects, the liquid resin is allowed to form chemical attachments with surface features of the internal reinforcing members.
  • the internal reinforcing members are treated with a sizing or other external coatings which enhance the chemical bond with the foaming liquid resin.
  • a sizing or other external coatings which enhance the chemical bond with the foaming liquid resin.
  • the dry beads are blown into a mold cavity. Initially, the dry beads are freely movable to form a free-flowing packing arrangement within the mold cavity. The dry beads are then heated while under packing pressure and are allowed to expand within the mold cavity to achieve a desired density target value. During the heating and expansion phase, the outer surfaces of the dry beads are very briefly liquified to allow chemical bonding with adjacent beads so as to form a familiar three-dimensional unitary foam matrix.
  • the wetting time of the dry beads is very brief compared to that of liquid resin compositions which are expanded using flowing agents.
  • the wetting times of dry beads are typically on the order of 0.1-1% of the wetting times of liquid resin compositions.
  • substantial attachment forces between the dry, expandable, flowable beads are achieved using conventional molding processes which do not require extended wetting times. In many instances, it would be difficult, if not impossible, to substantially extend the very brief wetting phase of the dry expandable flowable foam beads if manufacturing advantages of conventional dry foam molding techniques are to be maintained.
  • foamed articles having improved burst strength and other high performance qualities are produced using dry, expandable, flowable foam beads which form little, or no chemical attachment to internal reinforcing members.
  • Improved internal support is provided by internal reinforcing members without appreciable pull out strength between the outer surfaces of the internal reinforcing members and the foam matrix within which the internal reinforcing members are embedded.
  • foamed articles, such as concrete forms are manufactured according to the present invention, two or three-dimensional arrays of internal reinforcing members greatly increase the burst strength of the form modules when subjected to hydrostatic loadings of wet poured concrete.
  • Another object of the present invention is to provide substantial internal reinforcement for such foamed articles.
  • a further object of the present invention is to provide molding techniques for such foamed articles which can be quickly carried out using inexpensive techniques.
  • a further object of the present invention is to provide foamed articles having improved internal reinforcement without requiring substantial pull out strength to be formed between internal reinforcing members and the foam matrix formed by dry expandable flowable foam beads.
  • a further object of the present invention is to provide foamed articles of the above type utilizing an internal reinforcing member in the form of an openwork such as mesh, screen or other interconnecting two-dimensional form. Pierced or perforated sheets can also be employed.
  • a freestanding form module for receiving flowable materials to make a wall which includes the form module, the flowable materials exerting a force in a selected direction
  • the form module comprising at least two spaced-apart form members having opposed interior form surfaces, each form member including a wall portion and a rib portion extending from the wall portion toward another one of said form members.
  • At least one monolithic molded plastic tie member having opposed ends with a web member between the ends extending along a web axis, a bearing member at each end of the tie member, extending generally transverse to the web axis and embedded in the wall portion of a respective form member with the form member formed around so as to captively enclose the bearing member and each end of the tie member having a stabilizing member extending generally transverse to the web axis, spaced from the bearing member and embedded in the rib portion of a respective form member adjacent the interior form surface thereof with the form member formed around so as to captively enclose the stabilizing member.
  • the improvement in said form members comprises a reinforced foamed article including a three-dimensional foam matrix core of expanded dry flowable foam beads; an internal reinforcing openwork reinforcing member disposed in the foam matrix and attached to the expanded beads of the foam matrix; a sizing between at least some of the foam beads and the openwork reinforcing member; and a majority of said openwork reinforcing member oriented in said foam matrix in a direction generally perpendicular to said preselected direction.
  • a method of producing a reinforced foamed article comprising the steps of providing dry expandable flowable foam beads; an openwork reinforcing member and a mold cavity. Placing the openwork reinforcing member in the mold cavity. Flowing the foam beads into the mold cavity and around the openwork reinforcing member. Heating the foam beads and the openwork reinforcing member within the mold cavity while allowing the foam beads to expand and fuse with one another to form a three-dimensional foam matrix with the openwork reinforcing member disposed therein.
  • FIG. 1 is a perspective view of a concrete form module according to principles of the present invention
  • FIG. 2 is a cross-sectional view taken along the line 2 - 2 of FIG. 7;
  • FIG. 3 is a first end view of the cross-section of FIG. 2;
  • FIG. 4 is a second end view of the cross-section of FIG. 2;
  • FIG. 5 is cross-sectional view taken along the line 5 - 5 of FIG. 2;
  • FIG. 6 is a cross-sectional view taken along the line 6 - 6 of FIG. 2;
  • FIG. 7 is a top plan view of the module of FIG. 1;
  • FIG. 8 is a schematic view of a test sample
  • FIG. 9 is a schematic view of another test sample
  • FIG. 10 is a perspective view of an internal tie member
  • FIG. 11 is an exploded perspective view of another tie member.
  • FIG. 1 is a perspective view of a self-supporting foam module for use as a concrete form.
  • Module 10 preferably includes alternating tongue and groove interlocking edges that allow multiple modules to be interlocked in a two-dimensional array to form a continuous wall.
  • module 10 includes a serial succession of substantially cylindrical cavities or cells 12 which receive a flowable casting material, such as concrete, and which distribute the concrete throughout the module during a pour, when concrete is typically introduced into the top of a wall formed by multiple modules 10 .
  • the preferred casting material i.e., concrete or the like cementious product exhibits fluidic behavior, producing hydrostatic pressure that acts laterally, in a horizontal direction as indicated by arrows 14 in FIGS. 5 and 7, pressing against the inner surfaces 16 of opposed, discrete wall members 20 .
  • Hydrostatic forces of the poured concrete act from within the modules 10 in a direction which causes internal bursting pressure, tending to force the walls 20 apart from one another. This direction of applied force extends along a Z-axis.
  • the outer surface 24 of wall 20 extends in a plane, along a vertical Y-axis and a horizontal X-axis.
  • an internal reinforcing mesh 30 has elements 32 extending in a Y-direction and elements 34 in an X-direction, forming an openwork arranged in the form of a rectilinear grid.
  • the internal bursting force caused by hydrostatic pressure of the poured concrete eventually dissipates as the concrete sets, becoming less fluid and eventually hardening into a solid form. It is generally preferred when pouring a wall that the concrete is poured at a relatively slow rate, allowing the bottommost portion of the concrete within the wall to begin to set, preventing a head pressure or internal bursting pressure acting over the full height of the wall.
  • the rate of set of the poured concrete must be carefully monitored, taking into account the weight and temperature of the concrete mix, the rate of placement of the concrete use of admixtures in the concrete being poured and the effect of vibration or other methods of consolidating the poured concrete material.
  • the walls 20 of module 10 are preferably molded using foam material characterized as dry expandable flowable beads, as are known in the art, as distinguished from wet foaming systems in which a liquid resin is expanded by a blowing agent.
  • the foam concrete form modules illustrated in the figure herein are preferably made of dry flowable expandable beads of styrene and polystyrene of sizes ranging between 0.40 mm and 1.10 mm, commercially available from Huntsman Chemical Corp. as Product No. 7454.
  • Examples of other dry beads suitable for use with this embodiment of the present invention include: BASF Series BF or BFL (i.e., BF 422) available from BASF Corporation of Mount Olive, N.J.; Samsung Series SF (i.e., SF 301) available from Samsung Cheil Industries of Seoul, South Korea; and Nova M Grade (i.e., M77b or 35mb) available from Nova Chemicals Corporation of Pittsburgh, Pennsylvania.
  • the module walls 20 have height and width dimensions (extending in the X and Y directions) of 12′′ and 48′′, respectively. Walls 20 have a thickness ranging between 21 ⁇ 2′′ and 4′′ with minimum and maximum dimensions occurring in the pattern shown in FIG. 5. As can be seen in FIGS.
  • the internal wall surfaces 16 are irregular, i.e., non-planar, while the outer surfaces 24 of the walls have a generally flat, planar appearance as can be seen for example in FIG. 1.
  • the opposed walls 20 are joined together at a fixed spacing by tie members 40 preferably made of a non-metallic molded plastic material such as an ABS compound commercially available from DOW Chemical Company under the trade designation Magnum 9555.
  • the plastic ties 40 are constructed according to commonly assigned U.S. Pat. No. 5,701,710.
  • An individual tie 40 is shown in FIG. 10 having major bearing plates 42 , 44 lying adjacent outer surfaces 24 of walls 20 and minor bearing plates 80 , 82 lying adjacent the inner surfaces 26 of walls 20 .
  • plastic ties 40 further include cross members 46 , 48 and 50 which extend between the major bearing plates.
  • modules 10 may also be constructed using multi-component tie members shown in FIG. 11 included is a central component 160 located between a pair of outer components 134 .
  • the central component 160 is slidingly engaged with outer components 134 being received in grooves 148 formed in inner wall members 144 .
  • Inner wall members 144 include linear bearing surfaces 146 which face toward an interconnecting webbing 150 and outer, major bearing plate portions 142 .
  • the plastic tie members of a module have bearing surfaces embedded within the foam matrix of the walls 20 so as to form a unified load-bearing system therewith.
  • the plastic tie members reinforce the foam matrix walls 20 particularly with regard to internal bursting pressures extending in the Z-direction indicated by arrow 14 of FIG. 5.
  • the beads are dry and flowable when introduced into a mold. After a sufficient quantity of dry beads are packed into the internal cavity of a mold, the beads are heated in situ within the mold cavity. The beads respond to heating by softening and expanding within the mold cavity, exerting pressure on neighboring beads. The beads throughout the mold cavity undergo substantially simultaneous expansion upon introduction of heat. During the expansion, the outer surfaces of the beads are softened or liquified, with adjacent beads becoming fused together under pressure of the bead expansion.
  • the so-called “wetting phase” of the dry beads which coincides with their expansion phase, takes place over a relatively short time, on the order of 45 to 60 seconds which is for polystyrene beads of 0.40 to 1.10 inch diameter, compared to approximately 100-1000 seconds for liquid resin compositions.
  • the present invention is directed to the use of dry expandable flowable beads, in conjunction with conventional molding methods and apparatus.
  • the critical interaction period i.e., the wetting/expanding/fusing phase
  • the critical interaction period for other molding techniques is considerably shorter than the critical interaction period for other molding techniques, such as those employing liquid resin compositions. Due to the substantial differences between these two disciplines (dry expandable flowable beads and liquid resin compositions) the techniques and apparatus associated with liquid resin molding compositions are not applicable to the use of dry expandable flowable beads in a conventional molding application. It is understood that the critical interaction period for both disciplines involve both polymer surface melt interactions on the one hand and true chemical bonding and cross linking on the other hand.
  • reinforcement is provided by openwork reinforcing members 30 , lying in an X-Y direction, i.e., parallel to the outer flat surfaces 24 of walls 20 (see FIG. 1).
  • the reinforcing members are seen on-edge in FIG. 5 positioned so as to lie adjacent to or more preferably against the outer surfaces of major bearing plates 44 .
  • the openwork reinforcing members 30 most preferably comprise a rectilinear mesh having members 32 extending in the Y-direction and members 34 extending in the X-direction, as can be seen in FIG. 1.
  • Examples of materials used for reinforcing member 30 include Total Wall HC/Type PM hard coat mesh available from Total Wall, Inc. of Madison, Wis.; Total Wall sm/type PB soft coat mesh available from Total Wall, Inc. of Madison, Wis.; GlasGrid 8501 mesh available from Saint-Gobain Technical Fabrics of Niagra Falls, N.Y.; and Styrotek Hard coat mesh available from Styrotek, Inc. of Delano, Calif.
  • Reinforcing members of the rectilinear mesh type are generally preferred due to their ready commercial availability. If desired, the rectilinear mesh could be aligned along a bias direction, i.e., at acute angles to the horizontal and vertical directions. Multiple openwork members could also be employed, whether side by side or overlying or not.
  • the reinforcing members could however be made of virtually any material including cloth, plastic or metal, and can also be made as a hybrid composition of cloth, metal or plastic materials, for example.
  • the materials could, for example, be provided as fibers which are wound together in a roving fashion to form the elements 32 , 34 .
  • the elements could be knotted together, welded or otherwise joined together to form an openwork. If desired, the members forming the openwork need not be joined together with welding, or adhesives, or the like but may instead be interlaced as with metal screen fabric construction for example.
  • the opening size of the openwork may be of any dimension desired, but is preferably large enough to allow a substantially free flow of dry molding beads to pass through the reinforcing member as the mold cavity is filled with molding beads.
  • the preferred openings of the openwork preferably vary between 0.4 mm and approximately 3 inches.
  • the elements making up the openwork may be of any cross-sectional size desired but are preferably sized in relation to the cross-sectional size of the dry expandable flowable foam beads with which they are to be enmeshed. It is preferred that the mesh elements defining the mesh openings range between 1 ⁇ 4 bead diameters and 2-bead diameters.
  • the dry foam beads are freely flowable when introduced into the mold cavity and only upon later application of heat are the beads, particularly the outer surfaces of the beads, softened during the wetting/expanding phase. During this phase, substantial inter-bead pressures and pressures of expansion are developed sufficient to cause individual beads to “wrap around” or otherwise conform to the outer surfaces of the openwork members.
  • the outer surfaces of the openwork members may be coated with an appropriate sizing as is known in the art to augment attaching forces between the foam beads and the openwork members.
  • an appropriate sizing will introduce surface structures on the openwork members which allow the foam beads an easier,purchase or chemical bonding grasp.
  • the sizing may be thought of as promoting clogging of the openwork openings preventing a flow of beads and bead clusters to pass through the openwork in a direction toward the outer surfaces 24 of the wall members 20 (see FIG. 1).
  • the openwork preferred in the present invention may be relied upon to prevent the outward travel of beads and bead clusters during a bursting event caused by excessive internal pressures within the cavities 12 extending in the direction of arrow 14 of FIG. 5.
  • the openwork may provide sufficient burst resistance without employing a sizing to augment bead adhesion to the openwork members. If inter-bead adhesion strength is sufficiently adequate, it is unlikely during a burst failure mode that bead clusters formed by internal breakage of walls 20 would be small enough to pass through the openwork openings of conventional openwork materials.
  • the openwork may be viewed as providing adequate retention or burst strength capability even in the absence of a sizing or other performance coating applied to the openwork members. It will be realized by those skilled in the art that openwork members constructed as a roving, that is as a twisted interlocking set of fibers or filaments will provide continuous inter-filament interstices which provide a form of mechanical “sizing” or enhancement for bead attachment.
  • openwork may be formed as a pierced sheet or as the combination of a structure netting overlain by a flexible sheet of plastic or other material, similar to the construction of commonly available snow fence. Virtually any type of openwork construction may be employed in carrying out the present invention.
  • the openwork be provided in a generally planar form oriented in an X-Y or vertical plane direction. This arises from the structural application of the illustrated embodiments in which concrete in a liquified phase is poured into mold structures in such a way as to exhibit a lateral or Z-axis burst force. It is generally desirable that the reinforcement provided by the present invention extend in directions generally parallel to the direction of tension of the molded articles and perpendicular to the direction of the force to be resisted.
  • the reinforcement or openwork of the present invention can be applied in variant directions having a small component in the Z-direction.
  • the openwork can be applied as a flexible fabric having undulating portions which extend out of, i.e., away from a vertical plane. While such angular variances can be tolerated in carrying out the present invention, excessive angular deviations of the reinforcing material will likely result in a substantial reduction in the bursting strength of walls 20 .
  • the application of a particularly aggressive sizing agent may be employed to mitigate strength reduction.
  • openwork employed in carrying out the present invention to form an internal integrated reinforcing matrix have several important characteristics or properties which provide optimal reinforcing enhancement to a (usually unreinforced) matrix of dry flowable expandable beads which are molded in a commercially advantageous known manner.
  • the present invention contemplates the use of dry flowable expandable beads of virtually any composition and size in commercial use today.
  • bead materials include styrene, polystyrene, propylene, and polypropylene having bead sizes ranging between 0.1 mm and 2 mm.
  • the present invention has found immediate commercial application in the field of concrete form modules made of dry flowable expandable beads of styrene and polystyrene of sizes ranging between 0.1 mm and 1.6 mm.
  • the dry flowable expandable beads contemplated by the present invention undergo molding by injection into a mold cavity with subsequent loading of the mold/cavity with a substantial quantity of beads, and subsequent exposure of the beads to an external heat source which causes the outer surfaces of the beads to become wetted while the beads expand to achieve a desired target foam density.
  • This critical period in the formation of the molded structure is referred to herein as the wetting/expansion phase in which the previously dry flowable beads are expanded and joined together to achieve an integral solidified mass of selected (final) foam density.
  • the openwork is disposed in the interior of the mold cavity at the time the dry flowable expandable beads are injected in the mold cavity, and at the onset of the wetting/expanding phase of the molding operation.
  • Identifying characteristics of the reinforced molded article include: compatible chemical compositions of dry beads and openwork; that the dry beads are of the flowable expandable type so as to be free flowing to achieve desired packing or density throughout the mold cavity; a cross-sectional size of the openwork and the ratio of the cross-sectional size of the openwork to the length of the openwork elements forming the openwork openings; optionally sizing or the like surface treatment on the openwork to promote enhanced attachment to the expanding beads; folding or other compressed multiple layers of the openwork is generally not preferred; a proportion of openwork to foam beads of approximately 1% by mass; and an orientation of at least 5% of the openwork within the foam core in a direction parallel to the direction of tension and perpendicular to the direction of stress imparted to the molded article.
  • the openwork reinforcement of the present invention is employed in a commercially significant load bearing structure which employs a spaced apart series of plastic tie members 40 . Due to the configuration of cavities 12 within module 10 it was found desirable to provide added reinforcements adjacent the cavities, i.e., between the tie members 40 . If desired, the openwork reinforcement of the present invention could be employed at virtually any point within the foam matrix of walls 20 . For example, the openwork could be employed at points between the major and minor bearing plates 44 , 82 of tie members 40 .
  • the openwork of the present invention is employed in the form of a flexible fabric.
  • a pressure sensitive adhesive was employed to attach the openwork to the exposed outer surfaces of the major bearing plates and to allow the adhesive opportunity to fully cure before subjecting the openwork to the molding pressures of the expanding foam matrix. With the foam matrix fully cured, internal bursting forces applied from within cavities 12 will be transmitted by the openwork reinforcement to the major bearing plates of the tie members.
  • Examples of the present invention have been set forth with regard to a particular type of a commercially significant structure, that of a concrete form module.
  • the present invention is however not so limited and can be employed with virtually any decorative or structural member made from dry expandable foamable beads, including molded packaging materials.
  • the openwork reinforcement afforded by the present invention may be used with or without other internal reinforcing systems, such as the plastic ties of the preferred embodiment.
  • the openwork reinforcement be embedded within a foam matrix wall adjacent that surface of the wall located opposite the location of applied force.
  • the applied force is that of an outwardly directed bursting force imparted by a force system (i.e., the hydrostatic forces of poured concrete) located within a foam matrix structure.
  • a force system i.e., the hydrostatic forces of poured concrete
  • the openwork reinforcement be located adjacent the outer wall of the foam matrix structure, remote from the application site of the force to be resisted.
  • a generalized foam matrix structure is indicated at 200 .
  • Reinforcement of a wall surface portion 206 was studied.
  • the assumed direction of force to be resisted is indicated by arrow 208 and is applied to a wall portion having a total thickness Q .
  • the openwork reinforcement according to principles of the present invention is introduced at a distance P from the opposed surface 212 of structure 200 .
  • Openwork reinforcement 210 is embedded within the foam matrix core of structure 200 either with or without benefit of chemical sizing or other mechanical structural features to promote adhesion of the foam beads to the members comprising the openwork.
  • Outward bulging or dislocation of the openwork is resisted by the thickness portion of the foam matrix core indicated by the dimension P .
  • the ratio P/Q range between 0.28 and 0.5. Smaller ratios would indicate a reduced foam matrix layer to support the openwork against outward bulging.
  • an outward bulging or distortion of the foam matrix may not be desirable from an appearance standpoint.
  • the openwork 24 is located closer to the outer surface 24 of the foam matrix than would otherwise be preferred.
  • the openwork was determined to be located at a position P/Q ranging between 0.210 and 0.30.
  • the reduced value of P/Q i.e., the reduced foam matrix thickness between the openwork and the adjacent outer surface 24 of wall 20 is offset by cooperation between reinforcement of the present invention and the internal construction of module 10 .
  • Of particular interest here is the relatively close spacing of the major bearing plates 44 of ties 40 . With appropriate adhesive securement between the openwork and the major bearing plates as indicated above the outward bulging of openwork 30 under applied force is sufficiently reduced so as to allow reduced P/Q values of approximately 0.21.

Abstract

Reinforcement is provided for foam articles made from dry flowable expanding beads. The reinforcement includes a net work of elements, preferably woven or roving type. The net work is positioned within the foam matrix at a location remote from an applied force so as to impart increased bursting strength to the foam matrix.

Description

    BACKGROUND OF THE INVENTION
  • 1. Field of the Invention [0001]
  • The present invention pertains to reinforced foam articles and in particular to articles made with dry expandable flowable foam beads. [0002]
  • 2. Description of the Related Art [0003]
  • Ongoing efforts have been made to develop three-dimensional foam members for use in structural, i.e., load-bearing, applications. In the aircraft industry, for example, laminate structures have been proposed which include foam matrices formed from a so-called wet foaming process in which a liquid resin is flowed in place along with an expanding gas component or other blowing agent which reduces the density of the liquid resin to a desired level. The blowing agent may be incorporated in the liquid resin composition or may be introduced as the liquid resin composition is injected into the mold. The blowing agent may be liberated from solid or liquid components added to the liquid resin composition during mixing, or may comprise a gas, such as nitrogen or carbon dioxide, which is injected directly into the liquid resin composition. [0004]
  • One advantage of wet foaming processes is that the resin, being provided in a liquid form, has a prolonged wetting time in a liquid phase, and internal reinforcing components disposed within the core of the foamed articles are subjected to the expanding liquid resin over an extended time. This promotes intimate contact between the resin and the surfaces of the internal reinforcing members. During this time, the liquid resin conforms or flows around the outer surfaces of exposed internal reinforcing members. In addition to such conformance aspects, the liquid resin is allowed to form chemical attachments with surface features of the internal reinforcing members. [0005]
  • Often, the internal reinforcing members are treated with a sizing or other external coatings which enhance the chemical bond with the foaming liquid resin. As the prolonged wetting phase draws to an end, chemical interaction between the expanded resin and the outer surfaces of the internal reinforcing members is substantially completed achieving most, if not all of the resulting pull out strength present within the core of the resulting foamed article. [0006]
  • One example of a wet foaming process is given in U.S. Pat. No. 4,073,840 where discrete reinforcing fiber filaments are homogeneously dispersed in a liquid foamable resin composition prior to foaming of the composition, to form a fiber slurry. The fibers are typically provided in a bundle form and upon mixing in the foamable resin, the fiber bundles are separated and are wetted with the resin to form a wet foamable resin composition which is then fed into a mold apparatus where the foamable resin composition is allowed to foam to achieve its final density. Thermoset resin compositions such as foamable polyurethane resin compositions are preferred. As may be required for a particular process, catalysts, surfactants, foam stabilizers and curing agents are added to the foamable resin composition during mixing, prior to injection in the mold. [0007]
  • Despite advances in the art of producing foamed articles, further refinements are sought to allow the use of different foaming processes to produce foam articles having a self-supporting reinforced core, whose reinforcing properties are continuous throughout the body of the foamed article. [0008]
  • SUMMARY OF THE INVENTION
  • A wide variety of structural foamed articles are produced today using so-called “dry” bead processes. Examples of such articles are found in commonly assigned U.S. Pat. Nos. 5,701,710 and 5,809,728. The self-supporting concrete form modules provided by these patents have met with widespread commercial acceptance. The modules incorporate internal, plastic tie structures having bearing surfaces embedded within the opposed walls of the resulting concrete form modules. While the concrete form modules produced according to these patents may employ liquid resin compositions, it has been found commercially advantageous to form such modules commercially available using dry expandable flowable foam beads. [0009]
  • Typically, the dry beads are blown into a mold cavity. Initially, the dry beads are freely movable to form a free-flowing packing arrangement within the mold cavity. The dry beads are then heated while under packing pressure and are allowed to expand within the mold cavity to achieve a desired density target value. During the heating and expansion phase, the outer surfaces of the dry beads are very briefly liquified to allow chemical bonding with adjacent beads so as to form a familiar three-dimensional unitary foam matrix. The wetting time of the dry beads is very brief compared to that of liquid resin compositions which are expanded using flowing agents. The wetting times of dry beads are typically on the order of 0.1-1% of the wetting times of liquid resin compositions. As a result, if significant pull out strength is to be attained with reinforcing members disposed within the foam matrix, attachments must be initiated and completed very quickly, as the expanding beads are wrapped about or otherwise conform to the outer surfaces of the internal reinforcing members. [0010]
  • According to one aspect of the present invention, substantial attachment forces between the dry, expandable, flowable beads are achieved using conventional molding processes which do not require extended wetting times. In many instances, it would be difficult, if not impossible, to substantially extend the very brief wetting phase of the dry expandable flowable foam beads if manufacturing advantages of conventional dry foam molding techniques are to be maintained. [0011]
  • In other aspects of the present invention, foamed articles having improved burst strength and other high performance qualities are produced using dry, expandable, flowable foam beads which form little, or no chemical attachment to internal reinforcing members. Improved internal support is provided by internal reinforcing members without appreciable pull out strength between the outer surfaces of the internal reinforcing members and the foam matrix within which the internal reinforcing members are embedded. For example, when foamed articles, such as concrete forms, are manufactured according to the present invention, two or three-dimensional arrays of internal reinforcing members greatly increase the burst strength of the form modules when subjected to hydrostatic loadings of wet poured concrete. [0012]
  • While the present invention has found immediate acceptance in the field of self-supporting concrete form modules, virtually any useful structural foamed article will benefit from the present invention to achieve reinforcement without substantial additional costs to provide molded structural articles of commercial significance. Because existing dry bead foaming processes can be carried out according to principles of the present invention without substantial modification, reinforcement of existing foamed articles can be enjoyed without requiring the manufacturer to incur prolonged development times, and improved reinforced foamed articles can be quickly brought to the marketplace. [0013]
  • It is an object of the present invention to provide foamed articles utilizing dry expandable flowable foam beads. [0014]
  • Another object of the present invention is to provide substantial internal reinforcement for such foamed articles. [0015]
  • A further object of the present invention is to provide molding techniques for such foamed articles which can be quickly carried out using inexpensive techniques. [0016]
  • A further object of the present invention is to provide foamed articles having improved internal reinforcement without requiring substantial pull out strength to be formed between internal reinforcing members and the foam matrix formed by dry expandable flowable foam beads. [0017]
  • A further object of the present invention is to provide foamed articles of the above type utilizing an internal reinforcing member in the form of an openwork such as mesh, screen or other interconnecting two-dimensional form. Pierced or perforated sheets can also be employed. [0018]
  • These and other objects according to principles of the present invention are provided in a freestanding form module for receiving flowable materials to make a wall which includes the form module, the flowable materials exerting a force in a selected direction, the form module comprising at least two spaced-apart form members having opposed interior form surfaces, each form member including a wall portion and a rib portion extending from the wall portion toward another one of said form members. At least one monolithic molded plastic tie member having opposed ends with a web member between the ends extending along a web axis, a bearing member at each end of the tie member, extending generally transverse to the web axis and embedded in the wall portion of a respective form member with the form member formed around so as to captively enclose the bearing member and each end of the tie member having a stabilizing member extending generally transverse to the web axis, spaced from the bearing member and embedded in the rib portion of a respective form member adjacent the interior form surface thereof with the form member formed around so as to captively enclose the stabilizing member. The improvement in said form members comprises a reinforced foamed article including a three-dimensional foam matrix core of expanded dry flowable foam beads; an internal reinforcing openwork reinforcing member disposed in the foam matrix and attached to the expanded beads of the foam matrix; a sizing between at least some of the foam beads and the openwork reinforcing member; and a majority of said openwork reinforcing member oriented in said foam matrix in a direction generally perpendicular to said preselected direction. [0019]
  • Other aspects of the present invention, and attendant advantages are provided in a method of producing a reinforced foamed article comprising the steps of providing dry expandable flowable foam beads; an openwork reinforcing member and a mold cavity. Placing the openwork reinforcing member in the mold cavity. Flowing the foam beads into the mold cavity and around the openwork reinforcing member. Heating the foam beads and the openwork reinforcing member within the mold cavity while allowing the foam beads to expand and fuse with one another to form a three-dimensional foam matrix with the openwork reinforcing member disposed therein. [0020]
  • Aspects of the present invention are described with regard to a particular example of a commercially significant concrete form module. The present invention is however not limited and can be employed with virtually any decorative or structural member made from dry expandable foamable beads. Further, the reinforcement matrix afforded by the present invention may be used with or without other reinforcing systems, such as the plastic ties of the preferred embodiment. [0021]
  • BRIEF DESCRIPTION OF THE DRAWINGS
  • FIG. 1 is a perspective view of a concrete form module according to principles of the present invention; [0022]
  • FIG. 2 is a cross-sectional view taken along the line [0023] 2-2 of FIG. 7;
  • FIG. 3 is a first end view of the cross-section of FIG. 2; [0024]
  • FIG. 4 is a second end view of the cross-section of FIG. 2; [0025]
  • FIG. 5 is cross-sectional view taken along the line [0026] 5-5 of FIG. 2;
  • FIG. 6 is a cross-sectional view taken along the line [0027] 6-6 of FIG. 2;
  • FIG. 7 is a top plan view of the module of FIG. 1; [0028]
  • FIG. 8 is a schematic view of a test sample; [0029]
  • FIG. 9 is a schematic view of another test sample; [0030]
  • FIG. 10 is a perspective view of an internal tie member; and [0031]
  • FIG. 11 is an exploded perspective view of another tie member.[0032]
  • DETAILED DESCRIPTION OF THE PREFERRED EMBODIMENTS
  • As will be seen herein, the present invention may be employed to produce foam articles both decorative and structural of virtually any shape and size desired. The present invention has however found immediate commercial application in producing foam concrete forms of the type described in commonly assigned U.S. Pat. Nos. 5,701,710 and 5,809,728 the disclosures of which are incorporated as if fully set forth herein. Turning now to the drawings, FIG. 1 is a perspective view of a self-supporting foam module for use as a concrete form. [0033] Module 10 preferably includes alternating tongue and groove interlocking edges that allow multiple modules to be interlocked in a two-dimensional array to form a continuous wall. As can be seen in the top plan view of FIG. 7, module 10 includes a serial succession of substantially cylindrical cavities or cells 12 which receive a flowable casting material, such as concrete, and which distribute the concrete throughout the module during a pour, when concrete is typically introduced into the top of a wall formed by multiple modules 10.
  • During initial stages of the pour, the preferred casting material, i.e., concrete or the like cementious product exhibits fluidic behavior, producing hydrostatic pressure that acts laterally, in a horizontal direction as indicated by [0034] arrows 14 in FIGS. 5 and 7, pressing against the inner surfaces 16 of opposed, discrete wall members 20. Hydrostatic forces of the poured concrete act from within the modules 10 in a direction which causes internal bursting pressure, tending to force the walls 20 apart from one another. This direction of applied force extends along a Z-axis. Referring to FIG. 1, the outer surface 24 of wall 20 extends in a plane, along a vertical Y-axis and a horizontal X-axis. As shown in FIG. 1, an internal reinforcing mesh 30 has elements 32 extending in a Y-direction and elements 34 in an X-direction, forming an openwork arranged in the form of a rectilinear grid.
  • The internal bursting force caused by hydrostatic pressure of the poured concrete eventually dissipates as the concrete sets, becoming less fluid and eventually hardening into a solid form. It is generally preferred when pouring a wall that the concrete is poured at a relatively slow rate, allowing the bottommost portion of the concrete within the wall to begin to set, preventing a head pressure or internal bursting pressure acting over the full height of the wall. In practice, the rate of set of the poured concrete must be carefully monitored, taking into account the weight and temperature of the concrete mix, the rate of placement of the concrete use of admixtures in the concrete being poured and the effect of vibration or other methods of consolidating the poured concrete material. [0035]
  • The [0036] walls 20 of module 10 are preferably molded using foam material characterized as dry expandable flowable beads, as are known in the art, as distinguished from wet foaming systems in which a liquid resin is expanded by a blowing agent. The foam concrete form modules illustrated in the figure herein are preferably made of dry flowable expandable beads of styrene and polystyrene of sizes ranging between 0.40 mm and 1.10 mm, commercially available from Huntsman Chemical Corp. as Product No. 7454. Examples of other dry beads suitable for use with this embodiment of the present invention include: BASF Series BF or BFL (i.e., BF 422) available from BASF Corporation of Mount Olive, N.J.; Samsung Series SF (i.e., SF 301) available from Samsung Cheil Industries of Seoul, South Korea; and Nova M Grade (i.e., M77b or 35mb) available from Nova Chemicals Corporation of Pittsburgh, Pennsylvania. The module walls 20 have height and width dimensions (extending in the X and Y directions) of 12″ and 48″, respectively. Walls 20 have a thickness ranging between 2½″ and 4″ with minimum and maximum dimensions occurring in the pattern shown in FIG. 5. As can be seen in FIGS. 5 and 6 , the internal wall surfaces 16 are irregular, i.e., non-planar, while the outer surfaces 24 of the walls have a generally flat, planar appearance as can be seen for example in FIG. 1. Referring to FIGS. 5 and 6, the opposed walls 20 are joined together at a fixed spacing by tie members 40 preferably made of a non-metallic molded plastic material such as an ABS compound commercially available from DOW Chemical Company under the trade designation Magnum 9555. The plastic ties 40 are constructed according to commonly assigned U.S. Pat. No. 5,701,710. An individual tie 40 is shown in FIG. 10 having major bearing plates 42, 44 lying adjacent outer surfaces 24 of walls 20 and minor bearing plates 80, 82 lying adjacent the inner surfaces 26 of walls 20. Referring to FIG. 6, plastic ties 40 further include cross members 46, 48 and 50 which extend between the major bearing plates.
  • Referring to FIGS. 1 and 11, [0037] modules 10 may also be constructed using multi-component tie members shown in FIG. 11 included is a central component 160 located between a pair of outer components 134. The central component 160 is slidingly engaged with outer components 134 being received in grooves 148 formed in inner wall members 144. Inner wall members 144 include linear bearing surfaces 146 which face toward an interconnecting webbing 150 and outer, major bearing plate portions 142. Whether constructed in the unitary fashion as shown in FIG. 10 or in an interlocking multi-component fashion as illustrated in FIG. 11, the plastic tie members of a module have bearing surfaces embedded within the foam matrix of the walls 20 so as to form a unified load-bearing system therewith. The plastic tie members reinforce the foam matrix walls 20 particularly with regard to internal bursting pressures extending in the Z-direction indicated by arrow 14 of FIG. 5.
  • In the dry bead technology of the present invention, the beads are dry and flowable when introduced into a mold. After a sufficient quantity of dry beads are packed into the internal cavity of a mold, the beads are heated in situ within the mold cavity. The beads respond to heating by softening and expanding within the mold cavity, exerting pressure on neighboring beads. The beads throughout the mold cavity undergo substantially simultaneous expansion upon introduction of heat. During the expansion, the outer surfaces of the beads are softened or liquified, with adjacent beads becoming fused together under pressure of the bead expansion. The so-called “wetting phase” of the dry beads, which coincides with their expansion phase, takes place over a relatively short time, on the order of 45 to 60 seconds which is for polystyrene beads of 0.40 to 1.10 inch diameter, compared to approximately 100-1000 seconds for liquid resin compositions. [0038]
  • As mentioned above, the present invention is directed to the use of dry expandable flowable beads, in conjunction with conventional molding methods and apparatus. As emphasized above, the critical interaction period (i.e., the wetting/expanding/fusing phase) for the dry expandable flowable beads is considerably shorter than the critical interaction period for other molding techniques, such as those employing liquid resin compositions. Due to the substantial differences between these two disciplines (dry expandable flowable beads and liquid resin compositions) the techniques and apparatus associated with liquid resin molding compositions are not applicable to the use of dry expandable flowable beads in a conventional molding application. It is understood that the critical interaction period for both disciplines involve both polymer surface melt interactions on the one hand and true chemical bonding and cross linking on the other hand. However, it is important to realize that these two factors are not equally important to the two disciplines. With the molding discipline employing dry expandable flowable beads, polymer surface melt interactions which lead to good melt adhesion is the predominate factor promoted, while other factors such as true chemical bonding between the beads and other components of the mold composition are of far less importance. The successful molding compositions using dry expandable flowable beads focus on polymer surface melt interactions leading to good melt adhesion and this would not be compromised in an effort to promote true chemical bonding which is relatively unimportant to the success of the mold process. On the other hand, the molding of liquid resin compositions relies predominately on true chemical bonding, such as covalent bonding and cross linking. While polymer surface melt interactions may be present in the molding of liquid resin compositions, this factor is relatively unimportant and is not generally promoted at the risk of sacrificing the true chemical bonding which is of predominate importance for the molding of liquid resin compositions. [0039]
  • Despite the immediate commercial acceptance of concrete form modules constructed according to commonly assigned U.S. Pat. Nos. 5,701,710 and 5,809,728, further advances were sought with regard to strengthening the [0040] walls 20. In particular, reinforcement was desired to provide added resistance to the internal bursting pressure operating in the Z-direction indicated by arrow 14 in FIG. 5. As can be seen in FIG. 5, the plastic ties 40 provide a series of spaced apart reinforcements disposed between the cavities 12 which, due to their generally concave shape give rise to points of minimal wall thickness. It was desired to add reinforcement, particularly reinforcement against bursting pressures at the points of minimal wall thickness. As mentioned above, reinforcement is provided by openwork reinforcing members 30, lying in an X-Y direction, i.e., parallel to the outer flat surfaces 24 of walls 20 (see FIG. 1). The reinforcing members are seen on-edge in FIG. 5 positioned so as to lie adjacent to or more preferably against the outer surfaces of major bearing plates 44.
  • The [0041] openwork reinforcing members 30 most preferably comprise a rectilinear mesh having members 32 extending in the Y-direction and members 34 extending in the X-direction, as can be seen in FIG. 1. Examples of materials used for reinforcing member 30 include Total Wall HC/Type PM hard coat mesh available from Total Wall, Inc. of Madison, Wis.; Total Wall sm/type PB soft coat mesh available from Total Wall, Inc. of Madison, Wis.; GlasGrid 8501 mesh available from Saint-Gobain Technical Fabrics of Niagra Falls, N.Y.; and Styrotek Hard coat mesh available from Styrotek, Inc. of Delano, Calif.
  • Reinforcing members of the rectilinear mesh type are generally preferred due to their ready commercial availability. If desired, the rectilinear mesh could be aligned along a bias direction, i.e., at acute angles to the horizontal and vertical directions. Multiple openwork members could also be employed, whether side by side or overlying or not. [0042]
  • The reinforcing members could however be made of virtually any material including cloth, plastic or metal, and can also be made as a hybrid composition of cloth, metal or plastic materials, for example. The materials could, for example, be provided as fibers which are wound together in a roving fashion to form the [0043] elements 32, 34. The elements could be knotted together, welded or otherwise joined together to form an openwork. If desired, the members forming the openwork need not be joined together with welding, or adhesives, or the like but may instead be interlaced as with metal screen fabric construction for example.
  • The opening size of the openwork may be of any dimension desired, but is preferably large enough to allow a substantially free flow of dry molding beads to pass through the reinforcing member as the mold cavity is filled with molding beads. The preferred openings of the openwork preferably vary between 0.4 mm and approximately 3 inches. [0044]
  • The elements making up the openwork may be of any cross-sectional size desired but are preferably sized in relation to the cross-sectional size of the dry expandable flowable foam beads with which they are to be enmeshed. It is preferred that the mesh elements defining the mesh openings range between ¼ bead diameters and 2-bead diameters. As mentioned, the dry foam beads are freely flowable when introduced into the mold cavity and only upon later application of heat are the beads, particularly the outer surfaces of the beads, softened during the wetting/expanding phase. During this phase, substantial inter-bead pressures and pressures of expansion are developed sufficient to cause individual beads to “wrap around” or otherwise conform to the outer surfaces of the openwork members. [0045]
  • If desired, the outer surfaces of the openwork members may be coated with an appropriate sizing as is known in the art to augment attaching forces between the foam beads and the openwork members. [0046]
  • Typically, an appropriate sizing will introduce surface structures on the openwork members which allow the foam beads an easier,purchase or chemical bonding grasp. Upon an extreme bursting failure of [0047] module 10, the sizing may be thought of as promoting clogging of the openwork openings preventing a flow of beads and bead clusters to pass through the openwork in a direction toward the outer surfaces 24 of the wall members 20 (see FIG. 1).
  • The openwork preferred in the present invention may be relied upon to prevent the outward travel of beads and bead clusters during a bursting event caused by excessive internal pressures within the [0048] cavities 12 extending in the direction of arrow 14 of FIG. 5. In certain instances, depending primarily upon the mesh opening and the adhesion strength of bead clusters, the openwork may provide sufficient burst resistance without employing a sizing to augment bead adhesion to the openwork members. If inter-bead adhesion strength is sufficiently adequate, it is unlikely during a burst failure mode that bead clusters formed by internal breakage of walls 20 would be small enough to pass through the openwork openings of conventional openwork materials. Accordingly, the openwork may be viewed as providing adequate retention or burst strength capability even in the absence of a sizing or other performance coating applied to the openwork members. It will be realized by those skilled in the art that openwork members constructed as a roving, that is as a twisted interlocking set of fibers or filaments will provide continuous inter-filament interstices which provide a form of mechanical “sizing” or enhancement for bead attachment.
  • Several different types of openwork have been given above. In addition to these, the openwork may be formed as a pierced sheet or as the combination of a structure netting overlain by a flexible sheet of plastic or other material, similar to the construction of commonly available snow fence. Virtually any type of openwork construction may be employed in carrying out the present invention. [0049]
  • As mentioned, it is preferred that the openwork be provided in a generally planar form oriented in an X-Y or vertical plane direction. This arises from the structural application of the illustrated embodiments in which concrete in a liquified phase is poured into mold structures in such a way as to exhibit a lateral or Z-axis burst force. It is generally desirable that the reinforcement provided by the present invention extend in directions generally parallel to the direction of tension of the molded articles and perpendicular to the direction of the force to be resisted. [0050]
  • If desired, the reinforcement or openwork of the present invention can be applied in variant directions having a small component in the Z-direction. For example, the openwork can be applied as a flexible fabric having undulating portions which extend out of, i.e., away from a vertical plane. While such angular variances can be tolerated in carrying out the present invention, excessive angular deviations of the reinforcing material will likely result in a substantial reduction in the bursting strength of [0051] walls 20. The application of a particularly aggressive sizing agent may be employed to mitigate strength reduction.
  • Preferably, openwork employed in carrying out the present invention to form an internal integrated reinforcing matrix have several important characteristics or properties which provide optimal reinforcing enhancement to a (usually unreinforced) matrix of dry flowable expandable beads which are molded in a commercially advantageous known manner. The present invention contemplates the use of dry flowable expandable beads of virtually any composition and size in commercial use today. Examples of bead materials include styrene, polystyrene, propylene, and polypropylene having bead sizes ranging between 0.1 mm and 2 mm. The present invention has found immediate commercial application in the field of concrete form modules made of dry flowable expandable beads of styrene and polystyrene of sizes ranging between 0.1 mm and 1.6 mm. [0052]
  • Typically, the dry flowable expandable beads contemplated by the present invention undergo molding by injection into a mold cavity with subsequent loading of the mold/cavity with a substantial quantity of beads, and subsequent exposure of the beads to an external heat source which causes the outer surfaces of the beads to become wetted while the beads expand to achieve a desired target foam density. This critical period in the formation of the molded structure is referred to herein as the wetting/expansion phase in which the previously dry flowable beads are expanded and joined together to achieve an integral solidified mass of selected (final) foam density. According to one aspect of the present invention, the openwork is disposed in the interior of the mold cavity at the time the dry flowable expandable beads are injected in the mold cavity, and at the onset of the wetting/expanding phase of the molding operation. [0053]
  • It has been found important that certain identifying characteristics of the openwork is needed to achieve a desired strength enhancement compared to similar molded articles comprised of unreinforced dry flowable expandable beads. These desirable characteristics are believed helpful in obtaining a desired engagement between the outer surfaces of the openwork and the outer surfaces of the beads as they undergo the wetting/expanding phase of the molding operation. These characteristics will, to some extent, depend upon the bead material and bead size chosen for the particular molded article. [0054]
  • Identifying characteristics of the reinforced molded article include: compatible chemical compositions of dry beads and openwork; that the dry beads are of the flowable expandable type so as to be free flowing to achieve desired packing or density throughout the mold cavity; a cross-sectional size of the openwork and the ratio of the cross-sectional size of the openwork to the length of the openwork elements forming the openwork openings; optionally sizing or the like surface treatment on the openwork to promote enhanced attachment to the expanding beads; folding or other compressed multiple layers of the openwork is generally not preferred; a proportion of openwork to foam beads of approximately 1% by mass; and an orientation of at least 5% of the openwork within the foam core in a direction parallel to the direction of tension and perpendicular to the direction of stress imparted to the molded article. [0055]
  • As mentioned above, particularly in relation to FIG. 5, the openwork reinforcement of the present invention is employed in a commercially significant load bearing structure which employs a spaced apart series of [0056] plastic tie members 40. Due to the configuration of cavities 12 within module 10 it was found desirable to provide added reinforcements adjacent the cavities, i.e., between the tie members 40. If desired, the openwork reinforcement of the present invention could be employed at virtually any point within the foam matrix of walls 20. For example, the openwork could be employed at points between the major and minor bearing plates 44, 82 of tie members 40.
  • As indicated above, the openwork of the present invention is employed in the form of a flexible fabric. In order to take the fullest advantage of the reinforcement strength of the fabric used in the preferred concrete form embodiment it was found expedient to attach the openwork reinforcement to the [0057] major bearing plates 44 of the plastic ties 40. In the preferred embodiment, a pressure sensitive adhesive was employed to attach the openwork to the exposed outer surfaces of the major bearing plates and to allow the adhesive opportunity to fully cure before subjecting the openwork to the molding pressures of the expanding foam matrix. With the foam matrix fully cured, internal bursting forces applied from within cavities 12 will be transmitted by the openwork reinforcement to the major bearing plates of the tie members. It has been found that, even absent the adhesive joinder of the openwork to the major bearing plates, the openwork, held in place by the foam matrix, is adequate to retain heretofore impossible bursting strength. In the worst failure modes, the openwork was found to adequately retain the fluid concrete poured within cavities 12, albeit with an attending bulging dislocation of foam matrix at the outer surface 24 of walls 20.
  • Examples of the present invention have been set forth with regard to a particular type of a commercially significant structure, that of a concrete form module. The present invention is however not so limited and can be employed with virtually any decorative or structural member made from dry expandable foamable beads, including molded packaging materials. Further, the openwork reinforcement afforded by the present invention may be used with or without other internal reinforcing systems, such as the plastic ties of the preferred embodiment. [0058]
  • Referring to FIGS. 8 and 9, it is generally preferred that the openwork reinforcement be embedded within a foam matrix wall adjacent that surface of the wall located opposite the location of applied force. For example, in the illustrated embodiment, the applied force is that of an outwardly directed bursting force imparted by a force system (i.e., the hydrostatic forces of poured concrete) located within a foam matrix structure. Accordingly, it is generally preferred that the openwork reinforcement be located adjacent the outer wall of the foam matrix structure, remote from the application site of the force to be resisted. [0059]
  • Referring to FIG. 9, a generalized foam matrix structure is indicated at [0060] 200. Reinforcement of a wall surface portion 206 was studied. The assumed direction of force to be resisted is indicated by arrow 208 and is applied to a wall portion having a total thickness Q.
  • The openwork reinforcement according to principles of the present invention is introduced at a distance P from the [0061] opposed surface 212 of structure 200. Openwork reinforcement 210 is embedded within the foam matrix core of structure 200 either with or without benefit of chemical sizing or other mechanical structural features to promote adhesion of the foam beads to the members comprising the openwork. Outward bulging or dislocation of the openwork is resisted by the thickness portion of the foam matrix core indicated by the dimension P. It is generally preferred that the ratio P/Q range between 0.28 and 0.5. Smaller ratios would indicate a reduced foam matrix layer to support the openwork against outward bulging. As indicated above, while complete failure of the openwork is avoided, an outward bulging or distortion of the foam matrix may not be desirable from an appearance standpoint. The most preferred placement of openwork 210 at a position P/Q=0.33 is illustrated in FIG. 8.
  • As indicated above with reference to FIG. 5, for example, the [0062] openwork 24 is located closer to the outer surface 24 of the foam matrix than would otherwise be preferred. Studies were made of foam core samples taken between the cut lines 230 of FIG. 5. The openwork was determined to be located at a position P/Q ranging between 0.210 and 0.30. The reduced value of P/Q, i.e., the reduced foam matrix thickness between the openwork and the adjacent outer surface 24 of wall 20 is offset by cooperation between reinforcement of the present invention and the internal construction of module 10. Of particular interest here is the relatively close spacing of the major bearing plates 44 of ties 40. With appropriate adhesive securement between the openwork and the major bearing plates as indicated above the outward bulging of openwork 30 under applied force is sufficiently reduced so as to allow reduced P/Q values of approximately 0.21.
  • The drawings and the foregoing descriptions are not intended to represent the only forms of the invention in regard to the details of its construction and manner of operation. Changes in form and in the proportion of parts, as well as the substitution of equivalents, are contemplated as circumstances may suggest or render expedient; and although specific terms have been employed, they are intended in a generic and descriptive sense only and not for the purposes of limitation, the scope of the invention being delineated by the following claims. [0063]

Claims (19)

What is claimed is:
1. In a freestanding form module for receiving flowable materials to make a wall which includes the form module, the flowable materials exerting a force in a selected direction, the form module comprising at least two spaced-apart form members having opposed interior form surfaces, each form member including a wall portion and a rib portion extending from the wall portion toward another one of said form members; and at least one monolithic molded plastic tie member having opposed ends with a web member between the ends extending along a web axis, a bearing member at each end of the tie member, extending generally transverse to the web axis and embedded in the wall portion of a respective form member with the form member formed around so as to captively enclose the bearing member and each end of the tie member having a stabilizing member extending generally transverse to the web axis, spaced from the bearing member and embedded in the rib portion of a respective form member adjacent the interior form surface thereof with the form member formed around so as to captively enclose the stabilizing member;
the improvement in said form members comprising:
a reinforced foamed article including a three-dimensional foam matrix core of expanded dry flowable foam beads;
an internal reinforcing openwork reinforcing member disposed in the foam matrix and attached to the expanded beads of the foam matrix;
a sizing between at least some of the foam beads and the openwork reinforcing member; and
at least a majority of said openwork reinforcing member oriented in said foam matrix in a direction generally perpendicular to said preselected direction.
2. The improvement of claim 1 wherein at least 97% of said openwork reinforcing member is oriented in a direction generally perpendicular to said preselected direction.
3. The improvement of claim 1 wherein the foam beads are comprised of polystyrene and said openwork reinforcing member is comprised of fiberglass.
4. The improvement of claim 3 wherein 50% of the foam beads have a size dimension of 0.40 mm and 50% of the foam beads have a size dimension of 1.10 mm.
5. The improvement of claim 1 wherein the openwork reinforcing member is comprised of openwork members having openings ranging in size between 0.4 mm and approximately 3 inches.
6. A method of producing a reinforced foamed article comprising the steps of:
providing dry expandable flowable foam beads;
providing an openwork reinforcing member;
providing a mold cavity;
placing the openwork reinforcing member in the mold cavity;
flowing the foam beads into the mold cavity and around the openwork reinforcing member; and
heating the foam beads and the openwork reinforcing member within the mold cavity while allowing the foam beads to expand and fuse with one another to form a three-dimensional foam matrix with the openwork reinforcing member disposed therein.
7. The method of claim 6 further comprising the step of forming a chemical attachment between the openwork reinforcing member and the foam beads.
8. The method according to claim 7 further comprising the step of coating the openwork reinforcing member with a sizing material to enhance said chemical attachment.
9. The method according to claim 6 wherein the step of providing internal reinforcing fiber members comprises a step of providing internal reinforcing fiber members having an aspect ratio ranging between 0.001 and 0.00001.
10. The method according to claim 6 wherein the openwork reinforcing member comprises a fiberglass mesh.
11. The method according to claim 10 wherein said foam beads are comprised of one of said styrene and said polystyrene.
12. The method of claim 6 wherein the reinforced foam article is to be subjected to an applied force extending in a preselected direction, said method further comprising the step of providing a rigid bearing plate disposed in said foam matrix, said rigid bearing plate having a major surface facing in the preselected direction.
13. The method of claim 12 further comprising the step of attaching a portion of said openwork reinforcing member to said bearing plate.
14. The method of claim 12 further comprising the step of attaching a portion of said openwork reinforcing member to said bearing plate with a pressure sensitive adhesive.
15. The method of claim 6 wherein the reinforced foam article is to be subjected to an applied force extending in a preselected direction, said method further comprising the step of orienting at least a majority of said openwork reinforcing member in a direction generally perpendicular to said preselected direction.
16. The method of claim 15 wherein at least 97% of said openwork reinforcing member is oriented in a direction generally perpendicular to said preselected direction.
17. The method of claim 6 wherein the foam beads are comprised of polystyrene and said openwork reinforcing member is comprised of fiberglass.
18. The method of claim 17 wherein the foam beads have a size dimension of 0.40 mm to 1.10 mm.
19. The method of claim 17 wherein 50% of the foam beads have a size dimension of 0.40 mm and 50% of the foam beads have a size dimension of 1.10 mm.
US10/385,070 2003-03-10 2003-03-10 Reinforced foam articles Abandoned US20040177580A1 (en)

Priority Applications (1)

Application Number Priority Date Filing Date Title
US10/385,070 US20040177580A1 (en) 2003-03-10 2003-03-10 Reinforced foam articles

Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
US10/385,070 US20040177580A1 (en) 2003-03-10 2003-03-10 Reinforced foam articles

Publications (1)

Publication Number Publication Date
US20040177580A1 true US20040177580A1 (en) 2004-09-16

Family

ID=32961426

Family Applications (1)

Application Number Title Priority Date Filing Date
US10/385,070 Abandoned US20040177580A1 (en) 2003-03-10 2003-03-10 Reinforced foam articles

Country Status (1)

Country Link
US (1) US20040177580A1 (en)

Cited By (22)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US20060272884A1 (en) * 2005-06-07 2006-12-07 L&L Products, Inc. Noise reduction member and system
US20080086968A1 (en) * 2005-05-31 2008-04-17 Robert Kitchen Wall construction
US20090308011A1 (en) * 2006-07-21 2009-12-17 Phil-Insul Corporation Insulated concrete form panel reinforcement
US20100071314A1 (en) * 2008-09-23 2010-03-25 Felix Von Limburg Distance piece
US20100130589A1 (en) * 2003-09-18 2010-05-27 Freier Susan M MODULATION OF eIF4E EXPRESSION
US20110239566A1 (en) * 2010-04-02 2011-10-06 Romeo Ilarian Ciuperca Insulated concrete form and method of using same
WO2011138573A2 (en) 2010-04-01 2011-11-10 Siftek Limited A construction system
ES2404887R1 (en) * 2010-09-28 2013-06-17 Sanfer Global System S L WRAPPED LOST WINDING FOR VERTICAL ELEMENTS WITH EMBASSY MESH
US8752349B2 (en) * 2012-06-19 2014-06-17 Jesse Westaby Form system with lath covering
US20140263942A1 (en) * 2013-03-15 2014-09-18 Romeo Ilarian Ciuperca Hybrid insulated concrete form and method of making and using same
US20140260034A1 (en) * 2013-03-15 2014-09-18 Romeo Ilarian Ciuperca High performance, reinforced insulated precast concrete and tilt-up concrete structures and methods of making same
US20150118393A1 (en) * 2012-09-25 2015-04-30 Romeo Ilarian Ciuperca High performance, lightweight precast composite insulated concrete panels and high energy-efficient structures and methods of making same
CN105711080A (en) * 2014-12-01 2016-06-29 中国航空工业集团公司第六三一研究所 Overhead heightening device skeleton filling type reinforcing method
WO2016205922A1 (en) * 2015-06-23 2016-12-29 Ciro Devito Construction block
US9676166B1 (en) * 2014-12-23 2017-06-13 Waldemar Stachniuk Modular reinforced insulating concrete form
EP3130715A4 (en) * 2014-03-25 2018-01-03 Universitat Politècnica de València Anti-seismic, insulating construction element
US20190024374A1 (en) * 2016-01-15 2019-01-24 Llc "Ecocuber" Building element made of a fibrous material and building construction utilizing same
US10487520B2 (en) 2013-09-09 2019-11-26 Romeo Ilarian Ciuperca Insulated concrete slip form and method of accelerating concrete curing using same
US10639814B2 (en) 2013-05-13 2020-05-05 Romeo Ilarian Ciuperca Insulated concrete battery mold, insulated passive concrete curing system, accelerated concrete curing apparatus and method of using same
US10744674B2 (en) 2013-05-13 2020-08-18 Romeo Ilarian Ciuperca Removable composite insulated concrete form, insulated precast concrete table and method of accelerating concrete curing using same
US20210348383A1 (en) * 2018-10-15 2021-11-11 Start Somewhere gemeinnützige GmbH Wall block, range of wall blocks, and formwork for producing a wall block
US11536040B2 (en) 2016-01-31 2022-12-27 Romeo Ilarian Ciuperca Self-annealing concrete, self-annealing concrete forms, temperature monitoring system for self-annealing concrete forms and method of making and using same

Citations (83)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US2609320A (en) * 1947-05-29 1952-09-02 Johns Manville Method of making flexible unwoven fabric
US3172072A (en) * 1961-04-25 1965-03-02 Specialty Converters Reinforced foam in sheet form
US3496058A (en) * 1966-11-07 1970-02-17 Kaiser Aluminium Chem Corp Metallic foam laminate
US3506433A (en) * 1965-10-20 1970-04-14 Armour Ind Chem Co Plant growth control
US3552076A (en) * 1966-03-22 1971-01-05 Roher Bohm Ltd Concrete form
US3554851A (en) * 1962-02-26 1971-01-12 Artfiber Corp Glass reinforced foam structure and method of making the same
US3578544A (en) * 1968-01-18 1971-05-11 Phillips Petroleum Co Reinforced microporous laminates
US3951718A (en) * 1975-01-03 1976-04-20 Mcdonnell Douglas Corporation Method for producing reinforced insulating foam
US3960999A (en) * 1974-11-11 1976-06-01 Universal Oil Products Company Method of producing reinforced foamed structures
US4028158A (en) * 1976-01-19 1977-06-07 The Celotex Corporation Structural laminate and method for making same
US4032383A (en) * 1975-11-04 1977-06-28 Mcdonnell Douglas Corporation Fiber insertion device for continuous 3d foaming machine and method
US4044184A (en) * 1973-06-27 1977-08-23 Mitsubishi Chemical Industries Ltd. Cryogenic insulating structure
US4073840A (en) * 1973-10-19 1978-02-14 Exxon Research & Engineering Co. Method for forming a fiber reinforced foam article
US4118533A (en) * 1976-01-19 1978-10-03 Celotex Structural laminate and method for making same
US4163824A (en) * 1973-10-19 1979-08-07 Exxon Research & Engineering Co. Fiber foam and process
US4212917A (en) * 1978-06-01 1980-07-15 The Celotex Corporation Polyisocyanurate foam laminate
US4223501A (en) * 1978-12-29 1980-09-23 Rocky Mountain Foam Form, Inc. Concrete form
US4284683A (en) * 1978-03-13 1981-08-18 The Celotex Corporation Structural laminate
US4765109A (en) * 1987-09-25 1988-08-23 Boeshart Patrick E Adjustable tie
US4879855A (en) * 1988-04-20 1989-11-14 Berrenberg John L Attachment and reinforcement member for molded construction forms
US4884382A (en) * 1988-05-18 1989-12-05 Horobin David D Modular building-block form
US4894969A (en) * 1988-05-18 1990-01-23 Ag-Tech Packaging, Inc. Insulating block form for constructing concrete wall structures
US5008145A (en) * 1987-10-23 1991-04-16 The B. F. Goodrich Company Glass fiber reinforced poly(vinyl chloride) blend with improved heat distortion and tensile strength
US5028649A (en) * 1990-06-22 1991-07-02 Phillips Petroleum Company Polyethylene terephthalate molding compounds with sodium stearate and polyester amides
US5047450A (en) * 1988-04-05 1991-09-10 Phillips Petroleum Company Polyethylene terephthalate molding resin blends
US5065561A (en) * 1988-10-19 1991-11-19 American Construction Products, Inc. Form work system
US5068274A (en) * 1990-07-19 1991-11-26 Phillips Petroleum Company Secondary amides in polyethylene terephthalate molding compositions
US5091457A (en) * 1990-04-27 1992-02-25 Phillips Petroleum Company Polyethylene terephthalate molding compositions
US5091436A (en) * 1990-02-20 1992-02-25 Frisch Kurt C Reinforced foam composites comprising hydroxy-containing vinyl ester resin
US5179137A (en) * 1989-12-08 1993-01-12 Sumitomo Chemical Co., Ltd. Heat-resistant high-impact polystyrene composition
US5200261A (en) * 1989-12-11 1993-04-06 Toray Industries, Inc. Foam material reinforced with composite fibers
US5208269A (en) * 1992-07-16 1993-05-04 Basf Corporation Low-density RRIM using mineral fiber filler
US5240969A (en) * 1992-07-16 1993-08-31 Basf Corporation Low-density RRIM using mineral fiber filler
US5258232A (en) * 1987-09-21 1993-11-02 The Geon Company Articles from reinforced plasticized polyvinyl halide resin
US5283114A (en) * 1991-04-25 1994-02-01 Edison Polymer Innovation Corporation Wholly aromatic polyester fiber-reinforced polystyrene-poly(phenylene oxide) blend
US5459971A (en) * 1994-03-04 1995-10-24 Sparkman; Alan Connecting member for concrete form
US5478882A (en) * 1987-09-21 1995-12-26 The Geon Company Articles from reinforced plasticized polyvinyl halide resin
US5506046A (en) * 1992-08-11 1996-04-09 E. Khashoggi Industries Articles of manufacture fashioned from sheets having a highly inorganically filled organic polymer matrix
US5508072A (en) * 1992-08-11 1996-04-16 E. Khashoggi Industries Sheets having a highly inorganically filled organic polymer matrix
US5514417A (en) * 1994-08-04 1996-05-07 Schuller International, Inc. Method of and apparatus for coating a molded fibrous workpiece
US5525677A (en) * 1993-11-15 1996-06-11 Dongbu Chemical Co., Ltd. Compolymer of styrene and silane coupling agent and synthesizing method thereof and method for improving adhesion performance in fiber reinforced polystyrene composites by using the compolymers
US5527598A (en) * 1993-05-05 1996-06-18 Albany International Research Co. Composite sandwich element
US5545450A (en) * 1992-08-11 1996-08-13 E. Khashoggi Industries Molded articles having an inorganically filled organic polymer matrix
US5549771A (en) * 1994-12-23 1996-08-27 Brooker; David A. Fabrication of body containing lengths of fiber embedded therein
US5567363A (en) * 1994-10-14 1996-10-22 Electronics & Telecommunications Research Inst. Manufacturing method of a polymer GRIN lens using sulfonation
US5567504A (en) * 1994-05-31 1996-10-22 Schuller International, Inc. Glass fiber duct board with coated grooves and the method of making the same
US5580409A (en) * 1992-08-11 1996-12-03 E. Khashoggi Industries Methods for manufacturing articles of manufacture from hydraulically settable sheets
US5582670A (en) * 1992-08-11 1996-12-10 E. Khashoggi Industries Methods for the manufacture of sheets having a highly inorganically filled organic polymer matrix
US5609513A (en) * 1994-04-11 1997-03-11 Minnesota Mining And Manufacturing Company Cleaning and dressing fly lines
US5614307A (en) * 1992-08-11 1997-03-25 E. Khashoggi Industries Sheets made from moldable hydraulically settable compositions
US5641584A (en) * 1992-08-11 1997-06-24 E. Khashoggi Industries Highly insulative cementitious matrices and methods for their manufacture
US5658603A (en) * 1992-08-11 1997-08-19 E. Khashoggi Industries Systems for molding articles having an inorganically filled organic polymer matrix
US5660900A (en) * 1992-08-11 1997-08-26 E. Khashoggi Industries Inorganically filled, starch-bound compositions for manufacturing containers and other articles having a thermodynamically controlled cellular matrix
US5660903A (en) * 1992-08-11 1997-08-26 E. Khashoggi Industries Sheets having a highly inorganically filled organic polymer matrix
US5662731A (en) * 1992-08-11 1997-09-02 E. Khashoggi Industries Compositions for manufacturing fiber-reinforced, starch-bound articles having a foamed cellular matrix
US5665439A (en) * 1992-08-11 1997-09-09 E. Khashoggi Industries Articles of manufacture fashioned from hydraulically settable sheets
US5679145A (en) * 1992-08-11 1997-10-21 E. Khashoggi Industries Starch-based compositions having uniformly dispersed fibers used to manufacture high strength articles having a fiber-reinforced, starch-bound cellular matrix
US5681867A (en) * 1996-07-03 1997-10-28 Basf Corporation Low-density RRIM having improved coefficient of linear thermal expansion and heat deflection properties
US5683772A (en) * 1992-08-11 1997-11-04 E. Khashoggi Industries Articles having a starch-bound cellular matrix reinforced with uniformly dispersed fibers
US5698624A (en) * 1995-06-07 1997-12-16 Amcol International Corporation Exfoliated layered materials and nanocomposites comprising matrix polymers and said exfoliated layered materials formed with water-insoluble oligomers and polymers
US5701710A (en) * 1995-12-07 1997-12-30 Innovative Construction Technologies Corporation Self-supporting concrete form module
US5702710A (en) * 1994-10-04 1997-12-30 Centre International De Recherches Dermatologiques Galderma Dibenzofuran compounds and pharmaceutical/cosmetic compositions comprised thereof
US5705239A (en) * 1992-08-11 1998-01-06 E. Khashoggi Industries Molded articles having an inorganically filled organic polymer matrix
US5707571A (en) * 1991-03-28 1998-01-13 Reedy; Michael Edward Process for producing fiber reinforced foam having a random orientations of fibers
US5709913A (en) * 1992-08-11 1998-01-20 E. Khashoggi Industries Method and apparatus for manufacturing articles of manufacture from sheets having a highly inorganically filled organic polymer matrix
US5709827A (en) * 1992-08-11 1998-01-20 E. Khashoggi Industries Methods for manufacturing articles having a starch-bound cellular matrix
US5712033A (en) * 1996-08-05 1998-01-27 Owens-Corning Fiberglass Technology, Inc. Asphalt-containing organic fibers
US5716092A (en) * 1996-06-11 1998-02-10 Prince Corporation Visor and method of manufacturing
US5719092A (en) * 1996-05-31 1998-02-17 Eastman Kodak Company Fiber/polymer composite for use as a photographic support
US5720913A (en) * 1992-08-11 1998-02-24 E. Khashoggi Industries Methods for manufacturing sheets from hydraulically settable compositions
US5726247A (en) * 1996-06-14 1998-03-10 E. I. Du Pont De Nemours And Company Fluoropolymer nanocomposites
US5760121A (en) * 1995-06-07 1998-06-02 Amcol International Corporation Intercalates and exfoliates formed with oligomers and polymers and composite materials containing same
US5780156A (en) * 1996-10-03 1998-07-14 Basf Corporation Biocomponet fibers having distinct crystaline and amorphous polymer domains and method making same
US5797685A (en) * 1996-11-22 1998-08-25 Chrysler Corporation Gear shift tube support
US5830548A (en) * 1992-08-11 1998-11-03 E. Khashoggi Industries, Llc Articles of manufacture and methods for manufacturing laminate structures including inorganically filled sheets
US5832852A (en) * 1997-03-20 1998-11-10 Cinco, Inc. Cushion and method
US5844032A (en) * 1995-06-07 1998-12-01 Amcol International Corporation Intercalates and exfoliates formed with non-EVOH monomers, oligomers and polymers; and EVOH composite materials containing same
US5849830A (en) * 1995-06-07 1998-12-15 Amcol International Corporation Intercalates and exfoliates formed with N-alkenyl amides and/or acrylate-functional pyrrolidone and allylic monomers, oligomers and copolymers and composite materials containing same
US5853651A (en) * 1995-09-07 1998-12-29 Simula, Inc. High pressure hollow process for manufacturing composite structures
US5853512A (en) * 1997-02-21 1998-12-29 Efp Corporation Method of manufacturing unitary framed foam panels
US5873758A (en) * 1997-07-31 1999-02-23 Mullins; Devan M. Water ski handle
US5874134A (en) * 1996-01-29 1999-02-23 Regents Of The University Of Minnesota Production of nanostructured materials by hypersonic plasma particle deposition
US5996255A (en) * 1997-09-19 1999-12-07 Ventura; George Puncture resistant insole

Patent Citations (99)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US2609320A (en) * 1947-05-29 1952-09-02 Johns Manville Method of making flexible unwoven fabric
US3172072A (en) * 1961-04-25 1965-03-02 Specialty Converters Reinforced foam in sheet form
US3554851A (en) * 1962-02-26 1971-01-12 Artfiber Corp Glass reinforced foam structure and method of making the same
US3506433A (en) * 1965-10-20 1970-04-14 Armour Ind Chem Co Plant growth control
US3552076A (en) * 1966-03-22 1971-01-05 Roher Bohm Ltd Concrete form
US3788020A (en) * 1966-03-22 1974-01-29 Roher Bohm Ltd Foamed plastic concrete form with fire resistant tension member
US3496058A (en) * 1966-11-07 1970-02-17 Kaiser Aluminium Chem Corp Metallic foam laminate
US3578544A (en) * 1968-01-18 1971-05-11 Phillips Petroleum Co Reinforced microporous laminates
US4044184A (en) * 1973-06-27 1977-08-23 Mitsubishi Chemical Industries Ltd. Cryogenic insulating structure
US4073840A (en) * 1973-10-19 1978-02-14 Exxon Research & Engineering Co. Method for forming a fiber reinforced foam article
US4163824A (en) * 1973-10-19 1979-08-07 Exxon Research & Engineering Co. Fiber foam and process
US3960999A (en) * 1974-11-11 1976-06-01 Universal Oil Products Company Method of producing reinforced foamed structures
US3951718A (en) * 1975-01-03 1976-04-20 Mcdonnell Douglas Corporation Method for producing reinforced insulating foam
US4032383A (en) * 1975-11-04 1977-06-28 Mcdonnell Douglas Corporation Fiber insertion device for continuous 3d foaming machine and method
US4028158A (en) * 1976-01-19 1977-06-07 The Celotex Corporation Structural laminate and method for making same
US4118533A (en) * 1976-01-19 1978-10-03 Celotex Structural laminate and method for making same
US4284683A (en) * 1978-03-13 1981-08-18 The Celotex Corporation Structural laminate
US4212917A (en) * 1978-06-01 1980-07-15 The Celotex Corporation Polyisocyanurate foam laminate
US4223501A (en) * 1978-12-29 1980-09-23 Rocky Mountain Foam Form, Inc. Concrete form
US5258232A (en) * 1987-09-21 1993-11-02 The Geon Company Articles from reinforced plasticized polyvinyl halide resin
US5478882A (en) * 1987-09-21 1995-12-26 The Geon Company Articles from reinforced plasticized polyvinyl halide resin
US4765109A (en) * 1987-09-25 1988-08-23 Boeshart Patrick E Adjustable tie
US5008145A (en) * 1987-10-23 1991-04-16 The B. F. Goodrich Company Glass fiber reinforced poly(vinyl chloride) blend with improved heat distortion and tensile strength
US5047450A (en) * 1988-04-05 1991-09-10 Phillips Petroleum Company Polyethylene terephthalate molding resin blends
US4879855A (en) * 1988-04-20 1989-11-14 Berrenberg John L Attachment and reinforcement member for molded construction forms
US4884382A (en) * 1988-05-18 1989-12-05 Horobin David D Modular building-block form
US4894969A (en) * 1988-05-18 1990-01-23 Ag-Tech Packaging, Inc. Insulating block form for constructing concrete wall structures
US5065561A (en) * 1988-10-19 1991-11-19 American Construction Products, Inc. Form work system
US5179137A (en) * 1989-12-08 1993-01-12 Sumitomo Chemical Co., Ltd. Heat-resistant high-impact polystyrene composition
US5200261A (en) * 1989-12-11 1993-04-06 Toray Industries, Inc. Foam material reinforced with composite fibers
US5091436A (en) * 1990-02-20 1992-02-25 Frisch Kurt C Reinforced foam composites comprising hydroxy-containing vinyl ester resin
US5091457A (en) * 1990-04-27 1992-02-25 Phillips Petroleum Company Polyethylene terephthalate molding compositions
US5028649A (en) * 1990-06-22 1991-07-02 Phillips Petroleum Company Polyethylene terephthalate molding compounds with sodium stearate and polyester amides
US5068274A (en) * 1990-07-19 1991-11-26 Phillips Petroleum Company Secondary amides in polyethylene terephthalate molding compositions
US5707571A (en) * 1991-03-28 1998-01-13 Reedy; Michael Edward Process for producing fiber reinforced foam having a random orientations of fibers
US5283114A (en) * 1991-04-25 1994-02-01 Edison Polymer Innovation Corporation Wholly aromatic polyester fiber-reinforced polystyrene-poly(phenylene oxide) blend
US5240969A (en) * 1992-07-16 1993-08-31 Basf Corporation Low-density RRIM using mineral fiber filler
US5208269A (en) * 1992-07-16 1993-05-04 Basf Corporation Low-density RRIM using mineral fiber filler
US5582670A (en) * 1992-08-11 1996-12-10 E. Khashoggi Industries Methods for the manufacture of sheets having a highly inorganically filled organic polymer matrix
US5705239A (en) * 1992-08-11 1998-01-06 E. Khashoggi Industries Molded articles having an inorganically filled organic polymer matrix
US5879722A (en) * 1992-08-11 1999-03-09 E. Khashogi Industries System for manufacturing sheets from hydraulically settable compositions
US5868824A (en) * 1992-08-11 1999-02-09 E. Khashoggi Industries, Llc Inorganically filled, starch-based compositions for manufacturing containers and other articles having a thermodynamically controlled cellular matrix
US5830548A (en) * 1992-08-11 1998-11-03 E. Khashoggi Industries, Llc Articles of manufacture and methods for manufacturing laminate structures including inorganically filled sheets
US5545450A (en) * 1992-08-11 1996-08-13 E. Khashoggi Industries Molded articles having an inorganically filled organic polymer matrix
US5830305A (en) * 1992-08-11 1998-11-03 E. Khashoggi Industries, Llc Methods of molding articles having an inorganically filled organic polymer matrix
US5800647A (en) * 1992-08-11 1998-09-01 E. Khashoggi Industries, Llc Methods for manufacturing articles from sheets having a highly inorganically filled organic polymer matrix
US5783126A (en) * 1992-08-11 1998-07-21 E. Khashoggi Industries Method for manufacturing articles having inorganically filled, starch-bound cellular matrix
US5720913A (en) * 1992-08-11 1998-02-24 E. Khashoggi Industries Methods for manufacturing sheets from hydraulically settable compositions
US5580409A (en) * 1992-08-11 1996-12-03 E. Khashoggi Industries Methods for manufacturing articles of manufacture from hydraulically settable sheets
US5506046A (en) * 1992-08-11 1996-04-09 E. Khashoggi Industries Articles of manufacture fashioned from sheets having a highly inorganically filled organic polymer matrix
US5709827A (en) * 1992-08-11 1998-01-20 E. Khashoggi Industries Methods for manufacturing articles having a starch-bound cellular matrix
US5614307A (en) * 1992-08-11 1997-03-25 E. Khashoggi Industries Sheets made from moldable hydraulically settable compositions
US5626954A (en) * 1992-08-11 1997-05-06 E. Khashoggi Industries Sheets made from moldable hydraulically settable materials
US5641584A (en) * 1992-08-11 1997-06-24 E. Khashoggi Industries Highly insulative cementitious matrices and methods for their manufacture
US5658603A (en) * 1992-08-11 1997-08-19 E. Khashoggi Industries Systems for molding articles having an inorganically filled organic polymer matrix
US5660900A (en) * 1992-08-11 1997-08-26 E. Khashoggi Industries Inorganically filled, starch-bound compositions for manufacturing containers and other articles having a thermodynamically controlled cellular matrix
US5660903A (en) * 1992-08-11 1997-08-26 E. Khashoggi Industries Sheets having a highly inorganically filled organic polymer matrix
US5660904A (en) * 1992-08-11 1997-08-26 E. Khashoggi Industries Sheets having a highly inorganically filled organic polymer matrix
US5662731A (en) * 1992-08-11 1997-09-02 E. Khashoggi Industries Compositions for manufacturing fiber-reinforced, starch-bound articles having a foamed cellular matrix
US5665439A (en) * 1992-08-11 1997-09-09 E. Khashoggi Industries Articles of manufacture fashioned from hydraulically settable sheets
US5665442A (en) * 1992-08-11 1997-09-09 E. Khashoggi Industries Laminated sheets having a highly inorganically filled organic polymer matrix
US5679145A (en) * 1992-08-11 1997-10-21 E. Khashoggi Industries Starch-based compositions having uniformly dispersed fibers used to manufacture high strength articles having a fiber-reinforced, starch-bound cellular matrix
US5679381A (en) * 1992-08-11 1997-10-21 E. Khashoggi Industries Systems for manufacturing sheets from hydraulically settable compositions
US5709913A (en) * 1992-08-11 1998-01-20 E. Khashoggi Industries Method and apparatus for manufacturing articles of manufacture from sheets having a highly inorganically filled organic polymer matrix
US5683772A (en) * 1992-08-11 1997-11-04 E. Khashoggi Industries Articles having a starch-bound cellular matrix reinforced with uniformly dispersed fibers
US5691014A (en) * 1992-08-11 1997-11-25 E. Khashoggi Industries Coated articles having an inorganically filled organic polymer matrix
US5508072A (en) * 1992-08-11 1996-04-16 E. Khashoggi Industries Sheets having a highly inorganically filled organic polymer matrix
US5705238A (en) * 1992-08-11 1998-01-06 E. Khashoggi Industries Articles of manufacture fashioned from sheets having a highly inorganically filled organic polymer matrix
US5527598A (en) * 1993-05-05 1996-06-18 Albany International Research Co. Composite sandwich element
US5525677A (en) * 1993-11-15 1996-06-11 Dongbu Chemical Co., Ltd. Compolymer of styrene and silane coupling agent and synthesizing method thereof and method for improving adhesion performance in fiber reinforced polystyrene composites by using the compolymers
US5459971A (en) * 1994-03-04 1995-10-24 Sparkman; Alan Connecting member for concrete form
US5609513A (en) * 1994-04-11 1997-03-11 Minnesota Mining And Manufacturing Company Cleaning and dressing fly lines
US5567504A (en) * 1994-05-31 1996-10-22 Schuller International, Inc. Glass fiber duct board with coated grooves and the method of making the same
US5549753A (en) * 1994-08-04 1996-08-27 Schuller International, Inc. Apparatus for coating a molded fibrous workpiece
US5514417A (en) * 1994-08-04 1996-05-07 Schuller International, Inc. Method of and apparatus for coating a molded fibrous workpiece
US5702710A (en) * 1994-10-04 1997-12-30 Centre International De Recherches Dermatologiques Galderma Dibenzofuran compounds and pharmaceutical/cosmetic compositions comprised thereof
US5567363A (en) * 1994-10-14 1996-10-22 Electronics & Telecommunications Research Inst. Manufacturing method of a polymer GRIN lens using sulfonation
US5549771A (en) * 1994-12-23 1996-08-27 Brooker; David A. Fabrication of body containing lengths of fiber embedded therein
US5698624A (en) * 1995-06-07 1997-12-16 Amcol International Corporation Exfoliated layered materials and nanocomposites comprising matrix polymers and said exfoliated layered materials formed with water-insoluble oligomers and polymers
US5760121A (en) * 1995-06-07 1998-06-02 Amcol International Corporation Intercalates and exfoliates formed with oligomers and polymers and composite materials containing same
US5877248A (en) * 1995-06-07 1999-03-02 Amcol International Corporation Intercalates and exfoliates formed with oligomers and polymers and composite materials containing same
US5844032A (en) * 1995-06-07 1998-12-01 Amcol International Corporation Intercalates and exfoliates formed with non-EVOH monomers, oligomers and polymers; and EVOH composite materials containing same
US5849830A (en) * 1995-06-07 1998-12-15 Amcol International Corporation Intercalates and exfoliates formed with N-alkenyl amides and/or acrylate-functional pyrrolidone and allylic monomers, oligomers and copolymers and composite materials containing same
US5853651A (en) * 1995-09-07 1998-12-29 Simula, Inc. High pressure hollow process for manufacturing composite structures
US5809728A (en) * 1995-12-07 1998-09-22 Innovative Construction Technologies Corporation Self-supporting concrete form module
US5701710A (en) * 1995-12-07 1997-12-30 Innovative Construction Technologies Corporation Self-supporting concrete form module
US5874134A (en) * 1996-01-29 1999-02-23 Regents Of The University Of Minnesota Production of nanostructured materials by hypersonic plasma particle deposition
US5719092A (en) * 1996-05-31 1998-02-17 Eastman Kodak Company Fiber/polymer composite for use as a photographic support
US5716092A (en) * 1996-06-11 1998-02-10 Prince Corporation Visor and method of manufacturing
US5860690A (en) * 1996-06-11 1999-01-19 Prince Corporation Visor and method of manufacturing
US5726247A (en) * 1996-06-14 1998-03-10 E. I. Du Pont De Nemours And Company Fluoropolymer nanocomposites
US5681867A (en) * 1996-07-03 1997-10-28 Basf Corporation Low-density RRIM having improved coefficient of linear thermal expansion and heat deflection properties
US5712033A (en) * 1996-08-05 1998-01-27 Owens-Corning Fiberglass Technology, Inc. Asphalt-containing organic fibers
US5780156A (en) * 1996-10-03 1998-07-14 Basf Corporation Biocomponet fibers having distinct crystaline and amorphous polymer domains and method making same
US5797685A (en) * 1996-11-22 1998-08-25 Chrysler Corporation Gear shift tube support
US5853512A (en) * 1997-02-21 1998-12-29 Efp Corporation Method of manufacturing unitary framed foam panels
US5832852A (en) * 1997-03-20 1998-11-10 Cinco, Inc. Cushion and method
US5873758A (en) * 1997-07-31 1999-02-23 Mullins; Devan M. Water ski handle
US5996255A (en) * 1997-09-19 1999-12-07 Ventura; George Puncture resistant insole

Cited By (37)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US20100130589A1 (en) * 2003-09-18 2010-05-27 Freier Susan M MODULATION OF eIF4E EXPRESSION
US20080086968A1 (en) * 2005-05-31 2008-04-17 Robert Kitchen Wall construction
US7597382B2 (en) * 2005-06-07 2009-10-06 Zephyros, Inc. Noise reduction member and system
US7950723B2 (en) 2005-06-07 2011-05-31 Zephyros, Inc. Noise reduction member and system
US20110221234A1 (en) * 2005-06-07 2011-09-15 Zephyros, Inc. Noise reduction member and system
US20060272884A1 (en) * 2005-06-07 2006-12-07 L&L Products, Inc. Noise reduction member and system
US8276974B2 (en) 2005-06-07 2012-10-02 Zephyros, Inc. Noise reduction member and system
US20090308011A1 (en) * 2006-07-21 2009-12-17 Phil-Insul Corporation Insulated concrete form panel reinforcement
US8276339B2 (en) * 2008-09-23 2012-10-02 B.T. Innovation Gmbh Distance piece
US20100071314A1 (en) * 2008-09-23 2010-03-25 Felix Von Limburg Distance piece
WO2011138573A3 (en) * 2010-04-01 2012-04-12 Siftek Limited A construction system
WO2011138573A2 (en) 2010-04-01 2011-11-10 Siftek Limited A construction system
GB2493860A (en) * 2010-04-01 2013-02-20 Siftek Ltd A construction system
US8950137B2 (en) * 2010-04-02 2015-02-10 Romeo Ilarian Ciuperca Composite insulated foam panel
US8555583B2 (en) * 2010-04-02 2013-10-15 Romeo Ilarian Ciuperca Reinforced insulated concrete form
US20110239566A1 (en) * 2010-04-02 2011-10-06 Romeo Ilarian Ciuperca Insulated concrete form and method of using same
ES2404887R1 (en) * 2010-09-28 2013-06-17 Sanfer Global System S L WRAPPED LOST WINDING FOR VERTICAL ELEMENTS WITH EMBASSY MESH
US8752349B2 (en) * 2012-06-19 2014-06-17 Jesse Westaby Form system with lath covering
US9809981B2 (en) * 2012-09-25 2017-11-07 Romeo Ilarian Ciuperca High performance, lightweight precast composite insulated concrete panels and high energy-efficient structures and methods of making same
US20150118393A1 (en) * 2012-09-25 2015-04-30 Romeo Ilarian Ciuperca High performance, lightweight precast composite insulated concrete panels and high energy-efficient structures and methods of making same
US20140260034A1 (en) * 2013-03-15 2014-09-18 Romeo Ilarian Ciuperca High performance, reinforced insulated precast concrete and tilt-up concrete structures and methods of making same
US8844227B1 (en) * 2013-03-15 2014-09-30 Romeo Ilarian Ciuperca High performance, reinforced insulated precast concrete and tilt-up concrete structures and methods of making same
US9074379B2 (en) * 2013-03-15 2015-07-07 Romeo Ilarian Ciuperca Hybrid insulated concrete form and method of making and using same
US9410321B2 (en) * 2013-03-15 2016-08-09 Romeo Ilarian Ciuperca High performance, reinforced insulated precast concrete and tilt-up concrete structures and methods of making same
US9745749B2 (en) * 2013-03-15 2017-08-29 Romeo Ilarian Ciuperca High performance, reinforced insulated precast concrete and tilt-up concrete structures and methods of making same
US20140263942A1 (en) * 2013-03-15 2014-09-18 Romeo Ilarian Ciuperca Hybrid insulated concrete form and method of making and using same
US10744674B2 (en) 2013-05-13 2020-08-18 Romeo Ilarian Ciuperca Removable composite insulated concrete form, insulated precast concrete table and method of accelerating concrete curing using same
US10639814B2 (en) 2013-05-13 2020-05-05 Romeo Ilarian Ciuperca Insulated concrete battery mold, insulated passive concrete curing system, accelerated concrete curing apparatus and method of using same
US10487520B2 (en) 2013-09-09 2019-11-26 Romeo Ilarian Ciuperca Insulated concrete slip form and method of accelerating concrete curing using same
EP3130715A4 (en) * 2014-03-25 2018-01-03 Universitat Politècnica de València Anti-seismic, insulating construction element
CN105711080A (en) * 2014-12-01 2016-06-29 中国航空工业集团公司第六三一研究所 Overhead heightening device skeleton filling type reinforcing method
US9676166B1 (en) * 2014-12-23 2017-06-13 Waldemar Stachniuk Modular reinforced insulating concrete form
WO2016205922A1 (en) * 2015-06-23 2016-12-29 Ciro Devito Construction block
US20190024374A1 (en) * 2016-01-15 2019-01-24 Llc "Ecocuber" Building element made of a fibrous material and building construction utilizing same
US10458116B2 (en) * 2016-01-15 2019-10-29 LLC “Ecocuber” Building element made of a fibrous material and building construction utilizing same
US11536040B2 (en) 2016-01-31 2022-12-27 Romeo Ilarian Ciuperca Self-annealing concrete, self-annealing concrete forms, temperature monitoring system for self-annealing concrete forms and method of making and using same
US20210348383A1 (en) * 2018-10-15 2021-11-11 Start Somewhere gemeinnützige GmbH Wall block, range of wall blocks, and formwork for producing a wall block

Similar Documents

Publication Publication Date Title
US20040177580A1 (en) Reinforced foam articles
JP4991985B2 (en) Fiber reinforced composite core and panel
US5725940A (en) Composite molded article and method for making same
KR101027296B1 (en) Composite Structural Material and Method of Making Same
US8419883B2 (en) Fiber reinforced composite cores and panels
AU726177B2 (en) Syntactic foam core material for composite structures
CA2673013C (en) Fiber reinforced composite cores and panels
CA2010043C (en) Sandwich panel material and a method of providing a local reinforcement in a sandwich structure
US4966801A (en) Lightweight composite material
US20040177579A1 (en) Reinforced foam articles
CA2718456C (en) Blade constructs and methods of forming blade constructs
US6004650A (en) Fiber reinforced composite part and method of making same
US7018578B2 (en) Method of producing a hybrid matrix fiber composite
JPH08506281A (en) Method for manufacturing reinforced cement structural member
HU227725B1 (en) A woven carbon fiber fabric, a fiber reinforced plastic molding obtained by using the woven fabric, and a production method of the molding
US20080305705A1 (en) Reinforcing material with bulked fibres
US8220850B2 (en) Impact-absorbing element for a vehicle and methods of producing the same
KR101232004B1 (en) Improved core material
US5538785A (en) Construction element
JPH054291A (en) Manufacture of foamable-thermally-expandable web
EP1502726B1 (en) Materials for moldings
JPH0487855A (en) Bumper beam and manufacture thereof
US5192482A (en) Method of producing a local reinforcement in a sandwich structure
US5391425A (en) Composite material with shrinkage barrier
JPS60235850A (en) Foamed molding of polyolefin resin and manufacture thereof

Legal Events

Date Code Title Description
AS Assignment

Owner name: INNOVATIVE CONSTRUCTION TECHNOLOGIES, INC., IDAHO

Free format text: ASSIGNMENT OF ASSIGNORS INTEREST;ASSIGNOR:TREMELLING, TIM;REEL/FRAME:013880/0468

Effective date: 20030307

STCB Information on status: application discontinuation

Free format text: ABANDONED -- FAILURE TO RESPOND TO AN OFFICE ACTION