US20040222106A1 - Housing and method that provide extended resident time for dissolving generated oxygen into water - Google Patents

Housing and method that provide extended resident time for dissolving generated oxygen into water Download PDF

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US20040222106A1
US20040222106A1 US10/167,982 US16798202A US2004222106A1 US 20040222106 A1 US20040222106 A1 US 20040222106A1 US 16798202 A US16798202 A US 16798202A US 2004222106 A1 US2004222106 A1 US 2004222106A1
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water
housing
electrolytic cell
oxygen
outlet
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US10/167,982
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Gary Hough
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H2O Technologies Ltd
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H2O Technologies Ltd
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    • CCHEMISTRY; METALLURGY
    • C02TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
    • C02FTREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
    • C02F1/00Treatment of water, waste water, or sewage
    • C02F1/46Treatment of water, waste water, or sewage by electrochemical methods
    • C02F1/461Treatment of water, waste water, or sewage by electrochemical methods by electrolysis
    • C02F1/467Treatment of water, waste water, or sewage by electrochemical methods by electrolysis by electrochemical disinfection; by electrooxydation or by electroreduction
    • C02F1/4672Treatment of water, waste water, or sewage by electrochemical methods by electrolysis by electrochemical disinfection; by electrooxydation or by electroreduction by electrooxydation
    • CCHEMISTRY; METALLURGY
    • C02TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
    • C02FTREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
    • C02F1/00Treatment of water, waste water, or sewage
    • C02F1/46Treatment of water, waste water, or sewage by electrochemical methods
    • C02F1/461Treatment of water, waste water, or sewage by electrochemical methods by electrolysis
    • C02F1/46104Devices therefor; Their operating or servicing
    • CCHEMISTRY; METALLURGY
    • C02TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
    • C02FTREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
    • C02F1/00Treatment of water, waste water, or sewage
    • C02F1/001Processes for the treatment of water whereby the filtration technique is of importance
    • CCHEMISTRY; METALLURGY
    • C02TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
    • C02FTREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
    • C02F1/00Treatment of water, waste water, or sewage
    • C02F1/28Treatment of water, waste water, or sewage by sorption
    • C02F1/283Treatment of water, waste water, or sewage by sorption using coal, charred products, or inorganic mixtures containing them
    • CCHEMISTRY; METALLURGY
    • C02TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
    • C02FTREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
    • C02F1/00Treatment of water, waste water, or sewage
    • C02F1/72Treatment of water, waste water, or sewage by oxidation
    • C02F1/727Treatment of water, waste water, or sewage by oxidation using pure oxygen or oxygen rich gas
    • CCHEMISTRY; METALLURGY
    • C02TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
    • C02FTREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
    • C02F1/00Treatment of water, waste water, or sewage
    • C02F1/46Treatment of water, waste water, or sewage by electrochemical methods
    • C02F1/461Treatment of water, waste water, or sewage by electrochemical methods by electrolysis
    • C02F1/46104Devices therefor; Their operating or servicing
    • C02F1/46109Electrodes
    • C02F2001/46152Electrodes characterised by the shape or form
    • CCHEMISTRY; METALLURGY
    • C02TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
    • C02FTREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
    • C02F2201/00Apparatus for treatment of water, waste water or sewage
    • C02F2201/46Apparatus for electrochemical processes
    • C02F2201/461Electrolysis apparatus
    • C02F2201/46105Details relating to the electrolytic devices
    • C02F2201/4611Fluid flow
    • CCHEMISTRY; METALLURGY
    • C02TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
    • C02FTREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
    • C02F2201/00Apparatus for treatment of water, waste water or sewage
    • C02F2201/46Apparatus for electrochemical processes
    • C02F2201/461Electrolysis apparatus
    • C02F2201/46105Details relating to the electrolytic devices
    • C02F2201/46155Heating or cooling
    • CCHEMISTRY; METALLURGY
    • C02TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
    • C02FTREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
    • C02F2301/00General aspects of water treatment
    • C02F2301/02Fluid flow conditions
    • C02F2301/022Laminar
    • CCHEMISTRY; METALLURGY
    • C02TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
    • C02FTREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
    • C02F2303/00Specific treatment goals
    • C02F2303/04Disinfection

Definitions

  • This invention relax to dissolving oxygen into water, and more particularly, to an improved apparatus and method that provides an extended resident time for dissolving recently generated oxygen into water.
  • the oxygen content of water may be increased via electrolysis.
  • a current is supplied to a cathode and anode positioned in a water solution.
  • a DC voltage is connected to the electrodes in the water.
  • electricity passes through the water, splitting some of the water molecules into their component parts, causing the formation of hydrogen gas and oxygen gas.
  • an apparatus for increasing the quantity of dissolved oxygen into water.
  • the apparatus includes an inlet for receiving untreated water.
  • a cell housing is connected to the inlet.
  • Within the cell housing is an electrolytic cell. When power is supplied to the electrolytic cell, electricity flows through the water breaking some of the water molecules into their component parts of hydrogen gas and oxygen gas.
  • a vertically-oriented, longitudinally-extending housing is connected to the cell housing. The housing has a selected vertical length for providing a high resident time for water in the housing. The length is selected to be sufficiently long that a majority of the gaseous oxygen transitions to dissolved oxygen in the water.
  • the resident time housing has an open channel, which is unrestricted and with no obstructions therein. Further, in a preferred embodiment, it is a generally uniform cross-sectional area with a smooth wall to promote laminar flow.
  • the use of an unrestricted, laminar flow zone provides a quiet time for the oxygen to transition from the gaseous state into the dissolved state.
  • FIG. 1 is an isometric view of a first embodiment of an apparatus according to the present invention.
  • FIG. 2 is an isometric schematic view of an alternative embodiment according to principles of the present invention.
  • FIG. 3 is a first embodiment of an electrolytic cell according to principles of the present invention.
  • FIG. 4 is an alternative embodiment of an electrolytic cell according to principles of the present invention.
  • FIG. 1 shows the apparatus 10 for increasing the quantity of dissolved oxygen in the water.
  • the apparatus 10 includes an electrolytic cell housing 12 having an inlet section 14 connected prior to the cell housing 12 .
  • An inlet pipe 16 is connected to the inlet 14 for receiving water flowing and is shown by direction arrow 29 .
  • a power supply 18 is coupled to the electric cell housing 12 for providing direct current to the electrolytic cell as described in more detail later herein.
  • a resident time housing 22 is connected at the outlet of the cell housing 12 .
  • the resident time housing 22 is vertically oriented to provide a long channel through which water flows in a vertical direction.
  • the resident time housing 22 longitudinally extends for a selected vertical length above the cell 12 .
  • An outlet 38 housing a vent 32 therein is at the top of the housing 22 .
  • An outlet pipe 34 is connected to the outlet 38 for providing a flow of treated water.
  • the electrolytic cell in the housing 12 has direct current power supplied thereto so as to provide a flow of electric current through the water 30 flowing therein.
  • the passage of electric current causes some of the water molecules to split into their component parts creating hydrogen gas and oxygen gas.
  • the hydrogen gas represented by the large bubbles 24
  • the oxygen gas represented by the small bubbles 26
  • Both the hydrogen gas 24 and the oxygen gas 26 are, at this time, mainly in the gaseous state.
  • Hydrogen bubbles 24 are generally larger and more likely to remain separated from the water itself.
  • Oxygen bubbles are quite numerous and create a cloud effect immediately at the exit of the electrolytic cell 12 .
  • the water is usually moving through the tube as shown by direction arrow 30 .
  • the water may be stationary and even in those embodiments, the gases will still rise slowly through the tube, the gas being lighter than the water.
  • the oxygen 26 rises through the resident time housing 22 it will transition from a gaseous state to a dissolved state, greatly reducing the number of separate oxygen gas molecules therein.
  • the length l is selected to be sufficiently long that a majority of the oxygen molecules become dissolved oxygen in the water.
  • the hydrogen molecules are more likely to retain in the gaseous state through the entire length of the tube and thus will remain in the gaseous form as shown by bubbles 24 .
  • the resident time housing 22 is a straight, longitudinally-extending tube with an unrestricted cross-sectional area. This permits water to pass therethrough in laminar flow without encountering obstructions. This provides a quiet zone which permits the oxygen molecules to more easily be dissolved into the water. If the resident time housing 22 is made too short, the housing will terminate before a majority of the oxygen has dissolved into the water and will thus be exposed to surface air and exit in the gaseous form, rather than becoming dissolved in the water.
  • the distance l is selected to be in the range of 3 to 6 feet, 4 feet being the preferred range.
  • the diameter of the resident time housing 22 is in the range of 3-4 inches in one embodiment. In other embodiments, a smaller diameter tube is used. With such a housing length and diameter, flow rates in the range of 2 to 6 gallons per minute can be achieved while achieving high dissolved oxygen values. Thus, even at very high flow rates, such as 6 gallons per minute, the resident time of the water inside the housing 22 is sufficiently long that during this quiet period a majority of the generated gaseous oxygen transitions into the dissolved state so that the water exiting the top of the housing has a relatively high dissolved oxygen percentage.
  • the length l which is optimum is related to the flow rate desired, as well as the diameter of the tube and other factors. For a very low flow rate, a shorter length l is acceptable because the water will have sufficient resident time that a majority of the oxygen can transition into dissolved oxygen. On the other hand, for higher flow rates, a longer length l will be desired.
  • the desired feature of the invention is to maintain a resident time of the water prior to encountering a 90° bend in the flow or other turbulent-creating member that the gaseous oxygen may be rapidly dissolved to become dissolved oxygen.
  • the outlet 28 has a vent 32 connected thereto permitting hydrogen gas to escape at the top of the outlet 28 . Any other gases which remain in gaseous form at the outlet 28 will also be permitted to escape via vent 32 . However, since a majority of the oxygen has transitioned to the dissolved state, it will be retained in the water and will not escape via vent 32 .
  • the treated 30 then passes to an outlet pipe 34 where it is provided to the consumer.
  • a flow rate sensor 36 may monitor the rate at which treated water is provided to a user. If the water is flowing at an extremely high rate, the flow sensor may provide feedback to the power supply to increase the current or, conversely, if the flow rate is extremely low or zero, may reduce the current or turn it off as desired.
  • the flow rate sensor 36 can be positioned at any desired location, including prior to the inlet 16 , or other positions as desired by the user, it being shown only schematically for purposes of illustrating the ability to sense the flow and provide feedback if necessary.
  • the treated water 30 is thereafter provided to any desired user, which may include poultry, such as chickens and turkeys. Alternatively, it may also be provided to an outlet tap for human consumption.
  • the resident time housing 22 is clear so that a person may easily see the various gases inside the housing.
  • a light 38 is provided immediately behind the housing. The light 38 transmits light directly through the water 30 being treated so that an operator may see the hydrogen gas 24 and oxygen gas 26 within the water 30 . This provides feedback to the operator to confirm that the majority of the gaseous oxygen 26 is transitioned to the dissolved state prior to reaching the outlet 28 . Further, it provides visual stimulation and an artistic enjoyment for viewers. The generation of many different sized bubbles, and their passing at different speeds through the water as the water is also traveling through the tube, creates a dancing effect of the bubbles, which has a pleasing effect to the eye of the viewers.
  • FIG. 2 illustrates an embodiment which is more particularly suited for the delivery of oxygenated water for human consumption and viewing enjoyment.
  • a cell housing 12 is coupled at one end to an inlet 14 and at the other end to an outlet 28 .
  • a vent 32 permits hydrogen gas to be vented.
  • the resident time housing 22 is clear and has a light 38 at the back thereof.
  • the bubbles 24 and 26 are present, however, they are not shown in this figure, to provide a more clear illustration of the structure and operation of the present invention.
  • a chill unit 40 Prior to the inlet 14 , a chill unit 40 is provided in the inlet pipe 16 .
  • the purpose of the chill unit 40 is to reduce the temperature of the water to a low temperature level to provide enjoyable drinking for human consumption. It also has the distinct advantage of significantly increasing the amount of dissolved oxygen which the water 30 can retain, as explained in more detail elsewhere herein.
  • Untreated water is provided as shown by the arrow 29 into an inlet pipe 42 .
  • the untreated water passes through a filter 44 to ensure that all contaminants and undesired gases are removed therefrom.
  • the filter is of the activated charcoal type or other type which is known to remove chlorine gas and other substances.
  • the water then passes from the filter 44 into a transition pipe 46 . From the transition pipe 46 it passes into the chill unit 40 where it is reduced to a cool temperature for drinking.
  • the chill unit 40 may be of any type which is currently available in the market today, such chill units being well known.
  • a chill unit is often provided in the flow line, which includes a heat exchanger surrounded by ice or other temperature-reducing material. This will reduce the temperature of the water flowing therethrough to a desirable drinking temperature without freezing it.
  • a refrigeration unit such as the type powered by a motor and having a heat exchanger may also be used if desired.
  • the water passes from the chill unit 40 into the inlet tube 16 , the inlet 14 , and then through the electrolytic cell in the housing 12 .
  • the electrolytic cell generates hydrogen and oxygen gases as has been previously described.
  • the water 30 containing dissolved oxygen passes from the outlet 28 into an outlet pipe 34 . From the outlet pipe 34 the water is delivered to a consumer supply tube 48 .
  • the consumer supply tube 48 will have a smaller diameter than the resident time housing 22 , such as 3 ⁇ 4 of an inch, 1 ⁇ 2 inch, or less. By this time, the majority of the oxygen has entered to the dissolved state and thus the tube diameter can be restricted.
  • a gradual diameter reducer 50 is preferred so as to maintain a generally laminar flow and keep a substantial portion of the oxygen in the dissolved state. It may also be reduced in steps by having one or more reducers 50 . Thereafter, the treated water 30 is delivered to a tap 52 .
  • the tap 52 is operated manually by a user so as to provide drinking water from the system.
  • the tap 52 may be of any conventional type known in the art.
  • it may be of the type normally used for the dispension of beer or other carbonated beverages having the appropriate flow valves and lever 54 thereon so as to maintain the gas in the dissolved state.
  • Such flow valves are well known in the art, being used for the dispension of carbonated beverages, beer, and other liquids.
  • the user, or a waiter serving the user is thus able to easily place the oxygenated water into a glass or pitcher for consumption.
  • a small pump 56 causes recirculation of the water through a recirculation tube 58 into the transition pipe 46 .
  • the water thereafter enters to the chill unit and is returned to a low temperature prior to passing through the cell housing and having its dissolved oxygen content increased as has been described.
  • Cold water is capable absorbing significantly greater amounts of gases, including oxygen gas. Further, the chilled water can absorb the oxygen gas more rapidly and maintain a higher dissolved oxygen content than warm water. Chilling the water prior to it entering the electrolytic cell provides the advantage that the gas will be more rapidly absorbed into the water and further, that the water can hold a higher quantity of the dissolved oxygen than is possible at a higher temperature.
  • the chill unit 40 thus provides an improved drinking beverage for human consumption and also the advantage of increased dissolved oxygen quantities and at a faster rate than is possible without the chilling.
  • the device of FIG. 2 is of a type which would normally be installed in a restaurant, bar, or other location so as to provide high-quality water with a substantial dissolved oxygen content.
  • the housing 22 is therefore made aesthetically pleasing and the light 38 is selected to be of the type which will provide pleasant viewing.
  • the light 38 can, of course, be a single light of a selected color. Alternatively, a variety of different-colored lights switch on and off in a selected pattern or sequence so as to create an artistic appeal.
  • the light 38 represents any number of different types of lights, as well as different colors so as to provide the desired artistic visual effect while at the same time the generation of high quantities of dissolved oxygen in the water.
  • a removable coupling 60 is positioned at a bottom portion of the electrolytic cell 12 . Further, a removable coupling 62 is positioned at a top portion of the electrolytic cell.
  • the removable couplings are significant advantages in providing service and cleaning of the electrolytic cell 12 and the housing 22 .
  • operation of the system is terminated and water is drained from the system.
  • the couplings 60 and 62 are then rotated so as to separate the electrolytic cell 12 from the rest of the system.
  • the cell housing 12 is thereafter removed from the system for replacement, servicing or the like is desired. Thereafter, the cell housing 12 , having the new electrolytic cell or the cleaned cell therein is replaced and the couplings 60 and 62 are reattached so the system becomes fully operational.
  • the couplings 60 and 62 can be any acceptable coupling in the prior art, including rotatable threads, watertight couplings or the like, many such watertight connections being known.
  • FIGS. 3 and 4 show examples of the housing 12 having an electrolytic cell therein.
  • the electrolytic cell includes electrodes 20 which are appropriately connected to the positive and negative power supplies, as is known in the art.
  • the length 23 and the number of the electrodes 20 is selected so as to provide the desired amount of oxygen generation, again according to known principles.
  • the housing 12 has the same cross-sectional diameter as the resident time housing 22 so as to provide a generally smooth, laminar transition from the electrolytic cell to the resident time housing 22 .
  • the resident time housing 22 will begin immediately above the electrolytic cell so that the generated oxygen gas can begin to transition into the dissolved state.
  • the resident time housing 22 has a larger diameter than the cell housing 12 to provide an extended resident time for a given flow rate.

Abstract

An apparatus for increasing the quantity of dissolved oxygen in water. The apparatus includes an inlet for receiving untreated water. A cell housing having an electrolytic cell therein is coupled to the inlet. A resident time housing is connected to the cell housing for receiving water having oxygen and hydrogen gas therein. The resident time housing is vertically oriented and longitudinally extending for a selected vertical length above the cell housing. This provides sufficient resident time of the water in a quiet zone to permit the generated oxygen gas to transition into the dissolved state prior to reaching the top of the resident time housing. An outlet is provided at the top of the resident time housing. Treated water having a high dissolved oxygen content is delivered out of the outlet. A gas vent is provided at the outlet to permit the escape of hydrogen or other gases which have not been dissolved into the water. Preferably, a chill unit is provided prior to the electrolytic cell to reduce the temperature of the water to make it pleasing for human consumption and also to increase the quantity of dissolved oxygen which can enter the water. Additionally, a light or other artistic display may be provided adjacent to or with the resident time housing for the pleasure of viewers.

Description

    TECHNICAL FIELD
  • This invention relax to dissolving oxygen into water, and more particularly, to an improved apparatus and method that provides an extended resident time for dissolving recently generated oxygen into water. [0001]
  • BACKGROUND OF THE INVENTION
  • Many benefits may be obtained through the use of water containing an elevated quantity of dissolved oxygen. For example, certain studies have shown that animals, including chickens and turkeys, may become heavier for a given grain consumption if their drinking water has elevated oxygen levels. Increased levels of oxygen and water have been shown to purify the water, removing and neutralizing a variety of biological and chemical contaminants. In addition, there are indications that humans obtain considerable health benefits by drinking water with elevated levels of dissolved oxygen. [0002]
  • It is well known that the oxygen content of water may be increased via electrolysis. According to known techniques, a current is supplied to a cathode and anode positioned in a water solution. A DC voltage is connected to the electrodes in the water. When current is supplied, electricity passes through the water, splitting some of the water molecules into their component parts, causing the formation of hydrogen gas and oxygen gas. [0003]
  • Currently available systems for oxygenating water with electrolytic cells may not reach desired levels of oxygen, nor do they function as efficiently as desired. Accordingly, there is a need in the art for an improved system that increases the amount of dissolved oxygen in water at an improved efficiency. [0004]
  • SUMMARY OF THE INVENTION
  • According to principles of the present invention, an apparatus is provided for increasing the quantity of dissolved oxygen into water. The apparatus includes an inlet for receiving untreated water. A cell housing is connected to the inlet. Within the cell housing is an electrolytic cell. When power is supplied to the electrolytic cell, electricity flows through the water breaking some of the water molecules into their component parts of hydrogen gas and oxygen gas. At the outlet of the cell, both hydrogen gas and oxygen gas are present in the water. A vertically-oriented, longitudinally-extending housing is connected to the cell housing. The housing has a selected vertical length for providing a high resident time for water in the housing. The length is selected to be sufficiently long that a majority of the gaseous oxygen transitions to dissolved oxygen in the water. [0005]
  • The resident time housing has an open channel, which is unrestricted and with no obstructions therein. Further, in a preferred embodiment, it is a generally uniform cross-sectional area with a smooth wall to promote laminar flow. The use of an unrestricted, laminar flow zone provides a quiet time for the oxygen to transition from the gaseous state into the dissolved state.[0006]
  • BRIEF DESCRIPTION OF THE DRAWINGS
  • FIG. 1 is an isometric view of a first embodiment of an apparatus according to the present invention. [0007]
  • FIG. 2 is an isometric schematic view of an alternative embodiment according to principles of the present invention. [0008]
  • FIG. 3 is a first embodiment of an electrolytic cell according to principles of the present invention. [0009]
  • FIG. 4 is an alternative embodiment of an electrolytic cell according to principles of the present invention. [0010]
  • DETAILED DESCRIPTION OF THE INVENTION
  • FIG. 1 shows the apparatus [0011] 10 for increasing the quantity of dissolved oxygen in the water. The apparatus 10 includes an electrolytic cell housing 12 having an inlet section 14 connected prior to the cell housing 12. An inlet pipe 16 is connected to the inlet 14 for receiving water flowing and is shown by direction arrow 29.
  • A [0012] power supply 18 is coupled to the electric cell housing 12 for providing direct current to the electrolytic cell as described in more detail later herein.
  • A [0013] resident time housing 22 is connected at the outlet of the cell housing 12. The resident time housing 22 is vertically oriented to provide a long channel through which water flows in a vertical direction. The resident time housing 22 longitudinally extends for a selected vertical length above the cell 12.
  • An [0014] outlet 38 housing a vent 32 therein is at the top of the housing 22. An outlet pipe 34 is connected to the outlet 38 for providing a flow of treated water.
  • During operation, the electrolytic cell in the [0015] housing 12 has direct current power supplied thereto so as to provide a flow of electric current through the water 30 flowing therein. The passage of electric current causes some of the water molecules to split into their component parts creating hydrogen gas and oxygen gas. At the outlet of the electrolytic cell, the hydrogen gas, represented by the large bubbles 24 and the oxygen gas, represented by the small bubbles 26, exit from the electrolytic cell. Both the hydrogen gas 24 and the oxygen gas 26 are, at this time, mainly in the gaseous state. Hydrogen bubbles 24 are generally larger and more likely to remain separated from the water itself. Oxygen bubbles, on the other hand, are quite numerous and create a cloud effect immediately at the exit of the electrolytic cell 12. Both the hydrogen and oxygen, at this stage being in gaseous form, begin to rise in the water. In addition, the water is usually moving through the tube as shown by direction arrow 30. In some embodiments, the water may be stationary and even in those embodiments, the gases will still rise slowly through the tube, the gas being lighter than the water.
  • As the [0016] oxygen 26 rises through the resident time housing 22 it will transition from a gaseous state to a dissolved state, greatly reducing the number of separate oxygen gas molecules therein. The length l is selected to be sufficiently long that a majority of the oxygen molecules become dissolved oxygen in the water. On the other hand, the hydrogen molecules are more likely to retain in the gaseous state through the entire length of the tube and thus will remain in the gaseous form as shown by bubbles 24.
  • Accordingly to principles of the present invention, the [0017] resident time housing 22 is a straight, longitudinally-extending tube with an unrestricted cross-sectional area. This permits water to pass therethrough in laminar flow without encountering obstructions. This provides a quiet zone which permits the oxygen molecules to more easily be dissolved into the water. If the resident time housing 22 is made too short, the housing will terminate before a majority of the oxygen has dissolved into the water and will thus be exposed to surface air and exit in the gaseous form, rather than becoming dissolved in the water. Further, if turbulence is induced in the water, such as by having a sharp turn, a 90° elbow, or other obstructions immediately after the cell before sufficient quiet time has been permitted, then the oxygen will be inclined to remain in the gaseous state and not transition to dissolved oxygen. A shortcoming of many prior art devices is the presence of such obstructions, including sharp bends in the pipe, filters or other devices shortly after the electrolytic cell 12 which act as obstructions to prevent the rapid transition of the oxygen 26 into the dissolved state within the water.
  • According to one embodiment of the present invention, the distance l is selected to be in the range of 3 to 6 feet, 4 feet being the preferred range. The diameter of the [0018] resident time housing 22 is in the range of 3-4 inches in one embodiment. In other embodiments, a smaller diameter tube is used. With such a housing length and diameter, flow rates in the range of 2 to 6 gallons per minute can be achieved while achieving high dissolved oxygen values. Thus, even at very high flow rates, such as 6 gallons per minute, the resident time of the water inside the housing 22 is sufficiently long that during this quiet period a majority of the generated gaseous oxygen transitions into the dissolved state so that the water exiting the top of the housing has a relatively high dissolved oxygen percentage.
  • As will be appreciated, the length l which is optimum, is related to the flow rate desired, as well as the diameter of the tube and other factors. For a very low flow rate, a shorter length l is acceptable because the water will have sufficient resident time that a majority of the oxygen can transition into dissolved oxygen. On the other hand, for higher flow rates, a longer length l will be desired. The desired feature of the invention is to maintain a resident time of the water prior to encountering a 90° bend in the flow or other turbulent-creating member that the gaseous oxygen may be rapidly dissolved to become dissolved oxygen. [0019]
  • The [0020] outlet 28 has a vent 32 connected thereto permitting hydrogen gas to escape at the top of the outlet 28. Any other gases which remain in gaseous form at the outlet 28 will also be permitted to escape via vent 32. However, since a majority of the oxygen has transitioned to the dissolved state, it will be retained in the water and will not escape via vent 32. The treated 30 then passes to an outlet pipe 34 where it is provided to the consumer. If desired, a flow rate sensor 36 may monitor the rate at which treated water is provided to a user. If the water is flowing at an extremely high rate, the flow sensor may provide feedback to the power supply to increase the current or, conversely, if the flow rate is extremely low or zero, may reduce the current or turn it off as desired. The flow rate sensor 36 can be positioned at any desired location, including prior to the inlet 16, or other positions as desired by the user, it being shown only schematically for purposes of illustrating the ability to sense the flow and provide feedback if necessary.
  • The treated [0021] water 30 is thereafter provided to any desired user, which may include poultry, such as chickens and turkeys. Alternatively, it may also be provided to an outlet tap for human consumption.
  • According to one embodiment, the [0022] resident time housing 22 is clear so that a person may easily see the various gases inside the housing. A light 38 is provided immediately behind the housing. The light 38 transmits light directly through the water 30 being treated so that an operator may see the hydrogen gas 24 and oxygen gas 26 within the water 30. This provides feedback to the operator to confirm that the majority of the gaseous oxygen 26 is transitioned to the dissolved state prior to reaching the outlet 28. Further, it provides visual stimulation and an artistic enjoyment for viewers. The generation of many different sized bubbles, and their passing at different speeds through the water as the water is also traveling through the tube, creates a dancing effect of the bubbles, which has a pleasing effect to the eye of the viewers. This provides a distinct advantage in those situations where the water is being provided for human consumption. The person consuming the water has the advantage of confirming that oxygen is in fact being generated by the electrolytic cell. Further, he/she can confirm that the majority of the oxygen generated has transitioned into the dissolved state while at the same time having the enjoyment of viewing the artistic effect of the various bubbles as they are created and passed through the system. The use of this device, not only as an oxygen generator, but also as an artistic device for entertainment, is a significant advantage which is not obtainable in the prior art. Further, the immediate feedback to the user that the invention is achieving the desired result provides not only satisfaction and enjoyment but the assurance that a high-quality product is being properly delivered. This has significant commercial benefit for the sale of such water, as will be described with respect to the next embodiment.
  • FIG. 2 illustrates an embodiment which is more particularly suited for the delivery of oxygenated water for human consumption and viewing enjoyment. As with the device of FIG. 1, a [0023] cell housing 12 is coupled at one end to an inlet 14 and at the other end to an outlet 28. A vent 32 permits hydrogen gas to be vented. The resident time housing 22 is clear and has a light 38 at the back thereof. The bubbles 24 and 26 are present, however, they are not shown in this figure, to provide a more clear illustration of the structure and operation of the present invention. Prior to the inlet 14, a chill unit 40 is provided in the inlet pipe 16. The purpose of the chill unit 40 is to reduce the temperature of the water to a low temperature level to provide enjoyable drinking for human consumption. It also has the distinct advantage of significantly increasing the amount of dissolved oxygen which the water 30 can retain, as explained in more detail elsewhere herein.
  • Untreated water is provided as shown by the [0024] arrow 29 into an inlet pipe 42. The untreated water passes through a filter 44 to ensure that all contaminants and undesired gases are removed therefrom. Preferably, the filter is of the activated charcoal type or other type which is known to remove chlorine gas and other substances. The water then passes from the filter 44 into a transition pipe 46. From the transition pipe 46 it passes into the chill unit 40 where it is reduced to a cool temperature for drinking.
  • The [0025] chill unit 40 may be of any type which is currently available in the market today, such chill units being well known. For sample, in the delivery of beer or other tap beverages, a chill unit is often provided in the flow line, which includes a heat exchanger surrounded by ice or other temperature-reducing material. This will reduce the temperature of the water flowing therethrough to a desirable drinking temperature without freezing it. A refrigeration unit, such as the type powered by a motor and having a heat exchanger may also be used if desired.
  • The water passes from the [0026] chill unit 40 into the inlet tube 16, the inlet 14, and then through the electrolytic cell in the housing 12. The electrolytic cell generates hydrogen and oxygen gases as has been previously described. The water 30, containing dissolved oxygen passes from the outlet 28 into an outlet pipe 34. From the outlet pipe 34 the water is delivered to a consumer supply tube 48. Generally, the consumer supply tube 48 will have a smaller diameter than the resident time housing 22, such as ¾ of an inch, ½ inch, or less. By this time, the majority of the oxygen has entered to the dissolved state and thus the tube diameter can be restricted. However, a gradual diameter reducer 50 is preferred so as to maintain a generally laminar flow and keep a substantial portion of the oxygen in the dissolved state. It may also be reduced in steps by having one or more reducers 50. Thereafter, the treated water 30 is delivered to a tap 52.
  • The [0027] tap 52 is operated manually by a user so as to provide drinking water from the system. The tap 52 may be of any conventional type known in the art. For example, it may be of the type normally used for the dispension of beer or other carbonated beverages having the appropriate flow valves and lever 54 thereon so as to maintain the gas in the dissolved state. Such flow valves are well known in the art, being used for the dispension of carbonated beverages, beer, and other liquids. The user, or a waiter serving the user, is thus able to easily place the oxygenated water into a glass or pitcher for consumption.
  • Generally, water will not be constantly drawn from the [0028] valve 52. Rather, it will be removed as demanded by a user. Accordingly, it is desired to maintain the water in constant circulation so that it remains sufficiently chilled to be comfortable for drinking. According to one embodiment of the invention, a small pump 56 causes recirculation of the water through a recirculation tube 58 into the transition pipe 46. The water thereafter enters to the chill unit and is returned to a low temperature prior to passing through the cell housing and having its dissolved oxygen content increased as has been described.
  • Having the water at a low temperature prior to entering through the cell housing significantly improves the dissolved oxygen properties of the water. Cold water is capable absorbing significantly greater amounts of gases, including oxygen gas. Further, the chilled water can absorb the oxygen gas more rapidly and maintain a higher dissolved oxygen content than warm water. Chilling the water prior to it entering the electrolytic cell provides the advantage that the gas will be more rapidly absorbed into the water and further, that the water can hold a higher quantity of the dissolved oxygen than is possible at a higher temperature. The [0029] chill unit 40 thus provides an improved drinking beverage for human consumption and also the advantage of increased dissolved oxygen quantities and at a faster rate than is possible without the chilling.
  • As will be appreciated, the device of FIG. 2 is of a type which would normally be installed in a restaurant, bar, or other location so as to provide high-quality water with a substantial dissolved oxygen content. Often, the customers wish to view the generation of the treated water and the dissolving of oxygen gas into the water. The [0030] housing 22 is therefore made aesthetically pleasing and the light 38 is selected to be of the type which will provide pleasant viewing. The light 38 can, of course, be a single light of a selected color. Alternatively, a variety of different-colored lights switch on and off in a selected pattern or sequence so as to create an artistic appeal. Thus, the light 38 represents any number of different types of lights, as well as different colors so as to provide the desired artistic visual effect while at the same time the generation of high quantities of dissolved oxygen in the water.
  • An additional benefit of the present invention will now be described with respect to FIG. 1. As shown in FIG. 1, a [0031] removable coupling 60 is positioned at a bottom portion of the electrolytic cell 12. Further, a removable coupling 62 is positioned at a top portion of the electrolytic cell. The removable couplings are significant advantages in providing service and cleaning of the electrolytic cell 12 and the housing 22. When it is desired to service the electrolytic cell 12, such as cleaning the electrodes, replacing or servicing any of the components or the like, operation of the system is terminated and water is drained from the system. The couplings 60 and 62 are then rotated so as to separate the electrolytic cell 12 from the rest of the system. The cell housing 12 is thereafter removed from the system for replacement, servicing or the like is desired. Thereafter, the cell housing 12, having the new electrolytic cell or the cleaned cell therein is replaced and the couplings 60 and 62 are reattached so the system becomes fully operational. The couplings 60 and 62 can be any acceptable coupling in the prior art, including rotatable threads, watertight couplings or the like, many such watertight connections being known.
  • FIGS. 3 and 4 show examples of the [0032] housing 12 having an electrolytic cell therein. The electrolytic cell includes electrodes 20 which are appropriately connected to the positive and negative power supplies, as is known in the art. The length 23 and the number of the electrodes 20 is selected so as to provide the desired amount of oxygen generation, again according to known principles. In a preferred embodiment, the housing 12 has the same cross-sectional diameter as the resident time housing 22 so as to provide a generally smooth, laminar transition from the electrolytic cell to the resident time housing 22. Generally, the resident time housing 22 will begin immediately above the electrolytic cell so that the generated oxygen gas can begin to transition into the dissolved state. In an alternative embodiment, the resident time housing 22 has a larger diameter than the cell housing 12 to provide an extended resident time for a given flow rate.
  • The invention has been described and shown for a number of alternative embodiments. As will be appreciated, equivalent structures may be substituted for those shown on herein order to achieve the objects and purposes of the invention, the invention being as broad as the appended claims and is not limited to the specific embodiments shown herein. [0033]

Claims (14)

1. An apparatus for increasing the quantity of dissolved oxygen in water comprising:
an inlet for untreated water;
a cell housing having an electrolytic cell therein coupled to the inlet, the cell housing vertically oriented and longitudinally extending for a selected vertical length above the electrolytic cell; and
an outlet fluidly connected to the cell housing for removing treated water therefrom.
2. The apparatus according to claim 1 wherein the cell housing has generally the same cross-sectional area throughout for ensuring laminar flow of water from the electrolytic cell to the vertical length extending above the electrolytic cell.
3. The apparatus according to claim 1 wherein the vertical length extending above the electrolytic cell is a straight, longitudinally extending tube having an unrestricted, constant cross-sectional area so that water may pass therethrough in laminar flow without encountering obstructions.
4. The apparatus according to claim 1 wherein the vertical length of is selected to ensure that a majority of gaseous oxygen present at the electrolytic cell transitions into dissolved oxygen before reaching the outlet.
5. The apparatus according to claim 4, further including:
a first removable coupling member attached to the housing positioned prior to the electrolytic cell; and
a second removable coupling member attached to the housing positioned after the electrolytic cell for permitting access to the electrolytic cell.
6. The apparatus according to claim 1, further including a water chill unit positioned prior to the inlet for reducing the temperature of the water.
7. The apparatus according to claim 1, further including:
an outlet tube connected to the outlet for carrying treated water;
an outlet valve connected to the outlet tube for removing treated water from the outlet tube; and
a recirculation tube coupled from the outlet tube to the inlet for recirculating the treated water through the cell housing.
8. The apparatus according to claim 7, further including a pump positioned in the recirculation tube for providing the recirculation flow of the water.
9. The apparatus according to claim 7, further including a gradual cross-sectional reduction member positioned in the outlet tube and shaped to gradually reduce the cross-sectional area from a large cross-sectional area to a smaller cross-sectional area in the outlet tube.
10. A method of increasing the quantity of dissolved oxygen in water comprising:
chilling untreated water;
passing the chilled untreated water into an electrolytic cell that generates hydrogen gas and oxygen gas from the water;
passing treated water out of the electrolytic cell, the treated water containing hydrogen and oxygen in gaseous state;
transporting the treated water for a selected resident time period to allow some of the oxygen in a gaseous state to become dissolved oxygen in the treated water to increase the dissolved oxygen content of the water.
11. (Canceled)
12. The method according to claim 10 wherein the transporting step includes:
flowing the water in a laminar flow pattern in an unrestricted tube for permitting gaseous oxygen to transition into the dissolved state without obstructions or turbulent flow in the flowing water.
13. The method according to claim 10, further including recirculating the treated water through the electrolytic cell.
14. The method according to claim 10, further including reducing the cross-sectional diameter of a flow tube positioned for water to flow therethrough, the reduction being a gradual reduction without a sudden transition so as to maintain substantial laminar flow of the volume of water passing therethrough.
US10/167,982 1997-04-11 2002-06-12 Housing and method that provide extended resident time for dissolving generated oxygen into water Abandoned US20040222106A1 (en)

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US08/827,873 US5911870A (en) 1997-04-11 1997-04-11 Housing and method that provide extended resident time for dissolving generated oxygen into water
US09/315,385 US6110353A (en) 1997-04-11 1999-05-18 Housing and method that provide extended resident time for dissolving generated oxygen into water
US65042700A 2000-08-29 2000-08-29
US10/167,982 US20040222106A1 (en) 1997-04-11 2002-06-12 Housing and method that provide extended resident time for dissolving generated oxygen into water

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* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US7654728B2 (en) 1997-10-24 2010-02-02 Revalesio Corporation System and method for therapeutic application of dissolved oxygen
US7770814B2 (en) 1997-10-24 2010-08-10 Revalesio Corporation System and method for irrigating with aerated water
US7806584B2 (en) 1997-10-24 2010-10-05 Revalesio Corporation Diffuser/emulsifier
US7832920B2 (en) 2006-10-25 2010-11-16 Revalesio Corporation Mixing device for creating an output mixture by mixing a first material and a second material
KR100999944B1 (en) 2008-10-23 2010-12-09 (주)대우건설 Treatment device of contaminated ground water
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US20140271997A1 (en) * 2013-03-12 2014-09-18 Biyoung Biotechnology Co., Ltd. Method of exchanging gas in a process of making oxygenated water
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* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
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US6296756B1 (en) 1999-09-09 2001-10-02 H20 Technologies, Ltd. Hand portable water purification system
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US6332972B1 (en) 1999-12-17 2001-12-25 H20 Technologies, Ltd. Decontamination method and system, such as an in-situ groundwater decontamination system, producing dissolved oxygen and reactive initiators
US6391184B1 (en) * 1999-12-17 2002-05-21 H2O Technologies, Ltd. Decontamination method and system, such as an in-situ groundwater decontamination system, producing dissolved oxygen and reactive initiators
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WO2003066070A1 (en) * 2002-02-06 2003-08-14 H2O Technologies, Ltd. Method and apparatus for treating water for use in improving the intestinal flora of livestock and poultry
US6358395B1 (en) 2000-08-11 2002-03-19 H20 Technologies Ltd. Under the counter water treatment system
US20030077365A1 (en) * 2001-06-28 2003-04-24 Howarth Jonathan N. Environmentally-friendly microbiological and microbiocidal control in aqueous systems
US6908636B2 (en) 2001-06-28 2005-06-21 Albermarle Corporation Microbiological control in poultry processing
US7008523B2 (en) * 2001-07-16 2006-03-07 Miox Corporation Electrolytic cell for surface and point of use disinfection
US7005075B2 (en) * 2001-07-16 2006-02-28 Miox Corporation Gas drive electrolytic cell
US6758959B2 (en) * 2002-02-12 2004-07-06 Jerry Kellgren Method and apparatus for oxygenating ground water
US7396441B2 (en) 2002-02-22 2008-07-08 Aqua Innovations, Inc. Flow-through oxygenator
USRE47092E1 (en) 2002-02-22 2018-10-23 Oxygenator Water Technologies, Inc. Flow-through oxygenator
DE20204084U1 (en) * 2002-03-13 2002-07-11 Rev22 Ag Kreuzlingen Device for treating water
JP2004122043A (en) * 2002-10-04 2004-04-22 Okumine:Kk Apparatus for manufacturing ozone water
US20060073216A1 (en) * 2002-12-26 2006-04-06 Solution Biosciences, Inc. Compositions and methods for control of bovine mastitis
US7901276B2 (en) 2003-06-24 2011-03-08 Albemarle Corporation Microbiocidal control in the processing of meat-producing four-legged animals
US7255332B2 (en) 2004-05-25 2007-08-14 The Board Of Trustees Of The University Of Arkansas System and method for dissolving gases in liquids
US9340438B2 (en) 2004-05-25 2016-05-17 Board Of Trustees Of The University Of Arkansas Systems and methods for delivering dissolved gases into force-main and gravity sewers
US9248415B2 (en) 2004-05-25 2016-02-02 Board Of Trustees Of The University Of Arkansas Systems and methods for maximizing dissolved gas concentration of a single species of gas from a mixture of multiple gases
US9315402B2 (en) 2004-05-25 2016-04-19 Board Of Trustees Of The University Of Arkansas Systems and methods for wastewater treatment
KR100796738B1 (en) * 2005-01-03 2008-01-22 배금주 Apparatus for producing water of high oxygen content having high velocity of dissolution
WO2006073249A1 (en) * 2005-01-03 2006-07-13 Keum-Joo Bae Apparatus for producing water of high oxygen content having high velocity of dissolution
JP2009518014A (en) 2005-12-01 2009-05-07 ソリユーシヨン・バイオサイエンシズ・インコーポレーテツド Fungicide control in the treatment of meat quadrupeds
US8046867B2 (en) * 2006-02-10 2011-11-01 Tennant Company Mobile surface cleaner having a sparging device
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US8025787B2 (en) 2006-02-10 2011-09-27 Tennant Company Method and apparatus for generating, applying and neutralizing an electrochemically activated liquid
US8025786B2 (en) * 2006-02-10 2011-09-27 Tennant Company Method of generating sparged, electrochemically activated liquid
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US20080041732A1 (en) * 2006-06-14 2008-02-21 Herzog David W Portable in-situ oxygenation and hydrogenation remedial system
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Citations (43)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US2468357A (en) * 1946-11-25 1949-04-26 Ual J Brown Self-energizing electrolytic corrosion preventing device
US2864750A (en) * 1953-12-01 1958-12-16 Sta Lit Lighter Company Method and apparatus for water treatment
US3523891A (en) * 1969-02-19 1970-08-11 Purity Control Inc Electrolytic sewage treatment system and process
US3654119A (en) * 1970-10-12 1972-04-04 White Water Int Ltd Oligodynamic treatment of liquids
US3728245A (en) * 1971-01-13 1973-04-17 Cole Res Corp Apparatus for treating sewage
US3819504A (en) * 1972-04-28 1974-06-25 Diamond Shamrock Corp Method of maintaining cathodes of an electrolytic cell free of deposits
US3865710A (en) * 1972-03-07 1975-02-11 Camper & Nicholsons Holdings L Purification control unit
US3925176A (en) * 1973-10-10 1975-12-09 Adolph P Okert Apparatus and method for electrolytic sewage treatment
US3943044A (en) * 1971-09-07 1976-03-09 Diamond Shamrock Corporation Method for treating sewage water
US4017375A (en) * 1975-12-15 1977-04-12 Diamond Shamrock Corporation Bipolar electrode for an electrolytic cell
US4119517A (en) * 1976-06-14 1978-10-10 Sachs-Systemtechnik Gmbh Apparatus for purifying water
US4132620A (en) * 1978-02-02 1979-01-02 Diamond Shamrock Technologies S.A. Electrocatalytic electrodes
US4160716A (en) * 1976-08-30 1979-07-10 Diamond Shamrock Corporation Method for removing an entrained gas from a liquid medium
US4180445A (en) * 1978-03-27 1979-12-25 Diamond Shamrock Corporation Oxygen selective anode
US4312736A (en) * 1979-01-17 1982-01-26 Bbc Brown, Boveri & Company, Limited Electrolysis cell for water dissolution
US4328584A (en) * 1979-03-30 1982-05-04 Telefonaktiebolaget L M Ericsson Method and arrangement for supervising signal amplitude converters
US4419206A (en) * 1980-03-12 1983-12-06 Frame James R Electronic water treating device
US4425216A (en) * 1981-05-18 1984-01-10 Neymeyer Calvin E Gas generation apparatus
US4436601A (en) * 1981-07-24 1984-03-13 Diamond Shamrock Corporation Metal removal process
US4451341A (en) * 1982-12-29 1984-05-29 Hidrotronic De Colombia, S.A. Electrolytic water sterilization system
US4528083A (en) * 1983-04-15 1985-07-09 United Technologies Corporation Device for evolution of oxygen with ternary electrocatalysts containing valve metals
US4572775A (en) * 1982-02-05 1986-02-25 Paniagua Juan G Apparatus for sterilizing fluids
US4623436A (en) * 1985-01-10 1986-11-18 Showakoki Co., Ltd. Method and apparatus for removing impurities from liquids
US4639303A (en) * 1984-10-26 1987-01-27 Hoechst Aktiengesellschaft Electrolysis apparatus with horizontally disposed electrodes
US4761208A (en) * 1986-09-29 1988-08-02 Los Alamos Technical Associates, Inc. Electrolytic method and cell for sterilizing water
US4781805A (en) * 1988-02-16 1988-11-01 Vincent Dahlgren Method for controlling pollution and reducing calcium concentration in aqueous bodies
US4783246A (en) * 1987-12-01 1988-11-08 Eltech Systems Corporation Bipolar rapid pass electrolytic hypochlorite generator
US4784735A (en) * 1986-11-25 1988-11-15 The Dow Chemical Company Concentric tube membrane electrolytic cell with an internal recycle device
US4790914A (en) * 1985-09-30 1988-12-13 The Dow Chemical Company Electrolysis process using concentric tube membrane electrolytic cell
US4797182A (en) * 1986-04-17 1989-01-10 Eltech Systems Corporation Electrode with a platinum metal catalyst in surface film and its use
US4839007A (en) * 1987-02-20 1989-06-13 Bbc Brown Boveri Ag Method for purifying industrial waste water by direct oxidation of the organic pollutants
US4917782A (en) * 1988-03-02 1990-04-17 Advanced Water Systems, Inc. Electrolytic liquid purification process and apparatus
US4936979A (en) * 1987-11-27 1990-06-26 Brown Leonard L Swimming pool bacteria and algae control system and method
US5062940A (en) * 1988-03-02 1991-11-05 Water Regeneration Systems, Inc. Electrolytic liquid purification apparatus
US5292412A (en) * 1990-04-12 1994-03-08 Eltech Systems Corporation Removal of mercury from waste streams
US5324398A (en) * 1992-06-19 1994-06-28 Water Regeneration Systems, Inc. Capacitive discharge control circuit for use with electrolytic fluid treatment systems
US5389214A (en) * 1992-06-19 1995-02-14 Water Regeneration Systems, Inc. Fluid treatment system employing electrically reconfigurable electrode arrangement
US5427667A (en) * 1992-04-03 1995-06-27 Bakhir; Vitold M. Apparatus for electrochemical treatment of water
US5460702A (en) * 1994-03-30 1995-10-24 Nogsys Technology, Inc. Apparatus and method for the purification of water
US5690797A (en) * 1995-01-18 1997-11-25 Mitsubishi Corporation Hydrogen and oxygen gas generating system
US5911870A (en) * 1997-04-11 1999-06-15 H20 Technologies, Ltd. Housing and method that provide extended resident time for dissolving generated oxygen into water
US6332972B1 (en) * 1999-12-17 2001-12-25 H20 Technologies, Ltd. Decontamination method and system, such as an in-situ groundwater decontamination system, producing dissolved oxygen and reactive initiators
US6391184B1 (en) * 1999-12-17 2002-05-21 H2O Technologies, Ltd. Decontamination method and system, such as an in-situ groundwater decontamination system, producing dissolved oxygen and reactive initiators

Family Cites Families (5)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
DE2620634A1 (en) * 1976-05-10 1977-11-24 Paul Liesenhoff Treatment of sewage with oxygen in closed pipe - allowing use of compact appts. giving less noise as no aeration surface is exposed
DE3639572A1 (en) * 1986-11-20 1988-05-26 Anna Kursa Method for introducing gas into waste waters
DE3901321C1 (en) * 1989-01-18 1990-05-31 Emda Fabrik Elektro-Medizinischer Und Dentaler Apparate Georg Hartmann Gmbh & Co Kg, 6000 Frankfurt, De Apparatus for sterilising water by anodic oxidation
US5328584A (en) * 1992-06-19 1994-07-12 Water Regeneration Systems, Inc. Passive circulation in electrolytic fluid treatment systems
AU1874495A (en) * 1994-02-10 1995-08-29 Bruce Davies Electrocatalytic dissolved oxygen generator for water processing

Patent Citations (44)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US2468357A (en) * 1946-11-25 1949-04-26 Ual J Brown Self-energizing electrolytic corrosion preventing device
US2864750A (en) * 1953-12-01 1958-12-16 Sta Lit Lighter Company Method and apparatus for water treatment
US3523891A (en) * 1969-02-19 1970-08-11 Purity Control Inc Electrolytic sewage treatment system and process
US3654119A (en) * 1970-10-12 1972-04-04 White Water Int Ltd Oligodynamic treatment of liquids
US3728245A (en) * 1971-01-13 1973-04-17 Cole Res Corp Apparatus for treating sewage
US3943044A (en) * 1971-09-07 1976-03-09 Diamond Shamrock Corporation Method for treating sewage water
US3865710A (en) * 1972-03-07 1975-02-11 Camper & Nicholsons Holdings L Purification control unit
US3819504A (en) * 1972-04-28 1974-06-25 Diamond Shamrock Corp Method of maintaining cathodes of an electrolytic cell free of deposits
US3925176A (en) * 1973-10-10 1975-12-09 Adolph P Okert Apparatus and method for electrolytic sewage treatment
US4017375A (en) * 1975-12-15 1977-04-12 Diamond Shamrock Corporation Bipolar electrode for an electrolytic cell
US4119517A (en) * 1976-06-14 1978-10-10 Sachs-Systemtechnik Gmbh Apparatus for purifying water
US4160716A (en) * 1976-08-30 1979-07-10 Diamond Shamrock Corporation Method for removing an entrained gas from a liquid medium
US4132620A (en) * 1978-02-02 1979-01-02 Diamond Shamrock Technologies S.A. Electrocatalytic electrodes
US4180445A (en) * 1978-03-27 1979-12-25 Diamond Shamrock Corporation Oxygen selective anode
US4312736A (en) * 1979-01-17 1982-01-26 Bbc Brown, Boveri & Company, Limited Electrolysis cell for water dissolution
US4328584A (en) * 1979-03-30 1982-05-04 Telefonaktiebolaget L M Ericsson Method and arrangement for supervising signal amplitude converters
US4419206A (en) * 1980-03-12 1983-12-06 Frame James R Electronic water treating device
US4425216A (en) * 1981-05-18 1984-01-10 Neymeyer Calvin E Gas generation apparatus
US4436601A (en) * 1981-07-24 1984-03-13 Diamond Shamrock Corporation Metal removal process
US4572775A (en) * 1982-02-05 1986-02-25 Paniagua Juan G Apparatus for sterilizing fluids
US4451341A (en) * 1982-12-29 1984-05-29 Hidrotronic De Colombia, S.A. Electrolytic water sterilization system
US4528083A (en) * 1983-04-15 1985-07-09 United Technologies Corporation Device for evolution of oxygen with ternary electrocatalysts containing valve metals
US4639303A (en) * 1984-10-26 1987-01-27 Hoechst Aktiengesellschaft Electrolysis apparatus with horizontally disposed electrodes
US4623436A (en) * 1985-01-10 1986-11-18 Showakoki Co., Ltd. Method and apparatus for removing impurities from liquids
US4790914A (en) * 1985-09-30 1988-12-13 The Dow Chemical Company Electrolysis process using concentric tube membrane electrolytic cell
US4797182A (en) * 1986-04-17 1989-01-10 Eltech Systems Corporation Electrode with a platinum metal catalyst in surface film and its use
US4761208A (en) * 1986-09-29 1988-08-02 Los Alamos Technical Associates, Inc. Electrolytic method and cell for sterilizing water
US4784735A (en) * 1986-11-25 1988-11-15 The Dow Chemical Company Concentric tube membrane electrolytic cell with an internal recycle device
US4839007A (en) * 1987-02-20 1989-06-13 Bbc Brown Boveri Ag Method for purifying industrial waste water by direct oxidation of the organic pollutants
US4936979A (en) * 1987-11-27 1990-06-26 Brown Leonard L Swimming pool bacteria and algae control system and method
US4783246A (en) * 1987-12-01 1988-11-08 Eltech Systems Corporation Bipolar rapid pass electrolytic hypochlorite generator
US4781805A (en) * 1988-02-16 1988-11-01 Vincent Dahlgren Method for controlling pollution and reducing calcium concentration in aqueous bodies
US4917782A (en) * 1988-03-02 1990-04-17 Advanced Water Systems, Inc. Electrolytic liquid purification process and apparatus
US5062940A (en) * 1988-03-02 1991-11-05 Water Regeneration Systems, Inc. Electrolytic liquid purification apparatus
US5292412A (en) * 1990-04-12 1994-03-08 Eltech Systems Corporation Removal of mercury from waste streams
US5427667A (en) * 1992-04-03 1995-06-27 Bakhir; Vitold M. Apparatus for electrochemical treatment of water
US5324398A (en) * 1992-06-19 1994-06-28 Water Regeneration Systems, Inc. Capacitive discharge control circuit for use with electrolytic fluid treatment systems
US5389214A (en) * 1992-06-19 1995-02-14 Water Regeneration Systems, Inc. Fluid treatment system employing electrically reconfigurable electrode arrangement
US5460702A (en) * 1994-03-30 1995-10-24 Nogsys Technology, Inc. Apparatus and method for the purification of water
US5690797A (en) * 1995-01-18 1997-11-25 Mitsubishi Corporation Hydrogen and oxygen gas generating system
US5911870A (en) * 1997-04-11 1999-06-15 H20 Technologies, Ltd. Housing and method that provide extended resident time for dissolving generated oxygen into water
US6110353A (en) * 1997-04-11 2000-08-29 H20 Technologies, Ltd. Housing and method that provide extended resident time for dissolving generated oxygen into water
US6332972B1 (en) * 1999-12-17 2001-12-25 H20 Technologies, Ltd. Decontamination method and system, such as an in-situ groundwater decontamination system, producing dissolved oxygen and reactive initiators
US6391184B1 (en) * 1999-12-17 2002-05-21 H2O Technologies, Ltd. Decontamination method and system, such as an in-situ groundwater decontamination system, producing dissolved oxygen and reactive initiators

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US7654728B2 (en) 1997-10-24 2010-02-02 Revalesio Corporation System and method for therapeutic application of dissolved oxygen
US7887698B2 (en) 1997-10-24 2011-02-15 Revalesio Corporation Diffuser/emulsifier for aquaculture applications
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US8962700B2 (en) 2006-10-25 2015-02-24 Revalesio Corporation Electrokinetically-altered fluids comprising charge-stabilized gas-containing nanostructures
US7832920B2 (en) 2006-10-25 2010-11-16 Revalesio Corporation Mixing device for creating an output mixture by mixing a first material and a second material
US9004743B2 (en) 2006-10-25 2015-04-14 Revalesio Corporation Mixing device for creating an output mixture by mixing a first material and a second material
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US8980325B2 (en) 2008-05-01 2015-03-17 Revalesio Corporation Compositions and methods for treating digestive disorders
KR100999944B1 (en) 2008-10-23 2010-12-09 (주)대우건설 Treatment device of contaminated ground water
US9011922B2 (en) 2009-04-27 2015-04-21 Revalesio Corporation Compositions and methods for treating insulin resistance and diabetes mellitus
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US8974646B2 (en) 2010-05-03 2015-03-10 Ilbong Kim Portable hydrogen-rich water generator
US9198929B2 (en) 2010-05-07 2015-12-01 Revalesio Corporation Compositions and methods for enhancing physiological performance and recovery time
US9492404B2 (en) 2010-08-12 2016-11-15 Revalesio Corporation Compositions and methods for treatment of taupathy
US20140271997A1 (en) * 2013-03-12 2014-09-18 Biyoung Biotechnology Co., Ltd. Method of exchanging gas in a process of making oxygenated water

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US5911870A (en) 1999-06-15
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