US20050127421A1 - Semiconductor module having an insulation layer and method for fabricating a semiconductor module having an insulation layer - Google Patents
Semiconductor module having an insulation layer and method for fabricating a semiconductor module having an insulation layer Download PDFInfo
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- US20050127421A1 US20050127421A1 US10/502,930 US50293005A US2005127421A1 US 20050127421 A1 US20050127421 A1 US 20050127421A1 US 50293005 A US50293005 A US 50293005A US 2005127421 A1 US2005127421 A1 US 2005127421A1
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- 238000009413 insulation Methods 0.000 title claims abstract description 37
- 239000004065 semiconductor Substances 0.000 title claims abstract description 23
- 238000000034 method Methods 0.000 title claims description 9
- 239000000463 material Substances 0.000 claims abstract description 27
- VYPSYNLAJGMNEJ-UHFFFAOYSA-N Silicium dioxide Chemical compound O=[Si]=O VYPSYNLAJGMNEJ-UHFFFAOYSA-N 0.000 claims abstract description 17
- 229910052681 coesite Inorganic materials 0.000 claims abstract description 7
- 229910052906 cristobalite Inorganic materials 0.000 claims abstract description 7
- 239000000377 silicon dioxide Substances 0.000 claims abstract description 7
- 229910052682 stishovite Inorganic materials 0.000 claims abstract description 7
- 229910052905 tridymite Inorganic materials 0.000 claims abstract description 7
- 239000003989 dielectric material Substances 0.000 claims abstract description 6
- 239000002210 silicon-based material Substances 0.000 claims abstract description 4
- 239000003990 capacitor Substances 0.000 claims description 21
- 229910001508 alkali metal halide Inorganic materials 0.000 claims description 4
- -1 alkali metal halide compound Chemical class 0.000 claims description 3
- 229910052814 silicon oxide Inorganic materials 0.000 claims description 3
- 150000003388 sodium compounds Chemical class 0.000 claims 1
- PQXKHYXIUOZZFA-UHFFFAOYSA-M lithium fluoride Chemical compound [Li+].[F-] PQXKHYXIUOZZFA-UHFFFAOYSA-M 0.000 abstract description 7
- XUIMIQQOPSSXEZ-UHFFFAOYSA-N Silicon Chemical compound [Si] XUIMIQQOPSSXEZ-UHFFFAOYSA-N 0.000 description 11
- 229910052710 silicon Inorganic materials 0.000 description 11
- 239000010703 silicon Substances 0.000 description 11
- PNEYBMLMFCGWSK-UHFFFAOYSA-N Alumina Chemical compound [O-2].[O-2].[O-2].[Al+3].[Al+3] PNEYBMLMFCGWSK-UHFFFAOYSA-N 0.000 description 6
- 238000010276 construction Methods 0.000 description 6
- 239000000758 substrate Substances 0.000 description 6
- PUZPDOWCWNUUKD-UHFFFAOYSA-M sodium fluoride Chemical compound [F-].[Na+] PUZPDOWCWNUUKD-UHFFFAOYSA-M 0.000 description 5
- OYLGJCQECKOTOL-UHFFFAOYSA-L barium fluoride Chemical compound [F-].[F-].[Ba+2] OYLGJCQECKOTOL-UHFFFAOYSA-L 0.000 description 4
- 229910001632 barium fluoride Inorganic materials 0.000 description 4
- WUKWITHWXAAZEY-UHFFFAOYSA-L calcium difluoride Chemical compound [F-].[F-].[Ca+2] WUKWITHWXAAZEY-UHFFFAOYSA-L 0.000 description 4
- 229910001634 calcium fluoride Inorganic materials 0.000 description 4
- 239000012212 insulator Substances 0.000 description 4
- ORUIBWPALBXDOA-UHFFFAOYSA-L magnesium fluoride Chemical compound [F-].[F-].[Mg+2] ORUIBWPALBXDOA-UHFFFAOYSA-L 0.000 description 4
- 229910001635 magnesium fluoride Inorganic materials 0.000 description 4
- 238000000231 atomic layer deposition Methods 0.000 description 2
- 238000000151 deposition Methods 0.000 description 2
- 238000004519 manufacturing process Methods 0.000 description 2
- 229910052751 metal Inorganic materials 0.000 description 2
- 239000002184 metal Substances 0.000 description 2
- 239000000203 mixture Substances 0.000 description 2
- 229910021420 polycrystalline silicon Inorganic materials 0.000 description 2
- 229920005591 polysilicon Polymers 0.000 description 2
- 235000013024 sodium fluoride Nutrition 0.000 description 2
- 239000011775 sodium fluoride Substances 0.000 description 2
- 238000003860 storage Methods 0.000 description 2
- 229910004205 SiNX Inorganic materials 0.000 description 1
- 150000008045 alkali metal halides Chemical class 0.000 description 1
- 239000002800 charge carrier Substances 0.000 description 1
- 238000005229 chemical vapour deposition Methods 0.000 description 1
- 230000008021 deposition Effects 0.000 description 1
- 238000005516 engineering process Methods 0.000 description 1
- 230000005669 field effect Effects 0.000 description 1
- 150000004673 fluoride salts Chemical class 0.000 description 1
- 150000002222 fluorine compounds Chemical class 0.000 description 1
- 229910000449 hafnium oxide Inorganic materials 0.000 description 1
- WIHZLLGSGQNAGK-UHFFFAOYSA-N hafnium(4+);oxygen(2-) Chemical compound [O-2].[O-2].[Hf+4] WIHZLLGSGQNAGK-UHFFFAOYSA-N 0.000 description 1
- 230000010354 integration Effects 0.000 description 1
- 229910001512 metal fluoride Inorganic materials 0.000 description 1
- 229910052755 nonmetal Inorganic materials 0.000 description 1
- 150000002843 nonmetals Chemical class 0.000 description 1
- RVTZCBVAJQQJTK-UHFFFAOYSA-N oxygen(2-);zirconium(4+) Chemical compound [O-2].[O-2].[Zr+4] RVTZCBVAJQQJTK-UHFFFAOYSA-N 0.000 description 1
- 230000000704 physical effect Effects 0.000 description 1
- 229910001928 zirconium oxide Inorganic materials 0.000 description 1
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- H—ELECTRICITY
- H01—ELECTRIC ELEMENTS
- H01L—SEMICONDUCTOR DEVICES NOT COVERED BY CLASS H10
- H01L21/00—Processes or apparatus adapted for the manufacture or treatment of semiconductor or solid state devices or of parts thereof
- H01L21/02—Manufacture or treatment of semiconductor devices or of parts thereof
- H01L21/04—Manufacture or treatment of semiconductor devices or of parts thereof the devices having at least one potential-jump barrier or surface barrier, e.g. PN junction, depletion layer or carrier concentration layer
- H01L21/18—Manufacture or treatment of semiconductor devices or of parts thereof the devices having at least one potential-jump barrier or surface barrier, e.g. PN junction, depletion layer or carrier concentration layer the devices having semiconductor bodies comprising elements of Group IV of the Periodic System or AIIIBV compounds with or without impurities, e.g. doping materials
- H01L21/28—Manufacture of electrodes on semiconductor bodies using processes or apparatus not provided for in groups H01L21/20 - H01L21/268
- H01L21/28008—Making conductor-insulator-semiconductor electrodes
- H01L21/28017—Making conductor-insulator-semiconductor electrodes the insulator being formed after the semiconductor body, the semiconductor being silicon
- H01L21/28158—Making the insulator
- H01L21/28167—Making the insulator on single crystalline silicon, e.g. using a liquid, i.e. chemical oxidation
- H01L21/28194—Making the insulator on single crystalline silicon, e.g. using a liquid, i.e. chemical oxidation by deposition, e.g. evaporation, ALD, CVD, sputtering, laser deposition
-
- H—ELECTRICITY
- H01—ELECTRIC ELEMENTS
- H01L—SEMICONDUCTOR DEVICES NOT COVERED BY CLASS H10
- H01L28/00—Passive two-terminal components without a potential-jump or surface barrier for integrated circuits; Details thereof; Multistep manufacturing processes therefor
- H01L28/40—Capacitors
-
- H—ELECTRICITY
- H01—ELECTRIC ELEMENTS
- H01L—SEMICONDUCTOR DEVICES NOT COVERED BY CLASS H10
- H01L29/00—Semiconductor devices adapted for rectifying, amplifying, oscillating or switching, or capacitors or resistors with at least one potential-jump barrier or surface barrier, e.g. PN junction depletion layer or carrier concentration layer; Details of semiconductor bodies or of electrodes thereof ; Multistep manufacturing processes therefor
- H01L29/40—Electrodes ; Multistep manufacturing processes therefor
- H01L29/43—Electrodes ; Multistep manufacturing processes therefor characterised by the materials of which they are formed
- H01L29/49—Metal-insulator-semiconductor electrodes, e.g. gates of MOSFET
- H01L29/51—Insulating materials associated therewith
- H01L29/517—Insulating materials associated therewith the insulating material comprising a metallic compound, e.g. metal oxide, metal silicate
-
- H—ELECTRICITY
- H10—SEMICONDUCTOR DEVICES; ELECTRIC SOLID-STATE DEVICES NOT OTHERWISE PROVIDED FOR
- H10B—ELECTRONIC MEMORY DEVICES
- H10B12/00—Dynamic random access memory [DRAM] devices
- H10B12/01—Manufacture or treatment
- H10B12/02—Manufacture or treatment for one transistor one-capacitor [1T-1C] memory cells
- H10B12/03—Making the capacitor or connections thereto
-
- H—ELECTRICITY
- H01—ELECTRIC ELEMENTS
- H01L—SEMICONDUCTOR DEVICES NOT COVERED BY CLASS H10
- H01L21/00—Processes or apparatus adapted for the manufacture or treatment of semiconductor or solid state devices or of parts thereof
- H01L21/02—Manufacture or treatment of semiconductor devices or of parts thereof
- H01L21/02104—Forming layers
- H01L21/02107—Forming insulating materials on a substrate
- H01L21/02109—Forming insulating materials on a substrate characterised by the type of layer, e.g. type of material, porous/non-porous, pre-cursors, mixtures or laminates
- H01L21/02112—Forming insulating materials on a substrate characterised by the type of layer, e.g. type of material, porous/non-porous, pre-cursors, mixtures or laminates characterised by the material of the layer
- H01L21/02172—Forming insulating materials on a substrate characterised by the type of layer, e.g. type of material, porous/non-porous, pre-cursors, mixtures or laminates characterised by the material of the layer the material containing at least one metal element, e.g. metal oxides, metal nitrides, metal oxynitrides or metal carbides
- H01L21/02175—Forming insulating materials on a substrate characterised by the type of layer, e.g. type of material, porous/non-porous, pre-cursors, mixtures or laminates characterised by the material of the layer the material containing at least one metal element, e.g. metal oxides, metal nitrides, metal oxynitrides or metal carbides characterised by the metal
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- H—ELECTRICITY
- H01—ELECTRIC ELEMENTS
- H01L—SEMICONDUCTOR DEVICES NOT COVERED BY CLASS H10
- H01L21/00—Processes or apparatus adapted for the manufacture or treatment of semiconductor or solid state devices or of parts thereof
- H01L21/02—Manufacture or treatment of semiconductor devices or of parts thereof
- H01L21/02104—Forming layers
- H01L21/02107—Forming insulating materials on a substrate
- H01L21/02225—Forming insulating materials on a substrate characterised by the process for the formation of the insulating layer
- H01L21/0226—Forming insulating materials on a substrate characterised by the process for the formation of the insulating layer formation by a deposition process
- H01L21/02282—Forming insulating materials on a substrate characterised by the process for the formation of the insulating layer formation by a deposition process liquid deposition, e.g. spin-coating, sol-gel techniques, spray coating
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- H—ELECTRICITY
- H01—ELECTRIC ELEMENTS
- H01L—SEMICONDUCTOR DEVICES NOT COVERED BY CLASS H10
- H01L21/00—Processes or apparatus adapted for the manufacture or treatment of semiconductor or solid state devices or of parts thereof
- H01L21/02—Manufacture or treatment of semiconductor devices or of parts thereof
- H01L21/04—Manufacture or treatment of semiconductor devices or of parts thereof the devices having at least one potential-jump barrier or surface barrier, e.g. PN junction, depletion layer or carrier concentration layer
- H01L21/18—Manufacture or treatment of semiconductor devices or of parts thereof the devices having at least one potential-jump barrier or surface barrier, e.g. PN junction, depletion layer or carrier concentration layer the devices having semiconductor bodies comprising elements of Group IV of the Periodic System or AIIIBV compounds with or without impurities, e.g. doping materials
- H01L21/30—Treatment of semiconductor bodies using processes or apparatus not provided for in groups H01L21/20 - H01L21/26
- H01L21/31—Treatment of semiconductor bodies using processes or apparatus not provided for in groups H01L21/20 - H01L21/26 to form insulating layers thereon, e.g. for masking or by using photolithographic techniques; After treatment of these layers; Selection of materials for these layers
- H01L21/314—Inorganic layers
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- H—ELECTRICITY
- H10—SEMICONDUCTOR DEVICES; ELECTRIC SOLID-STATE DEVICES NOT OTHERWISE PROVIDED FOR
- H10B—ELECTRONIC MEMORY DEVICES
- H10B12/00—Dynamic random access memory [DRAM] devices
- H10B12/01—Manufacture or treatment
- H10B12/02—Manufacture or treatment for one transistor one-capacitor [1T-1C] memory cells
- H10B12/03—Making the capacitor or connections thereto
- H10B12/038—Making the capacitor or connections thereto the capacitor being in a trench in the substrate
-
- H—ELECTRICITY
- H10—SEMICONDUCTOR DEVICES; ELECTRIC SOLID-STATE DEVICES NOT OTHERWISE PROVIDED FOR
- H10B—ELECTRONIC MEMORY DEVICES
- H10B12/00—Dynamic random access memory [DRAM] devices
- H10B12/01—Manufacture or treatment
- H10B12/02—Manufacture or treatment for one transistor one-capacitor [1T-1C] memory cells
- H10B12/05—Making the transistor
Definitions
- the invention relates to a semiconductor module, and in particular, to a module having an insulation layer and a method for fabricating same.
- a memory module has a multiplicity of memory cells which, in a simple embodiment, are formed from one transistor and one capacitor.
- the storage capacitor has, by way of example, a storage electrode, an insulating intermediate layer and a counterelectrode.
- transistors having an insulated gate electrode are used in the construction of electronic circuits.
- the increasing integration density requires a miniaturization of the geometries of the memory cell and of the transistor. However, this leads to a smaller capacitor area, which corresponds to a smaller capacitor capacitance.
- a minimum capacitance can be complied with by making the insulating intermediate layer thinner, increasing the surface charge density of the capacitor area by means of alternative dielectrics, or increasing the capacitor area by means of suitable measures e.g. HSG (Hemispherical Silicon Grains). Materials having a higher dielectric constant than silicon oxide such as e.g. aluminium oxide, zirconium oxide or hafnium oxide, are currently being used as alternative dielectrics. In the case of the transistor, the miniaturization of the geometries leads to a thinner gate oxide layer, as a result of which the risk of electrical voltage flashovers and leakage currents is increased.
- the invention provides a semiconductor module having improved electrical properties and a method for fabricating a semiconductor module.
- a semiconductor module essentially comprising silicon, which has an insulation layer which is constructed from a dielectric material whose band gap is greater than that of SiO 2 .
- the insulation layer is preferably used as a gate insulation layer or as an insulation layer of a capacitor.
- the material according to the invention is suitable for forming insulation layers which have a relatively small leakage current and are robust with respect to voltage flashovers.
- insulation layers for example in the case of a memory cell or in the case of a field-effect transistor, can be made thinner than when using SiO x or SiN x or combinations thereof, and the surface charge density can thus be increased.
- insulator layers can be made thinner for the same leakage current.
- Alkali metal halides or other metal-halogen compounds are preferably suitable for forming the insulation layer according to the invention.
- Metal-fluorine compounds are suitable, in particular. Lithium fluoride, calcium fluoride, barium fluoride, magnesium fluoride or sodium fluoride is preferably used as the material.
- the abovementioned metal-fluorine compounds can be applied by means of epitaxial methods in the corresponding dimensions and patterned. Consequently, the metal-fluorine compounds are suitable for constructing an insulation layer which are used in particular in the fabrication of a semiconductor module constructed using silicon technology.
- FIG. 1 shows a memory cell
- FIG. 2 shows a MOS transistor
- FIG. 3 shows a table with preferred materials.
- FIG. 1 shows the construction of a memory cell of a dynamic memory module in a diagrammatic illustration.
- the dynamic memory module has a multiplicity of memory cells which can be individually addressed via word lines and bit lines and selection transistors.
- the information held in the memory module is stored in the form of an electrical charge in the memory cell.
- the memory cell is constructed in the form of a trench capacitor.
- the trench capacitor stores an electrical charge which corresponds to a value of the information 0 or 1.
- a different type of capacitor such as e.g. a stacked capacitor.
- FIG. 1 shows a silicon substrate 1 , into which is introduced a trench 2 surrounded with a first doping layer 3 .
- An insulation layer 4 is formed in the trench 2 in a manner adjoining the first doping layer 3 .
- the insulation layer 4 surrounds a conduction layer 5 which fills a large part of the trench 2 .
- the first doping layer 3 and the conduction layer 5 constitute two capacitor areas.
- the insulation layer 4 constitutes a dielectric layer arranged between the capacitor areas.
- the silicon substrate 1 is positively doped in the exemplary embodiment illustrated.
- the first doping layer 3 is highly negatively doped and the conduction layer 5 is constructed from a negatively doped polysilicon material.
- the first doping layer 3 is connected to a bit line via a selection transistor, which can be driven via a word line. By means of corresponding driving of the selection transistor, the charge stored in the memory cell is transferred to the bit line. From the bit line, the charge is amplified by means of an output amplifier and output via output drivers to an output of
- the dielectric insulation layer 4 preferably comprises a material whose band gap is greater than that of SiO 2 (9.9 eV).
- the material used preferably has a dielectric constant which is likewise greater than that of SiO 2 or SiN or mixtures of the materials.
- Materials having an alkali metal halide compound are preferably used for the construction of the insulation layer 4 , 8 .
- metal fluoride compounds are suitable for the construction of the insulation layer.
- Lithium fluoride (LiF), calcium fluoride (CaF), barium fluoride (BaF), magnesium fluoride (MgF) and sodium fluoride (NaF) are suitable for fabricating the insulation layer 4 , 8 on account of the physical properties.
- Deposition methods such as e.g. chemical vapour deposition methods or ALD methods (Atomic Layer Deposition) are used as preferred fabrication method.
- Corresponding methods and the deposition of the abovementioned fluorine compounds are known to the person skilled in the art and described for example in “CVD of non-metals”, William S. Reeves, New York, VCH 1996, ISBN 3-527-29295-0” in Chapter 7.1 ff.
- FIG. 2 shows a cross section through an integrated circuit of a semiconductor module which has a silicon substrate 1 , into which a third and a fourth doping layer 6 , 7 are introduced. Between the third and fourth doping layers 6 , 7 , a gate oxide layer 8 is applied on the silicon substrate 1 . A conductive contact layer 9 is formed on the gate oxide layer 8 .
- the silicon substrate 1 is positively doped.
- the third and fourth doping layers 6 , 7 constitute negatively doped silicon regions.
- the gate oxide layer 8 is formed as an insulation layer which may be constructed from the same materials as the insulation layer 4 of the memory cell of FIG. 1 .
- the contact layer 9 comprises a highly doped polysilicon material, metal or silicon/metal combinations. The dopings may also be formed in inverse fashion (p-type or n-type transistor).
- the semiconductor structure illustrated in FIG. 2 shows a MOS transistor having the third and fourth doping layers 6 , 7 as terminals and the contact layer 9 as gate terminal.
- the gate oxide layer 8 can be made very thin without large creepage currents or electrical damage to the gate oxide layer 8 occurring.
- the dopings may also be inverse dopings. With increasing miniaturization, thinner layers are also possible.
- the insulator layer can be made thinner than when using SiO 2 for the same leakage current, or with a lower leakage current for the same thickness.
- FIG. 3 shows a table with characteristic parameters of a selection of materials which are suitable for the construction of the insulation layer according to the invention.
- Lithium fluoride has a band gap of about 14 electronvolts and a dielectric constant of 9 .
- Calcium fluoride has a band gap of about 13 electronvolts and a dielectric constant of 6.8.
- Barium fluoride has a band gap of about 11 electronvolts and a dielectric constant of 7.3.
- Magnesium fluoride has a band gap of about 14 electronvolts and a dielectric constant in the region of 5.
- Sodium fluoride has a band gap of about 12 electronvolts and a dielectric constant of 6.
- combinations with other materials such as e.g. aluminium oxide, for forming the insulation layer.
- the insulation layer is applied in the form of a plurality of layers.
- the invention explained above uses the example of a memory cell of a dynamic memory module and a MOS transistor.
- the invention is not restricted to these circuits, but rather can be used for any type of circuit which is preferably constructed from a silicon material and in which a robust insulation layer is required.
- the insulation layer according to the invention can be used for any type of capacitor.
Abstract
A semiconductor module is described which is essentially constructed from a silicon material and has an insulation layer for example in the form of a gate insulation layer or a MOS transistor or in the form of an insulation layer of a memory cell for a dynamic memory module. The insulation layer preferably comprises a dielectric material whose band gap is greater than the band gap of SiO2. To construct the insulation layer, use is made of materials which have a metal-fluorine compound, such as e.g. lithium fluoride. Particularly thin insulation layers are provided by the material described.
Description
- This application is a national stage application under 371 of PCT/EP03/00377, filed on Jan. 16, 2003, which claims the benefit of priority to German Application No. 102 03 674.8, which was filed on Jan. 30, 2002.
- The invention relates to a semiconductor module, and in particular, to a module having an insulation layer and a method for fabricating same.
- Semiconductor modules are used to produce electronic integrated circuits. Basic elements such as e.g. capacitors and transistors are used in this case. Insulator layers are particularly critical in this case, which layers must have specific properties with regard to capacitance and leakage current. A memory module has a multiplicity of memory cells which, in a simple embodiment, are formed from one transistor and one capacitor. The storage capacitor has, by way of example, a storage electrode, an insulating intermediate layer and a counterelectrode. Furthermore, transistors having an insulated gate electrode are used in the construction of electronic circuits. The increasing integration density requires a miniaturization of the geometries of the memory cell and of the transistor. However, this leads to a smaller capacitor area, which corresponds to a smaller capacitor capacitance. For a functional memory cell, however, it is necessary to comply with a minimum capacitance. A minimum capacitance can be complied with by making the insulating intermediate layer thinner, increasing the surface charge density of the capacitor area by means of alternative dielectrics, or increasing the capacitor area by means of suitable measures e.g. HSG (Hemispherical Silicon Grains). Materials having a higher dielectric constant than silicon oxide such as e.g. aluminium oxide, zirconium oxide or hafnium oxide, are currently being used as alternative dielectrics. In the case of the transistor, the miniaturization of the geometries leads to a thinner gate oxide layer, as a result of which the risk of electrical voltage flashovers and leakage currents is increased.
- The invention provides a semiconductor module having improved electrical properties and a method for fabricating a semiconductor module.
- In one embodiment of the invention, there is a semiconductor module essentially comprising silicon, which has an insulation layer which is constructed from a dielectric material whose band gap is greater than that of SiO2. The insulation layer is preferably used as a gate insulation layer or as an insulation layer of a capacitor. On account of the large band gap, the material according to the invention is suitable for forming insulation layers which have a relatively small leakage current and are robust with respect to voltage flashovers. As a result, insulation layers, for example in the case of a memory cell or in the case of a field-effect transistor, can be made thinner than when using SiOx or SiNx or combinations thereof, and the surface charge density can thus be increased.
- In contrast to materials having larger dielectric constants, with the materials according to the invention which have a larger band gap for positive and negative charge carriers, insulator layers can be made thinner for the same leakage current.
- Alkali metal halides or other metal-halogen compounds are preferably suitable for forming the insulation layer according to the invention.
- Metal-fluorine compounds are suitable, in particular. Lithium fluoride, calcium fluoride, barium fluoride, magnesium fluoride or sodium fluoride is preferably used as the material. The abovementioned metal-fluorine compounds can be applied by means of epitaxial methods in the corresponding dimensions and patterned. Consequently, the metal-fluorine compounds are suitable for constructing an insulation layer which are used in particular in the fabrication of a semiconductor module constructed using silicon technology.
- The invention is explained in more detail below with reference to the figures, in which:
-
FIG. 1 shows a memory cell. -
FIG. 2 shows a MOS transistor. -
FIG. 3 shows a table with preferred materials. -
FIG. 1 shows the construction of a memory cell of a dynamic memory module in a diagrammatic illustration. The dynamic memory module has a multiplicity of memory cells which can be individually addressed via word lines and bit lines and selection transistors. The information held in the memory module is stored in the form of an electrical charge in the memory cell. The memory cell is constructed in the form of a trench capacitor. The trench capacitor stores an electrical charge which corresponds to a value of the information 0 or 1. Instead of a trench capacitor, it is also possible to use a different type of capacitor such as e.g. a stacked capacitor. -
FIG. 1 shows a silicon substrate 1, into which is introduced atrench 2 surrounded with afirst doping layer 3. Aninsulation layer 4 is formed in thetrench 2 in a manner adjoining thefirst doping layer 3. Theinsulation layer 4 surrounds aconduction layer 5 which fills a large part of thetrench 2. Thefirst doping layer 3 and theconduction layer 5 constitute two capacitor areas. Theinsulation layer 4 constitutes a dielectric layer arranged between the capacitor areas. The silicon substrate 1 is positively doped in the exemplary embodiment illustrated. Thefirst doping layer 3 is highly negatively doped and theconduction layer 5 is constructed from a negatively doped polysilicon material. Thefirst doping layer 3 is connected to a bit line via a selection transistor, which can be driven via a word line. By means of corresponding driving of the selection transistor, the charge stored in the memory cell is transferred to the bit line. From the bit line, the charge is amplified by means of an output amplifier and output via output drivers to an output of the memory module. - The
dielectric insulation layer 4 preferably comprises a material whose band gap is greater than that of SiO2 (9.9 eV). The material used preferably has a dielectric constant which is likewise greater than that of SiO2 or SiN or mixtures of the materials. Materials having an alkali metal halide compound are preferably used for the construction of theinsulation layer - Lithium fluoride (LiF), calcium fluoride (CaF), barium fluoride (BaF), magnesium fluoride (MgF) and sodium fluoride (NaF) are suitable for fabricating the
insulation layer -
FIG. 2 shows a cross section through an integrated circuit of a semiconductor module which has a silicon substrate 1, into which a third and afourth doping layer fourth doping layers gate oxide layer 8 is applied on the silicon substrate 1. Aconductive contact layer 9 is formed on thegate oxide layer 8. The silicon substrate 1 is positively doped. The third andfourth doping layers gate oxide layer 8 is formed as an insulation layer which may be constructed from the same materials as theinsulation layer 4 of the memory cell ofFIG. 1 . Thecontact layer 9 comprises a highly doped polysilicon material, metal or silicon/metal combinations. The dopings may also be formed in inverse fashion (p-type or n-type transistor). - The semiconductor structure illustrated in
FIG. 2 shows a MOS transistor having the third and fourth doping layers 6, 7 as terminals and thecontact layer 9 as gate terminal. On account of the preferred materials described above, thegate oxide layer 8 can be made very thin without large creepage currents or electrical damage to thegate oxide layer 8 occurring. - The dopings may also be inverse dopings. With increasing miniaturization, thinner layers are also possible.
- On account of the materials according to the invention, the insulator layer can be made thinner than when using SiO2 for the same leakage current, or with a lower leakage current for the same thickness.
-
FIG. 3 shows a table with characteristic parameters of a selection of materials which are suitable for the construction of the insulation layer according to the invention. - Lithium fluoride has a band gap of about 14 electronvolts and a dielectric constant of 9. Calcium fluoride has a band gap of about 13 electronvolts and a dielectric constant of 6.8. Barium fluoride has a band gap of about 11 electronvolts and a dielectric constant of 7.3. Magnesium fluoride has a band gap of about 14 electronvolts and a dielectric constant in the region of 5. Sodium fluoride has a band gap of about 12 electronvolts and a dielectric constant of 6. Depending on the embodiment, it is also possible to use mixtures or combinations of the materials according to the invention for the construction of an insulator layer. Furthermore, it is also possible to use combinations with other materials, such as e.g. aluminium oxide, for forming the insulation layer. In this case, the insulation layer is applied in the form of a plurality of layers.
- The invention explained above uses the example of a memory cell of a dynamic memory module and a MOS transistor. However, the invention is not restricted to these circuits, but rather can be used for any type of circuit which is preferably constructed from a silicon material and in which a robust insulation layer is required. The insulation layer according to the invention can be used for any type of capacitor.
- 1 Silicon substrate
- 2 Trench
- 3 1st doping layer
- 4 Insulation layer
- 5 Conduction layer
- 6 3rd doping layer
- 7 4th doping layer
- 8 Gate oxide
- 9 Contact layer
Claims (12)
1. A semiconductor module, essentially made of silicon material, comprising:
an insulation layer formed as a gate insulation layer as an insulation layer of a capacitor, wherein
the insulation layer is constructed from a dielectric material whose band gap is greater than that of SiO2, and the material has a sodium compound.
2. The semiconductor module according to claim 1 , wherein the material has a dielectric constant which is greater than or equal to the dielectric constant of silicon oxide.
3. The semiconductor module according to claim 1 , wherein the material has an alkali metal halide compound.
4. The semiconductor module according to claim 1 , wherein the material has a metal-fluorine compound.
5. The semiconductor module according to claim 1 , wherein the capacitor is part of a memory cell of a memory module.
6. A method for fabricating a semiconductor module, made essentially of silicon material,
comprising applying
a layer made of a dielectric material whose band gap is greater than the band gap of SiO2 as an insulation layer.
7. The semiconductor module according to claim 2 , wherein the material has an alkali metal halide compound.
8. The semiconductor module according to claim 2 , wherein the material has a metal-fluorine compound.
9. The semiconductor module according to claim 3 , wherein the material has a metal-fluorine compound.
10. The semiconductor module according to claim 2 , wherein the capacitor is part of a memory cell of a memory module.
11. The semiconductor module according to claim 3 , wherein the capacitor is part of a memory cell of a memory module.
12. The semiconductor module according to claim 4 , wherein the capacitor is part of a memory cell of a memory module.
Applications Claiming Priority (3)
Application Number | Priority Date | Filing Date | Title |
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DE10203674.8 | 2002-01-30 | ||
DE10203674A DE10203674A1 (en) | 2002-01-30 | 2002-01-30 | Semiconductor module with an insulation layer and method for producing a semiconductor module with an insulation layer |
PCT/EP2003/000377 WO2003065436A1 (en) | 2002-01-30 | 2003-01-16 | Semiconductor component with an insulating layer and method for the production of a semiconductor component with an insulating layer |
Publications (1)
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US20050127421A1 true US20050127421A1 (en) | 2005-06-16 |
Family
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Family Applications (1)
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US10/502,930 Abandoned US20050127421A1 (en) | 2002-01-30 | 2003-01-16 | Semiconductor module having an insulation layer and method for fabricating a semiconductor module having an insulation layer |
Country Status (5)
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---|---|
US (1) | US20050127421A1 (en) |
EP (1) | EP1470578A1 (en) |
DE (1) | DE10203674A1 (en) |
TW (1) | TWI223374B (en) |
WO (1) | WO2003065436A1 (en) |
Cited By (3)
Publication number | Priority date | Publication date | Assignee | Title |
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US20050151206A1 (en) * | 2003-12-30 | 2005-07-14 | Schwerin Ulrike G. | Transistor structure with a curved channel, memory cell and memory cell array for DRAMs, and methods for fabricating a DRAM |
US20100116780A1 (en) * | 2008-11-12 | 2010-05-13 | Jae Min Myoung | Method for patterning nanowires on substrate using novel sacrificial layer material |
US20140106070A1 (en) * | 2012-10-12 | 2014-04-17 | Asm Ip Holding B.V. | VAPOR DEPOSITION OF LiF THIN FILMS |
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US5858843A (en) * | 1996-09-27 | 1999-01-12 | Intel Corporation | Low temperature method of forming gate electrode and gate dielectric |
US6221553B1 (en) * | 1999-01-15 | 2001-04-24 | 3M Innovative Properties Company | Thermal transfer element for forming multilayer devices |
US6607952B1 (en) * | 1999-06-30 | 2003-08-19 | Kabushiki Kaisha Toshiba | Semiconductor device with a disposable gate and method of manufacturing the same |
US6617206B1 (en) * | 2000-06-07 | 2003-09-09 | Micron Technology, Inc. | Method of forming a capacitor structure |
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EP0055032B1 (en) * | 1980-12-23 | 1986-04-23 | National Research Development Corporation | Field effect transistors |
JPH0391931A (en) * | 1989-09-04 | 1991-04-17 | Oki Electric Ind Co Ltd | Polycrystalline silicon thin film transistor |
JPH05243567A (en) * | 1992-02-27 | 1993-09-21 | Ricoh Co Ltd | Mis type transistor element |
US6208001B1 (en) * | 1994-05-19 | 2001-03-27 | The United States Of America As Represented By The Secretary Of The Navy | Gallium arsenide semiconductor devices fabricated with insulator layer |
JPH10294432A (en) * | 1997-04-21 | 1998-11-04 | Sony Corp | Ferroelectric capacitor, ferroelectric nonvolatile storage device, and ferroelectric device |
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2002
- 2002-01-30 DE DE10203674A patent/DE10203674A1/en not_active Withdrawn
-
2003
- 2003-01-16 EP EP20030734672 patent/EP1470578A1/en not_active Withdrawn
- 2003-01-16 US US10/502,930 patent/US20050127421A1/en not_active Abandoned
- 2003-01-16 WO PCT/EP2003/000377 patent/WO2003065436A1/en not_active Application Discontinuation
- 2003-01-22 TW TW092101353A patent/TWI223374B/en active
Patent Citations (4)
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US5858843A (en) * | 1996-09-27 | 1999-01-12 | Intel Corporation | Low temperature method of forming gate electrode and gate dielectric |
US6221553B1 (en) * | 1999-01-15 | 2001-04-24 | 3M Innovative Properties Company | Thermal transfer element for forming multilayer devices |
US6607952B1 (en) * | 1999-06-30 | 2003-08-19 | Kabushiki Kaisha Toshiba | Semiconductor device with a disposable gate and method of manufacturing the same |
US6617206B1 (en) * | 2000-06-07 | 2003-09-09 | Micron Technology, Inc. | Method of forming a capacitor structure |
Cited By (9)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
US20050151206A1 (en) * | 2003-12-30 | 2005-07-14 | Schwerin Ulrike G. | Transistor structure with a curved channel, memory cell and memory cell array for DRAMs, and methods for fabricating a DRAM |
US20070052040A1 (en) * | 2003-12-30 | 2007-03-08 | Schwerin Ulrike G | Transistor with contoured channel and method for making the same |
US7279742B2 (en) * | 2003-12-30 | 2007-10-09 | Infineon Technologies Ag | Transistor structure with a curved channel, memory cell and memory cell array for DRAMs, and methods for fabricating a DRAM |
US20100116780A1 (en) * | 2008-11-12 | 2010-05-13 | Jae Min Myoung | Method for patterning nanowires on substrate using novel sacrificial layer material |
JP2010115772A (en) * | 2008-11-12 | 2010-05-27 | Industry-Academic Cooperation Foundation Yonsei Univ | Method of patterning nanowire on surface of substrate using new sacrificial layer material |
US8227348B2 (en) * | 2008-11-12 | 2012-07-24 | Industry-Academic Corporation Foundation, Yonsei University | Method for patterning nanowires on substrate using novel sacrificial layer material |
US20140106070A1 (en) * | 2012-10-12 | 2014-04-17 | Asm Ip Holding B.V. | VAPOR DEPOSITION OF LiF THIN FILMS |
US9382615B2 (en) * | 2012-10-12 | 2016-07-05 | Asm Ip Holding B.V. | Vapor deposition of LiF thin films |
US9909211B2 (en) | 2012-10-12 | 2018-03-06 | Asm Ip Holding B.V. | Vapor deposition of LiF thin films |
Also Published As
Publication number | Publication date |
---|---|
TWI223374B (en) | 2004-11-01 |
DE10203674A1 (en) | 2003-08-14 |
TW200401396A (en) | 2004-01-16 |
EP1470578A1 (en) | 2004-10-27 |
WO2003065436A1 (en) | 2003-08-07 |
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