US20060034147A1 - Kneading apparatus and method for kneading rubber-based composition using the same - Google Patents
Kneading apparatus and method for kneading rubber-based composition using the same Download PDFInfo
- Publication number
- US20060034147A1 US20060034147A1 US11/249,633 US24963305A US2006034147A1 US 20060034147 A1 US20060034147 A1 US 20060034147A1 US 24963305 A US24963305 A US 24963305A US 2006034147 A1 US2006034147 A1 US 2006034147A1
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- United States
- Prior art keywords
- kneading
- kneaded
- chamber
- rubber
- screw
- Prior art date
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- Abandoned
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- B—PERFORMING OPERATIONS; TRANSPORTING
- B29—WORKING OF PLASTICS; WORKING OF SUBSTANCES IN A PLASTIC STATE IN GENERAL
- B29C—SHAPING OR JOINING OF PLASTICS; SHAPING OF MATERIAL IN A PLASTIC STATE, NOT OTHERWISE PROVIDED FOR; AFTER-TREATMENT OF THE SHAPED PRODUCTS, e.g. REPAIRING
- B29C48/00—Extrusion moulding, i.e. expressing the moulding material through a die or nozzle which imparts the desired form; Apparatus therefor
- B29C48/25—Component parts, details or accessories; Auxiliary operations
- B29C48/78—Thermal treatment of the extrusion moulding material or of preformed parts or layers, e.g. by heating or cooling
- B29C48/86—Thermal treatment of the extrusion moulding material or of preformed parts or layers, e.g. by heating or cooling at the nozzle zone
- B29C48/87—Cooling
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- B—PERFORMING OPERATIONS; TRANSPORTING
- B29—WORKING OF PLASTICS; WORKING OF SUBSTANCES IN A PLASTIC STATE IN GENERAL
- B29B—PREPARATION OR PRETREATMENT OF THE MATERIAL TO BE SHAPED; MAKING GRANULES OR PREFORMS; RECOVERY OF PLASTICS OR OTHER CONSTITUENTS OF WASTE MATERIAL CONTAINING PLASTICS
- B29B7/00—Mixing; Kneading
- B29B7/30—Mixing; Kneading continuous, with mechanical mixing or kneading devices
- B29B7/34—Mixing; Kneading continuous, with mechanical mixing or kneading devices with movable mixing or kneading devices
- B29B7/38—Mixing; Kneading continuous, with mechanical mixing or kneading devices with movable mixing or kneading devices rotary
- B29B7/46—Mixing; Kneading continuous, with mechanical mixing or kneading devices with movable mixing or kneading devices rotary with more than one shaft
- B29B7/48—Mixing; Kneading continuous, with mechanical mixing or kneading devices with movable mixing or kneading devices rotary with more than one shaft with intermeshing devices, e.g. screws
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- B—PERFORMING OPERATIONS; TRANSPORTING
- B29—WORKING OF PLASTICS; WORKING OF SUBSTANCES IN A PLASTIC STATE IN GENERAL
- B29B—PREPARATION OR PRETREATMENT OF THE MATERIAL TO BE SHAPED; MAKING GRANULES OR PREFORMS; RECOVERY OF PLASTICS OR OTHER CONSTITUENTS OF WASTE MATERIAL CONTAINING PLASTICS
- B29B7/00—Mixing; Kneading
- B29B7/30—Mixing; Kneading continuous, with mechanical mixing or kneading devices
- B29B7/34—Mixing; Kneading continuous, with mechanical mixing or kneading devices with movable mixing or kneading devices
- B29B7/38—Mixing; Kneading continuous, with mechanical mixing or kneading devices with movable mixing or kneading devices rotary
- B29B7/46—Mixing; Kneading continuous, with mechanical mixing or kneading devices with movable mixing or kneading devices rotary with more than one shaft
- B29B7/48—Mixing; Kneading continuous, with mechanical mixing or kneading devices with movable mixing or kneading devices rotary with more than one shaft with intermeshing devices, e.g. screws
- B29B7/482—Mixing; Kneading continuous, with mechanical mixing or kneading devices with movable mixing or kneading devices rotary with more than one shaft with intermeshing devices, e.g. screws provided with screw parts in addition to other mixing parts, e.g. paddles, gears, discs
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- B—PERFORMING OPERATIONS; TRANSPORTING
- B29—WORKING OF PLASTICS; WORKING OF SUBSTANCES IN A PLASTIC STATE IN GENERAL
- B29B—PREPARATION OR PRETREATMENT OF THE MATERIAL TO BE SHAPED; MAKING GRANULES OR PREFORMS; RECOVERY OF PLASTICS OR OTHER CONSTITUENTS OF WASTE MATERIAL CONTAINING PLASTICS
- B29B7/00—Mixing; Kneading
- B29B7/30—Mixing; Kneading continuous, with mechanical mixing or kneading devices
- B29B7/34—Mixing; Kneading continuous, with mechanical mixing or kneading devices with movable mixing or kneading devices
- B29B7/38—Mixing; Kneading continuous, with mechanical mixing or kneading devices with movable mixing or kneading devices rotary
- B29B7/46—Mixing; Kneading continuous, with mechanical mixing or kneading devices with movable mixing or kneading devices rotary with more than one shaft
- B29B7/48—Mixing; Kneading continuous, with mechanical mixing or kneading devices with movable mixing or kneading devices rotary with more than one shaft with intermeshing devices, e.g. screws
- B29B7/488—Parts, e.g. casings, sealings; Accessories, e.g. flow controlling or throttling devices
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- B—PERFORMING OPERATIONS; TRANSPORTING
- B29—WORKING OF PLASTICS; WORKING OF SUBSTANCES IN A PLASTIC STATE IN GENERAL
- B29B—PREPARATION OR PRETREATMENT OF THE MATERIAL TO BE SHAPED; MAKING GRANULES OR PREFORMS; RECOVERY OF PLASTICS OR OTHER CONSTITUENTS OF WASTE MATERIAL CONTAINING PLASTICS
- B29B7/00—Mixing; Kneading
- B29B7/30—Mixing; Kneading continuous, with mechanical mixing or kneading devices
- B29B7/58—Component parts, details or accessories; Auxiliary operations
- B29B7/60—Component parts, details or accessories; Auxiliary operations for feeding, e.g. end guides for the incoming material
- B29B7/603—Component parts, details or accessories; Auxiliary operations for feeding, e.g. end guides for the incoming material in measured doses, e.g. proportioning of several materials
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- B—PERFORMING OPERATIONS; TRANSPORTING
- B29—WORKING OF PLASTICS; WORKING OF SUBSTANCES IN A PLASTIC STATE IN GENERAL
- B29B—PREPARATION OR PRETREATMENT OF THE MATERIAL TO BE SHAPED; MAKING GRANULES OR PREFORMS; RECOVERY OF PLASTICS OR OTHER CONSTITUENTS OF WASTE MATERIAL CONTAINING PLASTICS
- B29B7/00—Mixing; Kneading
- B29B7/30—Mixing; Kneading continuous, with mechanical mixing or kneading devices
- B29B7/58—Component parts, details or accessories; Auxiliary operations
- B29B7/72—Measuring, controlling or regulating
- B29B7/726—Measuring properties of mixture, e.g. temperature or density
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- B—PERFORMING OPERATIONS; TRANSPORTING
- B29—WORKING OF PLASTICS; WORKING OF SUBSTANCES IN A PLASTIC STATE IN GENERAL
- B29B—PREPARATION OR PRETREATMENT OF THE MATERIAL TO BE SHAPED; MAKING GRANULES OR PREFORMS; RECOVERY OF PLASTICS OR OTHER CONSTITUENTS OF WASTE MATERIAL CONTAINING PLASTICS
- B29B7/00—Mixing; Kneading
- B29B7/74—Mixing; Kneading using other mixers or combinations of mixers, e.g. of dissimilar mixers ; Plant
- B29B7/7476—Systems, i.e. flow charts or diagrams; Plants
- B29B7/7495—Systems, i.e. flow charts or diagrams; Plants for mixing rubber
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- B—PERFORMING OPERATIONS; TRANSPORTING
- B29—WORKING OF PLASTICS; WORKING OF SUBSTANCES IN A PLASTIC STATE IN GENERAL
- B29B—PREPARATION OR PRETREATMENT OF THE MATERIAL TO BE SHAPED; MAKING GRANULES OR PREFORMS; RECOVERY OF PLASTICS OR OTHER CONSTITUENTS OF WASTE MATERIAL CONTAINING PLASTICS
- B29B7/00—Mixing; Kneading
- B29B7/80—Component parts, details or accessories; Auxiliary operations
- B29B7/82—Heating or cooling
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- B—PERFORMING OPERATIONS; TRANSPORTING
- B29—WORKING OF PLASTICS; WORKING OF SUBSTANCES IN A PLASTIC STATE IN GENERAL
- B29B—PREPARATION OR PRETREATMENT OF THE MATERIAL TO BE SHAPED; MAKING GRANULES OR PREFORMS; RECOVERY OF PLASTICS OR OTHER CONSTITUENTS OF WASTE MATERIAL CONTAINING PLASTICS
- B29B7/00—Mixing; Kneading
- B29B7/80—Component parts, details or accessories; Auxiliary operations
- B29B7/84—Venting or degassing ; Removing liquids, e.g. by evaporating components
- B29B7/845—Venting, degassing or removing evaporated components in devices with rotary stirrers
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- B—PERFORMING OPERATIONS; TRANSPORTING
- B29—WORKING OF PLASTICS; WORKING OF SUBSTANCES IN A PLASTIC STATE IN GENERAL
- B29C—SHAPING OR JOINING OF PLASTICS; SHAPING OF MATERIAL IN A PLASTIC STATE, NOT OTHERWISE PROVIDED FOR; AFTER-TREATMENT OF THE SHAPED PRODUCTS, e.g. REPAIRING
- B29C48/00—Extrusion moulding, i.e. expressing the moulding material through a die or nozzle which imparts the desired form; Apparatus therefor
- B29C48/03—Extrusion moulding, i.e. expressing the moulding material through a die or nozzle which imparts the desired form; Apparatus therefor characterised by the shape of the extruded material at extrusion
- B29C48/07—Flat, e.g. panels
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- B—PERFORMING OPERATIONS; TRANSPORTING
- B29—WORKING OF PLASTICS; WORKING OF SUBSTANCES IN A PLASTIC STATE IN GENERAL
- B29C—SHAPING OR JOINING OF PLASTICS; SHAPING OF MATERIAL IN A PLASTIC STATE, NOT OTHERWISE PROVIDED FOR; AFTER-TREATMENT OF THE SHAPED PRODUCTS, e.g. REPAIRING
- B29C48/00—Extrusion moulding, i.e. expressing the moulding material through a die or nozzle which imparts the desired form; Apparatus therefor
- B29C48/25—Component parts, details or accessories; Auxiliary operations
- B29C48/36—Means for plasticising or homogenising the moulding material or forcing it through the nozzle or die
- B29C48/50—Details of extruders
- B29C48/505—Screws
- B29C48/54—Screws with additional forward-feeding elements
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- B—PERFORMING OPERATIONS; TRANSPORTING
- B29—WORKING OF PLASTICS; WORKING OF SUBSTANCES IN A PLASTIC STATE IN GENERAL
- B29C—SHAPING OR JOINING OF PLASTICS; SHAPING OF MATERIAL IN A PLASTIC STATE, NOT OTHERWISE PROVIDED FOR; AFTER-TREATMENT OF THE SHAPED PRODUCTS, e.g. REPAIRING
- B29C48/00—Extrusion moulding, i.e. expressing the moulding material through a die or nozzle which imparts the desired form; Apparatus therefor
- B29C48/25—Component parts, details or accessories; Auxiliary operations
- B29C48/36—Means for plasticising or homogenising the moulding material or forcing it through the nozzle or die
- B29C48/50—Details of extruders
- B29C48/505—Screws
- B29C48/57—Screws provided with kneading disc-like elements, e.g. with oval-shaped elements
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- B—PERFORMING OPERATIONS; TRANSPORTING
- B29—WORKING OF PLASTICS; WORKING OF SUBSTANCES IN A PLASTIC STATE IN GENERAL
- B29C—SHAPING OR JOINING OF PLASTICS; SHAPING OF MATERIAL IN A PLASTIC STATE, NOT OTHERWISE PROVIDED FOR; AFTER-TREATMENT OF THE SHAPED PRODUCTS, e.g. REPAIRING
- B29C48/00—Extrusion moulding, i.e. expressing the moulding material through a die or nozzle which imparts the desired form; Apparatus therefor
- B29C48/25—Component parts, details or accessories; Auxiliary operations
- B29C48/36—Means for plasticising or homogenising the moulding material or forcing it through the nozzle or die
- B29C48/50—Details of extruders
- B29C48/76—Venting, drying means; Degassing means
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- B—PERFORMING OPERATIONS; TRANSPORTING
- B29—WORKING OF PLASTICS; WORKING OF SUBSTANCES IN A PLASTIC STATE IN GENERAL
- B29C—SHAPING OR JOINING OF PLASTICS; SHAPING OF MATERIAL IN A PLASTIC STATE, NOT OTHERWISE PROVIDED FOR; AFTER-TREATMENT OF THE SHAPED PRODUCTS, e.g. REPAIRING
- B29C48/00—Extrusion moulding, i.e. expressing the moulding material through a die or nozzle which imparts the desired form; Apparatus therefor
- B29C48/25—Component parts, details or accessories; Auxiliary operations
- B29C48/36—Means for plasticising or homogenising the moulding material or forcing it through the nozzle or die
- B29C48/50—Details of extruders
- B29C48/76—Venting, drying means; Degassing means
- B29C48/765—Venting, drying means; Degassing means in the extruder apparatus
- B29C48/766—Venting, drying means; Degassing means in the extruder apparatus in screw extruders
- B29C48/767—Venting, drying means; Degassing means in the extruder apparatus in screw extruders through a degassing opening of a barrel
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- B—PERFORMING OPERATIONS; TRANSPORTING
- B29—WORKING OF PLASTICS; WORKING OF SUBSTANCES IN A PLASTIC STATE IN GENERAL
- B29C—SHAPING OR JOINING OF PLASTICS; SHAPING OF MATERIAL IN A PLASTIC STATE, NOT OTHERWISE PROVIDED FOR; AFTER-TREATMENT OF THE SHAPED PRODUCTS, e.g. REPAIRING
- B29C48/00—Extrusion moulding, i.e. expressing the moulding material through a die or nozzle which imparts the desired form; Apparatus therefor
- B29C48/25—Component parts, details or accessories; Auxiliary operations
- B29C48/78—Thermal treatment of the extrusion moulding material or of preformed parts or layers, e.g. by heating or cooling
- B29C48/793—Thermal treatment of the extrusion moulding material or of preformed parts or layers, e.g. by heating or cooling upstream of the plasticising zone, e.g. heating in the hopper
- B29C48/797—Cooling
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- B—PERFORMING OPERATIONS; TRANSPORTING
- B29—WORKING OF PLASTICS; WORKING OF SUBSTANCES IN A PLASTIC STATE IN GENERAL
- B29C—SHAPING OR JOINING OF PLASTICS; SHAPING OF MATERIAL IN A PLASTIC STATE, NOT OTHERWISE PROVIDED FOR; AFTER-TREATMENT OF THE SHAPED PRODUCTS, e.g. REPAIRING
- B29C48/00—Extrusion moulding, i.e. expressing the moulding material through a die or nozzle which imparts the desired form; Apparatus therefor
- B29C48/25—Component parts, details or accessories; Auxiliary operations
- B29C48/78—Thermal treatment of the extrusion moulding material or of preformed parts or layers, e.g. by heating or cooling
- B29C48/80—Thermal treatment of the extrusion moulding material or of preformed parts or layers, e.g. by heating or cooling at the plasticising zone, e.g. by heating cylinders
- B29C48/82—Cooling
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- B—PERFORMING OPERATIONS; TRANSPORTING
- B29—WORKING OF PLASTICS; WORKING OF SUBSTANCES IN A PLASTIC STATE IN GENERAL
- B29C—SHAPING OR JOINING OF PLASTICS; SHAPING OF MATERIAL IN A PLASTIC STATE, NOT OTHERWISE PROVIDED FOR; AFTER-TREATMENT OF THE SHAPED PRODUCTS, e.g. REPAIRING
- B29C48/00—Extrusion moulding, i.e. expressing the moulding material through a die or nozzle which imparts the desired form; Apparatus therefor
- B29C48/25—Component parts, details or accessories; Auxiliary operations
- B29C48/78—Thermal treatment of the extrusion moulding material or of preformed parts or layers, e.g. by heating or cooling
- B29C48/80—Thermal treatment of the extrusion moulding material or of preformed parts or layers, e.g. by heating or cooling at the plasticising zone, e.g. by heating cylinders
- B29C48/83—Heating or cooling the cylinders
- B29C48/834—Cooling
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- B—PERFORMING OPERATIONS; TRANSPORTING
- B29—WORKING OF PLASTICS; WORKING OF SUBSTANCES IN A PLASTIC STATE IN GENERAL
- B29C—SHAPING OR JOINING OF PLASTICS; SHAPING OF MATERIAL IN A PLASTIC STATE, NOT OTHERWISE PROVIDED FOR; AFTER-TREATMENT OF THE SHAPED PRODUCTS, e.g. REPAIRING
- B29C48/00—Extrusion moulding, i.e. expressing the moulding material through a die or nozzle which imparts the desired form; Apparatus therefor
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- B29C48/92—Measuring, controlling or regulating
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- B—PERFORMING OPERATIONS; TRANSPORTING
- B29—WORKING OF PLASTICS; WORKING OF SUBSTANCES IN A PLASTIC STATE IN GENERAL
- B29B—PREPARATION OR PRETREATMENT OF THE MATERIAL TO BE SHAPED; MAKING GRANULES OR PREFORMS; RECOVERY OF PLASTICS OR OTHER CONSTITUENTS OF WASTE MATERIAL CONTAINING PLASTICS
- B29B7/00—Mixing; Kneading
- B29B7/30—Mixing; Kneading continuous, with mechanical mixing or kneading devices
- B29B7/34—Mixing; Kneading continuous, with mechanical mixing or kneading devices with movable mixing or kneading devices
- B29B7/38—Mixing; Kneading continuous, with mechanical mixing or kneading devices with movable mixing or kneading devices rotary
- B29B7/46—Mixing; Kneading continuous, with mechanical mixing or kneading devices with movable mixing or kneading devices rotary with more than one shaft
- B29B7/465—Mixing; Kneading continuous, with mechanical mixing or kneading devices with movable mixing or kneading devices rotary with more than one shaft each shaft comprising rotor parts of the Banbury type in addition to screw parts
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- B—PERFORMING OPERATIONS; TRANSPORTING
- B29—WORKING OF PLASTICS; WORKING OF SUBSTANCES IN A PLASTIC STATE IN GENERAL
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- B29C2948/00—Indexing scheme relating to extrusion moulding
- B29C2948/92—Measuring, controlling or regulating
- B29C2948/92009—Measured parameter
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- B—PERFORMING OPERATIONS; TRANSPORTING
- B29—WORKING OF PLASTICS; WORKING OF SUBSTANCES IN A PLASTIC STATE IN GENERAL
- B29C—SHAPING OR JOINING OF PLASTICS; SHAPING OF MATERIAL IN A PLASTIC STATE, NOT OTHERWISE PROVIDED FOR; AFTER-TREATMENT OF THE SHAPED PRODUCTS, e.g. REPAIRING
- B29C2948/00—Indexing scheme relating to extrusion moulding
- B29C2948/92—Measuring, controlling or regulating
- B29C2948/92009—Measured parameter
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- B—PERFORMING OPERATIONS; TRANSPORTING
- B29—WORKING OF PLASTICS; WORKING OF SUBSTANCES IN A PLASTIC STATE IN GENERAL
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- B29C2948/92—Measuring, controlling or regulating
- B29C2948/92009—Measured parameter
- B29C2948/92314—Particular value claimed
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- B—PERFORMING OPERATIONS; TRANSPORTING
- B29—WORKING OF PLASTICS; WORKING OF SUBSTANCES IN A PLASTIC STATE IN GENERAL
- B29C—SHAPING OR JOINING OF PLASTICS; SHAPING OF MATERIAL IN A PLASTIC STATE, NOT OTHERWISE PROVIDED FOR; AFTER-TREATMENT OF THE SHAPED PRODUCTS, e.g. REPAIRING
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- B29C2948/92323—Location or phase of measurement
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- B—PERFORMING OPERATIONS; TRANSPORTING
- B29—WORKING OF PLASTICS; WORKING OF SUBSTANCES IN A PLASTIC STATE IN GENERAL
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- B29C2948/92—Measuring, controlling or regulating
- B29C2948/92323—Location or phase of measurement
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- B—PERFORMING OPERATIONS; TRANSPORTING
- B29—WORKING OF PLASTICS; WORKING OF SUBSTANCES IN A PLASTIC STATE IN GENERAL
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- B29C48/25—Component parts, details or accessories; Auxiliary operations
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- B29C48/395—Means for plasticising or homogenising the moulding material or forcing it through the nozzle or die using screws surrounded by a cooperating barrel, e.g. single screw extruders
- B29C48/40—Means for plasticising or homogenising the moulding material or forcing it through the nozzle or die using screws surrounded by a cooperating barrel, e.g. single screw extruders using two or more parallel screws or at least two parallel non-intermeshing screws, e.g. twin screw extruders
- B29C48/405—Intermeshing co-rotating screws
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- B29K—INDEXING SCHEME ASSOCIATED WITH SUBCLASSES B29B, B29C OR B29D, RELATING TO MOULDING MATERIALS OR TO MATERIALS FOR MOULDS, REINFORCEMENTS, FILLERS OR PREFORMED PARTS, e.g. INSERTS
- B29K2007/00—Use of natural rubber as moulding material
Definitions
- the present invention relates to kneading apparatuses. More particularly, the invention relates to a kneading apparatus used for masticating rubber and for kneading a rubber-based composition in which rubber and various compounding ingredients are mixed, and to a kneading method using the kneading apparatus.
- a batch process is often used, in which predetermined amounts of raw materials are intermittently kneaded.
- a method for continuously kneading a rubber-based composition has also been disclosed (Japanese Unexamined Patent Application Publication No. 11-262945).
- a twin-screw extruder which is a typical kneader for rubber-based compositions, is used.
- the twin-screw extruder is provided with a rubber feed port, and a rubber-feeding extruder is further connected thereto. Continuous kneading is performed by the twin-screw extruder while continuously feeding the rubber-based composition.
- the continuous kneading method according to Japanese Unexamined Patent Application Publication No. 11-262945 is not suitable for rubber-based compositions having high viscosities, and as described in Example 1 in the patent application publication, the method aims to continuously knead a rubber-based composition having a low viscosity, e.g., a Mooney viscosity (100° C.) of approximately 47.
- a rubber-based composition having a high viscosity e.g., a Mooney viscosity (100° C.) of more than 100
- a Mooney viscosity 100° C.
- kneading treatment is performed to improve the dispersion of various compounding ingredients and also to decrease the viscosity of the rubber-based composition to a viscosity suitable for later processes, such as extrusion molding.
- the viscosity is decreased because rubber molecular chains are cut due to mechanical shearing.
- kneading is performed by a batch-type kneader.
- the materials to be kneaded are recovered from the kneader and cooled to ambient temperature after sheet forming is performed. Kneading is performed again in order to decrease the viscosity.
- a rekneading step is referred to as a remill step.
- the remill step is usually repeated several times until the predetermined viscosity is achieved. Remilling is often performed approximately five times. Consequently, the productivity inevitably decreases due to repeated kneading by the batch-type kneader and cooling, and since thermal hysteresis then takes place, alteration of the rubber easily occurs.
- the objects of the present invention are to provide a kneading apparatus for rubber-based compositions having high viscosities in which continuous kneading treatment can be performed without repeated remilling, thus greatly improving productivity, and to provide a kneading method using the kneading apparatus.
- a kneading apparatus in one aspect of the present invention, includes a barrel having a cylindrical chamber; a screw assembly rotating in the chamber so that a material to be kneaded is extruded in the axial direction by the rotation, the screw assembly including a screw section having helical blades and a kneading blade section in order to allow the material to be kneaded to flow into the clearance between the inner wall of the chamber and a kneading blade of the kneading blade section, and to apply shearing forces to the material to be kneaded; a metering feeder for feeding the material to be kneaded at a substantially constant volumetric rate or at a substantially constant gravimetric rate from a feed port provided on the barrel into the chamber; an injecting device provided on the barrel for injecting a heat-removing medium into the chamber; and a discharging device for separating the heat-removing medium which has been injected into the chamber by the injecting device and mixed with
- continuous kneading can be performed while feeding the material to be kneaded to the kneading extruder at a constant rate, and injection of the heat-removing medium into the chamber and the discharge of the heat-removing medium from the chamber can also be performed continuously. That is, the heat-removing medium removes heat while being mixed with and brought into sufficient contact with the material to be kneaded which generates heat due to kneading, and the heat-removing medium is discharged from the chamber. Therefore, heat-removing treatment of the material to be kneaded can be efficiently performed during kneading.
- the positions and numbers of the injecting devices (injecting devices for heat-removing medium) and the discharging devices (discharging devices for heat-removing medium), as well as the amount of injection can be selected in any given manner, it is possible to adjust the cooling capacity appropriately depending on the characteristics of the rubber-based composition and the kneading extruder.
- the rubber-based composition when a rubber-based composition is fed at a high temperature or when the temperature of a rubber-based composition is increased while being passed through the rubber metering feeder and the kneading effect is decreased, the rubber-based composition is brought into contact with injected water in the kneading extruder so that the rubber-based composition is cooled primarily by the sensible heat of the water, and the water used for cooling is discharged through the discharging device, such as a slit, provided on the barrel, and thus cooling of the rubber-based composition is accelerated, and then the rubber-based composition may be subjected to the subsequent kneading step.
- the discharging device such as a slit
- Japanese Unexamined Patent Application Publication No. 7-227845 discloses a batch-type kneader in which water is added when kneading is performed.
- the publication relates to a method for reutilizing unvulcanized foamed rubber used for tires which has failed to meet the standards with respect to the expansion rate, dimensional accuracy, etc., and a foaming agent is decomposed and eliminated by kneading the unvulcanized foamed rubber mixed with a small amount of water in a batch-type hermetically closed mixer. That is, there are differences in the problems to be solved and the features between the present invention and Japanese Unexamined Patent Application Publication No. 7-227845.
- the discharging device for discharging the heat-removing medium includes a vacuum pump connected to the chamber for evacuating the chamber in the region in which the screw section is placed.
- the heat-removing medium is not limited to water.
- the discharging device for the heat-removing medium includes a slit formed in the barrel in the region in which the screw section placed.
- a dewatering device can be produced with a simple construction. Even if the rubber-based composition to be fed into the kneading extruder is in a high temperature state, it is possible to cool the composition efficiently before kneading treatment is performed.
- the kneading apparatus of the present invention further includes at least one gap-adjusting device provided at the outlet of the kneading blade section so as to sandwich the screw assembly, the gap-adjusting device being capable of adjusting a gap formed between the screw assembly and the gap-adjusting device.
- the extruded material to be kneaded is squeezed and the flow resistance of the material to be kneaded is changed, and thus the material residence time in the kneading extruder can be adjusted. That is, it is possible to adjust the filling factor of the material to be kneaded in the kneading blade section, and desired kneading conditions can be easily adjusted.
- the metering feeder is either a gear pump or a screw extruder connected to the feed port provided on the barrel.
- the gear pump or screw extruder as the metering feeder, it is possible to stably feed the material to be kneaded to the kneading extruder at a constant rate. Thereby, variations in the quality of the kneaded product can be suppressed.
- the form of the material to be kneaded is not particularly limited, and various forms, such as blocks, veils, sheets, and ribbons, may be selected.
- the kneading apparatus of the present invention further includes a temperature-measuring section for measuring the temperature of the material to be kneaded in the chamber, and a control section for controlling the amount of the heat-removing medium to be injected into the chamber or the speed of rotation of the screw assembly based on the measured temperature.
- a method for kneading a rubber-based composition including rubber and compounding ingredients using the kneading apparatus described above includes: a feeding step of feeding the rubber-based composition into the chamber at a substantially constant volumetric rate or at a substantially constant gravimetric rate by the metering feeder; a kneading step of allowing the rubber-based composition to flow into the clearance between the inner wall of the chamber and the kneading blade section and moving the rubber-based composition in the chamber while mixing and dispersing the rubber-based composition by means of shearing forces; a mixing step of injecting a heat-removing medium into the chamber by the injecting device and mixing the rubber-based composition with the heat-removing medium before or during kneading; and a discharging step of separating the heat-removing medium which has been injected into the chamber by the injecting device and mixed with the rubber-based composition from the rubber-based composition and discharging the heat-removing medium by the discharging
- a rubber-based composition can be continuously kneaded by the kneading extruder and heat removal can be simultaneously performed during kneading. Consequently, even in the case of a rubber-based composition having a high viscosity, kneading treatment can be performed so that the viscosity is decreased to a predetermined level without having a high temperature state. That is, a rubber-based composition having a high viscosity can be continuously kneaded without repeated remilling, resulting in a great improvement in productivity.
- FIG. 1 is a schematic sectional view of a kneading apparatus for rubber-based compositions, viewed from a side, in a first embodiment of the present invention
- FIG. 2 is a sectional view taken along the line II-II of FIG. 1 ;
- FIG. 3 is a schematic sectional view of a kneading apparatus for rubber-based compositions, viewed from a side, in a second embodiment of the present invention
- FIG. 4 is a schematic sectional view which shows a part of a kneading apparatus for rubber-based compositions in a third embodiment of the present invention
- FIG. 5 is a schematic diagram of a gate device at a cross section perpendicular to the shafts of the screw assembly
- FIG. 6 is a schematic diagram showing a kneading apparatus for rubber-based compositions in a fourth embodiment of the present invention.
- FIG. 7 is a schematic diagram showing a modified kneading apparatus for rubber-based compositions.
- FIG. 8 is a schematic diagram showing another modified kneading apparatus for rubber-based compositions.
- FIG. 1 is a schematic sectional view of a kneading apparatus for rubber-based compositions, viewed from a side, in this embodiment.
- the kneading apparatus includes a co-rotating intermeshing twin-screw kneading extruder 1 .
- a rubber metering feeder 2 is connected to the twin-screw kneading extruder 1 , and injection pumps 3 and 4 constituting injecting devices and vacuum pumps 5 and 6 constituting discharging devices are also connected thereto.
- the front end of the twin-screw kneading extruder 1 is exposed to air, and the rubber-based composition is discharged as a lump.
- the twin-screw kneading extruder 1 includes a screw assembly 7 composed of a pair of screws, and a barrel 9 including a cylindrical chamber 8 in which the screws rotate.
- the shafts of the screws are parallel to each other and completely overlap in the side view shown in FIG. 1 .
- a material to be kneaded is extruded in the axial direction by the rotation of each screw.
- the screw assembly 7 alternately includes screw sections 7 a (first), 7 c (second), 7 e (third), and 7 g (fourth) having helical blades and kneading blade sections 7 b (first), 7 d (second), 7 f (third), and 7 h (fourth) for allowing the material to be kneaded to flow in the clearance between the inner wall of the chamber 8 and the kneading blade sections and for applying shearing forces to the material to be kneaded. Both screws are connected to a driving device (not shown in the drawing) and are rotated by the driving device.
- the helical blades in each screw section are formed along the peripheries of the individual screw shafts so as to extend in the axial direction.
- the tops of the helical blades are positioned at the same distance from the centers of the shafts of the screws.
- the pair of screws having the helical blades formed in the same direction rotate in the same direction, and thereby the material to be kneaded is moved rightward in FIG. 1 .
- the helical pitches of the helical blades provided in the screw sections are not necessarily the same, and the helical blades may have densely pitched areas and sparsely pitched areas.
- the helical blades located downstream in the extrusion process may be densely pitched so that the material to be kneaded is subjected to a filling and compressing action, thus providing a dewatering function.
- the helical blades located in the areas adjacent to the space to be evacuated by suction may be densely pitched, or helical blades or sheets effective in blocking the material to be kneaded may be placed so that the areas adjacent to the space to be evacuated by suction are filled with the material to be kneaded, thereby displaying a sealing effect.
- reverse flighted screws which are helical blades formed in the opposite direction, may be partially provided, or rotors or kneading disks as return segments (L segments) in which blades in the opposite direction are formed may be partially provided so that the filling factor of the material to be kneaded is increased, thereby producing a pressurized state.
- each kneading blade section placed between the screw sections three kneading blades are provided along the periphery of each screw with an angle of 120° therebetween, each kneading blade having a cross section suitable for kneading, i.e., having a shape such that a bite angle to the material to be kneaded is created.
- Each kneading blade is helically and slowly wound about the screw shaft extending in the axial direction.
- the helical direction is reversed.
- the helical direction of the kneading blades located.
- the upstream in the extrusion process is defined as a normal direction and the helical direction of the kneading blades located downstream is defined as an opposite direction.
- the materials to be kneaded are transported to the kneading blade section composed of the kneading blades having the normal and opposite helical directions fill the kneading blade section to await kneading. Kneading is performed so that the material to be kneaded is made to flow between the kneading blades of both screws and between the kneading blades having the normal helical direction and the kneading blades having the opposite helical direction.
- FIG. 2 is a sectional view taken along the line II-II of FIG. 1 .
- FIG. 2 shows the state in which a material 11 to be kneaded is kneaded in the clearance between the inner wall of the chamber 8 and the kneading blades 10 .
- Three chip kneading blades 10 are provided along the periphery of each screw shaft with an angle of 120° therebetween and with a bite angle ⁇ .
- the midpoint in which the helical direction is reversed is not necessarily located in the exact middle of the kneading blade section, and the midpoint may be placed in the downstream side in the extrusion process so as to accelerate the transport of the material to be kneaded.
- the barrel 9 is constructed so as to form the chamber 8 .
- the barrel 9 is composed of detachable units, each unit being a screw section or a kneading blade section. This is because the barrel 9 is designed so that various combinations of the screw sections and the kneading blade sections can be selected or the numbers of the injecting devices and the discharging devices can be appropriately selected.
- a cooling jacket for passing a cooling medium may be internally or externally provided on at least one unit constituting the barrel 9 .
- a rubber feed port 12 for feeding a rubber-based composition into the chamber 8 is provided on the first screw section 7 a located upstream in the twin-screw kneading extruder 1 .
- the rubber metering feeder 2 having a twin screw extruding device is connected to the rubber feed port 12 .
- the raw materials of a rubber-based composition are continuously fed into the chamber 8 by the twin-screw extruding device.
- the rubber metering feeder 2 allows continuous feed of the raw material rubber at a constant rate regardless of the form of the raw material rubber, i.e., the raw material rubber may be in the form of powder or in a lump.
- the rubber metering feeder 2 does not necessarily include a twin-screw extruding device, and the rubber metering feeder 2 may include a single-screw extruding device, a multi-screw extruding device having more than three screws, or a gear pump. In either case, continuous feed can be performed at a constant rate regardless of the form of the raw material rubber.
- the injection pumps 3 and 4 are connected to injection ports 13 and 14 provided on the barrel at the positions where the second kneading blade section 7 d and the third kneading blade section 7 f are placed, respectively. These elements constitute the injecting devices. Water sent from the injection pumps 3 and 4 is injected into the chamber 8 through the injection ports 13 and 14 , and the material to be kneaded and the water are mixed together. Thereby, heat generated from the material to be kneaded can be removed.
- the vacuum pumps 5 and 6 are connected to suction ports 15 and 16 provided on the barrel at the positions where the third screw section 7 e and the fourth screw section 7 g are placed, respectively.
- the chamber 8 can be evacuated by suction in the regions where the third screw section 7 e and the fourth screw section 7 g are placed by the vacuum pumps 5 and 6 . Since the pressure is reduced as described above, water injected in the second screw section 7 d and the third screw section 7 f and contained in the material to be kneaded is vaporized and is sucked out by the vacuum pumps 5 and 6 .
- An injecting device is provided in the second kneading blade section 7 d first because a high-temperature state which requires cooling is not brought about in the first kneading blade section 7 b and because it may be necessary to accelerate the heat generation of the rubber-based material to a certain extent so that the rubber-based material is plasticized and the sealing effect is displayed in order to remove water under vacuum in the downstream process.
- an injecting device is not provided in the fourth kneading blade section 7 h in the last stage because it is not possible to perform dewatering by vacuum in the downstream side.
- the numbers of the kneading blade sections and the screw sections are not limited to this embodiment, and are preferably selected appropriately depending on the quality of the rubber-based composition to be processed and the desired decreased value of viscosity.
- the numbers and positions of the injecting devices and the discharging devices are also not limited to this embodiment.
- raw materials for a rubber-based composition including a filler, such as carbon black, and various compounding ingredients in various forms of powder, lump, or sheet are fed into the rubber metering feeder 2 .
- the raw material rubber fed into the rubber metering feeder 2 is transported to the feed port 12 of the twin-screw kneading extruder 1 at a constant rate by the twin-screw extruding device constituting the rubber metering feeder 2 .
- the raw material rubber fed into the twin-screw kneading extruder 1 at a constant rate through the feed port 12 is delivered to the chamber 8 at the position where the first screw section 7 b is located.
- the screw assembly 7 (a pair of screws) is already being rotated by a driving device (not shown in the drawing).
- the rubber-based composition as the material to be kneaded is extruded to the first kneading blade section 7 b by the rotating helical blades of the screw section 7 b .
- the material to be kneaded starts to fill between the inner wall of the chamber 8 and the kneading blades, and the material to be kneaded is made to flow and is mixed and dispersed in the clearance between the inner wall of the chamber 8 and the kneading blades while being applied with shearing forces, and thus kneading is performed.
- the material kneaded in the first kneading blade section 7 b moves to the second screw section 7 c by being extruded by the material filling the upstream side.
- the material moved to the second screw section 7 c is transported to the second kneading blade section 7 d by the rotation of the helical blades.
- the material transported to the second kneading blade section 7 d is kneaded again in the same manner as the first kneading blade section 7 b apart from the fact that water sent from the injection pump 3 is injected into the second kneading blade section 7 d through the injection port 13 . Consequently, the material to be kneaded is brought into contact with water during kneading.
- the temperature of the material to be kneaded is increased to a certain extent due to the heat generation during kneading in the first kneading blade section 7 b , and the temperature is further increased because heat generation occurs during kneading in the second kneading blade section 7 d.
- the water injected is mixed with the material to be kneaded and is brought into sufficient contact with the material to be kneaded, heat can be removed from the material to be kneaded.
- the material to be kneaded thus cooled by the injection of water is extruded to the third screw section 7 e by the material moved from the upstream side into the second kneading blade section 7 d.
- the material to be kneaded is transported in the same manner as the upstream screw section apart from the fact that the atmospheric gas in the chamber 8 is sucked out by the vacuum pump 5 through the suction port 15 and a reduced-pressure space is produced.
- the materials filled in the adjacent kneading blade sections display the sealing effect to secure the reduced-pressure space.
- the helical blades in the upstream end and the downstream end in the third screw section 7 e may be densely pitched in the axial direction and the helical blades at the position corresponding to the suction port 15 may be sparsely pitched so that the material to be kneaded fills the densely pitched area, thereby displaying the sealing effect.
- the material to be kneaded in which water is removed in the third screw section 7 e is transported to the third kneading blade section 7 f .
- kneading is performed while injecting water again for cooling in the same manner as the second kneading blade section 7 d .
- water is removed in the same manner as the third screw section 7 e .
- the material to be kneaded is then transported to the fourth kneading blade section 7 h which is the final stage, and just kneading is performed therein, and then the material is extruded as a lump from the front end into the air.
- FIG. 3 is a schematic sectional view of the kneading apparatus in this embodiment.
- the kneading apparatus includes a twin-screw kneading extruder 1 , and a rubber metering feeder 2 , injection pumps 3 and 4 , and a vacuum pump 5 connected to the twin-screw kneading extruder 1 .
- the twin-screw kneading extruder 1 includes a screw assembly 7 , a chamber 8 , and a barrel 9 .
- the screw assembly 7 has three screw sections and three kneading blade sections which are placed alternately.
- the injection pumps 3 and 4 are connected to a first screw section 7 b and a second kneading blade section 7 d through injection ports 13 and 14 , respectively, and the injection pump 5 is connected to a third screw section 7 e through a suction port 15 .
- the barrel in the region where the first screw section 7 b is located is provided with a slit portion 17 . In the slit portion 17 , slits are formed so as to connect the interior of the chamber 8 to the exterior of the chamber 8 .
- the kneading apparatus in this embodiment has a structure which is effective in kneading high-temperature raw material rubber directly by the twin-screw kneading extruder. The characteristic operation of the kneading apparatus will be described below.
- a rubber-based composition which has been kneaded to a certain extent by a batch-type mixer or the like and which has a high temperature is fed into the rubber metering feeder 2 .
- This process is performed, for example, when there is a difficulty in feeding at a constant rate unless the raw material rubber is heated to a temperature that allows plasticization, or in order to omit the step of cooling high temperature rubber.
- the fed material to be kneaded is transported to the downstream side by the first screw section 7 a , and at this stage water is injected from the injection pump 3 into the chamber 8 through the injection port 13 . Thereby, the high temperature material to be kneaded being transported is brought into contact with water and cooled.
- By appropriately setting the width of slits in the slit portion 17 it is possible to just discharge water used for cooling without discharging the material to be kneaded from the chamber 8 . Even when a large amount of cooling water is required, it is possible to efficiently remove the water, and a dewatering device can be produced with a simple construction.
- the numbers of the screw sections and the kneading blade sections and the numbers of the injecting devices and the discharging devices are not limited to this embodiment and can be appropriately selected depending on the quality of the rubber-based composition to be processed, the desired reduction value of viscosity, etc.
- FIG. 4 is a schematic sectional view which shows a part of a kneading apparatus in the third embodiment of the present invention, taken along the shafts of a screw assembly 7 .
- the kneading apparatus in this embodiment is the same as the first embodiment apart from the fact that a gate device 18 , which is a gap-adjusting device, is provided between the second kneading blade section 7 d and the third screw section 7 e .
- FIG. 5 is a sectional view of the gate device 18 , perpendicular to the shafts of the screw assembly 7 .
- the gate device 18 includes two gates 19 located so as to sandwich the screw assembly 7 , and the gates 19 are provided perpendicularly to the shafts of the screw assembly 7 and so as to be movable in relation to the screw assembly 7 .
- a gap formed between the screw assembly 7 and the gate 19 i.e., the area through which the material to be kneaded passes, can be adjusted.
- the extruded material to be kneaded is squeezed and the flow resistance of the material to be kneaded is changed, and thus the material residence time in the kneading apparatus can be adjusted.
- gate device 18 is not limited to the example described above. Gate devices may be provided in a plurality of kneading blade sections and screw sections. A gate device may be composed of two gate rods sandwiching the screw assembly 7 , each rotating without moving perpendicularly. A gate device may have a structure including a conical part provided on the screw assembly 7 and a slot formed between the conical part and the chamber, in which the chamber and the conical part are relatively moved in the axial direction of the screw assembly 7 . Alternatively, a pin type gate device may be used, such as the one seen in a rubber extruder.
- FIG. 6 is a schematic diagram showing a kneading apparatus in this embodiment.
- the kneading apparatus is the same as the first embodiment apart from the fact that temperature-measuring sections 20 a and 20 b for measuring the temperature of the material to be kneaded are provided in the second kneading blade section 7 d and the third kneading blade section 7 f .
- the kneading apparatus includes a control section for controlling the amount of water to be injected into the chamber 8 , and the speed of rotation of the screw assembly 7 based on the temperatures measured, and an input section for transmitting the values measured by the temperature-measuring sections 20 a and 20 b.
- the screw assembly 7 If the speed of rotation of the screw assembly 7 is increased, the kneading power is increased. Therefore, high speed revolution is desirable in view of kneading efficiency. However, as the speed of revolution is increased, the amount of heat generated from the material to be kneaded is increased. The heat generated from the material to be kneaded varies depending on the type of rubber-based compositions to be kneaded, the viscosity of the material during kneading, etc. Therefore, the screw assembly 7 is desirably rotated as fast as possible while monitoring the heat-generating state and appropriately adjusting the cooling capability so that the temperature of the material to be kneaded is properly maintained.
- the control section determines the amount of water injection necessary for keeping the material to be kneaded at a desired temperature, and the highest possible speed of rotation under the temperature and the amount of water injection, and the control section then prepares operational instructions for the injection pumps 3 and 4 as well as a driving motor 21 of the screw assembly 7 . Following the operational instructions, the injection pumps 3 and 4 and the driving motor 21 are operated. Thereby, it is possible to achieve the fastest and most efficient kneading conditions in response to the heat-generating state which changes during kneading.
- the rubber metering feeder does not necessarily include a screw extruding device or a gear pump.
- a device for feeding raw material rubber in the form of sheet or ribbon may be used, in which a sheet/ribbon rubber 23 as a raw material is directly fed to the feed port 12 from a sheet/ribbon stock 22 by a guide roller 24 .
- the kneading apparatus can be also used in the final step in addition to in the remilling step.
- a hopper 26 may be provided on the kneading apparatus so that the various compounding ingredients are fed together with raw material rubber.
- a metering feeder used for the various compounding ingredients which is similar to the rubber metering feeder is also connected the kneading apparatus.
- a sheet forming device may be provided on the front end of the twin-screw kneading extruder as shown in FIG. 7 .
- the sheet forming device includes an extrusion die 27 and a roller head 28 connected to the front end of the twin-screw kneading extruder. Consequently, sheet forming can be performed directly at the front end of the extruder, and by forming a sheet of the kneaded material, cooling is accelerated and handling in the subsequent step is facilitated.
- twin screws are not always required to rotate in the same direction.
- the twin screws may have helical blades so as to extrude the material to be kneaded by rotating in the different directions.
- the kneading blade section does not necessarily have three blades as described in the above embodiment.
- the kneading blade section may be composed of one blade or two blades.
- the kneading blade section may be composed of a plurality of kneading disks.
- the dewatering device may have a mechanism in which dewatering is performed by evaporation due to exposure to air. Thereby, power savings can be achieved. In such a case, it is also possible to remove water while preventing the leakage of the material reliably.
- the kneading extruder is not necessarily of a twin-screw type, and for example, a single-screw kneading extruder may be used.
- the kneading apparatus in accordance with the first embodiment with a twin-screw kneading extruder having a screw diameter of 59 mm. Cooling water at a temperature of 20° C. was injected by the injection pump.
- the rubber-based composition used as a raw material had a Mooney viscosity (100° C.) of 100, and it was continuously fed from the rubber metering feeder in which the temperature was adjusted to 60° C.
- the raw material rubber was fed at a rate of 50 kg/hr and at a rate of 100 kg/hr.
- Kneading was performed by varying the water-injecting conditions and the speed of rotation of the twin-screw kneading extruder, and then the temperature of the kneaded material at the discharge port of the extruder, a decrease in the Mooney viscosity, and the energy required to perform kneading were measured.
- the barrel was indirectly cooled by passing cooling water of 20° C. The results thereof are shown in Table 1.
- Example 1 is compared to Comparative Example in which no water injection was performed but with the same rotation speed, obviously, by injecting water, the temperature can be decreased to a level considerably lower than 160° C. which is considered to be the upper limit for the degradation of rubber physical properties.
- the viscosity is also decreased considerably. This is because the temperature of the rubber is decreased by water cooling and low temperature kneading enables efficient mechanical shearing.
- the above is also supported by the fact that the amount of energy required to perform kneading is large.
- Example 2 When Example 2 is compared to Example 3 in which the amount of water injected was increased to 14% with the same rotation speed, it has been found that the energy required to perform kneading is decreased due to an increase in the amount of water injected. Since a large amount of water is injected, it is believed that slipping of rubber often occurs in the kneading chamber. Testing was also conducted in other examples not shown in Table 1, and as a result, the energy required to perform kneading generally increased up to an injection of several to several ten percent, and at the amount of injection higher than that, the energy maintained equilibrium or decreased.
Abstract
A kneading apparatus includes a barrel having a cylindrical chamber; a screw assembly rotating in the chamber so that a material to be kneaded is extruded in the axial direction by the rotation, the screw assembly including a screw section having helical blades and a kneading blade section in order to allow the material to flow into the clearance between the inner wall of the chamber and the kneading blade section, and to apply shearing forces to the material; a metering feeder for feeding the material at a substantially constant volumetric or gravimetric rate into the chamber; an injecting device for injecting a heat-removing medium into the chamber; and a discharging device for separating the heat-removing medium from the material and discharging the heat-removing medium from the chamber. A kneading method using the kneading apparatus is also disclosed.
Description
- 1. Field of the Invention
- The present invention relates to kneading apparatuses. More particularly, the invention relates to a kneading apparatus used for masticating rubber and for kneading a rubber-based composition in which rubber and various compounding ingredients are mixed, and to a kneading method using the kneading apparatus.
- 2. Description of the Related Art
- In order to produce a kneaded rubber-based composition including rubber and various compounding ingredients, a batch process is often used, in which predetermined amounts of raw materials are intermittently kneaded. However, in order to improve productivity, a method for continuously kneading a rubber-based composition has also been disclosed (Japanese Unexamined Patent Application Publication No. 11-262945). In such a method, a twin-screw extruder, which is a typical kneader for rubber-based compositions, is used. The twin-screw extruder is provided with a rubber feed port, and a rubber-feeding extruder is further connected thereto. Continuous kneading is performed by the twin-screw extruder while continuously feeding the rubber-based composition.
- However, the continuous kneading method according to Japanese Unexamined Patent Application Publication No. 11-262945 is not suitable for rubber-based compositions having high viscosities, and as described in Example 1 in the patent application publication, the method aims to continuously knead a rubber-based composition having a low viscosity, e.g., a Mooney viscosity (100° C.) of approximately 47.
- When a rubber-based composition having a high viscosity, e.g., a Mooney viscosity (100° C.) of more than 100, is kneaded, such as in the case of a composition in which natural rubber as a major ingredient and 30 parts or more of carbon are mixed, kneading treatment is performed to improve the dispersion of various compounding ingredients and also to decrease the viscosity of the rubber-based composition to a viscosity suitable for later processes, such as extrusion molding. The viscosity is decreased because rubber molecular chains are cut due to mechanical shearing. However, heat generation due to mechanical shearing forces applied to rubber increases as the viscosity is increased, and if the temperature becomes excessively high, the physical properties of the rubber are changed, thereby degrading the performance of the rubber. In general, if the temperature exceeds 160° C., the performance of the rubber is hindered. Because of the high viscosity of rubber, the cutting effect of molecular chains due to mechanical shearing is easily demonstrated when kneading is performed at lower temperatures, which is also advantageous in terms of kneading efficiency. In practice, when a rubber-based composition with a high viscosity is kneaded, it is extremely difficult to achieve a predetermined decrease in viscosity and a predetermined degree of dispersion of the compounding ingredients while the materials to be kneaded are maintained at low temperatures so as not to exceed the temperature range required to-ensure the physical properties of the rubber. Therefore, kneading is performed by a batch-type kneader. When the temperature reaches approximately 160° C. during kneading, the materials to be kneaded are recovered from the kneader and cooled to ambient temperature after sheet forming is performed. Kneading is performed again in order to decrease the viscosity. Such a rekneading step is referred to as a remill step.
- However, when a rubber-based composition having a high viscosity is kneaded by the method described above, the remill step is usually repeated several times until the predetermined viscosity is achieved. Remilling is often performed approximately five times. Consequently, the productivity inevitably decreases due to repeated kneading by the batch-type kneader and cooling, and since thermal hysteresis then takes place, alteration of the rubber easily occurs.
- The objects of the present invention are to provide a kneading apparatus for rubber-based compositions having high viscosities in which continuous kneading treatment can be performed without repeated remilling, thus greatly improving productivity, and to provide a kneading method using the kneading apparatus.
- In one aspect of the present invention, a kneading apparatus includes a barrel having a cylindrical chamber; a screw assembly rotating in the chamber so that a material to be kneaded is extruded in the axial direction by the rotation, the screw assembly including a screw section having helical blades and a kneading blade section in order to allow the material to be kneaded to flow into the clearance between the inner wall of the chamber and a kneading blade of the kneading blade section, and to apply shearing forces to the material to be kneaded; a metering feeder for feeding the material to be kneaded at a substantially constant volumetric rate or at a substantially constant gravimetric rate from a feed port provided on the barrel into the chamber; an injecting device provided on the barrel for injecting a heat-removing medium into the chamber; and a discharging device for separating the heat-removing medium which has been injected into the chamber by the injecting device and mixed with the material to be kneaded from the material to be kneaded, and discharging the heat-removing medium from the chamber.
- In the structure described above, continuous kneading can be performed while feeding the material to be kneaded to the kneading extruder at a constant rate, and injection of the heat-removing medium into the chamber and the discharge of the heat-removing medium from the chamber can also be performed continuously. That is, the heat-removing medium removes heat while being mixed with and brought into sufficient contact with the material to be kneaded which generates heat due to kneading, and the heat-removing medium is discharged from the chamber. Therefore, heat-removing treatment of the material to be kneaded can be efficiently performed during kneading.
- Accordingly, by using an apparatus having the structure described above, it is possible to perform kneading treatment in which the viscosity is decreased to a predetermined level without having a high-temperature state even when the material to be kneaded is a rubber-based composition and the heat-removing medium is water. That is, with respect to a rubber-based composition having a high viscosity, continuous kneading treatment can be performed without repeated remilling, resulting in a great improvement in productivity. Additionally, in such a structure, since the positions and numbers of the injecting devices (injecting devices for heat-removing medium) and the discharging devices (discharging devices for heat-removing medium), as well as the amount of injection, can be selected in any given manner, it is possible to adjust the cooling capacity appropriately depending on the characteristics of the rubber-based composition and the kneading extruder.
- For example, when a rubber-based composition is fed at a high temperature or when the temperature of a rubber-based composition is increased while being passed through the rubber metering feeder and the kneading effect is decreased, the rubber-based composition is brought into contact with injected water in the kneading extruder so that the rubber-based composition is cooled primarily by the sensible heat of the water, and the water used for cooling is discharged through the discharging device, such as a slit, provided on the barrel, and thus cooling of the rubber-based composition is accelerated, and then the rubber-based composition may be subjected to the subsequent kneading step.
- Additionally, Japanese Unexamined Patent Application Publication No. 7-227845 discloses a batch-type kneader in which water is added when kneading is performed. The publication relates to a method for reutilizing unvulcanized foamed rubber used for tires which has failed to meet the standards with respect to the expansion rate, dimensional accuracy, etc., and a foaming agent is decomposed and eliminated by kneading the unvulcanized foamed rubber mixed with a small amount of water in a batch-type hermetically closed mixer. That is, there are differences in the problems to be solved and the features between the present invention and Japanese Unexamined Patent Application Publication No. 7-227845.
- Preferably, in the kneading apparatus of the present invention described above, the discharging device for discharging the heat-removing medium includes a vacuum pump connected to the chamber for evacuating the chamber in the region in which the screw section is placed.
- In such a structure, when water is used as the heat-removing medium, the water extruded together with the rubber-based composition to the screw section under reduced pressure is vaporized and sucked out by the vacuum pump, and just water can be eliminated efficiently without discharging the material to be kneaded from the chamber. That is, when water is separated from the material to be kneaded, the water absorbs heat of vaporization from the material to be kneaded, and since the heat of vaporization of water is significantly larger than the temperature-raising heat of water, it is possible to provide an efficient cooling means with a small amount of water. Since water is removed from the material to be kneaded by vaporization, water does not substantially remain in the kneaded material, and thus a discharging device with satisfactory dewaterability can be provided. Since the screw section which is interposed between two kneading blade sections is evacuated, the sealing effect can be displayed due to the material to be kneaded which is loaded in the kneading blade sections, and it is possible to provide a reduced pressure space sufficient for vaporizing water.
- Additionally, in the present invention, the heat-removing medium is not limited to water.
- Preferably, in the kneading apparatus of the present invention described above, the discharging device for the heat-removing medium includes a slit formed in the barrel in the region in which the screw section placed.
- In such a structure, even when water is used as the heat-removing medium and a large amount of cooling water is required, dewatering can be performed efficiently. A dewatering device can be produced with a simple construction. Even if the rubber-based composition to be fed into the kneading extruder is in a high temperature state, it is possible to cool the composition efficiently before kneading treatment is performed.
- Preferably, the kneading apparatus of the present invention further includes at least one gap-adjusting device provided at the outlet of the kneading blade section so as to sandwich the screw assembly, the gap-adjusting device being capable of adjusting a gap formed between the screw assembly and the gap-adjusting device.
- In such a structure, by changing the gap at the outlet of the kneading blade section, i.e., by changing the area through which the material to be kneaded passes, the extruded material to be kneaded is squeezed and the flow resistance of the material to be kneaded is changed, and thus the material residence time in the kneading extruder can be adjusted. That is, it is possible to adjust the filling factor of the material to be kneaded in the kneading blade section, and desired kneading conditions can be easily adjusted.
- Preferably, in the kneading apparatus of the present invention described above, the metering feeder is either a gear pump or a screw extruder connected to the feed port provided on the barrel.
- In such a structure, by using the gear pump or screw extruder as the metering feeder, it is possible to stably feed the material to be kneaded to the kneading extruder at a constant rate. Thereby, variations in the quality of the kneaded product can be suppressed. The form of the material to be kneaded is not particularly limited, and various forms, such as blocks, veils, sheets, and ribbons, may be selected.
- Preferably, the kneading apparatus of the present invention further includes a temperature-measuring section for measuring the temperature of the material to be kneaded in the chamber, and a control section for controlling the amount of the heat-removing medium to be injected into the chamber or the speed of rotation of the screw assembly based on the measured temperature.
- In such a structure, it is possible to change the driving conditions and the cooling conditions of the kneading extruder depending on the temperature of the material to be kneaded during kneading. That is, although the heat-generating state always changes during kneading, it is possible to change the cooling conditions and the speed of rotation appropriately so that the optimum kneading conditions can be achieved.
- In another aspect of the present invention, a method for kneading a rubber-based composition including rubber and compounding ingredients using the kneading apparatus described above includes: a feeding step of feeding the rubber-based composition into the chamber at a substantially constant volumetric rate or at a substantially constant gravimetric rate by the metering feeder; a kneading step of allowing the rubber-based composition to flow into the clearance between the inner wall of the chamber and the kneading blade section and moving the rubber-based composition in the chamber while mixing and dispersing the rubber-based composition by means of shearing forces; a mixing step of injecting a heat-removing medium into the chamber by the injecting device and mixing the rubber-based composition with the heat-removing medium before or during kneading; and a discharging step of separating the heat-removing medium which has been injected into the chamber by the injecting device and mixed with the rubber-based composition from the rubber-based composition and discharging the heat-removing medium by the discharging device.
- In such a method, a rubber-based composition can be continuously kneaded by the kneading extruder and heat removal can be simultaneously performed during kneading. Consequently, even in the case of a rubber-based composition having a high viscosity, kneading treatment can be performed so that the viscosity is decreased to a predetermined level without having a high temperature state. That is, a rubber-based composition having a high viscosity can be continuously kneaded without repeated remilling, resulting in a great improvement in productivity.
-
FIG. 1 is a schematic sectional view of a kneading apparatus for rubber-based compositions, viewed from a side, in a first embodiment of the present invention; -
FIG. 2 is a sectional view taken along the line II-II ofFIG. 1 ; -
FIG. 3 is a schematic sectional view of a kneading apparatus for rubber-based compositions, viewed from a side, in a second embodiment of the present invention; -
FIG. 4 is a schematic sectional view which shows a part of a kneading apparatus for rubber-based compositions in a third embodiment of the present invention; -
FIG. 5 is a schematic diagram of a gate device at a cross section perpendicular to the shafts of the screw assembly; -
FIG. 6 is a schematic diagram showing a kneading apparatus for rubber-based compositions in a fourth embodiment of the present invention; -
FIG. 7 is a schematic diagram showing a modified kneading apparatus for rubber-based compositions; and -
FIG. 8 is a schematic diagram showing another modified kneading apparatus for rubber-based compositions. - A first embodiment of the present invention will be described with reference to
FIG. 1 .FIG. 1 is a schematic sectional view of a kneading apparatus for rubber-based compositions, viewed from a side, in this embodiment. The kneading apparatus includes a co-rotating intermeshing twin-screw kneading extruder 1. Arubber metering feeder 2 is connected to the twin-screw kneading extruder 1, and injection pumps 3 and 4 constituting injecting devices andvacuum pumps - The twin-screw kneading extruder 1 includes a
screw assembly 7 composed of a pair of screws, and abarrel 9 including acylindrical chamber 8 in which the screws rotate. The shafts of the screws are parallel to each other and completely overlap in the side view shown inFIG. 1 . A material to be kneaded is extruded in the axial direction by the rotation of each screw. Thescrew assembly 7 alternately includesscrew sections 7 a (first), 7 c (second), 7 e (third), and 7 g (fourth) having helical blades andkneading blade sections 7 b (first), 7 d (second), 7 f (third), and 7 h (fourth) for allowing the material to be kneaded to flow in the clearance between the inner wall of thechamber 8 and the kneading blade sections and for applying shearing forces to the material to be kneaded. Both screws are connected to a driving device (not shown in the drawing) and are rotated by the driving device. - The helical blades in each screw section are formed along the peripheries of the individual screw shafts so as to extend in the axial direction. The tops of the helical blades are positioned at the same distance from the centers of the shafts of the screws. The pair of screws having the helical blades formed in the same direction rotate in the same direction, and thereby the material to be kneaded is moved rightward in
FIG. 1 . The helical pitches of the helical blades provided in the screw sections are not necessarily the same, and the helical blades may have densely pitched areas and sparsely pitched areas. For example, as will be described below, when water is injected for cooling the material to be kneaded, the helical blades located downstream in the extrusion process may be densely pitched so that the material to be kneaded is subjected to a filling and compressing action, thus providing a dewatering function. When a portion of thechamber 8 is evacuated by suction, the helical blades located in the areas adjacent to the space to be evacuated by suction may be densely pitched, or helical blades or sheets effective in blocking the material to be kneaded may be placed so that the areas adjacent to the space to be evacuated by suction are filled with the material to be kneaded, thereby displaying a sealing effect. Alternatively, reverse flighted screws, which are helical blades formed in the opposite direction, may be partially provided, or rotors or kneading disks as return segments (L segments) in which blades in the opposite direction are formed may be partially provided so that the filling factor of the material to be kneaded is increased, thereby producing a pressurized state. - In each kneading blade section placed between the screw sections, three kneading blades are provided along the periphery of each screw with an angle of 120° therebetween, each kneading blade having a cross section suitable for kneading, i.e., having a shape such that a bite angle to the material to be kneaded is created. Each kneading blade is helically and slowly wound about the screw shaft extending in the axial direction. At the midpoint of each kneading blade section, the helical direction is reversed. Herein, the helical direction of the kneading blades located. upstream in the extrusion process is defined as a normal direction and the helical direction of the kneading blades located downstream is defined as an opposite direction. The materials to be kneaded are transported to the kneading blade section composed of the kneading blades having the normal and opposite helical directions fill the kneading blade section to await kneading. Kneading is performed so that the material to be kneaded is made to flow between the kneading blades of both screws and between the kneading blades having the normal helical direction and the kneading blades having the opposite helical direction.
FIG. 2 is a sectional view taken along the line II-II ofFIG. 1 .FIG. 2 shows the state in which amaterial 11 to be kneaded is kneaded in the clearance between the inner wall of thechamber 8 and thekneading blades 10. Threechip kneading blades 10 are provided along the periphery of each screw shaft with an angle of 120° therebetween and with a bite angle α. Additionally, the midpoint in which the helical direction is reversed is not necessarily located in the exact middle of the kneading blade section, and the midpoint may be placed in the downstream side in the extrusion process so as to accelerate the transport of the material to be kneaded. - With respect to the structure of the
chamber 8, as shown inFIG. 2 , two cylindrical passages in which a pair of screws rotate are placed in parallel and are connected to each other. Thebarrel 9 is constructed so as to form thechamber 8. Thebarrel 9 is composed of detachable units, each unit being a screw section or a kneading blade section. This is because thebarrel 9 is designed so that various combinations of the screw sections and the kneading blade sections can be selected or the numbers of the injecting devices and the discharging devices can be appropriately selected. - Additionally, a cooling jacket for passing a cooling medium may be internally or externally provided on at least one unit constituting the
barrel 9. - A
rubber feed port 12 for feeding a rubber-based composition into thechamber 8 is provided on thefirst screw section 7 a located upstream in the twin-screw kneading extruder 1. As shown inFIG. 1 , therubber metering feeder 2 having a twin screw extruding device is connected to therubber feed port 12. The raw materials of a rubber-based composition are continuously fed into thechamber 8 by the twin-screw extruding device. Therubber metering feeder 2 allows continuous feed of the raw material rubber at a constant rate regardless of the form of the raw material rubber, i.e., the raw material rubber may be in the form of powder or in a lump. Additionally, therubber metering feeder 2 does not necessarily include a twin-screw extruding device, and therubber metering feeder 2 may include a single-screw extruding device, a multi-screw extruding device having more than three screws, or a gear pump. In either case, continuous feed can be performed at a constant rate regardless of the form of the raw material rubber. - In the twin-screw kneading extruder 1, the injection pumps 3 and 4 are connected to
injection ports kneading blade section 7 d and the thirdkneading blade section 7 f are placed, respectively. These elements constitute the injecting devices. Water sent from the injection pumps 3 and 4 is injected into thechamber 8 through theinjection ports - The
vacuum pumps ports third screw section 7 e and thefourth screw section 7 g are placed, respectively. Thechamber 8 can be evacuated by suction in the regions where thethird screw section 7 e and thefourth screw section 7 g are placed by thevacuum pumps second screw section 7 d and thethird screw section 7 f and contained in the material to be kneaded is vaporized and is sucked out by thevacuum pumps - An injecting device is provided in the second
kneading blade section 7 d first because a high-temperature state which requires cooling is not brought about in the firstkneading blade section 7 b and because it may be necessary to accelerate the heat generation of the rubber-based material to a certain extent so that the rubber-based material is plasticized and the sealing effect is displayed in order to remove water under vacuum in the downstream process. In the fourthkneading blade section 7 h in the last stage, an injecting device is not provided because it is not possible to perform dewatering by vacuum in the downstream side. In the meantime, when a rubber-based composition fed into the twin-screw kneading extruder 1 has a high temperature, since the rubber-based composition can display the sealing effect in the firstkneading blade section 7 b, it is possible to inject water in the firstkneading blade section 7 b and to evacuate by suction in the unit between the firstkneading blade section 7 b and the secondkneading blade section 7 d. - Moreover, when a cooling jacket for passing a cooling medium is provided, since indirect cooling is performed in addition to direct cooling by the injection of water, the removal of heat can be more effectively performed from a material to be kneaded which generates heat.
- Additionally, the numbers of the kneading blade sections and the screw sections are not limited to this embodiment, and are preferably selected appropriately depending on the quality of the rubber-based composition to be processed and the desired decreased value of viscosity. The numbers and positions of the injecting devices and the discharging devices are also not limited to this embodiment.
- Next, the operation of the kneading apparatus for rubber-based compositions in the first embodiment of the present invention will be described step by step in the process of producing a kneaded rubber-based composition. First, raw materials for a rubber-based composition including a filler, such as carbon black, and various compounding ingredients in various forms of powder, lump, or sheet are fed into the
rubber metering feeder 2. The raw material rubber fed into therubber metering feeder 2 is transported to thefeed port 12 of the twin-screw kneading extruder 1 at a constant rate by the twin-screw extruding device constituting therubber metering feeder 2. - The raw material rubber fed into the twin-screw kneading extruder 1 at a constant rate through the
feed port 12 is delivered to thechamber 8 at the position where thefirst screw section 7 b is located. At this stage, the screw assembly 7 (a pair of screws) is already being rotated by a driving device (not shown in the drawing). The rubber-based composition as the material to be kneaded is extruded to the firstkneading blade section 7 b by the rotating helical blades of thescrew section 7 b. In the firstkneading blade section 7 b, the material to be kneaded starts to fill between the inner wall of thechamber 8 and the kneading blades, and the material to be kneaded is made to flow and is mixed and dispersed in the clearance between the inner wall of thechamber 8 and the kneading blades while being applied with shearing forces, and thus kneading is performed. - The material kneaded in the first
kneading blade section 7 b moves to thesecond screw section 7 c by being extruded by the material filling the upstream side. The material moved to thesecond screw section 7 c is transported to the secondkneading blade section 7 d by the rotation of the helical blades. - The material transported to the second
kneading blade section 7 d is kneaded again in the same manner as the firstkneading blade section 7 b apart from the fact that water sent from theinjection pump 3 is injected into the secondkneading blade section 7 d through theinjection port 13. Consequently, the material to be kneaded is brought into contact with water during kneading. At this stage, the temperature of the material to be kneaded is increased to a certain extent due to the heat generation during kneading in the firstkneading blade section 7 b, and the temperature is further increased because heat generation occurs during kneading in the secondkneading blade section 7 d. However, since the water injected is mixed with the material to be kneaded and is brought into sufficient contact with the material to be kneaded, heat can be removed from the material to be kneaded. - The material to be kneaded thus cooled by the injection of water is extruded to the
third screw section 7 e by the material moved from the upstream side into the secondkneading blade section 7 d. In thethird screw section 7 e, the material to be kneaded is transported in the same manner as the upstream screw section apart from the fact that the atmospheric gas in thechamber 8 is sucked out by thevacuum pump 5 through thesuction port 15 and a reduced-pressure space is produced. At this stage, the materials filled in the adjacent kneading blade sections display the sealing effect to secure the reduced-pressure space. Alternatively, as described above, the helical blades in the upstream end and the downstream end in thethird screw section 7 e may be densely pitched in the axial direction and the helical blades at the position corresponding to thesuction port 15 may be sparsely pitched so that the material to be kneaded fills the densely pitched area, thereby displaying the sealing effect. - Since the
chamber 8 in which thethird screw section 7 e is evacuated as described above, vaporization and evaporation of the water contained in the material to be kneaded are accelerated. Since heat of vaporization of water is large, it is possible to efficiently remove heat from the material to be kneaded with the addition of a small amount of water. Accordingly, just water used for cooling is separated and dewatering is appropriately performed, and also both absorption of heat by water and removal of heat by vaporization are performed, and thereby cooling can be performed efficiently. - The material to be kneaded in which water is removed in the
third screw section 7 e is transported to the thirdkneading blade section 7 f. In the thirdkneading blade section 7 f, kneading is performed while injecting water again for cooling in the same manner as the secondkneading blade section 7 d. Furthermore, in thefourth screw section 7 g, water is removed in the same manner as thethird screw section 7 e. The material to be kneaded is then transported to the fourthkneading blade section 7 h which is the final stage, and just kneading is performed therein, and then the material is extruded as a lump from the front end into the air. - It is to be understood that the embodiment described above also covers the method for kneading rubber-based compositions in accordance with the present invention.
- A kneading apparatus for rubber-based compositions in a second embodiment of the present invention will now be described.
FIG. 3 is a schematic sectional view of the kneading apparatus in this embodiment. As shown inFIG. 3 , the kneading apparatus includes a twin-screw kneading extruder 1, and arubber metering feeder 2, injection pumps 3 and 4, and avacuum pump 5 connected to the twin-screw kneading extruder 1. The twin-screw kneading extruder 1 includes ascrew assembly 7, achamber 8, and abarrel 9. Thescrew assembly 7 has three screw sections and three kneading blade sections which are placed alternately. In the second embodiment, the injection pumps 3 and 4 are connected to afirst screw section 7 b and a secondkneading blade section 7 d throughinjection ports injection pump 5 is connected to athird screw section 7 e through asuction port 15. The barrel in the region where thefirst screw section 7 b is located is provided with aslit portion 17. In theslit portion 17, slits are formed so as to connect the interior of thechamber 8 to the exterior of thechamber 8. - The kneading apparatus in this embodiment has a structure which is effective in kneading high-temperature raw material rubber directly by the twin-screw kneading extruder. The characteristic operation of the kneading apparatus will be described below.
- For example, a rubber-based composition which has been kneaded to a certain extent by a batch-type mixer or the like and which has a high temperature is fed into the
rubber metering feeder 2. This process is performed, for example, when there is a difficulty in feeding at a constant rate unless the raw material rubber is heated to a temperature that allows plasticization, or in order to omit the step of cooling high temperature rubber. The fed material to be kneaded is transported to the downstream side by thefirst screw section 7 a, and at this stage water is injected from theinjection pump 3 into thechamber 8 through theinjection port 13. Thereby, the high temperature material to be kneaded being transported is brought into contact with water and cooled. The water which comes into contact with water and absorbs heat flows in thechamber 8 and is discharged from theslit portion 17. By appropriately setting the width of slits in theslit portion 17, it is possible to just discharge water used for cooling without discharging the material to be kneaded from thechamber 8. Even when a large amount of cooling water is required, it is possible to efficiently remove the water, and a dewatering device can be produced with a simple construction. - Since the material to be kneaded cooled in the
first screw section 7 a is processed afterward in the same manner as the first embodiment, the description thereof will be omitted. The numbers of the screw sections and the kneading blade sections and the numbers of the injecting devices and the discharging devices are not limited to this embodiment and can be appropriately selected depending on the quality of the rubber-based composition to be processed, the desired reduction value of viscosity, etc. - A kneading apparatus for rubber-based compositions in a third embodiment of the present invention will now be described.
FIG. 4 is a schematic sectional view which shows a part of a kneading apparatus in the third embodiment of the present invention, taken along the shafts of ascrew assembly 7. The kneading apparatus in this embodiment is the same as the first embodiment apart from the fact that agate device 18, which is a gap-adjusting device, is provided between the secondkneading blade section 7 d and thethird screw section 7 e.FIG. 5 is a sectional view of thegate device 18, perpendicular to the shafts of thescrew assembly 7. Thegate device 18 includes twogates 19 located so as to sandwich thescrew assembly 7, and thegates 19 are provided perpendicularly to the shafts of thescrew assembly 7 and so as to be movable in relation to thescrew assembly 7. Thereby, a gap formed between thescrew assembly 7 and thegate 19, i.e., the area through which the material to be kneaded passes, can be adjusted. By changing the gap, the extruded material to be kneaded is squeezed and the flow resistance of the material to be kneaded is changed, and thus the material residence time in the kneading apparatus can be adjusted. That is, it is possible to adjust the filling factor of the material to be kneaded in the kneading blade section, and desired kneading conditions can be easily adjusted. Additionally, thegate device 18 is not limited to the example described above. Gate devices may be provided in a plurality of kneading blade sections and screw sections. A gate device may be composed of two gate rods sandwiching thescrew assembly 7, each rotating without moving perpendicularly. A gate device may have a structure including a conical part provided on thescrew assembly 7 and a slot formed between the conical part and the chamber, in which the chamber and the conical part are relatively moved in the axial direction of thescrew assembly 7. Alternatively, a pin type gate device may be used, such as the one seen in a rubber extruder. - A kneading apparatus for rubber-based compositions in a fourth embodiment of the present invention will now be described.
FIG. 6 is a schematic diagram showing a kneading apparatus in this embodiment. The kneading apparatus is the same as the first embodiment apart from the fact that temperature-measuringsections kneading blade section 7 d and the thirdkneading blade section 7 f. Furthermore, the kneading apparatus includes a control section for controlling the amount of water to be injected into thechamber 8, and the speed of rotation of thescrew assembly 7 based on the temperatures measured, and an input section for transmitting the values measured by the temperature-measuringsections - If the speed of rotation of the
screw assembly 7 is increased, the kneading power is increased. Therefore, high speed revolution is desirable in view of kneading efficiency. However, as the speed of revolution is increased, the amount of heat generated from the material to be kneaded is increased. The heat generated from the material to be kneaded varies depending on the type of rubber-based compositions to be kneaded, the viscosity of the material during kneading, etc. Therefore, thescrew assembly 7 is desirably rotated as fast as possible while monitoring the heat-generating state and appropriately adjusting the cooling capability so that the temperature of the material to be kneaded is properly maintained. - In this embodiment, based on the temperatures measured in the
knead blade sections motor 21 of thescrew assembly 7. Following the operational instructions, the injection pumps 3 and 4 and the drivingmotor 21 are operated. Thereby, it is possible to achieve the fastest and most efficient kneading conditions in response to the heat-generating state which changes during kneading. - It is to be understood that the present invention is not limited to the individual embodiments described above. For example, the embodiments may be modified as follows.
- (1) The rubber metering feeder does not necessarily include a screw extruding device or a gear pump. For example, as in a kneading apparatus for rubber-based compositions shown in
FIG. 7 , a device for feeding raw material rubber in the form of sheet or ribbon may be used, in which a sheet/ribbon rubber 23 as a raw material is directly fed to thefeed port 12 from a sheet/ribbon stock 22 by aguide roller 24. When a directly connected rubber metering feeder, such as a screw extruding type, is used, if the temperature of the raw material rubber to be fed into the twin-screw kneading extruder is not increased sufficiently for plasticization, the constant feed accuracy is decreased, resulting in variations in the kneaded material. Therefore, when a directly connected rubber metering feeder is used, the raw material rubber must be heated to a certain extent, and as a result, with respect to the rubber fed into the twin-screw extruder which preferably has a low temperature, an increase in temperature to a certain extent is unavoidable. However, in accordance with the modified example described above, since it is possible to continuously feed the sheet/ribbon rubber 24 at a constant rate while keeping the low temperature, low temperature kneading is further ensured. - (2) Various compounding ingredients to be mixed with raw material rubber are added to and mixed with the raw material rubber by a batch-type kneader before being kneaded in the kneading apparatus for rubber-based compositions. However, as shown in
FIG. 7 , afeed port 25 for feeding various liquid compounding ingredients directly into the barrel into which raw material rubber is fed may be provided. Thereby, it is possible to knead various compounding ingredients by the twin-screw kneading extruder while feeding the compounding ingredients simultaneously with raw material rubber without preliminarily mixing the compounding ingredients by a batch-type kneader. In such a case, the kneading apparatus can be also used in the final step in addition to in the remilling step. When various compounding ingredients in the form of powders are added, as shown inFIG. 8 , ahopper 26 may be provided on the kneading apparatus so that the various compounding ingredients are fed together with raw material rubber. In such a case, preferably, a metering feeder used for the various compounding ingredients which is similar to the rubber metering feeder is also connected the kneading apparatus. - (3) A sheet forming device may be provided on the front end of the twin-screw kneading extruder as shown in
FIG. 7 . The sheet forming device includes anextrusion die 27 and aroller head 28 connected to the front end of the twin-screw kneading extruder. Consequently, sheet forming can be performed directly at the front end of the extruder, and by forming a sheet of the kneaded material, cooling is accelerated and handling in the subsequent step is facilitated. - (4) With respect to the direction of rotation of the screw assembly, twin screws are not always required to rotate in the same direction. The twin screws may have helical blades so as to extrude the material to be kneaded by rotating in the different directions.
- (5) The kneading blade section does not necessarily have three blades as described in the above embodiment. The kneading blade section may be composed of one blade or two blades. Alternatively, the kneading blade section may be composed of a plurality of kneading disks.
- (6) The dewatering device may have a mechanism in which dewatering is performed by evaporation due to exposure to air. Thereby, power savings can be achieved. In such a case, it is also possible to remove water while preventing the leakage of the material reliably.
- (7) The kneading extruder is not necessarily of a twin-screw type, and for example, a single-screw kneading extruder may be used.
- The present invention will be described more specifically based on the examples. However, it is to be understood that the present invention is not limited to the examples.
- Testing was performed using the kneading apparatus in accordance with the first embodiment with a twin-screw kneading extruder having a screw diameter of 59 mm. Cooling water at a temperature of 20° C. was injected by the injection pump. The rubber-based composition used as a raw material had a Mooney viscosity (100° C.) of 100, and it was continuously fed from the rubber metering feeder in which the temperature was adjusted to 60° C. The raw material rubber was fed at a rate of 50 kg/hr and at a rate of 100 kg/hr. Kneading was performed by varying the water-injecting conditions and the speed of rotation of the twin-screw kneading extruder, and then the temperature of the kneaded material at the discharge port of the extruder, a decrease in the Mooney viscosity, and the energy required to perform kneading were measured. The barrel was indirectly cooled by passing cooling water of 20° C. The results thereof are shown in Table 1.
TABLE 1 Rotation Decrease speed of in Rubber twin- Temperature viscosity feeding screw of rubber (Mooney rate Water extruder discharged viscosity Energy (kg/hr) injection (rpm) (° C.) 100° C.) (kWh/kg) Comparative 50 No 120 161 19 points 0.58 Example injection Example 1 50 7% 120 123 30 points 0.63 injection (3.5% × 2 spots) Example 2 50 7% 250 173 30 points 0.79 injection (3.5% × 2 spots) Example 3 50 14% 250 154 36 points 0.72 injection (7% × 2 spots) - First, testing performed at a rubber feeding rate of 50 kg/hr will be described. When Example 1 is compared to Comparative Example in which no water injection was performed but with the same rotation speed, obviously, by injecting water, the temperature can be decreased to a level considerably lower than 160° C. which is considered to be the upper limit for the degradation of rubber physical properties. The viscosity is also decreased considerably. This is because the temperature of the rubber is decreased by water cooling and low temperature kneading enables efficient mechanical shearing. The above is also supported by the fact that the amount of energy required to perform kneading is large.
- When Example 2 is compared to Example 3 in which the amount of water injected was increased to 14% with the same rotation speed, it has been found that the energy required to perform kneading is decreased due to an increase in the amount of water injected. Since a large amount of water is injected, it is believed that slipping of rubber often occurs in the kneading chamber. Testing was also conducted in other examples not shown in Table 1, and as a result, the energy required to perform kneading generally increased up to an injection of several to several ten percent, and at the amount of injection higher than that, the energy maintained equilibrium or decreased. In the slipping region at an injection of 10% or more, rubber was discharged at low temperatures, the decrease in viscosity was large, and thus, kneading was considered to be performed efficiently with low energy. However, water injected was not vaporized sufficiently, water in the liquid state was partially sucked out by the vacuum pump, and rubber was also sucked out together with water. Therefore, operation must be performed at the appropriate upper limit of water injection depending on the evacuating capability, the volume of the chamber, etc.
- Although the testing results at a rubber feeding rate of 100 kg/hr were not shown in Table 1, the decrease in temperature and the decrease in viscosity due to the injection of water were observed in the same manner as the case at the rate of 50 kg/hr. It has also been found that energy required to perform kneading decreases as the amount of water injected increases in the same manner as the case at the rate of 50 kg/hr.
- Consequently, it has been confirmed that, in accordance with the present invention, it is possible to provide a kneading apparatus for rubber-based compositions having high viscosities in which continuous kneading treatment can be performed without repeated remilling, thus greatly improving productivity, and to provide a kneading method using the kneading apparatus. Additionally, the effects of the examples described above can also be obtained in any embodiment of the present invention and the modifications thereof.
Claims (6)
1. A kneading apparatus comprising:
a barrel having a cylindrical chamber;
a screw assembly rotating in the chamber for extruding a material to be kneaded in the axial direction, said screw assembly comprising a screw section having helical blades and a kneading blade section for allowing the material to flow into the clearance between the inner wall of the chamber and a kneading blade of said kneading blade section, and for applying shearing forces to the material to be kneaded;
a metering feeder for feeding the material at a substantially constant volumetric rate or at a substantially constant gravimetric rate from a feed port provided on the barrel into the chamber;
an injecting device provided on the barrel for injecting a heat-removing liquid medium into a first portion of the chamber; and
a discharging device including a reduced pressure producing device for separating the heat-removing medium from the material at a second portion of the chamber downstream from the first portion; and
means for densely filling the material to be kneaded at positions adjacent the second portion of the chamber, and for sealing the second portion of the chamber such that said reduced pressure producing device can provide a reduced pressure at said second portion.
2-10. (canceled)
11. The kneading apparatus according to claim 1 , wherein said means for densely filling the material to be kneaded at positions adjacent the second portion of the chamber comprises an increased density of a pitch for the helical blades at positions adjacent the second portion of the chamber.
12. The kneading apparatus according to claim 1 , wherein said means for densely filling the material to be kneaded at positions adjacent the second portion of the chamber comprises helical blades or sheets capable of blocking the material to be kneaded.
13. The kneading apparatus according to claim 1 , wherein said means for densely filling the material to be kneaded at positions adjacent the second portion of the chamber comprises reverse flighted screws.
14. The kneading apparatus according to claim 1 , wherein said means for densely filling the material to be kneaded at positions adjacent the second portion of the chamber comprises rotors or kneading disks as return segments.
Priority Applications (2)
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US11/249,633 US20060034147A1 (en) | 2001-04-25 | 2005-10-14 | Kneading apparatus and method for kneading rubber-based composition using the same |
US13/205,265 US8177412B2 (en) | 2001-04-25 | 2011-08-08 | Kneading apparatus and method for kneading rubber-based composition using the same |
Applications Claiming Priority (4)
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JP2001127684A JP3868757B2 (en) | 2001-04-25 | 2001-04-25 | Rubber composition kneading apparatus and kneading method |
JP2001-127684 | 2001-04-25 | ||
US10/123,253 US7004616B2 (en) | 2001-04-25 | 2002-04-17 | Kneading apparatus and method for kneading rubber-based composition using the same |
US11/249,633 US20060034147A1 (en) | 2001-04-25 | 2005-10-14 | Kneading apparatus and method for kneading rubber-based composition using the same |
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US10/123,253 Continuation US7004616B2 (en) | 2001-04-25 | 2002-04-17 | Kneading apparatus and method for kneading rubber-based composition using the same |
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US13/205,265 Continuation US8177412B2 (en) | 2001-04-25 | 2011-08-08 | Kneading apparatus and method for kneading rubber-based composition using the same |
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US20060034147A1 true US20060034147A1 (en) | 2006-02-16 |
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US10/123,253 Expired - Fee Related US7004616B2 (en) | 2001-04-25 | 2002-04-17 | Kneading apparatus and method for kneading rubber-based composition using the same |
US11/249,633 Abandoned US20060034147A1 (en) | 2001-04-25 | 2005-10-14 | Kneading apparatus and method for kneading rubber-based composition using the same |
US13/205,265 Expired - Fee Related US8177412B2 (en) | 2001-04-25 | 2011-08-08 | Kneading apparatus and method for kneading rubber-based composition using the same |
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US10/123,253 Expired - Fee Related US7004616B2 (en) | 2001-04-25 | 2002-04-17 | Kneading apparatus and method for kneading rubber-based composition using the same |
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US13/205,265 Expired - Fee Related US8177412B2 (en) | 2001-04-25 | 2011-08-08 | Kneading apparatus and method for kneading rubber-based composition using the same |
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US (3) | US7004616B2 (en) |
EP (1) | EP1252999B1 (en) |
JP (1) | JP3868757B2 (en) |
KR (1) | KR100483415B1 (en) |
CN (1) | CN100418719C (en) |
AT (1) | ATE454256T1 (en) |
DE (1) | DE60234976D1 (en) |
TW (1) | TW586962B (en) |
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US8177412B2 (en) | 2001-04-25 | 2012-05-15 | Kobe Steel, Ltd. | Kneading apparatus and method for kneading rubber-based composition using the same |
US7083320B2 (en) * | 2001-11-15 | 2006-08-01 | Kobe Steel, Ltd. | Kneading apparatus and method, including selectable supply ports, for kneading rubber or rubber compositions |
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Also Published As
Publication number | Publication date |
---|---|
JP3868757B2 (en) | 2007-01-17 |
TW586962B (en) | 2004-05-11 |
CN1382573A (en) | 2002-12-04 |
ATE454256T1 (en) | 2010-01-15 |
DE60234976D1 (en) | 2010-02-25 |
US20020186612A1 (en) | 2002-12-12 |
CN100418719C (en) | 2008-09-17 |
EP1252999A1 (en) | 2002-10-30 |
JP2002321214A (en) | 2002-11-05 |
US8177412B2 (en) | 2012-05-15 |
US20110292755A1 (en) | 2011-12-01 |
KR20020082788A (en) | 2002-10-31 |
EP1252999B1 (en) | 2010-01-06 |
KR100483415B1 (en) | 2005-04-15 |
US7004616B2 (en) | 2006-02-28 |
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