US20070028650A1 - Method for introducing blowing air into glass container forming machine molds - Google Patents
Method for introducing blowing air into glass container forming machine molds Download PDFInfo
- Publication number
- US20070028650A1 US20070028650A1 US11/298,759 US29875905A US2007028650A1 US 20070028650 A1 US20070028650 A1 US 20070028650A1 US 29875905 A US29875905 A US 29875905A US 2007028650 A1 US2007028650 A1 US 2007028650A1
- Authority
- US
- United States
- Prior art keywords
- annular member
- recess
- valve
- collar
- plunger
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Abandoned
Links
- 239000011521 glass Substances 0.000 title claims abstract description 21
- 238000000034 method Methods 0.000 title claims abstract description 16
- 238000007664 blowing Methods 0.000 title description 5
- 239000012530 fluid Substances 0.000 claims description 7
- 230000005484 gravity Effects 0.000 claims description 3
- 229910000831 Steel Inorganic materials 0.000 description 1
- 239000000463 material Substances 0.000 description 1
- 239000007769 metal material Substances 0.000 description 1
- 238000012986 modification Methods 0.000 description 1
- 230000004048 modification Effects 0.000 description 1
- 239000010959 steel Substances 0.000 description 1
Images
Classifications
-
- C—CHEMISTRY; METALLURGY
- C03—GLASS; MINERAL OR SLAG WOOL
- C03B—MANUFACTURE, SHAPING, OR SUPPLEMENTARY PROCESSES
- C03B9/00—Blowing glass; Production of hollow glass articles
- C03B9/30—Details of blowing glass; Use of materials for the moulds
- C03B9/36—Blow heads; Supplying, ejecting or controlling the air
- C03B9/3645—Details thereof relating to plungers
-
- C—CHEMISTRY; METALLURGY
- C03—GLASS; MINERAL OR SLAG WOOL
- C03B—MANUFACTURE, SHAPING, OR SUPPLEMENTARY PROCESSES
- C03B9/00—Blowing glass; Production of hollow glass articles
- C03B9/13—Blowing glass; Production of hollow glass articles in gob feeder machines
- C03B9/14—Blowing glass; Production of hollow glass articles in gob feeder machines in "blow" machines or in "blow-and-blow" machines
- C03B9/16—Blowing glass; Production of hollow glass articles in gob feeder machines in "blow" machines or in "blow-and-blow" machines in machines with turn-over moulds
- C03B9/165—Details of such machines, e.g. guide funnels, turn-over mechanisms
Definitions
- This invention relates to a method of and an apparatus for introducing counterblow blowing air into glass gobs in blank molds of a glass container forming machine of the individual section (I.S.) type.
- FIG. 1 illustrates a series of steps that are followed in producing hollow glass containers from gobs of glass at a formable temperature on a glass container forming machine of the I.S. type by a process known as the blow and blow process.
- a preform of a glass container is formed in an inverted orientation, that is, with its open end down, in a first stage mold, which is often called a blank mold.
- the preform which is often called a blank or a parison, is then transferred by an inverting operation through an arc of 180° into a second stage mold, which is often called a blow mold, where the preform, is blown into its final configuration.
- View C of FIG. 2 of the '764 patent illustrates a step in the blow and blow process that is described as the counterblow step, a step in which blowing air is injected into a parison after the parison is properly settled at the bottom of the blank mold.
- counterblow air for use in the blow and blow process as practiced on an I.S. machine has been introduced into a gob of glass in the I.S. forming machine blank mold through a plunger that reciprocates with respect to the mold, and the glass gob therein that is to be blown into the desired shape of a parison, the counterblow air being blown only when the plunger is in its down position.
- This step is taught, for example, by the aforesaid Fortner et al. '548 patent at column 5, lines 49-57.
- a counterblow air introduction plunger that need not, and does not, reciprocate with respect to the gob and the mold during the introduction of counterblow air through the plunger.
- the plunger of the present invention has a non-reciprocating annular member that is positioned beneath the blank mold of the I.S. machine, and it also has a sliding valve member that reciprocates with respect to the annular member.
- the sliding member has a thin stem with an outwardly expanding frustoconical end that seats against a frustoconical surface of the annular member when no counterblow air is passing through the plunger.
- the valve also has an annular collar that is threadably secured to the stem of the sliding member, and the collar has a circumferential plurality of air passages passing therethrough. The collar slides within a recess of the annular member, to which blowing air is intermittently introduced, and is pressurized to unseat the frustoconical end of the sliding member from the frustoconical seat of the annular member to permit the blowing air to pass into the gob only when the recess of the annular member is pressurized.
- the sliding member Upon depressurization of the recess in the annular member, the sliding member will return, by gravity, to its seated position. In this way, the plunger remains in contact with the finish of the parison that is being blown throughout the counterblow step, and thereby avoids problems of distortion of the corkage of the parison finish that previously could occur during the counterblow step when proceeding by conventional teachings with respect to counterblowing of glass parisons.
- FIG. 1 is a partly schematic, elevational view, in cross-section and in a first condition of its operation, of a plunger according to a preferred embodiment of the present invention for introducing counterblow air into a blank mold of an I.S. glass container forming machine;
- FIG. 2 is a sectional view taken on line 2 - 2 of FIG. 1 ;
- FIG. 3 is a view like FIG. 1 showing the plunger depicted therein in a different condition of its operation.
- a counterblow air introduction plunger according to the preferred embodiment of the present invention is generally indicated by reference numeral 10 .
- the plunger 10 is made up of an annular housing member 12 , which does not reciprocate in operation with respect to a blank mold of an I.S. machine (not shown), a valve member 14 , which, in operation, slidingly reciprocates relative to the annular member 12 along a longitudinal central axis of the annular member 12 , and a collar 16 , which is secured to a stem portion 14 a of the valve member 14 to reciprocate therewith.
- the collar 16 moves slidingly to and fro within an enlarged recess portion 12 a at an inlet end of the annular member 12 , and the collar 16 has a circumferentially spaced-apart plurality of fluid flow passages 16 a extending therethrough, for purposes that will be hereinafter described more fully.
- the valve member 14 also has an upwardly extending, enlarged frustoconical portion 14 b at is upper free end, and, in a first position of the valve member 14 , as shown in FIG. 1 , the portion 14 b seats against an upper, upwardly expanding, frustoconical portion 12 b of the annular member 12 to block fluid flow through the plunger 10 .
- the travel of the valve member 14 with respect to the annular member 12 is limited by the position of the collar 16 on the stem 14 a of the valve member 14 , because the collar 16 cannot travel beyond a position in contact with a radial shoulder 12 c at an upper end of the recess 12 a of the annular member 12 .
- the recess 12 a of the annular member 12 further has a reduced diameter portion 12 d positioned axially inwardly of the shoulder 12 c for purposes that will be hereinafter described more fully.
- Counterblow air is intermittently delivered to the recess 12 a of the annular member 14 through an inlet line 20 , which is shown schematically, the air inlet line 20 having an on/off valve 22 therein to control the timing of the flow of the counterblow air to the annular member 12 .
- the recess 12 a is pressurized by the flow of counterblow air through the inlet line 20 , the pressure therein will pressurize an underside of the collar 16 , to cause the collar 16 and the valve member 14 jointly to elevate with respect to the annular member 12 , as shown in FIG. 3 .
- the collar 15 is threadably secured to an externally threaded portion 14 c of the stem portion 14 a of the valve member 14 , so that the collar 15 will engage the shoulder 12 a of the annular member 12 at an earlier or later position in the travel of the valve member 14 with respect to the annular member 12 , as desired.
- any pressurized air remaining in the recess 12 a of the annular member can escape into the reduced diameter portion 12 d through the passages 16 a and from there outwardly from the plunger 10 through an annulus between the valve portion 14 b of the valve member 14 and the valve seat 12 b of the annular member.
- the annular member 12 , the valve member 14 and the collar 16 of the plunger 10 are each formed of a suitable metallic material, preferably a heat-resistant grade of steel in view of the high temperatures that prevail in a region near blank molds of an I.S. machine. Such material has sufficient density to provide sufficient mass to the subassembly that includes the valve member 14 and the collar 16 to return it from the FIG. 3 position to the FIG. 1 position when the recess 12 a is depressurized, without the need for a return spring between an upper face of the collar 16 and the shoulder 12 c of the annular member 12 .
- a suitable metallic material preferably a heat-resistant grade of steel in view of the high temperatures that prevail in a region near blank molds of an I.S. machine.
- Such material has sufficient density to provide sufficient mass to the subassembly that includes the valve member 14 and the collar 16 to return it from the FIG. 3 position to the FIG. 1 position when the recess 12 a is depressurized, without the need for
Abstract
A method for intermittently delivering counterblow air to a gob glass at a formable temperature in a blank mold of an I.S. glass container forming machine being operated on the blow and blow process. The method utilizes a plunger having a fixed annular member with an enlarged recess at an inlet end and a valve seat at an upper end. The plunger has a sliding valve member with an annulus of the annular member, and the valve member has a stem portion and an enlarged vale seat portion at a free end thereof. Pressurized air is intermittently delivered to the recess of the annular member to urge a collar secured to the stem of a sliding valve of the plunger upwardly to unseat the valve portion from the seat of the annular member.
Description
- This is a division of application Ser. No. 10/172,550 filed Jun. 13, 2002.
- This invention relates to a method of and an apparatus for introducing counterblow blowing air into glass gobs in blank molds of a glass container forming machine of the individual section (I.S.) type.
- U.S. Pat. No. 4,364,764 (Farkas et al.), the disclosure of which is incorporated by reference herein, in
FIG. 1 , illustrates a series of steps that are followed in producing hollow glass containers from gobs of glass at a formable temperature on a glass container forming machine of the I.S. type by a process known as the blow and blow process. In the blow and blow process as practiced on an I.S. machine, a preform of a glass container is formed in an inverted orientation, that is, with its open end down, in a first stage mold, which is often called a blank mold. The preform, which is often called a blank or a parison, is then transferred by an inverting operation through an arc of 180° into a second stage mold, which is often called a blow mold, where the preform, is blown into its final configuration. View C of FIG. 2 of the '764 patent illustrates a step in the blow and blow process that is described as the counterblow step, a step in which blowing air is injected into a parison after the parison is properly settled at the bottom of the blank mold. - U.S. Pat. No. 4,191,548 (Fortner et al.), the disclosure of which is also incorporated by reference herein, discloses specific apparatus for introducing counterblow air into a glass perform in a blank mold of an I.S. machine that is operated on the blow and blow process.
- Heretofore, counterblow air for use in the blow and blow process as practiced on an I.S. machine has been introduced into a gob of glass in the I.S. forming machine blank mold through a plunger that reciprocates with respect to the mold, and the glass gob therein that is to be blown into the desired shape of a parison, the counterblow air being blown only when the plunger is in its down position. This step is taught, for example, by the aforesaid Fortner et al. '548 patent at column 5, lines 49-57. The step of withdrawing the plunger during introduction of counterblow air can, however, lead to the distortion of the “corkage” of the finish portion of the parison, as the term “corkage” is used in the aforesaid '548 patent.
- To avoid the aforesaid and other problems associated with the introduction of counterblow air into a glass gob to be blown into a parison in a blank mold of an I.S. glass container forming machine, there is provided a counterblow air introduction plunger that need not, and does not, reciprocate with respect to the gob and the mold during the introduction of counterblow air through the plunger. The plunger of the present invention has a non-reciprocating annular member that is positioned beneath the blank mold of the I.S. machine, and it also has a sliding valve member that reciprocates with respect to the annular member. The sliding member has a thin stem with an outwardly expanding frustoconical end that seats against a frustoconical surface of the annular member when no counterblow air is passing through the plunger. The valve also has an annular collar that is threadably secured to the stem of the sliding member, and the collar has a circumferential plurality of air passages passing therethrough. The collar slides within a recess of the annular member, to which blowing air is intermittently introduced, and is pressurized to unseat the frustoconical end of the sliding member from the frustoconical seat of the annular member to permit the blowing air to pass into the gob only when the recess of the annular member is pressurized. Upon depressurization of the recess in the annular member, the sliding member will return, by gravity, to its seated position. In this way, the plunger remains in contact with the finish of the parison that is being blown throughout the counterblow step, and thereby avoids problems of distortion of the corkage of the parison finish that previously could occur during the counterblow step when proceeding by conventional teachings with respect to counterblowing of glass parisons.
- Accordingly, it is an object of the present invention to provide an improved method of, and an apparatus for, introducing counterblow air into a gob of glass in a blank mold of an I.S. glass container forming machine. More particularly, it is an object of the present invention to provide a method and an apparatus of the foregoing character in which it is unnecessary to withdraw a counterblow air introduction plunger with respect to other structure of the blank mold during the counterblow air introduction step, to thereby avoid distortion of the corkage of the finish of the parison that is being formed in the blank mold.
- For a further understanding of the present invention and the objects thereof, attention is directed to the drawing and the following brief description thereof, to the detailed description of the invention and to the appended claims.
-
FIG. 1 is a partly schematic, elevational view, in cross-section and in a first condition of its operation, of a plunger according to a preferred embodiment of the present invention for introducing counterblow air into a blank mold of an I.S. glass container forming machine; -
FIG. 2 is a sectional view taken on line 2-2 ofFIG. 1 ; and -
FIG. 3 is a view likeFIG. 1 showing the plunger depicted therein in a different condition of its operation. - A counterblow air introduction plunger according to the preferred embodiment of the present invention is generally indicated by
reference numeral 10. Theplunger 10 is made up of anannular housing member 12, which does not reciprocate in operation with respect to a blank mold of an I.S. machine (not shown), avalve member 14, which, in operation, slidingly reciprocates relative to theannular member 12 along a longitudinal central axis of theannular member 12, and acollar 16, which is secured to astem portion 14 a of thevalve member 14 to reciprocate therewith. Thecollar 16 moves slidingly to and fro within an enlargedrecess portion 12 a at an inlet end of theannular member 12, and thecollar 16 has a circumferentially spaced-apart plurality offluid flow passages 16 a extending therethrough, for purposes that will be hereinafter described more fully. - The
valve member 14 also has an upwardly extending, enlarged frustoconical portion 14 b at is upper free end, and, in a first position of thevalve member 14, as shown inFIG. 1 , the portion 14 b seats against an upper, upwardly expanding,frustoconical portion 12 b of theannular member 12 to block fluid flow through theplunger 10. The travel of thevalve member 14 with respect to theannular member 12 is limited by the position of thecollar 16 on thestem 14 a of thevalve member 14, because thecollar 16 cannot travel beyond a position in contact with aradial shoulder 12 c at an upper end of therecess 12 a of theannular member 12. Therecess 12 a of theannular member 12 further has a reduceddiameter portion 12 d positioned axially inwardly of theshoulder 12 c for purposes that will be hereinafter described more fully. - Counterblow air is intermittently delivered to the
recess 12 a of theannular member 14 through aninlet line 20, which is shown schematically, theair inlet line 20 having an on/offvalve 22 therein to control the timing of the flow of the counterblow air to theannular member 12. When therecess 12 a is pressurized by the flow of counterblow air through theinlet line 20, the pressure therein will pressurize an underside of thecollar 16, to cause thecollar 16 and thevalve member 14 jointly to elevate with respect to theannular member 12, as shown inFIG. 3 . This will then permit pressurized air from therecess 12 a to flow through thepassages 16 a, and thereafter to escape in an annular gap between the portion 14 b of thevalve member 14 and thevalve seat 12 b of theannular member 12 to counterblow a gob of glass at a formable temperature in the blank mold with which theplunger 10 is associated. Upon the closing of thevalve 22, therecess 12 a will become depressurized, and this will permit thevalve member 14 and thecollar 16 to jointly return, by gravity, from theFIG. 3 position to theFIG. 1 position whereupon the portion 14 b of thevalve member 14 will be seated against thevalve seat 12 b of theannular member 12 to block further air flow through theannular member 12. To control the distance by which thevalve member 14 may rise with respect to theannular member 12, the collar 15 is threadably secured to an externally threaded portion 14 c of thestem portion 14 a of thevalve member 14, so that the collar 15 will engage theshoulder 12 a of theannular member 12 at an earlier or later position in the travel of thevalve member 14 with respect to theannular member 12, as desired. In that case, any pressurized air remaining in therecess 12 a of the annular member can escape into the reduceddiameter portion 12 d through thepassages 16 a and from there outwardly from theplunger 10 through an annulus between the valve portion 14 b of thevalve member 14 and thevalve seat 12 b of the annular member. - The
annular member 12, thevalve member 14 and thecollar 16 of theplunger 10 are each formed of a suitable metallic material, preferably a heat-resistant grade of steel in view of the high temperatures that prevail in a region near blank molds of an I.S. machine. Such material has sufficient density to provide sufficient mass to the subassembly that includes thevalve member 14 and thecollar 16 to return it from theFIG. 3 position to theFIG. 1 position when therecess 12 a is depressurized, without the need for a return spring between an upper face of thecollar 16 and theshoulder 12 c of theannular member 12. - Because the
annular member 12 stays in position during the passage of counterblow air therethrough, problems of distortion of the corkage in a finish portion of the parison being formed by the counterblow air, which characterized prior art counterblow air introduction systems that relied on a retractable plunger to permit counterblow air to flow into a gob being formed into a parison in a blank mold, are avoided. - Although the best mode contemplated by the inventor for carrying out the present invention as of the filing date hereof has been shown and described herein, it will be apparent to those skilled in the art that suitable modifications, variations, and equivalents may be made without departing from the scope of the invention, such scope being limited solely by the terms of the following claims and legal equivalents thereof.
Claims (3)
1-10. (canceled)
11. The method of introducing counterblow air into a gob of glass at a formable temperature in a blank mold of an I.S. glass container forming machine after the gob has settled in the blank mold, the method comprising:
providing a non-reciprocatable annular member, the annular member having a seat at an uppermost end thereof and an enlarged recess in a lowermost end thereof;
providing a sliding valve member with an enlarged valve portion at an uppermost end thereof and a stem extending downwardly from the valve portion, the sliding member being reciprocatable with respect to the annular member to move between a first position, where the valve portion seats against the seat of the annular member to block fluid flow through the annular member, and a second position, where the valve portion is unseated from the seat of the annular member to permit fluid flow through the annular member;
providing a collar on the stem of said sliding valve member to be reciprocatable with the sliding valve member with respect to the annular member, the collar being slidable within the recess of the annular member and having at least one fluid flow passage extending therethrough;
pressurizing the recess of the annular member with a fluid that acts on an underside of the collar to urge the collar upwardly, and thereby move the sliding valve member from the first position to the second position; and then
depressurizing the recess of the annular member to cause the sliding valve member to return, by gravity, to the first position.
12. The method according to claim 11 wherein the fluid is compressed air.
Priority Applications (1)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
US11/298,759 US20070028650A1 (en) | 2002-06-13 | 2005-12-09 | Method for introducing blowing air into glass container forming machine molds |
Applications Claiming Priority (2)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
US10/172,550 US7003982B2 (en) | 2002-06-13 | 2002-06-13 | Apparatus for introducing blowing air into glass container forming machine molds |
US11/298,759 US20070028650A1 (en) | 2002-06-13 | 2005-12-09 | Method for introducing blowing air into glass container forming machine molds |
Related Parent Applications (1)
Application Number | Title | Priority Date | Filing Date |
---|---|---|---|
US10/172,550 Division US7003982B2 (en) | 2002-06-13 | 2002-06-13 | Apparatus for introducing blowing air into glass container forming machine molds |
Publications (1)
Publication Number | Publication Date |
---|---|
US20070028650A1 true US20070028650A1 (en) | 2007-02-08 |
Family
ID=29583894
Family Applications (2)
Application Number | Title | Priority Date | Filing Date |
---|---|---|---|
US10/172,550 Expired - Lifetime US7003982B2 (en) | 2002-06-13 | 2002-06-13 | Apparatus for introducing blowing air into glass container forming machine molds |
US11/298,759 Abandoned US20070028650A1 (en) | 2002-06-13 | 2005-12-09 | Method for introducing blowing air into glass container forming machine molds |
Family Applications Before (1)
Application Number | Title | Priority Date | Filing Date |
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US10/172,550 Expired - Lifetime US7003982B2 (en) | 2002-06-13 | 2002-06-13 | Apparatus for introducing blowing air into glass container forming machine molds |
Country Status (13)
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US (2) | US7003982B2 (en) |
EP (1) | EP1371615B1 (en) |
JP (1) | JP4271504B2 (en) |
CN (1) | CN1315744C (en) |
AR (1) | AR040213A1 (en) |
AU (1) | AU2003204686A1 (en) |
BR (1) | BR0302069A (en) |
CA (1) | CA2390760A1 (en) |
MX (1) | MXPA03005173A (en) |
PE (1) | PE20040143A1 (en) |
PL (1) | PL360647A1 (en) |
RU (1) | RU2003117473A (en) |
ZA (1) | ZA200304593B (en) |
Families Citing this family (6)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
US7073352B2 (en) * | 2002-03-07 | 2006-07-11 | Vitro Global, S.A. | Method and a machine for the production of hollow glassware articles |
US6907756B2 (en) * | 2002-10-28 | 2005-06-21 | Joseph W. Kozora | Plunger for bottle forming I.S. machine |
US9440761B2 (en) * | 2010-05-31 | 2016-09-13 | Owens-Brockway Glass Container Inc. | Process and equipment for the fabrication of glass containers with internally threaded neck |
US8701444B2 (en) * | 2012-06-22 | 2014-04-22 | Owens-Brockway Glass Container Inc. | Plunger and parison mold assembly for a narrow-neck press-and-blow wine bottle |
FR2993879B1 (en) * | 2012-07-30 | 2016-12-09 | Pochet Du Courval | METHOD AND INSTALLATION FOR MANUFACTURING A HOLLOW GLASS ARTICLE HAVING A SPECIFIC GLASS INTERIOR DISTRIBUTION |
CN116395940B (en) * | 2023-03-17 | 2024-02-13 | 江苏新奥得玻璃制品股份有限公司 | Glass wine bottle blowing equipment and blowing method thereof |
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US2001764A (en) * | 1932-07-27 | 1935-05-21 | Howard W Stepp | Core drill and valve therefor |
US2725683A (en) * | 1953-01-26 | 1955-12-06 | Compule Corp | Method of blowing hollow glass vials |
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-
2002
- 2002-06-13 US US10/172,550 patent/US7003982B2/en not_active Expired - Lifetime
- 2002-06-14 CA CA002390760A patent/CA2390760A1/en not_active Abandoned
-
2003
- 2003-06-10 MX MXPA03005173A patent/MXPA03005173A/en active IP Right Grant
- 2003-06-10 EP EP03013100.7A patent/EP1371615B1/en not_active Expired - Lifetime
- 2003-06-11 RU RU2003117473/03A patent/RU2003117473A/en not_active Application Discontinuation
- 2003-06-12 CN CNB031438784A patent/CN1315744C/en not_active Expired - Fee Related
- 2003-06-12 ZA ZA200304593A patent/ZA200304593B/en unknown
- 2003-06-12 AU AU2003204686A patent/AU2003204686A1/en not_active Abandoned
- 2003-06-12 AR ARP030102106A patent/AR040213A1/en unknown
- 2003-06-12 PL PL03360647A patent/PL360647A1/en not_active Application Discontinuation
- 2003-06-12 PE PE2003000588A patent/PE20040143A1/en not_active Application Discontinuation
- 2003-06-13 BR BR0302069-0A patent/BR0302069A/en not_active IP Right Cessation
- 2003-06-13 JP JP2003169657A patent/JP4271504B2/en not_active Expired - Fee Related
-
2005
- 2005-12-09 US US11/298,759 patent/US20070028650A1/en not_active Abandoned
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US3209401A (en) * | 1960-07-14 | 1965-10-05 | Mehnert Gottfried | Blowing nozzle for blowing machines |
US3171732A (en) * | 1961-07-31 | 1965-03-02 | Chem Met Anderson Engineering | Glass bottle parison machine |
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Also Published As
Publication number | Publication date |
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BR0302069A (en) | 2004-08-17 |
JP4271504B2 (en) | 2009-06-03 |
EP1371615A3 (en) | 2006-02-08 |
MXPA03005173A (en) | 2004-09-06 |
EP1371615B1 (en) | 2017-04-05 |
US7003982B2 (en) | 2006-02-28 |
PL360647A1 (en) | 2003-12-15 |
US20030230115A1 (en) | 2003-12-18 |
CN1496963A (en) | 2004-05-19 |
CA2390760A1 (en) | 2003-12-13 |
JP2004018373A (en) | 2004-01-22 |
EP1371615A2 (en) | 2003-12-17 |
ZA200304593B (en) | 2004-04-29 |
AU2003204686A1 (en) | 2004-01-15 |
PE20040143A1 (en) | 2004-03-22 |
AR040213A1 (en) | 2005-03-16 |
CN1315744C (en) | 2007-05-16 |
RU2003117473A (en) | 2004-12-10 |
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