US20090158978A1 - Method of controlling a process of generating power by oxyfuel combustion - Google Patents
Method of controlling a process of generating power by oxyfuel combustion Download PDFInfo
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- US20090158978A1 US20090158978A1 US11/960,958 US96095807A US2009158978A1 US 20090158978 A1 US20090158978 A1 US 20090158978A1 US 96095807 A US96095807 A US 96095807A US 2009158978 A1 US2009158978 A1 US 2009158978A1
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- exhaust gas
- flow rate
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- F—MECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
- F23—COMBUSTION APPARATUS; COMBUSTION PROCESSES
- F23C—METHODS OR APPARATUS FOR COMBUSTION USING FLUID FUEL OR SOLID FUEL SUSPENDED IN A CARRIER GAS OR AIR
- F23C9/00—Combustion apparatus characterised by arrangements for returning combustion products or flue gases to the combustion chamber
- F23C9/003—Combustion apparatus characterised by arrangements for returning combustion products or flue gases to the combustion chamber for pulverulent fuel
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- F—MECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
- F23—COMBUSTION APPARATUS; COMBUSTION PROCESSES
- F23L—SUPPLYING AIR OR NON-COMBUSTIBLE LIQUIDS OR GASES TO COMBUSTION APPARATUS IN GENERAL ; VALVES OR DAMPERS SPECIALLY ADAPTED FOR CONTROLLING AIR SUPPLY OR DRAUGHT IN COMBUSTION APPARATUS; INDUCING DRAUGHT IN COMBUSTION APPARATUS; TOPS FOR CHIMNEYS OR VENTILATING SHAFTS; TERMINALS FOR FLUES
- F23L7/00—Supplying non-combustible liquids or gases, other than air, to the fire, e.g. oxygen, steam
- F23L7/007—Supplying oxygen or oxygen-enriched air
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- F—MECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
- F23—COMBUSTION APPARATUS; COMBUSTION PROCESSES
- F23C—METHODS OR APPARATUS FOR COMBUSTION USING FLUID FUEL OR SOLID FUEL SUSPENDED IN A CARRIER GAS OR AIR
- F23C2202/00—Fluegas recirculation
- F23C2202/30—Premixing fluegas with combustion air
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- F—MECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
- F23—COMBUSTION APPARATUS; COMBUSTION PROCESSES
- F23C—METHODS OR APPARATUS FOR COMBUSTION USING FLUID FUEL OR SOLID FUEL SUSPENDED IN A CARRIER GAS OR AIR
- F23C2202/00—Fluegas recirculation
- F23C2202/50—Control of recirculation rate
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- F—MECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
- F23—COMBUSTION APPARATUS; COMBUSTION PROCESSES
- F23L—SUPPLYING AIR OR NON-COMBUSTIBLE LIQUIDS OR GASES TO COMBUSTION APPARATUS IN GENERAL ; VALVES OR DAMPERS SPECIALLY ADAPTED FOR CONTROLLING AIR SUPPLY OR DRAUGHT IN COMBUSTION APPARATUS; INDUCING DRAUGHT IN COMBUSTION APPARATUS; TOPS FOR CHIMNEYS OR VENTILATING SHAFTS; TERMINALS FOR FLUES
- F23L2900/00—Special arrangements for supplying or treating air or oxidant for combustion; Injecting inert gas, water or steam into the combustion chamber
- F23L2900/07005—Injecting pure oxygen or oxygen enriched air
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- F—MECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
- F23—COMBUSTION APPARATUS; COMBUSTION PROCESSES
- F23L—SUPPLYING AIR OR NON-COMBUSTIBLE LIQUIDS OR GASES TO COMBUSTION APPARATUS IN GENERAL ; VALVES OR DAMPERS SPECIALLY ADAPTED FOR CONTROLLING AIR SUPPLY OR DRAUGHT IN COMBUSTION APPARATUS; INDUCING DRAUGHT IN COMBUSTION APPARATUS; TOPS FOR CHIMNEYS OR VENTILATING SHAFTS; TERMINALS FOR FLUES
- F23L2900/00—Special arrangements for supplying or treating air or oxidant for combustion; Injecting inert gas, water or steam into the combustion chamber
- F23L2900/07006—Control of the oxygen supply
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- F—MECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
- F23—COMBUSTION APPARATUS; COMBUSTION PROCESSES
- F23L—SUPPLYING AIR OR NON-COMBUSTIBLE LIQUIDS OR GASES TO COMBUSTION APPARATUS IN GENERAL ; VALVES OR DAMPERS SPECIALLY ADAPTED FOR CONTROLLING AIR SUPPLY OR DRAUGHT IN COMBUSTION APPARATUS; INDUCING DRAUGHT IN COMBUSTION APPARATUS; TOPS FOR CHIMNEYS OR VENTILATING SHAFTS; TERMINALS FOR FLUES
- F23L2900/00—Special arrangements for supplying or treating air or oxidant for combustion; Injecting inert gas, water or steam into the combustion chamber
- F23L2900/07007—Special arrangements for supplying or treating air or oxidant for combustion; Injecting inert gas, water or steam into the combustion chamber using specific ranges of oxygen percentage
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- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y02—TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
- Y02E—REDUCTION OF GREENHOUSE GAS [GHG] EMISSIONS, RELATED TO ENERGY GENERATION, TRANSMISSION OR DISTRIBUTION
- Y02E20/00—Combustion technologies with mitigation potential
- Y02E20/32—Direct CO2 mitigation
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- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y02—TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
- Y02E—REDUCTION OF GREENHOUSE GAS [GHG] EMISSIONS, RELATED TO ENERGY GENERATION, TRANSMISSION OR DISTRIBUTION
- Y02E20/00—Combustion technologies with mitigation potential
- Y02E20/34—Indirect CO2mitigation, i.e. by acting on non CO2directly related matters of the process, e.g. pre-heating or heat recovery
Definitions
- the present invention relates to a method of controlling a process of generating power by oxyfuel combustion. More particularly, the present invention relates to controlling oxyfuel combustion in different load conditions.
- Oxyfuel combustion is one of the methods suggested for removing CO 2 from the exhaust gases of a power generating boiler, such as a pulverized coal (PC) boiler or a circulating fluidized bed (CFB) boiler.
- Oxyfuel combustion is based on combusting carbonaceous fuel with substantially pure oxygen, typically, of at least 95% purity, so as to have carbon dioxide and water as the main components of the exhaust gas discharged from the boiler. Thereby, the carbon dioxide can be captured relatively easily, without having to separate it from a gas stream having nitrogen as its main component, as when combusting the fuel with air.
- the feeding rate of oxygen into a combustion system is regularly controlled together with the feeding rate of fuel, so that almost complete combustion of the fuel is obtained.
- a relatively low level, say 3%, of excess oxygen in the flue gas is sufficient to keep the CO level of the flue gas sufficiently low, but at low loads, a higher level of excess air is needed to maximize steam superheating and to complete combustion.
- the increased excess air at low loads leads to reduced boiler efficiency due to increased thermal stack losses.
- flue gas recirculation is advantageously used to lower the average oxygen content of the inlet gas.
- U.S. Pat. No. 6,935,251 discloses a method of combusting fuel with an oxidant stream comprising an oxygen-rich gas stream mixed with recirculated flue gas. According to this method, the rate of the flue gas recirculation is adjusted, so that the resulting mass flow rate of the flue gas is less than the corresponding mass flow rate of the flue gas generated by using air as the oxidant stream. By using such a reduced flue gas mass flow, the size of the flue gas channel and the pollution control equipment therein can be minimized.
- U.S. Pat. No. 6,418,865 suggests repowering an air-combustion boiler to oxycombustion by adjusting the exhaust gas recirculation rate so as to maintain the heat transfer at the original specification.
- An object of the present invention is to provide a method of controlling a process of generating power by oxyfuel combustion at different load conditions.
- a method of controlling a process of generating power in a power plant with a boiler by combusting carbonaceous fuel with substantially pure oxygen comprising, at full load conditions, the steps of (a1) introducing a first carbonaceous fuel feed stream into a furnace, (b1) introducing a first substantially pure oxygen feed stream into the furnace for combusting the first carbonaceous fuel feed stream with the oxygen, (c1) discharging exhaust gas via an exhaust gas channel from the furnace, (d1) recovering heat from the exhaust gas by heat exchange surfaces arranged in the exhaust gas channel, and (e1) recirculating a portion of the exhaust gas via an exhaust gas recirculating channel at a first recirculation flow rate to the furnace, to form, together with the first substantially pure oxygen feed stream, a first inlet gas stream having a predetermined average oxygen content, thereby discharging exhaust gas from the furnace at a first discharge flow rate, and in second load conditions, corresponding to 90% or less of the full load, the steps of (a2)
- a gas flow rate can be considered to mean a volume flow rate, unless otherwise stated.
- a substantially pure oxygen feed stream is meant an oxygen-rich stream, usually, having a purity of at least 95%, from an oxygen supply, such as a cryogenic air separator.
- the substantially pure oxygen feed stream is at all loads, as usual, such that substantially all of the fuel feed stream will be combusted with the oxygen, which means that the exhaust gas stream comprises a small amount, for example, 3%, of residual oxygen.
- the process also regularly comprises conventional measures for cleaning the exhaust gas from impurities, such as sulfur dioxide.
- the portion of the exhaust gas, which is not recirculated to the furnace may be discharged from the system by condensing water and recovering carbon dioxide for sequestration or further use.
- the second fuel feeding rate corresponds to reduced load conditions, i.e., 90% or less of the full load.
- the second load conditions may preferably be 80% or less of the full load, even more preferably, 70% or less of the full load.
- the exhaust gas recirculation rate is, at reduced load conditions, adjusted so that the flow rate of gas discharged from the furnace remains at a sufficiently high range.
- the exhaust gas flow rate may be fixed to a predetermined value or range, which depends on the conditions in question. The selected value or range is naturally such that it guarantees problem-free operation in all load conditions.
- the exhaust gas flow is sufficient to prevent, for example, unwanted excessive dust accumulation in low-velocity regions.
- the distribution of heat absorbed in different heat transfer surfaces can be distorted, because of the varying relative amount of heat transferred with the exhaust gas.
- the amount of superheating of steam or the preheating of the feedwater in the exhaust gas channel may, at low load conditions, become too low.
- the distribution of heat transfer in different heat transfer surfaces can be maintained even at low load conditions. Because the sufficient flow rate of gas discharged from the furnace is, according to the present invention, achieved by recirculating exhaust gas, not by discharging extra exhaust gas to the environment, the problem of reduced thermal efficiency due to thermal stack losses, is avoided.
- the flue gas recirculation is increased at low load conditions, so as to at least partially compensate for the decreased production of combustion gas.
- This method of controlling the flue gas recirculation clearly differs from the conventional method used in combustion with air, in which flue gas recirculation is used to avoid too high of temperatures in the furnace. At low load conditions, when the temperature in the furnace already decreases due to a reduced fuel feed rate, the need for conventional flue gas recirculation is minimized.
- the prevention of harmful decreasing of the exhaust gas flow rate at low load conditions by increasing or at least maintaining the recirculating gas flow rate is especially beneficial in oxyfuel combustion, where the equipment for high exhaust gas recirculation is usually readily available, and the gas flow to be compensated for consists mainly of the decreased CO 2 production.
- This is in clear contrast with air-fired combustion, where exhaust gas recirculation is normally low or missing, and the change of the exhaust gas at low loads includes, in addition to a reduced flow of carbon dioxide, also, as a larger component, a decreased flow of nitrogen.
- the application of the present invention in air-fired combustion would bring about high costs, due to the arrangements needed for high additional exhaust gas recirculation at low loads.
- the recirculated gas flow rate may be increased at low loads by the same amount, in moles, as the substantially pure oxygen feed stream is decreased. Thereby, the volume flow rate of the exhaust gas remains constant.
- the recirculated gas flow rate may be increased at low loads by a smaller amount or, at least, the recirculated gas flow rate shall advantageously be maintained at a constant level.
- the share of exhaust gas recirculated to the furnace is, at low loads, increased from that at full load. Thereby, the average oxygen content of the inlet gas is, at low loads, decreased.
- the oxyfuel combustion process of a retrofitted boiler advantageously uses a high exhaust gas recirculation rate.
- the fuel can be combusted by almost maintaining the original temperatures and gas flow rates.
- a similar construction is also advantageously used in dual-firing boilers, i.e., in boilers, which can be used both for combustion with air and for oxyfuel combustion.
- exhaust gas recirculation rates of about 81% to 75%, respectively, are required, the exact values depending on the level of impurities and residual oxygen in the flue gas.
- the designed oxygen content of the inlet gas is relatively low, say 20% to 25%
- the reason for this is that, for such a low oxygen boiler, even the maintaining of the exhaust gas flow rate increases the recirculated gas flow rate only by a relatively small amount.
- the exhaust gas flow rate can be allowed to slightly decrease, which means that the flow rate of the recirculated gas is increased even less.
- the maintaining of the exhaust gas flow rate, when changing the load from 100% to 70% in a boiler having, at full load, an inlet gas oxygen content of 25% is obtained by increasing the flow rate of the recirculated exhaust gas by about 10%. Because the flow rate of the exhaust gas is constant, the share of exhaust gas recirculated back to the furnace changes as the flow rate of the recirculated gas, i.e., by about 10%, typically, from 75% to 82%. The oxygen content of the inlet gas is thereby decreased from 25% to about 18%, i.e., it is multiplied by 0.72.
- the exhaust gas flow rate can be maintained, when reducing the load to 70%, by increasing the recirculation gas flow rate by about 7%, whereby the oxygen content of the inlet gas decreases from 20% to about 15%, i.e., it is multiplied by 0.75.
- the exhaust gas recirculation of an oxycombustion boiler having, at full load, an oxygen content of the inlet gas of 20% to 25% is, at 70% load, increased, such that the average oxygen content of the inlet gas stream is reduced to a value, which is preferably 0.70 to 0.78 times, even more preferably, 0.72 to 0.75 times, the average oxygen content of the inlet gas stream at full load.
- a new boiler which is especially designed for oxyfuel combustion, is usually intended for combustion of fuel at a relatively high temperature with an inlet gas having an average oxygen content, which is clearly higher than that of air.
- the furnace and flue gas channel of such a boiler are advantageously clearly smaller in size than those of a corresponding air-fired combustion system.
- a new oxyfuel combustion boiler thus differs considerably from an oxyfuel combustion boiler, which is retrofitted from an air-fired boiler or from a combustion system intended for oxyfuel combustion and air-fired combustion, for example, in the arrangement of heat transfer surfaces.
- the present invention can, however, advantageously be used both in new and in retrofitted oxyfuel combustion boilers.
- the average full load oxygen content of the inlet gas of a new oxyfuel combustion boiler may advantageously be, for example, about 40% to about 60%. These oxygen contents are typically obtained by recirculating about 58% to about 35%, respectively, of the exhaust gas back to the furnace. Then, for example, at 70% load, the flow rate of the exhaust gas can be maintained at its original value by increasing the exhaust gas recirculation to a value of about 71% to about 55%, respectively. These increased recirculation rates result in the average oxygen content of the inlet gas decreasing to a value of about 29% to about 43%, respectively, i.e., the oxygen contents are multiplied by about 0.72.
- a drawback of this controlling procedure is that the flow rate of the recirculated gas is thereby considerably increased at low loads.
- the maintaining of the exhaust gas flow rate when changing the load from 100% to 70% in a boiler having, at full load, an inlet gas oxygen content of 60% would require an increase of about 55% of the recirculation gas flow rate at full load. Readiness for such a high increase would mean having a largely oversized recirculation channel and a correspondingly oversized fan for the operation at low loads. In order to minimize additional costs due to such devices, it is advantageous to use somewhat lowered gas recirculation, at low loads, in high oxygen boilers.
- the flow rate of the recirculation gas is maintained at 70% load at the same value as at full load, the flow rate of the exhaust gas is typically decreased by almost 20%. This is obtained by increasing the share of the exhaust gas recirculated back to the furnace from about 35% to about 44%, whereby the oxygen content of the inlet gas is reduced from 60% to about 52%, i.e., it is multiplied by 0.87.
- the recirculation devices designed on the basis of the gas streams at full load can be used, but the decreased flow rate of the exhaust gas may cause problems.
- the recirculated gas flow rate is advantageously, at low loads, controlled to be between the values of the examples described above. For example, if the recirculated gas flow rate of an oxycombustion boiler designed for 60% full load inlet gas oxygen content is, at 70% load, increased by 20% of that at full load, whereby the inlet gas oxygen content is decreased to about 48%, i.e., it is multiplied by 0.80, the flow rate of the exhaust gas decreases only by about 12% of that obtained at full load.
- the exhaust gas recirculation of an oxycombustion boiler having, at full load, an oxygen content of the inlet gas of 40% to 60% is, at 70% load, increased, such that the average oxygen content of the inlet gas stream is reduced to a value, which is preferably 0.73 to 0.82 times, even more preferably, 0.77 to 0.81 times, the average oxygen content of the inlet gas stream at full load. It has been surprisingly found that these ranges provide cost efficient and problem-free operation of the boiler.
- the exhaust gas discharge rate is, in practice, adjusted at full load so as to obtain a desired average oxygen of the inlet gas.
- the process of controlling the exhaust gas flow, at low loads, in accordance with the present invention can be based on controlling the exhaust gas recirculation rate directly on the basis of the load, or on the basis of a measured fuel feeding rate.
- the controlling of the exhaust gas recirculation can be based on a measured flow rate of the exhaust gas discharged from the furnace.
- the exhaust gas recirculating rate can be controlled by adjusting the speed of a fan used for recirculating the exhaust gas, either directly to a set value, based on a desired recirculation rate, or by comparing a measured recirculated gas flow rate with the desired recirculation rate.
- the present invention can, advantageously, be used in different types of power generating boilers, especially, in circulating fluidized bed (CFB) boilers and pulverized coal (PC) boilers.
- the fuel is advantageously solid fuel, especially, coal, biofuel or refuse-derived fuel.
- the substantially pure oxygen is typically obtained from an oxygen supply, such as a cryogenic or a membrane-based air separation unit.
- the substantially pure oxygen and the recirculated exhaust gas may be fed to the furnace as separate streams, or they may be mixed to form an inlet stream to be fed to the furnace.
- the inlet gas may consist of a single gas flow, or it may consist of several flows, such as fluidization gas and secondary gas, in a CFB boiler, or primary, secondary and upper furnace inlet gas in a PC boiler. It is also possible that gas streams with different compositions are introduced into different portions of the furnace.
- FIG. 1 is a schematic diagram of an oxyfuel-combusting power plant suitable for application of the present invention.
- FIG. 1 shows a schematic diagram of a boiler plant 10 with a boiler 12 , which may be, for example, a pulverized coal (PC) boiler or a circulating fluidized bed (CFB) boiler.
- the furnace 14 of the boiler comprises conventional fuel feeding means 16 , means for introducing oxygen-containing inlet gas 18 into the furnace, and an exhaust gas channel 20 for discharging exhaust gas produced by combusting the fuel with the oxygen of the inlet gas.
- the details and type of some elements of the boiler 12 such as the fuel feeding means 16 and inlet gas feeding means 18 , naturally depend on the type of the boiler. Details such as, for example, burners, coal mills, means for separately feeding primary and secondary inlet gas, are, however, not important for the purposes of the present invention, and they are thus not shown in FIG. 1 .
- the oxygen-containing inlet gas is preferably a mixture of substantially pure oxygen, produced from an air stream 22 in an air separation unit (ASU) 24 , and a portion of the exhaust gas, which is recirculated via an exhaust gas recirculating channel 26 .
- the exhaust gas recirculating channel 26 advantageously comprises means, such as a fan 28 , for controlling the exhaust gas recirculating rate.
- the recirculating rate of the inlet gas is, in retrofitted boilers, advantageously adjusted such that the average 02 content of the inlet gas is, at full load, close to that of air, preferably from 20% to 25%.
- a new oxyfuel boiler may advantageously be designed for a much higher oxygen content of the inlet gas, and the recirculating rate of the exhaust gas is, correspondingly, much lower.
- the walls of the furnace 14 are preferably formed as a tube-wall construction, which forms evaporating heat transfer surfaces 30 , for converting preheated feedwater to steam.
- An upstream portion of the exhaust gas channel 20 comprises a superheating heat transfer surface 34 for recovering heat from the exhaust gas to superheat the steam.
- FIG. 1 shows only one superheating surface, but, in practice, the upstream portion 32 of the exhaust gas channel usually comprises multiple superheating and reheating surfaces.
- the downstream portion of the flue gas channel 20 advantageously comprises one or more economizers 38 , 42 for preheating feedwater to be fed to the evaporating heat transfer surfaces, and a gas-gas heater 40 for heating the inlet gas.
- the exhaust gas channel 20 also usually comprises different units for cleaning the exhaust gas from particles and gaseous pollutants, but they are not shown in FIG. 1 .
- FIG. 1 shows compressors 44 , 46 for pressurizing the exhaust gas, and an economizer 48 arranged between the compressors for inter-stage cooling.
- the carbon dioxide liquefying system usually comprises, in practice, more than two compression stages, usually, at least four stages, in order to increase the efficiency of the system.
- the economizer 42 is shown as a condensing cooler, whereby water is removed from the exhaust gas.
- the carbon dioxide sequestration system also usually comprises means for completely drying all water from the exhaust gas, and means for separating oxygen, and possible other impurities, from the carbon dioxide, which are, however, not shown in FIG. 1 .
- the load level i.e., the amount of fuel fed by the fuel feeding means 16 and the amount of oxygen provided by the air separation unit 24 are controlled by main control device 50 , on the basis of the prevailing power demand.
- the exhaust gas recirculating rate is adjusted by the fan 28 , so that the flow of the exhaust gas remains at a predetermined range.
- the speed of the fan 28 can be adjusted on the basis of, for example, the prevailing load, or a measured fuel feeding rate.
- the adjustment can, alternatively, be made on the basis of recirculated gas flow and/or the exhaust gas flow, as measured by suitable means 54 , 52 .
Abstract
Description
- 1. Field of the Invention
- The present invention relates to a method of controlling a process of generating power by oxyfuel combustion. More particularly, the present invention relates to controlling oxyfuel combustion in different load conditions.
- 2. Description of the Related Art
- Oxyfuel combustion is one of the methods suggested for removing CO2 from the exhaust gases of a power generating boiler, such as a pulverized coal (PC) boiler or a circulating fluidized bed (CFB) boiler. Oxyfuel combustion is based on combusting carbonaceous fuel with substantially pure oxygen, typically, of at least 95% purity, so as to have carbon dioxide and water as the main components of the exhaust gas discharged from the boiler. Thereby, the carbon dioxide can be captured relatively easily, without having to separate it from a gas stream having nitrogen as its main component, as when combusting the fuel with air.
- The feeding rate of oxygen into a combustion system is regularly controlled together with the feeding rate of fuel, so that almost complete combustion of the fuel is obtained. In conventional air-firing at full load, typically, a relatively low level, say 3%, of excess oxygen in the flue gas is sufficient to keep the CO level of the flue gas sufficiently low, but at low loads, a higher level of excess air is needed to maximize steam superheating and to complete combustion. The increased excess air at low loads leads to reduced boiler efficiency due to increased thermal stack losses.
- In conventional combustion with air, harmful effects caused by too high of combustion temperatures, such as increased NOX emissions or corrosion, or material strength problems of the furnace walls, are often prevented by recirculating a portion of the flue gas back to the furnace. Thus, the oxygen content of the inlet gas is reduced from the about 21% of air to a lower value, and the combustion temperature is thereby lowered.
- One of the advantages of oxyfuel combustion is the possibility to increase thermal efficiency of the process by using high combustion temperatures. However, combustion with nearly pure oxygen as the inlet gas would provide very high combustion temperatures. Therefore, in order to avoid harmful effects of too high of combustion temperatures, especially when repowering air-fired boilers to oxyfuel combustion, flue gas recirculation is advantageously used to lower the average oxygen content of the inlet gas.
- U.S. Pat. No. 6,935,251 discloses a method of combusting fuel with an oxidant stream comprising an oxygen-rich gas stream mixed with recirculated flue gas. According to this method, the rate of the flue gas recirculation is adjusted, so that the resulting mass flow rate of the flue gas is less than the corresponding mass flow rate of the flue gas generated by using air as the oxidant stream. By using such a reduced flue gas mass flow, the size of the flue gas channel and the pollution control equipment therein can be minimized. U.S. Pat. No. 6,418,865 suggests repowering an air-combustion boiler to oxycombustion by adjusting the exhaust gas recirculation rate so as to maintain the heat transfer at the original specification.
- One of the requirements of a power generation process is its applicability for use in different power demand conditions with high efficiency. According to conventional practice, reduced steam outputs are achieved by operating the boiler with reduced fuel and air feeding rates. Japanese patent publication No. 2007-147162 discloses a combustion control method of an oxygen burning boiler, wherein oxygen is supplied in an amount corresponding to the boiler load, and the exhaust gas recirculation rate is controlled so as to obtain the required absorption of heat for producing steam.
- For oxyfuel combustion, especially when the flue gas mass flow is less than that in combustion with air, the operation at low loads may lead to a distorted flow pattern of the flue gas, increasing the risk of operational problems, for example, due to excessive fouling or dust accumulation in low-velocity regions of the exhaust gas channel. Thus, there is a need for an improved method of controlling oxyfuel combustion in different load conditions.
- An object of the present invention is to provide a method of controlling a process of generating power by oxyfuel combustion at different load conditions.
- According to an aspect of the present invention, a method of controlling a process of generating power in a power plant with a boiler by combusting carbonaceous fuel with substantially pure oxygen is provided, the method comprising, at full load conditions, the steps of (a1) introducing a first carbonaceous fuel feed stream into a furnace, (b1) introducing a first substantially pure oxygen feed stream into the furnace for combusting the first carbonaceous fuel feed stream with the oxygen, (c1) discharging exhaust gas via an exhaust gas channel from the furnace, (d1) recovering heat from the exhaust gas by heat exchange surfaces arranged in the exhaust gas channel, and (e1) recirculating a portion of the exhaust gas via an exhaust gas recirculating channel at a first recirculation flow rate to the furnace, to form, together with the first substantially pure oxygen feed stream, a first inlet gas stream having a predetermined average oxygen content, thereby discharging exhaust gas from the furnace at a first discharge flow rate, and in second load conditions, corresponding to 90% or less of the full load, the steps of (a2) introducing a second carbonaceous fuel feed stream into the furnace, (b2) introducing a second substantially pure oxygen feed stream into the furnace for combusting the second carbonaceous fuel feed stream with the oxygen, (c2) discharging exhaust gas via the exhaust gas channel from the furnace, (d2) recovering heat from the exhaust gas by the heat exchange surfaces arranged in the exhaust gas channel, and (e2) recirculating a portion of the exhaust gas via the exhaust gas recirculating channel at a second recirculation flow rate to the furnace, to form together with the second substantially pure oxygen feed stream a second inlet gas stream, so as to discharge exhaust gas from the furnace at a second discharge flow rate, and controlling the second recirculation flow rate to be from the first recirculation flow rate to a value providing the second discharge flow rate to be substantially as high as the first discharge flow rate.
- Any reference to a gas flow rate, throughout this description, can be considered to mean a volume flow rate, unless otherwise stated. By a “substantially pure oxygen feed stream” is meant an oxygen-rich stream, usually, having a purity of at least 95%, from an oxygen supply, such as a cryogenic air separator. The substantially pure oxygen feed stream is at all loads, as usual, such that substantially all of the fuel feed stream will be combusted with the oxygen, which means that the exhaust gas stream comprises a small amount, for example, 3%, of residual oxygen. The process also regularly comprises conventional measures for cleaning the exhaust gas from impurities, such as sulfur dioxide. The portion of the exhaust gas, which is not recirculated to the furnace, may be discharged from the system by condensing water and recovering carbon dioxide for sequestration or further use.
- According to the present invention, the second fuel feeding rate corresponds to reduced load conditions, i.e., 90% or less of the full load. The second load conditions may preferably be 80% or less of the full load, even more preferably, 70% or less of the full load. According to the present method, the exhaust gas recirculation rate is, at reduced load conditions, adjusted so that the flow rate of gas discharged from the furnace remains at a sufficiently high range. By having a high exhaust gas flow rate at all load conditions, the designed flow pattern of the exhaust gas, and the distribution of heat transfer in different heat transfer surfaces of the boiler, can be maintained. In practice, the exhaust gas flow rate may be fixed to a predetermined value or range, which depends on the conditions in question. The selected value or range is naturally such that it guarantees problem-free operation in all load conditions. Thus, the exhaust gas flow is sufficient to prevent, for example, unwanted excessive dust accumulation in low-velocity regions.
- According to a conventional method, where the exhaust gas flow rate decreases at low load conditions, the distribution of heat absorbed in different heat transfer surfaces can be distorted, because of the varying relative amount of heat transferred with the exhaust gas. Thereby, for example, the amount of superheating of steam or the preheating of the feedwater in the exhaust gas channel may, at low load conditions, become too low. According to the present invention, the distribution of heat transfer in different heat transfer surfaces can be maintained even at low load conditions. Because the sufficient flow rate of gas discharged from the furnace is, according to the present invention, achieved by recirculating exhaust gas, not by discharging extra exhaust gas to the environment, the problem of reduced thermal efficiency due to thermal stack losses, is avoided.
- According to the present invention, the flue gas recirculation is increased at low load conditions, so as to at least partially compensate for the decreased production of combustion gas. This method of controlling the flue gas recirculation clearly differs from the conventional method used in combustion with air, in which flue gas recirculation is used to avoid too high of temperatures in the furnace. At low load conditions, when the temperature in the furnace already decreases due to a reduced fuel feed rate, the need for conventional flue gas recirculation is minimized.
- The prevention of harmful decreasing of the exhaust gas flow rate at low load conditions by increasing or at least maintaining the recirculating gas flow rate is especially beneficial in oxyfuel combustion, where the equipment for high exhaust gas recirculation is usually readily available, and the gas flow to be compensated for consists mainly of the decreased CO2 production. This is in clear contrast with air-fired combustion, where exhaust gas recirculation is normally low or missing, and the change of the exhaust gas at low loads includes, in addition to a reduced flow of carbon dioxide, also, as a larger component, a decreased flow of nitrogen. Thus, the application of the present invention in air-fired combustion would bring about high costs, due to the arrangements needed for high additional exhaust gas recirculation at low loads.
- When using the present invention, the recirculated gas flow rate may be increased at low loads by the same amount, in moles, as the substantially pure oxygen feed stream is decreased. Thereby, the volume flow rate of the exhaust gas remains constant. Alternatively, the recirculated gas flow rate may be increased at low loads by a smaller amount or, at least, the recirculated gas flow rate shall advantageously be maintained at a constant level. In all of these alternatives, the share of exhaust gas recirculated to the furnace is, at low loads, increased from that at full load. Thereby, the average oxygen content of the inlet gas is, at low loads, decreased.
- When retrofitting an air-fired boiler for oxyfuel combustion, it is usually required to maintain, as much as possible, of the original combustion system, and, therefore, it is advantageous to at least partially keep the original furnace, flue gas channel and heat transfer surfaces. Thus, in order to obtain an average oxygen content of the inlet gas, which is close to that of air, the oxyfuel combustion process of a retrofitted boiler advantageously uses a high exhaust gas recirculation rate. Thereby, the fuel can be combusted by almost maintaining the original temperatures and gas flow rates. A similar construction is also advantageously used in dual-firing boilers, i.e., in boilers, which can be used both for combustion with air and for oxyfuel combustion. To obtain average oxygen contents of the inlet gas of 20% to 25%, typically, exhaust gas recirculation rates of about 81% to 75%, respectively, are required, the exact values depending on the level of impurities and residual oxygen in the flue gas.
- For oxycombustion boilers in which the designed oxygen content of the inlet gas is relatively low, say 20% to 25%, it is especially advantageous to increase the recirculated gas flow rate at low loads, so that the flow rate of the exhaust gas remains substantially constant. The reason for this is that, for such a low oxygen boiler, even the maintaining of the exhaust gas flow rate increases the recirculated gas flow rate only by a relatively small amount. Alternatively, the exhaust gas flow rate can be allowed to slightly decrease, which means that the flow rate of the recirculated gas is increased even less.
- For example, the maintaining of the exhaust gas flow rate, when changing the load from 100% to 70% in a boiler having, at full load, an inlet gas oxygen content of 25%, is obtained by increasing the flow rate of the recirculated exhaust gas by about 10%. Because the flow rate of the exhaust gas is constant, the share of exhaust gas recirculated back to the furnace changes as the flow rate of the recirculated gas, i.e., by about 10%, typically, from 75% to 82%. The oxygen content of the inlet gas is thereby decreased from 25% to about 18%, i.e., it is multiplied by 0.72. Correspondingly, for a boiler with a 20% full load inlet gas oxygen content, the exhaust gas flow rate can be maintained, when reducing the load to 70%, by increasing the recirculation gas flow rate by about 7%, whereby the oxygen content of the inlet gas decreases from 20% to about 15%, i.e., it is multiplied by 0.75.
- According to a preferred embodiment of the present invention, the exhaust gas recirculation of an oxycombustion boiler having, at full load, an oxygen content of the inlet gas of 20% to 25%, is, at 70% load, increased, such that the average oxygen content of the inlet gas stream is reduced to a value, which is preferably 0.70 to 0.78 times, even more preferably, 0.72 to 0.75 times, the average oxygen content of the inlet gas stream at full load.
- A new boiler, which is especially designed for oxyfuel combustion, is usually intended for combustion of fuel at a relatively high temperature with an inlet gas having an average oxygen content, which is clearly higher than that of air. The furnace and flue gas channel of such a boiler are advantageously clearly smaller in size than those of a corresponding air-fired combustion system. A new oxyfuel combustion boiler thus differs considerably from an oxyfuel combustion boiler, which is retrofitted from an air-fired boiler or from a combustion system intended for oxyfuel combustion and air-fired combustion, for example, in the arrangement of heat transfer surfaces. The present invention can, however, advantageously be used both in new and in retrofitted oxyfuel combustion boilers.
- The average full load oxygen content of the inlet gas of a new oxyfuel combustion boiler may advantageously be, for example, about 40% to about 60%. These oxygen contents are typically obtained by recirculating about 58% to about 35%, respectively, of the exhaust gas back to the furnace. Then, for example, at 70% load, the flow rate of the exhaust gas can be maintained at its original value by increasing the exhaust gas recirculation to a value of about 71% to about 55%, respectively. These increased recirculation rates result in the average oxygen content of the inlet gas decreasing to a value of about 29% to about 43%, respectively, i.e., the oxygen contents are multiplied by about 0.72. A drawback of this controlling procedure is that the flow rate of the recirculated gas is thereby considerably increased at low loads. For example, the maintaining of the exhaust gas flow rate when changing the load from 100% to 70% in a boiler having, at full load, an inlet gas oxygen content of 60% would require an increase of about 55% of the recirculation gas flow rate at full load. Readiness for such a high increase would mean having a largely oversized recirculation channel and a correspondingly oversized fan for the operation at low loads. In order to minimize additional costs due to such devices, it is advantageous to use somewhat lowered gas recirculation, at low loads, in high oxygen boilers.
- If, alternatively, for an oxycombustion boiler designed for 60% full load inlet gas oxygen content, the flow rate of the recirculation gas is maintained at 70% load at the same value as at full load, the flow rate of the exhaust gas is typically decreased by almost 20%. This is obtained by increasing the share of the exhaust gas recirculated back to the furnace from about 35% to about 44%, whereby the oxygen content of the inlet gas is reduced from 60% to about 52%, i.e., it is multiplied by 0.87. In this case, the recirculation devices designed on the basis of the gas streams at full load can be used, but the decreased flow rate of the exhaust gas may cause problems.
- In cases when such a decreased exhaust gas flow rate already causes problems of dust accumulation or distorted heat transfer, the recirculated gas flow rate is advantageously, at low loads, controlled to be between the values of the examples described above. For example, if the recirculated gas flow rate of an oxycombustion boiler designed for 60% full load inlet gas oxygen content is, at 70% load, increased by 20% of that at full load, whereby the inlet gas oxygen content is decreased to about 48%, i.e., it is multiplied by 0.80, the flow rate of the exhaust gas decreases only by about 12% of that obtained at full load.
- According to a preferred embodiment of the present invention, the exhaust gas recirculation of an oxycombustion boiler having, at full load, an oxygen content of the inlet gas of 40% to 60%, is, at 70% load, increased, such that the average oxygen content of the inlet gas stream is reduced to a value, which is preferably 0.73 to 0.82 times, even more preferably, 0.77 to 0.81 times, the average oxygen content of the inlet gas stream at full load. It has been surprisingly found that these ranges provide cost efficient and problem-free operation of the boiler.
- The exhaust gas discharge rate is, in practice, adjusted at full load so as to obtain a desired average oxygen of the inlet gas. The process of controlling the exhaust gas flow, at low loads, in accordance with the present invention, can be based on controlling the exhaust gas recirculation rate directly on the basis of the load, or on the basis of a measured fuel feeding rate. Alternatively, the controlling of the exhaust gas recirculation can be based on a measured flow rate of the exhaust gas discharged from the furnace. The exhaust gas recirculating rate can be controlled by adjusting the speed of a fan used for recirculating the exhaust gas, either directly to a set value, based on a desired recirculation rate, or by comparing a measured recirculated gas flow rate with the desired recirculation rate.
- The present invention can, advantageously, be used in different types of power generating boilers, especially, in circulating fluidized bed (CFB) boilers and pulverized coal (PC) boilers. The fuel is advantageously solid fuel, especially, coal, biofuel or refuse-derived fuel. The substantially pure oxygen is typically obtained from an oxygen supply, such as a cryogenic or a membrane-based air separation unit.
- The substantially pure oxygen and the recirculated exhaust gas may be fed to the furnace as separate streams, or they may be mixed to form an inlet stream to be fed to the furnace. The inlet gas may consist of a single gas flow, or it may consist of several flows, such as fluidization gas and secondary gas, in a CFB boiler, or primary, secondary and upper furnace inlet gas in a PC boiler. It is also possible that gas streams with different compositions are introduced into different portions of the furnace.
- The brief description given above, as well as further objects, features, and advantages of the present invention, will be more fully appreciated by reference to the following detailed description of the currently preferred, but nonetheless illustrative, embodiments of the present invention, taken in conjunction with the accompanying drawing.
-
FIG. 1 is a schematic diagram of an oxyfuel-combusting power plant suitable for application of the present invention. -
FIG. 1 shows a schematic diagram of aboiler plant 10 with aboiler 12, which may be, for example, a pulverized coal (PC) boiler or a circulating fluidized bed (CFB) boiler. Thefurnace 14 of the boiler comprises conventional fuel feeding means 16, means for introducing oxygen-containinginlet gas 18 into the furnace, and anexhaust gas channel 20 for discharging exhaust gas produced by combusting the fuel with the oxygen of the inlet gas. The details and type of some elements of theboiler 12, such as the fuel feeding means 16 and inlet gas feeding means 18, naturally depend on the type of the boiler. Details such as, for example, burners, coal mills, means for separately feeding primary and secondary inlet gas, are, however, not important for the purposes of the present invention, and they are thus not shown inFIG. 1 . - The oxygen-containing inlet gas is preferably a mixture of substantially pure oxygen, produced from an
air stream 22 in an air separation unit (ASU) 24, and a portion of the exhaust gas, which is recirculated via an exhaustgas recirculating channel 26. The exhaustgas recirculating channel 26 advantageously comprises means, such as afan 28, for controlling the exhaust gas recirculating rate. The recirculating rate of the inlet gas is, in retrofitted boilers, advantageously adjusted such that the average 02 content of the inlet gas is, at full load, close to that of air, preferably from 20% to 25%. A new oxyfuel boiler may advantageously be designed for a much higher oxygen content of the inlet gas, and the recirculating rate of the exhaust gas is, correspondingly, much lower. In some applications of the present invention, it is also possible to introduce the streams of recirculated exhaust gas and substantially pure oxygen separately into thefurnace 14, for example, in different portions of the furnace. - The walls of the
furnace 14 are preferably formed as a tube-wall construction, which forms evaporating heat transfer surfaces 30, for converting preheated feedwater to steam. An upstream portion of theexhaust gas channel 20 comprises a superheatingheat transfer surface 34 for recovering heat from the exhaust gas to superheat the steam. For the sake of simplicity,FIG. 1 shows only one superheating surface, but, in practice, the upstream portion 32 of the exhaust gas channel usually comprises multiple superheating and reheating surfaces. - The downstream portion of the
flue gas channel 20 advantageously comprises one ormore economizers gas heater 40 for heating the inlet gas. Theexhaust gas channel 20 also usually comprises different units for cleaning the exhaust gas from particles and gaseous pollutants, but they are not shown inFIG. 1 . - Downstream of the branch point for the exhaust
gas recirculating channel 26 is advantageously arranged means for producing liquid carbon dioxide, typically, at a pressure of about 110 bar, so that it can be transported for further use or to be stored to a suitable place. Therefore,FIG. 1 showscompressors economizer 48 arranged between the compressors for inter-stage cooling. The carbon dioxide liquefying system usually comprises, in practice, more than two compression stages, usually, at least four stages, in order to increase the efficiency of the system. InFIG. 1 , theeconomizer 42 is shown as a condensing cooler, whereby water is removed from the exhaust gas. The carbon dioxide sequestration system also usually comprises means for completely drying all water from the exhaust gas, and means for separating oxygen, and possible other impurities, from the carbon dioxide, which are, however, not shown inFIG. 1 . - When generating power by the
boiler 10, the load level, i.e., the amount of fuel fed by the fuel feeding means 16 and the amount of oxygen provided by theair separation unit 24 are controlled bymain control device 50, on the basis of the prevailing power demand. Then, according to the present invention, the exhaust gas recirculating rate is adjusted by thefan 28, so that the flow of the exhaust gas remains at a predetermined range. The speed of thefan 28 can be adjusted on the basis of, for example, the prevailing load, or a measured fuel feeding rate. The adjustment can, alternatively, be made on the basis of recirculated gas flow and/or the exhaust gas flow, as measured bysuitable means - While the invention has been described herein by way of examples in connection with what are, at present, considered to be the most preferred embodiments, it is to be understood that the invention is not limited to the disclosed embodiments, but is intended to cover various combinations or modifications of its features, and several other applications included within the scope of the invention, as defined in the appended claims.
Claims (10)
Priority Applications (9)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
US11/960,958 US20090158978A1 (en) | 2007-12-20 | 2007-12-20 | Method of controlling a process of generating power by oxyfuel combustion |
AU2008341526A AU2008341526A1 (en) | 2007-12-20 | 2008-12-19 | Method of controlling a process of generating power by oxyfuel combustion |
CN2008801226012A CN101952659A (en) | 2007-12-20 | 2008-12-19 | Method of controlling a process of generating power by oxyfuel combustion |
EP08863429.0A EP2235440B1 (en) | 2007-12-20 | 2008-12-19 | Method of controlling a process of generating power by oxyfuel combustion |
JP2010539031A JP2011508174A (en) | 2007-12-20 | 2008-12-19 | Control method of power generation process by oxyfuel combustion |
RU2010130173/06A RU2442076C1 (en) | 2007-12-20 | 2008-12-19 | Method for controlling the process of power production at the power station |
KR1020107015685A KR20100110826A (en) | 2007-12-20 | 2008-12-19 | Method of controlling a process of generating power by oxyfuel combustion |
PCT/IB2008/055454 WO2009081364A2 (en) | 2007-12-20 | 2008-12-19 | Method of controlling a process of generating power by oxyfuel combustion |
ZA2010/04146A ZA201004146B (en) | 2007-12-20 | 2010-06-10 | Method of controlling a process of generating power by oxyfuel combustion |
Applications Claiming Priority (1)
Application Number | Priority Date | Filing Date | Title |
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US11/960,958 US20090158978A1 (en) | 2007-12-20 | 2007-12-20 | Method of controlling a process of generating power by oxyfuel combustion |
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US20090158978A1 true US20090158978A1 (en) | 2009-06-25 |
Family
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Family Applications (1)
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US11/960,958 Abandoned US20090158978A1 (en) | 2007-12-20 | 2007-12-20 | Method of controlling a process of generating power by oxyfuel combustion |
Country Status (9)
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US (1) | US20090158978A1 (en) |
EP (1) | EP2235440B1 (en) |
JP (1) | JP2011508174A (en) |
KR (1) | KR20100110826A (en) |
CN (1) | CN101952659A (en) |
AU (1) | AU2008341526A1 (en) |
RU (1) | RU2442076C1 (en) |
WO (1) | WO2009081364A2 (en) |
ZA (1) | ZA201004146B (en) |
Cited By (7)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
US20080302107A1 (en) * | 2007-06-08 | 2008-12-11 | Foster Wheeler Energy Corporation | Method of and power plant for generating power by oxyfuel combustion |
US20110011315A1 (en) * | 2009-07-14 | 2011-01-20 | Hitachi, Ltd. | Oxyfuel Boiler and Control Method for Oxyfuel Boiler |
WO2011086232A1 (en) | 2010-01-12 | 2011-07-21 | Foster Wheeler Energia Oy | Method of combusting different fuels in an oxycombustion boiler |
WO2011131837A1 (en) * | 2010-04-23 | 2011-10-27 | Foster Wheeler Energia Oy | Method of controlling combustion in a cfb boiler plant |
WO2012064545A3 (en) * | 2010-11-10 | 2013-11-28 | Praxair Technology, Inc. | Oxygen enhanced combustion of biomass |
EP2431579A3 (en) * | 2010-09-21 | 2014-02-19 | Hitachi Ltd. | Multipurpose thermal power plant system |
WO2013041848A3 (en) * | 2011-09-19 | 2014-03-13 | Doosan Babcock Limited | Energy storage technology for demanded supply optimisation |
Families Citing this family (4)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
JP2012149792A (en) * | 2011-01-17 | 2012-08-09 | Babcock Hitachi Kk | Exhausts gas treatment system |
MD4270C1 (en) * | 2013-06-06 | 2014-08-31 | Юрие ПАНФИЛ | Power plant for burning fuel and process for recycling smoke gases for fuel burning therein |
CN103953922B (en) * | 2014-05-15 | 2016-01-13 | 浙江菲尼克斯环境技术有限公司 | Low-carbon (LC) Inner eycle oxygen enrichment combustion technology device and combustion method again |
CN105627349B (en) * | 2016-01-15 | 2018-02-06 | 东南大学 | A kind of pure oxygen burning realizes CO2Trapping and the method and system of water circulation use |
Citations (6)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
US4355601A (en) * | 1981-09-25 | 1982-10-26 | Conoco Inc. | Recirculating flue gas fluidized bed heater |
US6200128B1 (en) * | 1997-06-09 | 2001-03-13 | Praxair Technology, Inc. | Method and apparatus for recovering sensible heat from a hot exhaust gas |
US20020028043A1 (en) * | 1998-09-16 | 2002-03-07 | Jolt Ltd. | Wireless optical communications without electronics |
US6418865B2 (en) * | 1999-06-10 | 2002-07-16 | American Air Liquide | Method for operating a boiler using oxygen-enriched oxidants |
US6532881B2 (en) * | 1999-06-10 | 2003-03-18 | L'air Liquide - Societe' Anonyme A' Directoire Et Conseil De Surveillance Pour L'etude Et L'exploitation De Procedes Georges Claude | Method for operating a boiler using oxygen-enriched oxidants |
US6935251B2 (en) * | 2002-02-15 | 2005-08-30 | American Air Liquide, Inc. | Steam-generating combustion system and method for emission control using oxygen enhancement |
Family Cites Families (2)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
DE19503348A1 (en) * | 1995-02-02 | 1996-08-08 | Erhard Liebig | Reducing nitrogen oxide(s) emissions in large scale plants |
JP4731293B2 (en) * | 2005-11-28 | 2011-07-20 | 電源開発株式会社 | Combustion control method and apparatus for oxyfuel boiler |
-
2007
- 2007-12-20 US US11/960,958 patent/US20090158978A1/en not_active Abandoned
-
2008
- 2008-12-19 KR KR1020107015685A patent/KR20100110826A/en not_active Application Discontinuation
- 2008-12-19 AU AU2008341526A patent/AU2008341526A1/en not_active Abandoned
- 2008-12-19 RU RU2010130173/06A patent/RU2442076C1/en not_active IP Right Cessation
- 2008-12-19 JP JP2010539031A patent/JP2011508174A/en not_active Abandoned
- 2008-12-19 WO PCT/IB2008/055454 patent/WO2009081364A2/en active Application Filing
- 2008-12-19 EP EP08863429.0A patent/EP2235440B1/en not_active Not-in-force
- 2008-12-19 CN CN2008801226012A patent/CN101952659A/en active Pending
-
2010
- 2010-06-10 ZA ZA2010/04146A patent/ZA201004146B/en unknown
Patent Citations (6)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
US4355601A (en) * | 1981-09-25 | 1982-10-26 | Conoco Inc. | Recirculating flue gas fluidized bed heater |
US6200128B1 (en) * | 1997-06-09 | 2001-03-13 | Praxair Technology, Inc. | Method and apparatus for recovering sensible heat from a hot exhaust gas |
US20020028043A1 (en) * | 1998-09-16 | 2002-03-07 | Jolt Ltd. | Wireless optical communications without electronics |
US6418865B2 (en) * | 1999-06-10 | 2002-07-16 | American Air Liquide | Method for operating a boiler using oxygen-enriched oxidants |
US6532881B2 (en) * | 1999-06-10 | 2003-03-18 | L'air Liquide - Societe' Anonyme A' Directoire Et Conseil De Surveillance Pour L'etude Et L'exploitation De Procedes Georges Claude | Method for operating a boiler using oxygen-enriched oxidants |
US6935251B2 (en) * | 2002-02-15 | 2005-08-30 | American Air Liquide, Inc. | Steam-generating combustion system and method for emission control using oxygen enhancement |
Cited By (10)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
US20080302107A1 (en) * | 2007-06-08 | 2008-12-11 | Foster Wheeler Energy Corporation | Method of and power plant for generating power by oxyfuel combustion |
US7874140B2 (en) * | 2007-06-08 | 2011-01-25 | Foster Wheeler North America Corp. | Method of and power plant for generating power by oxyfuel combustion |
US20110011315A1 (en) * | 2009-07-14 | 2011-01-20 | Hitachi, Ltd. | Oxyfuel Boiler and Control Method for Oxyfuel Boiler |
WO2011086232A1 (en) | 2010-01-12 | 2011-07-21 | Foster Wheeler Energia Oy | Method of combusting different fuels in an oxycombustion boiler |
EP2524167A1 (en) * | 2010-01-12 | 2012-11-21 | Foster Wheeler Energia Oy | Method of combusting different fuels in an oxycombustion boiler |
EP2524167A4 (en) * | 2010-01-12 | 2015-01-14 | Foster Wheeler Energia Oy | Method of combusting different fuels in an oxycombustion boiler |
WO2011131837A1 (en) * | 2010-04-23 | 2011-10-27 | Foster Wheeler Energia Oy | Method of controlling combustion in a cfb boiler plant |
EP2431579A3 (en) * | 2010-09-21 | 2014-02-19 | Hitachi Ltd. | Multipurpose thermal power plant system |
WO2012064545A3 (en) * | 2010-11-10 | 2013-11-28 | Praxair Technology, Inc. | Oxygen enhanced combustion of biomass |
WO2013041848A3 (en) * | 2011-09-19 | 2014-03-13 | Doosan Babcock Limited | Energy storage technology for demanded supply optimisation |
Also Published As
Publication number | Publication date |
---|---|
WO2009081364A2 (en) | 2009-07-02 |
EP2235440B1 (en) | 2017-11-08 |
AU2008341526A1 (en) | 2009-07-02 |
EP2235440A2 (en) | 2010-10-06 |
ZA201004146B (en) | 2011-05-25 |
RU2442076C1 (en) | 2012-02-10 |
WO2009081364A3 (en) | 2009-10-29 |
CN101952659A (en) | 2011-01-19 |
KR20100110826A (en) | 2010-10-13 |
JP2011508174A (en) | 2011-03-10 |
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