US20100276296A1 - Electrolytic hydrogen generating system - Google Patents

Electrolytic hydrogen generating system Download PDF

Info

Publication number
US20100276296A1
US20100276296A1 US12/611,727 US61172709A US2010276296A1 US 20100276296 A1 US20100276296 A1 US 20100276296A1 US 61172709 A US61172709 A US 61172709A US 2010276296 A1 US2010276296 A1 US 2010276296A1
Authority
US
United States
Prior art keywords
amperage
plates
threshold
actual
fuel cell
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Abandoned
Application number
US12/611,727
Inventor
Leslie Paul Arnett
Scott Alan Dehart
Robert E. Yelin
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Etorus Inc
Original Assignee
Etorus Inc
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Etorus Inc filed Critical Etorus Inc
Priority to US12/611,727 priority Critical patent/US20100276296A1/en
Priority to PCT/US2009/064119 priority patent/WO2010056799A2/en
Priority to CN2009801545559A priority patent/CN102282346A/en
Priority to ARP090104448A priority patent/AR074659A1/en
Assigned to ETORUS, INC. reassignment ETORUS, INC. ASSIGNMENT OF ASSIGNORS INTEREST (SEE DOCUMENT FOR DETAILS). Assignors: ARNETT, LESLIE PAUL, DEHART, SCOTT ALAN, YELIN, ROBERT E.
Publication of US20100276296A1 publication Critical patent/US20100276296A1/en
Abandoned legal-status Critical Current

Links

Images

Classifications

    • CCHEMISTRY; METALLURGY
    • C25ELECTROLYTIC OR ELECTROPHORETIC PROCESSES; APPARATUS THEREFOR
    • C25BELECTROLYTIC OR ELECTROPHORETIC PROCESSES FOR THE PRODUCTION OF COMPOUNDS OR NON-METALS; APPARATUS THEREFOR
    • C25B11/00Electrodes; Manufacture thereof not otherwise provided for
    • C25B11/02Electrodes; Manufacture thereof not otherwise provided for characterised by shape or form
    • C25B11/03Electrodes; Manufacture thereof not otherwise provided for characterised by shape or form perforated or foraminous
    • CCHEMISTRY; METALLURGY
    • C25ELECTROLYTIC OR ELECTROPHORETIC PROCESSES; APPARATUS THEREFOR
    • C25BELECTROLYTIC OR ELECTROPHORETIC PROCESSES FOR THE PRODUCTION OF COMPOUNDS OR NON-METALS; APPARATUS THEREFOR
    • C25B1/00Electrolytic production of inorganic compounds or non-metals
    • C25B1/01Products
    • C25B1/02Hydrogen or oxygen
    • C25B1/04Hydrogen or oxygen by electrolysis of water
    • CCHEMISTRY; METALLURGY
    • C25ELECTROLYTIC OR ELECTROPHORETIC PROCESSES; APPARATUS THEREFOR
    • C25BELECTROLYTIC OR ELECTROPHORETIC PROCESSES FOR THE PRODUCTION OF COMPOUNDS OR NON-METALS; APPARATUS THEREFOR
    • C25B11/00Electrodes; Manufacture thereof not otherwise provided for
    • CCHEMISTRY; METALLURGY
    • C25ELECTROLYTIC OR ELECTROPHORETIC PROCESSES; APPARATUS THEREFOR
    • C25BELECTROLYTIC OR ELECTROPHORETIC PROCESSES FOR THE PRODUCTION OF COMPOUNDS OR NON-METALS; APPARATUS THEREFOR
    • C25B11/00Electrodes; Manufacture thereof not otherwise provided for
    • C25B11/02Electrodes; Manufacture thereof not otherwise provided for characterised by shape or form
    • C25B11/036Bipolar electrodes
    • FMECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
    • F02COMBUSTION ENGINES; HOT-GAS OR COMBUSTION-PRODUCT ENGINE PLANTS
    • F02MSUPPLYING COMBUSTION ENGINES IN GENERAL WITH COMBUSTIBLE MIXTURES OR CONSTITUENTS THEREOF
    • F02M25/00Engine-pertinent apparatus for adding non-fuel substances or small quantities of secondary fuel to combustion-air, main fuel or fuel-air mixture
    • F02M25/10Engine-pertinent apparatus for adding non-fuel substances or small quantities of secondary fuel to combustion-air, main fuel or fuel-air mixture adding acetylene, non-waterborne hydrogen, non-airborne oxygen, or ozone
    • F02M25/12Engine-pertinent apparatus for adding non-fuel substances or small quantities of secondary fuel to combustion-air, main fuel or fuel-air mixture adding acetylene, non-waterborne hydrogen, non-airborne oxygen, or ozone the apparatus having means for generating such gases
    • YGENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y02TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
    • Y02EREDUCTION OF GREENHOUSE GAS [GHG] EMISSIONS, RELATED TO ENERGY GENERATION, TRANSMISSION OR DISTRIBUTION
    • Y02E60/00Enabling technologies; Technologies with a potential or indirect contribution to GHG emissions mitigation
    • Y02E60/30Hydrogen technology
    • Y02E60/36Hydrogen production from non-carbon containing sources, e.g. by water electrolysis
    • YGENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y02TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
    • Y02TCLIMATE CHANGE MITIGATION TECHNOLOGIES RELATED TO TRANSPORTATION
    • Y02T10/00Road transport of goods or passengers
    • Y02T10/10Internal combustion engine [ICE] based vehicles
    • Y02T10/12Improving ICE efficiencies

Definitions

  • One aspect is directed to a method of dynamically adding or removing a quantity of active plates in a plate assembly of a hydrogen generating system, the plate assembly comprising a plurality of plates.
  • the method includes receiving a minimum amperage threshold, a maximum amperage threshold, a maximum temperature threshold, a first actual amperage, and a first actual temperature of a hydrogen generating system, selecting a first plurality of plates from the plate assembly, wherein the selection is based on at least one of the following: the minimum amperage threshold, the maximum amperage threshold, the first actual amperage, and the first actual temperature, and applying a first voltage to the first plurality of plates.
  • a computer readable medium has instructions recorded thereon that when executed by a processor cause the processor to receive a minimum amperage threshold, a maximum amperage threshold, a maximum temperature threshold, a first actual amperage, and a first actual temperature of a hydrogen generating system, select a first plurality of plates from a plate assembly, wherein the selection is based on at least one of the following: the minimum amperage threshold, the maximum amperage threshold, the first actual amperage, and the first actual temperature, and apply a first voltage to the first plurality of plates.
  • FIG. 1 is a perspective of a hydrogen generating system of one suitable embodiment
  • FIG. 2 is a perspective of a frame of the device of FIG. 1 ;
  • FIG. 3 is an exploded view of the frame
  • FIG. 5 is an exploded cross-section taken in the plane of line 5 -- 5 of FIG. 4 ;
  • FIG. 6 is an exploded view of a housing of the system of FIG. 1 ;
  • FIG. 7 is a top plan view of the housing
  • FIG. 9 is a bottom perspective of a lid of the housing of FIG. 1 ;
  • FIG. 10 is a bottom plan view of the lid of FIG. 9 ;
  • FIG. 11 is a front elevation of the lid
  • FIG. 12 is a front elevation of the housing and showing a heater of the system
  • FIG. 13 is an exploded view of an electrode plate assembly of the housing of FIG. 6 ;
  • FIGS. 14A-14D are perspectives of plates of the electrode plate assembly
  • FIGS. 15A-15B are perspectives of connectors of the electrode plate assembly
  • FIGS. 16A-16C are perspectives of a retention bracket of the electrode plate assembly
  • FIG. 17 is a perspective of a plate assembly of a second embodiment
  • FIG. 18 is a block diagram of a vehicle including a hydrogen generating system
  • FIGS. 20 and 21 are flow charts showing an operation of the electronic controller
  • FIG. 22 is a flow chart showing an operation of the electronic controller dynamically adding or removing a quantity of active plates
  • FIG. 23 is a schematic of another embodiment of an electrode plate assembly
  • FIG. 24 is a graph showing how the electronic controller can determine which plate set is active
  • FIG. 25 is a graph that illustrates gas production versus time
  • FIG. 26 is a graph that illustrates temperature versus time
  • FIG. 27 is a graph that illustrates amperage versus time
  • FIG. 28 is a graph that illustrates efficiency versus time
  • FIG. 29 is a graph that illustrates gas production versus temperature
  • FIG. 30 is a perspective of a hydrogen generating system of another embodiment
  • FIG. 32 is a cross-section taken in the plane of lines 33 -- 33 of FIG. 30 ;
  • FIG. 33 is a cross-section taken in the plane of lines 33 -- 33 of FIG. 30 .
  • a fuel emission device or hydrogen generating system of one suitable embodiment is generally designated 11 .
  • the hydrogen generating system 11 generally comprises a housing 13 and a frame 15 for supporting the housing 13 .
  • the hydrogen generating system 11 and in particular the housing 13 and the frame 15 , are adapted for mounting on a vehicle 19 (see FIG. 18 ), such as a diesel tractor of a tractor-trailer combination, and operably connected to an internal combustion engine 21 (see FIG. 18 ).
  • a power source of the hydrogen generating system 11 may be, for example a 12 volt or a 24 volt source, though the hydrogen generating system 11 may be adapted to multiple voltage sources.
  • This embodiment also includes a reservoir 25 containing maintenance solution 27 , as shown in FIG. 5 , for facilitating continued operation of the hydrogen generating system 11 .
  • the reservoir 25 may, however, be omitted within the scope of this disclosure.
  • the frame 15 includes a floor 31 supporting the housing 13 , side walls 33 , and a back wall 35 (each of which are broadly referred to as “frame members”) such that the housing 13 is surrounded on three sides. In other embodiments, the back wall 35 may be omitted.
  • Upper ends of the side walls 33 have outwardly extending flanges 37 .
  • L-shaped brackets 39 are sized to engage the flanges 37 and to secure the housing 13 on the frame 15 .
  • the frame members are suitably secured by fasteners 41 (e.g., bolts and nuts), but may be secured in other ways, and may also be made as a one-piece unitary frame.
  • the frame 15 also includes an upright panel 43 secured to the back wall 35 .
  • the upright panel 43 has side flanges 45 along both vertical edges that extend forward around the side walls 33 .
  • the side flanges 45 add strength to the upright panel 43 .
  • the frame 15 is suitably made of steel, though other materials may be used.
  • the reservoir 25 includes a top 51 , a bottom 53 , a front wall 55 , a right wall 56 , a left wall 57 , and a back wall 58 .
  • the back wall 58 is generally flat and includes flanges 61 having holes 63 therein for receiving fasteners (not shown) therethrough. The fasteners secure the reservoir 25 to the upright panel 43 of the frame 15 .
  • the reservoir 25 includes a relatively large opening 64 formed in a neck 65 at the top 51 of the reservoir 25 .
  • the opening 64 is closed by a removable cap 67 that is suitably secured to the neck 65 (e.g., releasably secured by threads, not shown).
  • the reservoir 25 also includes an outlet port 69 extending from the bottom 53 of the reservoir 25 .
  • a suitable conduit such as a tube 71 (see FIG. 1 ) connects the outlet port 69 to the housing 13 .
  • the housing 13 defines an interior chamber 75 containing an electrolyte solution 77 , an electrode plate assembly 79 , a gasket 81 and a lid 83 .
  • the electrode plate assembly 79 is generally received in the chamber 75 , and at least partially submersed, and more suitably fully submersed in the electrolyte solution 77 .
  • the gasket 81 of this embodiment is an O-ring made of a material capable of withstanding high temperatures, such as 250° F. and is generally adapted to facilitate sealing the housing 13 .
  • the lid 83 of this embodiment is also generally rectangular and is configured to cover the chamber 75 .
  • the gasket 81 and the lid 83 are adapted to seal the housing 13 .
  • the lid 83 includes a set of channels 87 formed in an inner surface 89 of the lid 83 for channeling gas generated within the chamber 75 to a dome portion (e.g., collector 91 ) of the lid 83 .
  • the channels 87 are V-shaped in cross-section and an end of each of the channels 87 are adjacent to an end of the lid 83 .
  • Each of the channels 87 extend generally from the end adjacent to the lid 83 to the collector 91 .
  • An outlet 93 is disposed at an apex of the collector 91 .
  • a suitable delivery system, such as conduit 95 connects the outlet 93 to the engine 21 of the vehicle 19 (see FIG. 18 ).
  • the lid 83 has holes 96 around the periphery 97 for receiving fasteners that secure the lid 83 to the housing 13 .
  • the lid 83 has a square recess 99 for receiving a temperature sensor 101 (e.g., a thermistor) to sense the temperature of the hydrogen generating system 11 .
  • the sensor 101 may be disposed inside or outside the chamber 75 , and may be disposed anywhere on the housing 13 .
  • the delivery system may also include a condenser 100 disposed along the conduit 95 for inhibiting water vapor from entering the engine 21 .
  • the condenser may suitably be a bubbler-type condenser, though other types are contemplated.
  • the housing 13 has a generally rectangular opening for receiving the electrode plate assembly 79 when the lid 83 is removed.
  • the housing 13 also has four generally upright sides 103 and a bottom 105 . Ribs 106 on the sides 103 strengthen the housing 13 .
  • the housing 13 includes a flange 107 along an upper edge that mates with the lid 83 . Fasteners 98 extend through the lid 83 and the flange 107 of the housing 13 .
  • the housing 13 of this embodiment is of unitary, one-piece construction.
  • the housing 13 is made of a crack and corrosion resistant material.
  • the material may be non-insulating so that thermal energy (e.g., heat) can be more easily transmitted through the housing 13 .
  • One suitable material for the housing 13 is high-density polyethylene which can be molded to form the housing 13 .
  • Other materials may be used without departing from the scope of this disclosure.
  • an exterior of the bottom 105 of the housing 13 includes a central recess 109 .
  • the recess 109 spaces a portion of the housing 13 above the frame 15 , and is suitably configured to accommodate a heater 110 in abutting, thermal communication with the exterior of the bottom 105 (or generally the underside) of the housing 13 .
  • the heater 110 may be any suitable type of heater, including for example a radiant heater.
  • the heater 110 may be used to warm the housing 13 and the solution 77 therein to an operating temperature more quickly.
  • the electrode plate assembly 79 generally includes electrode plates, suitable brackets 121 (e.g., retention brackets), and connection posts 141 .
  • the electrode plates in this embodiment may be generally characterized as one of a neutral plate 125 N ( FIG. 14A ), an anode plate 125 A ( FIG. 14B ), or a cathode plate 125 C ( FIG. 14C ).
  • Each electrode plate is generally rectangular and may include notches 129 along each edge.
  • the neutral plate 125 N includes one notch 129 on a top edge 136 , one notch 129 on each side edge 137 , and two notches 129 along a bottom edge 138 to accommodate retention brackets 121 .
  • Each electrode plate may have fastener holes 131 in a periphery of each electrode plate for receiving fasteners 122 therethrough for use in securing the retention brackets 121 on the electrode plate assembly 79 .
  • One or more of the electrode plates may include surface features, such as openings or holes, that are sized and shaped to increase a surface area and “active sites” of the one or more electrode plates.
  • suitable surface features include a plurality of holes in the form of slots 133 formed in a central section of the neutral plate 125 N. Other shapes of openings are contemplated within the scope of the disclosure.
  • the slots 133 provide an increase in surface area of at least about 0.3%, and in some embodiments at least about 0.5%, when compared to a hypothetical plate of the same dimensions but without surface features.
  • a ratio of surface area of each electrode plate having surface features as compared to the hypothetical electrode plate without such features is at least 1.03, and in some embodiments at least about 1.05.
  • each electrode plate is 0.40005 ⁇ 0.17780 ⁇ 0.00160 meters (16 gauge) and includes 200 slots 133 .
  • Each slot 133 has a radius of 0.00117 meters. This configuration results in an increase in surface area of about 0.5% (with a ratio of 1.005) when the surface area of an electrode plate includes openings as compared to the hypothetical plate without such openings.
  • the cathode plate 125 C and the anode plate 124 A do not include slots 133 , but only holes 131 for receiving the fasteners 122 therethrough.
  • other embodiments have small slots 133 in the anode plate 125 A and/or the cathode plate 125 C.
  • the electrode plates may have other surface features for increasing surface area (e.g., additional surfaces, slits, holes, bumps, projections, or a rough or an abraded surface).
  • the plate 125 D of FIG. 14D includes projections 134 extending outward from a surface or face of the plate 125 D, and dimples or impressions 135 extending inward into the surface.
  • cathode plates 125 C (first and second cathode plates) are disposed at each end of the electrode plate assembly 79 so that the plates are in spaced apart relationship.
  • An anode plate 125 A is separate from the cathode plates 125 C and disposed in a center of the electrode plate assembly 79 intermediate the cathode plates in spaced apart relationship therewith.
  • a plurality of neutral plates 125 N are disposed between each cathode plate 125 C and the anode plate 125 A, each neutral plate in spaced relationship with the anode plate and the cathode plates.
  • the cathode plates 125 C and the anode plate 125 A may be swapped such that one anode plate 125 A is at each end of the electrode plate assembly 79 and one cathode plate 125 C is in the center of the electrode plate assembly 79 .
  • the number of neutral plates 125 N may also vary. In embodiments, for example, there may be 18 neutral plates 125 N, 16 neutral plates 125 N, 14 neutral plates 125 N, 12 neutral plates 125 N, 10 neutral plates 125 N, or 8 neutral plates 125 N. In the latter embodiment (8 neutral plates 125 N), there are a total of 11 electrode plates (8 neutral plates 125 N, one anode plate 125 A, and two cathode plates or end plates 125 C).
  • One advantage of using more electrode plates is that using more electrode plates enables the hydrogen generating system 11 to operate at a lower temperature.
  • the number of neutral plates 125 N on either side of the anode plate 125 A may be equal.
  • other numbers and configurations of the electrode plates are contemplated.
  • Two cathode plates 125 C may be electrically connected by suitable connectors, such as by a U-shaped connector 139 shown in FIG. 15A or by other suitable connector(s).
  • a post 141 extends upward from the U-shaped connector 139 .
  • the post 141 is suitably a “clench” or threaded fastener that is joined to the U-shaped connector 139 by a nut 143 .
  • the post 141 may be joined to the U-shaped connector 139 by a separate fastener, by welding, or the like.
  • the post 141 may also be formed as one-piece with the U-shaped connector 139 .
  • the U-shaped connector 139 is suitably joined to the cathode plates 125 C by a fastener, but may be joined in other suitable ways.
  • the U-shaped connector 139 and the post 141 may also both be formed as one-piece with one or both of the cathode plates 125 C.
  • An L-shaped connector 147 ( FIG. 15B ) has the post 141 extending upward from a main surface of the L-shaped connector 147 .
  • the L-shaped connector 147 is suitably joined to the anode plate 125 A at a top edge of the anode plate 125 A by threads as described above.
  • the post 141 may be made as one-piece with the L-shaped connector 147 and the anode plate 125 A.
  • the posts 141 are suitably connected to the power source by wires (not shown).
  • the electrode plate assembly 79 may alternatively be referred to as a “cell.” In further embodiments, more than one electrode plate assembly 79 , or cell, may be used. For example, a second electrode plate assembly, or cell, may be added to the electrode plate assembly 79 , described above, and more suitably a non-conductive barrier may be disposed between each of the electrode plate assemblies.
  • Each electrode plate is made of a suitable material that is resistant to reactivity with the solution 77 or amperage applied.
  • the electrode plates are made of a 316L stainless steel.
  • the material of an electrode plate is chosen to have an appropriate resistance.
  • Each electrode plate should be sufficiently thick to reduce electrical resistance and to inhibit significant flexing of the electrode plates. In some embodiments, each electrode plate is between 16 gauge and 20 gauge, and in one embodiment each electrode plate is 20 gauge.
  • a resistance of a wire is generally affected by four factors: (1) material (for example, gold and silver have relatively low resistance), (2) a thickness of the wire or the electrode plate, (3) a temperature of the wire or the electrode plate, and (4) a length of the wire (but a length of an electrode plate is not an applicable factor).
  • material for example, gold and silver have relatively low resistance
  • a thickness of the wire or the electrode plate the more space exists for a current to flow. As an electrode plate warms up, there is more energy therein and a resistance to a current and an electron flow decreases.
  • each retention bracket 121 is generally U-shaped.
  • Each bracket 121 is generally “combed”, meaning that each bracket 121 includes a bridge 148 and a plurality of spacers 149 (or teeth) spaced apart such that one electrode plate fits between two adjacent spacers 149 . Spacing between spacers 149 is uniform so that a spacing between each electrode plate is equal. In one embodiment, for example, the spacing between each electrode plate is suitably between about 2.0 mm and about 6.5 mm.
  • Fasteners extend through the brackets 121 and through the electrode plates to secure the stack (e.g., the electrode plate assembly), together.
  • Each bracket is suitably made of an electrically non-conductive material.
  • each electrode plate 151 is configured for an electrical connection point 153 at one end of each electrode plate 151 , for a total of 12 connection points.
  • the plates are interleaved such that connection points of adjacent plates 151 are opposite one another.
  • a first set of electrical connections 153 are attached (e.g., by jumper wires) to connector blocks 156 , with a corresponding second set of electrical connections 153 being attached to a respective wire harnesses (not shown) and connected to an electrical controller 202 (see FIG. 19 ).
  • the controller 202 switches an electrical current to various combinations of electrode plate sets to develop a best use of current in the hydrogen generating system 11 , such as by the method described below.
  • Generating system 11 ′ of another embodiment shown in FIG. 23 and FIGS. 30-32 is similar to the system 11 of FIGS. 1-12 .
  • the positioning of the electrode plates in generating system 11 ′ is shown schematically in FIG. 23 and described in more detail in the Example System below.
  • plate assembly 502 includes 22 electrode plates (six anode plates 510 , 512 , 514 , 516 , 518 , 520 , one cathode plate 508 , and 15 neutral plates 524 ).
  • the anode plates may instead be cathode plates, and the cathode plate may be an anode plate.
  • the anode plates 510 , 512 , 514 , 516 , 518 , 520 serve as neutral plates.
  • the cathode plate 508 includes a post 509 that extends through the lid 83
  • each anode plate 125 A includes a similar post 511 that extends through the lid 83 at an opposite end of the lid 83 .
  • the brackets 121 ′ of this embodiment include spacers 122 ′ that extend upward about 1.5 inches.
  • the brackets 121 are sized such that there is about 0.25 inches clearance between a bottom of the electrode plates and the housing 13 .
  • the brackets 121 may also be beveled to provide clearance of the electrode plates relative to the housing 13 .
  • a float mechanism 124 extends from a port in the lid 83 .
  • the float mechanism 124 serves to ensure that the solution 77 ′ is at a level above a top of the electrode plate assembly 502 .
  • the float mechanism 124 is suitably a conventional float 126 similar to a type used in a home toilet tank.
  • the mechanism 124 is in fluid communication with the solution 77 ′ in the chamber 75 ′ and with the reservoir 25 via tube 71 ′.
  • the float 126 pivots downward, opening a valve that allows maintenance solution (e.g., solution 27 ) from the reservoir 25 to enter the chamber 75 ′.
  • the float 126 moves upward and closes the valve.
  • the reservoir 25 is suitably disposed above the housing 13 ′ for gravity flow of the maintenance solution to the chamber.
  • each electrode plate can be monitored to control an amperage level generated. As described in detail below, power can be channeled to each electrode plate as needed to increase hydrogen production for a given amperage. This can increase the generation of hydrogen and oxygen available at start-up and significantly reduce a usual warm-up period required to get the hydrogen generating system 11 to full production at optimum temperature.
  • the housing 13 or 13 ′ has sufficient fluid (e.g., electrolyte solution 77 ) therein so that the electrode plates are submersed in the fluid. Opposite faces (both faces) of the electrode plates (any of the plates described herein) are exposed to the electrolyte solution. Also, the surface features as described herein are exposed to the solution.
  • the fluid of one embodiment is a solution having 20-320 mL of 2.14 molar potassium hydroxide diluted to 11.353 liters.
  • the electrolyte suitably contains color and buffers.
  • 200 mL of 2.14 molar solution is added to the chamber 75 or 75 ′ and diluted with distilled water to a capacity of the chamber, for example 11.353 liters.
  • a concentration of electrolyte facilitates the electrical current through the aqueous solution.
  • the reservoir 25 holds a maintenance solution (e.g., solution 27 ).
  • the maintenance solution includes two buffer solutions and distilled water, though it is contemplated to use only distilled water.
  • the first buffer is alkaline, and includes boric acid (H 2 B 4 O 7 ) and Sodium hydroxide, N a OH.
  • the solution has a pH of about 12.7.
  • the solution is made by dissolving the boric acid and sodium hydroxide in 1 liter of distilled water. This yields 0.1 M concentrations of each species. Then 10 mL of the solution is added to 3.7843 liters of distilled water. A suitable dye, such as bromothymol blue, may then be added.
  • the second buffer solution for the maintenance solution is also alkaline and includes dipotassium phosphate (K 2 HPO 4 ) and tripotassium phosphate K 3 PO 4 .
  • the solution has a pH in a range of 10-14, or in some embodiments between 11 and 13, and in some embodiments about 12.7. In one embodiment, there is between 10 grams and 20 grams of dipotassium phosphate and between about 9 grams and 15 grams of tripotassium phosphate, in another embodiment between about 30 grams and 32 grams of dipotassium phosphate and between 11 grams and 13 grams of tripotassium phosphate, and in one embodiment about 15.8 grams of dipotassium phosphate and about 19.6 grams of tripotassium phosphate.
  • the solution is made by dissolving the dipotassium phosphate and tripotassium phosphate in 1 liter of distilled water. This yields 0.1 M concentrations of each species. Then 10 mL of the solution is added to 3.7843 liters of distilled water. A suitable dye, such as bromothymol blue, may then be added.
  • FIG. 18 an exemplary block diagram of the vehicle 19 (e.g., a truck) including the hydrogen generating system 11 in communication with the engine 21 of the vehicle is shown.
  • system 11 ′ can be used instead.
  • Embodiments of the disclosure enable the hydrogen generating system 11 to generate a sufficient amount hydrogen gas per minute (e.g., 6 liters of hydrogen gas per minute) at a very low temperature (e.g., 40° F.) immediately upon start-up. Further, embodiments of the present disclosure enable the hydrogen generating system to manage heat at high temperatures (e.g., 140-180° F.) while producing acceptable quantities of hydrogen gas (e.g., over 2 liters per minute).
  • an exemplary block diagram of the hydrogen generating system 11 including an electronic controller 202 is shown.
  • Embodiments of the disclosure enable the electronic controller 202 to monitor an actual amperage and an actual temperature of the hydrogen generating system 11 . Further, the embodiments described herein enable the hydrogen generating system 11 to achieve increased amperage between electrode plates of a cell substantially immediately upon a start-up of the hydrogen generating system 11 by effectively omitting a quantity of electrode plates over which a voltage is applied.
  • the electronic controller 202 as described herein has one or more processors 204 or processing units, a memory area 206 , and some form of computer readable media.
  • computer readable media comprise computer storage media and communication media.
  • Computer storage media include volatile and nonvolatile, removable and non-removable media implemented in any method or technology for storage of information such as computer readable instructions, data structures, program modules or other data.
  • Communication media typically embody computer readable instructions, data structures, program modules, or other data in a modulated data signal such as a carrier wave or other transport mechanism and include any information delivery media. Combinations of any of the above are also included within the scope of computer readable media.
  • processor(s) 204 executes computer-executable instructions for implementing aspects of the disclosure.
  • the processor(s) 204 is programmed with instructions such as illustrated in FIGS. 20-22 .
  • the computer-executable instructions may be organized into one or more computer-executable components or modules.
  • program modules include, but are not limited to, routines, programs, objects, components, and data structures that perform particular tasks or implement particular abstract data types. Aspects of the present disclosure may be implemented with any number and organization of such components or modules.
  • aspects of the invention are not limited to the specific computer-executable instructions illustrated in the figures and described herein. Other embodiments of the invention may include different computer-executable instructions. Aspects of the disclosure may also be practiced in distributed computing environments where tasks are performed by remote processing devices that are linked through a communications network.
  • the processor(s) 204 is transformed into a special purpose microprocessor by executing computer-executable instructions or by otherwise being programmed.
  • the electronic controller 202 may be in communication with a display device (not shown) separate from or physically coupled to the hydrogen generating system 11 .
  • the display device may be a capacitive touch screen display, or a non-capacitive display.
  • User input functionality may also be provided in the display, where the display acts as a user input selection device such as in a touch screen.
  • the display device may provide a user with information regarding the hydrogen generating system 11 , such as, temperature, measured amperage, error messages, and the like.
  • the hydrogen generating system 11 includes a temperature sensor (e.g., temperature sensor 101 ) configured to measure an actual temperature of the hydrogen generating system 11 .
  • the temperature sensor 101 may be disposed on the outside of the housing 13 . Due to the thermal properties of the housing 13 , a temperature drop across a wall of the housing 13 is minimal so that the sensed/measured temperature is relatively close to the temperature inside the housing 13 .
  • the temperature sensor 101 may alternatively be disposed inside the housing 13 .
  • a time from a start-up to optimum operating temperature (e.g., about 140° F. to about 160° F.) of the hydrogen generating system 11 is a function of an amount of amperage generated by electrolysis. Therefore, as temperature increases, amperage increases, and an efficiency for producing hydrogen gas increases.
  • An amperage sensor (not shown) may be used to measure an actual amperage of the hydrogen generating system 11 .
  • the hydrogen generating system 11 includes resistors configured to measure an actual amperage.
  • a flow chart showing an operation of the electronic controller 202 is shown.
  • a target amperage e.g., about 20 amps to about 30 amps
  • a maximum threshold temperature e.g., about 180° F.
  • the target amperage and the maximum threshold temperature may be automatically set by a manufacturer and/or manually selected by a user via the display device.
  • the electronic controller 202 enables each electrode plate in the electrode plate assembly 79 to be individually monitored and controlled.
  • a quantity of electrode plates less than a total quantity of the electrode plates in the electrode plate assembly 79 to apply a voltage to is selected. Choosing to apply a voltage across a selected quantity of electrode plates less than a total quantity of the electrode plates in the electrode plate assembly 79 can result in higher currents dissipating more power. This causes a faster rise in a temperature of an electrolyte between the electrode plates to which the voltage is applied (e.g., the active electrode plate set), thereby increasing production of hydrogen gas that is being produced by the active electrode plates.
  • the electrolyte becomes more conductive, enabling an inclusion of additional electrode plates in the active electrode plate set and thus increasing the efficiency of hydrogen gas produced by the hydrogen generating system 11 .
  • Applying a voltage across a quantity of electrode plates less than a total quantity of electrode plates in the electrode plate assembly enables the hydrogen generating system to generate at least 2 liters of hydrogen gas per minute at a very low temperature (e.g., 40° F.) substantially immediately upon start-up.
  • a very low temperature e.g. 40° F.
  • the quantity of the plurality of electrode plates that receive the applied voltage may be based on at least one of the following: a temperature of an electrolytic solution, an amount of voltage applied, a distance between each of the plurality of electrode plates (e.g., about 3 mm), and a type and concentration of electrolytic solution used. This can increase generation of hydrogen and oxygen available at start-up and significantly reduce a warm-up period required to get the hydrogen generating system 11 to full production at optimum temperature, the process of which is described in detail below.
  • the electronic controller 202 provides a pulse of electricity at a particular voltage for a duty cycle of, for example, 4 ms (four milliseconds).
  • the length of the duty cycle i.e., 4 ms
  • the length of the duty cycle is merely exemplary and is not intended to limit the scope of the present disclosure.
  • One of ordinary skill in the art will appreciate that various lengths of time may be used, for example, 8 ms, 12 ms, and 14 ms may be used.
  • a duty cycle may be limited by applying the pulse for a fraction of the duty cycle.
  • a pulse may be applied for only 3 ms of the 4 ms duty cycle, 2 ms of the 4 ms duty cycle, or even 1 ms of the 4 ms duty cycle.
  • the pulse applied during the 4 ms duty cycle can be divided even further, for example, to 1/16 or 1/32 of the 4 ms duty cycle.
  • the electronic controller 202 can effectively lower the voltage applied to the selected number of the plurality of plates (e.g., by decreasing the time a pulse is applied in the duty cycle) to maintain the amperage at a desired level during operation.
  • the electronic controller 202 is configured to compare the actual amperage to an amperage threshold (e.g., 25 amps), compare the actual temperature to a maximum threshold temperature (e.g., 160° F.), and at 216 , adjust at least one of a duty cycle and/or the applied voltage based on the comparisons in order to regulate the actual temperature and the actual amperage. For example, if it is determined that an actual amperage exceeds a maximum amperage threshold (e.g., 30 amps) and/or the actual temperature is greater than the optimal temperature, the duty cycle may be adjusted to enable an average of an actual amperage to substantially equal the target amperage.
  • an amperage threshold e.g. 25 amps
  • a maximum threshold temperature e.g. 160° F.
  • the duty cycle may be adjusted to enable an average of an actual amperage to substantially equal the target amperage.
  • the duty cycle may be increased. For example, a maximum voltage may be applied to the selected quantity of plates for at least one duty cycle. Next, the actual amperage and the actual temperature of the hydrogen generating system are measured again, and the process is repeated.
  • a target amperage e.g., about 20 amps and about 30 amps
  • an optimal temperature e.g., about 160° F.
  • a maximum threshold temperature e.g. 180° F.
  • the optimal temperature is a range of temperatures, for example, the optimal temperature may be a temperature between 140° F. and 160° F.
  • a voltage is applied to at least some (e.g., a selected quantity) of the plurality of plates in the hydrogen generating system.
  • an actual amperage and an actual temperature of the hydrogen generating system 11 are determined/obtained, and thereafter, compared to the target amperage and the optimal temperature, respectively.
  • the actual amperage is below the maximum amperage threshold (e.g., an amperage that does not overburden a battery of the vehicle 19 )
  • full voltage is applied for at least one duty cycle.
  • the maximum amperage threshold i.e., the current reaches a level where components may be damaged
  • a duty cycle is computed resulting in an increased temperature.
  • the maximum amperage threshold may be 50 amps.
  • a duty cycle is computed and a rated amount of hydrogen gas is produced.
  • a duty cycle is reduced to maintain the temperature. After the duty cycle is reduced, the actual amperage is compared to the maximum safe amperage. If, at 322 , the actual amperage is less than or equal to a maximum safe amperage threshold, the actual temperature is compared to the maximum threshold temperature.
  • a current of the hydrogen generating system 11 is turned off, an actual temperature (e.g., a second actual temperature) is measured, and the current of the hydrogen generating system 11 is turned on when it is determined that the second actual temperature is below the maximum temperature threshold.
  • the current of the hydrogen generating system 11 is turned off for a predefined period of time (e.g., three minutes).
  • a predefined period of time e.g., three minutes.
  • an actual amperage e.g., a second actual amperage is determined and compared to the maximum safe amperage, and the process is repeated.
  • using interchangeable electrode plates as anodes and cathodes also maximizes gas production by optimizing the quantity of energized (e.g., active) electrode plates based on a target amperage. As more electrode plates are energized, the quantity of electrolyte to electrode plate transitions is increased which increases the gas production per amp.
  • energized e.g., active
  • a transition occurs where electricity passes from the liquid electrolyte to the metal of an electrode plate (the electrolyte/plate interface). Hydrogen gas is formed at this electrolyte/plate interface. Hence, if an electric current makes the same amount of hydrogen gas for each transition from liquid to metal, the more times a current is forced to make the transition, the more hydrogen gas is produced per amp and the more efficient the hydrogen generating system becomes.
  • anodes 514 and 516 in the embodiment shown in FIG. 23 are energized, the electrolyte increases in temperature, becomes more conductive, and the current increases. When the current reaches 30 amps, anodes 512 and 516 are energized. The current now drops because the additional transitions limit the current. This process continues as anodes 512 and 518 , then anodes 510 and 518 , and then anodes 510 and 520 are sequentially energized.
  • any single anode as opposed to multiple anodes, may be selected to be energized based, for example, on amperage and/or temperature.
  • the electrolyte concentration is set to allow sufficient current to flow at the largest plate set contemplated to produce the desired gas. As explained above, when an amperage threshold is detected, additional plates may be energized to enable the hydrogen generating system 11 operate at optimal production. The conversion to an optimal operating electrode plate configuration is a factor in the increased efficiency of the electrolysis process.
  • embodiments of the disclosure are operational with numerous other general purpose or special purpose computing system environments or configurations.
  • Examples of well known computing systems, environments, and/or configurations that may be suitable for use with aspects of the disclosure include, but are not limited to, mobile computing devices, personal computers, server computers, hand-held or laptop devices, multiprocessor systems, microprocessor-based systems, programmable consumer electronics, mobile telephones, network PCs, minicomputers, mainframe computers, distributed computing environments that include any of the above systems or devices, and the like.
  • FIG. 22 is a flow chart showing an operation of the electronic controller 202 dynamically adding or removing a quantity of active electrode plates from an electrode plate assembly (e.g., electrode plate assembly 502 in FIG. 23 ) based on at least one of an actual amperage and an actual temperature.
  • an electrode plate assembly e.g., electrode plate assembly 502 in FIG. 23
  • the electronic controller 202 selects a first plurality of plates (e.g., an initial plurality of plates) from the electrode plate assembly 502 .
  • the selection of the first plurality of plates is based on at least one of the following: the minimum amperage threshold, the maximum amperage threshold, and the first actual temperature of a hydrogen generating system.
  • the first actual temperature may be the temperature of the hydrogen generating system 11 upon start-up.
  • an actual amperage e.g., a first actual amperage
  • an actual temperature e.g., a second actual temperature
  • the first actual amperage is compared to the minimum amperage threshold and the maximum amperage threshold.
  • a voltage is again applied to the first plurality of electrode plates.
  • a second plurality of electrode plates is selected from the electrode plate assembly 502 whereafter a voltage is applied to the second plurality of electrode plates.
  • the first actual amperage is not between the minimum amperage threshold and the maximum amperage threshold, and, at 416 , the first actual amperage is not greater than or equal to the maximum amperage threshold, at 420 , it is determined if the first actual amperage is less than or equal to the minimum amperage threshold. If, at 420 , the first actual amperage is less than or equal to the minimum amperage threshold, the second plurality of plates selected includes more plates than the first plurality of plates.
  • a second plurality of electrode plates that includes fewer plates than the first plurality of plates is selected from the electrode plate assembly 502 .
  • FIG. 23 is a further example of an electrode plate assembly (e.g., the electrode plate assembly 502 described above).
  • the electrode plate assembly 502 can be used in place of the assembly shown above in FIGS. 6-8 in a housing, such as housing 13 ′, sized accordingly.
  • the electrode plate assembly 502 includes two cells (e.g., cell 504 and cell 506 ) that share a common cathode 506 .
  • the present disclosure enables the cells 504 and 506 to operate (or run) in parallel to achieve a sufficient amount of hydrogen gas production (e.g., about 2 liters of hydrogen gas per minute) at low temperatures (e.g., about 40 ° F.).
  • the cell 504 includes 11 electrode plates, three of which are anodes (e.g., anode 510 , anode 512 , and anode 514 ) and one of which is the cathode 508 .
  • the cell 506 includes 12 electrode plates, three of which are anodes (e.g., anode 516 , anode 518 , and anode 520 ) and one of which is the cathode 508 .
  • anodes e.g., anode 516 , anode 518 , and anode 520
  • cathode 508 The cell 506 includes 12 electrode plates, three of which are anodes (e.g., anode 516 , anode 518 , and anode 520 ) and one of which is the cathode 508 .
  • a distance between each electrode plate in the electrode plate assembly 502 is suitably about 3 mm, and a thickness of each electrode plate is suitably about 20 gauge.
  • a quantity of electrode plates, a distance between each electrode plate, and a thickness of each electrode plate are merely exemplary and are not intended to limit the scope of the present disclosure.
  • the electrode plate assembly 502 is configured to have a voltage applied to a quantity of electrode plates less than the total quantity of electrode plates in each cell 504 and 506 .
  • the total quantity of electrode plates e.g., 22 plates with the cells 504 and 506 operating in parallel
  • electrode plate sets e.g., electrode plate set 1 , electrode plate set 2 , electrode plate set 3 , electrode plate set 4 , and electrode plate set 5 .
  • Each electrode plate set has a different quantity of electrode plates.
  • a quantity of electrode plates in each electrode plate set increases from electrode plate set 1 to electrode plate set 5 .
  • electrode plate set 1 includes 14 electrode plates
  • electrode plate set 2 includes electrode 16 plates
  • electrode plate set 3 includes 18 electrode plates
  • electrode plate set 4 includes 20 electrode plates
  • electrode plate set 5 includes 22 electrode plates.
  • Each of the electrode plate sets are defined by anode plates at opposing ends of each electrode plate set.
  • electrode plate set 1 has anode 514 and anode 516 at opposing ends
  • electrode plate set 2 has anode 512 and anode 516 at opposing ends
  • electrode plate set 3 has anode 512 and anode 518 at opposing ends
  • electrode plate set 4 has anode 510 and anode 518 at opposing ends
  • electrode plate set 5 has anode 510 and anode 520 at opposing ends.
  • FIG. 24 is a graph that includes data that further illustrates how the electronic controller 202 determines which electrode plate set is active (e.g., which electrode plate set receives a voltage).
  • the determination is based on a target amperage, and more specifically, a target amperage range bound by a minimum amperage threshold and maximum amperage threshold.
  • the minimum amperage threshold is 20 amps and the maximum amperage threshold is 30 amps.
  • the minimum amperage threshold and the maximum amperage threshold may be automatically set and/or manually selected by a user via the display device.
  • the minimum amperage threshold of 20 amps and the maximum amperage threshold of 30 amps are merely exemplary are not intended to limit the scope of the present disclosure.
  • amperage decreases as a quantity of active electrode plates increase.
  • amperage increases as temperature increases.
  • applying a voltage to an electrode plate set with a lesser quantity of electrode plates will return a higher amperage compared to applying a voltage to an electrode plate set with a greater quantity of electrode plates at the same temperature. Therefore, when a voltage is applied to a particular electrode plate set and an actual amperage reaches the maximum amperage threshold, the electronic controller 202 activates an electrode plate set that has a greater quantity of electrode plates than the presently active electrode plate set, thereby decreasing the amperage.
  • the electronic controller 202 activates an electrode plate set that has a lesser quantity of electrode plates than the presently active electrode plate set, thereby increasing the amperage.
  • an electrode plate set that includes the least quantity of electrode plates (e.g., plate set 1 if the cells 504 and 506 are operating in parallel) returns the highest amperage. Therefore, in the example shown in FIG. 24 , because the temperature of the hydrogen generating system 11 is only at 60° F., the electronic controller 202 initially activates electrode plate set 1 , which returns an actual amperage of 34.8 amps. However, 34.8 amps is above the maximum amperage threshold of 30 amps. Therefore, the electronic controller 202 increases a quantity of active electrode plates by activating electrode plate set 2 . Activating electrode plate set 2 returns an actual amperage of 30.5 amps. However, 30.5 amps is still above the maximum amperage threshold of 30 amps. Therefore, the electronic controller 202 increases a quantity of active electrode plates by activating electrode plate set 3 . Activating electrode plate set 3 returns an actual amperage of 28 amps.
  • the temperature of the hydrogen generating system increases with time. As mentioned above, as the temperature of the hydrogen generating system 11 increases, amperage increases. Therefore, while the electrode plate set 3 initially returns an actual amperage of 28 amps, as time elapses, the temperature of the hydrogen generating system 11 increases from 69° F. to 78° F. However, once the temperature of the hydrogen generating system 11 reaches 78° F., the electrode plate set 3 returns an actual amperage of 30.30 amps, which is above the maximum amperage threshold of 30 amps. Therefore, the electronic controller 202 increases a quantity of active electrode plates by activating electrode plate set 4 , and at 78° F., the electrode plate set 4 returns an actual amperage of 23.7 amps.
  • the electrode plate set 4 returns an actual amperage of 31.50 amps, which is above the maximum amperage threshold of 30 amps. Therefore, the electronic controller 202 increases a quantity of active electrode plates by activating electrode plate set 5 , and at 118° F., the electrode plate set 5 returns an actual amperage of 26.2 amps.
  • the electronic controller 202 may stop operating each of the cells 504 and 506 in parallel. In this embodiment, operating only one cell, three electrode plate sets are left available:
  • electrode plate sets 6 , 7 , and 8 increase in total electrode plates by only 1 electrode plate, increasing the control and resolution.
  • the electronic controller 202 may also adjust the duty cycle.
  • FIG. 25 is a graph that illustrates gas production versus time.
  • the graph represents the results achieved by implementing what is shown in FIG. 22 , where the electronic controller 202 dynamically added/removed a quantity of electrode plates and/or at least one of the applied voltage and a duty cycle based on amperage and temperature.
  • the electronic controller 202 dynamically added/removed a quantity of electrode plates and/or at least one of the applied voltage and a duty cycle based on amperage and temperature.
  • about 2.8 liters of hydrogen gas are produced per minute upon initial start-up.
  • the last two points on the graph represent where a current was limited in order to prevent an increase in temperature.
  • FIG. 26 is a graph that illustrates temperature versus time. As expected, the temperature rises faster in the beginning when fewer electrode plates are active, and as more electrode plates are added, the rate of increase in the temperature is reduced.
  • FIG. 27 is a graph that illustrates current/amperage versus time. As shown in the graph, the actual amperage decreases with time because, as time elapses, temperature increases and a quantity of active electrode plates operated is increased to decrease the amperage (see FIG. 22 ). Further, power dissipated is equal to a voltage applied across a cell multiplied by the amps passing through the cell. As amperage drops at higher temperatures, the power flowing to the hydrogen generating system 11 drops and a rate of temperature rise slows down.
  • FIG. 28 is a graph that illustrates efficiency versus time, where efficiency is an amount of hydrogen gas produced per amperage of electricity. As shown in the graph, efficiency generally improves as temperature increases and the quantity of active electrode plates increases.
  • each plate set is as follows: electrode plate set 1 (0.083), electrode plate set 2 (0.092), electrode plate set 3 (0.094), electrode plate set 4 (0.104), and electrode plate set 5 (0.110). As shown here, increasing a quantity of active electrode plates between an anode and a cathode increases efficiency.
  • FIG. 29 is a graph that illustrates gas production versus temperature. As shown in the graph, about 2.7 liters of gas per minute is achievable at 60° F. These numbers are merely exemplary and are not intended to limit the scope of the present disclosure. For example, further tests have shown that 2 liters of hydrogen gas per minute can be achieved at only 40° F., without going over 30 amps.
  • the hydrogen generating system 11 is mounted in the vehicle 19 , such as a truck, and is mounted outside the engine 21 , for example, behind a cab of the truck.
  • vehicle 19 such as a truck
  • engine 21 for example, behind a cab of the truck.
  • Other mounting arrangements are contemplated.
  • the hydrogen output from the hydrogen generating system 11 is directed to the engine 21 of the truck.
  • the hydrogen gas is a supplement to the conventional fuel of such an engine (e.g., a petroleum-based fuel or “fossil fuel” such as unleaded gasoline, diesel, natural gas or propane).
  • the hydrogen gas can improve fuel efficiency of the engine 21 .
  • the hydrogen gas may enable the engine 21 to meet stringent emission standards while also increasing fuel economy and/or power output.

Abstract

A method of dynamically adding or removing a quantity of active plates in a plate assembly of a hydrogen generating system, the plate assembly comprising a plurality of plates. The method includes receiving a minimum amperage threshold, a maximum amperage threshold, a maximum temperature threshold, a first actual amperage, and a first actual temperature of a hydrogen generating system, selecting a first plurality of plates from the plate assembly, wherein the selection is based on at least one of the following: the minimum amperage threshold, the maximum amperage threshold, the first actual amperage, and the first actual temperature, and applying a first voltage to the first plurality of plates.

Description

    CROSS REFERENCE TO RELATED APPLICATIONS
  • This application claims the benefit of U.S. Provisional Patent Application No. 61/115,463 filed on Nov. 17, 2008 and 61/117,481 filed on Nov. 24, 2008, respectively, both of which are hereby incorporated by reference in their entirety.
  • BACKGROUND
  • The use of hydrogen and oxygen gas to supplement the conventional fuel in an internal combustion engine in order to increase the efficiency of the engine is known. For example, electrolytic hydrogen generating systems are known to produce hydrogen and oxygen gases for use as fuel additives. However, a satisfactory hydrogen generating system that efficiently uses the power supplied to the system and generates a sufficient supply of gases at acceptable temperatures does not yet exist.
  • BRIEF DESCRIPTION
  • One aspect is directed to a method of dynamically adding or removing a quantity of active plates in a plate assembly of a hydrogen generating system, the plate assembly comprising a plurality of plates. The method includes receiving a minimum amperage threshold, a maximum amperage threshold, a maximum temperature threshold, a first actual amperage, and a first actual temperature of a hydrogen generating system, selecting a first plurality of plates from the plate assembly, wherein the selection is based on at least one of the following: the minimum amperage threshold, the maximum amperage threshold, the first actual amperage, and the first actual temperature, and applying a first voltage to the first plurality of plates.
  • In another aspect, a computer readable medium has instructions recorded thereon that when executed by a processor cause the processor to receive a minimum amperage threshold, a maximum amperage threshold, a maximum temperature threshold, a first actual amperage, and a first actual temperature of a hydrogen generating system, select a first plurality of plates from a plate assembly, wherein the selection is based on at least one of the following: the minimum amperage threshold, the maximum amperage threshold, the first actual amperage, and the first actual temperature, and apply a first voltage to the first plurality of plates.
  • Various refinements exist of the features noted in relation to the above-mentioned aspects. Further features may also be incorporated in the above-mentioned aspects as well. These refinements and additional features may exist individually or in any combination. For instance, various features discussed below in relation to any of the illustrated embodiments may be incorporated into any of the above-described aspects, alone or in any combination.
  • BRIEF DESCRIPTION OF THE DRAWINGS
  • FIG. 1 is a perspective of a hydrogen generating system of one suitable embodiment;
  • FIG. 2 is a perspective of a frame of the device of FIG. 1;
  • FIG. 3 is an exploded view of the frame;
  • FIG. 4 is a front view of a reservoir of the system of FIG. 1;
  • FIG. 5 is an exploded cross-section taken in the plane of line 5--5 of FIG. 4;
  • FIG. 6 is an exploded view of a housing of the system of FIG. 1;
  • FIG. 7 is a top plan view of the housing;
  • FIG. 8 is a cross-section taken in the plane of lines 8--8 of FIG. 7;
  • FIG. 9 is a bottom perspective of a lid of the housing of FIG. 1;
  • FIG. 10 is a bottom plan view of the lid of FIG. 9;
  • FIG. 11 is a front elevation of the lid;
  • FIG. 12 is a front elevation of the housing and showing a heater of the system;
  • FIG. 13 is an exploded view of an electrode plate assembly of the housing of FIG. 6;
  • FIGS. 14A-14D are perspectives of plates of the electrode plate assembly;
  • FIGS. 15A-15B are perspectives of connectors of the electrode plate assembly;
  • FIGS. 16A-16C are perspectives of a retention bracket of the electrode plate assembly;
  • FIG. 17 is a perspective of a plate assembly of a second embodiment;
  • FIG. 18 is a block diagram of a vehicle including a hydrogen generating system;
  • FIG. 19 is a block diagram of a hydrogen generating system including an example electronic controller;
  • FIGS. 20 and 21 are flow charts showing an operation of the electronic controller;
  • FIG. 22 is a flow chart showing an operation of the electronic controller dynamically adding or removing a quantity of active plates;
  • FIG. 23 is a schematic of another embodiment of an electrode plate assembly;
  • FIG. 24 is a graph showing how the electronic controller can determine which plate set is active;
  • FIG. 25 is a graph that illustrates gas production versus time;
  • FIG. 26 is a graph that illustrates temperature versus time;
  • FIG. 27 is a graph that illustrates amperage versus time;
  • FIG. 28 is a graph that illustrates efficiency versus time;
  • FIG. 29 is a graph that illustrates gas production versus temperature;
  • FIG. 30 is a perspective of a hydrogen generating system of another embodiment;
  • FIG. 31 is a front elevation of the system of FIG. 30 with a housing removed to show a plate assembly;
  • FIG. 32 is a cross-section taken in the plane of lines 33--33 of FIG. 30; and
  • FIG. 33 is a cross-section taken in the plane of lines 33--33 of FIG. 30.
  • DETAILED DESCRIPTION
  • Referring now to the drawings and particularly to FIG. 1, a fuel emission device or hydrogen generating system of one suitable embodiment is generally designated 11. The hydrogen generating system 11 generally comprises a housing 13 and a frame 15 for supporting the housing 13. In this embodiment, the hydrogen generating system 11, and in particular the housing 13 and the frame 15, are adapted for mounting on a vehicle 19 (see FIG. 18), such as a diesel tractor of a tractor-trailer combination, and operably connected to an internal combustion engine 21 (see FIG. 18). A power source of the hydrogen generating system 11 may be, for example a 12 volt or a 24 volt source, though the hydrogen generating system 11 may be adapted to multiple voltage sources. This embodiment also includes a reservoir 25 containing maintenance solution 27, as shown in FIG. 5, for facilitating continued operation of the hydrogen generating system 11. The reservoir 25 may, however, be omitted within the scope of this disclosure.
  • As shown in FIGS. 2 and 3, the frame 15 includes a floor 31 supporting the housing 13, side walls 33, and a back wall 35 (each of which are broadly referred to as “frame members”) such that the housing 13 is surrounded on three sides. In other embodiments, the back wall 35 may be omitted. Upper ends of the side walls 33 have outwardly extending flanges 37. L-shaped brackets 39 are sized to engage the flanges 37 and to secure the housing 13 on the frame 15. The frame members are suitably secured by fasteners 41 (e.g., bolts and nuts), but may be secured in other ways, and may also be made as a one-piece unitary frame.
  • The frame 15 also includes an upright panel 43 secured to the back wall 35. The upright panel 43 has side flanges 45 along both vertical edges that extend forward around the side walls 33. The side flanges 45 add strength to the upright panel 43. The frame 15 is suitably made of steel, though other materials may be used.
  • Referring to FIGS. 4-5, the reservoir 25 includes a top 51, a bottom 53, a front wall 55, a right wall 56, a left wall 57, and a back wall 58. The back wall 58 is generally flat and includes flanges 61 having holes 63 therein for receiving fasteners (not shown) therethrough. The fasteners secure the reservoir 25 to the upright panel 43 of the frame 15.
  • The reservoir 25 includes a relatively large opening 64 formed in a neck 65 at the top 51 of the reservoir 25. The opening 64 is closed by a removable cap 67 that is suitably secured to the neck 65 (e.g., releasably secured by threads, not shown). The reservoir 25 also includes an outlet port 69 extending from the bottom 53 of the reservoir 25. A suitable conduit such as a tube 71 (see FIG. 1) connects the outlet port 69 to the housing 13.
  • Referring to FIGS. 6-8, the housing 13 defines an interior chamber 75 containing an electrolyte solution 77, an electrode plate assembly 79, a gasket 81 and a lid 83. The electrode plate assembly 79 is generally received in the chamber 75, and at least partially submersed, and more suitably fully submersed in the electrolyte solution 77. The gasket 81 of this embodiment is an O-ring made of a material capable of withstanding high temperatures, such as 250° F. and is generally adapted to facilitate sealing the housing 13. The lid 83 of this embodiment is also generally rectangular and is configured to cover the chamber 75. The gasket 81 and the lid 83 are adapted to seal the housing 13.
  • Referring to FIGS. 9-11, the lid 83 includes a set of channels 87 formed in an inner surface 89 of the lid 83 for channeling gas generated within the chamber 75 to a dome portion (e.g., collector 91) of the lid 83. In this embodiment, the channels 87 are V-shaped in cross-section and an end of each of the channels 87 are adjacent to an end of the lid 83. Each of the channels 87 extend generally from the end adjacent to the lid 83 to the collector 91. An outlet 93 is disposed at an apex of the collector 91. A suitable delivery system, such as conduit 95 (see FIG. 1) connects the outlet 93 to the engine 21 of the vehicle 19 (see FIG. 18). The lid 83 has holes 96 around the periphery 97 for receiving fasteners that secure the lid 83 to the housing 13. The lid 83 has a square recess 99 for receiving a temperature sensor 101 (e.g., a thermistor) to sense the temperature of the hydrogen generating system 11. The sensor 101 may be disposed inside or outside the chamber 75, and may be disposed anywhere on the housing 13.
  • The delivery system may also include a condenser 100 disposed along the conduit 95 for inhibiting water vapor from entering the engine 21. The condenser may suitably be a bubbler-type condenser, though other types are contemplated.
  • Referring to FIGS. 6 and 12, the housing 13 has a generally rectangular opening for receiving the electrode plate assembly 79 when the lid 83 is removed. The housing 13 also has four generally upright sides 103 and a bottom 105. Ribs 106 on the sides 103 strengthen the housing 13. The housing 13 includes a flange 107 along an upper edge that mates with the lid 83. Fasteners 98 extend through the lid 83 and the flange 107 of the housing 13.
  • The housing 13 of this embodiment is of unitary, one-piece construction. The housing 13 is made of a crack and corrosion resistant material. Also, the material may be non-insulating so that thermal energy (e.g., heat) can be more easily transmitted through the housing 13. One suitable material for the housing 13 is high-density polyethylene which can be molded to form the housing 13. Other materials may be used without departing from the scope of this disclosure.
  • As shown in FIG. 12, an exterior of the bottom 105 of the housing 13 includes a central recess 109. The recess 109 spaces a portion of the housing 13 above the frame 15, and is suitably configured to accommodate a heater 110 in abutting, thermal communication with the exterior of the bottom 105 (or generally the underside) of the housing 13. The heater 110 may be any suitable type of heater, including for example a radiant heater. The heater 110 may be used to warm the housing 13 and the solution 77 therein to an operating temperature more quickly.
  • Referring to FIG. 13, the electrode plate assembly 79 generally includes electrode plates, suitable brackets 121 (e.g., retention brackets), and connection posts 141. The electrode plates in this embodiment may be generally characterized as one of a neutral plate 125N (FIG. 14A), an anode plate 125A (FIG. 14B), or a cathode plate 125C (FIG. 14C). Each electrode plate is generally rectangular and may include notches 129 along each edge. For example, as shown in FIG. 14A, the neutral plate 125N includes one notch 129 on a top edge 136, one notch 129 on each side edge 137, and two notches 129 along a bottom edge 138 to accommodate retention brackets 121. Each electrode plate may have fastener holes 131 in a periphery of each electrode plate for receiving fasteners 122 therethrough for use in securing the retention brackets 121 on the electrode plate assembly 79.
  • One or more of the electrode plates may include surface features, such as openings or holes, that are sized and shaped to increase a surface area and “active sites” of the one or more electrode plates. As shown in FIG. 14A, suitable surface features include a plurality of holes in the form of slots 133 formed in a central section of the neutral plate 125N. Other shapes of openings are contemplated within the scope of the disclosure. The slots 133 provide an increase in surface area of at least about 0.3%, and in some embodiments at least about 0.5%, when compared to a hypothetical plate of the same dimensions but without surface features. A ratio of surface area of each electrode plate having surface features as compared to the hypothetical electrode plate without such features is at least 1.03, and in some embodiments at least about 1.05.
  • In one example (further described below in the Example surface area section) each electrode plate is 0.40005×0.17780×0.00160 meters (16 gauge) and includes 200 slots 133. Each slot 133 has a radius of 0.00117 meters. This configuration results in an increase in surface area of about 0.5% (with a ratio of 1.005) when the surface area of an electrode plate includes openings as compared to the hypothetical plate without such openings. In this embodiment, the cathode plate 125C and the anode plate 124A do not include slots 133, but only holes 131 for receiving the fasteners 122 therethrough. However, other embodiments have small slots 133 in the anode plate 125A and/or the cathode plate 125C. The electrode plates may have other surface features for increasing surface area (e.g., additional surfaces, slits, holes, bumps, projections, or a rough or an abraded surface). For example, the plate 125D of FIG. 14D includes projections 134 extending outward from a surface or face of the plate 125D, and dimples or impressions 135 extending inward into the surface.
  • In one suitable plate assembly shown in FIG. 13, cathode plates 125C (first and second cathode plates) are disposed at each end of the electrode plate assembly 79 so that the plates are in spaced apart relationship. An anode plate 125A is separate from the cathode plates 125C and disposed in a center of the electrode plate assembly 79 intermediate the cathode plates in spaced apart relationship therewith. A plurality of neutral plates 125N are disposed between each cathode plate 125C and the anode plate 125A, each neutral plate in spaced relationship with the anode plate and the cathode plates.
  • The cathode plates 125C and the anode plate 125A may be swapped such that one anode plate 125A is at each end of the electrode plate assembly 79 and one cathode plate 125C is in the center of the electrode plate assembly 79. The number of neutral plates 125N may also vary. In embodiments, for example, there may be 18 neutral plates 125N, 16 neutral plates 125N, 14 neutral plates 125N, 12 neutral plates 125N, 10 neutral plates 125N, or 8 neutral plates 125N. In the latter embodiment (8 neutral plates 125N), there are a total of 11 electrode plates (8 neutral plates 125N, one anode plate 125A, and two cathode plates or end plates 125C).
  • One advantage of using more electrode plates is that using more electrode plates enables the hydrogen generating system 11 to operate at a lower temperature. For example, in embodiments where the anode plate 125A is in the center of the electrode plate assembly 79, the number of neutral plates 125N on either side of the anode plate 125A may be equal. However, other numbers and configurations of the electrode plates are contemplated.
  • Two cathode plates 125C may be electrically connected by suitable connectors, such as by a U-shaped connector 139 shown in FIG. 15A or by other suitable connector(s). A post 141 extends upward from the U-shaped connector 139. In this embodiment, the post 141 is suitably a “clench” or threaded fastener that is joined to the U-shaped connector 139 by a nut 143. The post 141 may be joined to the U-shaped connector 139 by a separate fastener, by welding, or the like. The post 141 may also be formed as one-piece with the U-shaped connector 139. Likewise, the U-shaped connector 139 is suitably joined to the cathode plates 125C by a fastener, but may be joined in other suitable ways. For example, the U-shaped connector 139 and the post 141 may also both be formed as one-piece with one or both of the cathode plates 125C.
  • An L-shaped connector 147 (FIG. 15B) has the post 141 extending upward from a main surface of the L-shaped connector 147. The L-shaped connector 147 is suitably joined to the anode plate 125A at a top edge of the anode plate 125A by threads as described above. Like the U-shaped connector 139 of FIG. 15A, the post 141 may be made as one-piece with the L-shaped connector 147 and the anode plate 125A. The posts 141 are suitably connected to the power source by wires (not shown).
  • In the embodiment shown in FIG. 13, the electrode plate assembly 79 may alternatively be referred to as a “cell.” In further embodiments, more than one electrode plate assembly 79, or cell, may be used. For example, a second electrode plate assembly, or cell, may be added to the electrode plate assembly 79, described above, and more suitably a non-conductive barrier may be disposed between each of the electrode plate assemblies.
  • Each electrode plate is made of a suitable material that is resistant to reactivity with the solution 77 or amperage applied. In one embodiment, the electrode plates are made of a 316L stainless steel. The material of an electrode plate is chosen to have an appropriate resistance. Each electrode plate should be sufficiently thick to reduce electrical resistance and to inhibit significant flexing of the electrode plates. In some embodiments, each electrode plate is between 16 gauge and 20 gauge, and in one embodiment each electrode plate is 20 gauge. Note that a resistance of a wire (and by analogy an electrode plate) is generally affected by four factors: (1) material (for example, gold and silver have relatively low resistance), (2) a thickness of the wire or the electrode plate, (3) a temperature of the wire or the electrode plate, and (4) a length of the wire (but a length of an electrode plate is not an applicable factor). The thicker an electrode plate, the more space exists for a current to flow. As an electrode plate warms up, there is more energy therein and a resistance to a current and an electron flow decreases.
  • Referring to FIGS. 16A-C, each retention bracket 121 is generally U-shaped. Each bracket 121 is generally “combed”, meaning that each bracket 121 includes a bridge 148 and a plurality of spacers 149 (or teeth) spaced apart such that one electrode plate fits between two adjacent spacers 149. Spacing between spacers 149 is uniform so that a spacing between each electrode plate is equal. In one embodiment, for example, the spacing between each electrode plate is suitably between about 2.0 mm and about 6.5 mm. Fasteners (for example, the fasteners 122) extend through the brackets 121 and through the electrode plates to secure the stack (e.g., the electrode plate assembly), together. Each bracket is suitably made of an electrically non-conductive material.
  • Referring to FIG. 17, in this embodiment, there are 12 interleaved electrode plates 151. The electrode plates 151 may be formed as described above (e.g., of low carbon stainless steel). Each electrode plate 151 is configured for an electrical connection point 153 at one end of each electrode plate 151, for a total of 12 connection points. The plates are interleaved such that connection points of adjacent plates 151 are opposite one another. A first set of electrical connections 153 are attached (e.g., by jumper wires) to connector blocks 156, with a corresponding second set of electrical connections 153 being attached to a respective wire harnesses (not shown) and connected to an electrical controller 202 (see FIG. 19). Generally, the controller 202 switches an electrical current to various combinations of electrode plate sets to develop a best use of current in the hydrogen generating system 11, such as by the method described below.
  • Generating system 11′ of another embodiment shown in FIG. 23 and FIGS. 30-32 is similar to the system 11 of FIGS. 1-12. The positioning of the electrode plates in generating system 11′ is shown schematically in FIG. 23 and described in more detail in the Example System below. In this embodiment, plate assembly 502 includes 22 electrode plates (six anode plates 510, 512, 514, 516, 518, 520, one cathode plate 508, and 15 neutral plates 524). Alternatively, the anode plates may instead be cathode plates, and the cathode plate may be an anode plate. Also, if not energized, the anode plates 510, 512, 514, 516, 518, 520 serve as neutral plates. As shown, the cathode plate 508 includes a post 509 that extends through the lid 83, and each anode plate 125A includes a similar post 511 that extends through the lid 83 at an opposite end of the lid 83.
  • The brackets 121′ of this embodiment include spacers 122′ that extend upward about 1.5 inches. The brackets 121 are sized such that there is about 0.25 inches clearance between a bottom of the electrode plates and the housing 13. The brackets 121 may also be beveled to provide clearance of the electrode plates relative to the housing 13.
  • Referring to FIG. 32, a float mechanism 124 extends from a port in the lid 83. The float mechanism 124 serves to ensure that the solution 77′ is at a level above a top of the electrode plate assembly 502. The float mechanism 124 is suitably a conventional float 126 similar to a type used in a home toilet tank. The mechanism 124 is in fluid communication with the solution 77′ in the chamber 75′ and with the reservoir 25 via tube 71′. When the level of the solution 77′ begins to fall, the float 126 pivots downward, opening a valve that allows maintenance solution (e.g., solution 27) from the reservoir 25 to enter the chamber 75′. As the level of the solution 77′ rises, the float 126 moves upward and closes the valve. Note that the reservoir 25 is suitably disposed above the housing 13′ for gravity flow of the maintenance solution to the chamber.
  • One advantage of some embodiments of this disclosure is that each electrode plate can be monitored to control an amperage level generated. As described in detail below, power can be channeled to each electrode plate as needed to increase hydrogen production for a given amperage. This can increase the generation of hydrogen and oxygen available at start-up and significantly reduce a usual warm-up period required to get the hydrogen generating system 11 to full production at optimum temperature.
  • Starter and Maintenance Solutions:
  • The housing 13 or 13′ has sufficient fluid (e.g., electrolyte solution 77) therein so that the electrode plates are submersed in the fluid. Opposite faces (both faces) of the electrode plates (any of the plates described herein) are exposed to the electrolyte solution. Also, the surface features as described herein are exposed to the solution. The fluid of one embodiment is a solution having 20-320 mL of 2.14 molar potassium hydroxide diluted to 11.353 liters. In this embodiment, the electrolyte suitably contains color and buffers.
  • In the above embodiment, 200 mL of 2.14 molar solution is added to the chamber 75 or 75′ and diluted with distilled water to a capacity of the chamber, for example 11.353 liters. A concentration of electrolyte facilitates the electrical current through the aqueous solution.
  • The reservoir 25 holds a maintenance solution (e.g., solution 27). In one embodiment, the maintenance solution includes two buffer solutions and distilled water, though it is contemplated to use only distilled water. The first buffer is alkaline, and includes boric acid (H2B4O7) and Sodium hydroxide, NaOH. The solution has a pH of about 12.7. In one embodiment, there is between 25 grams and 35 grams of boric acid and between about 9 grams and 15 grams of sodium hydroxide, in another embodiment between about 30 and 32 grams of boric acid and between 11 grams and 13 grams of sodium hydroxide, and in one embodiment about 31.4 grams of boric acid and about 12 grams of sodium hydroxide. In one embodiment, the solution is made by dissolving the boric acid and sodium hydroxide in 1 liter of distilled water. This yields 0.1 M concentrations of each species. Then 10 mL of the solution is added to 3.7843 liters of distilled water. A suitable dye, such as bromothymol blue, may then be added.
  • The second buffer solution for the maintenance solution is also alkaline and includes dipotassium phosphate (K2HPO4) and tripotassium phosphate K3PO4. The solution has a pH in a range of 10-14, or in some embodiments between 11 and 13, and in some embodiments about 12.7. In one embodiment, there is between 10 grams and 20 grams of dipotassium phosphate and between about 9 grams and 15 grams of tripotassium phosphate, in another embodiment between about 30 grams and 32 grams of dipotassium phosphate and between 11 grams and 13 grams of tripotassium phosphate, and in one embodiment about 15.8 grams of dipotassium phosphate and about 19.6 grams of tripotassium phosphate. In one embodiment, the solution is made by dissolving the dipotassium phosphate and tripotassium phosphate in 1 liter of distilled water. This yields 0.1 M concentrations of each species. Then 10 mL of the solution is added to 3.7843 liters of distilled water. A suitable dye, such as bromothymol blue, may then be added.
  • Example System:
  • Referring to FIG. 18, an exemplary block diagram of the vehicle 19 (e.g., a truck) including the hydrogen generating system 11 in communication with the engine 21 of the vehicle is shown. Note that system 11′ can be used instead. Embodiments of the disclosure enable the hydrogen generating system 11 to generate a sufficient amount hydrogen gas per minute (e.g., 6 liters of hydrogen gas per minute) at a very low temperature (e.g., 40° F.) immediately upon start-up. Further, embodiments of the present disclosure enable the hydrogen generating system to manage heat at high temperatures (e.g., 140-180° F.) while producing acceptable quantities of hydrogen gas (e.g., over 2 liters per minute).
  • Referring to FIG. 19, an exemplary block diagram of the hydrogen generating system 11 including an electronic controller 202 is shown. Embodiments of the disclosure enable the electronic controller 202 to monitor an actual amperage and an actual temperature of the hydrogen generating system 11. Further, the embodiments described herein enable the hydrogen generating system 11 to achieve increased amperage between electrode plates of a cell substantially immediately upon a start-up of the hydrogen generating system 11 by effectively omitting a quantity of electrode plates over which a voltage is applied.
  • The electronic controller 202 as described herein has one or more processors 204 or processing units, a memory area 206, and some form of computer readable media. By way of example and not limitation, computer readable media comprise computer storage media and communication media. Computer storage media include volatile and nonvolatile, removable and non-removable media implemented in any method or technology for storage of information such as computer readable instructions, data structures, program modules or other data. Communication media typically embody computer readable instructions, data structures, program modules, or other data in a modulated data signal such as a carrier wave or other transport mechanism and include any information delivery media. Combinations of any of the above are also included within the scope of computer readable media.
  • Although the processor(s) 204 is shown separate from the memory area 206, embodiments of the disclosure contemplate that the memory area 206 may be onboard the processor(s) 204 such as in some embedded systems. The processor(s) 204 executes computer-executable instructions for implementing aspects of the disclosure. For example, the processor(s) 204 is programmed with instructions such as illustrated in FIGS. 20-22. The computer-executable instructions may be organized into one or more computer-executable components or modules. Generally, program modules include, but are not limited to, routines, programs, objects, components, and data structures that perform particular tasks or implement particular abstract data types. Aspects of the present disclosure may be implemented with any number and organization of such components or modules. For example, aspects of the invention are not limited to the specific computer-executable instructions illustrated in the figures and described herein. Other embodiments of the invention may include different computer-executable instructions. Aspects of the disclosure may also be practiced in distributed computing environments where tasks are performed by remote processing devices that are linked through a communications network. The processor(s) 204 is transformed into a special purpose microprocessor by executing computer-executable instructions or by otherwise being programmed.
  • The electronic controller 202 may be in communication with a display device (not shown) separate from or physically coupled to the hydrogen generating system 11. The display device may be a capacitive touch screen display, or a non-capacitive display. User input functionality may also be provided in the display, where the display acts as a user input selection device such as in a touch screen. The display device may provide a user with information regarding the hydrogen generating system 11, such as, temperature, measured amperage, error messages, and the like.
  • In this embodiment, the hydrogen generating system 11 includes a temperature sensor (e.g., temperature sensor 101) configured to measure an actual temperature of the hydrogen generating system 11. The temperature sensor 101 may be disposed on the outside of the housing 13. Due to the thermal properties of the housing 13, a temperature drop across a wall of the housing 13 is minimal so that the sensed/measured temperature is relatively close to the temperature inside the housing 13. However, the temperature sensor 101 may alternatively be disposed inside the housing 13.
  • A time from a start-up to optimum operating temperature (e.g., about 140° F. to about 160° F.) of the hydrogen generating system 11 is a function of an amount of amperage generated by electrolysis. Therefore, as temperature increases, amperage increases, and an efficiency for producing hydrogen gas increases. An amperage sensor (not shown) may be used to measure an actual amperage of the hydrogen generating system 11. In a further embodiment, the hydrogen generating system 11 includes resistors configured to measure an actual amperage.
  • Referring next to FIG. 20, a flow chart showing an operation of the electronic controller 202 is shown. Upon a start-up of the hydrogen generating system 11, at 208 a target amperage (e.g., about 20 amps to about 30 amps) and a maximum threshold temperature (e.g., about 180° F.) is received. The target amperage and the maximum threshold temperature may be automatically set by a manufacturer and/or manually selected by a user via the display device.
  • To control amperage, the electronic controller 202 enables each electrode plate in the electrode plate assembly 79 to be individually monitored and controlled. At 210, a quantity of electrode plates less than a total quantity of the electrode plates in the electrode plate assembly 79 to apply a voltage to is selected. Choosing to apply a voltage across a selected quantity of electrode plates less than a total quantity of the electrode plates in the electrode plate assembly 79 can result in higher currents dissipating more power. This causes a faster rise in a temperature of an electrolyte between the electrode plates to which the voltage is applied (e.g., the active electrode plate set), thereby increasing production of hydrogen gas that is being produced by the active electrode plates. For example, as temperature increases, the electrolyte becomes more conductive, enabling an inclusion of additional electrode plates in the active electrode plate set and thus increasing the efficiency of hydrogen gas produced by the hydrogen generating system 11. Applying a voltage across a quantity of electrode plates less than a total quantity of electrode plates in the electrode plate assembly enables the hydrogen generating system to generate at least 2 liters of hydrogen gas per minute at a very low temperature (e.g., 40° F.) substantially immediately upon start-up. In one embodiment, only the electrode plates required to achieve the target amperage receive an applied voltage. The quantity of the plurality of electrode plates that receive the applied voltage may be based on at least one of the following: a temperature of an electrolytic solution, an amount of voltage applied, a distance between each of the plurality of electrode plates (e.g., about 3 mm), and a type and concentration of electrolytic solution used. This can increase generation of hydrogen and oxygen available at start-up and significantly reduce a warm-up period required to get the hydrogen generating system 11 to full production at optimum temperature, the process of which is described in detail below.
  • The electronic controller 202 provides a pulse of electricity at a particular voltage for a duty cycle of, for example, 4 ms (four milliseconds). The length of the duty cycle (i.e., 4 ms) is merely exemplary and is not intended to limit the scope of the present disclosure. One of ordinary skill in the art will appreciate that various lengths of time may be used, for example, 8 ms, 12 ms, and 14 ms may be used. A duty cycle may be limited by applying the pulse for a fraction of the duty cycle. For example, with a duty cycle of 4 ms, a pulse may be applied for only 3 ms of the 4 ms duty cycle, 2 ms of the 4 ms duty cycle, or even 1 ms of the 4 ms duty cycle. In further embodiments, the pulse applied during the 4 ms duty cycle can be divided even further, for example, to 1/16 or 1/32 of the 4 ms duty cycle.
  • After a voltage is applied to the selected quantity of plates, at 212, an actual amperage and an actual temperature of the hydrogen generating system 11 are measured. To compensate for an increased temperature as the process of electrolysis occurs, the electronic controller 202 can effectively lower the voltage applied to the selected number of the plurality of plates (e.g., by decreasing the time a pulse is applied in the duty cycle) to maintain the amperage at a desired level during operation. For example, at 214, the electronic controller 202 is configured to compare the actual amperage to an amperage threshold (e.g., 25 amps), compare the actual temperature to a maximum threshold temperature (e.g., 160° F.), and at 216, adjust at least one of a duty cycle and/or the applied voltage based on the comparisons in order to regulate the actual temperature and the actual amperage. For example, if it is determined that an actual amperage exceeds a maximum amperage threshold (e.g., 30 amps) and/or the actual temperature is greater than the optimal temperature, the duty cycle may be adjusted to enable an average of an actual amperage to substantially equal the target amperage. In contrast, if it is determined that the actual amperage is equal to or less than the maximum amperage threshold, and the actual temperature is less than or equal to the optimal temperature, at 218, the duty cycle may be increased. For example, a maximum voltage may be applied to the selected quantity of plates for at least one duty cycle. Next, the actual amperage and the actual temperature of the hydrogen generating system are measured again, and the process is repeated.
  • Referring next to FIG. 21, an additional flow chart showing an operation of the electronic controller 202 is shown. At 302, upon an initialization of the processor(s) 204 and other hardware associated with the hydrogen generating system 11, a target amperage (e.g., about 20 amps and about 30 amps), an optimal temperature (e.g., about 160° F.), and a maximum threshold temperature (e.g., 180° F.) are determined/received at 304. In one embodiment, the optimal temperature is a range of temperatures, for example, the optimal temperature may be a temperature between 140° F. and 160° F. After the target amperage, the optimal temperature, and the maximum threshold temperature are determined/received, a voltage is applied to at least some (e.g., a selected quantity) of the plurality of plates in the hydrogen generating system.
  • Using the amperage sensor (not shown) and the temperature sensor 101, at 306, an actual amperage and an actual temperature of the hydrogen generating system 11 are determined/obtained, and thereafter, compared to the target amperage and the optimal temperature, respectively. At 308, if the actual amperage is below the maximum amperage threshold (e.g., an amperage that does not overburden a battery of the vehicle 19), and if the actual temperature is below the optimal temperature, at 310, full voltage is applied for at least one duty cycle.
  • At 312, if the actual amperage exceeds the maximum amperage threshold, i.e., the current reaches a level where components may be damaged, and if the actual temperature is below the optimal temperature, at 314, a duty cycle is computed resulting in an increased temperature. As one example, the maximum amperage threshold may be 50 amps. However, at 316, if the actual temperature equals the optimal temperature, at 318, a duty cycle is computed and a rated amount of hydrogen gas is produced.
  • If however, at 316, the actual temperature exceeds the optimal temperature, at 320, a duty cycle is reduced to maintain the temperature. After the duty cycle is reduced, the actual amperage is compared to the maximum safe amperage. If, at 322, the actual amperage is less than or equal to a maximum safe amperage threshold, the actual temperature is compared to the maximum threshold temperature. At 328, if the actual temperature exceeds the maximum temperature threshold, at 330, a current of the hydrogen generating system 11 is turned off, an actual temperature (e.g., a second actual temperature) is measured, and the current of the hydrogen generating system 11 is turned on when it is determined that the second actual temperature is below the maximum temperature threshold.
  • If however, at 322, after the duty cycle has been reduced and the actual amperage exceeds a maximum safe amperage threshold (to prevent damage to the system), at 324, the current of the hydrogen generating system 11 is turned off for a predefined period of time (e.g., three minutes). At 326, after the predefined period of time, the current is turned back on. Thereafter, an actual amperage (e.g., a second actual amperage) is determined and compared to the maximum safe amperage, and the process is repeated.
  • In addition to the above advantages, using interchangeable electrode plates as anodes and cathodes also maximizes gas production by optimizing the quantity of energized (e.g., active) electrode plates based on a target amperage. As more electrode plates are energized, the quantity of electrolyte to electrode plate transitions is increased which increases the gas production per amp.
  • A transition occurs where electricity passes from the liquid electrolyte to the metal of an electrode plate (the electrolyte/plate interface). Hydrogen gas is formed at this electrolyte/plate interface. Hence, if an electric current makes the same amount of hydrogen gas for each transition from liquid to metal, the more times a current is forced to make the transition, the more hydrogen gas is produced per amp and the more efficient the hydrogen generating system becomes.
  • For example, when anodes 514 and 516 in the embodiment shown in FIG. 23 are energized, the electrolyte increases in temperature, becomes more conductive, and the current increases. When the current reaches 30 amps, anodes 512 and 516 are energized. The current now drops because the additional transitions limit the current. This process continues as anodes 512 and 518, then anodes 510 and 518, and then anodes 510 and 520 are sequentially energized. After anodes 510 and 520 have been energized, individual anodes are energized, starting with anode 514 followed in turn by anode 516, anode 512, anode 518, anode 510, and finally anode 520. In practice, it is not necessary to perform all the steps just described. Some steps may not be reached while others may be skipped. As further described below, any single anode, as opposed to multiple anodes, may be selected to be energized based, for example, on amperage and/or temperature. The electrolyte concentration is set to allow sufficient current to flow at the largest plate set contemplated to produce the desired gas. As explained above, when an amperage threshold is detected, additional plates may be energized to enable the hydrogen generating system 11 operate at optimal production. The conversion to an optimal operating electrode plate configuration is a factor in the increased efficiency of the electrolysis process.
  • Further, as a temperature of an aqueous solution increases, an amperage of the hydrogen generating system 11 also increases. Therefore, with 200 mL of electrolytic solution using multiple anodes and cathodes, an actual amperage may become excessive. The methods of controlling and/or limiting the actual amperage while allowing a use of multiple anodes and cathodes described above enable a use of the multiple anodes and cathodes to provide constant amperage from a start-up of the electrolytic generating system 11 until it is turned off.
  • Although described in connection with an exemplary computing system environment, embodiments of the disclosure are operational with numerous other general purpose or special purpose computing system environments or configurations. Examples of well known computing systems, environments, and/or configurations that may be suitable for use with aspects of the disclosure include, but are not limited to, mobile computing devices, personal computers, server computers, hand-held or laptop devices, multiprocessor systems, microprocessor-based systems, programmable consumer electronics, mobile telephones, network PCs, minicomputers, mainframe computers, distributed computing environments that include any of the above systems or devices, and the like.
  • A method for dynamically adding or removing a quantity of active electrode plates based on actual amperage will now be described with reference to FIGS. 22-28.
  • FIG. 22 is a flow chart showing an operation of the electronic controller 202 dynamically adding or removing a quantity of active electrode plates from an electrode plate assembly (e.g., electrode plate assembly 502 in FIG. 23) based on at least one of an actual amperage and an actual temperature.
  • At 402, upon receiving a minimum amperage threshold, a maximum amperage threshold, a maximum temperature threshold, and an actual temperature (e.g., first actual temperature of the hydrogen generating system 11), at 404, the electronic controller 202 selects a first plurality of plates (e.g., an initial plurality of plates) from the electrode plate assembly 502. The selection of the first plurality of plates is based on at least one of the following: the minimum amperage threshold, the maximum amperage threshold, and the first actual temperature of a hydrogen generating system. The first actual temperature may be the temperature of the hydrogen generating system 11 upon start-up. After the first plurality of plates is selected, at 406, a voltage is applied to the first plurality of plates.
  • After the voltage is applied to the first plurality of plates, at 408, an actual amperage (e.g., a first actual amperage) and an actual temperature (e.g., a second actual temperature) of the hydrogen generating system 11 is determined. At 410, the first actual amperage is compared to the minimum amperage threshold and the maximum amperage threshold. At 412, if it is determined, based on the comparison, that the first actual amperage is between the minimum amperage threshold and the maximum amperage threshold, at 414, a voltage is again applied to the first plurality of electrode plates. If however, at 412, it is determined that the first actual amperage is not between the minimum amperage threshold and the maximum amperage threshold, and, at 416, the first actual amperage is greater than or equal to the maximum amperage threshold, at 418, a second plurality of electrode plates is selected from the electrode plate assembly 502 whereafter a voltage is applied to the second plurality of electrode plates.
  • If however, at 412, it is determined that the first actual amperage is not between the minimum amperage threshold and the maximum amperage threshold, and, at 416, the first actual amperage is not greater than or equal to the maximum amperage threshold, at 420, it is determined if the first actual amperage is less than or equal to the minimum amperage threshold. If, at 420, the first actual amperage is less than or equal to the minimum amperage threshold, the second plurality of plates selected includes more plates than the first plurality of plates. However, if the second actual amperage is equal to the minimum amperage threshold or if the second actual amperage is below the minimum amperage threshold, at 422, a second plurality of electrode plates that includes fewer plates than the first plurality of plates is selected from the electrode plate assembly 502.
  • FIG. 23 is a further example of an electrode plate assembly (e.g., the electrode plate assembly 502 described above). The electrode plate assembly 502 can be used in place of the assembly shown above in FIGS. 6-8 in a housing, such as housing 13′, sized accordingly.
  • The electrode plate assembly 502 includes two cells (e.g., cell 504 and cell 506) that share a common cathode 506. The present disclosure enables the cells 504 and 506 to operate (or run) in parallel to achieve a sufficient amount of hydrogen gas production (e.g., about 2 liters of hydrogen gas per minute) at low temperatures (e.g., about 40° F.). The cell 504 includes 11 electrode plates, three of which are anodes (e.g., anode 510, anode 512, and anode 514) and one of which is the cathode 508. The cell 506 includes 12 electrode plates, three of which are anodes (e.g., anode 516, anode 518, and anode 520) and one of which is the cathode 508. By providing two cells that are asymmetrical (cell 504 including 11 electrode plates, and the cell 506 including 12 electrode plates), increased control and increased resolution is obtained. That is, with the cells operating in parallel, the electronic controller 202 is able to increase and decrease a quantity of active electrode plates in smaller amounts, described below.
  • In this embodiment, a distance between each electrode plate in the electrode plate assembly 502 is suitably about 3 mm, and a thickness of each electrode plate is suitably about 20 gauge. One of ordinary skill in the art will appreciate that a quantity of electrode plates, a distance between each electrode plate, and a thickness of each electrode plate are merely exemplary and are not intended to limit the scope of the present disclosure.
  • The electrode plate assembly 502 is configured to have a voltage applied to a quantity of electrode plates less than the total quantity of electrode plates in each cell 504 and 506. To achieve this, the total quantity of electrode plates (e.g., 22 plates with the cells 504 and 506 operating in parallel) are separated into electrode plate sets (e.g., electrode plate set 1, electrode plate set 2, electrode plate set 3, electrode plate set 4, and electrode plate set 5). Each electrode plate set has a different quantity of electrode plates. In this embodiment, a quantity of electrode plates in each electrode plate set increases from electrode plate set 1 to electrode plate set 5. For example, electrode plate set 1 includes 14 electrode plates, electrode plate set 2 includes electrode 16 plates, electrode plate set 3 includes 18 electrode plates, electrode plate set 4 includes 20 electrode plates, and electrode plate set 5 includes 22 electrode plates. Each of the electrode plate sets are defined by anode plates at opposing ends of each electrode plate set. For example, electrode plate set 1 has anode 514 and anode 516 at opposing ends, electrode plate set 2 has anode 512 and anode 516 at opposing ends, electrode plate set 3 has anode 512 and anode 518 at opposing ends, electrode plate set 4 has anode 510 and anode 518 at opposing ends, and electrode plate set 5 has anode 510 and anode 520 at opposing ends.
  • FIG. 24 is a graph that includes data that further illustrates how the electronic controller 202 determines which electrode plate set is active (e.g., which electrode plate set receives a voltage). In this embodiment, the determination is based on a target amperage, and more specifically, a target amperage range bound by a minimum amperage threshold and maximum amperage threshold. In this example, the minimum amperage threshold is 20 amps and the maximum amperage threshold is 30 amps. The minimum amperage threshold and the maximum amperage threshold may be automatically set and/or manually selected by a user via the display device. Furthermore, the minimum amperage threshold of 20 amps and the maximum amperage threshold of 30 amps are merely exemplary are not intended to limit the scope of the present disclosure.
  • Generally speaking, at any given temperature, amperage decreases as a quantity of active electrode plates increase. In addition, at any given quantity of active electrode plates, amperage increases as temperature increases. Based on this understanding, at a given temperature, applying a voltage to an electrode plate set with a lesser quantity of electrode plates will return a higher amperage compared to applying a voltage to an electrode plate set with a greater quantity of electrode plates at the same temperature. Therefore, when a voltage is applied to a particular electrode plate set and an actual amperage reaches the maximum amperage threshold, the electronic controller 202 activates an electrode plate set that has a greater quantity of electrode plates than the presently active electrode plate set, thereby decreasing the amperage. In contrast, when a voltage is applied to a particular electrode plate set, and an actual amperage reaches the minimum amperage threshold, the electronic controller 202 activates an electrode plate set that has a lesser quantity of electrode plates than the presently active electrode plate set, thereby increasing the amperage.
  • Thus, at a given temperature, applying a voltage to an electrode plate set that includes the least quantity of electrode plates (e.g., plate set 1 if the cells 504 and 506 are operating in parallel) returns the highest amperage. Therefore, in the example shown in FIG. 24, because the temperature of the hydrogen generating system 11 is only at 60° F., the electronic controller 202 initially activates electrode plate set 1, which returns an actual amperage of 34.8 amps. However, 34.8 amps is above the maximum amperage threshold of 30 amps. Therefore, the electronic controller 202 increases a quantity of active electrode plates by activating electrode plate set 2. Activating electrode plate set 2 returns an actual amperage of 30.5 amps. However, 30.5 amps is still above the maximum amperage threshold of 30 amps. Therefore, the electronic controller 202 increases a quantity of active electrode plates by activating electrode plate set 3. Activating electrode plate set 3 returns an actual amperage of 28 amps.
  • As shown in FIG. 24, the temperature of the hydrogen generating system increases with time. As mentioned above, as the temperature of the hydrogen generating system 11 increases, amperage increases. Therefore, while the electrode plate set 3 initially returns an actual amperage of 28 amps, as time elapses, the temperature of the hydrogen generating system 11 increases from 69° F. to 78° F. However, once the temperature of the hydrogen generating system 11 reaches 78° F., the electrode plate set 3 returns an actual amperage of 30.30 amps, which is above the maximum amperage threshold of 30 amps. Therefore, the electronic controller 202 increases a quantity of active electrode plates by activating electrode plate set 4, and at 78° F., the electrode plate set 4 returns an actual amperage of 23.7 amps. Once the temperature of the hydrogen generating system 11 reaches 118° F., the electrode plate set 4 returns an actual amperage of 31.50 amps, which is above the maximum amperage threshold of 30 amps. Therefore, the electronic controller 202 increases a quantity of active electrode plates by activating electrode plate set 5, and at 118° F., the electrode plate set 5 returns an actual amperage of 26.2 amps.
  • As mentioned above, using two cells (e.g., cells 504 and 506) that are asymmetrical increases control and resolution. For example, once the hydrogen generating system 11 reaches an optimal temperature, the electronic controller 202 may stop operating each of the cells 504 and 506 in parallel. In this embodiment, operating only one cell, three electrode plate sets are left available:
      • (1) electrode plate set 6, which is in the cell 506, and includes all of the electrode plates from anode 518 to the cathode 508, totaling 10 electrode plates;
      • (2) electrode plate set 7, which is in the cell 504, and includes all of the electrode plates from anode 510 to the cathode 508, totaling 11 electrode plates; and
      • (3) electrode plate set 8, which is in the cell 506 and includes all of the electrode plates from anode 520 to the cathode 508, totaling 12 electrode plates.
  • Thus, because the cell 506 has one more electrode plate than the cell 504 (making the two cells asymmetrical), electrode plate sets 6, 7, and 8 increase in total electrode plates by only 1 electrode plate, increasing the control and resolution.
  • In addition to adding and removing a quantity of active electrode plates to maintain an amperage between a minimum amperage threshold and maximum amperage threshold, if a temperature of the hydrogen generating system 11 exceeds a maximum temperature threshold, the electronic controller 202 may also adjust the duty cycle.
  • FIG. 25 is a graph that illustrates gas production versus time. The graph represents the results achieved by implementing what is shown in FIG. 22, where the electronic controller 202 dynamically added/removed a quantity of electrode plates and/or at least one of the applied voltage and a duty cycle based on amperage and temperature. As shown in the graph, about 2.8 liters of hydrogen gas are produced per minute upon initial start-up. The last two points on the graph (points 602 and 604) represent where a current was limited in order to prevent an increase in temperature.
  • FIG. 26 is a graph that illustrates temperature versus time. As expected, the temperature rises faster in the beginning when fewer electrode plates are active, and as more electrode plates are added, the rate of increase in the temperature is reduced.
  • FIG. 27 is a graph that illustrates current/amperage versus time. As shown in the graph, the actual amperage decreases with time because, as time elapses, temperature increases and a quantity of active electrode plates operated is increased to decrease the amperage (see FIG. 22). Further, power dissipated is equal to a voltage applied across a cell multiplied by the amps passing through the cell. As amperage drops at higher temperatures, the power flowing to the hydrogen generating system 11 drops and a rate of temperature rise slows down.
  • FIG. 28 is a graph that illustrates efficiency versus time, where efficiency is an amount of hydrogen gas produced per amperage of electricity. As shown in the graph, efficiency generally improves as temperature increases and the quantity of active electrode plates increases.
  • With reference back to FIG. 27, as shown in the graph, the actual amperage decreases with time. The efficiency achieved in each plate set is as follows: electrode plate set 1 (0.083), electrode plate set 2 (0.092), electrode plate set 3 (0.094), electrode plate set 4 (0.104), and electrode plate set 5 (0.110). As shown here, increasing a quantity of active electrode plates between an anode and a cathode increases efficiency.
  • FIG. 29 is a graph that illustrates gas production versus temperature. As shown in the graph, about 2.7 liters of gas per minute is achievable at 60° F. These numbers are merely exemplary and are not intended to limit the scope of the present disclosure. For example, further tests have shown that 2 liters of hydrogen gas per minute can be achieved at only 40° F., without going over 30 amps.
  • Operating Environment
  • In one embodiment shown in FIG. 18, the hydrogen generating system 11 is mounted in the vehicle 19, such as a truck, and is mounted outside the engine 21, for example, behind a cab of the truck. Other mounting arrangements are contemplated.
  • In this embodiment, the hydrogen output from the hydrogen generating system 11 is directed to the engine 21 of the truck. The hydrogen gas is a supplement to the conventional fuel of such an engine (e.g., a petroleum-based fuel or “fossil fuel” such as unleaded gasoline, diesel, natural gas or propane). The hydrogen gas can improve fuel efficiency of the engine 21. The hydrogen gas may enable the engine 21 to meet stringent emission standards while also increasing fuel economy and/or power output.
  • Example Surface Area Increase Due to Holes in the Plate Plate Parameters
      • Hole radius=0.00117 meters
      • Length of plate=0.40005 meters
      • Width of plate=0.17780 meters
      • Thickness of plate=16 gauge=0.00160 meters
      • Number of holes=200
        Surface Area of Plate with no Holes
      • Top & Bottom
      • 0.40005 meters×0.17780 meters=2.80035 meters2 (L×W) 2.80035×2=5.6007 meters2 (top and bottom)
      • Sides
      • 0.00160 meters×0.17780 meters×2=0.02235 meters2 (short sides)
      • 0.00160 meters×0.40005 meters×2=0.05029 meters2 (long sides)
    Total Surface Area of Plate
      • 5.6007 meters2+0.02235 meters2+0.05029 meters2=5.67258 meters2
        Surface Area Removed from Holes Being Added
      • 200×pi×r2×2=200×0.07976×0.00117×0.00117×2 =0.06756 int
        Surface Area Gained from Cylinders Being Formed at Each Hole Made
      • 200{(2×pi×r×r)+(2×pi×r×h)−(2×pi×r×r)} Note accounts for the top/bottom circles removed.
      • 200{(2×0.07976 meters×0.00117 meters×0.00117 meters)+(2×0.07976 meters×0.00117 meters×0.00160 meters)−(2×0.07976 meters×0.00117 meters×0.00117 meters)}=200×(2×0.07976 meters×0.00117 meters×0.00160 meters)=0.09446 meters2
        Surface Area of Plates with Holes
      • Surface Area of Plates with Holes={Surface area of Solid Plate−Surface area of plate removed to form holes +Surface Area Gained from Formation of Cylinders where holes are made}
      • Surface Area of Plates with Holes=(5.67258 meters2−0.06756 meters2+0.09627 meters2)=5.69620 meters2
        Ratio of Surface Area of Plates with Holes vs. Solid Plate—16 Gauge
      • Plate with Holes/Solid Plate=5.69620/5.67258=0.02553 or 0.51% more surface area
  • When introducing elements of the present invention or the embodiment(s) thereof, the articles “a”, “an”, “the” and “said” are intended to mean that there are one or more of the elements. The terms “comprising”, “including” and “having” are intended to be inclusive and mean that there may be additional elements other than the listed elements.
  • As various changes could be made in the above constructions without departing from the scope of the invention, it is intended that all matter contained in the above description and shown in the accompanying drawing[s] shall be interpreted as illustrative and not in a limiting sense.

Claims (30)

1. A method of dynamically adding or removing a quantity of active plates in a plate assembly of a hydrogen generating system, the plate assembly comprising a plurality of plates, the method comprising:
receiving a minimum amperage threshold, a maximum amperage threshold, a maximum temperature threshold, a first actual amperage, and a first actual temperature of a hydrogen generating system;
selecting a first plurality of plates from the plate assembly, wherein the selection is based on at least one of the following: the minimum amperage threshold, the maximum amperage threshold, the first actual amperage, and the first actual temperature; and
applying a first voltage to the first plurality of plates.
2. The method of claim 1, further comprising:
determining a second actual amperage and a second actual temperature after applying the first voltage to the first plurality of plates;
comparing the second actual amperage to the minimum amperage threshold and the maximum amperage threshold;
applying a second voltage to the first plurality of plates if the first actual amperage is between the minimum amperage threshold and the maximum amperage threshold;
selecting a second plurality of plates from the plate assembly if the first actual amperage is not between the minimum amperage threshold and the maximum amperage threshold; and
applying the second voltage to the second plurality of plates if the first actual amperage is not between the minimum amperage threshold and the maximum amperage threshold.
3. The method of claim 2 wherein the second plurality of plates includes more plates than the first plurality of plates if the second actual amperage is equal to or exceeds the maximum amperage threshold.
4. The method of claim 2 wherein the second plurality of plates includes fewer plates than the first plurality of plates if the second actual amperage is equal to or below the minimum amperage threshold.
5. The method of claim 2 further comprising comparing the second actual temperature to the maximum temperature threshold.
6. The method of claim 5 wherein the second voltage is the same as the first voltage if the second actual temperature is below the maximum temperature threshold.
7. The method of claim 5 wherein the second voltage is lower than the first voltage if the second actual temperature is equal to or exceeds the maximum temperature threshold.
8. The method of claim 1 wherein the plate assembly comprises a first fuel cell and a second fuel cell.
9. The method of claim 8 wherein the first fuel cell and the second fuel cell share a common cathode.
10. The method of claim 8 wherein the first fuel cell and the second fuel cell share a common anode.
11. The method of claim 8 wherein each of the first fuel cell and the second fuel cell comprises one or more plates, and wherein at least one of the one or more plates is configured to be an anode, and at least one or more of the other plates is configured to be a cathode.
12. The method of claim 8 wherein the first fuel cell has fewer plates than the second fuel cell.
13. The method of claim 8 further comprising operating each of the first fuel cell and the second fuel cell in parallel.
14. The method of claim 8 wherein at least one plate in the first plurality of plates is in the first fuel cell and wherein at least one plate in the first plurality of plates is in the second fuel cell.
15. The method of claim 14 wherein the at least one plate in the first fuel cell is an anode plate and wherein the at least one plate in the second fuel cell is an anode plate.
16. A computer readable medium having instructions recorded thereon that when executed by a processor cause the processor to:
receive a minimum amperage threshold, a maximum amperage threshold, a maximum temperature threshold, a first actual amperage, and a first actual temperature of a hydrogen generating system;
select a first plurality of plates from a plate assembly, wherein the selection is based on at least one of the following: the minimum amperage threshold, the maximum amperage threshold, the first actual amperage, and the first actual temperature; and
apply a first voltage to the first plurality of plates.
17. The computer readable media of claim 16 further comprising instructions recorded thereon that when executed by a processor cause the processor to:
determine a second actual amperage and a second actual temperature after applying the first voltage to the first plurality of plates;
compare the second actual amperage to the minimum amperage threshold and the maximum amperage threshold;
apply a second voltage to the first plurality of plates if the first actual amperage is between the minimum amperage threshold and the maximum amperage threshold;
select a second plurality of plates from the plate assembly if the first actual amperage is not between the minimum amperage threshold and the maximum amperage threshold; and
apply the second voltage to the second plurality of plates if the first actual amperage is not between the minimum amperage threshold and the maximum amperage threshold.
18. The computer readable media of claim 17 wherein the second plurality of plates includes more plates than the first plurality of plates if the second actual amperage is equal to or exceeds the maximum amperage threshold.
19. The computer readable media of claim 17 wherein the second plurality of plates includes fewer plates than the first plurality of plates if the second actual amperage is equal to or below the minimum amperage threshold.
20. The computer readable media of claim 17 further comprising instructions recorded thereon that when executed by a processor cause the processor to compare the second actual temperature to the maximum temperature threshold.
21. The computer readable media of claim 20 wherein the second voltage is the same as the first voltage if the second actual temperature is below the maximum temperature threshold.
22. The computer readable media of claim 20 wherein the second voltage is lower than the first voltage if the second actual temperature is equal to or exceeds the maximum temperature threshold.
23. The computer readable media of claim 16 wherein the plate assembly comprises a first fuel cell and a second fuel cell.
24. The computer readable media of claim 23 wherein the first fuel cell and the second fuel cell share a common cathode.
25. The computer readable media of claim 23 wherein the first fuel cell and the second fuel cell share a common anode.
26. The computer readable media of claim 23 wherein each of the first fuel cell and the second fuel cell comprises one or more plates, and wherein at least one of the one or more plates is configured to be an anode, and at least one or more of the other plates is configured to be a cathode.
27. The computer readable media of claim 23 wherein the first fuel cell has fewer plates than the second fuel cell.
28. The computer readable media of claim 23 further comprising instructions recorded thereon that when executed by a processor cause the processor to operate each of the first fuel cell and the second fuel cell in parallel.
29. The computer readable media of claim 23 wherein at least one plate in the first plurality of plates is in the first fuel cell and wherein at least one plate in the first plurality of plates is in the second fuel cell.
30. The computer readable media of claim 29 wherein the at least one plate in the first fuel cell is an anode plate and wherein the at least one plate in the second fuel cell is an anode plate.
US12/611,727 2008-11-17 2009-11-03 Electrolytic hydrogen generating system Abandoned US20100276296A1 (en)

Priority Applications (4)

Application Number Priority Date Filing Date Title
US12/611,727 US20100276296A1 (en) 2008-11-17 2009-11-03 Electrolytic hydrogen generating system
PCT/US2009/064119 WO2010056799A2 (en) 2008-11-17 2009-11-12 Electrolytic hydrogen generating system
CN2009801545559A CN102282346A (en) 2008-11-17 2009-11-12 Electrolytic hydrogen generating system
ARP090104448A AR074659A1 (en) 2008-11-17 2009-11-17 HYDROGEN GENERATOR ELECTROLYTIC SYSTEM

Applications Claiming Priority (3)

Application Number Priority Date Filing Date Title
US11546308P 2008-11-17 2008-11-17
US11748108P 2008-11-24 2008-11-24
US12/611,727 US20100276296A1 (en) 2008-11-17 2009-11-03 Electrolytic hydrogen generating system

Publications (1)

Publication Number Publication Date
US20100276296A1 true US20100276296A1 (en) 2010-11-04

Family

ID=43029592

Family Applications (4)

Application Number Title Priority Date Filing Date
US12/611,727 Abandoned US20100276296A1 (en) 2008-11-17 2009-11-03 Electrolytic hydrogen generating system
US12/611,661 Abandoned US20100276279A1 (en) 2008-11-17 2009-11-03 Electrolytic hydrogen generating system
US12/611,722 Abandoned US20100276295A1 (en) 2008-11-17 2009-11-03 Electrolytic hydrogen generating system
US12/611,689 Abandoned US20100314259A1 (en) 2008-11-17 2009-11-03 Electrolytic hydrogen generating system

Family Applications After (3)

Application Number Title Priority Date Filing Date
US12/611,661 Abandoned US20100276279A1 (en) 2008-11-17 2009-11-03 Electrolytic hydrogen generating system
US12/611,722 Abandoned US20100276295A1 (en) 2008-11-17 2009-11-03 Electrolytic hydrogen generating system
US12/611,689 Abandoned US20100314259A1 (en) 2008-11-17 2009-11-03 Electrolytic hydrogen generating system

Country Status (3)

Country Link
US (4) US20100276296A1 (en)
CN (1) CN102282346A (en)
AR (1) AR074659A1 (en)

Cited By (2)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US10975479B2 (en) * 2018-03-08 2021-04-13 Ugsi Solutions, Inc. Electrolytic cells and water treatment systems containing the same
US11795557B2 (en) * 2019-09-17 2023-10-24 Kabushiki Kaisha Toshiba Electrochemical reaction device

Families Citing this family (21)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US8449737B2 (en) * 2008-09-13 2013-05-28 David Thomas Richardson Hydrogen and oxygen generator having semi-isolated series cell construction
US20110005939A1 (en) * 2009-07-09 2011-01-13 Haylin Hydrogen Systems, Llc Generation of high octane hydrogen gas from acetic acid
JP5378439B2 (en) * 2011-04-05 2013-12-25 本田技研工業株式会社 Water electrolysis system and operation method thereof
US8613273B2 (en) 2011-06-08 2013-12-24 Royce Walker & Co., Ltd Fuel conditioning modules and methods
US9518330B2 (en) * 2011-10-21 2016-12-13 Global Hydrogen Technologies, Inc. Electrolyzing cell for generating hydrogen and oxygen and method of use
US20120111734A1 (en) * 2012-01-19 2012-05-10 Edward Kramer Water Electrolyzer System and Method
TW201332656A (en) * 2012-02-14 2013-08-16 Epoch Energy Technology Corp Health oxy-hydrogen gas supply facility
KR20190132563A (en) 2012-02-27 2019-11-27 디이이씨 아이엔씨 Oxygen-rich plasma generators for boosting internal combustion engines
CN102828196A (en) * 2012-08-31 2012-12-19 苏州竞立制氢设备有限公司 Water electrolysis hydrogen production plastic electrode frame electrode plate capable of measuring electrolytic voltage and production method
US9051872B2 (en) 2013-02-01 2015-06-09 Serge V. Monros Hydrogen on-demand fuel system for internal combustion engines
CA2888649C (en) * 2013-02-01 2017-08-22 Serge V. Monros Hydrogen on-demand fuel system for internal combustion engines
US10113241B2 (en) * 2014-02-04 2018-10-30 Jeffrey Allen Kaiser Control board for controlling channel sequencing of positive and negative DC voltage and current
BG111782A (en) * 2014-06-27 2016-01-29 "Хидродженика Корпорейшън" Оод OXIDIZED GENERATOR AND METHOD FOR OBTAINING OXYGEN GAS
KR101663460B1 (en) * 2015-04-13 2016-10-07 주식회사 스마트파워 Hydrogen and oxygen generator
CN204999979U (en) * 2015-08-05 2016-01-27 林信涌 An electrolysis apparatus
EP3426900A4 (en) 2016-03-07 2019-12-11 Hytech Power, Inc. A method of generating and distributing a second fuel for an internal combustion engine
US20190234348A1 (en) 2018-01-29 2019-08-01 Hytech Power, Llc Ultra Low HHO Injection
IT201800002441A1 (en) 2018-02-06 2019-08-06 Diego Soriano ELECTROLYTIC CELL AND UNIVERSAL OXYDROGEN GENERATOR
CZ2019276A3 (en) * 2019-05-03 2020-07-08 H2 Solution s.r.o. Gas production reactor
US20210094850A1 (en) * 2019-09-30 2021-04-01 ionogen Inc. Bubble-Generating Electrochemical Reactors and Systems for Manufacturing a Sanitizing, a Disinfecting, and/or a Cleaning Solution
CN111005029A (en) * 2019-12-31 2020-04-14 广东省新材料研究所 Electrolytic aquatic product gas pressure self-balancing device and application thereof

Citations (46)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US321759A (en) * 1885-07-07 John scudamoee sellon
US441958A (en) * 1890-12-02 Sylvania
US1319940A (en) * 1919-10-28 Assigiffob
US1458377A (en) * 1919-11-18 1923-06-12 A A Simonds Dayton Company Storage battery
US3256504A (en) * 1961-01-11 1966-06-14 Fidelman Morris Galvanic hydrogen producer
US4054502A (en) * 1975-02-03 1977-10-18 Societe De Recherches Techniques Et Industrielles Quick start electrolysis apparatus
US4125680A (en) * 1977-08-18 1978-11-14 Exxon Research & Engineering Co. Bipolar carbon-plastic electrode structure-containing multicell electrochemical device and method of making same
US4271793A (en) * 1979-08-31 1981-06-09 Valdespino Joseph M Internal combustion engine
US4422909A (en) * 1979-12-17 1983-12-27 Occidental Chemical Corporation Electrolytic process for the manufacture of alkali metal halate
US5348817A (en) * 1993-06-02 1994-09-20 Gnb Battery Technologies Inc. Bipolar lead-acid battery
US5450822A (en) * 1994-02-01 1995-09-19 Cunningham; John E. Apparatus and method for electrolysis to enhance combustion in an internal combustion engine
US5455125A (en) * 1992-09-18 1995-10-03 Matsushita Electric Industrial Co., Ltd. Medium or large scale sealed metal oxide/metal hydride battery
US5840172A (en) * 1997-03-25 1998-11-24 Whatman Inc. Direct current hydrogen generator, system and method
US6036827A (en) * 1997-06-27 2000-03-14 Lynntech, Inc. Electrolyzer
US6265108B1 (en) * 1999-12-02 2001-07-24 Subhas Chandra Chalasani Flooded valve regulated lead-acid battery having improved life
US6306539B1 (en) * 1997-09-02 2001-10-23 Kvg Technologies, Inc. Mat of glass and other fibers in a separator of a storage battery
US6332434B1 (en) * 1998-06-29 2001-12-25 Fatpower Inc. Hydrogen generating apparatus and components therefor
US6336430B2 (en) * 1998-06-29 2002-01-08 Fatpower Inc. Hydrogen generating apparatus
US6495277B1 (en) * 1999-07-27 2002-12-17 Idatech, Llc Fuel cell system controller
US6503648B1 (en) * 2001-03-26 2003-01-07 Biomed Solutions, Llc Implantable fuel cell
US6524453B1 (en) * 1998-04-21 2003-02-25 Fatpower Inc. Electrode assembly
US6630061B2 (en) * 2000-10-24 2003-10-07 Jae-Heung Lee Apparatus for generating a mixture gas of oxygen and hydrogen
US20030205482A1 (en) * 2002-05-02 2003-11-06 Allen Larry D. Method and apparatus for generating hydrogen and oxygen
US20030235724A1 (en) * 2002-06-21 2003-12-25 Ord Jason S. Hydrogen generating apparatus
US20040040838A1 (en) * 2002-08-28 2004-03-04 Fatpower Inc. Electrolyzer
US6720101B1 (en) * 2001-06-08 2004-04-13 Palcan Fuel Cell Co. Ltd Solid cage fuel cell stack
US20040074781A1 (en) * 2002-10-22 2004-04-22 Dennis Klein Hydrogen generator for uses in a vehicle fuel system
US6733913B2 (en) * 1996-06-06 2004-05-11 Lynntech, Inc. Fuel cell system for low pressure operation
US6817320B2 (en) * 2001-01-19 2004-11-16 Fat Power Inc. Hydrogen generating apparatus and components therefor
US6835481B2 (en) * 2000-03-29 2004-12-28 Idatech, Llc Fuel cell system with load management
US6878477B2 (en) * 2001-05-15 2005-04-12 Hydrogenics Corporation Fuel cell flow field plate
US6939449B2 (en) * 2002-12-24 2005-09-06 General Atomics Water electrolyzer and system
US7156081B2 (en) * 1997-01-13 2007-01-02 Royce Walker & Co., Ltd. Fuel conditioning assembly
US20070042239A1 (en) * 2005-08-19 2007-02-22 Tatung Company Fuel cell system
US20070111089A1 (en) * 2005-08-30 2007-05-17 Railpower Technologies Corp. Electrochemical cell for hybrid electric vehicle applications
US20070112425A1 (en) * 2005-04-22 2007-05-17 Laurent Schaller Catheter-based tissue remodeling devices and methods
US20070138006A1 (en) * 2005-12-21 2007-06-21 Oakes Thomas W System and Method for Generating Hydrogen Gas
US20070151778A1 (en) * 2005-08-02 2007-07-05 Hy-Drive Technologies Ltd. Vehicle operation assembly
US20070172727A1 (en) * 2004-06-16 2007-07-26 Kazuhiro Sugie Lead storage battery
US7258779B2 (en) * 2001-11-13 2007-08-21 Alan Patrick Casey Method and means for hydrogen and oxygen generation
US7261062B2 (en) * 2005-07-15 2007-08-28 Holt Cecil G Water fuel convertor
US20080257740A1 (en) * 2004-11-02 2008-10-23 Hy-Drive Technologies Ltd. Electrolysis Cell Electrolyte Pumping System
US20080283392A1 (en) * 2006-11-19 2008-11-20 Tadeusz Karabin Hydrogen producing unit
US20100025258A1 (en) * 2006-01-27 2010-02-04 Hy-Drive Technologies Ltd. Hydrogen generating apparatus with hydrogen concentration sensors
US20100043730A1 (en) * 2006-01-30 2010-02-25 Hy-Drive Technologies Ltd. Hydrogen generating system for operation with engine turbo condition
US20100064892A1 (en) * 2006-01-30 2010-03-18 Hy-Drive Technologies Ltd. Gas/liquid separator for hydrogen generating apparatus

Family Cites Families (6)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US20040079650A1 (en) * 1998-11-23 2004-04-29 Morkovsky Paul E. Electrocoagulation reactor
US6375812B1 (en) * 2000-03-13 2002-04-23 Hamilton Sundstrand Corporation Water electrolysis system
US6890410B2 (en) * 2002-12-10 2005-05-10 John T. Sullivan Apparatus for converting a fluid into at least two gasses through electrolysis
US8221610B2 (en) * 2003-10-10 2012-07-17 Ohio University Electrochemical method for providing hydrogen using ammonia and ethanol
CA2648480C (en) * 2005-04-05 2014-01-14 Cropley Holdings Ltd. Household appliances which utilize an electrolyzer and electrolyzer that may be used therein
US8097130B2 (en) * 2006-10-18 2012-01-17 Balboa Instruments, Inc. Integrated water treatment system

Patent Citations (49)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US321759A (en) * 1885-07-07 John scudamoee sellon
US441958A (en) * 1890-12-02 Sylvania
US1319940A (en) * 1919-10-28 Assigiffob
US1458377A (en) * 1919-11-18 1923-06-12 A A Simonds Dayton Company Storage battery
US3256504A (en) * 1961-01-11 1966-06-14 Fidelman Morris Galvanic hydrogen producer
US4054502A (en) * 1975-02-03 1977-10-18 Societe De Recherches Techniques Et Industrielles Quick start electrolysis apparatus
US4125680A (en) * 1977-08-18 1978-11-14 Exxon Research & Engineering Co. Bipolar carbon-plastic electrode structure-containing multicell electrochemical device and method of making same
US4271793A (en) * 1979-08-31 1981-06-09 Valdespino Joseph M Internal combustion engine
US4422909A (en) * 1979-12-17 1983-12-27 Occidental Chemical Corporation Electrolytic process for the manufacture of alkali metal halate
US5455125A (en) * 1992-09-18 1995-10-03 Matsushita Electric Industrial Co., Ltd. Medium or large scale sealed metal oxide/metal hydride battery
US5348817A (en) * 1993-06-02 1994-09-20 Gnb Battery Technologies Inc. Bipolar lead-acid battery
US5450822A (en) * 1994-02-01 1995-09-19 Cunningham; John E. Apparatus and method for electrolysis to enhance combustion in an internal combustion engine
US6733913B2 (en) * 1996-06-06 2004-05-11 Lynntech, Inc. Fuel cell system for low pressure operation
US7156081B2 (en) * 1997-01-13 2007-01-02 Royce Walker & Co., Ltd. Fuel conditioning assembly
US5840172A (en) * 1997-03-25 1998-11-24 Whatman Inc. Direct current hydrogen generator, system and method
US6036827A (en) * 1997-06-27 2000-03-14 Lynntech, Inc. Electrolyzer
US6306539B1 (en) * 1997-09-02 2001-10-23 Kvg Technologies, Inc. Mat of glass and other fibers in a separator of a storage battery
US6524453B1 (en) * 1998-04-21 2003-02-25 Fatpower Inc. Electrode assembly
US6332434B1 (en) * 1998-06-29 2001-12-25 Fatpower Inc. Hydrogen generating apparatus and components therefor
US6336430B2 (en) * 1998-06-29 2002-01-08 Fatpower Inc. Hydrogen generating apparatus
US6495277B1 (en) * 1999-07-27 2002-12-17 Idatech, Llc Fuel cell system controller
US6265108B1 (en) * 1999-12-02 2001-07-24 Subhas Chandra Chalasani Flooded valve regulated lead-acid battery having improved life
US6835481B2 (en) * 2000-03-29 2004-12-28 Idatech, Llc Fuel cell system with load management
US6630061B2 (en) * 2000-10-24 2003-10-07 Jae-Heung Lee Apparatus for generating a mixture gas of oxygen and hydrogen
US6817320B2 (en) * 2001-01-19 2004-11-16 Fat Power Inc. Hydrogen generating apparatus and components therefor
US20050126515A1 (en) * 2001-01-19 2005-06-16 Fatpower Inc. Hydrogen generating apparatus and components therefor
US7240641B2 (en) * 2001-01-19 2007-07-10 Hy-Drive Technologies Ltd. Hydrogen generating apparatus and components therefor
US6503648B1 (en) * 2001-03-26 2003-01-07 Biomed Solutions, Llc Implantable fuel cell
US6878477B2 (en) * 2001-05-15 2005-04-12 Hydrogenics Corporation Fuel cell flow field plate
US6720101B1 (en) * 2001-06-08 2004-04-13 Palcan Fuel Cell Co. Ltd Solid cage fuel cell stack
US7258779B2 (en) * 2001-11-13 2007-08-21 Alan Patrick Casey Method and means for hydrogen and oxygen generation
US20030205482A1 (en) * 2002-05-02 2003-11-06 Allen Larry D. Method and apparatus for generating hydrogen and oxygen
US20030235724A1 (en) * 2002-06-21 2003-12-25 Ord Jason S. Hydrogen generating apparatus
US20040040838A1 (en) * 2002-08-28 2004-03-04 Fatpower Inc. Electrolyzer
US7651602B2 (en) * 2002-08-28 2010-01-26 Fatpower, Inc. Electrolyzer
US20040074781A1 (en) * 2002-10-22 2004-04-22 Dennis Klein Hydrogen generator for uses in a vehicle fuel system
US6939449B2 (en) * 2002-12-24 2005-09-06 General Atomics Water electrolyzer and system
US20070172727A1 (en) * 2004-06-16 2007-07-26 Kazuhiro Sugie Lead storage battery
US20080257740A1 (en) * 2004-11-02 2008-10-23 Hy-Drive Technologies Ltd. Electrolysis Cell Electrolyte Pumping System
US20070112425A1 (en) * 2005-04-22 2007-05-17 Laurent Schaller Catheter-based tissue remodeling devices and methods
US7261062B2 (en) * 2005-07-15 2007-08-28 Holt Cecil G Water fuel convertor
US20070151778A1 (en) * 2005-08-02 2007-07-05 Hy-Drive Technologies Ltd. Vehicle operation assembly
US20070042239A1 (en) * 2005-08-19 2007-02-22 Tatung Company Fuel cell system
US20070111089A1 (en) * 2005-08-30 2007-05-17 Railpower Technologies Corp. Electrochemical cell for hybrid electric vehicle applications
US20070138006A1 (en) * 2005-12-21 2007-06-21 Oakes Thomas W System and Method for Generating Hydrogen Gas
US20100025258A1 (en) * 2006-01-27 2010-02-04 Hy-Drive Technologies Ltd. Hydrogen generating apparatus with hydrogen concentration sensors
US20100043730A1 (en) * 2006-01-30 2010-02-25 Hy-Drive Technologies Ltd. Hydrogen generating system for operation with engine turbo condition
US20100064892A1 (en) * 2006-01-30 2010-03-18 Hy-Drive Technologies Ltd. Gas/liquid separator for hydrogen generating apparatus
US20080283392A1 (en) * 2006-11-19 2008-11-20 Tadeusz Karabin Hydrogen producing unit

Cited By (2)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US10975479B2 (en) * 2018-03-08 2021-04-13 Ugsi Solutions, Inc. Electrolytic cells and water treatment systems containing the same
US11795557B2 (en) * 2019-09-17 2023-10-24 Kabushiki Kaisha Toshiba Electrochemical reaction device

Also Published As

Publication number Publication date
US20100276295A1 (en) 2010-11-04
AR074659A1 (en) 2011-02-02
US20100276279A1 (en) 2010-11-04
CN102282346A (en) 2011-12-14
US20100314259A1 (en) 2010-12-16

Similar Documents

Publication Publication Date Title
US20100276296A1 (en) Electrolytic hydrogen generating system
US10680268B2 (en) Method and system to maintain electrolyte stability for all-iron redox flow batteries
US20170159618A1 (en) Hydrogen on Demand Electrolysis Fuel Cell System
US6770186B2 (en) Rechargeable hydrogen-fueled motor vehicle
KR101906741B1 (en) Oxyhydrogen generator and method for producing oxyhydrogen gas
US20210234184A1 (en) Cost-efficient high energy density redox flow battery
CN110301060B (en) Electrolyte for iron flow battery
AU2007279151B2 (en) Water electrolysis device
CN108475802A (en) Regenerative fuel cell
US20230361331A1 (en) Method for iron preformation in redox flow batteries
WO2010056799A2 (en) Electrolytic hydrogen generating system
Frey et al. Spatiotemporal decoupling of water electrolysis for dual-use grid energy storage and hydrogen generation
US20190020082A1 (en) Reversible electrochemical system comprising two pem devices in oxidation and reduction electrodes configuration
Luin et al. Electrolysis energy efficiency of highly concentrated FeCl2 solutions for power-to-solid energy storage technology
JPH11323584A (en) Electrolytic cell with ion exchange membrane
KR20160034535A (en) Secondary Battery
JP2014189839A (en) Electrolysis system
JP2019204644A (en) Flow battery and flow battery system
Dziekan CHARACTERIZATION AND DEVELOPMENT OF A SINGLE FLUID, PRIMARY FLOW BATTERY WITH SIMULTANEOUS HYDROGEN AND ELECTRICITY OUTPUTS
Scott et al. A study of current distribution in a DEM cell during bromate formation
KR100872427B1 (en) Fueltank turnover displayer of fuel cell and method thereof
AU2022358704A1 (en) Hybrid redox fuel cell system
WO2015104717A1 (en) Hydrogen cell
WO2024026426A1 (en) High energy density electrolyte
CN1567627A (en) Nourrice tank changing time announcement device and method for fuel cell

Legal Events

Date Code Title Description
AS Assignment

Owner name: ETORUS, INC., CALIFORNIA

Free format text: ASSIGNMENT OF ASSIGNORS INTEREST;ASSIGNORS:ARNETT, LESLIE PAUL;DEHART, SCOTT ALAN;YELIN, ROBERT E.;SIGNING DATES FROM 20091106 TO 20091111;REEL/FRAME:023765/0362

STCB Information on status: application discontinuation

Free format text: ABANDONED -- FAILURE TO RESPOND TO AN OFFICE ACTION