US20110129385A1 - Copper-zinc alloy - Google Patents

Copper-zinc alloy Download PDF

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Publication number
US20110129385A1
US20110129385A1 US12/592,522 US59252209A US2011129385A1 US 20110129385 A1 US20110129385 A1 US 20110129385A1 US 59252209 A US59252209 A US 59252209A US 2011129385 A1 US2011129385 A1 US 2011129385A1
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United States
Prior art keywords
alloy
copper
zinc
weight
corrosion resistance
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Abandoned
Application number
US12/592,522
Inventor
Tsu-Shu Yang-Tung
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Chan Wen Copper Industry Co Ltd
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Chan Wen Copper Industry Co Ltd
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
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Priority to US12/592,522 priority Critical patent/US20110129385A1/en
Assigned to CHAN WEN COPPER INDUSTRY CO., LTD. reassignment CHAN WEN COPPER INDUSTRY CO., LTD. ASSIGNMENT OF ASSIGNORS INTEREST (SEE DOCUMENT FOR DETAILS). Assignors: YANG-TUNG, TSU-SHU
Publication of US20110129385A1 publication Critical patent/US20110129385A1/en
Abandoned legal-status Critical Current

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    • CCHEMISTRY; METALLURGY
    • C22METALLURGY; FERROUS OR NON-FERROUS ALLOYS; TREATMENT OF ALLOYS OR NON-FERROUS METALS
    • C22CALLOYS
    • C22C9/00Alloys based on copper
    • C22C9/04Alloys based on copper with zinc as the next major constituent

Definitions

  • the present invention is related to the lead free Copper-Zinc alloy, which particularly focuses on decreasing the cost of lead free Copper-Zinc alloy to prevent the Copper-Zinc alloy from polluting our environment and improving mechanical ability.
  • Typical copper-zinc alloys comprise a number of materials, such as Iron (Fe), Aluminum (Al), Tin (Sn), Nickel (Ni), and unavoidable impurities for increasing the corrosion resistance, strengthen tensile, or the like.
  • U.S. Pat. No. 4,990,309 to Miyafuji et al. discloses one of the typical high strength Copper-Nickel-Tin-Zinc-Aluminum alloys containing Nickel (Ni), Tin (Sn), Aluminum (Al), Manganese (Mg), Zinc (Zn), Chromium (Cr), the balance of copper and inevitable impurities.
  • the typical high strength Copper-Nickel-Tin-Zinc-Aluminum alloy contains a large amounts of the copper up to 80% in terms of weight.
  • the copper is an expensive material that may greatly increase the cost of the alloy and that may greatly decrease or reduce the competition of the alloy.
  • U.S. Pat. No. 5,658,401 to Gaag et al. discloses another typical Copper-Zinc alloy for semi-finished products and articles which are highly loaded and subjected to extreme wear especially synchronizing rings.
  • the typical Copper-Zinc alloy comprises the Lead (Pb) which is toxic may damage worker health during producing Copper-Lead-Zinc alloy and will also release toxicity into drinking water which will damage human health and pollute our environment.
  • Pb Lead
  • U.S. Pat. No. 7,128,871 to Davitz discloses a further typical silver-colored, tarnish-resistant, corrosion-resistant alloy with low percentages of copper and zinc for jewelry items, tableware items, dental items or other items that should resist tarnishing or corrosion and which require a non-brittle alloy.
  • the typical silver-colored alloy includes a large amount or percentage of the silver up to about 92-95% in terms of weight which is an expensive material that may greatly increase the cost of the alloy and that may greatly decrease or reduce the competition of the alloy.
  • the present invention has arisen to mitigate and/or obviate the afore-described disadvantages of the conventional copper-zinc alloys.
  • the primary objective of the present invention is to provide a Copper-Zinc alloy to decrease amount of Copper material for decreasing the cost of the Copper-Zinc alloy and without any lead engaged therein for preventing the copper-zinc alloy from polluting our environment or damage human health.
  • a copper-zinc alloy comprising 56-65%, by weight, of Copper (Cu), 0.2-2.0%, by weight, of Tin (Sn) to improve the tensile strength and the corrosion resistance of Zinc (Zn), 0.1-1.0% by weight, of Aluminum (Al) to ameliorate yielding strength and the corrosion resistance of the alloy, 0.01-0.6%, by weight, of Nickel (Ni) to improve tensile strength and the corrosion resistance of Zinc (Zn) and the heat conductivity of the alloy, lower than 0.5% by weight, of Iron (Fe), and selected at least one element from Phosphorus (P) and Arsenic (As) which amounts range from 0.02-0.25% and 0.01-0.2%. Combining both materials could not be more than 0.35%, and the remaining percent, by weight, of Zinc (Zn) with inevitable impurities.
  • a Copper-Zinc alloy in accordance with the present invention primarily comprises a Copper material (Cu), which is composed of 56 to 65 percent in terms of weight that is relatively lower than that contained in the other invention related to Lead Free Copper-Zinc alloys to decrease the cost of the Lead Free Copper-Zinc alloy, Tin (Sn), which is composed of 0.2 to 2.0 percentage in terms of weight, may ameliorate the tensile strength and also strengthen the corrosion resistance of alloy.
  • Tin (Sn) when the amounts of Tin (Sn) increase, the relatively fragile or brittle material: CuZnSn will be generated and may influence the deformation of the alloy, but will improve the cutting characteristic to the alloy.
  • the amounts of Tin (Sn) when the amounts of Tin (Sn) is lower than 0.3 percentage, the cutting property of the alloy may not be improved, and when the amounts of Tin (Sn) is more than 0.8 percentage, the cutting property and the tensile strength of alloy may be improved and the characteristic of corrosion resistance may be gradually strengthened.
  • the amounts of Tin (Sn) is more than 2.0 percentage, the corrosion speed of zinc (Zn) is about 0.010 mm/Hr, the more Tin (Sn), the better the cutting property of the alloy and the better the corrosion resistance of zinc (Zn).
  • the best amounts of Tin (Sn) is 0.2-2.0 percentage in terms of weight.
  • the alloy also contains Aluminum (Al), which is 0.1-1.0 percentage, by weight, that could improve the yielding strength and the corrosion resistance of the alloy. However, it may slightly weaken the ductibility of the alloy. Too much percentage of Aluminum (Al) may decrease the stretchability of the alloy. In addition, the specific gravity of Aluminum (Al) is relatively lighter than specific gravity of the other Copper-Zinc alloy. Adding a specific amount of Aluminum (Al) may relatively decrease weight of alloy. Both Aluminum (Al) and Tin (Sn) could improve the cutting property of the alloy.
  • the alloy also may comprise Iron (Fe) which could be well mixed the particle of the alloy. However, Iron (Fe) which contain too much inside alloy may weaken the property of corrosion resistance. Therefore, alloy could not contain too much percentage of Iron (Fe) therein. And the amount of Iron (Fe) is preferably no more than 0.5%, in terms of weight.
  • the alloy may further comprise unavoidable impurities therein.
  • the alloy which comprises Nickel (Ni) which may even particle of the alloy, strengthen yielding strength, tensile strength, corrosion resistance and heat conductivity of the alloy. Besides, the microstructure which is composed of Nickel will be more uniform after heating or extruding.
  • the percentage of Nickel ranged preferably between 0.01 to 0.6 percentages, in terms of weight.
  • Zinc (Zn) which may remarkably weaken heating conductivity and electric conductivity. However, composed of Zinc could improve yielding strength.
  • contained amount of Zinc (Zn) is more than 20%, the corrosion may be occurred in humid environment or in sea, particularly when the environment contains Ammonia (NH 3 ).
  • the cutting effect of the alloy will be improved when the percentage of Zinc (Zn) is more than 33%. Too much zinc (Zn) may decrease the malleability of the alloy. More than 45% of Zinc contained in alloy will be no economic value.
  • to solve corrosion problem is to increase composition of Nickel, Aluminum and Tin instead of decreasing composition of Zinc.
  • the alloy will comprise at least one of other materials, which could be Phosphorus (P) or Arsenic (As) or both. Combining with both materials will be no more than 0.35%.
  • the alloy which is composed of Phosphorus (P) or Arsenic (As) could strengthen the corrosion resistance. The more Phosphorus (P) and Arsenic (As) are, the better corrosion resistance of the alloy is.
  • Phosphorus (P) could be used as deoxidizer and mend the flowing of melting Copper (Cu) and may improve the characteristic of welding, the corrosion resistance and the anti-softness of the alloy. However adding Phosphorus (P) will weaken the heat conductivity and the electric conductivity of the alloy. In additional, an excess of Phosphorus may generate the fragile or brittle characteristic to the alloy, such that the amount of Phosphorus (P) is preferably ranged between 0.03-0.25% in terms of weight.
  • Arsenic (As) may be suitably melted in copper (Cu), but may greatly decrease the heat conductivity and the electric conductivity of the alloy, and Arsenic (As) may strengthen the corrosion resistance of the alloy, but will weaken the electric potential of copper (Cu).
  • Such material which contains in alloy is preferably ranged between 0.01-0.2%, in terms of weight.
  • the Copper-Zinc alloy in accordance with the present invention includes a decreased amount of copper material for decreasing the cost of the Copper-Zinc alloy and including no lead engaged therein for preventing the copper-zinc alloy from polluting our environment.

Abstract

A copper-zinc alloy includes 56-65%, by weight, of Copper (Cu), 0.2-2.0%, by weight, of Tin (Sn) for improving tensile strength of Copper (Cu) and for strengthening the corrosion resistance of Zinc (Zn), 0.1-1.0%, by weight, of Aluminum (Al) for ameliorating the yielding and tensile strength and corrosion resistance of the alloy, 0.01-0.6%, by weight, of Nickel (Ni) for improving the yielding and the tensile strength and the resistance and the heat conductivity of the alloy, lower than 0.5%, by weight, of Ferrite (Fe), with the balance being Zinc (Zn) and inevitable impurities, the alloy also includes a secondary material, which is Phosphorus (p), Arsenic (As) or both for strengthening the corrosion resistance of the alloy.

Description

    BACKGROUND OF THE INVENTION
  • 1. Field of the Invention
  • The present invention is related to the lead free Copper-Zinc alloy, which particularly focuses on decreasing the cost of lead free Copper-Zinc alloy to prevent the Copper-Zinc alloy from polluting our environment and improving mechanical ability.
  • 2. Description of the Prior Art
  • Typical copper-zinc alloys comprise a number of materials, such as Iron (Fe), Aluminum (Al), Tin (Sn), Nickel (Ni), and unavoidable impurities for increasing the corrosion resistance, strengthen tensile, or the like.
  • For example, U.S. Pat. No. 4,990,309 to Miyafuji et al. discloses one of the typical high strength Copper-Nickel-Tin-Zinc-Aluminum alloys containing Nickel (Ni), Tin (Sn), Aluminum (Al), Manganese (Mg), Zinc (Zn), Chromium (Cr), the balance of copper and inevitable impurities.
  • The typical high strength Copper-Nickel-Tin-Zinc-Aluminum alloy contains a large amounts of the copper up to 80% in terms of weight. However, the copper is an expensive material that may greatly increase the cost of the alloy and that may greatly decrease or reduce the competition of the alloy.
  • U.S. Pat. No. 5,658,401 to Gaag et al. discloses another typical Copper-Zinc alloy for semi-finished products and articles which are highly loaded and subjected to extreme wear especially synchronizing rings.
  • However, the typical Copper-Zinc alloy comprises the Lead (Pb) which is toxic may damage worker health during producing Copper-Lead-Zinc alloy and will also release toxicity into drinking water which will damage human health and pollute our environment.
  • U.S. Pat. No. 7,128,871 to Davitz discloses a further typical silver-colored, tarnish-resistant, corrosion-resistant alloy with low percentages of copper and zinc for jewelry items, tableware items, dental items or other items that should resist tarnishing or corrosion and which require a non-brittle alloy.
  • However, the typical silver-colored alloy includes a large amount or percentage of the silver up to about 92-95% in terms of weight which is an expensive material that may greatly increase the cost of the alloy and that may greatly decrease or reduce the competition of the alloy.
  • The present invention has arisen to mitigate and/or obviate the afore-described disadvantages of the conventional copper-zinc alloys.
  • SUMMARY OF THE INVENTION
  • The primary objective of the present invention is to provide a Copper-Zinc alloy to decrease amount of Copper material for decreasing the cost of the Copper-Zinc alloy and without any lead engaged therein for preventing the copper-zinc alloy from polluting our environment or damage human health.
  • In accordance with one aspect of the invention, there is provided a copper-zinc alloy comprising 56-65%, by weight, of Copper (Cu), 0.2-2.0%, by weight, of Tin (Sn) to improve the tensile strength and the corrosion resistance of Zinc (Zn), 0.1-1.0% by weight, of Aluminum (Al) to ameliorate yielding strength and the corrosion resistance of the alloy, 0.01-0.6%, by weight, of Nickel (Ni) to improve tensile strength and the corrosion resistance of Zinc (Zn) and the heat conductivity of the alloy, lower than 0.5% by weight, of Iron (Fe), and selected at least one element from Phosphorus (P) and Arsenic (As) which amounts range from 0.02-0.25% and 0.01-0.2%. Combining both materials could not be more than 0.35%, and the remaining percent, by weight, of Zinc (Zn) with inevitable impurities.
  • Further objectives and advantages of the present invention will become apparent from a careful reading of the detailed description provided herein below, with appropriate reference to the accompanying drawings.
  • DETAILED DESCRIPTION OF THE PREFERRED EMBODIMENT
  • A Copper-Zinc alloy in accordance with the present invention primarily comprises a Copper material (Cu), which is composed of 56 to 65 percent in terms of weight that is relatively lower than that contained in the other invention related to Lead Free Copper-Zinc alloys to decrease the cost of the Lead Free Copper-Zinc alloy, Tin (Sn), which is composed of 0.2 to 2.0 percentage in terms of weight, may ameliorate the tensile strength and also strengthen the corrosion resistance of alloy. However, when the amounts of Tin (Sn) increase, the relatively fragile or brittle material: CuZnSn will be generated and may influence the deformation of the alloy, but will improve the cutting characteristic to the alloy.
  • For example, when the amounts of Tin (Sn) is lower than 0.3 percentage, the cutting property of the alloy may not be improved, and when the amounts of Tin (Sn) is more than 0.8 percentage, the cutting property and the tensile strength of alloy may be improved and the characteristic of corrosion resistance may be gradually strengthened. When the amounts of Tin (Sn) is more than 2.0 percentage, the corrosion speed of zinc (Zn) is about 0.010 mm/Hr, the more Tin (Sn), the better the cutting property of the alloy and the better the corrosion resistance of zinc (Zn). However, when too much Tin (Sn) is contained in the alloy, the ductibility of the alloy will be decreased. Therefore, the best amounts of Tin (Sn) is 0.2-2.0 percentage in terms of weight.
  • The alloy also contains Aluminum (Al), which is 0.1-1.0 percentage, by weight, that could improve the yielding strength and the corrosion resistance of the alloy. However, it may slightly weaken the ductibility of the alloy. Too much percentage of Aluminum (Al) may decrease the stretchability of the alloy. In addition, the specific gravity of Aluminum (Al) is relatively lighter than specific gravity of the other Copper-Zinc alloy. Adding a specific amount of Aluminum (Al) may relatively decrease weight of alloy. Both Aluminum (Al) and Tin (Sn) could improve the cutting property of the alloy.
  • The alloy also may comprise Iron (Fe) which could be well mixed the particle of the alloy. However, Iron (Fe) which contain too much inside alloy may weaken the property of corrosion resistance. Therefore, alloy could not contain too much percentage of Iron (Fe) therein. And the amount of Iron (Fe) is preferably no more than 0.5%, in terms of weight. The alloy may further comprise unavoidable impurities therein.
  • The alloy which comprises Nickel (Ni) which may even particle of the alloy, strengthen yielding strength, tensile strength, corrosion resistance and heat conductivity of the alloy. Besides, the microstructure which is composed of Nickel will be more uniform after heating or extruding. The percentage of Nickel ranged preferably between 0.01 to 0.6 percentages, in terms of weight.
  • The remaining balance of the alloy is Zinc (Zn), which may remarkably weaken heating conductivity and electric conductivity. However, composed of Zinc could improve yielding strength. When contained amount of Zinc (Zn) is more than 20%, the corrosion may be occurred in humid environment or in sea, particularly when the environment contains Ammonia (NH3). The cutting effect of the alloy will be improved when the percentage of Zinc (Zn) is more than 33%. Too much zinc (Zn) may decrease the malleability of the alloy. More than 45% of Zinc contained in alloy will be no economic value. In this invention, to solve corrosion problem is to increase composition of Nickel, Aluminum and Tin instead of decreasing composition of Zinc.
  • Further, the alloy will comprise at least one of other materials, which could be Phosphorus (P) or Arsenic (As) or both. Combining with both materials will be no more than 0.35%. The alloy which is composed of Phosphorus (P) or Arsenic (As) could strengthen the corrosion resistance. The more Phosphorus (P) and Arsenic (As) are, the better corrosion resistance of the alloy is.
  • Phosphorus (P) could be used as deoxidizer and mend the flowing of melting Copper (Cu) and may improve the characteristic of welding, the corrosion resistance and the anti-softness of the alloy. However adding Phosphorus (P) will weaken the heat conductivity and the electric conductivity of the alloy. In additional, an excess of Phosphorus may generate the fragile or brittle characteristic to the alloy, such that the amount of Phosphorus (P) is preferably ranged between 0.03-0.25% in terms of weight.
  • Arsenic (As) may be suitably melted in copper (Cu), but may greatly decrease the heat conductivity and the electric conductivity of the alloy, and Arsenic (As) may strengthen the corrosion resistance of the alloy, but will weaken the electric potential of copper (Cu). Such material which contains in alloy is preferably ranged between 0.01-0.2%, in terms of weight.
  • Accordingly, the Copper-Zinc alloy in accordance with the present invention includes a decreased amount of copper material for decreasing the cost of the Copper-Zinc alloy and including no lead engaged therein for preventing the copper-zinc alloy from polluting our environment.
  • Although this invention has been described with a certain degree of particularity, it is to be understood that the present disclosure has been made by way of example only and that numerous changes in the detailed construction and the combination and arrangement of parts may be resorted to without departing from the spirit and scope of the invention as hereinafter claimed.

Claims (1)

1. A copper-zinc alloy comprising:
56-65%, by weight, of Copper (Cu),
0.2-2.0%, by weight, of Tin (Sn),
0.1-1.0%, by weight, of Aluminum (Al),
0.01-0.6%, by weight, of Nickel (Ni),
lower than 0.5%, by weight, of Iron (Fe), and
at least one element selected from Phosphorus (P) and Arsenic (As), which are 0.03-0.25%, by weight, of Phosphorus (P), 0.01-0.2%, by weight, of Arsenic (As), combining both materials being no more than 0.35%,
with the balance being Zinc (Zn) and inevitable impurities.
US12/592,522 2009-11-27 2009-11-27 Copper-zinc alloy Abandoned US20110129385A1 (en)

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Cited By (4)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US20130329763A1 (en) * 2012-06-07 2013-12-12 Cymer, Inc. Corrosion resistant electrodes for laser chambers
CN104087782A (en) * 2013-04-01 2014-10-08 浙江艾迪西流体控制股份有限公司 Low-lead brass alloy and preparation method thereof
CN104087781A (en) * 2013-04-01 2014-10-08 浙江艾迪西流体控制股份有限公司 Bismuth-free low-lead brass alloy and preparation method thereof
AU2014202540B2 (en) * 2014-01-03 2016-07-07 Jiaxing Idc Plumbing & Heating Technology Ltd. Lead-free bismuth-free silicon-free brass

Citations (5)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US3956027A (en) * 1975-04-09 1976-05-11 Olin Corporation Processing copper base alloys
US4990309A (en) * 1988-09-16 1991-02-05 Kabushiki Kaisha Kobe Seiko Sho High strength copper-nickel-tin-zinc-aluminum alloy of excellent bending processability
US5658401A (en) * 1993-11-18 1997-08-19 Diehl Gmbh & Co. Copper-zinc alloy
US7128871B2 (en) * 2004-02-25 2006-10-31 Sterilite Llc Silver-colored alloy with low percentages of copper and zinc
US20100135848A1 (en) * 2008-12-02 2010-06-03 Chuankai Xu Lead-free free-cutting silicon brass alloy

Patent Citations (5)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US3956027A (en) * 1975-04-09 1976-05-11 Olin Corporation Processing copper base alloys
US4990309A (en) * 1988-09-16 1991-02-05 Kabushiki Kaisha Kobe Seiko Sho High strength copper-nickel-tin-zinc-aluminum alloy of excellent bending processability
US5658401A (en) * 1993-11-18 1997-08-19 Diehl Gmbh & Co. Copper-zinc alloy
US7128871B2 (en) * 2004-02-25 2006-10-31 Sterilite Llc Silver-colored alloy with low percentages of copper and zinc
US20100135848A1 (en) * 2008-12-02 2010-06-03 Chuankai Xu Lead-free free-cutting silicon brass alloy

Cited By (10)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US20130329763A1 (en) * 2012-06-07 2013-12-12 Cymer, Inc. Corrosion resistant electrodes for laser chambers
KR20150016982A (en) * 2012-06-07 2015-02-13 사이머 엘엘씨 Corrosion resistant electrodes for laser chambers
US9246298B2 (en) * 2012-06-07 2016-01-26 Cymer, Llc Corrosion resistant electrodes for laser chambers
US20160126689A1 (en) * 2012-06-07 2016-05-05 Cymer, Llc Corrosion Resistant Electrodes for Laser Chambers
EP2859627A4 (en) * 2012-06-07 2016-07-13 Cymer LLC Corrosion resistant electrodes for laser chambers
TWI625907B (en) * 2012-06-07 2018-06-01 希瑪有限責任公司 Laser system,method for generating laser light in the laser system,and electrode
KR102079052B1 (en) * 2012-06-07 2020-02-19 사이머 엘엘씨 Corrosion resistant electrodes for laser chambers
CN104087782A (en) * 2013-04-01 2014-10-08 浙江艾迪西流体控制股份有限公司 Low-lead brass alloy and preparation method thereof
CN104087781A (en) * 2013-04-01 2014-10-08 浙江艾迪西流体控制股份有限公司 Bismuth-free low-lead brass alloy and preparation method thereof
AU2014202540B2 (en) * 2014-01-03 2016-07-07 Jiaxing Idc Plumbing & Heating Technology Ltd. Lead-free bismuth-free silicon-free brass

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Owner name: CHAN WEN COPPER INDUSTRY CO., LTD., TAIWAN

Free format text: ASSIGNMENT OF ASSIGNORS INTEREST;ASSIGNOR:YANG-TUNG, TSU-SHU;REEL/FRAME:023616/0239

Effective date: 20091015

STCB Information on status: application discontinuation

Free format text: ABANDONED -- FAILURE TO RESPOND TO AN OFFICE ACTION