US20130102094A1 - Method for fabricating organic el device and method for evaluating organic el device - Google Patents
Method for fabricating organic el device and method for evaluating organic el device Download PDFInfo
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- US20130102094A1 US20130102094A1 US13/693,335 US201213693335A US2013102094A1 US 20130102094 A1 US20130102094 A1 US 20130102094A1 US 201213693335 A US201213693335 A US 201213693335A US 2013102094 A1 US2013102094 A1 US 2013102094A1
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Images
Classifications
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- H01L51/56—
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- H—ELECTRICITY
- H10—SEMICONDUCTOR DEVICES; ELECTRIC SOLID-STATE DEVICES NOT OTHERWISE PROVIDED FOR
- H10K—ORGANIC ELECTRIC SOLID-STATE DEVICES
- H10K71/00—Manufacture or treatment specially adapted for the organic devices covered by this subclass
-
- H—ELECTRICITY
- H10—SEMICONDUCTOR DEVICES; ELECTRIC SOLID-STATE DEVICES NOT OTHERWISE PROVIDED FOR
- H10K—ORGANIC ELECTRIC SOLID-STATE DEVICES
- H10K71/00—Manufacture or treatment specially adapted for the organic devices covered by this subclass
- H10K71/861—Repairing
Definitions
- One or more exemplary embodiments disclosed herein relate generally to a method for fabricating an organic electroluminescence device.
- organic electroluminescence hereafter referred to as organic EL
- organic EL organic electroluminescence
- the patent literature 1 discloses a technique for recovering the light-emission function of the organic EL device by irradiating the electrodes around the foreign material in the organic EL device with laser so as to separate the electrode into a region contacting the foreign material and a region not contacting the region or the foreign material.
- the leakage part is specified from weak light emitted from a flat-panel display device when a reverse-bias voltage is applied, and the specified leakage part is irradiated with a laser beam. With this, the defect in light emission caused by the leakage is repaired.
- Patent Literature 1 Japanese Unexamined Patent Application Publication No. 2005-276600
- Patent Literature 2 Japanese Unexamined Patent Application Publication No. 2006-323032
- One non-limiting and exemplary embodiment provides a method for fabricating the organic EL device including an evaluation method capable of evaluating whether or not the repair is successful when the light-emission defect caused by the short-circuit in the organic EL device is repaired by irradiating the organic EL device with the laser beam.
- the method for fabricating the organic EL device disclosed here feature a method for fabricating an organic electroluminescence (EL) device, and the method includes: irradiating an organic EL device having a defective portion with a laser beam; measuring first luminance of light emitted from the organic EL device after the organic EL device is irradiated with the laser beam, while supplying, to the organic EL device, a first amount of current with which the organic EL device in a normal state would emit light having luminance corresponding to a first grayscale level smaller than a reference grayscale level; re-irradiating the organic EL device with the laser beam when the first luminance measured in the measuring is smaller than a determination threshold; and measuring second luminance of light emitted from the organic EL device when the first luminance measured in the measuring is greater than or equal to the determination threshold, while supplying, to the organic EL device, a second amount of current with which the organic EL device in the normal state would emit light having luminance corresponding to a second gray
- luminance of the light in a low grayscale level is measured prior to the conventional test in which the luminance of light in a high grayscale level is measured. Accordingly, it is possible to securely find the light-emitting device on which the laser repairing is incomplete, and repairing the device.
- FIG. 1 is a schematic cross-sectional diagram illustrating an example of the organic EL device according to the embodiment.
- FIG. 2 is a top view of the organic EL device representing an example of a cathode having increased resistance.
- FIG. 3 is a flowchart illustrating an example of the method for fabricating the organic EL device according to the embodiment.
- FIG. 4 is a schematic cross-sectional diagram illustrating an example of the organic EL device prepared in the embodiment.
- FIG. 5 is a flowchart illustrating an example of a process of detecting the shorted part of the light-emitting device according to the embodiment.
- FIG. 6 is a flowchart illustrating an example of the process for repairing a defect caused by the short-circuit according to the embodiment.
- FIG. 7 is a structural diagram illustrating an example of a system for performing laser repairing according to the embodiment.
- FIG. 8 ( a ) is a graph illustrating an example of the light-emission characteristics of the organic EL device in states including normal, repair successful, and repair unsuccessful.
- FIG. 8 ( b ) is a graph illustrating low grayscale level in FIG. 8 ( a ) enlarged.
- FIG. 9A is an equivalent circuit diagram of the organic EL device having a shorted part due to a foreign material.
- FIG. 9B is a graph illustrating an example of current-voltage characteristics of the organic EL device having a shorted part due to the foreign material.
- FIG. 10 is an external view of a television system having the organic EL device according to the present disclosure.
- the inventors found out the following problem after the repair disclosed in the Background Art is performed.
- One requirement for the successful repair is that the maximum luminance of the light emitted from the repaired organic EL device recovers to a level greater than or equal to an acceptable threshold value. Accordingly, typically, in the conventional repair, a test for checking the luminance of the light emission is performed after applying a luminance signal of high grayscale level (for example, around the maximum grayscale level) on the repaired organic EL device.
- the high grayscale level light-emission test is performed by checking the light-emission of a normal intensity using visible light. Accordingly, the test can be easily performed either as visual checking by a test worker or mechanical auto-recognition. This significantly contributes to simplifying the repair process and increasing the efficiency of the repair process.
- One non-limiting and exemplary embodiment provides a method for fabricating the organic EL device including an evaluation method capable of evaluating whether or not the repair is successful when the light-emission defect caused by the short-circuit in the organic EL device is repaired by irradiating the organic EL device with the laser beam.
- the method for fabricating the organic EL device includes: irradiating an organic EL device having a defective portion with a laser beam; measuring first luminance of light emitted from the organic EL device after the organic EL device is irradiated with the laser beam, while supplying, to the organic EL device, a first amount of current with which the organic EL device in a normal state would emit light having luminance corresponding to a first grayscale level smaller than a reference grayscale level; re-irradiating the organic EL device with the laser beam when the first luminance measured in the measuring is smaller than a determination threshold; and measuring second luminance of light emitted from the organic EL device when the first luminance measured in the measuring is greater than or equal to the determination threshold, while supplying, to the organic EL device, a second amount of current with which the organic EL device in the normal state would emit light having luminance corresponding to a second grayscale level greater than or equal to the reference grayscale level.
- luminance of the light in the low grayscale level is measured prior to the conventional test in which the luminance of the light in the high grayscale level is measured. Accordingly, it is possible to accurately find the light-emitting device on which the laser repairing is incomplete, and repairing the device.
- the determination threshold for the first luminance may be 50% of luminance corresponding to the first grayscale level of the light emitted from the organic EL device in the normal state.
- the organic EL device having luminance of the light less than half the luminance of the normal organic EL device is especially likely to be recognized by the user. Accordingly, it is effective to select such an organic EL device and attempt the re-repair by the laser re-irradiation.
- the first grayscale level may be a grayscale level corresponding to the light emitted from the organic EL device in the normal state having a luminance of 1 cd/m 2 .
- the luminance 1 cd/m 2 of the light emitted is an example of an upper limit value of the luminance substantially recognized as black by the user, and the user recognizes light with any luminance lower than or equal to 1 cd/m 2 as black.
- the upper limit value of the luminance substantially recognized as black uniformly by the user significantly differs depending on the capacity, usage, and use environment of the display apparatus including the organic EL panel incorporated therein. Accordingly, the specific value of the first grayscale level should be appropriately selected depending on the capacity, usage, and use environment of the display apparatus.
- the second grayscale level may be a grayscale level around a maximum grayscale level of the organic EL device.
- the high-grayscale level light-emission test performed near the maximum grayscale level checks whether the maximum light emission luminance greater than or equal to the acceptable threshold is restored in the organic EL device after the laser irradiation, and also serves as a tolerance test for checking whether or not the tolerance of the organic EL device is degraded by the laser irradiation. Accordingly, this is significantly helpful for simplifying and increasing the efficiency of the repair process.
- FIG. 1 is a cross-sectional schematic diagram according to the embodiment 1.
- the organic EL device 1 illustrated in FIG. 1 is an organic functional device including an organic layer having an anode, a cathode, and a light-emitting layer disposed between the anode and the cathode.
- the organic EL device 1 includes a planarizing film 10 , an anode 11 , a hole injection layer 12 , a light-emitting layer 13 , a bank 14 , an electron injection layer 15 , a cathode 16 , a thin-film sealing layer 17 , a sealing resin layer 19 , and a transparent glass 18 provided above a transparent glass 9 .
- the anode 11 and the cathode 16 correspond to the lower electrode layer and the upper electrode layer according to the present disclosure, respectively.
- the hole injection layer 12 , the light-emitting layer 13 , and the electron injection layer 15 correspond to the organic layer according to the present disclosure.
- Transparent glasses 9 and 18 are substrates for protecting the light-emitting surface of the light-emitting panel, and is a transparent alkali-free glass having a thickness of 0.5 mm, for example.
- the planarizing film 10 is made of an insulating organic material, and is formed on a substrate including driving thin-film transistors (TFT).
- TFT driving thin-film transistors
- the anode 11 receives holes, that is, a flow of current from an external circuit, and formed of a reflective electrode made of Al, a silver alloy APC, or others stacked on the planarizing film 10 .
- the thickness of a reflective electrode is 10 nm to 40 nm, for example.
- the anode 11 may be a two-layered structure formed of indium tin oxide (ITO), a silver alloy APC, and others, for example.
- ITO indium tin oxide
- APC silver alloy APC
- the hole injection layer 12 is a layer having a hole injecting material as a major component.
- the hole injecting material is a material having a function for stably injecting holes injected from the side of the anode 11 into the light-emitting layer 13 , or supporting the generation of the holes and injecting the holes on the light-emitting layer 13 .
- compounds such as Poly (3, 4-ethylenedioxythiophene) (PEDOT) and aniline have been used.
- the light-emitting layer 13 is a layer which emits light by an application of a voltage between the anode 11 and the cathode 16 , and is a stacked structure including a lower layer, ⁇ -NPD(Bis[N-(1-naphthyl)-N-phenyl]benzidine) and an upper layer, Alq3(tris-(8-hydroxyquinoline)aluminum).
- the electron injection layer 15 is a layer having an electron injecting material as a major component.
- the material having electron injecting property is a material having a function for injecting the electrons injected from the cathode 16 stably, or supporting the generation of the electrodes and injecting the electrons into the light-emitting layer 13 , and Poly(p-phenylene vinylene) (PPV) is used, for example.
- the cathode 16 receives supply of electrons, that is, is a cathode from which current flows to the external circuit, and has a stacked structure of ITO which is a transparent metal oxide, for example.
- the cathode 16 may be formed as a transparent electrode out of Mg, Ag, and others.
- the thickness of the electrode is 10 nm to 40 nm, for example.
- the bank 14 is a wall for separating the light-emitting layer 13 for each light-emitting region 2 allowing individual driving for the light emission, and is made of a photo-sensitive resin.
- the thin-film sealing layer 17 is made of silicon nitride, and has a function of blocking the light-emitting layer 13 and the cathode from moisture and oxygen. This is for preventing the light-emitting layer 13 itself and the cathode 16 from being degraded (being oxidized) by the exposure to the moisture and oxygen.
- the sealing resin layer 19 is an acrylic or epoxy resin, and has a function of joining a layer integrally formed on the substrate from the planarizing film 10 to the thin-film sealing layer 17 and the transparent glass 18 .
- the stacked structure of the anode 11 , the light-emitting layer 13 , and the cathode 16 is the basic configuration of the organic EL device 1 .
- the holes and the electrons are injected into the light-emitting layer 13 from the anode 11 side and the cathode 16 side, respectively.
- the energy generated by the injected holes and electrons re-combined in the light-emitting layer 13 , the luminescent material in the light-emitting layer 13 is excited and emits light.
- the material for the hole injection layer 12 and the electron injection layer 15 are not limited in the present disclosure, and a known organic material or inorganic material is used.
- the hole transport layer may be provided between the hole injection layer 12 and the light-emitting layer 13 , and an electron transport layer may be provided between the electron injection layer 15 and the light-emitting layer 13 .
- the hole transport layer may be provided instead of the hole injection layer 12
- an electron transport layer may be provided instead of the electron injection layer 15 .
- the hole transport layer is a layer having a hole transporting material as a major component.
- the hole transporting material with electron donor property is a material having a tendency to become positive ion (holes), and a property for transmitting the generated holes by charge transfer between molecules, and is a material suitable for transporting the electrons from the anode 11 to the light-emitting layer 13 .
- the electron transport layer is a layer having an electron transporting material as a major component.
- the electron transporting material is a material having an electron acceptor property and tendency to become negative ion, and transmits the generated electrons by the charge transfer between molecules, and is a material suitable for transporting the charges from the cathode 16 to the light-emitting layer 13 .
- the organic EL device 1 may further include color filters (light-adjusting layers) for adjusting the colors of red, green, and blue, under the transparent glass 18 to cover the light-emitting regions separated by the bank 14 .
- color filters light-adjusting layers
- the hole injection layer 12 , the light-emitting layer 13 , and the electron injection layer 15 are collectively referred to as the organic layer 30 .
- the hole transport layer and the electron transport layer are included, these layers are also included in the organic layer 30 .
- the thickness of the organic layer 30 is, for example, 100 nm to 200 nm.
- one organic EL device 1 is composed by a planarizing film 10 , the anode 11 , the organic layer 30 , the cathode 16 , the thin-film sealing layer 17 , the sealing resin layer 19 , and the transparent glass 18 disposed in a light-emitting region 2 separated by the bank 14 and can be individually controlled for light-emission.
- the organic EL panel (image display panel) is composed by arranging the organic EL device 1 in a matrix, and providing driving circuits each for controlling the light-emission from one of the organic EL devices 1 .
- a part including one organic EL device and its corresponding driving circuit in the organic EL panel is referred to as a pixel.
- a conductive foreign material 20 is included between the anode 11 and the cathode 16 in the fabrication process, and the anode 11 and the cathode 16 are short-circuited through the foreign material 20 .
- the shorted part caused by the foreign material 20 is an example of the defective part of the light-emitting region 2 .
- an irradiation trace 16 a is formed by irradiation of the laser beam on a part of the cathode near the foreign material 20 .
- the details of the repair by the irradiation of the laser beam shall be described later.
- FIG. 2 is a top view of the organic EL device 1 , and illustrates a typical example of a position of the irradiation trace 16 a in the plane, formed by the laser irradiation on the light-emitting region 2 having a shorted part by the foreign material 20 .
- the AA′ cross-section illustrated in FIG. 2 corresponds to FIG. 1 .
- the laser beam is emitted, tracing a closed path surrounding the shorted part of the cathode 16 due to the foreign material 20 .
- a square of 20 ⁇ m ⁇ 20 ⁇ m is set in a periphery away from the foreign material 20 for approximately 10 ⁇ m, and an outline of the square may be irradiated with the laser beam.
- the irradiation trace 16 a illustrated in FIG. 2 is formed in the cathode 16 .
- the resistance value of the irradiation trace 16 a is higher than the original resistance value of the cathode 16 which is not irradiated with the laser beam.
- the expression “increasing the resistance” refers to an action of irradiating a part to be irradiated with the laser beam so as to increase the resistance value of the part to be higher than the resistance value before the laser irradiation.
- This fabrication method includes a process for solving the malfunction caused by the defective part of the organic EL device 1 .
- FIG. 3 is a flowchart illustrating the method for fabricating the organic EL device 1 according to the present disclosure.
- the organic EL panel is prepared (S 10 ).
- the organic EL panel includes pixels each of which includes the organic EL device 1 and a driving circuit for driving the organic EL device 1 arranged in a matrix.
- This process includes a process for stacking and forming the organic EL device 1 included in the pixels arranged in a matrix.
- step S 10 the entire screen of the organic EL panel prepared in step S 10 is turned on, and an entire-screen lighting test for selecting an organic EL panel having no problem with the screen display property is performed (S 20 ).
- step S 20 the organic EL panels selected in step S 20 are tested for dark spot in the pixel and are repaired (S 30 ).
- the light-emitting region for each pixel is tested, and a shorted part in which the anode 11 and the cathode 16 are shorted in each light-emitting region is detected as a defective part (S 40 ).
- step S 50 the malfunction caused by the defective part detected in step S 40 is repaired by laser irradiation (S 50 ).
- the process in step S 50 includes a recovery evaluation process which is characteristic process of the present disclosure for evaluating the organic EL device after the laser irradiation.
- FIG. 4 is a partial cross-sectional schematic diagram of the organic EL panel prepared in the first process of the present disclosure.
- FIG. 4 illustrates a cross-sectional structure of the organic EL device 1 A in which the anode 11 and the cathode 16 are shorted due to the foreign material 20 .
- the planarizing film 10 made of an insulating organic material is formed on a substrate including the TFT, and the anode 11 is subsequently formed on the planarizing film 10 .
- the anode 11 is formed by depositing Al of 30 nm on the planarizing film 10 by the sputtering method, and a subsequent patterning process using the photolithography and the wet etching.
- the hole injection layer 12 is formed on the anode 11 by spin-coating the PEDOT solution including PEDOT dissolved in a solvent made of xylene.
- the light-emitting layer 13 is formed by stacking ⁇ -NPD, Alq3 by the vacuum vapor deposition method.
- the electron injection layer 15 is formed on the light-emitting layer 13 by spin-coating Poly (p-phenylene vinylene) (PPV) dissolved in a solvent made of xylene or chloroform.
- PV spin-coating Poly (p-phenylene vinylene)
- the cathode 16 is formed without exposing, in the air, the substrate on which the electron injection layer 15 is formed. More specifically, the cathode 16 is formed on the electron injection layer 15 by stacking indium tin oxide (ITO) for 35 nm by the sputtering method. Here, the cathode 16 is in an amorphous state.
- ITO indium tin oxide
- the organic EL device having a function as a light-emitting device is formed. Note that, between the process for forming the anode 11 and the process for forming the hole injection layer 12 , the bank 14 made of a resin with a photosensitive surface is formed at a predetermined position.
- the thin-film sealing layer 17 is formed on the cathode 16 ; by stacking silicon nitride for 500 nm using the plasma chemical vapor deposition (CVD) method, for example.
- the thin-film sealing layer 17 is formed in contact with the surface of the cathode 16 .
- the requirement for the protective film is strict, and a non-oxygen inorganic material represented as the silicon nitride described above is used, for example.
- the thin-film sealing layer 17 may be formed of an oxygen inorganic material such as silicon oxide (Si x O y ) and silicon oxynitride (Si x O y N z ), and a structure including multiple layers of the inorganic materials.
- the forming method is not limited to the plasma CVD method, and may also be other methods such as the sputtering method using argon plasma.
- the sealing resin layer 19 is applied on the surface of the thin-film sealing layer 17 .
- the transparent glass 18 is provided on the sealing resin layer 19 applied.
- the color filter (light-adjusting layer) is formed on the main surface of the transparent glass 18 .
- the transparent glass 18 is provided on the sealing resin layer 19 applied, with the surface on which the color filters are formed is facing downward.
- the thin-film sealing layer 17 , the sealing resin layer 19 and the transparent glass 18 serve as the protective layer.
- the sealing resin layer 19 is cured by applying heat or energy line while applying pressure downward from the upper surface side of the transparent glass 18 , bonding the transparent glass 18 and the thin-film sealing layer 17 .
- the organic EL device 1 A illustrated in FIG. 4 is formed.
- the process for forming the anode 11 , the hole injection layer 12 , the light-emitting layer 13 , the electron injection layer 15 and the cathode 16 is not limited by the present disclosure.
- the organic EL devices in the entire screen of the organic EL panel prepared in step S 10 is turned on for lighting for testing whether or not there is a problem in the display characteristics on the screen such as uneven luminance, linear display defect, and dark spots out of acceptable level.
- organic EL panels without any problem are selected, and disqualified panels are used as recycled parts or discarded.
- the foreign material 20 remains when Al, which is the material for the anode 11 is attached on the anode 11 after the anode 11 is formed, and the hole injection layer 12 , the light-emitting layer 13 , the electron transport layer 15 , and the cathode 16 are subsequently stacked thereon.
- the size of the foreign material 20 is, for example, approximately a diameter of 200 nm and a height of 500 nm, for example. If there is a shorted part between the anode 11 and the cathode 16 by the foreign material 20 , current which is supposed to drive the light-emission flows in the shorted part. Consequently, the light-emitting region 2 does not sufficiently emit light or emit light at all.
- the pixel corresponding to the light-emitting region 2 which lost a normal light-emitting function is referred to as a defective pixel.
- FIG. 5 is an operational flowchart for describing step S 40 according to the embodiment.
- the light on the organic EL panel selected at step S 20 is turned on (S 41 ). More specifically, a reverse bias voltage is applied to all of the pixels in the organic EL panel simultaneously by the driving circuit in the organic EL panel or by an external testing apparatus connected. Here, all of the pixels are captured by a CCD camera or others at the same time.
- the luminance of the light emitted from each of the pixels is calculated based on the captured image in the reverse-bias voltage application period, and a pixel which is emitting light with luminance smaller than or equal to the predetermined threshold is detected as a defective pixel (S 42 ).
- the detected defective pixel is enlarged and observed (S 43 ). More specifically, the defective pixel is observed using a photomicrographic camera, for example.
- the foreign material 20 is identified in a region of the defective pixel enlarged for observation (S 44 ).
- a reverse bias voltage is applied on the defective pixel detected in step S 42 , and a light-emitting point emitting leakage light is identified (S 45 ).
- current does not flow in the organic EL device by the reverse bias voltage.
- the leakage light emitted by the leakage current is observed in the shorted part.
- a point emitting the leakage light in the light-emitting region is identified by an image obtained by capturing the leakage light-emitting state.
- a predetermined reverse bias voltage is applied in the pixels to be tested. Subsequently, the point emitting light greater than or equal to threshold intensity in a period when a reverse bias voltage is applied is determined. Note that, since the leakage light emitted by applying a reverse bias voltage is weak, the image capturing by a CCD camera or others is performed in a completely light-shielded environment, for example. Subsequently, the intensity of light emitted from each imaging point is compared with a threshold. With this, whether or not there is leakage light-emission is determined. The leakage light emitting point is determined as described above.
- the CCD camera a cooled CCD camera is used, for example. With this, even when imaging weak leakage light emitted from the organic EL device, it is possible to secure a predetermined S/N ratio. Accordingly, it is possible to eliminate the noise at the time of testing, thereby improving the accuracy of detecting the point emitting the leakage light.
- the position of the shorted part in the defective pixel is located by synthesizing the image of the defective pixel when the forward bias voltage is applied which is enlarged and observed at step S 44 , and the image of the leakage light-emitting point when the reverse-bias voltage is applied at step S 45 (S 46 ).
- the position of the shorted part is located by matching the position of the foreign material located at step S 44 and the position of the leakage light-emitting point located at step S 45 .
- the shorted part may be located by using only the position of the foreign material or the leakage light-emitting point.
- detection of the light-emitting region having a shorted part is not limited to the method described above, and may be detected based on a current value by measuring a current value flowing between the anode 11 and the cathode 16 of the organic EL device.
- a current value equivalent to a normal pixel is obtained when the forward bias voltage is applied, and leakage light emission is observed when the reverse-bias voltage is applied may be determined as the defective pixel.
- step S 50 includes a recovery evaluation process which is characteristic process of the present disclosure for evaluating the organic EL device after the laser irradiation.
- FIG. 6 is an operational flowchart for describing step S 50 according to the embodiment.
- FIG. 7 is a structural diagram illustrating an example of a system for performing laser repairing according to the embodiment.
- the system illustrated in FIG. 7 includes a laser oscillator 101 , a CCD cameral 103 , a lighting 104 , and a stage 105 .
- the organic EL panel having the organic EL device 1 A, an item in fabrication process, is disposed and fixed on the stage 105 .
- the laser oscillator 101 can emit a laser beam having an ultrashort pulse with a wavelength of 750 nm to 1600 nm, output energy of 1 ⁇ J to 30 ⁇ J, and a pulse width in the order of a few femtoseconds to a few picoseconds.
- the ultrashort pulse laser includes a femtosecond laser, for example, and a suitable range of the pulse is 100 fs to 20 ps.
- the resistance in a part of the cathode 16 is increased by focusing the laser on the cathode 16 .
- the range of the output energy capable of increasing the resistance of the part of the cathode 16 is dependent on the wavelength of the laser beam emitted.
- the cathode 16 is irradiated with a laser beam having a pulse width greater than or equal to 20 psec, the organic layer 30 will be damaged.
- the organic EL device in the range of the laser wavelength, and by irradiating the organic EL device with a laser having a pulse width in a range of the pulse width allows increase the resistance in part of the cathode 16 easily.
- the CCD camera 103 captures the organic EL panel on the stage 105 .
- the lighting 104 emits supplemental light necessary for imaging the organic EL panel.
- the stage 105 is used for placing the organic EL panel, is movable in the height direction Z, and the planar directions X and Y, and positions an area of the organic EL device to be irradiated with the laser.
- the height of the part of the organic EL device to be irradiated with laser (irradiated part) is set (S 51 ). More specifically, the position of the stage 105 in the depth direction Z is adjusted such that the focus of the laser beam is on the cathode 16 in the organic EL device 1 A.
- the irradiation line of the laser beam is set (S 52 ). More specifically, as illustrated in FIG. 2 , the irradiation line in the plane to be traced by the laser beam is set in a position defined as a closed path surrounding the shorted part of the cathode 16 due to the foreign material 20 (for example, on the outline of a square of 20 ⁇ m ⁇ 20 ⁇ m defined at a periphery approximately 10 ⁇ m away from the foreign material in the cathode 16 ).
- the area surrounded by the irradiation line is smaller than or equal to one third of the area of the light-emitting region 2 , for example.
- a part of the irradiation line near the starting point and a part of the irradiation line near the end point may cross each other.
- the first laser irradiation process of irradiating the organic EL panel with a laser is performed, tracing the irradiation line set in step S 52 at the height of the stage 105 determined at step S 51 (S 53 ).
- the organic EL panel is evaluated as to whether or not the light-emitting function of the defective pixel has recovered (S 54 ).
- a low grayscale level light-emission checking process of measuring luminance of light emitted from the organic EL device after the organic EL device is irradiated with the laser beam while supplying, to the organic EL device, a first amount of current with which the organic EL device in a normal state would emit light having luminance corresponding to a first grayscale level smaller than a reference grayscale level is performed (S 55 ), and if the measured luminance is smaller than a threshold for determination (No in S 56 ), the process returns to step S 53 , and the second laser irradiation process for irradiating the organic EL device with a laser beam again is performed.
- a high grayscale level light-emission checking process of measuring luminance of light emitted from the organic EL device when the luminance measured in step S 55 is greater than or equal to the determination threshold, while supplying, to the organic EL device, a second amount of current with which the organic EL device in the normal state would emit light having luminance corresponding to a second grayscale level greater than or equal to the reference grayscale level is performed (S 57 ).
- the high grayscale level light-emission checking process is performed in the same manner as a typical conventional recovery checking test.
- the inventors conducted an experiment for measuring the light-emitting characteristics of multiple organic EL devices determined as emitting light having acceptable maximum luminance after laser irradiation.
- current corresponding to every one of 256 grayscale levels from 0 (light off) to 255 (maximum luminance) was sequentially supplied to the organic EL device, and the luminance corresponding to each grayscale level was measured.
- FIG. 8 ( a ) is a graph illustrating an example of the light-emission characteristics of the organic EL device illustrating the states including normal, repair successful, and repair unsuccessful.
- FIG. 8 ( b ) is a graph illustrating the low grayscale level part of FIG. 8 ( a ) enlarged.
- the graph indicated as normal indicates the designed luminance value of the pixel emitting light by a supply of the current corresponding to each grayscale level if the organic EL device is normal.
- the regular organic EL device without light emission malfunction caused by the short-circuit emits light mostly following the light emission property described above.
- the graphs marked as repair successful and repair unsuccessful illustrate light-emitting characteristics measured on an organic EL device with recovered luminance in low grayscale level and light-emitting characteristics measured on an organic EL device with non-recovered low grayscale level luminance, among the organic EL devices with acceptable maximum light emission luminance recovered.
- both the organic EL devices whose repair is successful or unsuccessful indicate the same light-emission characteristics.
- the illustration of the light-emission characteristics greater than or equal to 200 cd/m 2 is omitted, it is confirmed that the organic EL device emits light having luminance greater than or equal to half the luminance of the normal EL device when the current corresponding to the maximum grayscale level is supplied. Accordingly, the organic EL devices pass the high-grayscale level light-emission test in which the threshold for the determination is set to be 50% of the normal luminance.
- FIG. 8 ( b ) when the grayscale level is lower than or equal to level 50 , the luminance of the light emitted from the organic EL device whose repair was unsuccessful remains in less than half the luminance of the normal organic EL device.
- the inventors assumed that the cause of the difference in the light-emission characteristics is in the difference in the level of increased resistance at the shorted part by the laser irradiation, and considered the following issues.
- FIG. 9A is an equivalent circuit diagram of the organic EL device having a shorted part by the foreign material
- FIG. 9B is a graph illustrating an example of the current-voltage characteristics of the organic EL device having a shorted part caused by the foreign material.
- the thick line illustrates current flowing in the organic layer 30 .
- the organic layer 30 has non-linear current-voltage characteristics as a diode.
- the fine lines illustrate current flowing in the shorted part caused by the foreign material 20 .
- the shorted part has a resistance value dependent on the resistance value of the irradiation trace 16 a after the laser irradiation.
- the graphs in the fine broken line and the fine solid line are models for a case in which the increased resistance of the shorted part by the laser irradiation is insufficient (repair unsuccessful) and sufficient (repair successful).
- the organic EL device when the organic EL device is driven by large current, that is, when the organic EL device emits light in high grayscale level, the current flowing in the organic layer 30 is dominant, and thus the insufficient resistance on the shorted part is not evident.
- the organic EL device when the organic EL device is driven at small current, that is, when the organic EL device emits light in a low grayscale level, the current flowing in the shorted part is dominant. Consequently, the organic EL device in which the resistance at the shorted part is not sufficiently increased does not emit light at all or emits light in extremely low luminance. This aspect matches the phenomenon found by the inventors very well.
- the inventors devised a method in which the repair method described in the flowchart of FIG. 6 . More specifically, first, the light-emission checking at low grayscale level is performed on the organic EL device after the laser irradiation. When the desired luminance is not obtained at the low-grayscale level light emission checking, the high-grayscale level light emission checking which is the typical recovery checking test is performed after increasing the resistance values of the irradiation trace.
- the low-grayscale level light-emission checking in which the luminance of emitted light in low grayscale level is performed (S 55 ). If the measured luminance is lower than the threshold for the determination (No in S 56 ), the process returns to step S 53 , and an attempt to increase the resistance in the device by irradiating the device with the laser beam again is performed. Accordingly, the possibility of missing the light-emission defect in the low grayscale level is reduced compared to the conventional technology, allowing a repair of the organic EL device with higher accuracy.
- the threshold used for the determination at step S 56 may be 50% of the luminance corresponding to the first grayscale level when the organic EL device is normal.
- the organic EL device having a luminance of the light less than half the luminance of the normal organic EL device is especially likely to be recognized by the user. Accordingly, it is effective to select such an organic EL device and attempt the re-repair by the laser re-irradiation.
- the first grayscale level may be the first grayscale level is a grayscale level corresponding to the light emitted from the organic EL device in the normal state having a luminance of 1 cd/m 2 (for example, level 26 ).
- the luminance 1 cd/m 2 of the light emitted is an example of the upper limit value of the luminance substantially recognized as black by the user, and the user recognizes light with any luminance lower than or equal to 1 cd/m 2 as black.
- the upper limit value of the luminance substantially recognized as black uniformly by the user significantly differs depending on the capacity, usage, and use environment of the display apparatus including the organic EL panel incorporated therein. Accordingly, the specific value of the first grayscale level should be appropriately selected depending on the capacity, usage, and use environment of the display apparatus.
- the second grayscale level may be the grayscale level near the maximum grayscale level of the organic EL device.
- the high-grayscale level light-emission test performed near the maximum grayscale level checks whether the maximum light emission luminance greater than or equal to the acceptable threshold is restored in the organic EL device after the laser irradiation, and also serves as a tolerance test for checking whether or not the tolerance of the organic EL device is damaged by the laser irradiation. Accordingly, this is significantly helpful for simplifying and increasing the efficiency of the repair process.
- the lower electrode is the anode and the upper electrode is the cathode
- the lower electrode may be the cathode
- the upper electrode may be the anode
- the planarizing film, the anode, the hole injection layer, the light-emitting layer, the bank, the electron injection layer, the cathode, the thin-film sealing layer, the sealing resin layer and the transparent glass included in the organic EL device may not be limited to the configuration described the embodiment.
- the materials, the configurations, and the forming methods may be changed.
- the hole transport layer may be provided between the hole injection layer and the light-emitting layer, and the electron transport layer may be provided between the electron injection layer and the light emitting layer.
- the color filters for adjusting the colors in red, green, and blue may be provided under the transparent glass to cover the light-emitting regions separated by the bank.
- the femtosecond laser described above can pass through the color filters. Accordingly, it is possible to solve the short-circuit through the color filters.
- the irradiation position of the laser may not be limited to the embodiment described above, but may be set in a predetermined range including the foreign material or shorted part, or only on the foreign material or the shorted part. Alternatively, the irradiation position may be set to surround the periphery of the foreign material or the shorted part. Furthermore, the laser irradiation may not be limited on the cathode, but may be performed on the anode.
- the present disclosure is suitable for fabricating the thin-flat television system having the organic EL device illustrated in FIG. 10 , for example.
- the organic EL device and the method for fabricating the organic EL device according to the present disclosure is applicable to the technology fields such as flat-panel television or displays for personal computers, where there is a demand for increased size of the screen and a higher resolution.
Abstract
Description
- This is a continuation application of PCT Patent Application No. PCT/JP2011/005226 filed on Sep. 15, 2011, designating the United States of America. The entire disclosure of the above-identified application, including the specification, drawings and claims is incorporated herein by reference in their entirety.
- One or more exemplary embodiments disclosed herein relate generally to a method for fabricating an organic electroluminescence device.
- Conventionally, in an organic electroluminescence (hereafter referred to as organic EL) device including an anode, a cathode, and an organic layer disposed between the anode and the cathode, there is a case in which a conductive foreign material is attached or mixed during the fabrication process. This could lead to undesirable short-circuit (leakage) between the anode and the cathode, causing light-emission defect in the organic EL device.
- In this case, there is a known method for repairing the defect due to short-circuit, by increasing resistance of a shorted part or a target region determined around the shorted region by laser irradiation (for example, see the patent literature 1).
- The
patent literature 1 discloses a technique for recovering the light-emission function of the organic EL device by irradiating the electrodes around the foreign material in the organic EL device with laser so as to separate the electrode into a region contacting the foreign material and a region not contacting the region or the foreign material. - Furthermore, in a technique according to the
patent literature 2, the leakage part is specified from weak light emitted from a flat-panel display device when a reverse-bias voltage is applied, and the specified leakage part is irradiated with a laser beam. With this, the defect in light emission caused by the leakage is repaired. - [Patent Literature 1] Japanese Unexamined Patent Application Publication No. 2005-276600
- [Patent Literature 2] Japanese Unexamined Patent Application Publication No. 2006-323032
- Conventionally, the techniques for repair have been known. However, there is a problem that the accuracy of the test for determining whether the repair was successful or not is not sufficient.
- One non-limiting and exemplary embodiment provides a method for fabricating the organic EL device including an evaluation method capable of evaluating whether or not the repair is successful when the light-emission defect caused by the short-circuit in the organic EL device is repaired by irradiating the organic EL device with the laser beam.
- In one general aspect, the method for fabricating the organic EL device disclosed here feature a method for fabricating an organic electroluminescence (EL) device, and the method includes: irradiating an organic EL device having a defective portion with a laser beam; measuring first luminance of light emitted from the organic EL device after the organic EL device is irradiated with the laser beam, while supplying, to the organic EL device, a first amount of current with which the organic EL device in a normal state would emit light having luminance corresponding to a first grayscale level smaller than a reference grayscale level; re-irradiating the organic EL device with the laser beam when the first luminance measured in the measuring is smaller than a determination threshold; and measuring second luminance of light emitted from the organic EL device when the first luminance measured in the measuring is greater than or equal to the determination threshold, while supplying, to the organic EL device, a second amount of current with which the organic EL device in the normal state would emit light having luminance corresponding to a second grayscale level greater than or equal to the reference grayscale level.
- Additional benefits and advantages of the disclosed embodiments will be apparent from the Specification and Drawings. The benefits and/or advantages may be individually obtained by the various embodiments and features of the Specification and Drawings, which need not all be provided in order to obtain one or more of such benefits and/or advantages.
- According to the method for fabricating the organic EL device, luminance of the light in a low grayscale level is measured prior to the conventional test in which the luminance of light in a high grayscale level is measured. Accordingly, it is possible to securely find the light-emitting device on which the laser repairing is incomplete, and repairing the device.
- These and other advantages and features will become apparent from the following description thereof taken in conjunction with the accompanying Drawings, by way of non-limiting examples of embodiments of the present disclosure.
-
FIG. 1 is a schematic cross-sectional diagram illustrating an example of the organic EL device according to the embodiment. -
FIG. 2 is a top view of the organic EL device representing an example of a cathode having increased resistance. -
FIG. 3 is a flowchart illustrating an example of the method for fabricating the organic EL device according to the embodiment. -
FIG. 4 is a schematic cross-sectional diagram illustrating an example of the organic EL device prepared in the embodiment. -
FIG. 5 is a flowchart illustrating an example of a process of detecting the shorted part of the light-emitting device according to the embodiment. -
FIG. 6 is a flowchart illustrating an example of the process for repairing a defect caused by the short-circuit according to the embodiment. -
FIG. 7 is a structural diagram illustrating an example of a system for performing laser repairing according to the embodiment. -
FIG. 8 (a) is a graph illustrating an example of the light-emission characteristics of the organic EL device in states including normal, repair successful, and repair unsuccessful.FIG. 8 (b) is a graph illustrating low grayscale level inFIG. 8 (a) enlarged. -
FIG. 9A is an equivalent circuit diagram of the organic EL device having a shorted part due to a foreign material. -
FIG. 9B is a graph illustrating an example of current-voltage characteristics of the organic EL device having a shorted part due to the foreign material. -
FIG. 10 is an external view of a television system having the organic EL device according to the present disclosure. - The inventors found out the following problem after the repair disclosed in the Background Art is performed.
- One requirement for the successful repair is that the maximum luminance of the light emitted from the repaired organic EL device recovers to a level greater than or equal to an acceptable threshold value. Accordingly, typically, in the conventional repair, a test for checking the luminance of the light emission is performed after applying a luminance signal of high grayscale level (for example, around the maximum grayscale level) on the repaired organic EL device.
- The high grayscale level light-emission test is performed by checking the light-emission of a normal intensity using visible light. Accordingly, the test can be easily performed either as visual checking by a test worker or mechanical auto-recognition. This significantly contributes to simplifying the repair process and increasing the efficiency of the repair process.
- However, the inventors noticed that even if the maximum light-emission luminance has recovered to the acceptable level in the high grayscale level light-emission test, there are organic EL elements not emitting light at all or emitting light having extremely low luminance, when a luminance signal of a lower grayscale level is given. Missing the defect in the light-emission at the low grayscale level could be a cause to deteriorated reliability of repair, which is a significant problem.
- One non-limiting and exemplary embodiment provides a method for fabricating the organic EL device including an evaluation method capable of evaluating whether or not the repair is successful when the light-emission defect caused by the short-circuit in the organic EL device is repaired by irradiating the organic EL device with the laser beam.
- The method for fabricating the organic EL device according to an aspect of the present disclosure includes: irradiating an organic EL device having a defective portion with a laser beam; measuring first luminance of light emitted from the organic EL device after the organic EL device is irradiated with the laser beam, while supplying, to the organic EL device, a first amount of current with which the organic EL device in a normal state would emit light having luminance corresponding to a first grayscale level smaller than a reference grayscale level; re-irradiating the organic EL device with the laser beam when the first luminance measured in the measuring is smaller than a determination threshold; and measuring second luminance of light emitted from the organic EL device when the first luminance measured in the measuring is greater than or equal to the determination threshold, while supplying, to the organic EL device, a second amount of current with which the organic EL device in the normal state would emit light having luminance corresponding to a second grayscale level greater than or equal to the reference grayscale level.
- According to the method for fabricating the organic EL device, luminance of the light in the low grayscale level is measured prior to the conventional test in which the luminance of the light in the high grayscale level is measured. Accordingly, it is possible to accurately find the light-emitting device on which the laser repairing is incomplete, and repairing the device.
- In the method for fabricating the organic EL device, the determination threshold for the first luminance may be 50% of luminance corresponding to the first grayscale level of the light emitted from the organic EL device in the normal state.
- The organic EL device having luminance of the light less than half the luminance of the normal organic EL device is especially likely to be recognized by the user. Accordingly, it is effective to select such an organic EL device and attempt the re-repair by the laser re-irradiation.
- In the method for fabricating the organic EL device, the first grayscale level may be a grayscale level corresponding to the light emitted from the organic EL device in the normal state having a luminance of 1 cd/m2.
- The
luminance 1 cd/m2 of the light emitted is an example of an upper limit value of the luminance substantially recognized as black by the user, and the user recognizes light with any luminance lower than or equal to 1 cd/m2 as black. - Accordingly, in the grayscale level with which the normal organic EL device would emit light having luminance of 1 cd/m2, if the luminance of the light emitted from the organic EL device after repair is recovered to 50% of the normal luminance, that is, at 0.5 cd/m2, it is acceptable to have insufficient luminance of light emitted from the repaired organic EL device in a lower grayscale level which is simply recognized as black by the user.
- Note that, the upper limit value of the luminance substantially recognized as black uniformly by the user significantly differs depending on the capacity, usage, and use environment of the display apparatus including the organic EL panel incorporated therein. Accordingly, the specific value of the first grayscale level should be appropriately selected depending on the capacity, usage, and use environment of the display apparatus.
- In the method for fabricating the organic EL device, the second grayscale level may be a grayscale level around a maximum grayscale level of the organic EL device.
- The high-grayscale level light-emission test performed near the maximum grayscale level checks whether the maximum light emission luminance greater than or equal to the acceptable threshold is restored in the organic EL device after the laser irradiation, and also serves as a tolerance test for checking whether or not the tolerance of the organic EL device is degraded by the laser irradiation. Accordingly, this is significantly helpful for simplifying and increasing the efficiency of the repair process.
- The following shall describe the method for fabricating the organic EL device according to the embodiment and the organic EL device fabricated by the fabrication method shall be described with reference to the drawings. Note that, in the following description, the same reference numerals are assigned to the same or corresponding elements throughout the drawings, and overlapping description for these elements is omitted.
- Device Configuration
-
FIG. 1 is a cross-sectional schematic diagram according to theembodiment 1. Theorganic EL device 1 illustrated inFIG. 1 is an organic functional device including an organic layer having an anode, a cathode, and a light-emitting layer disposed between the anode and the cathode. - As illustrated in
FIG. 1 , theorganic EL device 1 includes aplanarizing film 10, ananode 11, ahole injection layer 12, a light-emittinglayer 13, abank 14, anelectron injection layer 15, acathode 16, a thin-film sealing layer 17, a sealingresin layer 19, and atransparent glass 18 provided above atransparent glass 9. - The
anode 11 and thecathode 16 correspond to the lower electrode layer and the upper electrode layer according to the present disclosure, respectively. Thehole injection layer 12, the light-emittinglayer 13, and theelectron injection layer 15 correspond to the organic layer according to the present disclosure. -
Transparent glasses - The
planarizing film 10 is made of an insulating organic material, and is formed on a substrate including driving thin-film transistors (TFT). - The
anode 11 receives holes, that is, a flow of current from an external circuit, and formed of a reflective electrode made of Al, a silver alloy APC, or others stacked on theplanarizing film 10. The thickness of a reflective electrode is 10 nm to 40 nm, for example. Note that, theanode 11 may be a two-layered structure formed of indium tin oxide (ITO), a silver alloy APC, and others, for example. As illustrated above, by forming theanode 11 with a highly reflective material such as APC, the irradiated laser beam is reflected on the highly reflective metal. Accordingly, it is possible to focus the laser beam on a layer to be focused highly efficiently. - The
hole injection layer 12 is a layer having a hole injecting material as a major component. The hole injecting material is a material having a function for stably injecting holes injected from the side of theanode 11 into the light-emittinglayer 13, or supporting the generation of the holes and injecting the holes on the light-emittinglayer 13. For example, compounds such as Poly (3, 4-ethylenedioxythiophene) (PEDOT) and aniline have been used. - The light-emitting
layer 13 is a layer which emits light by an application of a voltage between theanode 11 and thecathode 16, and is a stacked structure including a lower layer, α-NPD(Bis[N-(1-naphthyl)-N-phenyl]benzidine) and an upper layer, Alq3(tris-(8-hydroxyquinoline)aluminum). - The
electron injection layer 15 is a layer having an electron injecting material as a major component. The material having electron injecting property is a material having a function for injecting the electrons injected from thecathode 16 stably, or supporting the generation of the electrodes and injecting the electrons into the light-emittinglayer 13, and Poly(p-phenylene vinylene) (PPV) is used, for example. - The
cathode 16 receives supply of electrons, that is, is a cathode from which current flows to the external circuit, and has a stacked structure of ITO which is a transparent metal oxide, for example. Thecathode 16 may be formed as a transparent electrode out of Mg, Ag, and others. The thickness of the electrode is 10 nm to 40 nm, for example. - The
bank 14 is a wall for separating the light-emittinglayer 13 for each light-emittingregion 2 allowing individual driving for the light emission, and is made of a photo-sensitive resin. - The thin-
film sealing layer 17 is made of silicon nitride, and has a function of blocking the light-emittinglayer 13 and the cathode from moisture and oxygen. This is for preventing the light-emittinglayer 13 itself and thecathode 16 from being degraded (being oxidized) by the exposure to the moisture and oxygen. - The sealing
resin layer 19 is an acrylic or epoxy resin, and has a function of joining a layer integrally formed on the substrate from theplanarizing film 10 to the thin-film sealing layer 17 and thetransparent glass 18. - The stacked structure of the
anode 11, the light-emittinglayer 13, and thecathode 16 is the basic configuration of theorganic EL device 1. With this configuration, when appropriate voltage is applied between theanode 11 and thecathode 16, the holes and the electrons are injected into the light-emittinglayer 13 from theanode 11 side and thecathode 16 side, respectively. With the energy generated by the injected holes and electrons re-combined in the light-emittinglayer 13, the luminescent material in the light-emittinglayer 13 is excited and emits light. - Note that, the material for the
hole injection layer 12 and theelectron injection layer 15 are not limited in the present disclosure, and a known organic material or inorganic material is used. - Furthermore, with regard to the configuration of the
organic EL device 1, the hole transport layer may be provided between thehole injection layer 12 and the light-emittinglayer 13, and an electron transport layer may be provided between theelectron injection layer 15 and the light-emittinglayer 13. Alternatively, the hole transport layer may be provided instead of thehole injection layer 12, and an electron transport layer may be provided instead of theelectron injection layer 15. The hole transport layer is a layer having a hole transporting material as a major component. Here, the hole transporting material with electron donor property is a material having a tendency to become positive ion (holes), and a property for transmitting the generated holes by charge transfer between molecules, and is a material suitable for transporting the electrons from theanode 11 to the light-emittinglayer 13. The electron transport layer is a layer having an electron transporting material as a major component. Here, the electron transporting material is a material having an electron acceptor property and tendency to become negative ion, and transmits the generated electrons by the charge transfer between molecules, and is a material suitable for transporting the charges from thecathode 16 to the light-emittinglayer 13. - Furthermore, the
organic EL device 1 may further include color filters (light-adjusting layers) for adjusting the colors of red, green, and blue, under thetransparent glass 18 to cover the light-emitting regions separated by thebank 14. - Note that, in the present disclosure, the
hole injection layer 12, the light-emittinglayer 13, and theelectron injection layer 15 are collectively referred to as theorganic layer 30. When the hole transport layer and the electron transport layer are included, these layers are also included in theorganic layer 30. The thickness of theorganic layer 30 is, for example, 100 nm to 200 nm. - Furthermore, one
organic EL device 1 is composed by aplanarizing film 10, theanode 11, theorganic layer 30, thecathode 16, the thin-film sealing layer 17, the sealingresin layer 19, and thetransparent glass 18 disposed in a light-emittingregion 2 separated by thebank 14 and can be individually controlled for light-emission. - The organic EL panel (image display panel) is composed by arranging the
organic EL device 1 in a matrix, and providing driving circuits each for controlling the light-emission from one of theorganic EL devices 1. In this Specification, a part including one organic EL device and its corresponding driving circuit in the organic EL panel is referred to as a pixel. - In the
organic EL device 1 illustrated inFIG. 1 , a conductiveforeign material 20 is included between theanode 11 and thecathode 16 in the fabrication process, and theanode 11 and thecathode 16 are short-circuited through theforeign material 20. The shorted part caused by theforeign material 20 is an example of the defective part of the light-emittingregion 2. - In addition, in order to solve (repair) the defect due to the short-circuit between the
anode 11 and thecathode 16 caused by theforeign material 20, anirradiation trace 16 a is formed by irradiation of the laser beam on a part of the cathode near theforeign material 20. The details of the repair by the irradiation of the laser beam shall be described later. -
FIG. 2 is a top view of theorganic EL device 1, and illustrates a typical example of a position of theirradiation trace 16 a in the plane, formed by the laser irradiation on the light-emittingregion 2 having a shorted part by theforeign material 20. The AA′ cross-section illustrated inFIG. 2 corresponds toFIG. 1 . - The laser beam is emitted, tracing a closed path surrounding the shorted part of the
cathode 16 due to theforeign material 20. For example, a square of 20 μm×20 μm is set in a periphery away from theforeign material 20 for approximately 10 μm, and an outline of the square may be irradiated with the laser beam. As a result, theirradiation trace 16 a illustrated inFIG. 2 is formed in thecathode 16. The resistance value of theirradiation trace 16 a is higher than the original resistance value of thecathode 16 which is not irradiated with the laser beam. - In the following description, the expression “increasing the resistance” refers to an action of irradiating a part to be irradiated with the laser beam so as to increase the resistance value of the part to be higher than the resistance value before the laser irradiation.
- Fabrication Method
- Next, a method for fabricating the
organic EL device 1 shall be described. This fabrication method includes a process for solving the malfunction caused by the defective part of theorganic EL device 1. -
FIG. 3 is a flowchart illustrating the method for fabricating theorganic EL device 1 according to the present disclosure. - First, the organic EL panel is prepared (S10). The organic EL panel includes pixels each of which includes the
organic EL device 1 and a driving circuit for driving theorganic EL device 1 arranged in a matrix. This process includes a process for stacking and forming theorganic EL device 1 included in the pixels arranged in a matrix. - Next, the entire screen of the organic EL panel prepared in step S10 is turned on, and an entire-screen lighting test for selecting an organic EL panel having no problem with the screen display property is performed (S20).
- Next, the organic EL panels selected in step S20 are tested for dark spot in the pixel and are repaired (S30).
- First, the light-emitting region for each pixel is tested, and a shorted part in which the
anode 11 and thecathode 16 are shorted in each light-emitting region is detected as a defective part (S40). - Next, the malfunction caused by the defective part detected in step S40 is repaired by laser irradiation (S50). The process in step S50 includes a recovery evaluation process which is characteristic process of the present disclosure for evaluating the organic EL device after the laser irradiation.
- The following shall describe the processes described above in further detail.
- First, the process for preparing the organic EL panel (S10) shall be described.
-
FIG. 4 is a partial cross-sectional schematic diagram of the organic EL panel prepared in the first process of the present disclosure.FIG. 4 illustrates a cross-sectional structure of theorganic EL device 1A in which theanode 11 and thecathode 16 are shorted due to theforeign material 20. - First, the
planarizing film 10 made of an insulating organic material is formed on a substrate including the TFT, and theanode 11 is subsequently formed on theplanarizing film 10. Theanode 11 is formed by depositing Al of 30 nm on theplanarizing film 10 by the sputtering method, and a subsequent patterning process using the photolithography and the wet etching. - Next, the
hole injection layer 12 is formed on theanode 11 by spin-coating the PEDOT solution including PEDOT dissolved in a solvent made of xylene. - Next, on the
hole injection layer 12, the light-emittinglayer 13 is formed by stacking α-NPD, Alq3 by the vacuum vapor deposition method. - Next, the
electron injection layer 15 is formed on the light-emittinglayer 13 by spin-coating Poly (p-phenylene vinylene) (PPV) dissolved in a solvent made of xylene or chloroform. - Subsequently, the
cathode 16 is formed without exposing, in the air, the substrate on which theelectron injection layer 15 is formed. More specifically, thecathode 16 is formed on theelectron injection layer 15 by stacking indium tin oxide (ITO) for 35 nm by the sputtering method. Here, thecathode 16 is in an amorphous state. - With the fabrication process, the organic EL device having a function as a light-emitting device is formed. Note that, between the process for forming the
anode 11 and the process for forming thehole injection layer 12, thebank 14 made of a resin with a photosensitive surface is formed at a predetermined position. - Next, the thin-
film sealing layer 17 is formed on thecathode 16; by stacking silicon nitride for 500 nm using the plasma chemical vapor deposition (CVD) method, for example. Next, the thin-film sealing layer 17 is formed in contact with the surface of thecathode 16. Thus, the requirement for the protective film is strict, and a non-oxygen inorganic material represented as the silicon nitride described above is used, for example. In addition, for example, the thin-film sealing layer 17 may be formed of an oxygen inorganic material such as silicon oxide (SixOy) and silicon oxynitride (SixOyNz), and a structure including multiple layers of the inorganic materials. Furthermore, the forming method is not limited to the plasma CVD method, and may also be other methods such as the sputtering method using argon plasma. - Next, the sealing
resin layer 19 is applied on the surface of the thin-film sealing layer 17. Subsequently, thetransparent glass 18 is provided on the sealingresin layer 19 applied. Here, the color filter (light-adjusting layer) is formed on the main surface of thetransparent glass 18. In this case, thetransparent glass 18 is provided on the sealingresin layer 19 applied, with the surface on which the color filters are formed is facing downward. Note that, the thin-film sealing layer 17, the sealingresin layer 19 and thetransparent glass 18 serve as the protective layer. - Finally, the sealing
resin layer 19 is cured by applying heat or energy line while applying pressure downward from the upper surface side of thetransparent glass 18, bonding thetransparent glass 18 and the thin-film sealing layer 17. - With the forming method described above, the
organic EL device 1A illustrated inFIG. 4 is formed. - Note that, the process for forming the
anode 11, thehole injection layer 12, the light-emittinglayer 13, theelectron injection layer 15 and thecathode 16 is not limited by the present disclosure. - Furthermore, there is a defective part due to the short-circuit in the light-emitting
region 2 in theorganic EL device 1A, that is, the shorted part between theanode 11 and thecathode 16 by theforeign material 20 mixed in the fabrication process. - Next, the entire screen lighting testing process (S20) shall be described.
- In the entire screen lighting testing process, the organic EL devices in the entire screen of the organic EL panel prepared in step S10 is turned on for lighting for testing whether or not there is a problem in the display characteristics on the screen such as uneven luminance, linear display defect, and dark spots out of acceptable level. With this process, organic EL panels without any problem are selected, and disqualified panels are used as recycled parts or discarded.
- Next, the process for specifying the defective part of the organic EL device (S40) in the defective pixel testing and the repair process for the organic EL device (S30) shall be described.
- In
FIG. 4 , theforeign material 20 remains when Al, which is the material for theanode 11 is attached on theanode 11 after theanode 11 is formed, and thehole injection layer 12, the light-emittinglayer 13, theelectron transport layer 15, and thecathode 16 are subsequently stacked thereon. The size of theforeign material 20 is, for example, approximately a diameter of 200 nm and a height of 500 nm, for example. If there is a shorted part between theanode 11 and thecathode 16 by theforeign material 20, current which is supposed to drive the light-emission flows in the shorted part. Consequently, the light-emittingregion 2 does not sufficiently emit light or emit light at all. The pixel corresponding to the light-emittingregion 2 which lost a normal light-emitting function is referred to as a defective pixel. -
FIG. 5 is an operational flowchart for describing step S40 according to the embodiment. - First, the light on the organic EL panel selected at step S20 is turned on (S41). More specifically, a reverse bias voltage is applied to all of the pixels in the organic EL panel simultaneously by the driving circuit in the organic EL panel or by an external testing apparatus connected. Here, all of the pixels are captured by a CCD camera or others at the same time.
- Subsequently, the luminance of the light emitted from each of the pixels is calculated based on the captured image in the reverse-bias voltage application period, and a pixel which is emitting light with luminance smaller than or equal to the predetermined threshold is detected as a defective pixel (S42).
- Next, the detected defective pixel is enlarged and observed (S43). More specifically, the defective pixel is observed using a photomicrographic camera, for example.
- Here, the
foreign material 20 is identified in a region of the defective pixel enlarged for observation (S44). - Next, a reverse bias voltage is applied on the defective pixel detected in step S42, and a light-emitting point emitting leakage light is identified (S45). In the normal pixel, current does not flow in the organic EL device by the reverse bias voltage. However, in the light-emitting region having a shorted part, the leakage light emitted by the leakage current is observed in the shorted part. A point emitting the leakage light in the light-emitting region is identified by an image obtained by capturing the leakage light-emitting state.
- More specifically, by driving circuits included in the organic EL panel, or by the external source meter connected, a predetermined reverse bias voltage is applied in the pixels to be tested. Subsequently, the point emitting light greater than or equal to threshold intensity in a period when a reverse bias voltage is applied is determined. Note that, since the leakage light emitted by applying a reverse bias voltage is weak, the image capturing by a CCD camera or others is performed in a completely light-shielded environment, for example. Subsequently, the intensity of light emitted from each imaging point is compared with a threshold. With this, whether or not there is leakage light-emission is determined. The leakage light emitting point is determined as described above.
- Note that, as the CCD camera, a cooled CCD camera is used, for example. With this, even when imaging weak leakage light emitted from the organic EL device, it is possible to secure a predetermined S/N ratio. Accordingly, it is possible to eliminate the noise at the time of testing, thereby improving the accuracy of detecting the point emitting the leakage light.
- Next, the position of the shorted part in the defective pixel is located by synthesizing the image of the defective pixel when the forward bias voltage is applied which is enlarged and observed at step S44, and the image of the leakage light-emitting point when the reverse-bias voltage is applied at step S45 (S46).
- Note that, in the process for locating the shorted part in step S46, the position of the shorted part is located by matching the position of the foreign material located at step S44 and the position of the leakage light-emitting point located at step S45. Alternatively, the shorted part may be located by using only the position of the foreign material or the leakage light-emitting point.
- Furthermore, detection of the light-emitting region having a shorted part is not limited to the method described above, and may be detected based on a current value by measuring a current value flowing between the
anode 11 and thecathode 16 of the organic EL device. In this case, a current value equivalent to a normal pixel is obtained when the forward bias voltage is applied, and leakage light emission is observed when the reverse-bias voltage is applied may be determined as the defective pixel. - Next, a process (S50) of repairing the malfunction caused by the defective part of the organic EL device by irradiating the organic EL device with a laser beam shall be described. The process in step S50 includes a recovery evaluation process which is characteristic process of the present disclosure for evaluating the organic EL device after the laser irradiation.
-
FIG. 6 is an operational flowchart for describing step S50 according to the embodiment.FIG. 7 is a structural diagram illustrating an example of a system for performing laser repairing according to the embodiment. The system illustrated inFIG. 7 includes alaser oscillator 101, aCCD cameral 103, alighting 104, and astage 105. Furthermore, the organic EL panel having theorganic EL device 1A, an item in fabrication process, is disposed and fixed on thestage 105. - The
laser oscillator 101 can emit a laser beam having an ultrashort pulse with a wavelength of 750 nm to 1600 nm, output energy of 1 μJ to 30 μJ, and a pulse width in the order of a few femtoseconds to a few picoseconds. The ultrashort pulse laser includes a femtosecond laser, for example, and a suitable range of the pulse is 100 fs to 20 ps. By the irradiation of the ultrashort pulse laser, it is possible to increase the resistance of the component of the anode or cathode in the amorphous state. Furthermore, the resistance of the transparent conductive material which cannot be easily processed using the other laser can be increased. - In this embodiment, the resistance in a part of the
cathode 16 is increased by focusing the laser on thecathode 16. Here, the range of the output energy capable of increasing the resistance of the part of thecathode 16 is dependent on the wavelength of the laser beam emitted. When thecathode 16 is irradiated with a laser having excessive output energy, the laser beam reaches theorganic layer 30 provided under thecathode 16, damaging theorganic layer 30. If thecathode 16 is irradiated with a laser beam having insufficient energy, the resistance in thecathode 16 does not increase. If thecathode 16 is irradiated with a laser beam having a pulse width greater than or equal to 20 psec, theorganic layer 30 will be damaged. In view of the above, in the range of the laser wavelength, and by irradiating the organic EL device with a laser having a pulse width in a range of the pulse width allows increase the resistance in part of thecathode 16 easily. - The
CCD camera 103 captures the organic EL panel on thestage 105. - The
lighting 104 emits supplemental light necessary for imaging the organic EL panel. - The
stage 105 is used for placing the organic EL panel, is movable in the height direction Z, and the planar directions X and Y, and positions an area of the organic EL device to be irradiated with the laser. - The following shall specifically describe the repair process (S50) with reference to the flowchart in
FIG. 6 . - First, the height of the part of the organic EL device to be irradiated with laser (irradiated part) is set (S51). More specifically, the position of the
stage 105 in the depth direction Z is adjusted such that the focus of the laser beam is on thecathode 16 in theorganic EL device 1A. - Next, the irradiation line of the laser beam is set (S52). More specifically, as illustrated in
FIG. 2 , the irradiation line in the plane to be traced by the laser beam is set in a position defined as a closed path surrounding the shorted part of thecathode 16 due to the foreign material 20 (for example, on the outline of a square of 20 μm×20 μm defined at a periphery approximately 10 μm away from the foreign material in the cathode 16). The area surrounded by the irradiation line is smaller than or equal to one third of the area of the light-emittingregion 2, for example. In addition, in order to securely form a closed path with the irradiation trace, a part of the irradiation line near the starting point and a part of the irradiation line near the end point may cross each other. - Next, the first laser irradiation process of irradiating the organic EL panel with a laser is performed, tracing the irradiation line set in step S52 at the height of the
stage 105 determined at step S51 (S53). - Next, with the laser irradiation described above, the organic EL panel is evaluated as to whether or not the light-emitting function of the defective pixel has recovered (S54).
- In the recovery evaluation process at step S54, first, a low grayscale level light-emission checking process of measuring luminance of light emitted from the organic EL device after the organic EL device is irradiated with the laser beam, while supplying, to the organic EL device, a first amount of current with which the organic EL device in a normal state would emit light having luminance corresponding to a first grayscale level smaller than a reference grayscale level is performed (S55), and if the measured luminance is smaller than a threshold for determination (No in S56), the process returns to step S53, and the second laser irradiation process for irradiating the organic EL device with a laser beam again is performed.
- If the luminance measured at step S55 is greater than or equal to the determination threshold (Yes in S56), a high grayscale level light-emission checking process of measuring luminance of light emitted from the organic EL device when the luminance measured in step S55 is greater than or equal to the determination threshold, while supplying, to the organic EL device, a second amount of current with which the organic EL device in the normal state would emit light having luminance corresponding to a second grayscale level greater than or equal to the reference grayscale level is performed (S57). The high grayscale level light-emission checking process is performed in the same manner as a typical conventional recovery checking test.
- Examples of the effects of the recovery evaluation process described above, and a suitable example of the first grayscale level, the second grayscale level, and the threshold for the determination shall be described with reference to
FIG. 8 (a) and (b), andFIG. 9A andFIG. 9B . - As described above, the inventors noticed that there is an organic EL device which emits light with extremely low luminance when a luminance signal of lower grayscale level is given, even if the conventional high-grayscale level light emission test confirms that the maximum acceptable light-emission luminance has been recovered.
- In order to consider the measures on the problem, the inventors conducted an experiment for measuring the light-emitting characteristics of multiple organic EL devices determined as emitting light having acceptable maximum luminance after laser irradiation. In this experiment, current corresponding to every one of 256 grayscale levels from 0 (light off) to 255 (maximum luminance) was sequentially supplied to the organic EL device, and the luminance corresponding to each grayscale level was measured.
-
FIG. 8 (a) is a graph illustrating an example of the light-emission characteristics of the organic EL device illustrating the states including normal, repair successful, and repair unsuccessful.FIG. 8 (b) is a graph illustrating the low grayscale level part ofFIG. 8 (a) enlarged. - Among these graphs, the graph indicated as normal indicates the designed luminance value of the pixel emitting light by a supply of the current corresponding to each grayscale level if the organic EL device is normal. The regular organic EL device without light emission malfunction caused by the short-circuit emits light mostly following the light emission property described above.
- In addition, the graphs marked as repair successful and repair unsuccessful illustrate light-emitting characteristics measured on an organic EL device with recovered luminance in low grayscale level and light-emitting characteristics measured on an organic EL device with non-recovered low grayscale level luminance, among the organic EL devices with acceptable maximum light emission luminance recovered.
- As illustrated in
FIG. 8 (a), with a grayscale level greater than or equal tolevel 140, both the organic EL devices whose repair is successful or unsuccessful indicate the same light-emission characteristics. Although the illustration of the light-emission characteristics greater than or equal to 200 cd/m2 is omitted, it is confirmed that the organic EL device emits light having luminance greater than or equal to half the luminance of the normal EL device when the current corresponding to the maximum grayscale level is supplied. Accordingly, the organic EL devices pass the high-grayscale level light-emission test in which the threshold for the determination is set to be 50% of the normal luminance. However, as illustrated inFIG. 8 (b), when the grayscale level is lower than or equal tolevel 50, the luminance of the light emitted from the organic EL device whose repair was unsuccessful remains in less than half the luminance of the normal organic EL device. - The inventors assumed that the cause of the difference in the light-emission characteristics is in the difference in the level of increased resistance at the shorted part by the laser irradiation, and considered the following issues.
-
FIG. 9A is an equivalent circuit diagram of the organic EL device having a shorted part by the foreign material, andFIG. 9B is a graph illustrating an example of the current-voltage characteristics of the organic EL device having a shorted part caused by the foreign material. - In
FIG. 9A andFIG. 9B , the thick line illustrates current flowing in theorganic layer 30. Theorganic layer 30 has non-linear current-voltage characteristics as a diode. The fine lines illustrate current flowing in the shorted part caused by theforeign material 20. The shorted part has a resistance value dependent on the resistance value of theirradiation trace 16 a after the laser irradiation. Here, the graphs in the fine broken line and the fine solid line are models for a case in which the increased resistance of the shorted part by the laser irradiation is insufficient (repair unsuccessful) and sufficient (repair successful). - As illustrated in
FIG. 9B , when the organic EL device is driven by large current, that is, when the organic EL device emits light in high grayscale level, the current flowing in theorganic layer 30 is dominant, and thus the insufficient resistance on the shorted part is not evident. On the other hand, when the organic EL device is driven at small current, that is, when the organic EL device emits light in a low grayscale level, the current flowing in the shorted part is dominant. Consequently, the organic EL device in which the resistance at the shorted part is not sufficiently increased does not emit light at all or emits light in extremely low luminance. This aspect matches the phenomenon found by the inventors very well. - Based on the speculation described above, the inventors devised a method in which the repair method described in the flowchart of
FIG. 6 . More specifically, first, the light-emission checking at low grayscale level is performed on the organic EL device after the laser irradiation. When the desired luminance is not obtained at the low-grayscale level light emission checking, the high-grayscale level light emission checking which is the typical recovery checking test is performed after increasing the resistance values of the irradiation trace. - As illustrated in
FIG. 6 , when irradiating the laser at step S53, no light is emitted from the defective pixel when the forward bias voltage is applied until the tracing of the irradiation line by the laser beam is complete and the irradiation trace becomes a closed path. - Subsequently, when the tracing of the irradiation line is complete, although the region surrounded by the irradiation trace does not emit light by the application of the forward bias voltage, the other light emission from the other region can be observed. When this phenomenon is observed on the entire organic EL light-emitting panel, even if the region which is a square of 20 μm×20 μm does not emit light, the non-light emitting region is not visualized, thereby solving the malfunction in light emission caused by the short-circuit.
- Subsequently, in the recovery evaluation process at step S54, prior to the conventional high grayscale level light-emission checking for measuring the high-grayscale level light-emission luminance (S57), the low-grayscale level light-emission checking in which the luminance of emitted light in low grayscale level is performed (S55). If the measured luminance is lower than the threshold for the determination (No in S56), the process returns to step S53, and an attempt to increase the resistance in the device by irradiating the device with the laser beam again is performed. Accordingly, the possibility of missing the light-emission defect in the low grayscale level is reduced compared to the conventional technology, allowing a repair of the organic EL device with higher accuracy.
- Here, the threshold used for the determination at step S56 may be 50% of the luminance corresponding to the first grayscale level when the organic EL device is normal. The organic EL device having a luminance of the light less than half the luminance of the normal organic EL device is especially likely to be recognized by the user. Accordingly, it is effective to select such an organic EL device and attempt the re-repair by the laser re-irradiation.
- The first grayscale level may be the first grayscale level is a grayscale level corresponding to the light emitted from the organic EL device in the normal state having a luminance of 1 cd/m2 (for example, level 26). The
luminance 1 cd/m2 of the light emitted is an example of the upper limit value of the luminance substantially recognized as black by the user, and the user recognizes light with any luminance lower than or equal to 1 cd/m2 as black. Accordingly, in the grayscale level with which the normal organic EL device would emit light having luminance of 1 cd/m2, if the luminance of the light emitted from the organic EL device after repair is recovered to 50% of the normal luminance, that is, at 0.5 cd/m2, it is acceptable to have insufficient luminance of light emitted from the repaired organic EL device in a lower grayscale level which is simply recognized as black by the user. - Note that, the upper limit value of the luminance substantially recognized as black uniformly by the user significantly differs depending on the capacity, usage, and use environment of the display apparatus including the organic EL panel incorporated therein. Accordingly, the specific value of the first grayscale level should be appropriately selected depending on the capacity, usage, and use environment of the display apparatus.
- The second grayscale level may be the grayscale level near the maximum grayscale level of the organic EL device. The high-grayscale level light-emission test performed near the maximum grayscale level checks whether the maximum light emission luminance greater than or equal to the acceptable threshold is restored in the organic EL device after the laser irradiation, and also serves as a tolerance test for checking whether or not the tolerance of the organic EL device is damaged by the laser irradiation. Accordingly, this is significantly helpful for simplifying and increasing the efficiency of the repair process.
- Although only some exemplary embodiments of the present disclosure have been described in detail above, those skilled in the art will readily appreciate that many modifications are possible in the exemplary embodiments without materially departing from the novel teachings and advantages of the present invention. Accordingly, all such modifications are intended to be included within the scope of the present disclosure.
- For example, in the embodiment described above, a configuration in which the lower electrode is the anode and the upper electrode is the cathode is described. However, the lower electrode may be the cathode, and the upper electrode may be the anode. In addition, the planarizing film, the anode, the hole injection layer, the light-emitting layer, the bank, the electron injection layer, the cathode, the thin-film sealing layer, the sealing resin layer and the transparent glass included in the organic EL device may not be limited to the configuration described the embodiment. The materials, the configurations, and the forming methods may be changed. For example, the hole transport layer may be provided between the hole injection layer and the light-emitting layer, and the electron transport layer may be provided between the electron injection layer and the light emitting layer. Furthermore, the color filters for adjusting the colors in red, green, and blue may be provided under the transparent glass to cover the light-emitting regions separated by the bank. The femtosecond laser described above can pass through the color filters. Accordingly, it is possible to solve the short-circuit through the color filters.
- Furthermore, the irradiation position of the laser may not be limited to the embodiment described above, but may be set in a predetermined range including the foreign material or shorted part, or only on the foreign material or the shorted part. Alternatively, the irradiation position may be set to surround the periphery of the foreign material or the shorted part. Furthermore, the laser irradiation may not be limited on the cathode, but may be performed on the anode.
- The present disclosure is suitable for fabricating the thin-flat television system having the organic EL device illustrated in
FIG. 10 , for example. - The organic EL device and the method for fabricating the organic EL device according to the present disclosure is applicable to the technology fields such as flat-panel television or displays for personal computers, where there is a demand for increased size of the screen and a higher resolution.
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Cited By (7)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
US20140154818A1 (en) * | 2012-06-14 | 2014-06-05 | Panasonic Corporation | Defect detection method, method for repairing organic el element, and organic el display panel |
US8765494B2 (en) * | 2011-09-15 | 2014-07-01 | Panasonic Corporation | Method for fabricating organic EL device and method for evaluating organic EL device |
US9040967B2 (en) | 2010-12-01 | 2015-05-26 | Joled Inc. | Method for manufacturing organic electroluminescence device and organic electroluminescence device |
US9853216B2 (en) | 2013-05-23 | 2017-12-26 | Joled Inc. | Method and apparatus for correcting bright spots in an OLED by laser |
US9882175B2 (en) | 2014-06-12 | 2018-01-30 | Joled Inc. | Method for manufacturing display panel |
US10678076B2 (en) * | 2017-01-30 | 2020-06-09 | Facebook Technologies, Llc | Treating display panel using laser |
US11910696B2 (en) * | 2020-11-09 | 2024-02-20 | Jdi Design And Development G.K. | Self-luminous display panel and self-luminous display panel manufacturing method |
Families Citing this family (1)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
JP2016099505A (en) | 2014-11-21 | 2016-05-30 | 株式会社Joled | Display device |
Citations (6)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
US20060274021A1 (en) * | 2005-06-07 | 2006-12-07 | Samsung Electronics Co., Ltd. | Display device |
US7838858B2 (en) * | 2005-05-31 | 2010-11-23 | Nikon Corporation | Evaluation system and method of a search operation that detects a detection subject on an object |
US8197334B2 (en) * | 2007-10-29 | 2012-06-12 | Igt | Circulating data card apparatus and management system |
US20120320294A1 (en) * | 2008-01-21 | 2012-12-20 | Samsung Display Co., Ltd. | Liquid crystal display |
US8531477B2 (en) * | 2010-09-07 | 2013-09-10 | ARMSTEL Holding, LLC | Devices and methods for providing an enhanced monochromatic display |
US8552299B2 (en) * | 2008-03-05 | 2013-10-08 | The Board Of Trustees Of The University Of Illinois | Stretchable and foldable electronic devices |
Family Cites Families (12)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
JPH0834125B2 (en) * | 1988-12-01 | 1996-03-29 | 松下電器産業株式会社 | Method for manufacturing multicolor thin film EL device |
TWI223569B (en) | 2002-03-20 | 2004-11-01 | Sanyo Electric Co | Method for reducing light quantity of organic EL panel and organic EL panel |
JP4270891B2 (en) * | 2003-01-21 | 2009-06-03 | 三洋電機株式会社 | Laser repair method for EL display device |
JP2005276600A (en) | 2004-03-24 | 2005-10-06 | Hitachi Ltd | Manufacturing method of organic electroluminescent display device |
JP2006323032A (en) | 2005-05-17 | 2006-11-30 | Sony Corp | Apparatus and method for repairing defective pixel of flat panel display device |
JP2007042498A (en) * | 2005-08-04 | 2007-02-15 | Aitesu:Kk | Repairing method of organic el by laser and repairing device by laser |
JP2008034264A (en) * | 2006-07-28 | 2008-02-14 | Toshiba Matsushita Display Technology Co Ltd | Laser repairing method of el display device, laser repair device of el display device, program, and recording medium |
CN102227952B (en) | 2009-04-24 | 2014-01-22 | 松下电器产业株式会社 | Method for manufacturing organic el display |
JP2011090889A (en) * | 2009-10-22 | 2011-05-06 | Panasonic Corp | Manufacturing method of organic el display device, its inspection device, and inspection method |
JP2011134490A (en) * | 2009-12-22 | 2011-07-07 | Hitachi High-Technologies Corp | Facilities and method for correcting organic el display panel |
WO2012140691A1 (en) | 2011-04-12 | 2012-10-18 | パナソニック株式会社 | Method for manufacturing organic el element and method for setting focal point of laser |
WO2013038454A1 (en) * | 2011-09-15 | 2013-03-21 | パナソニック株式会社 | Organic el element manufacturing method and evaluation method |
-
2011
- 2011-09-15 WO PCT/JP2011/005226 patent/WO2013038454A1/en active Application Filing
- 2011-09-15 JP JP2012541666A patent/JP5654037B2/en active Active
-
2012
- 2012-12-04 US US13/693,335 patent/US8765494B2/en not_active Expired - Fee Related
Patent Citations (6)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
US7838858B2 (en) * | 2005-05-31 | 2010-11-23 | Nikon Corporation | Evaluation system and method of a search operation that detects a detection subject on an object |
US20060274021A1 (en) * | 2005-06-07 | 2006-12-07 | Samsung Electronics Co., Ltd. | Display device |
US8197334B2 (en) * | 2007-10-29 | 2012-06-12 | Igt | Circulating data card apparatus and management system |
US20120320294A1 (en) * | 2008-01-21 | 2012-12-20 | Samsung Display Co., Ltd. | Liquid crystal display |
US8552299B2 (en) * | 2008-03-05 | 2013-10-08 | The Board Of Trustees Of The University Of Illinois | Stretchable and foldable electronic devices |
US8531477B2 (en) * | 2010-09-07 | 2013-09-10 | ARMSTEL Holding, LLC | Devices and methods for providing an enhanced monochromatic display |
Cited By (8)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
US9040967B2 (en) | 2010-12-01 | 2015-05-26 | Joled Inc. | Method for manufacturing organic electroluminescence device and organic electroluminescence device |
US8765494B2 (en) * | 2011-09-15 | 2014-07-01 | Panasonic Corporation | Method for fabricating organic EL device and method for evaluating organic EL device |
US20140154818A1 (en) * | 2012-06-14 | 2014-06-05 | Panasonic Corporation | Defect detection method, method for repairing organic el element, and organic el display panel |
US9121914B2 (en) * | 2012-06-14 | 2015-09-01 | Joled Inc. | Defect detection method, method for repairing organic EL element, and organic EL display panel |
US9853216B2 (en) | 2013-05-23 | 2017-12-26 | Joled Inc. | Method and apparatus for correcting bright spots in an OLED by laser |
US9882175B2 (en) | 2014-06-12 | 2018-01-30 | Joled Inc. | Method for manufacturing display panel |
US10678076B2 (en) * | 2017-01-30 | 2020-06-09 | Facebook Technologies, Llc | Treating display panel using laser |
US11910696B2 (en) * | 2020-11-09 | 2024-02-20 | Jdi Design And Development G.K. | Self-luminous display panel and self-luminous display panel manufacturing method |
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JPWO2013038454A1 (en) | 2015-03-23 |
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JP5654037B2 (en) | 2015-01-14 |
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