US20140093419A1 - Mold made of nickel-phosphorus alloy - Google Patents

Mold made of nickel-phosphorus alloy Download PDF

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Publication number
US20140093419A1
US20140093419A1 US13/727,465 US201213727465A US2014093419A1 US 20140093419 A1 US20140093419 A1 US 20140093419A1 US 201213727465 A US201213727465 A US 201213727465A US 2014093419 A1 US2014093419 A1 US 2014093419A1
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Prior art keywords
nickel
phosphorus
mold
phosphorus alloy
alloy
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Abandoned
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US13/727,465
Inventor
Zih-Wei Wang
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Hon Hai Precision Industry Co Ltd
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Hon Hai Precision Industry Co Ltd
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Assigned to HON HAI PRECISION INDUSTRY CO., LTD. reassignment HON HAI PRECISION INDUSTRY CO., LTD. ASSIGNMENT OF ASSIGNORS INTEREST (SEE DOCUMENT FOR DETAILS). Assignors: WANG, ZIH-WEI
Publication of US20140093419A1 publication Critical patent/US20140093419A1/en
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    • CCHEMISTRY; METALLURGY
    • C22METALLURGY; FERROUS OR NON-FERROUS ALLOYS; TREATMENT OF ALLOYS OR NON-FERROUS METALS
    • C22CALLOYS
    • C22C19/00Alloys based on nickel or cobalt

Definitions

  • the present disclosure relates to alloy materials, and particularly, to a nickel-phosphorus alloy and a mold made of the nickel-phosphorus alloy.
  • nickel-phosphorus alloys are used and manufactured as molds.
  • the nickel-phosphorus alloy includes many other kinds of metal and the percentage of the nickel element is low, a number of small defects (i.e., scratches) may be easily formed on a contact surface of the mold.
  • FIG. 1 is a cross-sectional view of part of a mold in accordance with an exemplary embodiment.
  • FIG. 2 is a microscopic view of a molding surface of the mold of FIG. 1 .
  • FIG. 3 is a microscopic view of a molding surface of a mold made of an alloy of nickel and phosphorus of related art.
  • the weight percent of the nickel element is about 86.95%, and the weight percent of the phosphorus element is about 13.05%.
  • the atomic percent of the nickel element is about 78.01%, and the atomic percent of the phosphorus element is about 21.99%.
  • the phosphorus element is non-metallic.
  • the processing characteristics of the phosphorus element in an alloy is greatly improved.
  • the machinability of the nickel-phosphorus alloy will be improved.
  • the nickel-phosphorus alloy is changed from a crystalline state to an amorphous state as the weight percent of the phosphorus element is increased.
  • the weight percent of the phosphorus element is greater than about 13%, the hardness and the abrasion resistance of the nickel-phosphorus alloy decreases.
  • the hardness, the toughness, the abrasion resistance, and the machinability of the nickel-phosphorus alloy with a crystalline state is better than the machinability of the nickel-phosphorus alloy with an amorphous state.
  • FIG. 2 shows the molding surface 11 of the mold 10 , the mold 10 being made of the nickel-phosphorus alloy of this embodiment.
  • FIG. 3 shows a molding surface of another mold, which is made of a nickel-phosphorus alloy of related art.
  • the machining traces on the molding surface of FIG. 3 are more obvious than that of FIG. 2 . That is to say, the roughness of the molding surfaces 11 of the mold 10 made of the nickel-phosphorus alloy of this embodiment is significantly less than that of the mold made of the nickel-phosphorus alloy of related art.
  • the cutting depth is about 6 ⁇ m
  • the feed rate of the tool is about 10 mm/min
  • the rotation speed of the tool is about 1100 rpm
  • the cutting edge radius is about 0.3-0.5 mm. According to a number of experiments, the machining precision of the molding surface 11 of the mold 10 will be improved by using the above parameters.

Abstract

A nickel-phosphorus alloy is consisted of nickel and phosphorus. The weight percent of the nickel element is from about 86.95% to about 87.05%. The weight percent of the phosphorus element is from about 12.95% to about 13.05%.

Description

    BACKGROUND
  • 1. Technical Field
  • The present disclosure relates to alloy materials, and particularly, to a nickel-phosphorus alloy and a mold made of the nickel-phosphorus alloy.
  • 2. Description of Related Art
  • As the hardness, the toughness, the abrasion resistance, and the processing characteristics of nickel-phosphorus alloys are better than other alloys, nickel-phosphorus alloys are used and manufactured as molds. However, as the nickel-phosphorus alloy includes many other kinds of metal and the percentage of the nickel element is low, a number of small defects (i.e., scratches) may be easily formed on a contact surface of the mold.
  • Therefore, it is desirable to provide a nickel-phosphorus alloy and a mold, which can overcome the limitations described.
  • BRIEF DESCRIPTION OF THE DRAWINGS
  • FIG. 1 is a cross-sectional view of part of a mold in accordance with an exemplary embodiment.
  • FIG. 2 is a microscopic view of a molding surface of the mold of FIG. 1.
  • FIG. 3 is a microscopic view of a molding surface of a mold made of an alloy of nickel and phosphorus of related art.
  • DETAILED DESCRIPTION
  • Embodiments of the disclosure will be described with reference to the drawings.
  • FIG. 1 shows a mold 10, according to an exemplary embodiment. The mold 10 is configured for molding a plastic element (not shown), and includes a molding surface 11. In the embodiment, the plastic element is a lens.
  • The mold 10 is made of a nickel-phosphorus alloy. The nickel-phosphorus alloy is consisted of a nickel element and a phosphorus element.
  • The weight percent of the nickel element is from about 86.95% to about 87.05%, and the weight percent of the phosphorus element is from about 12.95% to about 13.05%.
  • In order to improve the machinability of nickel-phosphorus alloys, the weight percent of the nickel element is about 86.95%, and the weight percent of the phosphorus element is about 13.05%. The atomic percent of the nickel element is about 78.01%, and the atomic percent of the phosphorus element is about 21.99%.
  • The nickel element is metallic. The mechanical strength and the ductility of the nickel element are good. The nickel element is hard to dissolve and resistant to high temperatures. The chemical stability of the nickel element is high, and it has a very low oxidation factor.
  • The phosphorus element is non-metallic. When the phosphorus element is doped into the nickel element, the processing characteristics of the phosphorus element in an alloy is greatly improved.
  • When the weight percent of the phosphorus element is lower than about 13%, the machinability of the nickel-phosphorus alloy will be improved. The nickel-phosphorus alloy is changed from a crystalline state to an amorphous state as the weight percent of the phosphorus element is increased. However, when the weight percent of the phosphorus element is greater than about 13%, the hardness and the abrasion resistance of the nickel-phosphorus alloy decreases. The hardness, the toughness, the abrasion resistance, and the machinability of the nickel-phosphorus alloy with a crystalline state is better than the machinability of the nickel-phosphorus alloy with an amorphous state.
  • In the process of manufacturing the nickel-phosphorus alloy, the nickel element and the phosphorus element are mixed according to above percentages. Then, the nickel element and the phosphorus element are heated to a molten state under a vacuum, the nickel element and the phosphorus element mix completely. The nickel-phosphorus alloy gradually crystallizes as the temperature of the compound drops.
  • FIG. 2 shows the molding surface 11 of the mold 10, the mold 10 being made of the nickel-phosphorus alloy of this embodiment. FIG. 3 shows a molding surface of another mold, which is made of a nickel-phosphorus alloy of related art.
  • The machining traces on the molding surface of FIG. 3 (of related art) are more obvious than that of FIG. 2. That is to say, the roughness of the molding surfaces 11 of the mold 10 made of the nickel-phosphorus alloy of this embodiment is significantly less than that of the mold made of the nickel-phosphorus alloy of related art.
  • In the process of machining the molding surface 11 of the mold 10 by a tool (not shown), the cutting depth is about 6 μm, the feed rate of the tool is about 10 mm/min, the rotation speed of the tool is about 1100 rpm, and the cutting edge radius is about 0.3-0.5 mm. According to a number of experiments, the machining precision of the molding surface 11 of the mold 10 will be improved by using the above parameters.
  • Particular embodiments are shown and described by way of illustration only. The principles and the features of the present disclosure may be employed in various and numerous embodiments thereof without departing from the scope of the disclosure as claimed. The above-described embodiments illustrate the scope of the disclosure but do not restrict the scope of the disclosure.

Claims (6)

What is claimed is:
1. A nickel-phosphorus alloy, consisting of:
a nickel element, the weight percent of the nickel element being from about 86.95% to about 87.05%; and
a phosphorus element, the weight percent of the phosphorus element being from about 12.95% to about 13.05%.
2. The nickel-phosphorus alloy of claim 1, wherein the weight percent of the nickel element is about 86.95%, the weight percent of the phosphorus element is about 13.05%.
3. The nickel-phosphorus alloy of claim 1, wherein the atomic percent of the nickel element is about 78.01%, and the atomic percent of the phosphorus element is about 21.99%.
4. A mold made of a nickel-phosphorus alloy, the nickel-phosphorus alloy consisting of:
a nickel element, the weight percent of the nickel element being from about 86.95% to about 87.05%; and
a phosphorus element, the weight percent of the phosphorus element being from about 12.95% to about 13.05%.
5. The mold of claim 1, wherein the weight percent of the nickel element is about 86. 95%, the weight percent of the phosphorus element is about 13.05%.
6. The mold of claim 1, wherein the atomic percent of the nickel element is about 78.01%, and the atomic percent of the phosphorus element is about 21.99%.
US13/727,465 2012-10-02 2012-12-26 Mold made of nickel-phosphorus alloy Abandoned US20140093419A1 (en)

Applications Claiming Priority (2)

Application Number Priority Date Filing Date Title
TW101136286 2012-10-02
TW101136286A TW201414857A (en) 2012-10-02 2012-10-02 Nickel-phosphorus alloy and mold cord

Publications (1)

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US20140093419A1 true US20140093419A1 (en) 2014-04-03

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TW (1) TW201414857A (en)

Cited By (2)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US9917770B1 (en) 2014-03-29 2018-03-13 Akamai Technologies, Inc. Traffic on-boarding for acceleration through out-of-band security authenticators
CN115927891A (en) * 2023-02-08 2023-04-07 承德天大钒业有限责任公司 Nickel-phosphorus intermediate alloy and preparation method thereof

Citations (17)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US3733667A (en) * 1971-09-10 1973-05-22 H Myashita Para-magnetic hard alloys
GB1376825A (en) * 1971-02-16 1974-12-11 Commissariat Energie Atomique Filters
US3892890A (en) * 1972-05-12 1975-07-01 Hitachi Ltd Process for forming carbon coatings
US4037646A (en) * 1975-06-13 1977-07-26 Sumitomo Metal Industries, Ltd. Molds for continuously casting steel
US4283225A (en) * 1978-06-05 1981-08-11 Allied Chemical Corporation Process for fabricating homogeneous, ductile brazing foils and products produced thereby
US4293089A (en) * 1979-05-08 1981-10-06 The United States Of America As Represented By The United States Department Of Energy Brazing method
US4673468A (en) * 1985-05-09 1987-06-16 Burlington Industries, Inc. Commercial nickel phosphorus electroplating
US6220497B1 (en) * 1998-01-16 2001-04-24 Xcellsis Gmbh Method for soldering microstructured sheet metal
US6406611B1 (en) * 1999-12-08 2002-06-18 University Of Alabama In Huntsville Nickel cobalt phosphorous low stress electroplating
US6500384B1 (en) * 1999-09-28 2002-12-31 Suzuki Motor Corporation Process for the hardening treatment of sintered members
US6607614B1 (en) * 1997-10-20 2003-08-19 Techmetals, Inc. Amorphous non-laminar phosphorous alloys
US6877651B2 (en) * 2002-12-02 2005-04-12 Thomas A. Sandin Method of joining ceramic or graphite to metal with an alloy having high nickel or cobalt content, alloys for joining the same, and products formed therewith
US20070183703A1 (en) * 2003-12-19 2007-08-09 Ab Skf Rolling bearing having a nickel-phosphorus coating
JP2009161801A (en) * 2007-12-28 2009-07-23 Nippon Kinzoku Co Ltd Stainless steel sheet having composite plated layer for soldering, and product manufactured by using the same
US20100200120A1 (en) * 2009-02-06 2010-08-12 Kabushiki Kaisha Toyota Chuo Kenkyusho Conductive film, corrosion-resistant conduction film, corrosion-resistant conduction Material and process for producing the same
US20100215983A1 (en) * 2009-02-20 2010-08-26 Kennametal Inc. Brazed Claddings for Cast Iron Substrates
US20110200842A1 (en) * 2008-10-17 2011-08-18 Atotech Deutschland Gmbh Stress-reduced ni-p/pd stacks for bondable wafer surfaces

Patent Citations (18)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
GB1376825A (en) * 1971-02-16 1974-12-11 Commissariat Energie Atomique Filters
US3733667A (en) * 1971-09-10 1973-05-22 H Myashita Para-magnetic hard alloys
US3892890A (en) * 1972-05-12 1975-07-01 Hitachi Ltd Process for forming carbon coatings
US4037646A (en) * 1975-06-13 1977-07-26 Sumitomo Metal Industries, Ltd. Molds for continuously casting steel
US4283225A (en) * 1978-06-05 1981-08-11 Allied Chemical Corporation Process for fabricating homogeneous, ductile brazing foils and products produced thereby
US4293089A (en) * 1979-05-08 1981-10-06 The United States Of America As Represented By The United States Department Of Energy Brazing method
US4673468A (en) * 1985-05-09 1987-06-16 Burlington Industries, Inc. Commercial nickel phosphorus electroplating
US6607614B1 (en) * 1997-10-20 2003-08-19 Techmetals, Inc. Amorphous non-laminar phosphorous alloys
US6220497B1 (en) * 1998-01-16 2001-04-24 Xcellsis Gmbh Method for soldering microstructured sheet metal
US20020164262A1 (en) * 1998-12-09 2002-11-07 University Of Alabama In Huntsville And United States Government Nickel cobalt phosphorous low stress electroplating
US6500384B1 (en) * 1999-09-28 2002-12-31 Suzuki Motor Corporation Process for the hardening treatment of sintered members
US6406611B1 (en) * 1999-12-08 2002-06-18 University Of Alabama In Huntsville Nickel cobalt phosphorous low stress electroplating
US6877651B2 (en) * 2002-12-02 2005-04-12 Thomas A. Sandin Method of joining ceramic or graphite to metal with an alloy having high nickel or cobalt content, alloys for joining the same, and products formed therewith
US20070183703A1 (en) * 2003-12-19 2007-08-09 Ab Skf Rolling bearing having a nickel-phosphorus coating
JP2009161801A (en) * 2007-12-28 2009-07-23 Nippon Kinzoku Co Ltd Stainless steel sheet having composite plated layer for soldering, and product manufactured by using the same
US20110200842A1 (en) * 2008-10-17 2011-08-18 Atotech Deutschland Gmbh Stress-reduced ni-p/pd stacks for bondable wafer surfaces
US20100200120A1 (en) * 2009-02-06 2010-08-12 Kabushiki Kaisha Toyota Chuo Kenkyusho Conductive film, corrosion-resistant conduction film, corrosion-resistant conduction Material and process for producing the same
US20100215983A1 (en) * 2009-02-20 2010-08-26 Kennametal Inc. Brazed Claddings for Cast Iron Substrates

Cited By (3)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US9917770B1 (en) 2014-03-29 2018-03-13 Akamai Technologies, Inc. Traffic on-boarding for acceleration through out-of-band security authenticators
US10038631B1 (en) 2014-03-29 2018-07-31 Akamai Technologies, Inc. Traffic on-boarding for acceleration through out-of-band security authenticators
CN115927891A (en) * 2023-02-08 2023-04-07 承德天大钒业有限责任公司 Nickel-phosphorus intermediate alloy and preparation method thereof

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Owner name: HON HAI PRECISION INDUSTRY CO., LTD., TAIWAN

Free format text: ASSIGNMENT OF ASSIGNORS INTEREST;ASSIGNOR:WANG, ZIH-WEI;REEL/FRAME:029528/0845

Effective date: 20121225

STCB Information on status: application discontinuation

Free format text: ABANDONED -- FAILURE TO RESPOND TO AN OFFICE ACTION