US2287837A - Method and apparatus for applying coating materials - Google Patents

Method and apparatus for applying coating materials Download PDF

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US2287837A
US2287837A US375432A US37543241A US2287837A US 2287837 A US2287837 A US 2287837A US 375432 A US375432 A US 375432A US 37543241 A US37543241 A US 37543241A US 2287837 A US2287837 A US 2287837A
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sheet
particles
electrodes
electrode
coating
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US375432A
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Company Granite Trust
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3M Co
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Minnesota Mining and Manufacturing Co
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    • BPERFORMING OPERATIONS; TRANSPORTING
    • B05SPRAYING OR ATOMISING IN GENERAL; APPLYING FLUENT MATERIALS TO SURFACES, IN GENERAL
    • B05DPROCESSES FOR APPLYING FLUENT MATERIALS TO SURFACES, IN GENERAL
    • B05D1/00Processes for applying liquids or other fluent materials
    • B05D1/16Flocking otherwise than by spraying
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B05SPRAYING OR ATOMISING IN GENERAL; APPLYING FLUENT MATERIALS TO SURFACES, IN GENERAL
    • B05BSPRAYING APPARATUS; ATOMISING APPARATUS; NOZZLES
    • B05B5/00Electrostatic spraying apparatus; Spraying apparatus with means for charging the spray electrically; Apparatus for spraying liquids or other fluent materials by other electric means
    • B05B5/08Plant for applying liquids or other fluent materials to objects
    • B05B5/14Plant for applying liquids or other fluent materials to objects specially adapted for coating continuously moving elongated bodies, e.g. wires, strips, pipes
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B05SPRAYING OR ATOMISING IN GENERAL; APPLYING FLUENT MATERIALS TO SURFACES, IN GENERAL
    • B05CAPPARATUS FOR APPLYING FLUENT MATERIALS TO SURFACES, IN GENERAL
    • B05C19/00Apparatus specially adapted for applying particulate materials to surfaces
    • B05C19/001Flocking
    • B05C19/002Electrostatic flocking
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B24GRINDING; POLISHING
    • B24DTOOLS FOR GRINDING, BUFFING OR SHARPENING
    • B24D11/00Constructional features of flexible abrasive materials; Special features in the manufacture of such materials
    • B24D11/001Manufacture of flexible abrasive materials
    • B24D11/005Making abrasive webs
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B44DECORATIVE ARTS
    • B44CPRODUCING DECORATIVE EFFECTS; MOSAICS; TARSIA WORK; PAPERHANGING
    • B44C1/00Processes, not specifically provided for elsewhere, for producing decorative surface effects
    • B44C1/10Applying flat materials, e.g. leaflets, pieces of fabrics
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B05SPRAYING OR ATOMISING IN GENERAL; APPLYING FLUENT MATERIALS TO SURFACES, IN GENERAL
    • B05DPROCESSES FOR APPLYING FLUENT MATERIALS TO SURFACES, IN GENERAL
    • B05D1/00Processes for applying liquids or other fluent materials
    • B05D1/007Processes for applying liquids or other fluent materials using an electrostatic field
    • YGENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y10TECHNICAL SUBJECTS COVERED BY FORMER USPC
    • Y10STECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y10S101/00Printing
    • Y10S101/37Printing employing electrostatic force

Definitions

  • This invention relates to a method of and apparatus for applying particles and various forms of comminuted materials to a base member, and to the resulting product.
  • the principal objects of the invention are to provide a novel method and apparatus for applying particles and finely divided materials, such,' for example, as flock, linters, and the like fibrous material, abrasive particles, etc., to one or more surfaces of a base member, such as a piece of sheet material; to provide means for controlling the manner and rate of application or disposition of the particles so as to obtain a uniformly coated product having predetermined characteristics; and to provide means whereby unlimited lengths of sheet material may be coated efiiciently and progressively, on either or both sides, more quickly, densely, uniformly and cheaply than by any apparatus and/or method heretofore used.
  • particles and finely divided materials such,' for example, as flock, linters, and the like fibrous material, abrasive particles, etc.
  • Another objects of the invention are to provide a strong and flexible product having a dense, homogeneous, villous finish simulating the appearance of either suede or a pile fabric; and to provide a finish of any desired density wherein the major portion of the fibers are disposed at substantially the same angle relative to the surface of the base sheet with their ends firmly embedded in an adhesive coating carried thereby.
  • the surface (or surfaces) of the base member, or article to be coated is first rendered adhesive, as for example by the application of a suitable cementitlous material, such as rubber cement, wax, paraflin, glue, or the like adhesive.
  • a suitable cementitlous material such as rubber cement, wax, paraflin, glue, or the like adhesive.
  • the base member is passed through an electrostatic field set up between one or more pairs of oppositely charged electrodes, and during its passage through the electrostatic field the particles to be applied are carried in a uniformly dispersed formation into the field either by gravity, a current of air, or in any other suitable manner.
  • the particles being conveyed to the field are charged in any suitable manner with the same charge as that of the electrode projecting them against the base member, and to this end they may be passed through a metallic screen or the like member which is connect ed in the circuit of the projecting electrode.
  • the particles upon entering the electrostatic field are projected against the adhesive surface of the base member more uniformly and efliciently, and with much greater force than would otherwise be possible.
  • the individual particles are more effectively aligned in the direction of the lines of force of the electrostatic field and, due to the increased force with which they are projected against the surface of the base member, are more deeply and firmly embedded in the adhesive surface of the base member.
  • migration of the charged particles toward the adjacent or projecting electrode is greatly minimized, if not substantially eliminated, and consequently considerable waste is eliminated and the efficiency of the method and apparatus is appreciably increased.
  • the construction and arrangement of the electrodes is such as to provide an electrostatic field of uniform flux density which extends across the path of the surface of the article to be coated and at an angle to its path of travel.
  • the position of the individual particles relative to the surface of the base member may be controlled and /or varied by adjusting the relative position of the electrodes so as to attainthe desired direction of the lines of force of the electrostatic field relative to the surface of the base member.
  • one or both of the electrodes may be adjustably mounted so that their position relative to each other may be varied.
  • the electrostatic field may be produced by a suitable source of potential such as a Kenotron or the like alternating current rectifier, a static machine, mechanical rectifier, or any other source which may be susceptible to control.
  • a suitable source of potential such as a Kenotron or the like alternating current rectifier, a static machine, mechanical rectifier, or any other source which may be susceptible to control.
  • the potential impressed upon or across the electrodes may vary within wide ranges, depending upon the character of the material to be deposited, the desired rate of deposition, etc., and the usual types of control instrumentalities may be employed to provide an electrostatic field of the desired characteristics.
  • the rate of deposition or application may be so controlled as to produce a coated product of any desired density by varying the quantity of particles supplied, the rate of travel of the base member through the field, and/or the electrical characteristics of the field, i. e., the flux density,
  • suitable means may be employed to control the rate of delivery of the particles and the rate of travel of the base member, and appropriate devices such as rheostats and various types of impedances, together with the usual indicators (ammeters, voltmeters, etc.), may be connected in the electrical circuits or circuit to provide for the adjustment necessary to obtain an electrostatic field suitable for the application or deposition of the particular type of material to be applied.
  • the adhesive surface of the sheet material or base member contains an inflammable solvent
  • suitable means may be employed to discharge or neutralize the static charge on the surface of the coated sheet before winding.
  • an ultra-violet light may be employed or, if desired, the coated sheet may be passed between electrodes connected to a high potential alternating current circuit, either of which is effective to discharge or neutralize any static charge carried by the coated sheet.
  • Fig. 1 is a diagrammatic side elevation, in section, showing one embodiment of my apparatus
  • Fig. 2 is a diagrammatic plan view of the apparatus shown in Fig. 1, the means for feeding the particles to be applied being omitted;
  • Fig. 3 is a diagrammatic side elevation, in section, showing a modified form of apparatus
  • Fig. 4 is a section on line 4-4 of Fig.
  • Fig. 5 is a schematic diagram illustrating one arrangement of the electrical connections
  • Fig. 5a is a graphic representation of a pulsating current used in connection with certain forms of the apparatus herein shown;
  • Figs. 6 to 9, inclusive are schematic diagrams illustrating other arrangements of the electrical connections
  • Fig. 10 is a schematic diagram showing the electrical connections of a Kenotron transformer
  • Fig. 11 is a fragmentary section showing a piece of fabric before the application of an adhesive coating
  • Fig. 12 is a fragmentary section showing the fabric after the application of the adhesive coat- Figs. 13 to 16, inclusive, are enlarged fragmentary sections showing difierent specimens of sheet material after being coated in accordance with the present invention
  • Fig. 17 is a horizontal view with parts shown in section of another modified form of apparatus.
  • Fig. 18 is a plan view of the apparatus shown in Fi 7:
  • Figs, 19 and 20 are horizontal views, with parts shown in section of further modified forms of apparatus.
  • the embodiment shown in Figs. 1 and 2 comprises a coating apparatus III, a deposition apparatus designated by the numeral H, and a winding mechanism II.
  • the coating apparatus may be of any type suitable for applying a coating of adhesive such as rubber cement, wax, glue, parafi'in, or the like cementitious material to one or both surfaces of a base member or sheet material S, and as here shown comprises a tank'or trough l9 having guide rolls l6, I1, 20, 2
  • the temperature and fluidity of the bath 23 may be controlled in any suitable manner as by steam coils 26.
  • 2 may be of any conventional form and is here shown as comprising a guide roll l3, a winding drum l4, and a reel I5, upon which the coated sheet material is wound.
  • Suitable mean (not o y be provided to regulate the speed of the winding drum l4 and thus control the rate of travel of the sheet material S,
  • the deposition apparatus comprises a boxlike structure or housing preferably having uprights or walls of suitable electrical non-conducting material which define the deposition zone or chamber 30, the top of which may be open as shown in Fig. 1.
  • and 32 are provided with vertically extending slots or openings 33 and 34, respectively, through which the sheet material S may be conducted into and out of the zone or chamber 30, and guide rolls 35, 36, 31 and 38 are provided to support the sheet S for movement along a predetermined path through the deposition zone or chamber 30.
  • , .2 and 43 are mounted in pairs, each electrode comprising an elongate metallic bar secured to a suitable support and having a series of pointed members or prongs secured thereto and arranged as shown in Fig. 2.
  • the electrodes are arranged in pairs 40, 4
  • the elements of each pair are disposed on opposite Sides of the path of travel of the sheet S and are preferably inclined at an angle to its line of travel so as to provide an electrostatic field which extends diagonally across the path of movement of the sheet S. The purpose of this inclined arrangement is to insure a more even coating when the comminuted material is fed to the electrostatic field from the top.
  • Suitable means are provided to conduct the material to be deposited on the sheet S into the electrostatic fields set up between each pair of electrodes and to this end hoppers 50 and 5
  • these screens may be integral with the the density of the coating applied to the sheet material may be varied as desired,
  • FIG. 3 and 4 is a preferred form of deposition apparatus and includes all the essential elements of the apparatus shown in the previously described embodiment.
  • a pulsating current such as may be derived from a two-tube Kenotron rectifier, or a continuous (non-pulsating) current such as may be derived from a static machine, mechanical rectifier with a suitable condenser, a high voltage generator, or the like, the arrangement shown in Figs. 6 to 9 being particularly suitable for use with a pulsating current.
  • a pulsating current such as may be derived from a two-tube Kenotron rectifier, or a continuous (non-pulsating) current such as may be derived from a static machine, mechanical rectifier with a suitable condenser, a high voltage generator, or the like, the arrangement shown in Figs. 6 to 9 being particularly suitable for use with a pulsating current.
  • the electrodes 40 and 43 are connected to each other by a conductor 55 and by a conductor 56 to a suitable source of potential, here shown as a Kenotron rectifier designated generally by the numeral 60.
  • and 42 are connected to each other by a conductor 51 and to the ground by a conductor 58.
  • the conductors 55 and 55 are preferably connected to the negative terminal of the Kenotron 60 or other source of potential and its positive terminal may be grounded by means of conductor 53 or connected to the positive terminal of the source of potential, as desired.
  • the main circuit comprising the conductor 59, the ground and conductor 58, at which point the main circuit branches into two circuits, one of which comprises electrodes 42 and 43 and the conductor 55, the second branch circuit comprising the conductor 51 and electrodes 4
  • the conductor 56 connects the branch circuits to the negative terminal of the Kenotron and thus completes the main circuit from the Kenotron to the electrodes.
  • the screens 52 and 53 may be connected to the electrodes 40 and 43, respectively, so that the particles discharged into the electrostatic field are first given a negative charge. 52 and 53 are preferably positioned so that the charged particles are delivered into that portion of the electrostatic field between the projecting electrode and the adjacent surface of the sheet to be coated.
  • electrodes 40 and 42 are connected one to the negative ter-
  • this arrange- Y ment is used in conjunction with the apparatus ground or to the positive terminal of the source of potential by conductors 5i and 58, respectively, and the electrodes 4
  • These electrodes and the bar 65 constitute, in effect, a unit which acts as a condenser and which builds up its charge as the potential increases from zero to maximum and discharges through the electrodes 4
  • and 43 are connected to each other by a conductor 62 which is connected to one terminal of a condenser 83, the other terminal of the condenser being grounded.
  • the flow of current through the circuit as the potential increases from zero to maximum is from electrode 42 to 43 and from electrode 4
  • and 43 become fully charged so that when the potential drops from maximum to zero, there is a discharge from electrodes 4
  • Either of the arrangements shown in Figs. 5, 6 and '1 may be used with the apparatus shown in Figs. 1 to 4 in coating either or both sides of the sheet S.
  • the arrangement shown in Fig. 8 comprises a single pair of electrodes 40 and 4
  • This arrangement is particularly suitable where only one side of the sheet S isto be coated.
  • Fig. 9 The arrangement shown in Fig. 9 is substantially the same as that shown in Fig. '1 except that instead of using two pairs of electrodes. four pairs, 4040 4
  • Fig. 10 is shown a preferred form of electrical connections which affords an efiective means of controlling the characteristics of the electrostatic field when an alternating current rectifier is used as a source of potential.
  • the numerals 66 and 61 designate the alternating current power supply lines which are connected to the terminals of the primary windings 58 and 69 of a main transformer 10 and a filament transformer 1
  • Rheostats 12 and 13 are connected in the respective circuits so as to control their outputs.
  • One terminal of the secondary winding 14 of the main transformer 10 is. grounded by means of the conductor 59 (see also Figs.
  • the output of the rectifier may be accurately controlled by adjusting the rheostats l2 and I3 and thus the electrostatic fields set up between the electrodes may be varied so as to attain the desired strength, density, etc.
  • the sheet material 5 such as a piece of fabric 10 (Fig. 11)
  • Fig. 12
  • adhesive such as glue, paraffin, rubber cement, wax or the like
  • the rheostats I2 and 13 are adjusted to produce the desired potential across the electrodes and thus establish an electrostatic field ofthe desired strength and intensity.
  • the material to be applied is fed from the hoppers 50 and at a predetermined rate and after passing through the screens 52 and 53 where the individual particles receive a negative charge, they are then carried by gravity into the electrostatic field.
  • material such as flock, linters and the like fibers, as well as the various forms of abrasive material such as carborundum, pumice, tripoli, etc.
  • the individual particles upon entering the electrostatic field due to their elongate nature, become aligned in the direction of the electrostatic lines of force and are uniformly projected or bombarded against the adhesive surface of the sheet S so that their ends are deeply and firmly embedded in the adhesive coating at substantially the same angle and their projecting portions are disposed in substantial parallelism relative to each other.
  • the individual particles Due to the initial charge imparted to the particles, they tend to repel each other and become dispersed so that upon being projected against the adhesive surface of the sheet S the individual particles are spaced relatively to each other. As the individual particles align themselves with their major axes coinciding with the direction of the electrostatic lines of force, they may be applied to the sheet S so that their major axes are disposed at any desired angle relative to the surface of the sheet and consequently a greater number of particles per unit area may be applied to the sheet and with greater uniformity than is otherwise possible.
  • sheet S After having received a coating of particles on one or both surfaces, sheet S is guided out of the deposition zone and passed between a pair of ultra-violet lights L and L' or other suitable means operative to discharge or neutralize the static charge carried by the coated surface without causing sparking. After removing the static charge on the sheet, it is then wound up on the reel l5. During both the coating and deposition operations the sheet S is held under slight tension by the pull of the winding drum and reel.
  • the density of the coating may be varied, as desired, by varying either the rate of travel of the sheet S, the rate of delivery of the particles from the hoppers 50 and 5
  • a potential of the order of 15,000 to 25,000 vo";s may be used, although it is preferred to use potentials from 100,000 to 500,000 volts, particularly where heavier particles are being applied or where the rate of application is to be greatly increased, the particular voltage depending upon the character of the particles, the rate of travel of the sheet, and various other operating conditions.
  • Figs. 17 to 20 are shown different modified forms of deposition apparatus particularly suitable for the application of flock, linters, asbestos fiber, wood pulp fibers, fine abrasives and the like materials, to an adhesive coated surface of a base member.
  • the sheet material S is drawn from the supply roll over a spreader roll ll provided with, a spreader blade 82 which. is operative to distribute a fluid or plastic adhesive 83, such as rubber cement or the like, uniformly over the surface of the sheet S.
  • a fluid or plastic adhesive 83 such as rubber cement or the like
  • the sheet is drawn over or about a guide member which constitutes a part of the deposition apparatus. Thereafter the sheet is drawn downwardly between a pair of discharging electrodes 84, 84 connected to a suitable source of high potential alternating current, then over a guide roll 86 and wound on a reel 81, as in the previousl described embodiments.
  • the guide member preferably comprises a plate electrode interposed between two sheets of electrical nonconducting material such as Bakelite, the upper sheet or layer 88 having a smooth surface and being provided with a rounded or beveled edge as shown in Fig. 17.
  • the negative electrode 90 is disposed opposite the end of the electrode 85 and is arranged so as to establish a field whose lines of force intersect the path of travel of the sheet S at any desired angle.
  • the length of each electrode is sufilcient to provide an electrostatic field having a width corresponding to that of the sheet S.
  • a supply hopper BI is disposed above the electrostatic field and is constructed and arranged to deliver the fibrous material onto a screen 82 or the like device interposed between the field and the hopper.
  • the electrical connections are shown schematically in Fig. 17 wherein a conductor connects the screen 92 and the electrode 90 to the negative terminal of a suitable source of potential designated by the numeral 96, the positive terminal being grounded by a conductor 91 or connected to the electrode 85, as desired.
  • the electrode 85 may be grounded by a conductor 98 or otherwise connected to the conductor 91, and suitable means such as a controller 99 and rheostat [00 may be provided to control the potential and fiow of current in the circuit. If desired, a voltmeter I0!
  • the electrodes 84, 84 when connected as shown in Fig. 17, establish an alternating electrostatic field across the path of the coated sheet and are thus effective to discharge or neutralize any static charge carried by the sheet.
  • the operation of the apparatus is substantially the same as that of the previously described embodiments, it being understood that the present arrangement is designed to coat only one surface of the sheet S at one time.
  • the cementitious material is applied to the sheet S in the same manner as in the embodiment shown in Figs. 17 and 18.
  • a roller electrode I05 is used.
  • the roller electrode provides a guide roll about which the sheet S is drawn on its way to the winding drum or reel (not shown) and may be connected to the ground or otherwise, as in the previously described embodiments.
  • the negative electrode I01 comprises a metallic screen member which is shaped to provide a substantially horizontal portion I08 through which the particles discharged from the hopper I09 may pass, and a depending portion IIO disposed opposite but parallel to the roller electrode I05.
  • the supply hopper I09 is disposed above the horizontal portion I08 of the negative electrode so as to discharge the particles onto its horizontal portion.
  • the negative electrode is connected to the negative terminal of the sourceof potential and the usual control devices may be provided as in the previously described embodiment.
  • the embodiment shown in Fig. 20 is somewhat similar to that shown in Figs. 17 and 19 but is particularly designed for use in applying particles to a sheet having an adhesive coating which comprises a thermoplastic cementitious material, such as wax, paraflin, etc., which must be maiiitained in a relatively fluid or tacky condition during the deposition operation in order that the ends of the particles may be firmly embedded therein.
  • the apparatus embodies all the essential elements shown in Figs. 17 to 19 but in place of the electrodes shown therein, a metallic block IN and rotor II5 are used.
  • the block Ill constitutes the positive electrode and preferably comprises a metallic casting having a series of longitudinally extending ducts or channels II6 which may be connected to a steam or hot water supply (not shown).
  • the outer walls of the block II 4 which contactwith the sheet material are smooth and the adjacent corner is preferably rounded or beveled to provide a suitable guiding surface over which the sheet S is drawn.
  • the rotor II5 constitutes the negative or. projecting electrode and preferably comprises a cylindrical screen or grating supported on a circular plate which is rotatably mounted on a stationary tubular shaft I IT.
  • the tubular shaft II! is provided with a radially disposed axially extending slot co-extensive with the longitudinal extent of the screen and facing away from the electrode III.
  • a conduit H9 having an elongate, horizontally extending, flaring mouth or entrance I20 dis posed in radial alignment with the slot H8, is disposed closely adjacent to the electrode II5, as shown, and may be connected to a suitable suction fan or the like (not shown).
  • a supply hopper I09 and a charging screen II I are provided as in the embodiment shown in Fig. 17 and similar electrical connections, controls and means for discharging the static charge from the coated sheet may be employed.
  • the electrode I I5 is continuously rotated, compressed air being introduced into the shaft I I1 and discharged through the slot I I8, and the electrode I I4 is maintained at a. predetermined temperature by the flow of steam or hot water through the ducts H6.
  • the force of the air striking against the screen or grating of the electrode H5 is sufiicient to remove any accumulations of oriented fibrous material or other particles and carry them into the conduit I20, thus keeping the negative or projecting electrode relatively free of oriented material.
  • Figs. 13 to 16, inclusive are shown diiferent types of coated sheet material produced in accordance with the present invention.
  • the products shown in Figs. 13 and 14 each comprise a base member or backing sheet I2I, such as a sheet of heavy paper, a layer I22 of glue or the like binder, and a coating of abrasive particles I23 which have their ends deeply embedded in the binder I22.
  • the individual particles are more or less elongate in character and are disposed with their major axes substantially at right angles to the surface of the backing sheet, and that their free ends, being disposed in substantial parallelism relative to each other, present a most effective cutting or abrading surface.
  • the product shown in Fig. 15 comprises a backing sheet I25, such as a sheet of fabric, a layer I26 of rubber cement or the like soft or flexible binder, and a coating I 21 of fibrous material such as cotton flock or linters. It will be noted that the ends of the individual fibers are deeply embedded in the cementitious layer I26 and are disposed in uniformly spaced relation with their body portions extending outwardly in substantial parallelism, thus presenting an ap pearance which simulates that of a pile fabric.
  • Fig. 16 is similar to that shown in Fig. 15 except that the backing sheet consists of a sheet of heavy paper I28 and the fibers of the coating I27 are disposed at an angle of to relative to the backing sheet I28, thus presenting an appearance resembling suede.
  • Figs. 15 and 16 are greatly superior to those made in accordance with the prior practices wherein the fibrous material is deposited on an adhesive surface of a backing sheet by means of a current of air or by gravity.
  • the individual fibers are heterogene'ously disposed on the surface of the adhesive and hence do not assume any definite position relative to each other. Consequently, such products do not possess the dense and uniform characteristics nor the attractive appearance or finish of those made in accordance with the present in vention.
  • the wearing qualities of such products are greatly inferior to those made in accordance with the present invention due to the fact that the individual particles are not embedded to a suificient extent, if at all, in the adhesive, and as the body portions and the ends of the individual fibers provide the surface of the product, the individual fibers are soon worn away or are easily dislodged from the adhesive and hence expose uncoated areas of the binder.
  • the individual fibers, being firmly embedded in the adhesive are not easily dislodged and as their ends constitute the major portion of the surface of the product, they efiectlvely resist wearing.
  • Apparatus for app yin coating particles to a base member having a surface previously rendered adhesive comprising a pair of spaced electrodes cooperating to form a projecting and receiving'electrode assembly, means for charging said electrodes with opposite electrostatic charges thereby to produce an electrostatic field, means for supporting said base member with said adhesive surface between said electrodes, means.
  • Apparatus for applying coating particles to a base member having a surface previously rendered adhesive comprising a pair of spaced electrodes cooperating to form a projecting and receiving electrode assembly, means for charging said electrodes with opposite electrostatic charges thereby to produce an electrostatic field.
  • means for supporting said hue member with said adhesive surface between said electrodes means. positioned outside of the effective field between said electrodes, for imparting an electrostatic charge to substantially all of a dispersion of coating material in particle form to be applied to said base member and of a polarity corresponding to the polarity of a projecting electrode of the said assembly, and means for conducting the charged coating particles into the said electrostatic field between the spaced electrodes intermediate the adhesive coating of said base member and the adjacent projecting electrode.

Description

June 30, 1942. J. s. SMYSER 2,287,337
METHOD AND APPARATUS FOR APPLYING COATING MATERIALS Original Filed April 25, 1934 4 Sheets-Sheet l g g s x @QQ/W June so, 1942. J. 5. sMY-sE R 2,287,837
METHOD AND APPARATUS FOR APPLYING COATING MATERIALS oii i'n il Filed April 25, 1954 4 Sheets-Sheet 2 W//////////////////I///////////////////////////n nmnuu umnman P mumnm ilHHHIIHIiI 91 a? .56
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June 30, 1942. .1. s. SMYSER 2,237,337
METHOD AND APPARATUS FOR APPLYING COATING MATERIALS Original Filed April 25, 1934 4 Sheets-Sheet 3 4? Miam 63 .181 E l j w i JTJQ J8? fl' W////////////////% M, fl {8726 5 J17 60 V////////////////////%? J36 m 1 mo '6 4: M rlzniw Z,
June 30, 1942.
METHOD-AND APPARATU on APPLYING equine; MATERIALS .4: shee ts-sh 'e' et 4 Original Filed April 25, 1934 Patented June 30, 1942 METHOD AND APPARATUS FOR APPLYING COATING MATERIALS James S. Smyser, deceased, late of Quincy, Mass by Granite Trust Company, executor, Quincy, Mass., assignor to Minnesota Mining & Manufacturing Company, St. Paul, Minn, a corporation of Delaware Substituted for abandoned application Serial No.
722,288, April 25, 1934.. This application January 22, 1941, Serial No. 375,432
6 Claims.
This invention relates to a method of and apparatus for applying particles and various forms of comminuted materials to a base member, and to the resulting product.
This application is a continuation of the application of James S. Smyser, Serial No. 722,288, filed April 25, 1934.
The principal objects of the invention are to provide a novel method and apparatus for applying particles and finely divided materials, such,' for example, as flock, linters, and the like fibrous material, abrasive particles, etc., to one or more surfaces of a base member, such as a piece of sheet material; to provide means for controlling the manner and rate of application or disposition of the particles so as to obtain a uniformly coated product having predetermined characteristics; and to provide means whereby unlimited lengths of sheet material may be coated efiiciently and progressively, on either or both sides, more quickly, densely, uniformly and cheaply than by any apparatus and/or method heretofore used.
Other objects of the invention are to provide a strong and flexible product having a dense, homogeneous, villous finish simulating the appearance of either suede or a pile fabric; and to provide a finish of any desired density wherein the major portion of the fibers are disposed at substantially the same angle relative to the surface of the base sheet with their ends firmly embedded in an adhesive coating carried thereby.
Further objects relate to the construction of the apparatus and to the mode of operation of the method, and will be apparent from a consideration of the following description and accompanying drawings which exemplify different embodiments of the invention in its apparatus, product and process aspects.
In accordance with the present invention the surface (or surfaces) of the base member, or article to be coated is first rendered adhesive, as for example by the application of a suitable cementitlous material, such as rubber cement, wax, paraflin, glue, or the like adhesive. When thus coated the base member is passed through an electrostatic field set up between one or more pairs of oppositely charged electrodes, and during its passage through the electrostatic field the particles to be applied are carried in a uniformly dispersed formation into the field either by gravity, a current of air, or in any other suitable manner.
Preferably the particles being conveyed to the field are charged in any suitable manner with the same charge as that of the electrode projecting them against the base member, and to this end they may be passed through a metallic screen or the like member which is connect ed in the circuit of the projecting electrode. When thus charged, the particles, upon entering the electrostatic field are projected against the adhesive surface of the base member more uniformly and efliciently, and with much greater force than would otherwise be possible. Furthermore, the individual particles are more effectively aligned in the direction of the lines of force of the electrostatic field and, due to the increased force with which they are projected against the surface of the base member, are more deeply and firmly embedded in the adhesive surface of the base member. Moreover, migration of the charged particles toward the adjacent or projecting electrode is greatly minimized, if not substantially eliminated, and consequently considerable waste is eliminated and the efficiency of the method and apparatus is appreciably increased.
The construction and arrangement of the electrodes is such as to provide an electrostatic field of uniform flux density which extends across the path of the surface of the article to be coated and at an angle to its path of travel. The position of the individual particles relative to the surface of the base member may be controlled and /or varied by adjusting the relative position of the electrodes so as to attainthe desired direction of the lines of force of the electrostatic field relative to the surface of the base member. To this end one or both of the electrodes may be adjustably mounted so that their position relative to each other may be varied.
The electrostatic field may be produced by a suitable source of potential such as a Kenotron or the like alternating current rectifier, a static machine, mechanical rectifier, or any other source which may be susceptible to control. The potential impressed upon or across the electrodes may vary within wide ranges, depending upon the character of the material to be deposited, the desired rate of deposition, etc., and the usual types of control instrumentalities may be employed to provide an electrostatic field of the desired characteristics.
The rate of deposition or application may be so controlled as to produce a coated product of any desired density by varying the quantity of particles supplied, the rate of travel of the base member through the field, and/or the electrical characteristics of the field, i. e., the flux density,
voltage across the electrodes, etc. To this end suitable means may be employed to control the rate of delivery of the particles and the rate of travel of the base member, and appropriate devices such as rheostats and various types of impedances, together with the usual indicators (ammeters, voltmeters, etc.), may be connected in the electrical circuits or circuit to provide for the adjustment necessary to obtain an electrostatic field suitable for the application or deposition of the particular type of material to be applied.
Where high potentials are employed or where the adhesive surface of the sheet material or base member contains an inflammable solvent, it is necessary to prevent sparking and suitable means may be employed to discharge or neutralize the static charge on the surface of the coated sheet before winding. To this end an ultra-violet light may be employed or, if desired, the coated sheet may be passed between electrodes connected to a high potential alternating current circuit, either of which is effective to discharge or neutralize any static charge carried by the coated sheet.
In the drawings:
Fig. 1 is a diagrammatic side elevation, in section, showing one embodiment of my apparatus;
Fig. 2 is a diagrammatic plan view of the apparatus shown in Fig. 1, the means for feeding the particles to be applied being omitted;
Fig. 3 is a diagrammatic side elevation, in section, showing a modified form of apparatus;
Fig. 4 is a section on line 4-4 of Fig.
Fig. 5 is a schematic diagram illustrating one arrangement of the electrical connections;
Fig. 5a is a graphic representation of a pulsating current used in connection with certain forms of the apparatus herein shown;
Figs. 6 to 9, inclusive are schematic diagrams illustrating other arrangements of the electrical connections;
Fig. 10 is a schematic diagram showing the electrical connections of a Kenotron transformer;
Fig. 11 is a fragmentary section showing a piece of fabric before the application of an adhesive coating;
Fig. 12 is a fragmentary section showing the fabric after the application of the adhesive coat- Figs. 13 to 16, inclusive, are enlarged fragmentary sections showing difierent specimens of sheet material after being coated in accordance with the present invention;
Fig. 17 is a horizontal view with parts shown in section of another modified form of apparatus;
Fig. 18 is a plan view of the apparatus shown in Fi 7: and
Figs, 19 and 20 are horizontal views, with parts shown in section of further modified forms of apparatus.
The embodiment shown in Figs. 1 and 2 comprises a coating apparatus III, a deposition apparatus designated by the numeral H, and a winding mechanism II. The coating apparatus may be of any type suitable for applying a coating of adhesive such as rubber cement, wax, glue, parafi'in, or the like cementitious material to one or both surfaces of a base member or sheet material S, and as here shown comprises a tank'or trough l9 having guide rolls l6, I1, 20, 2| and 22 to conduct the sheet material through a fiuid bath 23 of suitable adhesive, and squeeze rolls 24 and 25 to remove excess adhesive and distribute the coating uniformly over the surfaces of the sheet S. The temperature and fluidity of the bath 23 may be controlled in any suitable manner as by steam coils 26. The winding apparatus |2 may be of any conventional form and is here shown as comprising a guide roll l3, a winding drum l4, and a reel I5, upon which the coated sheet material is wound. Suitable mean (not o y be provided to regulate the speed of the winding drum l4 and thus control the rate of travel of the sheet material S,
The deposition apparatus comprises a boxlike structure or housing preferably having uprights or walls of suitable electrical non-conducting material which define the deposition zone or chamber 30, the top of which may be open as shown in Fig. 1. The end walls 3| and 32 are provided with vertically extending slots or openings 33 and 34, respectively, through which the sheet material S may be conducted into and out of the zone or chamber 30, and guide rolls 35, 36, 31 and 38 are provided to support the sheet S for movement along a predetermined path through the deposition zone or chamber 30.
Electrodes 40, 4|, .2 and 43 are mounted in pairs, each electrode comprising an elongate metallic bar secured to a suitable support and having a series of pointed members or prongs secured thereto and arranged as shown in Fig. 2. The electrodes are arranged in pairs 40, 4| and 42, 43 and may be connected to any suitable source of potential as hereinafter described. The elements of each pair are disposed on opposite Sides of the path of travel of the sheet S and are preferably inclined at an angle to its line of travel so as to provide an electrostatic field which extends diagonally across the path of movement of the sheet S. The purpose of this inclined arrangement is to insure a more even coating when the comminuted material is fed to the electrostatic field from the top.
Suitable means are provided to conduct the material to be deposited on the sheet S into the electrostatic fields set up between each pair of electrodes and to this end hoppers 50 and 5| may be arranged directly above electrodes 40, 4| and 42, 43, respectively. If it be desired to coat one side of the sheet S only, the hoppers may be arranged to discharge the coating material into a zone between the projecting electrode and surface of the sheet to which the material is to be applied. Where both sides of the sheet S are to be coated, the hoppers may be arranged to discharge the particles on both sides of the sheet S or, if desired, one hopper may be arranged to discharge the material on one side of the sheet and the other hopper on the opposite side, the particular arrangement depending upon the connections of the electrodes for the most effective results.
At some convenient location between the hoppers 50, 5| and the electrostatic fields, there may be provided means for imparting an electrostatic charge to the particles to be applied and to this end metallic screens 52 and 53, or th like, may be mounted beneath the discharge openings of the hoppers 50 and 5|, as shown in Fig. l, or,
.if desired, these screens may be integral with the the density of the coating applied to the sheet material may be varied as desired,
The embodiment shown in Figs. 3 and 4 is a preferred form of deposition apparatus and includes all the essential elements of the apparatus shown in the previously described embodiment.
v bodiment.
In Figs. 5 to 9, inclusive, are shown various ways in which the electrodes may be connected for use with a pulsating current (graphically represented in Fig. 5:!) such as may be derived from a two-tube Kenotron rectifier, or a continuous (non-pulsating) current such as may be derived from a static machine, mechanical rectifier with a suitable condenser, a high voltage generator, or the like, the arrangement shown in Figs. 6 to 9 being particularly suitable for use with a pulsating current. Y
In the arrangement shown in Fig. 5, the electrodes 40 and 43 are connected to each other by a conductor 55 and by a conductor 56 to a suitable source of potential, here shown as a Kenotron rectifier designated generally by the numeral 60. The electrodes 4| and 42 are connected to each other by a conductor 51 and to the ground by a conductor 58. With this arrangement the conductors 55 and 55 are preferably connected to the negative terminal of the Kenotron 60 or other source of potential and its positive terminal may be grounded by means of conductor 53 or connected to the positive terminal of the source of potential, as desired. When thus connected the current fiows from the Kenotron through a main circuit comprising the conductor 59, the ground and conductor 58, at which point the main circuit branches into two circuits, one of which comprises electrodes 42 and 43 and the conductor 55, the second branch circuit comprising the conductor 51 and electrodes 4| and 40. The conductor 56 connects the branch circuits to the negative terminal of the Kenotron and thus completes the main circuit from the Kenotron to the electrodes.
This arrangement is particularly suitable for use when both sides of the sheet S are to be coated as it will be noted that the negative or projecting electrodes 43 and 43 are on opposite sides of the sheet S and the intensity of the electrostatic fields established between each pair of electrodes is always the same.
shown in Figs. 1 and 2, the screens 52 and 53 may be connected to the electrodes 40 and 43, respectively, so that the particles discharged into the electrostatic field are first given a negative charge. 52 and 53 are preferably positioned so that the charged particles are delivered into that portion of the electrostatic field between the projecting electrode and the adjacent surface of the sheet to be coated.
In the arrangement shown in Fig. 6, electrodes 40 and 42 are connected one to the negative ter- When this arrange- Y ment is used in conjunction with the apparatus ground or to the positive terminal of the source of potential by conductors 5i and 58, respectively, and the electrodes 4| and 43 are connected to each other by a heavy metallic bar 65 which provides an appreciable capacitance in the circuit between the electrodes 4| and 43. These electrodes and the bar 65 constitute, in effect, a unit which acts as a condenser and which builds up its charge as the potential increases from zero to maximum and discharges through the electrodes 4| and 43 as the potential drops from maximum to zero (Fig. 5a). In place of the bar 55, the alternative arrangement shown in Fig. 7 may be used, in which case the electrodes 4| and 43 are connected to each other by a conductor 62 which is connected to one terminal of a condenser 83, the other terminal of the condenser being grounded. With either of these arrangements the flow of current through the circuit as the potential increases from zero to maximum is from electrode 42 to 43 and from electrode 4| to 48, the electrodes 4| and 42 being positively charged and electrodes 43 and 43 bein negatively charged. When the potential reaches a maximum the electrodes 4| and 43 become fully charged so that when the potential drops from maximum to zero, there is a discharge from electrodes 4| and 43 through electrodes 43 and 42, respectively. Either of the arrangements shown in Figs. 5, 6 and '1 may be used with the apparatus shown in Figs. 1 to 4 in coating either or both sides of the sheet S.
The arrangement shown in Fig. 8 comprises a single pair of electrodes 40 and 4|, the electrode 40 being connected to the Kenotron 68 by conductor 56, and the electrode 4| being connected to the ground or the conductor 59, as preferred, by a circuit which includes the condenser 63. This arrangement is particularly suitable where only one side of the sheet S isto be coated.
The arrangement shown in Fig. 9 is substantially the same as that shown in Fig. '1 except that instead of using two pairs of electrodes. four pairs, 4040 4|4|*, etc. arranged in tandem are employed. This arrangement is particularly suitable where a much denser coatin of material is to be applied.
In Fig. 10 is shown a preferred form of electrical connections which affords an efiective means of controlling the characteristics of the electrostatic field when an alternating current rectifier is used as a source of potential. The numerals 66 and 61 designate the alternating current power supply lines which are connected to the terminals of the primary windings 58 and 69 of a main transformer 10 and a filament transformer 1|, respectively. Rheostats 12 and 13 are connected in the respective circuits so as to control their outputs. One terminal of the secondary winding 14 of the main transformer 10 is. grounded by means of the conductor 59 (see also Figs. 5 to 9) and the other terminal is connected to the filament circuit of the rectifier or Kenotron The hoppers 50 and 5| and the screens minal of the Kenotron and the other to the Figs. 5 to 10. With this arrangement, the output of the rectifier may be accurately controlled by adjusting the rheostats l2 and I3 and thus the electrostatic fields set up between the electrodes may be varied so as to attain the desired strength, density, etc.
In using the apparatus shown in Figs. 1 to 4 to carry out the process, the sheet material 5, such as a piece of fabric 10 (Fig. 11), is drawn from the supply roll [8, through the bath 23 where a coating 1| (Fig. 12) of adhesive such as glue, paraffin, rubber cement, wax or the like is applied to both surfaces. While the adhesive coating is still tacky the sheet is guided between each pair of electrodes, as indicated in Figs 1 to 10. The rheostats I2 and 13 are adjusted to produce the desired potential across the electrodes and thus establish an electrostatic field ofthe desired strength and intensity. After having made these adjustments the material to be applied is fed from the hoppers 50 and at a predetermined rate and after passing through the screens 52 and 53 where the individual particles receive a negative charge, they are then carried by gravity into the electrostatic field. When material such as flock, linters and the like fibers, as well as the various forms of abrasive material such as carborundum, pumice, tripoli, etc., constitute the coating material being applied, the individual particles upon entering the electrostatic field, due to their elongate nature, become aligned in the direction of the electrostatic lines of force and are uniformly projected or bombarded against the adhesive surface of the sheet S so that their ends are deeply and firmly embedded in the adhesive coating at substantially the same angle and their projecting portions are disposed in substantial parallelism relative to each other. Due to the initial charge imparted to the particles, they tend to repel each other and become dispersed so that upon being projected against the adhesive surface of the sheet S the individual particles are spaced relatively to each other. As the individual particles align themselves with their major axes coinciding with the direction of the electrostatic lines of force, they may be applied to the sheet S so that their major axes are disposed at any desired angle relative to the surface of the sheet and consequently a greater number of particles per unit area may be applied to the sheet and with greater uniformity than is otherwise possible. When thus applied, their embedded ends are held in spaced relation to each other on the sheet S and by reason of capillary action and the removal of the film of air surrounding the particles the adhesive creeps up or rises along their sides forming a meniscus about the embedded ends of each individual particle.
After having received a coating of particles on one or both surfaces, sheet S is guided out of the deposition zone and passed between a pair of ultra-violet lights L and L' or other suitable means operative to discharge or neutralize the static charge carried by the coated surface without causing sparking. After removing the static charge on the sheet, it is then wound up on the reel l5. During both the coating and deposition operations the sheet S is held under slight tension by the pull of the winding drum and reel. The density of the coating may be varied, as desired, by varying either the rate of travel of the sheet S, the rate of delivery of the particles from the hoppers 50 and 5|, or both, and the strength of the electrostatic field may be varied accordingly.
When applying fibrous material at a relatively low rate, a potential of the order of 15,000 to 25,000 vo";s may be used, although it is preferred to use potentials from 100,000 to 500,000 volts, particularly where heavier particles are being applied or where the rate of application is to be greatly increased, the particular voltage depending upon the character of the particles, the rate of travel of the sheet, and various other operating conditions.
In Figs. 17 to 20 are shown different modified forms of deposition apparatus particularly suitable for the application of flock, linters, asbestos fiber, wood pulp fibers, fine abrasives and the like materials, to an adhesive coated surface of a base member. In the embodiment shown in Figs. 17 and 18 the sheet material S is drawn from the supply roll over a spreader roll ll provided with, a spreader blade 82 which. is operative to distribute a fluid or plastic adhesive 83, such as rubber cement or the like, uniformly over the surface of the sheet S. After having received a coating of adhesive of suitable thickness, the sheet is drawn over or about a guide member which constitutes a part of the deposition apparatus. Thereafter the sheet is drawn downwardly between a pair of discharging electrodes 84, 84 connected to a suitable source of high potential alternating current, then over a guide roll 86 and wound on a reel 81, as in the previousl described embodiments.
The guide member preferably comprises a plate electrode interposed between two sheets of electrical nonconducting material such as Bakelite, the upper sheet or layer 88 having a smooth surface and being provided with a rounded or beveled edge as shown in Fig. 17. The negative electrode 90 is disposed opposite the end of the electrode 85 and is arranged so as to establish a field whose lines of force intersect the path of travel of the sheet S at any desired angle. Preferably the length of each electrode is sufilcient to provide an electrostatic field having a width corresponding to that of the sheet S.
A supply hopper BI is disposed above the electrostatic field and is constructed and arranged to deliver the fibrous material onto a screen 82 or the like device interposed between the field and the hopper. The electrical connections are shown schematically in Fig. 17 wherein a conductor connects the screen 92 and the electrode 90 to the negative terminal of a suitable source of potential designated by the numeral 96, the positive terminal being grounded by a conductor 91 or connected to the electrode 85, as desired. The electrode 85 may be grounded by a conductor 98 or otherwise connected to the conductor 91, and suitable means such as a controller 99 and rheostat [00 may be provided to control the potential and fiow of current in the circuit. If desired, a voltmeter I0! may be connected in the circuit in the usual manner. The electrodes 84, 84 when connected as shown in Fig. 17, establish an alternating electrostatic field across the path of the coated sheet and are thus effective to discharge or neutralize any static charge carried by the sheet. The operation of the apparatus is substantially the same as that of the previously described embodiments, it being understood that the present arrangement is designed to coat only one surface of the sheet S at one time.
In the embodiment shown in Fig. 19, the cementitious material is applied to the sheet S in the same manner as in the embodiment shown in Figs. 17 and 18. In place of the guide member and plate electrode shown in Figs. 1'7 and 18, a roller electrode I05 is used. The roller electrode provides a guide roll about which the sheet S is drawn on its way to the winding drum or reel (not shown) and may be connected to the ground or otherwise, as in the previously described embodiments. The negative electrode I01 comprises a metallic screen member which is shaped to provide a substantially horizontal portion I08 through which the particles discharged from the hopper I09 may pass, and a depending portion IIO disposed opposite but parallel to the roller electrode I05. The supply hopper I09 is disposed above the horizontal portion I08 of the negative electrode so as to discharge the particles onto its horizontal portion. The negative electrode is connected to the negative terminal of the sourceof potential and the usual control devices may be provided as in the previously described embodiment.
The embodiment shown in Fig. 20 is somewhat similar to that shown in Figs. 17 and 19 but is particularly designed for use in applying particles to a sheet having an adhesive coating which comprises a thermoplastic cementitious material, such as wax, paraflin, etc., which must be maiiitained in a relatively fluid or tacky condition during the deposition operation in order that the ends of the particles may be firmly embedded therein. The apparatus embodies all the essential elements shown in Figs. 17 to 19 but in place of the electrodes shown therein, a metallic block IN and rotor II5 are used. The block Ill constitutes the positive electrode and preferably comprises a metallic casting having a series of longitudinally extending ducts or channels II6 which may be connected to a steam or hot water supply (not shown). The outer walls of the block II 4 which contactwith the sheet material are smooth and the adjacent corner is preferably rounded or beveled to provide a suitable guiding surface over which the sheet S is drawn. The rotor II5 constitutes the negative or. projecting electrode and preferably comprises a cylindrical screen or grating supported on a circular plate which is rotatably mounted on a stationary tubular shaft I IT. The tubular shaft II! is provided with a radially disposed axially extending slot co-extensive with the longitudinal extent of the screen and facing away from the electrode III. A conduit H9 having an elongate, horizontally extending, flaring mouth or entrance I20 dis posed in radial alignment with the slot H8, is disposed closely adjacent to the electrode II5, as shown, and may be connected to a suitable suction fan or the like (not shown). A supply hopper I09 and a charging screen II I are provided as in the embodiment shown in Fig. 17 and similar electrical connections, controls and means for discharging the static charge from the coated sheet may be employed. During the deposition operation the electrode I I5 is continuously rotated, compressed air being introduced into the shaft I I1 and discharged through the slot I I8, and the electrode I I4 is maintained at a. predetermined temperature by the flow of steam or hot water through the ducts H6. The force of the air striking against the screen or grating of the electrode H5 is sufiicient to remove any accumulations of oriented fibrous material or other particles and carry them into the conduit I20, thus keeping the negative or projecting electrode relatively free of oriented material.
In Figs. 13 to 16, inclusive, are shown diiferent types of coated sheet material produced in accordance with the present invention. The products shown in Figs. 13 and 14 each comprise a base member or backing sheet I2I, such as a sheet of heavy paper, a layer I22 of glue or the like binder, and a coating of abrasive particles I23 which have their ends deeply embedded in the binder I22. It will be noted that the individual particles are more or less elongate in character and are disposed with their major axes substantially at right angles to the surface of the backing sheet, and that their free ends, being disposed in substantial parallelism relative to each other, present a most effective cutting or abrading surface.
The product shown in Fig. 15 comprises a backing sheet I25, such as a sheet of fabric, a layer I26 of rubber cement or the like soft or flexible binder, and a coating I 21 of fibrous material such as cotton flock or linters. It will be noted that the ends of the individual fibers are deeply embedded in the cementitious layer I26 and are disposed in uniformly spaced relation with their body portions extending outwardly in substantial parallelism, thus presenting an ap pearance which simulates that of a pile fabric.
The embodiment shown in Fig. 16 is similar to that shown in Fig. 15 except that the backing sheet consists of a sheet of heavy paper I28 and the fibers of the coating I27 are disposed at an angle of to relative to the backing sheet I28, thus presenting an appearance resembling suede.
The products shown in Figs. 15 and 16 are greatly superior to those made in accordance with the prior practices wherein the fibrous material is deposited on an adhesive surface of a backing sheet by means of a current of air or by gravity. In such products the individual fibers are heterogene'ously disposed on the surface of the adhesive and hence do not assume any definite position relative to each other. Consequently, such products do not possess the dense and uniform characteristics nor the attractive appearance or finish of those made in accordance with the present in vention. Moreover, the wearing qualities of such products are greatly inferior to those made in accordance with the present invention due to the fact that the individual particles are not embedded to a suificient extent, if at all, in the adhesive, and as the body portions and the ends of the individual fibers provide the surface of the product, the individual fibers are soon worn away or are easily dislodged from the adhesive and hence expose uncoated areas of the binder. In the products made in accordance with the present invention the individual fibers, being firmly embedded in the adhesive, are not easily dislodged and as their ends constitute the major portion of the surface of the product, they efiectlvely resist wearing. Furthermore, due to the fact that a much denser coating may be applied to the adhesive surface of the backing sheet, there is a greater number of fibers per unit area to resist wearing and abrasion, and consequently the product will outwear those made in accordance with the prior practices.
While there are shown and described different desirable embodiments of the present invention, it is to be understood that this disclosure is for the purpose of illustration only and that various changes and modifications may be made without departing from the spirit and scope of the invention as set forth in the appended claims.
Whatisclaimed is: I
1. In the process of coating a surface with solid particles wherein said particles are to be adhesively united to said surface, and which comprises forming an electrostatic field between a projecting and receiving electrode, the steps which include positioning an adhesively coated surface in said field, imparting an electrostatic charge of the same polarity as that of the projecting electrode to substantially all of the particles to be coated before they enter said field and then introducing the particles thus charged into said field in a position to be impelled, oriented and dispersed by said field upon said adhesive surface.
2. The process of claim 1 in which the charge that is imparted to the particles before introducing them into said field is imparted by contacting the particles with an electrically charged body outside of said field.
3. The process of claim 1 in which the charge that is imparted to the particles before introducing them into said field is imparted by contacting the particles with an electrically charged body outside of said field, said charge being of a potential at least as great as that of the projecting electrode of said field.
4. In the process of coating a surface with finely divided particles of solid matter wherein said particles are to be held to said surface by firmly embedding at least a part of each particle in a coating of adhesive thereon andwherein the particles are brought into contact with and positioned on the surface by means of the projecting, orienting and dispersing effect of an electrostatic field formed between a projecting and receiving electrode, and in which the field alone would charge the majority of the particles otherwise than by contact with any of the fields electrodes, the steps comprising substantially separating and charging substantially all of the particles by contacting them with an electrically charged body having the same polarity and of a potential at least as great as the potential of the projecting electrode of said field before introducing them into said field, positioning the adhesive coated surface in the field and then introducing the thus charged particles into the field between the adhesive coated surface and the projecting electrode thereby insuring substantially uniform behavior of substantially all the particles that enter the field throughout the coating process and insuring that the maximum whereby a product coated with solid particles which are adhesively united thereto is secured. in which the particles are uniformly oriented, dispersed and positioned, and firmly retained in the adhesive.
5. Apparatus for app yin coating particles to a base member having a surface previously rendered adhesive. comprising a pair of spaced electrodes cooperating to form a projecting and receiving'electrode assembly, means for charging said electrodes with opposite electrostatic charges thereby to produce an electrostatic field, means for supporting said base member with said adhesive surface between said electrodes, means. positioned outside of the efiective field between said electrodes, for imparting an electrostatic charge to substantially all of a dispersion of coating material in particle form to be applied to said base member and of a polarity corresponding to the polarity of a projecting electrode of the said assembly, said last mentioned means being positioned to conduct the charged coating particles into the said electrostatic field between the spaced electrodes intermediate the adhesive coating of said base member and the adjacent projecting electrode.
6. Apparatus for applying coating particles to a base member having a surface previously rendered adhesive, comprising a pair of spaced electrodes cooperating to form a projecting and receiving electrode assembly, means for charging said electrodes with opposite electrostatic charges thereby to produce an electrostatic field. means for supporting said hue member with said adhesive surface between said electrodes, means. positioned outside of the effective field between said electrodes, for imparting an electrostatic charge to substantially all of a dispersion of coating material in particle form to be applied to said base member and of a polarity corresponding to the polarity of a projecting electrode of the said assembly, and means for conducting the charged coating particles into the said electrostatic field between the spaced electrodes intermediate the adhesive coating of said base member and the adjacent projecting electrode.
GRANITE TRUST COMPANY, IRVING L. SHAW,
Vice President,
pr ie t naorient d p rsing power of the Executor of the Last Will and Testament of field is exerted on substantially every particle James S, Smyser, deceased.
CERTIFICATE OF comenon. v Patent No. 2,237, 7, June 50, 191 2.
arms 3. SHYSER, DECEASED, BY
emuum TRUST comm, mm.
It is hereby certified that error appears in the above numbered patent requiring correction as follows: In the heaciing to the printed specifica tion, line 9, for Substituted for abndoned epplicat1on" read --Coritinnation of application--; and that the said Letters Patent -should be read -w1th this correction therein that the same may conform to the record of the case in the Patent Office,
Signed and sealed this' 29th day of September, A. .n. 1912.
Henry Van Arsdale, (Seal) Acting Commissioner of Patents.
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Cited By (33)

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US2421787A (en) * 1945-01-26 1947-06-10 Harper J Ransburg Company Electrostatic coating method
US2526780A (en) * 1945-10-22 1950-10-24 Ransburg Electro Coating Corp Apparatus for coating articles
US2676562A (en) * 1946-11-06 1954-04-27 Koppers Co Inc Apparatus for producing granulecoated bases
US2608176A (en) * 1948-03-16 1952-08-26 American Can Co Apparatus for electrostatically coating articles
US2658009A (en) * 1948-05-13 1953-11-03 Ransburg Electro Coating Corp Electrostatic coating method and apparatus
US2662833A (en) * 1948-06-16 1953-12-15 Ransburg Electro Coating Corp Electrostatic coating method and apparatus
US2729191A (en) * 1950-07-15 1956-01-03 Ransburg Electro Coating Corp Electrostatic coating apparatus
US2742018A (en) * 1952-01-02 1956-04-17 Lindquist Theodore Apparatus for coating by electrostatic force
DE917001C (en) * 1952-01-13 1954-08-23 Bergische Textil Und Kunststof Process for reducing the slip resistance of the reverse side of pile fabrics, in particular upholstery fabrics and carpets
US2715074A (en) * 1952-01-30 1955-08-09 Palladium Soc Watertight and air pervious flocked sheet material and method of making same
US2698814A (en) * 1952-05-01 1955-01-04 Ransburg Electro Coating Corp Electrostatic coating apparatus and method
US2824813A (en) * 1952-05-12 1958-02-25 Haloid Co Method for developing electrostatic latent images
US2820719A (en) * 1952-08-27 1958-01-21 Davies Young Soap Company Process for rendering fabrics water repellent
US2811134A (en) * 1953-06-15 1957-10-29 Standard Products Co Apparatus for preventing flock build-up on a flocking machine electrode
US2768903A (en) * 1953-06-18 1956-10-30 Otto W Schick Method and apparatus for applying flocking to an article
US2716380A (en) * 1953-11-02 1955-08-30 Lithographic Technical Foundat Spray dampening system for lithographic offset printing presses
US2922883A (en) * 1955-03-03 1960-01-26 Rca Corp Electrostatic charging means and method
US2885556A (en) * 1955-08-01 1959-05-05 Haloid Xerox Inc Simultaneous charging device and method
US2986473A (en) * 1957-03-15 1961-05-30 Ritzerfeld Wilhelm Transfer sheets and method of making the same
US3323934A (en) * 1962-08-07 1967-06-06 M E S Sa De Machines Electrost Electrostatic coating process and apparatus
US3380845A (en) * 1963-12-06 1968-04-30 Commercial Plastics Ltd Coating opposite sides of web employing electrostatic field
US6554945B1 (en) * 1999-08-12 2003-04-29 Mesac Corporation Electrostatic flocking chamber for forming electrostatic flocking apparatus
EP1075876A3 (en) * 1999-08-12 2004-02-04 Mesac Corporation Electrostatic flocking chamber for forming electrostatic flocking apparatus
US8834618B2 (en) 2009-12-03 2014-09-16 3M Innovative Properties Company Method of inhibiting water adsorption of powder by addition of hydrophobic nanoparticles
WO2011068678A1 (en) 2009-12-03 2011-06-09 3M Innovative Properties Company Method of electrostatic deposition of particles, abrasive grain and articles
US8894466B2 (en) 2009-12-03 2014-11-25 3M Innovative Properties Company Method of electrostatic deposition of particles, abrasive grain and articles
WO2012112322A2 (en) 2011-02-16 2012-08-23 3M Innovative Properties Company Electrostatic abrasive particle coating apparatus and method
EP2675575A4 (en) * 2011-02-16 2014-11-05 3M Innovative Properties Co Electrostatic abrasive particle coating apparatus and method
EP2675575A2 (en) * 2011-02-16 2013-12-25 3M Innovative Properties Company Electrostatic abrasive particle coating apparatus and method
US9040122B2 (en) 2011-02-16 2015-05-26 3M Innovative Properties Company Electrostatic abrasive particle coating apparatus and method
US9676078B2 (en) 2011-02-16 2017-06-13 3M Innovative Properties Company Electrostatic abrasive particle coating apparatus and method
US20220241931A1 (en) * 2019-07-18 2022-08-04 3M Innovative Properties Company Electrostatic particle alignment method and abrasive article
US11577367B2 (en) * 2019-07-18 2023-02-14 3M Innovative Properties Company Electrostatic particle alignment method and abrasive article

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