US2404778A - Apparatus for producing ozone - Google Patents

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US2404778A
US2404778A US448987A US44898742A US2404778A US 2404778 A US2404778 A US 2404778A US 448987 A US448987 A US 448987A US 44898742 A US44898742 A US 44898742A US 2404778 A US2404778 A US 2404778A
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air
chamber
compressor
ozone
refrigerant
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Donald K Allison
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    • FMECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
    • F25REFRIGERATION OR COOLING; COMBINED HEATING AND REFRIGERATION SYSTEMS; HEAT PUMP SYSTEMS; MANUFACTURE OR STORAGE OF ICE; LIQUEFACTION SOLIDIFICATION OF GASES
    • F25BREFRIGERATION MACHINES, PLANTS OR SYSTEMS; COMBINED HEATING AND REFRIGERATION SYSTEMS; HEAT PUMP SYSTEMS
    • F25B1/00Compression machines, plants or systems with non-reversible cycle
    • F25B1/06Compression machines, plants or systems with non-reversible cycle with compressor of jet type, e.g. using liquid under pressure
    • AHUMAN NECESSITIES
    • A61MEDICAL OR VETERINARY SCIENCE; HYGIENE
    • A61LMETHODS OR APPARATUS FOR STERILISING MATERIALS OR OBJECTS IN GENERAL; DISINFECTION, STERILISATION OR DEODORISATION OF AIR; CHEMICAL ASPECTS OF BANDAGES, DRESSINGS, ABSORBENT PADS OR SURGICAL ARTICLES; MATERIALS FOR BANDAGES, DRESSINGS, ABSORBENT PADS OR SURGICAL ARTICLES
    • A61L2/00Methods or apparatus for disinfecting or sterilising materials or objects other than foodstuffs or contact lenses; Accessories therefor
    • A61L2/16Methods or apparatus for disinfecting or sterilising materials or objects other than foodstuffs or contact lenses; Accessories therefor using chemical substances
    • A61L2/20Gaseous substances, e.g. vapours
    • A61L2/202Ozone
    • CCHEMISTRY; METALLURGY
    • C01INORGANIC CHEMISTRY
    • C01BNON-METALLIC ELEMENTS; COMPOUNDS THEREOF; METALLOIDS OR COMPOUNDS THEREOF NOT COVERED BY SUBCLASS C01C
    • C01B13/00Oxygen; Ozone; Oxides or hydroxides in general
    • C01B13/10Preparation of ozone
    • C01B13/11Preparation of ozone by electric discharge
    • FMECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
    • F02COMBUSTION ENGINES; HOT-GAS OR COMBUSTION-PRODUCT ENGINE PLANTS
    • F02GHOT GAS OR COMBUSTION-PRODUCT POSITIVE-DISPLACEMENT ENGINE PLANTS; USE OF WASTE HEAT OF COMBUSTION ENGINES; NOT OTHERWISE PROVIDED FOR
    • F02G5/00Profiting from waste heat of combustion engines, not otherwise provided for
    • FMECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
    • F25REFRIGERATION OR COOLING; COMBINED HEATING AND REFRIGERATION SYSTEMS; HEAT PUMP SYSTEMS; MANUFACTURE OR STORAGE OF ICE; LIQUEFACTION SOLIDIFICATION OF GASES
    • F25BREFRIGERATION MACHINES, PLANTS OR SYSTEMS; COMBINED HEATING AND REFRIGERATION SYSTEMS; HEAT PUMP SYSTEMS
    • F25B27/00Machines, plants or systems, using particular sources of energy
    • F25B27/02Machines, plants or systems, using particular sources of energy using waste heat, e.g. from internal-combustion engines
    • CCHEMISTRY; METALLURGY
    • C01INORGANIC CHEMISTRY
    • C01BNON-METALLIC ELEMENTS; COMPOUNDS THEREOF; METALLOIDS OR COMPOUNDS THEREOF NOT COVERED BY SUBCLASS C01C
    • C01B2201/00Preparation of ozone by electrical discharge
    • C01B2201/60Feed streams for electrical dischargers
    • C01B2201/66Pretreatment of the feed
    • CCHEMISTRY; METALLURGY
    • C01INORGANIC CHEMISTRY
    • C01BNON-METALLIC ELEMENTS; COMPOUNDS THEREOF; METALLOIDS OR COMPOUNDS THEREOF NOT COVERED BY SUBCLASS C01C
    • C01B2201/00Preparation of ozone by electrical discharge
    • C01B2201/70Cooling of the discharger; Means for making cooling unnecessary
    • YGENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y02TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
    • Y02ATECHNOLOGIES FOR ADAPTATION TO CLIMATE CHANGE
    • Y02A30/00Adapting or protecting infrastructure or their operation
    • Y02A30/27Relating to heating, ventilation or air conditioning [HVAC] technologies
    • Y02A30/274Relating to heating, ventilation or air conditioning [HVAC] technologies using waste energy, e.g. from internal combustion engine
    • YGENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y02TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
    • Y02TCLIMATE CHANGE MITIGATION TECHNOLOGIES RELATED TO TRANSPORTATION
    • Y02T10/00Road transport of goods or passengers
    • Y02T10/10Internal combustion engine [ICE] based vehicles
    • Y02T10/12Improving ICE efficiencies

Definitions

  • Patented July 30, 1946 APPARATUS FOR, PRODUCING OZONE Donald K. Allison, Beverly Hills, Calif.
  • My invention relates to an apparatus for producing ozone, and among the objects of my invention are:
  • the figure is a diagrammatical view of my apparatus for producing ozone.
  • Air to be treated in order to form ozone is drawn through a filter I by a compressor 2.
  • the air is compressed and passed through a refrigerating unit or heat exchanger 3 which may remove not only the heat generated during compression but lower the temperature below that of the incoming air, and in cooling the air remove therefrom a large percentage of water which may be drained oif by a drain valve 411.
  • the heat exchanger may comprise a shell 4 with a suitable refrigerating coil 5'therein, and may incorporate baflies 6 to insure proper heat transfer.
  • the compressed and refrigerated air passes through a bleeder valve 1 to an air motor 8.
  • the bleeder valve is a three-way valv providing connection between the refrigerator unit and the motor, or permitting discharge of the compressed air to atmosphere so as to by-pass the ozone generator, to be described hereinafter, during an initial warming up period.
  • the air motor drives a shaft 9 and propeller I0.
  • the propeller I is mounted within an ozonizer chamber II which contains ozone generating elements I2. These may comprise sets of plates divided into two groups separated by dielectric material and connected to the secondary of a high voltage transformer I3.
  • the ozonizer chamber II i provided with a jacket I4.
  • the refrigerating unit and the jacket of the ozonizer chamber are connected to a refrigerant supply pipe I and to a refrigerant return pipe I6,
  • the air from the air motor exhausts into the ozonizer chamber and circulates therein by means of the propeller and is drawn from the ozonizer chamber as needed through a discharge line I! controlled by a valve I8.
  • Another control valve' is may be interposed between the filter I and compressor 2.
  • the supply pipe and return pipes I5 and I6 are connected, respectively; to the lower and upper ends of an evaporator 2L
  • a pump 22 is interposed in the supply pipe I5 so as to move liquid from the evaporator 2
  • Various refrigerants may be used; ordinary water may be employed.
  • the evaporator 2I is maintained at a sub-atmospheric pressure as will be described hereinafter.
  • a float 23 which controls a valve 24 regulates the height of liquid in the evaporator, fluid being suppliedfrom a branch of a supply line 25 connected with a sump or reservoir 26.
  • the supply line also leads to a pump 21 which withdraws a refrigerant from the sump and delivers it to the jacket 28 of the internal combustion engine 29 which serves as a preheater, the engine 29 being provided with a governor controlled carburetor 29a, as shown.
  • the heated refrigerant passes from the jacket'to a boiler 30.
  • of the internal combustion engine is coiled in the boiler 30.
  • the internal combustion engine drives an electric generator 32 for supplying current to drive the mo-' tors connected with the several pumps 22 and 21, as well as the compressor 2 and transformer I3.
  • Heated refrigerant in the gaseous phase is discharged through jets 33 extending. into vacuum pressure.
  • Each of the condensers is provided with heat exchanger coils 38 which are connected to an evaporative cooler 39; a pump 49 maintains circulation.
  • the last of the series 'of condensers 36 discharges into the sump 26, from which it is withdrawn for recycling, part of the refrigerant being heated by the otherwise wasted heat from the internal combustion engine and the other part circulating in the cold circuit of the refrigerating system, that is, through the supply and return pipes l5 and 16.
  • the ozonizer By utilizing the otherwise wasted heat of the internal combustion engine it is possible to so cool the air that the ozonizer operates at maximum efficiency. It should be noted that the process of ozonizing the air tends to heat it and that the amount of ozone that can be generated diminishes as the temperature of the air increases, so that it is of utmost .pratical importance to'maintain the air at as low a temperature as possible. It is also mandatory that the cost per unit of ozone produced be as low as possible.
  • Wasted heat of the internal combustion engine which supplies the power for the differentparts of the apparatus either by mechanical connection, as by the belt and pulley arrangement, 4
  • An apparatus for producing ozone comprising an air compressor, a refrigerating unit for chilling .air compressed by said compressor, an ozonizing chamber having electrical means associated therewith, means for conducting chilled air from said unit to said chamberfor ozonization by said electrical means, means for varying the amount of ozonized air withdrawn from said chamber thereby varying the load on said compressor and electrical means, and means 'for'supplying a refrigerant to said refrigerating unit and for automatically regulating the refrigerating eifect thereof in accordance with variations in the amount of ozonized air withdrawn from the chamber, comprising a heat responsive refrigerating system including said refrigerating unit, an electrical generator for energizing said electrical means, .an internal combustion engine drivably connected with said compressor and generator, the power output of said engine then varying in proportion to the load on the compressor and electrical means and hence varying ,in accordance with the variation in the amount of ozonized air withdrawn, and means .to transmit heat generated incidental to
  • An apparatus for producing ozone comprising an air compressor, an air motor, and an ozonizing chamber, means to conduct compressed air from said compressor to said motor to drive the same and from the motor to said chamber, electrical discharge means within said chamber for ozonizing the air conducted thereto, a fan drivably connected with the air motor and positioned within the chamber forlcirculating air over said discharge means, means for varying the amount of o-Zonized air withdrawn from said chamber thereby varying the load on said compressor and electrical discharge means, and means for supplying a refrigerant to the exterior of the chamber and for automatically regulating the refrigerating effect thereof in accordance with variations in the amount of ozonized air Withdrawn from the chamber, comprising a heat responsive refrigerating system including said refrigerant supply means, an electrical generator for energizing said electrical means, an internal combustion engine drivably connected with the cmopressor and generator, the power output of the engine then varying in proportion to the load on the compressor and electricalmeans and hence varying in accordance
  • An apparatus for producing ozone comprising an air compressor, anairmotor, 'andan ozonizing chamber, .means to conduct compressed air from said compressor to said motor to drive the same and from the latter to said chamber, a refrigerating unit for cooling the air 'con'duc'te'd'from the compressor to themotor, a secondrefrigerating unit for cooling said chamber, electrical discharge means Within the chamber for ozonizing the air conducted thereto, -a fan 'drivably connected with the air motor and positioned'within the chamber for circulating air over said discharge means, means 'for Varying the amount of "ozon-ized air withdrawn from said chamber thereby varying the load on said compressor and electrical discharge means, and means for supplying a refrigerant to both said refrigerating unit and for automatically regulating the reftigeratinge'ffect thereof in accordance with variations-in the amount of ozonized air withdrawn from the chamber, comprising a heat responsive refrigerating system including both said ie'friger

Description

Patented July 30, 1946 APPARATUS FOR, PRODUCING OZONE Donald K. Allison, Beverly Hills, Calif.
Application June 29, 1942, Serial No. 448,987
8 Claims.
My invention relates to an apparatus for producing ozone, and among the objects of my invention are:
First, to provide an apparatus for producing ozone wherein the air to be treated is compressed and then subjected to refrigeration to remove moisture, as well as lower its temperature prior to introduction into the ozone chamber;
Second, to provide an apparatus of this character which employs a novel refrigerating system operated on energy otherwis wasted, thereby increasing the over-all efficiency;
Third, to provide an apparatus of this character wherein the amount of refrigeration automatically changes in response to changes in demand of ozone; and
Fourth, to provide an apparatus for producing ozone which is inherently capable of being formed into a compact, portable self-contained unit and which is particularly designed for the treatment of water.
The figure is a diagrammatical view of my apparatus for producing ozone.
Air to be treated in order to form ozone is drawn through a filter I by a compressor 2. The air is compressed and passed through a refrigerating unit or heat exchanger 3 which may remove not only the heat generated during compression but lower the temperature below that of the incoming air, and in cooling the air remove therefrom a large percentage of water which may be drained oif by a drain valve 411. The heat exchanger may comprise a shell 4 with a suitable refrigerating coil 5'therein, and may incorporate baflies 6 to insure proper heat transfer. The compressed and refrigerated air passes through a bleeder valve 1 to an air motor 8. The bleeder valve is a three-way valv providing connection between the refrigerator unit and the motor, or permitting discharge of the compressed air to atmosphere so as to by-pass the ozone generator, to be described hereinafter, during an initial warming up period.
The air motor drives a shaft 9 and propeller I0. The propeller I is mounted within an ozonizer chamber II which contains ozone generating elements I2. These may comprise sets of plates divided into two groups separated by dielectric material and connected to the secondary of a high voltage transformer I3. The ozonizer chamber II i provided with a jacket I4. The refrigerating unit and the jacket of the ozonizer chamber are connected to a refrigerant supply pipe I and to a refrigerant return pipe I6,
2 through which a refrigerant circulates; the refrigerant of course being isolated from the air.
The air from the air motor exhausts into the ozonizer chamber and circulates therein by means of the propeller and is drawn from the ozonizer chamber as needed through a discharge line I! controlled by a valve I8. Another control valve' is may be interposed between the filter I and compressor 2. V
The supply pipe and return pipes I5 and I6 are connected, respectively; to the lower and upper ends of an evaporator 2L A pump 22 is interposed in the supply pipe I5 so as to move liquid from the evaporator 2|. Various refrigerants may be used; ordinary water may be employed. The evaporator 2I is maintained at a sub-atmospheric pressure as will be described hereinafter. A float 23 which controls a valve 24 regulates the height of liquid in the evaporator, fluid being suppliedfrom a branch of a supply line 25 connected with a sump or reservoir 26.
The supply line also leads to a pump 21 which withdraws a refrigerant from the sump and delivers it to the jacket 28 of the internal combustion engine 29 which serves as a preheater, the engine 29 being provided with a governor controlled carburetor 29a, as shown. The heated refrigerant passes from the jacket'to a boiler 30.
In addition, the exhaust pipe 3| of the internal combustion engine is coiled in the boiler 30. The internal combustion engine drives an electric generator 32 for supplying current to drive the mo-' tors connected with the several pumps 22 and 21, as well as the compressor 2 and transformer I3.
Heated refrigerant in the gaseous phase is discharged through jets 33 extending. into vacuum pressure. Each of the condensers is provided with heat exchanger coils 38 which are connected to an evaporative cooler 39; a pump 49 maintains circulation. The last of the series 'of condensers 36 discharges into the sump 26, from which it is withdrawn for recycling, part of the refrigerant being heated by the otherwise wasted heat from the internal combustion engine and the other part circulating in the cold circuit of the refrigerating system, that is, through the supply and return pipes l5 and 16.
By utilizing the otherwise wasted heat of the internal combustion engine it is possible to so cool the air that the ozonizer operates at maximum efficiency. It should be noted that the process of ozonizing the air tends to heat it and that the amount of ozone that can be generated diminishes as the temperature of the air increases, so that it is of utmost .pratical importance to'maintain the air at as low a temperature as possible. It is also mandatory that the cost per unit of ozone produced be as low as possible. All of these desirable goals are attained by utilizing the Wasted heat of the internal combustion engine which supplies the power for the differentparts of the apparatus either by mechanical connection, as by the belt and pulley arrangement, 4| between engine and compressor, or through the generator and electrical motors supplied by the gen- A erator and connected to the parts tob'e operated.
A further important advantage is gained, namely, the demands on the internal combustion engine are, of course, proportional to the load on the compressor and the transformer. "When the quantity of ozone being drawn oil" is lowered the power requirements are lowered and therefore the heat generated by the internal combustion engine is lowered. As a consequence, the amount of refrigeration is reduced.
While the internal combustion engine has ample capacity for heating the refrigerant for the purposeof cooling the air to be ozonized, it is of course possible to provide a jacket on the compressor and absorb .heat from this source as well.
Various changes and alternate arrangements may be made within the scope of the appends claims, in which it is my intention to claim all novelty inherent in the invention.
I claim:
1. An apparatus for producing ozone comprising an air compressor, a refrigerating unit for chilling .air compressed by said compressor, an ozonizing chamber having electrical means associated therewith, means for conducting chilled air from said unit to said chamberfor ozonization by said electrical means, means for varying the amount of ozonized air withdrawn from said chamber thereby varying the load on said compressor and electrical means, and means 'for'supplying a refrigerant to said refrigerating unit and for automatically regulating the refrigerating eifect thereof in accordance with variations in the amount of ozonized air withdrawn from the chamber, comprising a heat responsive refrigerating system including said refrigerating unit, an electrical generator for energizing said electrical means, .an internal combustion engine drivably connected with said compressor and generator, the power output of said engine then varying in proportion to the load on the compressor and electrical means and hence varying ,in accordance with the variation in the amount of ozonized air withdrawn, and means .to transmit heat generated incidental to Operation of the engine to said heat responsive refrigerating system.
2. An apparatus for producing ozone comprising an air compressor, an air motor, and an ozonizing chamber, means to conduct compressed air from said compressor to said motor to drive the same and from the motor to said chamber, electrical discharge means within said chamber for ozonizing the air conducted thereto, a fan drivably connected with the air motor and positioned within the chamber forlcirculating air over said discharge means, means for varying the amount of o-Zonized air withdrawn from said chamber thereby varying the load on said compressor and electrical discharge means, and means for supplying a refrigerant to the exterior of the chamber and for automatically regulating the refrigerating effect thereof in accordance with variations in the amount of ozonized air Withdrawn from the chamber, comprising a heat responsive refrigerating system including said refrigerant supply means, an electrical generator for energizing said electrical means, an internal combustion engine drivably connected with the cmopressor and generator, the power output of the engine then varying in proportion to the load on the compressor and electricalmeans and hence varying in accordance Withthe'variat'ions in't'he amount of ozonized air withdrawn from said chamber, and means totransmit heat generated incidental to the operation of .the engine to said heat responsive refrigeratingsystem.
3. An apparatus for producing ozone comprising an air compressor, anairmotor, 'andan ozonizing chamber, .means to conduct compressed air from said compressor to said motor to drive the same and from the latter to said chamber, a refrigerating unit for cooling the air 'con'duc'te'd'from the compressor to themotor, a secondrefrigerating unit for cooling said chamber, electrical discharge means Within the chamber for ozonizing the air conducted thereto, -a fan 'drivably connected with the air motor and positioned'within the chamber for circulating air over said discharge means, means 'for Varying the amount of "ozon-ized air withdrawn from said chamber thereby varying the load on said compressor and electrical discharge means, and means for supplying a refrigerant to both said refrigerating unit and for automatically regulating the reftigeratinge'ffect thereof in accordance with variations-in the amount of ozonized air withdrawn from the chamber, comprising a heat responsive refrigerating system including both said ie'frigerating units, an electrical generator for energizing -said .DONA'LD lK. ALLISON.
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Cited By (28)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US2660559A (en) * 1949-08-31 1953-11-24 Maryland Lab Inc Method and apparatus for the purification of liquids
US2704274A (en) * 1946-10-25 1955-03-15 Robert W Fulwider Apparatus and method for producing liquid ozone
US3872313A (en) * 1974-03-13 1975-03-18 Aerojet General Co Ozone generator
US3884819A (en) * 1974-08-19 1975-05-20 Ozone Inc Gas cooling and drying system for corona discharge ozone generating unit
US4164850A (en) * 1975-11-12 1979-08-21 Lowi Jr Alvin Combined engine cooling system and waste-heat driven automotive air conditioning system
US4342200A (en) * 1975-11-12 1982-08-03 Daeco Fuels And Engineering Company Combined engine cooling system and waste-heat driven heat pump
US4627924A (en) * 1983-03-29 1986-12-09 Degremont Process and apparatus for the recovery of energy from an ozone production unit
US4859429A (en) * 1988-06-30 1989-08-22 Technological Resources Corp. Ozone generating device
US5117648A (en) * 1990-10-16 1992-06-02 Northeastern University Refrigeration system with ejector and working fluid storage
US5239837A (en) * 1990-10-16 1993-08-31 Northeastern University Hydrocarbon fluid, ejector refrigeration system
US5241720A (en) * 1992-09-04 1993-09-07 Tri-O-Clean Laundry Systems, Inc. Laundry waste water treatment and wash process
US5435978A (en) * 1991-08-08 1995-07-25 Sumitomo Precision Products Co., Ltd. Plate-type ozonizer
US5697187A (en) * 1995-12-13 1997-12-16 Oxlon, Inc. Method for treatment of crops by an irrigation solution
US20080127913A1 (en) * 2004-12-24 2008-06-05 Renault Trucks Engine Cooling System
WO2008118564A2 (en) * 2007-03-06 2008-10-02 Steris Inc. Decontamination unit and process
US8960581B1 (en) 2004-08-11 2015-02-24 Genesis Iii, Inc. Hammer
US8998120B1 (en) 2009-05-22 2015-04-07 Genesis Iii, Inc. Curved hammer
US9358546B1 (en) 2011-08-03 2016-06-07 Genesis Iii, Inc. Multi-connector hammer and protective arm
USD839934S1 (en) 2017-12-06 2019-02-05 Roger Young Swing hammer
US10201814B1 (en) 2004-08-11 2019-02-12 Genesis Iii, Inc. Hammer
USD840447S1 (en) 2017-12-06 2019-02-12 Roger Young Swing hammer
US10207274B1 (en) 2017-08-21 2019-02-19 Roger Young Non-forged hammermill hammer
USD861048S1 (en) 2017-12-06 2019-09-24 Roger Young Swing hammer
US10478824B2 (en) 2017-08-21 2019-11-19 Bliss Industries, Llc System and method for installing hammers
US10486160B2 (en) 2017-08-21 2019-11-26 Bliss Industries, Llc Method of replacing hammers and spacers
US10610870B2 (en) 2017-08-21 2020-04-07 Bliss Industries, Llc Hot and cold forming hammer and method of assembly
USD905136S1 (en) 2018-03-05 2020-12-15 Bliss Industries, Llc Hammermill hammer
US11839879B2 (en) 2020-10-09 2023-12-12 Genesis Iii, Inc. Hammer

Cited By (44)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US2704274A (en) * 1946-10-25 1955-03-15 Robert W Fulwider Apparatus and method for producing liquid ozone
US2660559A (en) * 1949-08-31 1953-11-24 Maryland Lab Inc Method and apparatus for the purification of liquids
US3872313A (en) * 1974-03-13 1975-03-18 Aerojet General Co Ozone generator
US3884819A (en) * 1974-08-19 1975-05-20 Ozone Inc Gas cooling and drying system for corona discharge ozone generating unit
US4164850A (en) * 1975-11-12 1979-08-21 Lowi Jr Alvin Combined engine cooling system and waste-heat driven automotive air conditioning system
US4342200A (en) * 1975-11-12 1982-08-03 Daeco Fuels And Engineering Company Combined engine cooling system and waste-heat driven heat pump
US4627924A (en) * 1983-03-29 1986-12-09 Degremont Process and apparatus for the recovery of energy from an ozone production unit
US4859429A (en) * 1988-06-30 1989-08-22 Technological Resources Corp. Ozone generating device
US5309736A (en) * 1990-10-16 1994-05-10 Northeastern University Hydrocarbon fluid, ejector refrigeration system
US5239837A (en) * 1990-10-16 1993-08-31 Northeastern University Hydrocarbon fluid, ejector refrigeration system
US5117648A (en) * 1990-10-16 1992-06-02 Northeastern University Refrigeration system with ejector and working fluid storage
US5435978A (en) * 1991-08-08 1995-07-25 Sumitomo Precision Products Co., Ltd. Plate-type ozonizer
US5241720A (en) * 1992-09-04 1993-09-07 Tri-O-Clean Laundry Systems, Inc. Laundry waste water treatment and wash process
WO1994005845A1 (en) * 1992-09-04 1994-03-17 Tri-O-Clean Laundry Systems, Inc. Laundry waste water treatment and wash process
US5697187A (en) * 1995-12-13 1997-12-16 Oxlon, Inc. Method for treatment of crops by an irrigation solution
US8960581B1 (en) 2004-08-11 2015-02-24 Genesis Iii, Inc. Hammer
US10201814B1 (en) 2004-08-11 2019-02-12 Genesis Iii, Inc. Hammer
US11185866B2 (en) 2004-08-11 2021-11-30 Genesis Iii, Inc. Hammer
US9566584B2 (en) 2004-08-11 2017-02-14 Genesis Iii, Inc. Hammer
US9737894B1 (en) 2004-08-11 2017-08-22 Genesis Iii, Inc. Hammer
US11103875B1 (en) 2004-08-11 2021-08-31 Genesis Iii, Inc. Hammer
US7673593B2 (en) * 2004-12-24 2010-03-09 Renault Trucks Engine cooling system
US20080127913A1 (en) * 2004-12-24 2008-06-05 Renault Trucks Engine Cooling System
WO2008118564A2 (en) * 2007-03-06 2008-10-02 Steris Inc. Decontamination unit and process
US20080279721A1 (en) * 2007-03-06 2008-11-13 Weiss Richard A Decontamination unit and process
WO2008118564A3 (en) * 2007-03-06 2008-12-24 Steris Inc Decontamination unit and process
US7993601B2 (en) 2007-03-06 2011-08-09 Steris Inc. Decontamination unit and process
US8998120B1 (en) 2009-05-22 2015-04-07 Genesis Iii, Inc. Curved hammer
US11759789B1 (en) 2009-05-22 2023-09-19 Genesis Iii, Inc. Curved hammer
US10857540B1 (en) 2009-05-22 2020-12-08 Genesis Iii, Inc. Curved hammer
US10486159B2 (en) 2011-08-03 2019-11-26 Genesis Iii, Inc. Multi-connector hammer
US11396021B2 (en) 2011-08-03 2022-07-26 Genesis Iii, Inc. Multi-connector hammer
US9358546B1 (en) 2011-08-03 2016-06-07 Genesis Iii, Inc. Multi-connector hammer and protective arm
US10478824B2 (en) 2017-08-21 2019-11-19 Bliss Industries, Llc System and method for installing hammers
US10486160B2 (en) 2017-08-21 2019-11-26 Bliss Industries, Llc Method of replacing hammers and spacers
US10507468B2 (en) 2017-08-21 2019-12-17 Bliss Industries, Llc Non-forged hammermill hammer
US10610870B2 (en) 2017-08-21 2020-04-07 Bliss Industries, Llc Hot and cold forming hammer and method of assembly
US10207274B1 (en) 2017-08-21 2019-02-19 Roger Young Non-forged hammermill hammer
USD840447S1 (en) 2017-12-06 2019-02-12 Roger Young Swing hammer
USD839934S1 (en) 2017-12-06 2019-02-05 Roger Young Swing hammer
USD861048S1 (en) 2017-12-06 2019-09-24 Roger Young Swing hammer
USD857066S1 (en) 2017-12-06 2019-08-20 Roger Young Swing hammer
USD905136S1 (en) 2018-03-05 2020-12-15 Bliss Industries, Llc Hammermill hammer
US11839879B2 (en) 2020-10-09 2023-12-12 Genesis Iii, Inc. Hammer

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