US2423290A - Aluminum conducting surface treatment - Google Patents

Aluminum conducting surface treatment Download PDF

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Publication number
US2423290A
US2423290A US591813A US59181345A US2423290A US 2423290 A US2423290 A US 2423290A US 591813 A US591813 A US 591813A US 59181345 A US59181345 A US 59181345A US 2423290 A US2423290 A US 2423290A
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Prior art keywords
zinc
cable
aluminum
petrolatum
surface treatment
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Expired - Lifetime
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US591813A
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Bonwitt Wilhelm Friedrich
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FCI USA LLC
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Burndy Engineering Co Inc
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Priority to US591813A priority Critical patent/US2423290A/en
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    • HELECTRICITY
    • H01ELECTRIC ELEMENTS
    • H01RELECTRICALLY-CONDUCTIVE CONNECTIONS; STRUCTURAL ASSOCIATIONS OF A PLURALITY OF MUTUALLY-INSULATED ELECTRICAL CONNECTING ELEMENTS; COUPLING DEVICES; CURRENT COLLECTORS
    • H01R4/00Electrically-conductive connections between two or more conductive members in direct contact, i.e. touching one another; Means for effecting or maintaining such contact; Electrically-conductive connections having two or more spaced connecting locations for conductors and using contact members penetrating insulation
    • H01R4/58Electrically-conductive connections between two or more conductive members in direct contact, i.e. touching one another; Means for effecting or maintaining such contact; Electrically-conductive connections having two or more spaced connecting locations for conductors and using contact members penetrating insulation characterised by the form or material of the contacting members
    • H01R4/62Connections between conductors of different materials; Connections between or with aluminium or steel-core aluminium conductors
    • YGENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y10TECHNICAL SUBJECTS COVERED BY FORMER USPC
    • Y10TTECHNICAL SUBJECTS COVERED BY FORMER US CLASSIFICATION
    • Y10T29/00Metal working
    • Y10T29/49Method of mechanical manufacture
    • Y10T29/49826Assembling or joining
    • Y10T29/49885Assembling or joining with coating before or during assembling

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Description

ALUMINUM CONDUCTING SURFACE TREATMENT Filed lay 3, 1945 In wa IIIIIIJIIIII III] Ill Zint-Peirdlalam 122/ M1 AT OR EY Patented July 1, 1947 ALUIVIINUM CONDUCTING SURFACE TREATMENT Wilhelm Friedrich Bonwitt, Mount Vernon, N. Y., assignor to Burndy Engineering Company, Inc.,
3 Claims.
My invention relates to a method for treating aluminum conductors and/or connectors to increase the electrical joint efficiency of the connection between the two. This application is a continuation-in-part of my application entitled Aluminum conductor surface treatment," filed June 26-, 1943, Ser. No. 492,416.
In my earlier application I disclosed a method 01 treating aluminum surfaces by first applying concentrated nitric acid to the surface, drying the treated surface by air, and thereafter covering the surface with a zinc-petrolatum coating.
In the present application I have discovered a corporation of New York Application May 3, 1945, Serial No. 591,813
that the electrical resistance of the connection canbe reduced, especially where a stranded aluminum cable is employed, by just coating the strands of the cable with the zinc-petrolatum.
Accordingly the primary object of my invention is to provide a method of treating aluminum conductors, and/or connectors, so that a connection comprising a connector secured by pressure to an aluminum conductor will have an electrical resistance equal to or less than an unbroken cable having the same length as the combined connection.
Another object is to provide a method of treating such a connection where the conductor comprises a stranded aluminum cable.
I accomplish thee and other objects and obtain my new results as will be apparent from the device described in the following specification, particularly pointed out in the claims, and illustrated in the accompanying drawing in which:
Fig. 1 is an exploded side view of a piece of aluminum stranded cable and an electrical terminal connector, shown in section and filled with zinc-petrolatum.
Fig. 2 is a side view showing in section the final connection.
In the drawing, reference numeral l0 designates an aluminum terminal, having a tongue section II provided with an aperture 12, and a barrel [3, having a bore i4 sufilcient in diameter to receive an aluminum conductor designated as I5, composed oi strands H5.
The bore i4 is completely filled with zincpetrolatum IT, a mixture of metallic zinc dust suspended in a heavy petrolatum jelly, and when a connection is desired, the cable I5 is inserted 'into the bore of the barrel, forcing the zincpetrolatum to completely fill the interstices of the cable end. The final indentation of the barrel as shown by reference numeral I8, results in a final connection that has approximately one-half the electrical resistance of the untreated connection.
This has been brought out by tests in which untreated connections were compared to connections that were treated in the foregoing manner.
For a pair of terminals indented to the ends of short lengths of No. 4 aluminum aircraft cable to form jumpers having an overall length of 2%", the resistance in microhms for the untreated connections was 91.92. Where the cable ends were treated with the zinc-petrolatum the resistance was 69.57. In other words, the relative conductivity in percent had increased from 88.9 to 117.5.
The improvement can be attributed to the method of treatment alone since all other variables such as size, stranding of cable, size of terminal, depth of indentation, length, etc., were kept constant.
Thus, starting with exactly the same cable, terminal, and indentation, the electrical conductivity of the finished connection can be increased by one-third by the addition of the zinc-petro- -latum treatment alone.
In addition to providing lower initial resistance, the zinc-petrolatum mixture helps to inhibit corrosion of the cable connection as was pointed out in my earlier application. The tests made show, after considerable exposure, a relatively small increase in resistance of the treated connections, as compared with the larger increase in resistance of the untreated connections.
The zinc-petrolatum having considerable zinc dust contained therein, the pressure of the indented connection is apparently suillcient to cause the zinc dust to penetrate the oxide film formed on the aluminum surfaces and to furnish a conducting path from aluminum to aluminum through the zinc particles. Where stranded cable is used, and the zinc petrolatum is forced between the ends of the cable strands, the particles of metallic zinc coating each strand, break through the film of oxide and thereby provide numerous low resistance current paths from strand to strand, and from strand to connector. This effecti'vely reduces the transverse resistance between strands, and prevents the cable from operating as a series of parallel conductors having high resistance between them.- Moreover the zinc-petrolatum prevents and inhibits the formation of oxides and other products of corrosion in the electrical connection after it has been made and is in actual use.
Where a terminal is provided with an open back, it is important to temporarily close this second opening while inserting the cable, in order to prevent the zinc-petrolatum from escaping from the open back instead of penetrating the stranded cable end. This temporary blocking of the open back may be accomplished by covering the second opening with a finger during the insertion of the cable.
It is possible to use a metal other than zinc. and a binder other than petrolatum. A metal to replace zinc would have to be close to zinc in the galvanic series. Such a metal would be cadmium, magnesium, etc. The substitute for petrolatum would have to be some unctuous substance, nondrying, and have the consistency of substantially that of petrolatum at room temperature. Many wax or wax-like substances have these properties,
When convenient, the contacting connector may be cleaned by degreasing using Oakite, etched by a trisodium phosphate solution, bright dipped in diluted nitric acid and zinc flashed. Other materials may be used to accomplish these operations. Some additional improvements in the electrical and corrosion characteristics may be thus obtained.
I have thus described my invention, but I desire it understood that it is not confined to the particular forms or uses shown and described, the same being merely illustrative, and that the invention may be carried out in other ways Without departing from the spirit of my invention, and, therefore, I claim broadly the right to employ all equivalent instrumentalities coming within the scope of the appended claims, and by means of which, objects of my invention are attained and new results accomplished, as it is obvious that the particular embodiments herein shown and described are only some of the many that can be employed to attain these objects and accomplish these results.
I claim:
4 1. An electrical connector having a. tubular body for inserting an aluminum conductor therein, said body completely filled with a material comprising a mixture of an unctuous substance with fine metal particles taken from a group WILHELM FRIEDRICH BONWI'IT.
REFERENCES CITED The following references are of record in the file of this patent:
UNITED STATES PATENTS Number Name Date 1,863,429 Willmore June 14, 1932 1,548,552 Prax Aug. 4, 1925 2,038,535 Brenizer Apr. 28, 1936 FOREIGN PATENTS Number Country Date 363,075 Great Britain Dec. 17, 1931
US591813A 1945-05-03 1945-05-03 Aluminum conducting surface treatment Expired - Lifetime US2423290A (en)

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Cited By (34)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US2551299A (en) * 1943-10-06 1951-05-01 Aircraft Marine Prod Inc Electrical connector and method of making the same
US2632237A (en) * 1953-03-24 Method of making a mechanical joint
US2635163A (en) * 1950-12-30 1953-04-14 Wiegand Co Edwin L Electric heating
US2666803A (en) * 1950-05-13 1954-01-19 Burgess Battery Co Battery with conductive wax intercell connections
US2702756A (en) * 1950-05-13 1955-02-22 Burgess Battery Co Electrically conductive wax compositions
US2766194A (en) * 1953-04-15 1956-10-09 Philco Corp Method of plating
US2815497A (en) * 1953-04-23 1957-12-03 Amp Inc Connector for aluminum wire
US2858516A (en) * 1956-01-16 1958-10-28 Earl F Lindahl Connector for electrical conductors
US2869103A (en) * 1953-06-02 1959-01-13 Amp Inc Metal-bearing paste and aluminum connection containing the same
US2868863A (en) * 1954-01-05 1959-01-13 Kaiser Aluminium Chem Corp Aluminum to copper connection
US2897409A (en) * 1954-10-06 1959-07-28 Sprague Electric Co Plating process
US2901722A (en) * 1953-04-21 1959-08-25 Burndy Corp Coating for metal to reduce electrical contact resistance
US2906987A (en) * 1955-12-28 1959-09-29 Amp Inc Stabilized crimped connections
US2951228A (en) * 1956-04-11 1960-08-30 Amp Inc Electrical connector
US2951110A (en) * 1956-10-17 1960-08-30 Burndy Corp Sealed mixture-containing connector
US2968788A (en) * 1956-10-17 1961-01-17 Burndy Corp Electric terminal
US2970204A (en) * 1958-02-27 1961-01-31 Piceu Electric welding method and composition
US3040292A (en) * 1959-07-15 1962-06-19 Bernard Welding Equip Co Cable connector
US3156763A (en) * 1961-06-19 1964-11-10 Aluminum Co Of America Electrical conductor joining practices
US3266008A (en) * 1964-01-13 1966-08-09 Essex Wire Corp Electrical terminal and method of applying same to conductors
US3332867A (en) * 1963-10-03 1967-07-25 Walter L Miller Conductive adhesive bonding of a galvanic anode to a hull
US3426143A (en) * 1966-12-21 1969-02-04 Nat Telephone Supply Co The Dead end connector and connection for aluminum conductors
US3864234A (en) * 1973-05-08 1975-02-04 Smith Corp A O Cathodic Protection System for Water Heaters with Sealant
US3869361A (en) * 1972-12-26 1975-03-04 Trw Inc Method for making an electrically-conductive connection specifically for underground lines
US3912358A (en) * 1973-06-19 1975-10-14 Roger D Miller Aluminum alloy compression type connectors for use with aluminum or copper conductors
US3914001A (en) * 1973-12-26 1975-10-21 Reynolds Metals Co Electrical grounding apparatus and method and washer for use therewith
US5476576A (en) * 1991-08-15 1995-12-19 Winn And Coales International Limited Impressed current cathodic protection system
US5828008A (en) * 1997-02-06 1998-10-27 Barnstead/Thermolyne Fastener assembly for establishing a mechanical and electrical connection to coated metal
US20060292922A1 (en) * 2004-03-23 2006-12-28 Gebauer & Griller Kabelwerke Gesellschaft M.B.H. Process for connecting terminal elements to an electrical conductor consisting of aluminum, and electrical conductor produced by the process
US20070184715A1 (en) * 2002-12-20 2007-08-09 Yazaki Corporation Method of connecting terminal and electric wire
US20140235116A1 (en) * 2011-08-31 2014-08-21 Autonetworks Technologies, Ltd. Aluminum-based terminal fitting
EP2786449A4 (en) * 2011-11-29 2017-04-19 Ideal Industries Inc. Methods and apparatus for preventing oxidation of an electrical connection
US20170346198A1 (en) * 2016-05-24 2017-11-30 Hubbell Incorporated Oxide inhibitor capsule
USD868701S1 (en) * 2014-08-07 2019-12-03 Henkel Ag & Co. Kgaa Overhead transmission conductor cable

Citations (4)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US1548552A (en) * 1920-06-16 1925-08-04 Joseph F Prax Battery connection
GB363075A (en) * 1930-02-17 1931-12-17 Vaw Ver Aluminium Werke Ag A method of obtaining good contact between conductors of aluminium and its alloys
US1863429A (en) * 1929-11-18 1932-06-14 Aluminum Co Of America Bus bar joint
US2038535A (en) * 1934-11-19 1936-04-28 Andrew V Groupe Art of joining wires with sleeves

Patent Citations (4)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US1548552A (en) * 1920-06-16 1925-08-04 Joseph F Prax Battery connection
US1863429A (en) * 1929-11-18 1932-06-14 Aluminum Co Of America Bus bar joint
GB363075A (en) * 1930-02-17 1931-12-17 Vaw Ver Aluminium Werke Ag A method of obtaining good contact between conductors of aluminium and its alloys
US2038535A (en) * 1934-11-19 1936-04-28 Andrew V Groupe Art of joining wires with sleeves

Cited By (36)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US2632237A (en) * 1953-03-24 Method of making a mechanical joint
US2551299A (en) * 1943-10-06 1951-05-01 Aircraft Marine Prod Inc Electrical connector and method of making the same
US2666803A (en) * 1950-05-13 1954-01-19 Burgess Battery Co Battery with conductive wax intercell connections
US2702756A (en) * 1950-05-13 1955-02-22 Burgess Battery Co Electrically conductive wax compositions
US2635163A (en) * 1950-12-30 1953-04-14 Wiegand Co Edwin L Electric heating
US2766194A (en) * 1953-04-15 1956-10-09 Philco Corp Method of plating
US2901722A (en) * 1953-04-21 1959-08-25 Burndy Corp Coating for metal to reduce electrical contact resistance
US2815497A (en) * 1953-04-23 1957-12-03 Amp Inc Connector for aluminum wire
US2869103A (en) * 1953-06-02 1959-01-13 Amp Inc Metal-bearing paste and aluminum connection containing the same
US2868863A (en) * 1954-01-05 1959-01-13 Kaiser Aluminium Chem Corp Aluminum to copper connection
US2897409A (en) * 1954-10-06 1959-07-28 Sprague Electric Co Plating process
US2906987A (en) * 1955-12-28 1959-09-29 Amp Inc Stabilized crimped connections
US2858516A (en) * 1956-01-16 1958-10-28 Earl F Lindahl Connector for electrical conductors
US2951228A (en) * 1956-04-11 1960-08-30 Amp Inc Electrical connector
US2951110A (en) * 1956-10-17 1960-08-30 Burndy Corp Sealed mixture-containing connector
US2968788A (en) * 1956-10-17 1961-01-17 Burndy Corp Electric terminal
US2970204A (en) * 1958-02-27 1961-01-31 Piceu Electric welding method and composition
US3040292A (en) * 1959-07-15 1962-06-19 Bernard Welding Equip Co Cable connector
US3156763A (en) * 1961-06-19 1964-11-10 Aluminum Co Of America Electrical conductor joining practices
US3332867A (en) * 1963-10-03 1967-07-25 Walter L Miller Conductive adhesive bonding of a galvanic anode to a hull
US3266008A (en) * 1964-01-13 1966-08-09 Essex Wire Corp Electrical terminal and method of applying same to conductors
US3426143A (en) * 1966-12-21 1969-02-04 Nat Telephone Supply Co The Dead end connector and connection for aluminum conductors
US3869361A (en) * 1972-12-26 1975-03-04 Trw Inc Method for making an electrically-conductive connection specifically for underground lines
US3864234A (en) * 1973-05-08 1975-02-04 Smith Corp A O Cathodic Protection System for Water Heaters with Sealant
US3912358A (en) * 1973-06-19 1975-10-14 Roger D Miller Aluminum alloy compression type connectors for use with aluminum or copper conductors
US3914001A (en) * 1973-12-26 1975-10-21 Reynolds Metals Co Electrical grounding apparatus and method and washer for use therewith
US5476576A (en) * 1991-08-15 1995-12-19 Winn And Coales International Limited Impressed current cathodic protection system
US5828008A (en) * 1997-02-06 1998-10-27 Barnstead/Thermolyne Fastener assembly for establishing a mechanical and electrical connection to coated metal
US20070184715A1 (en) * 2002-12-20 2007-08-09 Yazaki Corporation Method of connecting terminal and electric wire
US20060292922A1 (en) * 2004-03-23 2006-12-28 Gebauer & Griller Kabelwerke Gesellschaft M.B.H. Process for connecting terminal elements to an electrical conductor consisting of aluminum, and electrical conductor produced by the process
US20140235116A1 (en) * 2011-08-31 2014-08-21 Autonetworks Technologies, Ltd. Aluminum-based terminal fitting
US9490550B2 (en) * 2011-08-31 2016-11-08 Autonetworks Technologies, Ltd. Aluminum-based terminal fitting
EP2786449A4 (en) * 2011-11-29 2017-04-19 Ideal Industries Inc. Methods and apparatus for preventing oxidation of an electrical connection
USD868701S1 (en) * 2014-08-07 2019-12-03 Henkel Ag & Co. Kgaa Overhead transmission conductor cable
US20170346198A1 (en) * 2016-05-24 2017-11-30 Hubbell Incorporated Oxide inhibitor capsule
US10505292B2 (en) * 2016-05-24 2019-12-10 Hubbell Incorporated Oxide inhibitor capsule

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