US2911280A - Methods of printing textile fabrics - Google Patents

Methods of printing textile fabrics Download PDF

Info

Publication number
US2911280A
US2911280A US625634A US62563456A US2911280A US 2911280 A US2911280 A US 2911280A US 625634 A US625634 A US 625634A US 62563456 A US62563456 A US 62563456A US 2911280 A US2911280 A US 2911280A
Authority
US
United States
Prior art keywords
fabric
printing
pattern
layer
fabrics
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Expired - Lifetime
Application number
US625634A
Inventor
Cicogna Lucio
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Star Stampa Tessuti Artistici SpA
Original Assignee
Star Stampa Tessuti Artistici SpA
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Star Stampa Tessuti Artistici SpA filed Critical Star Stampa Tessuti Artistici SpA
Application granted granted Critical
Publication of US2911280A publication Critical patent/US2911280A/en
Anticipated expiration legal-status Critical
Expired - Lifetime legal-status Critical Current

Links

Classifications

    • D—TEXTILES; PAPER
    • D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
    • D06P—DYEING OR PRINTING TEXTILES; DYEING LEATHER, FURS OR SOLID MACROMOLECULAR SUBSTANCES IN ANY FORM
    • D06P5/00—Other features in dyeing or printing textiles, or dyeing leather, furs, or solid macromolecular substances in any form
    • D06P5/003—Transfer printing
    • D06P5/007—Transfer printing using non-subliming dyes
    • D06P5/008—Migrating dyes
    • Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y10—TECHNICAL SUBJECTS COVERED BY FORMER USPC
    • Y10S—TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y10S8/00—Bleaching and dyeing; fluid treatment and chemical modification of textiles and fibers
    • Y10S8/916—Natural fiber dyeing
    • Y10S8/917—Wool or silk
    • Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y10—TECHNICAL SUBJECTS COVERED BY FORMER USPC
    • Y10S—TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y10S8/00—Bleaching and dyeing; fluid treatment and chemical modification of textiles and fibers
    • Y10S8/916—Natural fiber dyeing
    • Y10S8/918—Cellulose textile
    • Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y10—TECHNICAL SUBJECTS COVERED BY FORMER USPC
    • Y10S—TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y10S8/00—Bleaching and dyeing; fluid treatment and chemical modification of textiles and fibers
    • Y10S8/92—Synthetic fiber dyeing
    • Y10S8/921—Cellulose ester or ether
    • Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y10—TECHNICAL SUBJECTS COVERED BY FORMER USPC
    • Y10S—TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y10S8/00—Bleaching and dyeing; fluid treatment and chemical modification of textiles and fibers
    • Y10S8/92—Synthetic fiber dyeing
    • Y10S8/924—Polyamide fiber

Definitions

  • This invention relates to improvements in methods of printing textile fabrics.
  • a method of printing textile fabrics, more particularly transferring colored patterns on to fabrics is known, by which a multi-colored pattern is first printed on an inextensible support, then transferred onto the fabric by superposing said support on the fabric and subjecting both to the action of pressure, heat and solvents, the inextensible support being preferably paper the surface of which adapted to receive the colored pattern is treated so as to cause the dyestuffs by which the pattern is formed to temporarily adhere to the support, whereby they are readily transferred on to the fabric.
  • U.S. Patent No. 2,583,286 (Albini-Colombo) describes in detail a method of the kind referred to above and indicates the nature of the substances to be used for treating the surface of the inextensible support and substances to be admixed to the dyestuffs to make possible the transfer of multi-colored patterns from the inextensible support to the fabric.
  • a further purpose of this invention is to facilitate in a method of the kind referred to above removal of the dyestuff from the inextensible support, transfer thereof onto the fabric and firm anchoring to the latter without spreading beyond the regions to be dyed or staining the fabrics by the action of substances admixed to the dyestuffs in order to adapt them for printing on paper and transferring the colored patterns from the latter on to the fabric.
  • a further purpose of this invention is to print on textile fabrics colored patterns which are durable and maintain gloss and intensity of colors even after usual washing and steaming treatment to which fabrics are normally subjected for finishing.
  • a further purpose of this invention is to provide a method of printing colored patterns of fabrics which is easy and inexpensive to carry out, whereby overall cost ofvmanufacture of printed fabrics is reduced.
  • This second coating is then dried.
  • (2) Printing the colored pattern on paper. This step is carried out by firstly preparing a fluid mixture by mixing together in the manner described above the following substances in the proportions indicated:
  • Printing of colored patterns on the paper surface coated as described above is efiected by means of machines for calcographic printing, preferably by a continuous process using rotative machines for calcographic printing.
  • the inextensible support is in the form of a long paper, web unwinding from a spool and travelling through the cylinders of the machine.
  • the cylinders of the printing machine are engraved to a depth such as to leave on paper about 4 grams per square meter surface.
  • the latter should be fluid enough to readily wet the cylinders and quickly dry as the paper travels from one cylinder to the next one.
  • This step is carried out by causing the fabric and paper web to travel in superposed relationship between two suitably heated pressure cylinders.
  • the equipment for carrying out this step can be of the type disclosed by US. Patent No. 2,583,286.
  • the temperature and pressure adopted during this step of transferring the colored pattern onto the fabrics amounts to 150 C. and 100-150 kg./square centimeter, respectively. However, these values may undergo certain variations according to the type of fabric onto which the colored pattern is transferred.
  • the resinous substances in the second paper coating layer melt and act to bind the dyestuif to the paper.
  • the raised temperature moreover promotes penetration of the colored mass into the fabric and is largely snfficient for dissolving the paper coating, more particularly the first layer, the melting point of which is considerably lower, whereby removal of the dyestufis from the paper during the transfer step is facilitated.
  • the high pressure satisfactorily smooths the fabric surface and causes a thorough contact between the juxtaposed surfaces of the paper and fabric.
  • Lyoprint DA Ciba B Solvent salt, G Lyoprint and Rongalite are trade names of products available on the Italian market;
  • oil-soluble resins known as Albertol or Albertole resins are produced by heating phenolformaldehyde resins with a natural resin such as rosin or with rosin esters. The condensation reaction forming the phenol-formaldehyde resin may take place in the These oil-soluble phenolnaphtha, acetone, carbon tetrachloride and various petroleum distillates.
  • the non-stretchable carrier should receive the colored pattern only temporarily, then yield it under the combined action of heat and pressure without any spreading of the various colors and inherent alteration of the pattern, the substances with which the carrier is coated should melt at a temperature below the melting point of the substance incorporating the dye.
  • Albertol is a product which fully meets this requirement. Its melting point (105 C.) is higher than the melting point of the compositions with which the non stretchable carrier is coated.
  • Monopol soap has the property of lowering the melting temperature of the coating applied to the non-deformable carrier and makes possible adhesion of the dye to the non-deformable carrier, which would be impossible when using a soap containing coating and when the dye is dispersed in a resin dissolved in a solvent.
  • Monopol soap moreover facilitates dispersion of the practically water insoluble Albertol contained in the composition which according to this application is admitted to the dye, in water, during washing.
  • a method of printing fabrics by transferring a colored pattern from a non-deformable carrier onto fabric the steps of applying a first layer of a mixture comprising supersulphonated emulsifying oil, sodium sulphoricinate, sodium palmitate, butyl Cellosolve and distilled water, coating said first layer with a second layer of a mixture comprising supersulphonated emulsifying oil containing sodium sulphoricinate, zinc stearate, xylene and a resin obtained from the condensation of phenolformaldehyde with admixture of colophonium and rosin esters, color-printing the pattern on the treated side of said non-deformable carrier, said design consisting of a dye admixed with a binder washable during the final treatment of the fabric, treating the fabric with substances adapted to set the dyes, transferring the pattern on to the fabric, setting of the dyes by steaming the fabric and washing off the binder.

Description

United States Patent METHODS PRINTING TEXTILE FABRICS Lucio Cicogna, Milan, Italy, assiguor to Star Stampa Tessuti Artistici S.p.A., Milan, Italy N Drawing. Application December 3, 1956 Serial No. 625,634
This invention relates to improvements in methods of printing textile fabrics.
A method of printing textile fabrics, more particularly transferring colored patterns on to fabrics is known, by which a multi-colored pattern is first printed on an inextensible support, then transferred onto the fabric by superposing said support on the fabric and subjecting both to the action of pressure, heat and solvents, the inextensible support being preferably paper the surface of which adapted to receive the colored pattern is treated so as to cause the dyestuffs by which the pattern is formed to temporarily adhere to the support, whereby they are readily transferred on to the fabric.
U.S. Patent No. 2,583,286 (Albini-Colombo) describes in detail a method of the kind referred to above and indicates the nature of the substances to be used for treating the surface of the inextensible support and substances to be admixed to the dyestuffs to make possible the transfer of multi-colored patterns from the inextensible support to the fabric.
However, practical results attained in carrying out the method according to said patent proved fully runsatisfactory in a number of cases, more particularly when the patterns are printed on the paper by means of machines for calcographic printing generally, especially continuously operating rotative machines for calcographic printing. In fact, U.S. Patent No..2,583,286 proposes using mixtures which, if prepared in accordance with the percentages of ingredients indicates, make the method disclosed by said patent fully unpracticable.
It is purpose of this invention to provide a method of printing textile fabrics by transferring colored patterns from an inextensible support such as paper, on to fabrics through the action of heat and pressure which makes it possible to print the colored pattern on said inextensible support through the use of machines, for calcographic printing, especially continuously operating rotative machines for calcographic printing.
,A further purpose of this invention is to facilitate in a method of the kind referred to above removal of the dyestuff from the inextensible support, transfer thereof onto the fabric and firm anchoring to the latter without spreading beyond the regions to be dyed or staining the fabrics by the action of substances admixed to the dyestuffs in order to adapt them for printing on paper and transferring the colored patterns from the latter on to the fabric. V
A further purpose of this invention is to print on textile fabrics colored patterns which are durable and maintain gloss and intensity of colors even after usual washing and steaming treatment to which fabrics are normally subjected for finishing.
A further purpose of this invention is to provide a method of printing colored patterns of fabrics which is easy and inexpensive to carry out, whereby overall cost ofvmanufacture of printed fabrics is reduced.
' The above and further purposes and advantages of the ice Patented Nov. 3', 1959 invention will be clear-1y understood from the appended specification including preferred examples of substances to be used for carrying out my improved method and further useful measures for full success thereof.
As mentioned above, my improved process has been developed with a view to utilising for temporary applying the colored pattern to the inextensible support, such as paper machines for calcographic printing, more particularly rotative machines for calcographic printing.
' With this object in view as well as in order to afiford a satisfactory transfer of the colors from the inextensible support on to the fabrics the method comprises the following steps: 7
1) Coating the surface of the inextensible support adapt to temporarily receive the colored pattern by substances adapted to'improve transfer of the dyestuffs on said support on to the fabric in the next step.
Example: Monoglossy paperhaving a Weight of 60-70 grams per square meter is first coated with a layer weighing about 4 grams per square meter'of dry extract, obtained from a mixture prepared as follows:
I dissolve in the cold, then heat in a Water-bath to a temperature of about 40-50" C. the following roportions of:
Percent by weight Supersulphonated emulsifying oil containing sodium sulphoricinate Sodium palmitate 30 Butyl Cellosolve 38 Distilled water. 18
The paper is dried then covered by a second coating comprising a layer weight about 0.5 gram per square meter of dry extract, obtained from a mixture prepared in the above described manner and comprising:
7 Percent by weight Supersulphonated emulsifying oil containing sodium sulphoricinate 4 Zinc stearate 0.5 Xylene e Resin from condensation of phenol-formaldehyde with admixture of c'olophom'um and rosin esters 0.5
This second coating is then dried. (2) Printing the colored pattern on paper. This step is carried out by firstly preparing a fluid mixture by mixing together in the manner described above the following substances in the proportions indicated:
Parts by weight Resin from condensation of phenol-formaldehyde with admixture of colophonium and rosin esters 3-3.5 Supersulphonated emulsifying oil containing sodium sulphoricinate l Xylene 6-11 pattern should be transferred from the paper, as-well upon I the desired fastness of color to external agents.
Generally, I can recommend selecting the following dyestuffs depending upon the-kind of fabrics:
Cotton-vat dyes, direct dyes;
Wool, silk, nylonacid dyestuffs;
Acetate, Terylenee acetate dispersed dyestuffs.
Printing of colored patterns on the paper surface coated as described above is efiected by means of machines for calcographic printing, preferably by a continuous process using rotative machines for calcographic printing. In the latter case the inextensible support is in the form of a long paper, web unwinding from a spool and travelling through the cylinders of the machine.
The cylinders of the printing machine are engraved to a depth such as to leave on paper about 4 grams per square meter surface.
The dyestuff supplied .by each cylinder is dried between the successive cylinders of the machine by an air jet blown in order to evaporate the solvent in the printing ink. The latter should be fluid enough to readily wet the cylinders and quickly dry as the paper travels from one cylinder to the next one.
(3) Transfer of the printed colored pattern by accurately superposing on the fabric the colors being accurately in register with their respective paper zones.
This step is carried out by causing the fabric and paper web to travel in superposed relationship between two suitably heated pressure cylinders.
The equipment for carrying out this step can be of the type disclosed by US. Patent No. 2,583,286.
The temperature and pressure adopted during this step of transferring the colored pattern onto the fabrics amounts to 150 C. and 100-150 kg./square centimeter, respectively. However, these values may undergo certain variations according to the type of fabric onto which the colored pattern is transferred.
At the raised temperature the resinous substances in the second paper coating layer melt and act to bind the dyestuif to the paper. The raised temperature moreover promotes penetration of the colored mass into the fabric and is largely snfficient for dissolving the paper coating, more particularly the first layer, the melting point of which is considerably lower, whereby removal of the dyestufis from the paper during the transfer step is facilitated.
The high pressure satisfactorily smooths the fabric surface and causes a thorough contact between the juxtaposed surfaces of the paper and fabric.
The fabric is of course impregnated before transferring the colored pattern thereto by substances adapted to promote development and setting of the dyes. These substances are conveniently selected in accordance with the properties of the treated fabric and dyestuffs employed. Selections of the substances is obvious to experts in the art and is no part of this invention.
Examples of impregnating baths are as follows:
Direct dyes:
7 presence of the added resin.
formaldehyde resins are soluble in benzol, solvent Cotton Percent Lyoprint DA Ciba 1 Urea 18 Britishgum thickener 1:1 5 Water 76 Silk Urea 20 Britishgum thickener 13 Ammonium tartrate 3 Water; 63 Wool-- B Solvent salt 4 Ammonium oxalate 5 Gum arabic thickener 1:1 5
Water 86 Nylon or acetate G Lyoprint 4 Ammonium oxalate 5 Gum arabic thickener 5 Water 86 Cotton fabrics printed by vat dyestuifs are impregnated by a bath of the following composition:
Percent Rongalite 15 34 B. caustic soda 1O Ur a 10 B solvent salt 2. 5 'Glycen'ne 2. 5 Sodium sulphoricinate 2. 5 Britishgum thickener 1:1 10 Water 47. 5
The terms Lyoprint DA Ciba, B Solvent salt, G Lyoprint and Rongalite are trade names of products available on the Italian market;
According to their properties the fabrics are treated after transfer of the pattern by steaming to set the dyestuffs, washing to remove thickeners or otherwise treated as required. Such treatments are known and currently carried out in the art of dyeing fabrics.
Certain substances mentioned above as ingredients of the mixtures for coating paper and additions to the dyestuffs are available on the markets by the following trade names:
Supersulphonated emulsifying oil containing sodium sulphoricinateMonopol soap.
Sodium palmitateMarsei1les soap.
Resin obtained by condensation of phenolformaldehyde admixed with colophonium and with rosin esters- Albertol, more particularly Albertol Q 116 (melting point C.).
This product is identified in the textbook entitled Synthetic Resins and their Plastics, by Carlton Ellis, published in 1923, pages 147 and 148. Thus, as described in this book, oil-soluble resins known as Albertol or Albertole resins are produced by heating phenolformaldehyde resins with a natural resin such as rosin or with rosin esters. The condensation reaction forming the phenol-formaldehyde resin may take place in the These oil-soluble phenolnaphtha, acetone, carbon tetrachloride and various petroleum distillates.
These products were found particularly useful in carrying out my improved method.
In fact, since the non-stretchable carrier should receive the colored pattern only temporarily, then yield it under the combined action of heat and pressure without any spreading of the various colors and inherent alteration of the pattern, the substances with which the carrier is coated should melt at a temperature below the melting point of the substance incorporating the dye.
Albertol is a product which fully meets this requirement. Its melting point (105 C.) is higher than the melting point of the compositions with which the non stretchable carrier is coated. I
By acting on the carrier which has already been provided with the coating and printed with the colored pattern. by the action of heat, the back-ground to which the color is anchored is fused, but the resin with which the color or dye is mixed does not fuse so promptly, this explaining why the dye does not spread.
Since Albertol is easily solublein solvents, the resin can be easily eliminated from the, fabric, avoiding brown spots forming on the latteron a clear background. Monopol soap has the property of lowering the melting temperature of the coating applied to the non-deformable carrier and makes possible adhesion of the dye to the non-deformable carrier, which would be impossible when using a soap containing coating and when the dye is dispersed in a resin dissolved in a solvent. Monopol soap moreover facilitates dispersion of the practically water insoluble Albertol contained in the composition which according to this application is admitted to the dye, in water, during washing.
Finally, Marseilles soap is suitable for increasing solubility in water of Monopol soap. Any coating that adhered to the fabric during printing can therefore be removed during washing of the fabric.
This application is a continuation-in-part of my co pending application Serial No. 412,884, filed Feb. 26, 1954, and now abandoned.
What I claim is:
1. In a method of printing fabrics by transferring a colored pattern from a non-deformable carrier onto fabric, the steps of applying a first layer of a mixture comprising supersulphonated emulsifying oil, sodium sulphoricinate, sodium palmitate, butyl Cellosolve and distilled water, coating said first layer with a second layer of a mixture comprising supersulphonated emulsifying oil containing sodium sulphoricinate, zinc stearate, xylene and a resin obtained from the condensation of phenolformaldehyde with admixture of colophonium and rosin esters, color-printing the pattern on the treated side of said non-deformable carrier, said design consisting of a dye admixed with a binder washable during the final treatment of the fabric, treating the fabric with substances adapted to set the dyes, transferring the pattern on to the fabric, setting of the dyes by steaming the fabric and washing off the binder.
2. In a process as claimed in claim 1, wherein said first layer consists of:
Percent by weight Supersulphonated emulsifying oil containing sodium sulphoricinate 14 Sodium palmitate 30 Butyl Cellosolve 38 Distilled water 18 3. In a method as claimed in claim 1, wherein said second layer consists of:
Percent by weight Supersulphonated emulsifying oil containing sodium sulphoricinate 4 Zinc stearate v 0.5 Xylene 95 Resin from the condensation of phenol-formaldehyde with admixture of colophonium and rosin esters" 0.5
4. In a method as claimed in claim 1, the step of admixing the dye with the following composition:
Parts by weight Resin from the condensation of phenol-formaldehyde with admixture of colophonium and rosin

Claims (1)

1. IN A METHOD OF PRINTING FABRICS BY TRANSFERRING A COLORED PATTERN FROM A NON-DEFORMABLE CARRIER ONTO FABRIC, THE STEPS OF APPLYING A FIRST LAYER OF A MIXTURE COMPRISING SUPERSULPHONATED EMULSIFYING OIL, SODIUM SULPHORICINATE, SODIUM PALMITATE, BUTYL CELLOSOLVE AND DISTILLED WATER, COATING SAID FIRST LAYER WITH A SECOND LAYER OF A MIXTURE COMPRISING SUPERSULPHONATE EMULSIFYING OIL CONTAINING SODIUM SULPHORICINATE, ZINC STEARTE, XYLENE AND A RESIN OBTAINED FROM THE CONDENSATION OF PHENOLFORMALDEHYDE WITH ADMIXTURE OF COLOPHONIUM AND ROSIN ESTERS, COLOR-PRINTING THE PATTERN ON THE TREATED SIDE OF SAID NON-DEFORMABLE CARRIER, SAID DESIGN CONSISTING OF A DYE ADMIXED WITH A BINDER WASHABLE DURING THE FINAL TREATMENT OF THE FABRIC, TREATING THE FABRIC WITH SUBSTANCES ADAPTED TO SET THE DYES, TRANSFERRING THE PATTERN ON TO THE FABRIC, SETTING OF THE DYES BY STEAMING THE FABRIC AND WASHING OFF THE BINDER.
US625634A 1953-02-28 1956-12-03 Methods of printing textile fabrics Expired - Lifetime US2911280A (en)

Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
IT2911280X 1953-02-28

Publications (1)

Publication Number Publication Date
US2911280A true US2911280A (en) 1959-11-03

Family

ID=11436268

Family Applications (1)

Application Number Title Priority Date Filing Date
US625634A Expired - Lifetime US2911280A (en) 1953-02-28 1956-12-03 Methods of printing textile fabrics

Country Status (1)

Country Link
US (1) US2911280A (en)

Cited By (21)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US3223526A (en) * 1959-05-28 1965-12-14 Minnesota Mining & Mfg Printing processes including size reduction of graphic intelligence
US3918895A (en) * 1972-10-09 1975-11-11 Dainippon Printing Co Ltd Transfer printing method
US3966396A (en) * 1974-12-18 1976-06-29 F P Licensing Co Inc Textile printing process and transfer medium
US3969071A (en) * 1973-09-13 1976-07-13 Sublistatic Holding S.A. Carriers and their use in printing and dyeing
US3992140A (en) * 1973-05-18 1976-11-16 Bayer Aktiengesellschaft Printing inks for transfer printing
US3999939A (en) * 1973-05-10 1976-12-28 Bayer Aktiengesellschaft Transfer printing process
US4027345A (en) * 1974-06-14 1977-06-07 Toyo Boseki Kabushiki Kaisha Transfer printing
US4033716A (en) * 1973-11-02 1977-07-05 Ciba-Geigy Ag Transfer printing process for hydrophilic fibrous material
US4088440A (en) * 1973-08-03 1978-05-09 Heberlein Textildruck Ag Transfer printing of treated cellulosics
US4190417A (en) * 1976-11-11 1980-02-26 Mobay Chemical Corporation Process for dyeing and printing sheets
US4207069A (en) * 1976-02-26 1980-06-10 Toppan Printing Co., Ltd. Method of printing cellulose fiber and polyester/cellulose mixed fiber
US4208182A (en) * 1976-02-17 1980-06-17 Toyo Ink Manufacturing Co., Ltd. Process for transfer printing at elevated temperatures
US4351871A (en) * 1974-02-15 1982-09-28 Lewis Edward J Decorating textile fabrics
US4523402A (en) * 1981-11-09 1985-06-18 Dobson Charles Edward Sign construction
US4664670A (en) * 1983-12-16 1987-05-12 Sicpa Holding Sa Transfer printing sheet carrying impregnant and transfer printing of cellulose, wool, silk or polyamide textile materials
US5380391A (en) * 1993-03-08 1995-01-10 Mahn, Jr.; John Heat activated transfer for elastomeric materials
US5413841A (en) * 1991-09-11 1995-05-09 Mahn, Sr.; John E. Heat activated transfers with machine readable indicia
US5869168A (en) * 1997-01-10 1999-02-09 Mahn, Jr.; John Reflective heat activated transfer
US6013351A (en) * 1997-01-10 2000-01-11 Mahn, Jr.; John Decorated thermoplastic articles
US20040176232A1 (en) * 2003-03-06 2004-09-09 The C.W. Zumbiel Co. Consumer product package and method of manufacture
US20100212059A1 (en) * 2009-02-24 2010-08-26 Lee Peter Morrison Methods and garments for dye sublimation

Citations (3)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US1783606A (en) * 1927-06-30 1930-12-02 Dreyfus Camille Process of printing fabrics
US1965257A (en) * 1932-08-25 1934-07-03 Decorative Dev Inc Method of and apparatus for printing and dyeing
US2583286A (en) * 1952-01-22 Process for printing textile fabrics

Patent Citations (3)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US2583286A (en) * 1952-01-22 Process for printing textile fabrics
US1783606A (en) * 1927-06-30 1930-12-02 Dreyfus Camille Process of printing fabrics
US1965257A (en) * 1932-08-25 1934-07-03 Decorative Dev Inc Method of and apparatus for printing and dyeing

Cited By (24)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US3223526A (en) * 1959-05-28 1965-12-14 Minnesota Mining & Mfg Printing processes including size reduction of graphic intelligence
US3918895A (en) * 1972-10-09 1975-11-11 Dainippon Printing Co Ltd Transfer printing method
US3999939A (en) * 1973-05-10 1976-12-28 Bayer Aktiengesellschaft Transfer printing process
US3992140A (en) * 1973-05-18 1976-11-16 Bayer Aktiengesellschaft Printing inks for transfer printing
US4088440A (en) * 1973-08-03 1978-05-09 Heberlein Textildruck Ag Transfer printing of treated cellulosics
US3969071A (en) * 1973-09-13 1976-07-13 Sublistatic Holding S.A. Carriers and their use in printing and dyeing
US4033716A (en) * 1973-11-02 1977-07-05 Ciba-Geigy Ag Transfer printing process for hydrophilic fibrous material
US4351871A (en) * 1974-02-15 1982-09-28 Lewis Edward J Decorating textile fabrics
US4027345A (en) * 1974-06-14 1977-06-07 Toyo Boseki Kabushiki Kaisha Transfer printing
US3966396A (en) * 1974-12-18 1976-06-29 F P Licensing Co Inc Textile printing process and transfer medium
US4208182A (en) * 1976-02-17 1980-06-17 Toyo Ink Manufacturing Co., Ltd. Process for transfer printing at elevated temperatures
US4207069A (en) * 1976-02-26 1980-06-10 Toppan Printing Co., Ltd. Method of printing cellulose fiber and polyester/cellulose mixed fiber
US4190417A (en) * 1976-11-11 1980-02-26 Mobay Chemical Corporation Process for dyeing and printing sheets
US4523402A (en) * 1981-11-09 1985-06-18 Dobson Charles Edward Sign construction
US4767420A (en) * 1983-12-16 1988-08-30 Sicpa Holding S.A. Transfer printing sheet with impregnating agents and two-component electrophotographic toner and transfer printing of textile materials of cotton
US4664670A (en) * 1983-12-16 1987-05-12 Sicpa Holding Sa Transfer printing sheet carrying impregnant and transfer printing of cellulose, wool, silk or polyamide textile materials
US5413841A (en) * 1991-09-11 1995-05-09 Mahn, Sr.; John E. Heat activated transfers with machine readable indicia
US5380391A (en) * 1993-03-08 1995-01-10 Mahn, Jr.; John Heat activated transfer for elastomeric materials
US5869168A (en) * 1997-01-10 1999-02-09 Mahn, Jr.; John Reflective heat activated transfer
US6013351A (en) * 1997-01-10 2000-01-11 Mahn, Jr.; John Decorated thermoplastic articles
US20040176232A1 (en) * 2003-03-06 2004-09-09 The C.W. Zumbiel Co. Consumer product package and method of manufacture
US6916765B2 (en) 2003-03-06 2005-07-12 The C. W. Zumbiel Co. Consumer product package and method of manufacture
US20050215406A1 (en) * 2003-03-06 2005-09-29 The C.W. Zumbiel Company Consumer product package and method of manufacture
US20100212059A1 (en) * 2009-02-24 2010-08-26 Lee Peter Morrison Methods and garments for dye sublimation

Similar Documents

Publication Publication Date Title
US2911280A (en) Methods of printing textile fabrics
US4314813A (en) Flock transfer sheet and flock transfer printing process
US4351871A (en) Decorating textile fabrics
US3918895A (en) Transfer printing method
US4253838A (en) Heat transfer printing sheet and heat transfer printing method using the same
US3922445A (en) Heat transfer printing sheet
US3782896A (en) Sublimation transferring hydroxy or amino-dialkylamino-dicyanostyryl dye and diisocyanate fixation of dyed textile and transfer sheets therefor
JPH03500428A (en) Method for transfer printing a pattern onto a wet textile web, apparatus for use in the method, and pattern carrier web
JP4880008B2 (en) Dry transfer paper for natural leather and transfer printing method
CN103184706A (en) Preparation method and use method for paper for textile fabric printing
CN110699992A (en) Thermal transfer method of fabric pattern
US1744829A (en) Process of printing and embossing materials containing thermoplastic derivatives of cellulose
CA1095202A (en) Process for dyeing of printing a textile substrate
DE2449324A1 (en) TRANSFER PRINTING PROCESS FOR INKING AND PRINTING ORGANIC MATERIAL THAT CAN BE DYED WITH CATIONIC DYES
US2323871A (en) Method of coloring material
JP2010070737A (en) Transfer paper for dry transfer printing for natural leather and dry transfer printing method
US2342642A (en) Method of coloring textiles with pigments
US2338252A (en) Decorating composition for textiles
CH179075A (en) Capillary active agent.
US2619403A (en) Emulsified volatile hydrocarbon liquids as printing paste thickeners
US4121897A (en) Process for printing on solid molded articles made from urea formaldehyde resin or melamine formaldehyde resin
US2202283A (en) Method of decorating textiles and composition for use therein
EP0416888B1 (en) Printing of fabrics
US1783606A (en) Process of printing fabrics
DE2359515A1 (en) DRY THERMAL PROCESS FOR INKING AND PRINTING ORGANIC MATERIALS COLORABLE WITH CATIONIC DYES