US2939201A - Trilobal textile filament - Google Patents
Trilobal textile filament Download PDFInfo
- Publication number
- US2939201A US2939201A US82251459A US2939201A US 2939201 A US2939201 A US 2939201A US 82251459 A US82251459 A US 82251459A US 2939201 A US2939201 A US 2939201A
- Authority
- US
- United States
- Prior art keywords
- filaments
- yarn
- luster
- highlight
- filament
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Expired - Lifetime
Links
- 239000004753 textile Substances 0.000 title claims description 13
- 229920001059 synthetic polymer Polymers 0.000 claims description 7
- 239000004744 fabric Substances 0.000 description 45
- 239000002932 luster Substances 0.000 description 43
- 239000000835 fiber Substances 0.000 description 36
- 239000000523 sample Substances 0.000 description 34
- 229920000642 polymer Polymers 0.000 description 24
- 238000012986 modification Methods 0.000 description 20
- 230000004048 modification Effects 0.000 description 20
- GWEVSGVZZGPLCZ-UHFFFAOYSA-N Titan oxide Chemical compound O=[Ti]=O GWEVSGVZZGPLCZ-UHFFFAOYSA-N 0.000 description 18
- -1 polyethylene terephthalate Polymers 0.000 description 18
- LYCAIKOWRPUZTN-UHFFFAOYSA-N Ethylene glycol Chemical compound OCCO LYCAIKOWRPUZTN-UHFFFAOYSA-N 0.000 description 13
- 238000000034 method Methods 0.000 description 12
- 239000002689 soil Substances 0.000 description 11
- 239000000463 material Substances 0.000 description 10
- 238000012360 testing method Methods 0.000 description 10
- 229920002302 Nylon 6,6 Polymers 0.000 description 9
- 239000004408 titanium dioxide Substances 0.000 description 9
- 229920000728 polyester Polymers 0.000 description 8
- 239000004952 Polyamide Substances 0.000 description 6
- 238000010276 construction Methods 0.000 description 6
- 239000000155 melt Substances 0.000 description 6
- 230000003287 optical effect Effects 0.000 description 6
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- 239000000047 product Substances 0.000 description 6
- 238000009987 spinning Methods 0.000 description 6
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- 229910001220 stainless steel Inorganic materials 0.000 description 5
- 239000010935 stainless steel Substances 0.000 description 5
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- ATUOYWHBWRKTHZ-UHFFFAOYSA-N Propane Chemical compound CCC ATUOYWHBWRKTHZ-UHFFFAOYSA-N 0.000 description 4
- KKEYFWRCBNTPAC-UHFFFAOYSA-N Terephthalic acid Chemical compound OC(=O)C1=CC=C(C(O)=O)C=C1 KKEYFWRCBNTPAC-UHFFFAOYSA-N 0.000 description 4
- 239000000975 dye Substances 0.000 description 4
- 238000009732 tufting Methods 0.000 description 4
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- 239000013068 control sample Substances 0.000 description 3
- 230000001747 exhibiting effect Effects 0.000 description 3
- 238000005259 measurement Methods 0.000 description 3
- 229920002994 synthetic fiber Polymers 0.000 description 3
- 239000012209 synthetic fiber Substances 0.000 description 3
- 238000010998 test method Methods 0.000 description 3
- 238000005406 washing Methods 0.000 description 3
- 239000002759 woven fabric Substances 0.000 description 3
- HSQFVBWFPBKHEB-UHFFFAOYSA-N 2,3,4-trichlorophenol Chemical compound OC1=CC=C(Cl)C(Cl)=C1Cl HSQFVBWFPBKHEB-UHFFFAOYSA-N 0.000 description 2
- OEPOKWHJYJXUGD-UHFFFAOYSA-N 2-(3-phenylmethoxyphenyl)-1,3-thiazole-4-carbaldehyde Chemical compound O=CC1=CSC(C=2C=C(OCC=3C=CC=CC=3)C=CC=2)=N1 OEPOKWHJYJXUGD-UHFFFAOYSA-N 0.000 description 2
- GVNWZKBFMFUVNX-UHFFFAOYSA-N Adipamide Chemical compound NC(=O)CCCCC(N)=O GVNWZKBFMFUVNX-UHFFFAOYSA-N 0.000 description 2
- 240000000491 Corchorus aestuans Species 0.000 description 2
- 235000011777 Corchorus aestuans Nutrition 0.000 description 2
- 235000010862 Corchorus capsularis Nutrition 0.000 description 2
- 229920000742 Cotton Polymers 0.000 description 2
- 241001125831 Istiophoridae Species 0.000 description 2
- BAPJBEWLBFYGME-UHFFFAOYSA-N Methyl acrylate Chemical compound COC(=O)C=C BAPJBEWLBFYGME-UHFFFAOYSA-N 0.000 description 2
- ISWSIDIOOBJBQZ-UHFFFAOYSA-N Phenol Chemical compound OC1=CC=CC=C1 ISWSIDIOOBJBQZ-UHFFFAOYSA-N 0.000 description 2
- 229920000297 Rayon Polymers 0.000 description 2
- BZHJMEDXRYGGRV-UHFFFAOYSA-N Vinyl chloride Chemical compound ClC=C BZHJMEDXRYGGRV-UHFFFAOYSA-N 0.000 description 2
- 239000012736 aqueous medium Substances 0.000 description 2
- 238000009835 boiling Methods 0.000 description 2
- 239000000919 ceramic Substances 0.000 description 2
- 229920001577 copolymer Polymers 0.000 description 2
- 238000012937 correction Methods 0.000 description 2
- WOZVHXUHUFLZGK-UHFFFAOYSA-N dimethyl terephthalate Chemical compound COC(=O)C1=CC=C(C(=O)OC)C=C1 WOZVHXUHUFLZGK-UHFFFAOYSA-N 0.000 description 2
- 239000012153 distilled water Substances 0.000 description 2
- 238000004043 dyeing Methods 0.000 description 2
- 239000005337 ground glass Substances 0.000 description 2
- WGCNASOHLSPBMP-UHFFFAOYSA-N hydroxyacetaldehyde Natural products OCC=O WGCNASOHLSPBMP-UHFFFAOYSA-N 0.000 description 2
- 238000002074 melt spinning Methods 0.000 description 2
- 229920001778 nylon Polymers 0.000 description 2
- 229920002239 polyacrylonitrile Polymers 0.000 description 2
- 229920000573 polyethylene Polymers 0.000 description 2
- 239000001294 propane Substances 0.000 description 2
- 239000002964 rayon Substances 0.000 description 2
- 229910052708 sodium Inorganic materials 0.000 description 2
- 239000011734 sodium Substances 0.000 description 2
- OGIDPMRJRNCKJF-UHFFFAOYSA-N titanium oxide Inorganic materials [Ti]=O OGIDPMRJRNCKJF-UHFFFAOYSA-N 0.000 description 2
- 238000009941 weaving Methods 0.000 description 2
- KGIGUEBEKRSTEW-UHFFFAOYSA-N 2-vinylpyridine Chemical compound C=CC1=CC=CC=N1 KGIGUEBEKRSTEW-UHFFFAOYSA-N 0.000 description 1
- 125000004203 4-hydroxyphenyl group Chemical group [H]OC1=C([H])C([H])=C(*)C([H])=C1[H] 0.000 description 1
- QTBSBXVTEAMEQO-UHFFFAOYSA-M Acetate Chemical compound CC([O-])=O QTBSBXVTEAMEQO-UHFFFAOYSA-M 0.000 description 1
- NLHHRLWOUZZQLW-UHFFFAOYSA-N Acrylonitrile Chemical compound C=CC#N NLHHRLWOUZZQLW-UHFFFAOYSA-N 0.000 description 1
- 108700028369 Alleles Proteins 0.000 description 1
- 241000272517 Anseriformes Species 0.000 description 1
- 238000012935 Averaging Methods 0.000 description 1
- 229920001634 Copolyester Polymers 0.000 description 1
- 241000156978 Erebia Species 0.000 description 1
- VGGSQFUCUMXWEO-UHFFFAOYSA-N Ethene Chemical compound C=C VGGSQFUCUMXWEO-UHFFFAOYSA-N 0.000 description 1
- 239000005977 Ethylene Substances 0.000 description 1
- DGAQECJNVWCQMB-PUAWFVPOSA-M Ilexoside XXIX Chemical compound C[C@@H]1CC[C@@]2(CC[C@@]3(C(=CC[C@H]4[C@]3(CC[C@@H]5[C@@]4(CC[C@@H](C5(C)C)OS(=O)(=O)[O-])C)C)[C@@H]2[C@]1(C)O)C)C(=O)O[C@H]6[C@@H]([C@H]([C@@H]([C@H](O6)CO)O)O)O.[Na+] DGAQECJNVWCQMB-PUAWFVPOSA-M 0.000 description 1
- 239000004677 Nylon Substances 0.000 description 1
- 239000004698 Polyethylene Substances 0.000 description 1
- 208000037062 Polyps Diseases 0.000 description 1
- 108091092920 SmY RNA Proteins 0.000 description 1
- 241001237710 Smyrna Species 0.000 description 1
- 230000002411 adverse Effects 0.000 description 1
- 230000005540 biological transmission Effects 0.000 description 1
- 229920002301 cellulose acetate Polymers 0.000 description 1
- UUAGAQFQZIEFAH-UHFFFAOYSA-N chlorotrifluoroethylene Chemical group FC(F)=C(F)Cl UUAGAQFQZIEFAH-UHFFFAOYSA-N 0.000 description 1
- 238000004581 coalescence Methods 0.000 description 1
- 239000002131 composite material Substances 0.000 description 1
- 230000006835 compression Effects 0.000 description 1
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- 239000007859 condensation product Substances 0.000 description 1
- 238000002788 crimping Methods 0.000 description 1
- 210000003298 dental enamel Anatomy 0.000 description 1
- 239000003599 detergent Substances 0.000 description 1
- 239000006185 dispersion Substances 0.000 description 1
- 229920001038 ethylene copolymer Polymers 0.000 description 1
- 125000000816 ethylene group Chemical group [H]C([H])([*:1])C([H])([H])[*:2] 0.000 description 1
- 238000011156 evaluation Methods 0.000 description 1
- 238000009998 heat setting Methods 0.000 description 1
- 125000004836 hexamethylene group Chemical group [H]C([H])([*:2])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])[*:1] 0.000 description 1
- 150000002531 isophthalic acids Chemical class 0.000 description 1
- 239000004816 latex Substances 0.000 description 1
- 229920000126 latex Polymers 0.000 description 1
- 238000004519 manufacturing process Methods 0.000 description 1
- 230000000873 masking effect Effects 0.000 description 1
- FJXWKBZRTWEWBJ-UHFFFAOYSA-N nonanediamide Chemical compound NC(=O)CCCCCCCC(N)=O FJXWKBZRTWEWBJ-UHFFFAOYSA-N 0.000 description 1
- 239000004745 nonwoven fabric Substances 0.000 description 1
- 230000000704 physical effect Effects 0.000 description 1
- 229920003023 plastic Polymers 0.000 description 1
- 239000004033 plastic Substances 0.000 description 1
- 229920003229 poly(methyl methacrylate) Polymers 0.000 description 1
- 239000004417 polycarbonate Substances 0.000 description 1
- 229920000515 polycarbonate Polymers 0.000 description 1
- 229920006149 polyester-amide block copolymer Polymers 0.000 description 1
- 239000004926 polymethyl methacrylate Substances 0.000 description 1
- 229920002635 polyurethane Polymers 0.000 description 1
- 239000004814 polyurethane Substances 0.000 description 1
- 238000002360 preparation method Methods 0.000 description 1
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- 238000010791 quenching Methods 0.000 description 1
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- 239000004627 regenerated cellulose Substances 0.000 description 1
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- 125000000020 sulfo group Chemical group O=S(=O)([*])O[H] 0.000 description 1
- 230000003655 tactile properties Effects 0.000 description 1
- 150000003504 terephthalic acids Chemical class 0.000 description 1
Images
Classifications
-
- D—TEXTILES; PAPER
- D01—NATURAL OR MAN-MADE THREADS OR FIBRES; SPINNING
- D01D—MECHANICAL METHODS OR APPARATUS IN THE MANUFACTURE OF ARTIFICIAL FILAMENTS, THREADS, FIBRES, BRISTLES OR RIBBONS
- D01D5/00—Formation of filaments, threads, or the like
- D01D5/253—Formation of filaments, threads, or the like with a non-circular cross section; Spinnerette packs therefor
-
- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y10—TECHNICAL SUBJECTS COVERED BY FORMER USPC
- Y10T—TECHNICAL SUBJECTS COVERED BY FORMER US CLASSIFICATION
- Y10T428/00—Stock material or miscellaneous articles
- Y10T428/29—Coated or structually defined flake, particle, cell, strand, strand portion, rod, filament, macroscopic fiber or mass thereof
- Y10T428/2913—Rod, strand, filament or fiber
- Y10T428/2973—Particular cross section
-
- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y10—TECHNICAL SUBJECTS COVERED BY FORMER USPC
- Y10T—TECHNICAL SUBJECTS COVERED BY FORMER US CLASSIFICATION
- Y10T442/00—Fabric [woven, knitted, or nonwoven textile or cloth, etc.]
- Y10T442/30—Woven fabric [i.e., woven strand or strip material]
- Y10T442/3065—Including strand which is of specific structural definition
- Y10T442/3089—Cross-sectional configuration of strand material is specified
- Y10T442/3114—Cross-sectional configuration of the strand material is other than circular
- Y10T442/3122—Cross-sectional configuration is multi-lobal
-
- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y10—TECHNICAL SUBJECTS COVERED BY FORMER USPC
- Y10T—TECHNICAL SUBJECTS COVERED BY FORMER US CLASSIFICATION
- Y10T442/00—Fabric [woven, knitted, or nonwoven textile or cloth, etc.]
- Y10T442/40—Knit fabric [i.e., knit strand or strip material]
- Y10T442/425—Including strand which is of specific structural definition
- Y10T442/431—Cross-sectional configuration of strand material is specified
-
- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y10—TECHNICAL SUBJECTS COVERED BY FORMER USPC
- Y10T—TECHNICAL SUBJECTS COVERED BY FORMER US CLASSIFICATION
- Y10T442/00—Fabric [woven, knitted, or nonwoven textile or cloth, etc.]
- Y10T442/60—Nonwoven fabric [i.e., nonwoven strand or fiber material]
- Y10T442/608—Including strand or fiber material which is of specific structural definition
- Y10T442/609—Cross-sectional configuration of strand or fiber material is specified
- Y10T442/61—Cross-sectional configuration varies longitudinally along strand or fiber material
Definitions
- This invention relates to novel trilobal synthetic filaments and fibers having improved optical properties and improved resistance to soiling when incorporated in textile materials.
- an object of this invention to provide novel fibers and filaments particularly adapted for use in the construction of floor coverings having improved properties.
- a further object is to provide synthetic fibers and filaments of particular cross-section configuration that give higher resistance to soiling when used in carpets.
- Another object is to provide a synthetic carpet fiber which produces a carpet having improved dye brightness and covering power compared with carpets heretofore available.
- Another object is to provide woven and knitted fabrics exhibiting a unique luster highlight in addition to other desirable properties.
- a still further object is to provide textile materials having a combination of unique optical properties, improved resistance to soiling, and high covering power.
- Still another object is to provide new and improved floor covering fabrics.
- novel filaments and fibers prepared from synthetic polymers which have a cross-sectional shape consisting of three essentially symmetrical lobes located about a central point.
- each lobe of the filaments has a curved terminal portion generated by a radius, the origin of which nited States Patent lCC is along the line of symmetry of the lobe.
- Each lobe has essentially straight side portions extending outwardly and tangent to the curved portion at each end.
- the arm angle is defined by extension of the sides.
- the tips of the three lobes define a circle having its center equidistant from their extremities.
- the ratio of the tip radius to the radius of the circumscribed circle must be between about 0.16 and about 0.63, and the arm angle must be between about 17 and about +77.
- the modification ratio of the radius of the circumscribed circle to an inscribed circle must be between about 1.27 and about 2.6.
- filaments and fibers will be used interchangeably in their usual and accepted sense.
- luster highlight is meant the frequency of and the degree of concentration (in area) of the high intensity light reflected from a small area of a yarn or textile material relative to the average of the total amount of light reflected from M R 1 R a Tr ns (I) A A cos 5 sin (30- sin 60 The significance of the symbols will be discussed later herein.
- the filaments of this invention may be prepared by extruding molten polymer or a solution of the polymer through an orifice which provides a trilobal shape.
- Spinning conditions must, of course, be varied, depending on the particular synthetic polymer being spun. Conditions should be controlled to give filaments which have a substantially uniform cross-sectional shape along their length. Although the shape of the filaments must remain Within the limits previously described, slight variations in the parameters may occur along the length of the filament or from filament to filament in a bundle without adversely affecting their unique properties. In addition, the cross-sections may not be perfectly symmetrical.
- the denier of the filaments may vary within wide limits; however, deniers in the range from 1 to 35 arev usually preferred. The optimum denier will be dictated by the end use of'the textile material being prepared.
- Figures 1 and 2 are enlarged representations of crosssections of filaments of this invention.
- Figures 3 and 4 are graphs showing the areas in which the critical parameters defining the cross-sections of the filaments of this invention appear.
- Equation I which is set out at line 35 of column 2
- All of the possible cross-sectional shapes of trilobal filaments can be described by the following five parameters, the relation of which is illustrated in Figures 1 and 2:
- Equation I expresses the interrelation of these parameters. Although the equation is'w'ritten in terms of five variables, it will be apparent that by specifying any three of the variables the remaining two are fixed. It will also be'apparent that trilobal crosssections may be defined by other suitable equations. For convenience, .I have chosen to d'efin'e my invention in terms of the tip radius ratio the arm angle A, and the modificationfra'tio M.
- the filaments must have an arm angle A and a tip radius ratio It R betweenabout 0.22 and about 0.37, and the modification ratio M between about-1.75 and about 2.6.
- the arm angle A be between about 7 and about 74, the tip radius ratio between about 0.275 and about 0.62, and the modification ratio M between about 1.33 and 2.0.
- the filaments of the present invention exhibit a unique luster highlight since sparkle and glitter have heretofore been thought tobe attributable to thepresence of relatively large, fiat surface areas along the fiber axis.
- the surface of the fibers should be free from notches, unevenness, or grooves.
- only those filaments and fibers having the limited parameters described-in Figures 3 and 49f the accompanying drawings exhibit a combination "of the unique luster highlight and greatly improved soiling resistance.
- thefilaments of this invention exhibit high covering power and color clarity. Surprisingly, these features may all be obtained without the addition of delusterants, the in: corporation of which has heretofore been considered necessary in order to obtain good covering power. How ever, depending on the end use of the products, it may be-desirable to include delusterants, such as titanium dioxide, in -amounts up to about 2%. When delusterants are includeithe unique luster highlight, although somewhat subdued, is still present. 7
- spinning conditions as well as the type 'of rspinneret used in preparing the novel filaments of this invention will vary, depending on the type of polymer being spun.
- melt spinning polymers such as polyesters and polyamides
- the data recorded in 305 the table were the average of four evaluations of fresh carpet samples lying flat on a table and cut to a size of The tows were then chopped into 3-inch, 15 demer 9 by 11 inches.
- A. Luster highlight index The luster highlight inde was determined by an Optical Wrinkleometer comprised of a light source, a traveling specimen holder, a photomultiplier tube, and a recorder system.
- the light source used was a 35 mm.
- Argus 300 slide projector mounted so that the angle of light incidence to the lo'ngl' pm the output of the cell.
- the traveling specimenholder was a mechanical lathe bed powered by a variable speed motor.
- the yarn sample 1.8 inches long, was traversed at a speed of 1.31 inches per minutera V
- the photomultiplier tube (N 931A, gas filled) was mountd in the same horizontal plane as'the light source.
- Theangle of reflectance from the long axis of the yarn was 60. Reflectance was measured from 13 yarns (0.226 inch across the yarns and 0.00284 inch along the long axis of the-yarns). To accomplish this, a 50 mm.
- the lens was mounted between the specimen and the photomultiplier tube.
- the yarn image was focused on a ground glass between the lens system and the photomultiplier tube, and the desired yarn area tojbe, measured, as indicated above, was obtained by masking off a slit on the ground glass of f inch by inch which regulated the light reaching the photomultiplier tube.
- the instrument was cali- C. Seam slippage.-The seam slippage test measures Testing Materials Method Designation D434-42.' The Instron Tester (Instron Engineering Corp, Quincy,
- ported values.v are the average: resistance to slippage in fiber. (Yarn distortion is a measure of the distortion, in inches, of warp or filling yarns in woven fabric after sur- .face friction has been applied. The test used follows the tentative method of testing issued by the American '-Society for Testing Materials (Dl336-54-T An effec- Itive weight of one pound was used on the upper friction murn Requirements for Rayon and Acetate Fabrics, L2
- First number refers to total denier
- second number refers to number of filaments.
- EXAMPLE V Two samples of polyhexamethylene adipamide multifilament yarn having trilobal cross sections were spun using the spinning conditions set forth in Table 6. One end of each of the samples was bulked by feeding it through a jet with steam according to the process described in the copending application of Breen and Lauterbach, US. application Serial No. 698,103, filed November 22, 1957. Three ends of the treated yarn were fed to each needle of a standard tufting machine and were tufted into a jute backing to make a loop pile carpet as described in Example 1. into two parts, one-half being dyed red and the other half left undyed. Soil resistance rating and luster highlight rating were accomplished as described in Example I.
- Samples F10 and F11 were prepared from polymer, having a relative viscosity of 19.5 (10% solution of polymer in 10 parts of phenol and 7 parts of trichlorophenol), as described in Belgian Patent 549,179.
- the polymer was melt spun at 296 C. through a stainless steel spinnert of the type described in Example I in which the arms of the openings were 4 mils wide and 7 mils long.
- the effective thickness of the spinneret at the holes was 12 mils.
- the extruded filaments were quenched in cross-flow air having a velocity of 65 ft./ min. and a temperature of 70 F., and then wound up as a 50 filament yarn at a windup speed of 1500 yards per minute.
- the total denier of the spun yarn was 170.
- the spun yarn was then drawn at a.
- Sample F11 was prepared substantially as in- Each carpet sample was divided dicated above except a spinneret having round orifices and melt spun at 296 C. through a stainless steel spin neret having symmetrical trilobal and round openings as previously described.
- the extruded filaments Upon leaving the spinneret, the extruded filaments were quenched in cross-flow air having a velocity of 89 feet per minute and a temperature of 70 F., and then wound up as a 203 denier, 50 filament yarn at a windup speed of 1500 yards per minute.
- the spun yarn was then drawn at a temperature of 102 C. using a one-quarter inch diameter ceramic snubbing pin, a draw ratio of 2.9, and a windup speed of 750 yards per minute.
- the drawn yarn was found to have a total denier of 70, a tenacity of 4.0 grams per denier, and a break elongation of 25% V
- the parameters of each of the four continuous filaments are given in Table 7, together with test data.
- polyester yarn 50 filaments, 1.4 denier per filament
- a twist of five 2 turns per inch were used in the warp and zero twist in the filling.
- the loom construction was 100 ends and picks.
- Each fabric was scoured at the boil in aqueous medium in relaxed condition and then dried. The fabrics were heat set for one minute at 390 F.
- the finished Weight of each fabric was 2.2 ounces per square yard.
- the fabrics were tested for covering power, for soiling in accordance with the soiling test described below, and were rated subjectively for luster highlight as described in Example I. The results of the tests show much better cover, luster highlight,
- Soiling test The relative soilability of the woven fabric was tested by tumbling in the presence of a standard dry soil composed of the following materials:
- the dry soil was mixed with 150 ml. of water, treated on a ball mill, dried at 110 C., and was then broken up and put through a ZOO-mesh screen.
- the changes in reflectance after soiling and after washing expressed as percentage of the original reflectance were reported.
- the soilingwashing sequence was repeated twice.
- the reflectance measurements are the percent of the original reflectance, i.e., reflectance before soiling, retained after the washing following the second soiling.
- Soiling was carried out by placing two samples in each of two jars of soil. The jars were tumbled with one hun dred 0.25 inch stainless steel balls for forty-five minutes at 70 F. The reflectance of each sample was measured after soiling. The samples were then washed in a Launder-Ometer, manufactured by the Atlas Electric Devices Company, for twenty minutes in 200 ml. of distilled water at F. with 0.25% of a detergent, made and sold by Procter and Gamble under the tradename Tide, and fifty 0.25 inch stainless steel balls. After washing, the samples were rinsed in distilled water, air dried, and the reflectance again determined. Reflect-ance measurements were determined using a Photovolt Refiectometer, Model 610 (Photovolt Corporation). The instrument was calibrated using a white enamel working standard (Catalog #6162, Photovolt Corporation) ha-ving 70-75 percentage reflectance with a green tristimulus filter (Catalog #6130, Photovolt Corporation).
- EXAMPLE IX Made from ethylene glycol, 98 mol percent dimethylterephthalate and 2 mol percent sodium 3,5-di- (carbomethoxy) benzenesulfouate.
- EXAMPLE 9 VIII Several transparent polymethyl methacrylate cylinders of various cross-sectional shapes were machined to give enlarged fiber models having parameters listed in Table 9. A point source of light was moved in all positions with respect to an exposed slit perpendicular tothe axis of and in front of each model. The reflected light was measured by exposing photographic paper, and the resulting exposed portions were integrated to give single numbers representing total light reflections from internal surfaces for each model. Models with a value of at least typify samples which would have sufficient internally reflected light to exhibit a combination of good luster highlight and soil resistance,whereas those models with numbers substantially less than 50 confirm the unsatisfactory luster highlight of actual fiber samples tested. The models as well as the filaments described in the preceding examples are plotted on the graph in Figures 3 and 4.
- Sample F14 One sample of yarn, identified as Sample F14, was prepared from polyethylene terephthalate polymer having a relative viscosity of 25.5 (10%. solution of polymer in 10 parts phenol and 7 parts of trichlorophenol), as described in U.S. Patent 2,465,319.
- the polymer containing 0.3% TiO was melt spun at 305 C. through a stainless steel spinneret having a diameter of 3 inches. This spinneret was used to spin two yarn bundles, each bundle consisting of 34 continuous filaments.
- the individual filaments were spun from a group of four holes, each of which had a diameter of 6 mils, with three of the holes arranged radially 120 apart about the fourth hole to produce one coalesced filament.
- the distance between the center hole and each of the three radialholes was 7 mils, center to center.
- the efiective thickness of the spinneret at each hole was 8 mils.
- each extruded filament formed by coalescence of the polymer from each group of four holes, was quenched with cross-flow air having a velocity of approximately 20 ft./min. and a temperature 7 of F.
- the filaments were wound up as a 34-filarnent yarn at a windu'p speed of 600 yds./niin.
- the drawn yarn was found to have a total denier of 52.3, a tenacity of 43 grams "per denier, a break elongation of 24.5%, and a boil-ofi" shrinkage of 9.5%. Measurements made on yarn cross-sections showed that each filament had an average modification ratio (M) of 1.65, an average angle (A) of 18.4, and an average ratio 1 R of 0.45.
- the F14 yarn described above was woven into a plain weave taffeta fabric. In weaving, a twist of 7 2 turns per inch were used in the warp and zero twist in the filling. The loom construction was 1:16 ends and 92 picks.
- the fabric was. scoured .at the boil in. aqueous medium in a jig and then dried, followed by heat-setting for one minute at 390 F.
- the finished weight of the .fabric was 1.78 ounces per square yard, :having .a construction of 141 ends and 102 picks.
- the fabric was rated subjectively for luster highlight by five people, using the same scale as described in Example 1. The average of the five ratings was 2.1.
- EXAMPLE X1 Seven samples of polyhexamethylene adiparnide were melt spun from polymer containing 0.75% titanium dioxide by weight through spinnerets of the type described in the aforementioned copending application Serial No. 517,434 as trilobal filaments under slightly varying conditions to give yarns having cross-sections as indicated for Samples F20 through F26, inclusive, in Table 11. Two samples of round filaments (F18 and F19) were also spun and made into similar yarns to serve as controls. Each of these nine yarns contained 13 filaments and had a total denier of 40.
- Example IX Each of the yarns was woven into a plain-weave fabric, the warp yarns of each fabric having a twist of 7 /2 2 turns per inch and the filling yarns each having a twist of one-half 2 turns per inch. All nine fabrics were finished by the method described in Example IX. These fabrics when rated subjectively by five people for luster highlight showed the trilobal fibers to be superior to comparable control fabrics having fibers of round cross-section based on the same scale as used in Example I. The fabric constructions and luster highlight ratings for all nine fabrics are given in Table 11.
- the melt contained 0.02% titanium dioxide.
- the yarn (identified as Sample C11) was melt spun through a spinneret containing 68 holes, each hole being characterized by three slots lying at 120 to each other and joined at the center. The length of each rectangular slot was approximately 12 mils and the width 3 mils.
- the temperature of the melt adjacent to the spinneret was 296 C.
- the chimney air flow was 340 ft. /min. at a temperature of 50 F.
- the yarn was spun at 429 yards per minute and was drawn approximately 4 x, giving a final denier of about 1000.
- One end of the drawn yarn was bulked by the same process as that described in Example V.
- a tufted carpet was prepared from the bulked yarn and was tested for luster highlight and soil resistance.
- the luster highlight rating of the tufted carpet was 1.7. This carpet was rated for soiling as considerably better, i.e., it soiled much less, than a control carpet made of round fibers of the same denier and composition.
- the polymer was melt spun into a multifilament yarn through a spinneret containing 20 holes, each hole being an equilateral triangle 9 mils long on each side. At each vertex of the triangle a square slot was cut, running 3 mils in length from the vertex and being 3 mils wide. The temperature of the melt at the spinneret was 200 C.
- the yarn windup speed was 65 yards per minute and the denier of the as-spun yarn was 2300.
- the yarn was drawn at approximately 6 x at 124 C. over a hot pin.
- the as-drawn yarn had a tenacity of 4.6 grams per denier
- the drawn yarn was wound on a cone and in this form was compared with a sample of polypropylene yarn made of filaments having a round cross-section.
- the yarn of trilobal polypropylene filaments exhibited a unique luster highlight to the unaided eye, compared to the dull, fiat appearance of the round filament yarn.
- EXAMPLE XV This example describes the preparation of full-fashioned ladies hosiery using the trilobal filaments of this invention.
- the hosiery were knit on a 60-gauge, 4-position Reiner full-fashioned hosiery machine (Robert Reiner,
- leg fabric continuous filament yarn 15 denier, 2 filament, 1/ 4 Z twist
- polyhexamethylene adipamide containing 0.3% titanium dioxide by weight
- hosiery were extremely brilliant, exhibiting a high level Hosiery prepared with conventional 1544/; 2 nylon .yarn of round filaments in the leg fabric using thesame procedure and dyes as above did not exhibit any ofthese luster highlights but, by comparison, appeared extremely dull and had low color clarity.
- the luster highlight in the sample of trilobal filaments and the difference between this "and the dull flatness in the sample of round filaments were readily apparent with'the hosiery layingfiat on a surface or while being worn.
- the staple fiber or continuous filaments of the present invention may be prepared from a variety of synthetic polymers.
- the polyamides such as p'olyhexamethylene adipamide, pol hexamethylene sebacarnide, polycaproamide, polyxylylene azelamide, p'o'lyo'ct'amethylene oxalar'nide, polyp'yrrolidone, polymetaphenylene isophthalamide, polymers phenylene adipamide; copolyamides, and irradiation grafted polyamides; and the polyesters and copolyesters such as the condensation products of ethylene glycol with terephthalic acid, ethylene" glycol with a 98/2 mixture of terephthalic/S-(sddiuni sulfo)-isophthalic acids, ethylene glycol with a 90/10 mixture of terephthalic and isophthalic acids, polyesters derived from 2,2-bis(sddiuni sulfo)
- fibers and filaments may be crimped or u'ncrirnped, drawn or undrawn, and/or bulked or unbulked. Mixtures of the above fibers as Well as blends containing a major proportion of the synthetic fibers of this invention with a minor proportion of natural fibers may be used to prepare fabrics.
- the filaments of this invention are particularly useful in bulked form. Bulking may be conveniently achieved by a number of methods. For example, a particularly desirable bulking process is described in the copending application of Breed and Lauterbach, Serial No. 698,103,
- tr'ilobal filaments of this invention may also be treated according to the process described in the copending application of Breen and Sussr'nan, Serial No.8 10,671, filed May 4, 1959, to provide desirable products.
- the sides of the lobes of the filament need not be absolutely straight nor must the curved terminal portion be perfectly circular.
- the sides may curve slightly inwardly or outwardly.
- Other slight distortions may be introduced in the filament when it is spun or during the processing operations, such as drawing, crimping, twisting, dyeing, or bulking.
- the chief advantage of this invention is that it provides 'seam' slippage and less yarn distortion than those made from filaments of round cross-section
- the improved fabrics also exhibit a greater coefiicient of friction, resulting in betterfabric tactile properties.
- the improved soiling resistance of the woven, knitted, and non-Woven fabricstof this invention includes resistance to soiling by either dry or oily soils.
- the higher denier pile fabrics exhibit better mechanical bulk both before being used as ,well as after being in use when compared with control fabrics having round fibers and fibers having moderate to high modification ratios.
- the fibers oi the present invention have improved dye wash fastness over fibers having higher modification ratios.
- novelfibers of this invention have a higher rate of dyeing and a greater stifiness than round fibers due to their more efiicient cross-sectional shape. Also, they do not collapse as do those fibers of higher modification ratio. Another advantage is that knitted fabrics prepared from the bulked trilobal filament yarns exhibit less pickiness? than do comparable fabrics knitted from bulked round filament yarns.
- novel fibers and filaments of this invention may be employed to produce a Wide variety of different types of fabrics, including both apparel and industrial textile products.
- Specific examples of these products include shirtings, suitings, dress and blouse fabrics, hosiery, sheeting, lingerie, taffetas, georgettes, sand-crepes, tissuefailles, foulards, broadcloths, batistes, rainwear, surah, tricot, tulles, circular knitted goods, satiris, chifi'ons, sheers', wash-wear fabrics, crepes, casement fabrics, upholstery, filter cloths, ducks,.beltin'gs, webbing, braids, cordage'and twine, fiber-reinforced laminates, tire cord, coated fabrics, stufiing materials, floor coverings, and tiles.
- the products of this invention are particularly useful in preparing various types of carpeting, e.g.,- tufted, chenille, Smyrna, Wilton, Saxony, Brussels; velvet, Axminster', Orientals, knitted, pleated, and the like, due to their improvedsoil resistance, unique luster highlight, dye brightness, and bulkingpower. e
- a textile filament prepared from a synthetic polymer having an essentially trilobal cross-section along its length, said cross-section a tip radius ratio and an arm angle A within the range represented by the area LNP on Figure 3 of the drawing and a modification ratio M within the range represented by the area VUZ on Figure 4 of the drawing, the lobes of said cross section being substantially equi-spaced and having an essen tially symmetrical configuration.
- polyester contains a major proportion of terephthalate radicals and up to 2 mol percent of 5-(sodium sulfo)-isophthalate radicals.
- the yarn of claim 11 comprised of filaments wherein the arm angle A is between about 7 and 60.
- a knitted textile fabric prepared from the yarn of claim 13.
- a textile fabric having improved luster highlight and improved covering power comprised of filaments prepared from a synthetic polymer having an essentially uniform trilobal cross-section along its length, said crosssection having a tip radius ratio and an arm angle A within the range represented by the area LNP on Figure 3 of the drawing and a modification ratio M within the range represented by the area VUZ on Figure 4 of the drawing, the lobes of said cross section being substantially equi-spaced and having an essentially symmetrical configuration.
- a floor covering material having improved optical properties and improved resistance to soiling comprised of textile filaments prepared from a synthetic polymer having an essentially uniform trilobal cross-section along its length, said cross section having a tip radius ratio and an arm angle A within the range represented by the area LNP on Figure 3 of the drawing and a modification ratio M within the range represented by the area VUZ on Figure 4 of the drawing, the lobes of said cross section being substantially equi-spaced and having an essentially symmetrical configuration.
Description
A DEGREES June 7, 1960 Filed June: 24, 1958 M. c. HOLLAND 2,939,201
TRILOBAL TEXTILE FILAMENT 2 Sheets-Sheet l :I 6 l ,5 I I QINVENTOR o o o o o c c to 9 N N e MARLIN C. HOLLAND BY ,QQJ-W ATTORNEY 2 Sheets-Sheet 2 Filed June 24, 1959 INVENTOR MARLIN C. HOLLAND ATTORNEY TRHDBAL TEXTILE FILAMENT Marlin C. Holland, Wilmington, Del., assignor to E. I. du Pont de Nemonrs and Company, Wilmington, Del., a corporation of Delaware Filed June 24, 1959, Ser. No. 822,514
19 Claims. (CI. -2882) This invention relates to novel trilobal synthetic filaments and fibers having improved optical properties and improved resistance to soiling when incorporated in textile materials.
This application is a continuation-in-part of my copending application Serial No. 748,447, filed July 14, 1958, and now abandoned.
Various synthetic fibers have been used in the construction of floor coverings. The two most important examples in recent years have been rayon and nylon fibers employed in the face or pile. It has been customary to select a fiber which has a minimum surface area, i.e., fiber most nearly round in cross-section, in order to provide minimum soiling of carpets. Various modifications of the cross-section of carpet fibers have been proposed but in this connection those cross-sections having relatively high degrees of modification have been chosen to provide the greatest improvement in stiffness. Fibers of even moderately high modification ratios tend to soil readily and tend to distort and collapse when bent around the sharp radii encountered in carpet use, leading to reduced bulk and compression resistance. Also, such fibers tend to fibrillate and break off in use. It has also been proposed to incorporate in the manufacture of the fiber various delusterants, such as titanium dioxide, in order to improve the resistance of the carpet to soiling. However, the use of delustered round fibers as well as fibers having a moderate to high modification ratio, as well as other odd shapes, has always resulted in an undesirable chalky appearance, lacking luster.
It is, therefore, an object of this invention to provide novel fibers and filaments particularly adapted for use in the construction of floor coverings having improved properties. A further object is to provide synthetic fibers and filaments of particular cross-section configuration that give higher resistance to soiling when used in carpets. Another object is to provide a synthetic carpet fiber which produces a carpet having improved dye brightness and covering power compared with carpets heretofore available. Another object is to provide woven and knitted fabrics exhibiting a unique luster highlight in addition to other desirable properties. A still further object is to provide textile materials having a combination of unique optical properties, improved resistance to soiling, and high covering power. Still another object is to provide new and improved floor covering fabrics. Other objects will appear hereinafter. I
The objects of this invention are accomplished by providing novel filaments and fibers prepared from synthetic polymers which have a cross-sectional shape consisting of three essentially symmetrical lobes located about a central point. By maintaining the cross-sectional shape within certain parameters to be defined in detail later herein, the products prepared from such filaments and fibers not only exhibit outstanding and unique optical properties but also efiibit greatly improved resistance to soiling.
In general, each lobe of the filaments has a curved terminal portion generated by a radius, the origin of which nited States Patent lCC is along the line of symmetry of the lobe. Each lobe has essentially straight side portions extending outwardly and tangent to the curved portion at each end. The arm angle is defined by extension of the sides. The tips of the three lobes define a circle having its center equidistant from their extremities. In accordance with this invention, the ratio of the tip radius to the radius of the circumscribed circle must be between about 0.16 and about 0.63, and the arm angle must be between about 17 and about +77. In addition, the modification ratio of the radius of the circumscribed circle to an inscribed circle must be between about 1.27 and about 2.6. However, it will be apparent from the detailed description which follows that only certain combinations of the aforementioned parameters in accordance with the teachings of this invention provide filaments having a combination of outstanding properties.
Throughout the specification and claims, the terms filaments and fibers will be used interchangeably in their usual and accepted sense. By the term luster highlight is meant the frequency of and the degree of concentration (in area) of the high intensity light reflected from a small area of a yarn or textile material relative to the average of the total amount of light reflected from M R 1 R a Tr ns (I) A A cos 5 sin (30- sin 60 The significance of the symbols will be discussed later herein.
In general, the filaments of this invention may be prepared by extruding molten polymer or a solution of the polymer through an orifice which provides a trilobal shape. Spinning conditions must, of course, be varied, depending on the particular synthetic polymer being spun. Conditions should be controlled to give filaments which have a substantially uniform cross-sectional shape along their length. Although the shape of the filaments must remain Within the limits previously described, slight variations in the parameters may occur along the length of the filament or from filament to filament in a bundle without adversely affecting their unique properties. In addition, the cross-sections may not be perfectly symmetrical. The denier of the filaments may vary within wide limits; however, deniers in the range from 1 to 35 arev usually preferred. The optimum denier will be dictated by the end use of'the textile material being prepared.
The present invention will be more fully understood by reference to the following detailed description and the accompanying drawings, in which:
Figures 1 and 2 are enlarged representations of crosssections of filaments of this invention; and
Figures 3 and 4 are graphs showing the areas in which the critical parameters defining the cross-sections of the filaments of this invention appear.
In Figures 3 and 4, the filaments and models described in the examples which follow have been plotted as points. Triangles with the code letter C have been used to designate filaments utilized in preparing carpet samples such as those described in Example I. Circles with the code letter F denote filaments used in preparing woven fabric samples such as those described in Example II. Crosses denote the plastic models described in Example VIII,
- lobal configurations are defined by Equation I which is set out at line 35 of column 2, only a very limited group of filaments exhibit the unique properties previously me'ntioned. All of the possible cross-sectional shapes of trilobal filaments can be described by the following five parameters, the relation of which is illustrated in Figures 1 and 2:
(1) The ratio of tip radius r of the lobeto the radius R of a circle 11 having a center circumscribed about the tips I) of the lobes; f
(2) The arm angle A formed by extending the essentially straight portions 1 and f of each lobe;
(3) The ratio of the length d'e of the essentially straight portion to the radius R of the circumscribed circle; i
(4) The ratio of the radius r, of the arc g to the radius R; and i r v (5) The ratio of the radius R to the radius R of a circle having center c inscribed within the cross-section, commonly referred to as the modification ratio M. As previously indicated, Equation I expresses the interrelation of these parameters. Although the equation is'w'ritten in terms of five variables, it will be apparent that by specifying any three of the variables the remaining two are fixed. It will also be'apparent that trilobal crosssections may be defined by other suitable equations. For convenience, .I have chosen to d'efin'e my invention in terms of the tip radius ratio the arm angle A, and the modificationfra'tio M.
Referring again to Equation I, actual trilobal shapes are described only under the following conditions:
However, as previouslyi, indicated, "only a very specific group of the'many' possible shapes provide the outstanding optical and soilingiproperties. 1
Since a word definition bf the parameters whichdefine the special group of filaments of this invention wouldjbe quite lengthy and unduly complex; I have chosen to describe the filaments by reference to Figures 3 and 4 of the drawings. In view 'of 'the' fact thatthree paramete'rs'are' required to define the filaments, reference must be made to both of the aforementioned figures.
Referring now to Figure 3, the filaments must have an arm angle A and a tip radius ratio It R betweenabout 0.22 and about 0.37, and the modification ratio M between about-1.75 and about 2.6. Inpreparing fiat fabrics, it is preferred that the arm angle A be between about 7 and about 74, the tip radius ratio between about 0.275 and about 0.62, and the modification ratio M between about 1.33 and 2.0.
It will be noted that the areas shown on the graphs are not regulargeometrical figures as might be expected. if a three-dimensional plot were made incorporating the points'on the-graph using the modification ratio as the vertical dimension, it would appear as a volume having apeak at a modification ratio of about 2.6 andthen sloping off as indicated in Figure 4. V
It is indeed surprising that the filaments of the present invention exhibit a unique luster highlight since sparkle and glitter have heretofore been thought tobe attributable to thepresence of relatively large, fiat surface areas along the fiber axis. In addition, it has been generally accepted that in order to obtain optimum resistance to soiling, the surface of the fibers should be free from notches, unevenness, or grooves. Contrary to the teachings of the prior art and previous theories, only those filaments and fibers having the limited parameters described-in Figures 3 and 49f the accompanying drawings exhibit a combination "of the unique luster highlight and greatly improved soiling resistance.
In addition to theluster highlight and soiling resistance, thefilaments of this invention exhibit high covering power and color clarity. Surprisingly, these features may all be obtained without the addition of delusterants, the in: corporation of which has heretofore been considered necessary in order to obtain good covering power. How ever, depending on the end use of the products, it may be-desirable to include delusterants, such as titanium dioxide, in -amounts up to about 2%. When delusterants are includeithe unique luster highlight, although somewhat subdued, is still present. 7
7 As. previously indicated, spinning conditions as well as the type 'of rspinneret used in preparing the novel filaments of this invention will vary, depending on the type of polymer being spun. For example, ;in melt spinning polymers such as polyesters and polyamides, -a-spinneret of the type shown in Figure XI of the copending application of Lehrnicke, US. application Serial No. 517,434, :filed June 23, 1955., may be advantageously used; certain adjustmerits in the dimensions of the orifices, the viscosity of the polymer, the melt temperature, and the quenching condit ons may be madein order to produce filaments liaving'pa'r-ameters Within the scope'of this-invention as Will be more fully described in the following examples which are intended to further illustrate this invention and counter each time one person walked over the mat. lead carpet 27 inches wide and -6 feet long for removing in which parts and percentages are by weight unless Otherwise indicated. The various tests used to illustrate the improved properties of the filaments of this invention are described in detail in the examples.
EXAMPLE I Polyhexamethylene adipamide was melt spun at a temperature of 291 C. into a multifilament yarn through a spinneret having 79 round holes. The melt contained 0.02% titanium dioxide by weight. Five additional samples of the same polymer were melt spun through a spinneret of the type described in the aforementioned copending application Serial No. 517,434 under slightly varying conditions to give yarns having cross-sectional configurations as indicated in Table l. Tows of approximately 100,000 denier were prepared.
(1) Perfect, no visible soiling,
(2) Slight soiling as compared with control sample (unsoiled),
(3) Moderate soiling as compared with control sample,-
(4) Severe increase in soiling as compared with control Table 1 sample, and
(5) Extremely bad soiling as compared to control sample.
Chim- Sample No. ney Air Spun Ang la M 11 0 The ratmgs obtained for each sample were averaged, and
$23 A U R the average reported as the soil rating.
B. Luster highlight. 'Ihe luster highlight rating was 150 ,100 37 1'8 033 determined by averaging the subjective ratings of four 200 4,100 29 2.1 0.23 persons. Ratings were made on a scale from 1 to 5 with i8; 2% }g 5 3 31%,: 25 a rating of 1 representing a high luster highlight and a 22.5 3,420 0 4.0 0.21 rating of 5 no luster highlight. The data recorded in 305 the table were the average of four evaluations of fresh carpet samples lying flat on a table and cut to a size of The tows were then chopped into 3-inch, 15 demer 9 by 11 inches.
Table 2 Boiling Rating E Luster E." Pile Carpet High- Green Undyed Yarn F Yarn Thick- Sample No. light Dyed I: Carpet {{Denier' Weight ness} Rating ,Oarpet (4,000 ('Iotal); (om/yd.) (Inches) (8,000 Trafiie afii 1 Average for 18 carpets.
Also average for woven, tufted, loop pile and cut pile fabrics containing yarns prepared by cotton, woolen and worsted systems, both green and brown dyed 1 Average for 22 carpets. Also average for woven, tufted, loop pile and out pile fabrics containing yarns prepared by cotton, woolen and worsted systems.
3 Calculated from weight of all polyamide yarn removed from a 6 square inch carpet sample after sample was treated in boiling water.
4 Measured on an Instron Testing Machine at 0.1 p.s.i.
per filament staple fiber, spun into yarn, and three ends were plied together to give a yarn having a total denier as indicated in Table 2. Each of the yarns was tufted into a 12 oz./yil. woven .jute backing on a 7 inch gauge tufting machine. One-half of each carpet sample was dyed green. The other half was left undyed but was scoured at 212 F. A standard latex dispersion was applied to the backing of each carpet sample. The carpet samples were then evaluated for soiling and luster highlight with the results listed in Table 2. Sample numbers in Table 2 correspond to those set forth in Table 1. The methods used were as follows:
A. Sailing-Carpet samples were cut to a size of 7.5 inches by 22 inches with the longest dimension in the tufting direction. The samples were then attached to the floor by double-faced tape two inches wide. An electric mat switch 24 by 24 inches was placed adjacent to the samples. A trafiic cycle was recorded by an electric A EXAMPLE H Three samples of polyhexamethylene adipamide polymer containing 0.3% by weight titanium dioxide were melt spun into one round and two non-round continuous multifilament yarns. The melt spinning conditions were essentially the same except for the shape of the spin neret orifice. In the case of the non-round filaments, a spinneret of the type described in Example I was used. Each of the samples (70 denier, 34 filaments, having one-half Z-twist per inch) were woven into a plain weave fabric and were then tested for luster highlight, soiling resistance, percent transmitted light, percent reflected light, and seam slippage. Test procedures were as follows:
A. Luster highlight index.The luster highlight inde was determined by an Optical Wrinkleometer comprised of a light source, a traveling specimen holder, a photomultiplier tube, and a recorder system. The light source used was a 35 mm. Argus 300 slide projector mounted so that the angle of light incidence to the lo'ngl' pm the output of the cell.
axis of a yarn sample was 60.
the specimen the lens cap of the projector was 15 inches from the point'on the specimen being measured. 7
a The traveling specimenholder was a mechanical lathe bed powered by a variable speed motor. A yarnholder,
comprised. of a ;-wooden block on which. the yarn waswound, was fastened :onthe bed with the long axis of the yarn oriented in the same direction as the movement of the bed with the plane of the yarn perpendicular to the bed. The yarn sample, 1.8 inches long, was traversed at a speed of 1.31 inches per minutera V The photomultiplier tube (N 931A, gas filled) was mountd in the same horizontal plane as'the light source. Theangle of reflectance from the long axis of the yarn was 60. Reflectance was measured from 13 yarns (0.226 inch across the yarns and 0.00284 inch along the long axis of the-yarns). To accomplish this, a 50 mm. lens was mounted between the specimen and the photomultiplier tube. The yarn image was focused on a ground glass between the lens system and the photomultiplier tube, and the desired yarn area tojbe, measured, as indicated above, was obtained by masking off a slit on the ground glass of f inch by inch which regulated the light reaching the photomultiplier tube.
"The electrical output of the photomultiplier tube was fed into a Leeds & Northrup Type G? recorder with a 0-10 millivolt 'full' scale span, with aback .electromotive force voltage and voltage divider in the recorder system' to give a full scale span of 22.24 to 40.89 millivolts on the recorder chart. 7 V l The light tracing on the recorder was converted to a Luster Highlight 'Index hy multiplying peak frequency per given length of yarn and theaverage difference in the chart units between adjacent chart peaks. An index of 20 is exceptionally good. An index below about; is
poor. 7 y
3. Percent transmitted light. -In'determining' the percent transmitted light, I which is a measuring of white The light'source was operated atllSvolts from a constant voltage. supply and was mounted so-that when the'light was focused on pounds to produce a 0.25 inch elongation. Slippages of less than 0.25 inch are reported as not measurable; The following data were obtained for the three-samples.
1 Table 3 Samples Fabric Construntion (ends and picks) 122 x 7' Fabric Weight (0z./ydfi) c L96 Luster Highlight Tndpsz' 6' a Light; TransmissionJt' (percent) 11. 7.- Light Reflectance-I, .(percent)-. Seam slippage (warp 0.25
in.) fill- 24.4 lbs.
Filament Configuration round Angle A EXAMPLE III 7 Two samples of the same polyhexamethylene adipamide were melt spun using the spinning conditions described in Example II except. the multifilament yarn was a 30 den er, 10 filament yarn. Sample, F4 was prepared properties of the. fabrics made from round cross section light transmitted by a fabric within the range of 1% to V 20% transmission, a photoelectric cell, a light source and "a sample were arranged in a wooden'box, the inside sur-i face of which was painted a flat-black. The amount'of light transmitted through a circular area of each sample which was illuminated by difiuse light was measured. A"
' 1-00-watt frosted incandescent lamp placed six inches from placed in the beam of transmitted light, about eighteen V inches'from the sample, and a Simpson Microammeter, Model 29 (0-50microampere range), was used to measculated by dividing the average of four meter readings for four samples by three.
The instrument was cali- C. Seam slippage.-The seam slippage test measures Testing Materials Method Designation D434-42.' The Instron Tester (Instron Engineering Corp, Quincy,
Mass.) has been substituted 'for the constanttrate of' traverse type of tester specified, and sewing thread of polyethylene terephthalate with equivalent diameter has been substituted for the #OOcotton thread specified. Re-
ported values.v are the average: resistance to slippage in fiber. (Yarn distortion is a measure of the distortion, in inches, of warp or filling yarns in woven fabric after sur- .face friction has been applied. The test used follows the tentative method of testing issued by the American '-Society for Testing Materials (Dl336-54-T An effec- Itive weight of one pound was used on the upper friction murn Requirements for Rayon and Acetate Fabrics, L2
drurn'as recommended in the American Standard Mini American Standards Assoc).
Table 4 Samples Yarn Distortion (inches) 7 EXAMPLE 1v Six pir ns of continuous multifilamcnt polyhexamethylene adipamide yarn, containing 0.3% by weight titanium dioxide, spun under conditions similar to those described in Example 11 and having configurations as set forth'in Table 5 were rated subjectivelyby three people. Luster highlight ratings are based on the samescaleas described in Example vl, lhigh luster to 5-,no apparent luster. The results were as follows:
First number refers to total denier, and second number refers to number of filaments.
EXAMPLE V Two samples of polyhexamethylene adipamide multifilament yarn having trilobal cross sections were spun using the spinning conditions set forth in Table 6. One end of each of the samples was bulked by feeding it through a jet with steam according to the process described in the copending application of Breen and Lauterbach, US. application Serial No. 698,103, filed November 22, 1957. Three ends of the treated yarn were fed to each needle of a standard tufting machine and were tufted into a jute backing to make a loop pile carpet as described in Example 1. into two parts, one-half being dyed red and the other half left undyed. Soil resistance rating and luster highlight rating were accomplished as described in Example I.
The data obtained is set out in the following table:
Table 6 Samples Allele A an 13. M 1. Fl 2. 2.
Melt Temperature 285 0.... 291 C. Chimney Air Flow (i'tfi/min)- 2" 150. Unbulked Yarn (denier-filaments-twistl 1, 160-684]. 1, 020-68-0. 2
m. Bulked Yarn Denier 2,012 1,975. Pile Yarn Weight (0z./yd.'-) 21 19. Luster Highlight Rating 1.0 2.5. Soiling Rating-Red Dyed Carpets (8,000 1. 9 2. 3.
Trafiic Cycles).
EXAMPLE VI Four samples of polyester filaments were prepared. Samples F10 and F11 were prepared from polymer, having a relative viscosity of 19.5 (10% solution of polymer in 10 parts of phenol and 7 parts of trichlorophenol), as described in Belgian Patent 549,179.
In preparing Sample F10 the polymer was melt spun at 296 C. through a stainless steel spinnert of the type described in Example I in which the arms of the openings were 4 mils wide and 7 mils long. The effective thickness of the spinneret at the holes was 12 mils. Upon leaving the spinneret, the extruded filaments were quenched in cross-flow air having a velocity of 65 ft./ min. and a temperature of 70 F., and then wound up as a 50 filament yarn at a windup speed of 1500 yards per minute. The total denier of the spun yarn was 170. The spun yarn was then drawn at a. temperature of 104, using a one-quarter inch ceramic snubbing pin, a draw ratio of 2.5, and a windup speed of 604 yards per minute. The drawn yarn was found to have a total denier of 70, a tenacity of 3.0 grams per denier, and a break elongation of 25%. Sample F11 was prepared substantially as in- Each carpet sample was divided dicated above except a spinneret having round orifices and melt spun at 296 C. through a stainless steel spin neret having symmetrical trilobal and round openings as previously described. Upon leaving the spinneret, the extruded filaments were quenched in cross-flow air having a velocity of 89 feet per minute and a temperature of 70 F., and then wound up as a 203 denier, 50 filament yarn at a windup speed of 1500 yards per minute. The spun yarn was then drawn at a temperature of 102 C. using a one-quarter inch diameter ceramic snubbing pin, a draw ratio of 2.9, and a windup speed of 750 yards per minute. The drawn yarn was found to have a total denier of 70, a tenacity of 4.0 grams per denier, and a break elongation of 25% V The parameters of each of the four continuous filaments are given in Table 7, together with test data. Each sample of polyester yarn (50 filaments, 1.4 denier per filament) was used to make a plain weave taffeta fabric. In weaving, a twist of five 2 turns per inch were used in the warp and zero twist in the filling. The loom construction was 100 ends and picks. Each fabric was scoured at the boil in aqueous medium in relaxed condition and then dried. The fabrics were heat set for one minute at 390 F. The finished Weight of each fabric was 2.2 ounces per square yard. The fabrics were tested for covering power, for soiling in accordance with the soiling test described below, and were rated subjectively for luster highlight as described in Example I. The results of the tests show much better cover, luster highlight,
and soiling resistance for Samples F10 and F 12 than for the control Samples F11 and F13.
Soiling test-The relative soilability of the woven fabric was tested by tumbling in the presence of a standard dry soil composed of the following materials:
The dry soil was mixed with 150 ml. of water, treated on a ball mill, dried at 110 C., and was then broken up and put through a ZOO-mesh screen. The changes in reflectance after soiling and after washing expressed as percentage of the original reflectance were reported. The soilingwashing sequence was repeated twice. The reflectance measurements are the percent of the original reflectance, i.e., reflectance before soiling, retained after the washing following the second soiling.
Soiling was carried out by placing two samples in each of two jars of soil. The jars were tumbled with one hun dred 0.25 inch stainless steel balls for forty-five minutes at 70 F. The reflectance of each sample was measured after soiling. The samples were then washed in a Launder-Ometer, manufactured by the Atlas Electric Devices Company, for twenty minutes in 200 ml. of distilled water at F. with 0.25% of a detergent, made and sold by Procter and Gamble under the tradename Tide, and fifty 0.25 inch stainless steel balls. After washing, the samples were rinsed in distilled water, air dried, and the reflectance again determined. Reflect-ance measurements were determined using a Photovolt Refiectometer, Model 610 (Photovolt Corporation). The instrument was calibrated using a white enamel working standard (Catalog #6162, Photovolt Corporation) ha-ving 70-75 percentage reflectance with a green tristimulus filter (Catalog #6130, Photovolt Corporation).
Table 7 Table 9 Total Samples Model Angle M Light A C) R Reflec- 6 tion F10 F11 1 F12 F13 1.54 "0.3" 71 Angle A 40.6 41.6 1.8 0.3 80 M 1. 50 1. 1. 57 1.0 l; 87 0. 3 77 2.1 0.3 87 0. 47 0.42 2.22 0.3 59 R 1. 52 0. 375 so Covering Power: 7 1. 8 0. 38 50 6.07 7. 37 4. 50 7. 53 3. 56 0 19 70.9' 59.6 73.0 57.2 2.75 0.3 37 Selling Test (Perce 2.9 0.3 69. 6 61. 4 69. 9 62. 4. 1. 0 9 2.7 a 3.7 2.61 4.2
EXAMPLE IX Made from ethylene glycol, 98 mol percent dimethylterephthalate and 2 mol percent sodium 3,5-di- (carbomethoxy) benzenesulfouate.
9 Made from polyethylene terephthalate.
3 Light reflectaucemeasured as described 111 U.S. Patent 2,828,528.
Both yarns exhibited satisfactory luster highlight before bulking and could be bulked as described inExample V. These yarns are adaptable for tufting .into carpets having good resistance tosoiling.
EXAMPLE 9 VIII Several transparent polymethyl methacrylate cylinders of various cross-sectional shapes were machined to give enlarged fiber models having parameters listed in Table 9. A point source of light was moved in all positions with respect to an exposed slit perpendicular tothe axis of and in front of each model. The reflected light was measured by exposing photographic paper, and the resulting exposed portions were integrated to give single numbers representing total light reflections from internal surfaces for each model. Models with a value of at least typify samples which would have sufficient internally reflected light to exhibit a combination of good luster highlight and soil resistance,whereas those models with numbers substantially less than 50 confirm the unsatisfactory luster highlight of actual fiber samples tested. The models as well as the filaments described in the preceding examples are plotted on the graph in Figures 3 and 4.
One sample of yarn, identified as Sample F14, was prepared from polyethylene terephthalate polymer having a relative viscosity of 25.5 (10%. solution of polymer in 10 parts phenol and 7 parts of trichlorophenol), as described in U.S. Patent 2,465,319.
The polymer containing 0.3% TiO was melt spun at 305 C. through a stainless steel spinneret having a diameter of 3 inches. This spinneret was used to spin two yarn bundles, each bundle consisting of 34 continuous filaments. The individual filaments were spun from a group of four holes, each of which had a diameter of 6 mils, with three of the holes arranged radially 120 apart about the fourth hole to produce one coalesced filament. The distance between the center hole and each of the three radialholes was 7 mils, center to center. The efiective thickness of the spinneret at each hole was 8 mils.
Upon leaving the spinneret, each extruded filament, formed by coalescence of the polymer from each group of four holes, was quenched with cross-flow air having a velocity of approximately 20 ft./min. and a temperature 7 of F. The filaments were wound up as a 34-filarnent yarn at a windu'p speed of 600 yds./niin.
The drawn yarn was found to have a total denier of 52.3, a tenacity of 43 grams "per denier, a break elongation of 24.5%, and a boil-ofi" shrinkage of 9.5%. Measurements made on yarn cross-sections showed that each filament had an average modification ratio (M) of 1.65, an average angle (A) of 18.4, and an average ratio 1 R of 0.45.
The F14 yarn described above was woven into a plain weave taffeta fabric. In weaving, a twist of 7 2 turns per inch were used in the warp and zero twist in the filling. The loom construction was 1:16 ends and 92 picks. The fabric was. scoured .at the boil in. aqueous medium in a jig and then dried, followed by heat-setting for one minute at 390 F. The finished weight of the .fabricwas 1.78 ounces per square yard, :having .a construction of 141 ends and 102 picks. The fabric was rated subjectively for luster highlight by five people, using the same scale as described in Example 1. The average of the five ratings was 2.1.
' EXAMPLE X Z Y Three samples of polyethylene terephthalate multi-fil-amerit yarn were spun with the same 'spinneret described in Example IX, except that spinning conditions were adjusted to produce the cross-sectional parameters described in Table 10. r
Table 10 V Yarn Fabric Details (total Luster Sample denier- Angle M 2. High- No. number A R Warp, Fill, Weight, light fila- Ends/111.. Picks/In. Oz. Yd. Rating merits) 13 These three yarns were woven into fabric and finished by the same procedure as that described in Example IX. Luster highlight ratings reported in Table 1'0 were based on the same scale as described in Example I, and the values reported were the average subjective ratings of five people. Samples F16 and F17 were rated as being much poorer than Sample F15 in luster highlight.
EXAMPLE X1 Seven samples of polyhexamethylene adiparnide were melt spun from polymer containing 0.75% titanium dioxide by weight through spinnerets of the type described in the aforementioned copending application Serial No. 517,434 as trilobal filaments under slightly varying conditions to give yarns having cross-sections as indicated for Samples F20 through F26, inclusive, in Table 11. Two samples of round filaments (F18 and F19) were also spun and made into similar yarns to serve as controls. Each of these nine yarns contained 13 filaments and had a total denier of 40.
Each of the yarns was woven into a plain-weave fabric, the warp yarns of each fabric having a twist of 7 /2 2 turns per inch and the filling yarns each having a twist of one-half 2 turns per inch. All nine fabrics were finished by the method described in Example IX. These fabrics when rated subjectively by five people for luster highlight showed the trilobal fibers to be superior to comparable control fabrics having fibers of round cross-section based on the same scale as used in Example I. The fabric constructions and luster highlight ratings for all nine fabrics are given in Table 11.
Table 11 Fabric Details Luster Angle M Q High- A() R Warp F111 Weight light Ends/ Picks] Oz./Yd. Rating In. In.
1. 146 102 1. 38 5. 0 1. 0 142 102 1. 38 4. 3 1.42 0. 55 151 103 1. 45 2. 7 1.49 0.44 151 102 l. 46 2. 1. 54 O. 51 147 101 l. 42 2. 1 1. 64 0. 48 145 101 1. 43 2. 3 1. 68 0. 36 148 101 1. 41 2. 3 1. 77 0.41 151 97 1. 40 3.1 1. 84 0. 36 153 97 1. 43 2. 9
1 Round cross-section containing 2.0% TiO, by weight. 2 Round cross-section containing 0.3% T102 by weight.
EXAMPLE XII Filaments of polyhexamethylene adipamide having a trilobal cross-section (angle A=30, M =2.03,
were melt spun into a multifilament yarn. The melt contained 0.02% titanium dioxide. The yarn (identified as Sample C11) was melt spun through a spinneret containing 68 holes, each hole being characterized by three slots lying at 120 to each other and joined at the center. The length of each rectangular slot was approximately 12 mils and the width 3 mils. The temperature of the melt adjacent to the spinneret was 296 C. The chimney air flow was 340 ft. /min. at a temperature of 50 F. The yarn was spun at 429 yards per minute and was drawn approximately 4 x, giving a final denier of about 1000. One end of the drawn yarn was bulked by the same process as that described in Example V. A tufted carpet was prepared from the bulked yarn and was tested for luster highlight and soil resistance. The luster highlight rating of the tufted carpet was 1.7. This carpet was rated for soiling as considerably better, i.e., it soiled much less, than a control carpet made of round fibers of the same denier and composition.
EXAMPLE XIII Four different samples of trilobal polyhexamethylene" adipamide filaments were melt spun into yarns using the same type of spinneret as described in Example XII but adjusting the spinning conditions slightly to give the fi1a-:
ment parameters listed in Table 12. The amount of titanium dioxide in each melt is alsolisted in Table 12. Each yarn was bulked and then made into a tufted carpet as described in Example XII. Each carpet was rated for luster highlight and the ratings are given in Table 12.
Table 12 Luster Sample No. Angle M r T10, High- A T (Percent) light Rating The carpets were rated for soil resistance as much better, i.e., less soiling, than the same control carpet of round filaments referred to in Example XII.
EXAMPLE XIV A sample of polypropylene, having a melt index of.
12 at C. as measured by ASTM Test Method D-123852T, was melt spun into filaments (identified as Sample K1) having a trilobal cross-section (angle A=39,M=1.95,
The polymer was melt spun into a multifilament yarn through a spinneret containing 20 holes, each hole being an equilateral triangle 9 mils long on each side. At each vertex of the triangle a square slot was cut, running 3 mils in length from the vertex and being 3 mils wide. The temperature of the melt at the spinneret was 200 C.
The yarn windup speed was 65 yards per minute and the denier of the as-spun yarn was 2300. The yarn was drawn at approximately 6 x at 124 C. over a hot pin. The as-drawn yarn had a tenacity of 4.6 grams per denier,
an elongation of 76%, and an initial modulus of 54 grams per denier. Each filament had a denier of 20. The drawn yarn was wound on a cone and in this form was compared with a sample of polypropylene yarn made of filaments having a round cross-section. The yarn of trilobal polypropylene filaments exhibited a unique luster highlight to the unaided eye, compared to the dull, fiat appearance of the round filament yarn.
EXAMPLE XV This example describes the preparation of full-fashioned ladies hosiery using the trilobal filaments of this invention. The hosiery were knit on a 60-gauge, 4-position Reiner full-fashioned hosiery machine (Robert Reiner,
Inc., Weehawken, N.l.), using for the leg fabric continuous filament yarn (15 denier, 2 filament, 1/ 4 Z twist) of polyhexamethylene adipamide containing 0.3% titanium dioxide by weight, each filament having a trilobal cross-section wherein the angle A=57, M=1.S0, and
" of luster highlight.
' round filament hosiery are dyed.
hosiery were extremely brilliant, exhibiting a high level Hosiery prepared with conventional 1544/; 2 nylon .yarn of round filaments in the leg fabric using thesame procedure and dyes as above did not exhibit any ofthese luster highlights but, by comparison, appeared extremely dull and had low color clarity. The luster highlight in the sample of trilobal filaments and the difference between this "and the dull flatness in the sample of round filaments were readily apparent with'the hosiery layingfiat on a surface or while being worn.
Although the above hosiery. were seam-type hosiery equally attractive Womens hosiery exhibiting unique luster highlight were prepared with trilobal filament yarns in seamless hosiery. In other hosiery samples the welt yarns and splicing yarns were also made of trilobal crosssection filaments to produce hosiery in which all sections of the hosiery exhibited luster highlight. The trilobal filament hosiery may be dyed toany and allsliades that The foregoing examples clearly illustrate the fact that the cross-sectional shape of the fiber or filament is critical in producing yarns and woven, knitted, and non-Woven fabrics which have a combination of luster highlight, soil resistance, and other desirable physical properties.
, The staple fiber or continuous filaments of the present invention may be prepared from a variety of synthetic polymers. 'Am'ong the most important polymers are the polyamides such as p'olyhexamethylene adipamide, pol hexamethylene sebacarnide, polycaproamide, polyxylylene azelamide, p'o'lyo'ct'amethylene oxalar'nide, polyp'yrrolidone, polymetaphenylene isophthalamide, polymers phenylene adipamide; copolyamides, and irradiation grafted polyamides; and the polyesters and copolyesters such as the condensation products of ethylene glycol with terephthalic acid, ethylene" glycol with a 98/2 mixture of terephthalic/S-(sddiuni sulfo)-isophthalic acids, ethylene glycol with a 90/10 mixture of terephthalic and isophthalic acids, polyesters derived from 2,2-bis(4-hydr'oxyphenyl) propane, and trans-p-hexahydroxylylene glycol with terephthalic acid; acrylonitrile polymers and copolymers such as poiyacryionitrile, copolymersof acrylonitrile with vinyl pyridine, vinylidene chloride, vinyl chloride, or methyl acrylate; vinyl chloride polymers and copolyme'rs, vinylidene chloride polymers and copolymers; polyurethanes, e.g., those described in French Patent 1,172,566, polyesteramides, polyethylenes, polypropylen'es, polycarbonates such'as those derived from 2,2-
bis'(4-hydroxyphenyl) propane, fluorinated ethylene polymers and copolymers such aspolymers of 'tetrafiuoroethylene, hexailuoropropene, and monochlorotrifluoroethylene; composite filaments such as,for example, a sheath of polyamides around a coreof' polyester as described in the application of Breen, Serial No. 621,443, filed November 9, 1956, now abandoned, of whichSerial No. 771,676, filed November 3, 1958, is a continuation-.
in part, and two acrylonitrile polymers differing in ionizable group content spun as a sheath and core as described in the'application of Taylor, Serial No. 640,722, filed T "February 18', 1957, now abandoned, of'which Serial No.
771,677, filed November 3, 1958 is a continuation-in-part;
' cellulose acetate, regenerated cellulose, and the like. The
fibers and filaments may be crimped or u'ncrirnped, drawn or undrawn, and/or bulked or unbulked. Mixtures of the above fibers as Well as blends containing a major proportion of the synthetic fibers of this invention with a minor proportion of natural fibers may be used to prepare fabrics.
The filaments of this invention are particularly useful in bulked form. Bulking may be conveniently achieved by a number of methods. For example, a particularly desirable bulking process is described in the copending application of Breed and Lauterbach, Serial No. 698,103,
7 filedYNovember 22, 1957. The novel filaments of this invention are peculiarly adaptable to being Processed by.
the bulking process of the just mentioned application;
, iii I The tr'ilobal filaments of this invention may also be treated according to the process described in the copending application of Breen and Sussr'nan, Serial No.8 10,671, filed May 4, 1959, to provide desirable products.
Obviously, slight variations in the configuration of the filaments of this invention may be present without impairing their desirable properties, e.g., the sides of the lobes of the filament need not be absolutely straight nor must the curved terminal portion be perfectly circular. The sides may curve slightly inwardly or outwardly. Other slight distortions may be introduced in the filament when it is spun or during the processing operations, such as drawing, crimping, twisting, dyeing, or bulking.
' The chief advantage of this invention is that it provides 'seam' slippage and less yarn distortion than those made from filaments of round cross-section The improved fabrics also exhibit a greater coefiicient of friction, resulting in betterfabric tactile properties. The improved soiling resistance of the woven, knitted, and non-Woven fabricstof this invention includes resistance to soiling by either dry or oily soils. The higher denier pile fabrics exhibit better mechanical bulk both before being used as ,well as after being in use when compared with control fabrics having round fibers and fibers having moderate to high modification ratios. In addition, the fibers oi the present invention have improved dye wash fastness over fibers having higher modification ratios. The novelfibers of this invention have a higher rate of dyeing and a greater stifiness than round fibers due to their more efiicient cross-sectional shape. Also, they do not collapse as do those fibers of higher modification ratio. Another advantage is that knitted fabrics prepared from the bulked trilobal filament yarns exhibit less pickiness? than do comparable fabrics knitted from bulked round filament yarns.
The novel fibers and filaments of this invention may be employed to produce a Wide variety of different types of fabrics, including both apparel and industrial textile products. Specific examples of these products include shirtings, suitings, dress and blouse fabrics, hosiery, sheeting, lingerie, taffetas, georgettes, sand-crepes, tissuefailles, foulards, broadcloths, batistes, rainwear, surah, tricot, tulles, circular knitted goods, satiris, chifi'ons, sheers', wash-wear fabrics, crepes, casement fabrics, upholstery, filter cloths, ducks,.beltin'gs, webbing, braids, cordage'and twine, fiber-reinforced laminates, tire cord, coated fabrics, stufiing materials, floor coverings, and tiles. The products of this invention are particularly useful in preparing various types of carpeting, e.g.,- tufted, chenille, Smyrna, Wilton, Saxony, Brussels; velvet, Axminster', Orientals, knitted, pleated, and the like, due to their improvedsoil resistance, unique luster highlight, dye brightness, and bulkingpower. e
It will be apparent that many widely different embodiments of this invention may be made without departing from the spirit and scope thereof, and therefore it is not intended to be limitedexcept as indicated in'the appended claims I claim:
1. A textile filament prepared from a synthetic polymer having an essentially trilobal cross-section along its length, said cross-section a tip radius ratio and an arm angle A within the range represented by the area LNP on Figure 3 of the drawing and a modification ratio M within the range represented by the area VUZ on Figure 4 of the drawing, the lobes of said cross section being substantially equi-spaced and having an essen tially symmetrical configuration.
2. The filament of claim 1 wherein said polymer is a polyester.
3. The filament or" claim 2 wherein said polymer is comprised of polyethylene terephthalate.
4. The filament of claim 2 wherein said polyester contains a major proportion of terephthalate radicals and up to 2 mol percent of 5-(sodium sulfo)-isophthalate radicals.
5. The filament of claim 1 wherein said polymer is polypropylene.
6. The filament of claim 1 wherein said polymer is a polyamide.
7. The filament of claim 6 wherein said polyarnide is polyhexamethylene adipamide.
8. The filament of claim 1 wherein the tip radius ratio and an arm angle A within the range represented by the area LNP on Figure 3 of the drawing and a modification ratio M within the range represented by the area VUZ on Figure 4 of the drawing, the lobes of said cross section being substantially equi-spaced and having an essentially symmetrical configuration.
12. The yarn of claim 11 comprised of filaments wherein the arm angle A is between about 7 and 60.
-13. The yarn of claim 12 wherein the tip radius ratio is within the range represented by the area QST on Figure 3 of the drawing.
14. A knitted textile fabric prepared from the yarn of claim 13.
15. The yarn of claim 11 wherein said filaments are continuous filaments.
16. A textile fabric having improved luster highlight and improved covering power comprised of filaments prepared from a synthetic polymer having an essentially uniform trilobal cross-section along its length, said crosssection having a tip radius ratio and an arm angle A within the range represented by the area LNP on Figure 3 of the drawing and a modification ratio M within the range represented by the area VUZ on Figure 4 of the drawing, the lobes of said cross section being substantially equi-spaced and having an essentially symmetrical configuration.
17. The fabric of claim 16 wherein said tip radius ratio is between about 0.275 and 0.62, said arm angle A is between about 7 and 74, and said modification ratio M is between about 1.33 and 2.0.
18. A floor covering material having improved optical properties and improved resistance to soiling comprised of textile filaments prepared from a synthetic polymer having an essentially uniform trilobal cross-section along its length, said cross section having a tip radius ratio and an arm angle A within the range represented by the area LNP on Figure 3 of the drawing and a modification ratio M within the range represented by the area VUZ on Figure 4 of the drawing, the lobes of said cross section being substantially equi-spaced and having an essentially symmetrical configuration.
19. The material of claim 18 wherein said tip radius ratio is between about 0.22 and 0.37, said arm angle A is between about -17 and 40, and said modification ratio M is between about 1.7 5 and 2.6.
References Cited in the file of this patent UNITED STATES PATENTS UNITED STATES PATENT OFFICE Certificate of Correction Patent No. 2,939,201 June 7, 1960 Marlin C. Holland It is hereby certified that error appears in the printed specification of the above numbered patent requiring correction and that the said Letters Patent should read as corrected below.
cos
R- TBBLl R- column 13, lines 54: to 56, strike out the opening parenthesis; column 14, Table 12,
heading to the fourth column thereof should appear as shown below instead of as in the patent:
F column 17, line 2, after cross-section insert having.
Signed and sealed this 22nd day of November 1960.
Attest KARL H. AXLINE, ROBERT C. WATSON, Atteating Oficer. Oouwnissz'omr of Patents.
Claims (1)
1. A TEXTILE FILAMENT PREPARED FROM A SYNTHETIC POLYMER HAVING AN ESSENTIALLY TRILOBAL CROSS-SECTION ALONG ITS LENGTH, SAID CROSS-SECTION A TIP RADIUS RATIO
Priority Applications (6)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
NL241210D NL241210A (en) | 1958-07-14 | ||
BE580688D BE580688A (en) | 1958-07-14 | ||
US82251459 US2939201A (en) | 1959-06-24 | 1959-06-24 | Trilobal textile filament |
FR800027A FR1233756A (en) | 1958-07-14 | 1959-07-11 | New trilobed synthetic filaments and fibers |
GB24016/59A GB924087A (en) | 1958-07-14 | 1959-07-13 | Improvements in or relating to fabrics other than garments |
CH7573059A CH398465A (en) | 1958-07-14 | 1959-07-14 | Process for the production of a textile floor covering from pile fabric or a decoration fabric |
Applications Claiming Priority (1)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
US82251459 US2939201A (en) | 1959-06-24 | 1959-06-24 | Trilobal textile filament |
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US2939201A true US2939201A (en) | 1960-06-07 |
Family
ID=25236241
Family Applications (1)
Application Number | Title | Priority Date | Filing Date |
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US82251459 Expired - Lifetime US2939201A (en) | 1958-07-14 | 1959-06-24 | Trilobal textile filament |
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US (1) | US2939201A (en) |
Cited By (61)
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US3097416A (en) * | 1960-09-26 | 1963-07-16 | Du Pont | Textile filaments |
US3109278A (en) * | 1960-08-19 | 1963-11-05 | Du Pont | Multilobal textile filaments having controlled uniform twist and fabrics prepared therefrom |
US3109220A (en) * | 1960-08-19 | 1963-11-05 | Du Pont | Tetralobal cross-sectioned filaments |
US3109768A (en) * | 1960-01-06 | 1963-11-05 | Du Pont | Textile filament |
US3121040A (en) * | 1962-10-19 | 1964-02-11 | Polymers Inc | Unoriented polyolefin filaments |
US3156085A (en) * | 1959-09-24 | 1964-11-10 | Du Pont | Continuous composite polyester filament yarn |
US3169089A (en) * | 1960-04-22 | 1965-02-09 | Celanese Corp | Filaments |
US3169363A (en) * | 1963-02-14 | 1965-02-16 | Eastman Kodak Co | Elastomeric yarn |
US3216186A (en) * | 1963-05-14 | 1965-11-09 | Allied Chem | Modified cross section yarn |
US3220173A (en) * | 1964-12-02 | 1965-11-30 | Du Pont | Trilobal filamentary yarns |
US3239865A (en) * | 1965-03-24 | 1966-03-15 | E B & A C Whiting Company | Brush containing polypropylene bristles |
US3308221A (en) * | 1963-05-14 | 1967-03-07 | Allied Chem | Melt spinning of modified cross section yarn |
US3508390A (en) * | 1968-09-30 | 1970-04-28 | Allied Chem | Modified filament and fabrics produced therefrom |
US3635259A (en) * | 1970-02-27 | 1972-01-18 | Burlington Industries Inc | Imitation mohair fabric |
US3846969A (en) * | 1972-04-13 | 1974-11-12 | Du Pont | False-twist texturing yarn of polyester filaments having multilobal cross sections |
DE2445558A1 (en) * | 1973-09-24 | 1975-03-27 | Du Pont | POLYESTER THREAD OR FIBER AND ITS OR YOUR USE |
US3903348A (en) * | 1973-10-09 | 1975-09-02 | Akzona Inc | Antisoiling synthetic fibers |
DE2611830A1 (en) * | 1975-03-20 | 1976-09-30 | Du Pont | MIXTURE AND MIXED YARN MADE OF CRIMPED POLYAMIDE STAPLE FIBER AND METHOD OF MANUFACTURING THE SAME |
US4001369A (en) * | 1976-03-04 | 1977-01-04 | E. I. Du Pont De Nemours And Company | Process for cospinning trilobal filaments |
US4041689A (en) * | 1975-11-11 | 1977-08-16 | E. I. Du Pont De Nemours And Company | Multilobal polyester yarn |
USRE29363E (en) * | 1973-08-30 | 1977-08-23 | E. I. Du Pont De Nemours And Company | False-twist texturing yarn of polyester filaments having multilobal cross sections |
US4062204A (en) * | 1973-06-18 | 1977-12-13 | Ancase S.A. | High luster interlock fabric incorporating producer twist yarns |
US4091065A (en) * | 1976-12-14 | 1978-05-23 | E. I. Du Pont De Nemours And Company | Melt spinning process |
DE2853352A1 (en) * | 1977-12-12 | 1979-06-13 | Monsanto Co | PROCESS FOR SPINNING A MULTIFILAMENT POLYESTER YARN |
JPS575912A (en) * | 1980-06-04 | 1982-01-12 | Toray Ind Inc | Modified cross-section yarn and its production |
US4492731A (en) * | 1982-11-22 | 1985-01-08 | E. I. Du Pont De Nemours And Company | Trilobal filaments exhibiting high bulk and sparkle |
US4583357A (en) * | 1983-11-21 | 1986-04-22 | Monsanto Company | Partially oriented nylon yarn and process |
EP0201812A2 (en) * | 1985-05-13 | 1986-11-20 | AlliedSignal Inc. | Hollow trilobal cross-section filament |
US4646514A (en) * | 1983-04-25 | 1987-03-03 | Monsanto Company | Partially oriented nylon yarn and process |
US4702875A (en) * | 1985-06-14 | 1987-10-27 | E. I. Du Pont De Nemours And Company | Process for producing high tenacity polyhexamethylene adipamide yarn having ribbon cross-section |
US4719060A (en) * | 1986-07-17 | 1988-01-12 | E. I. Du Pont De Nemours And Company | Method of predicting yarn properties |
US4760691A (en) * | 1983-04-25 | 1988-08-02 | Monsanto Company | Partially oriented nylon yarn and process |
US4801503A (en) * | 1985-06-14 | 1989-01-31 | E. I. Du Pont De Nemours And Company | High tenacity polyhexamethylene adipamide yarn having ribbon cross-section filaments |
US4816550A (en) * | 1985-09-17 | 1989-03-28 | Monsanto Company | Polyamide feed yarn for air-jet texturing |
USRE33059E (en) * | 1983-11-21 | 1989-09-19 | Monsanto Company | Partially oriented nylon yarn and process |
US5108838A (en) * | 1991-08-27 | 1992-04-28 | E. I. Du Pont De Nemours And Company | Trilobal and tetralobal filaments exhibiting low glitter and high bulk |
US5175038A (en) * | 1990-09-07 | 1992-12-29 | E. I. Du Pont De Nemours And Company | Carpet yarns and carpets with improved balance of newness retention and bulk |
US5176926A (en) * | 1991-08-27 | 1993-01-05 | E. I. Du Pont De Nemours And Company | Spinnerets for producing trilobal and tetralobal filaments exhibiting low glitter and high bulk |
US5202185A (en) * | 1989-05-22 | 1993-04-13 | E. I. Du Pont De Nemours And Company | Sheath-core spinning of multilobal conductive core filaments |
US5208106A (en) * | 1991-08-27 | 1993-05-04 | E. I. Du Pont De Nemours And Company | Trilobal and tetralobal filaments exhibiting low glitter and high bulk |
US5208107A (en) * | 1991-05-31 | 1993-05-04 | Basf Corporation | Hollow trilobal cross-section filament |
US5322736A (en) * | 1993-06-24 | 1994-06-21 | Alliedsignal Inc. | Hollow-trilobal cross-section filaments |
US5334452A (en) * | 1992-11-16 | 1994-08-02 | Monsanto Company | Carpet fibers having multifoliate cross-sectional configuration |
WO1999039029A1 (en) * | 1998-01-30 | 1999-08-05 | E.I. Du Pont De Nemours And Company | Filament having a trilobal cross section and a trilobal void |
US20020098356A1 (en) * | 1996-09-16 | 2002-07-25 | Basf Corporation | Dyed sheath/core fibers and methods of making same |
WO2002072932A1 (en) * | 2001-03-14 | 2002-09-19 | E. I. Du Pont De Nemours And Company | Melt spun yarns having high lustre |
US20030104163A1 (en) * | 1996-09-16 | 2003-06-05 | Basf Corporation, Inc. | Colored fibers having resistance to ozone fading |
US6589653B2 (en) | 2001-08-08 | 2003-07-08 | E. I. Du Pont De Nemours And Company | Filament having a quadrilobate exterior cross-section and a four-sided void |
US6673442B2 (en) | 2000-05-25 | 2004-01-06 | E.I. Du Pont De Nemours And Company | Multilobal polymer filaments and articles produced therefrom |
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EP0602201B2 (en) † | 1992-07-03 | 2004-01-28 | Nylstar Sa | Shaped-section fine-fibre filament yarn and method of producing it |
US20040132375A1 (en) * | 2000-10-16 | 2004-07-08 | Toyotaka Fukuhara | Thermal insulating material for housing use and method of using the same |
US7033669B2 (en) | 2002-02-13 | 2006-04-25 | Honeywell Int Inc | Cationically dyed fibers and articles containing the same |
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US20120064281A1 (en) * | 2009-05-18 | 2012-03-15 | James Taylor | Tufted Carpet for Automotive Applications |
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US20180206564A1 (en) * | 2017-01-20 | 2018-07-26 | Jun Ji | Process for producing a knitted sweatband |
US20180206572A1 (en) * | 2017-01-20 | 2018-07-26 | Jun Ji | Process for producing air knit headwear |
US10465320B2 (en) | 2012-05-12 | 2019-11-05 | Autoneum Management Ag | Needle punched carpet |
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US3156085A (en) * | 1959-09-24 | 1964-11-10 | Du Pont | Continuous composite polyester filament yarn |
US3109768A (en) * | 1960-01-06 | 1963-11-05 | Du Pont | Textile filament |
US3169089A (en) * | 1960-04-22 | 1965-02-09 | Celanese Corp | Filaments |
US3109278A (en) * | 1960-08-19 | 1963-11-05 | Du Pont | Multilobal textile filaments having controlled uniform twist and fabrics prepared therefrom |
US3109220A (en) * | 1960-08-19 | 1963-11-05 | Du Pont | Tetralobal cross-sectioned filaments |
US3097416A (en) * | 1960-09-26 | 1963-07-16 | Du Pont | Textile filaments |
US3121040A (en) * | 1962-10-19 | 1964-02-11 | Polymers Inc | Unoriented polyolefin filaments |
US3169363A (en) * | 1963-02-14 | 1965-02-16 | Eastman Kodak Co | Elastomeric yarn |
US3216186A (en) * | 1963-05-14 | 1965-11-09 | Allied Chem | Modified cross section yarn |
US3308221A (en) * | 1963-05-14 | 1967-03-07 | Allied Chem | Melt spinning of modified cross section yarn |
US3220173A (en) * | 1964-12-02 | 1965-11-30 | Du Pont | Trilobal filamentary yarns |
US3239865A (en) * | 1965-03-24 | 1966-03-15 | E B & A C Whiting Company | Brush containing polypropylene bristles |
US3508390A (en) * | 1968-09-30 | 1970-04-28 | Allied Chem | Modified filament and fabrics produced therefrom |
US3635259A (en) * | 1970-02-27 | 1972-01-18 | Burlington Industries Inc | Imitation mohair fabric |
US3846969A (en) * | 1972-04-13 | 1974-11-12 | Du Pont | False-twist texturing yarn of polyester filaments having multilobal cross sections |
US4062204A (en) * | 1973-06-18 | 1977-12-13 | Ancase S.A. | High luster interlock fabric incorporating producer twist yarns |
USRE29363E (en) * | 1973-08-30 | 1977-08-23 | E. I. Du Pont De Nemours And Company | False-twist texturing yarn of polyester filaments having multilobal cross sections |
DE2445558A1 (en) * | 1973-09-24 | 1975-03-27 | Du Pont | POLYESTER THREAD OR FIBER AND ITS OR YOUR USE |
US3903348A (en) * | 1973-10-09 | 1975-09-02 | Akzona Inc | Antisoiling synthetic fibers |
DE2611830A1 (en) * | 1975-03-20 | 1976-09-30 | Du Pont | MIXTURE AND MIXED YARN MADE OF CRIMPED POLYAMIDE STAPLE FIBER AND METHOD OF MANUFACTURING THE SAME |
US4041689A (en) * | 1975-11-11 | 1977-08-16 | E. I. Du Pont De Nemours And Company | Multilobal polyester yarn |
US4001369A (en) * | 1976-03-04 | 1977-01-04 | E. I. Du Pont De Nemours And Company | Process for cospinning trilobal filaments |
DE2657050A1 (en) * | 1976-03-04 | 1977-09-08 | Du Pont | PROCESS FOR THE COMMON SPINNING OF AT LEAST TWO SYNTHETIC TRIPLE LEAF FEDES |
FR2343063A1 (en) * | 1976-03-04 | 1977-09-30 | Du Pont | ADVANCED IN JOINT SPINNING OF SYNTHETIC TRILOBE FILAMENTS |
US4091065A (en) * | 1976-12-14 | 1978-05-23 | E. I. Du Pont De Nemours And Company | Melt spinning process |
DE2853352A1 (en) * | 1977-12-12 | 1979-06-13 | Monsanto Co | PROCESS FOR SPINNING A MULTIFILAMENT POLYESTER YARN |
JPS575912A (en) * | 1980-06-04 | 1982-01-12 | Toray Ind Inc | Modified cross-section yarn and its production |
JPS6253606B2 (en) * | 1980-06-04 | 1987-11-11 | Toray Industries | |
US4492731A (en) * | 1982-11-22 | 1985-01-08 | E. I. Du Pont De Nemours And Company | Trilobal filaments exhibiting high bulk and sparkle |
US4760691A (en) * | 1983-04-25 | 1988-08-02 | Monsanto Company | Partially oriented nylon yarn and process |
US4646514A (en) * | 1983-04-25 | 1987-03-03 | Monsanto Company | Partially oriented nylon yarn and process |
US4583357A (en) * | 1983-11-21 | 1986-04-22 | Monsanto Company | Partially oriented nylon yarn and process |
USRE33059E (en) * | 1983-11-21 | 1989-09-19 | Monsanto Company | Partially oriented nylon yarn and process |
EP0201812B1 (en) * | 1985-05-13 | 1991-05-02 | AlliedSignal Inc. | Hollow trilobal cross-section filament |
EP0201812A2 (en) * | 1985-05-13 | 1986-11-20 | AlliedSignal Inc. | Hollow trilobal cross-section filament |
US4801503A (en) * | 1985-06-14 | 1989-01-31 | E. I. Du Pont De Nemours And Company | High tenacity polyhexamethylene adipamide yarn having ribbon cross-section filaments |
US4702875A (en) * | 1985-06-14 | 1987-10-27 | E. I. Du Pont De Nemours And Company | Process for producing high tenacity polyhexamethylene adipamide yarn having ribbon cross-section |
US4816550A (en) * | 1985-09-17 | 1989-03-28 | Monsanto Company | Polyamide feed yarn for air-jet texturing |
US4719060A (en) * | 1986-07-17 | 1988-01-12 | E. I. Du Pont De Nemours And Company | Method of predicting yarn properties |
US5202185A (en) * | 1989-05-22 | 1993-04-13 | E. I. Du Pont De Nemours And Company | Sheath-core spinning of multilobal conductive core filaments |
US5175038A (en) * | 1990-09-07 | 1992-12-29 | E. I. Du Pont De Nemours And Company | Carpet yarns and carpets with improved balance of newness retention and bulk |
US5208107A (en) * | 1991-05-31 | 1993-05-04 | Basf Corporation | Hollow trilobal cross-section filament |
US5108838A (en) * | 1991-08-27 | 1992-04-28 | E. I. Du Pont De Nemours And Company | Trilobal and tetralobal filaments exhibiting low glitter and high bulk |
US5208106A (en) * | 1991-08-27 | 1993-05-04 | E. I. Du Pont De Nemours And Company | Trilobal and tetralobal filaments exhibiting low glitter and high bulk |
US5176926A (en) * | 1991-08-27 | 1993-01-05 | E. I. Du Pont De Nemours And Company | Spinnerets for producing trilobal and tetralobal filaments exhibiting low glitter and high bulk |
EP0602201B2 (en) † | 1992-07-03 | 2004-01-28 | Nylstar Sa | Shaped-section fine-fibre filament yarn and method of producing it |
US5334452A (en) * | 1992-11-16 | 1994-08-02 | Monsanto Company | Carpet fibers having multifoliate cross-sectional configuration |
US5322736A (en) * | 1993-06-24 | 1994-06-21 | Alliedsignal Inc. | Hollow-trilobal cross-section filaments |
US20020098356A1 (en) * | 1996-09-16 | 2002-07-25 | Basf Corporation | Dyed sheath/core fibers and methods of making same |
US20020110688A1 (en) * | 1996-09-16 | 2002-08-15 | Basf Corporation | Dyed sheath/core fibers and methods of making same |
US6531218B2 (en) | 1996-09-16 | 2003-03-11 | Basf Corporation | Dyed sheath/core fibers and methods of making same |
US20030104163A1 (en) * | 1996-09-16 | 2003-06-05 | Basf Corporation, Inc. | Colored fibers having resistance to ozone fading |
WO1999039029A1 (en) * | 1998-01-30 | 1999-08-05 | E.I. Du Pont De Nemours And Company | Filament having a trilobal cross section and a trilobal void |
US6048615A (en) * | 1998-01-30 | 2000-04-11 | E. I. Du Pont De Nemours And Company | Filament having a trilobal cross-section and a trilobal void |
US6673442B2 (en) | 2000-05-25 | 2004-01-06 | E.I. Du Pont De Nemours And Company | Multilobal polymer filaments and articles produced therefrom |
US6855420B2 (en) | 2000-05-25 | 2005-02-15 | Invista North America S.A.R.L. | Multilobal polymer filaments and articles produced therefrom |
US20040132375A1 (en) * | 2000-10-16 | 2004-07-08 | Toyotaka Fukuhara | Thermal insulating material for housing use and method of using the same |
US6652965B2 (en) | 2001-03-14 | 2003-11-25 | E. I. Du Pont De Nemours And Company | Melt spun yarns having high luster |
WO2002072932A1 (en) * | 2001-03-14 | 2002-09-19 | E. I. Du Pont De Nemours And Company | Melt spun yarns having high lustre |
US20040046278A1 (en) * | 2001-03-14 | 2004-03-11 | Merigold Richard J. | Melt spun yarns having high lustre |
AU2002245681B2 (en) * | 2001-03-14 | 2006-11-09 | Invista Technologies S.A.R.L. | Melt spun yarns having high lustre |
US6589653B2 (en) | 2001-08-08 | 2003-07-08 | E. I. Du Pont De Nemours And Company | Filament having a quadrilobate exterior cross-section and a four-sided void |
US6673450B2 (en) | 2002-02-11 | 2004-01-06 | Honeywell International Inc. | Soft hand, low luster, high body carpet filaments |
US20040071963A1 (en) * | 2002-02-11 | 2004-04-15 | Honeywell International Inc. | Soft hand, low luster, high body carpet filaments |
US7033669B2 (en) | 2002-02-13 | 2006-04-25 | Honeywell Int Inc | Cationically dyed fibers and articles containing the same |
US20080210769A1 (en) * | 2006-10-09 | 2008-09-04 | Lg Electronics Inc. | Heating system, drying machine having the heating system, and method of controlling the heating system |
US8042284B2 (en) * | 2006-10-09 | 2011-10-25 | Lg Electronics Inc. | Heating system, drying machine having the heating system, and method of controlling the heating system |
US20120064281A1 (en) * | 2009-05-18 | 2012-03-15 | James Taylor | Tufted Carpet for Automotive Applications |
US10465320B2 (en) | 2012-05-12 | 2019-11-05 | Autoneum Management Ag | Needle punched carpet |
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US20140271745A1 (en) * | 2013-03-15 | 2014-09-18 | The Procter & Gamble Company | Personal Care Article Comprising Dissolvable Fibers |
US20180206564A1 (en) * | 2017-01-20 | 2018-07-26 | Jun Ji | Process for producing a knitted sweatband |
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