US3046186A - Cationic sizing emulsions and paper sized therewith - Google Patents
Cationic sizing emulsions and paper sized therewith Download PDFInfo
- Publication number
- US3046186A US3046186A US665124A US66512457A US3046186A US 3046186 A US3046186 A US 3046186A US 665124 A US665124 A US 665124A US 66512457 A US66512457 A US 66512457A US 3046186 A US3046186 A US 3046186A
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- United States
- Prior art keywords
- ketene dimer
- paper
- cationic
- fibers
- emulsion
- Prior art date
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- Expired - Lifetime
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- 239000000839 emulsion Substances 0.000 title claims description 34
- 125000002091 cationic group Chemical group 0.000 title description 31
- 238000004513 sizing Methods 0.000 title description 20
- WASQWSOJHCZDFK-UHFFFAOYSA-N diketene Chemical compound C=C1CC(=O)O1 WASQWSOJHCZDFK-UHFFFAOYSA-N 0.000 claims description 45
- 239000000835 fiber Substances 0.000 claims description 22
- 239000000725 suspension Substances 0.000 claims description 22
- 239000003795 chemical substances by application Substances 0.000 claims description 18
- 238000000034 method Methods 0.000 claims description 15
- 229920001187 thermosetting polymer Polymers 0.000 claims description 11
- 230000002209 hydrophobic effect Effects 0.000 claims description 10
- 238000005728 strengthening Methods 0.000 claims description 10
- 239000002253 acid Substances 0.000 claims description 8
- 229920002678 cellulose Polymers 0.000 claims description 7
- 239000001913 cellulose Substances 0.000 claims description 7
- 238000004519 manufacturing process Methods 0.000 claims description 7
- 239000007900 aqueous suspension Substances 0.000 claims description 6
- 238000010438 heat treatment Methods 0.000 claims description 5
- 239000012736 aqueous medium Substances 0.000 claims description 3
- 239000007859 condensation product Substances 0.000 claims description 3
- 239000000123 paper Substances 0.000 description 21
- 239000002270 dispersing agent Substances 0.000 description 14
- 239000000243 solution Substances 0.000 description 10
- WSFSSNUMVMOOMR-UHFFFAOYSA-N Formaldehyde Chemical compound O=C WSFSSNUMVMOOMR-UHFFFAOYSA-N 0.000 description 9
- 239000003995 emulsifying agent Substances 0.000 description 9
- 239000007787 solid Substances 0.000 description 8
- 229920005989 resin Polymers 0.000 description 7
- 239000011347 resin Substances 0.000 description 7
- 238000001179 sorption measurement Methods 0.000 description 7
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 description 7
- -1 aliphatic ammonium salts Chemical class 0.000 description 6
- 239000000539 dimer Substances 0.000 description 6
- 239000000463 material Substances 0.000 description 6
- 229920000642 polymer Polymers 0.000 description 6
- 125000003368 amide group Chemical group 0.000 description 5
- 125000001453 quaternary ammonium group Chemical group 0.000 description 5
- NLXLAEXVIDQMFP-UHFFFAOYSA-N Ammonium chloride Substances [NH4+].[Cl-] NLXLAEXVIDQMFP-UHFFFAOYSA-N 0.000 description 4
- IJGRMHOSHXDMSA-UHFFFAOYSA-N Atomic nitrogen Chemical compound N#N IJGRMHOSHXDMSA-UHFFFAOYSA-N 0.000 description 4
- OKTJSMMVPCPJKN-UHFFFAOYSA-N Carbon Chemical compound [C] OKTJSMMVPCPJKN-UHFFFAOYSA-N 0.000 description 4
- 229920003043 Cellulose fiber Polymers 0.000 description 4
- 238000006243 chemical reaction Methods 0.000 description 4
- 238000009833 condensation Methods 0.000 description 4
- 230000005494 condensation Effects 0.000 description 4
- 239000006185 dispersion Substances 0.000 description 4
- 150000002561 ketenes Chemical class 0.000 description 4
- JVTAAEKCZFNVCJ-UHFFFAOYSA-N lactic acid Chemical compound CC(O)C(O)=O JVTAAEKCZFNVCJ-UHFFFAOYSA-N 0.000 description 4
- 239000007788 liquid Substances 0.000 description 4
- 239000012071 phase Substances 0.000 description 4
- 238000002360 preparation method Methods 0.000 description 4
- 239000000047 product Substances 0.000 description 4
- UHOVQNZJYSORNB-UHFFFAOYSA-N Benzene Chemical compound C1=CC=CC=C1 UHOVQNZJYSORNB-UHFFFAOYSA-N 0.000 description 3
- 229920000877 Melamine resin Polymers 0.000 description 3
- 229920002873 Polyethylenimine Polymers 0.000 description 3
- 125000001931 aliphatic group Chemical group 0.000 description 3
- 150000001408 amides Chemical class 0.000 description 3
- 235000019270 ammonium chloride Nutrition 0.000 description 3
- 125000000129 anionic group Chemical group 0.000 description 3
- 239000002585 base Substances 0.000 description 3
- 239000000084 colloidal system Substances 0.000 description 3
- 230000003247 decreasing effect Effects 0.000 description 3
- 125000000118 dimethyl group Chemical group [H]C([H])([H])* 0.000 description 3
- QJGQUHMNIGDVPM-UHFFFAOYSA-N nitrogen group Chemical group [N] QJGQUHMNIGDVPM-UHFFFAOYSA-N 0.000 description 3
- 239000002245 particle Substances 0.000 description 3
- HRPVXLWXLXDGHG-UHFFFAOYSA-N Acrylamide Chemical compound NC(=O)C=C HRPVXLWXLXDGHG-UHFFFAOYSA-N 0.000 description 2
- QGZKDVFQNNGYKY-UHFFFAOYSA-N Ammonia Chemical compound N QGZKDVFQNNGYKY-UHFFFAOYSA-N 0.000 description 2
- VEXZGXHMUGYJMC-UHFFFAOYSA-N Hydrochloric acid Chemical compound Cl VEXZGXHMUGYJMC-UHFFFAOYSA-N 0.000 description 2
- KFZMGEQAYNKOFK-UHFFFAOYSA-N Isopropanol Chemical compound CC(C)O KFZMGEQAYNKOFK-UHFFFAOYSA-N 0.000 description 2
- 235000021355 Stearic acid Nutrition 0.000 description 2
- PPBRXRYQALVLMV-UHFFFAOYSA-N Styrene Chemical compound C=CC1=CC=CC=C1 PPBRXRYQALVLMV-UHFFFAOYSA-N 0.000 description 2
- XSQUKJJJFZCRTK-UHFFFAOYSA-N Urea Chemical compound NC(N)=O XSQUKJJJFZCRTK-UHFFFAOYSA-N 0.000 description 2
- 239000007864 aqueous solution Substances 0.000 description 2
- 239000004202 carbamide Substances 0.000 description 2
- 239000007795 chemical reaction product Substances 0.000 description 2
- CCGKOQOJPYTBIH-UHFFFAOYSA-N ethenone Chemical compound C=C=O CCGKOQOJPYTBIH-UHFFFAOYSA-N 0.000 description 2
- IVJISJACKSSFGE-UHFFFAOYSA-N formaldehyde;1,3,5-triazine-2,4,6-triamine Chemical compound O=C.NC1=NC(N)=NC(N)=N1 IVJISJACKSSFGE-UHFFFAOYSA-N 0.000 description 2
- 239000004310 lactic acid Substances 0.000 description 2
- 235000014655 lactic acid Nutrition 0.000 description 2
- 239000002609 medium Substances 0.000 description 2
- 239000000203 mixture Substances 0.000 description 2
- 229910052757 nitrogen Inorganic materials 0.000 description 2
- QIQXTHQIDYTFRH-UHFFFAOYSA-N octadecanoic acid Chemical compound CCCCCCCCCCCCCCCCCC(O)=O QIQXTHQIDYTFRH-UHFFFAOYSA-N 0.000 description 2
- OQCDKBAXFALNLD-UHFFFAOYSA-N octadecanoic acid Natural products CCCCCCCC(C)CCCCCCCCC(O)=O OQCDKBAXFALNLD-UHFFFAOYSA-N 0.000 description 2
- 239000000344 soap Substances 0.000 description 2
- 239000008117 stearic acid Substances 0.000 description 2
- 238000009827 uniform distribution Methods 0.000 description 2
- MLQBTMWHIOYKKC-KTKRTIGZSA-N (z)-octadec-9-enoyl chloride Chemical compound CCCCCCCC\C=C/CCCCCCCC(Cl)=O MLQBTMWHIOYKKC-KTKRTIGZSA-N 0.000 description 1
- ZRZHXNCATOYMJH-UHFFFAOYSA-N 1-(chloromethyl)-4-ethenylbenzene Chemical compound ClCC1=CC=C(C=C)C=C1 ZRZHXNCATOYMJH-UHFFFAOYSA-N 0.000 description 1
- UITVEGAFGYIBSV-UHFFFAOYSA-N 1-octadecylpiperazine Chemical compound CCCCCCCCCCCCCCCCCCN1CCNCC1 UITVEGAFGYIBSV-UHFFFAOYSA-N 0.000 description 1
- OIYRIYSVXPOOLN-UHFFFAOYSA-N 1-octadecylpiperidine Chemical compound CCCCCCCCCCCCCCCCCCN1CCCCC1 OIYRIYSVXPOOLN-UHFFFAOYSA-N 0.000 description 1
- VILCJCGEZXAXTO-UHFFFAOYSA-N 2,2,2-tetramine Chemical compound NCCNCCNCCN VILCJCGEZXAXTO-UHFFFAOYSA-N 0.000 description 1
- 125000003903 2-propenyl group Chemical group [H]C([*])([H])C([H])=C([H])[H] 0.000 description 1
- XOGJBKWFLRETGW-UHFFFAOYSA-N 5-aminotriazine-4-carbaldehyde Chemical compound NC1=CN=NN=C1C=O XOGJBKWFLRETGW-UHFFFAOYSA-N 0.000 description 1
- 102100038343 Ammonium transporter Rh type C Human genes 0.000 description 1
- KWIUHFFTVRNATP-UHFFFAOYSA-N Betaine Natural products C[N+](C)(C)CC([O-])=O KWIUHFFTVRNATP-UHFFFAOYSA-N 0.000 description 1
- 241000282994 Cervidae Species 0.000 description 1
- XZMCDFZZKTWFGF-UHFFFAOYSA-N Cyanamide Chemical compound NC#N XZMCDFZZKTWFGF-UHFFFAOYSA-N 0.000 description 1
- MHZGKXUYDGKKIU-UHFFFAOYSA-N Decylamine Chemical compound CCCCCCCCCCN MHZGKXUYDGKKIU-UHFFFAOYSA-N 0.000 description 1
- RPNUMPOLZDHAAY-UHFFFAOYSA-N Diethylenetriamine Chemical compound NCCNCCN RPNUMPOLZDHAAY-UHFFFAOYSA-N 0.000 description 1
- RWSOTUBLDIXVET-UHFFFAOYSA-N Dihydrogen sulfide Chemical class S RWSOTUBLDIXVET-UHFFFAOYSA-N 0.000 description 1
- BRLQWZUYTZBJKN-UHFFFAOYSA-N Epichlorohydrin Chemical compound ClCC1CO1 BRLQWZUYTZBJKN-UHFFFAOYSA-N 0.000 description 1
- IAYPIBMASNFSPL-UHFFFAOYSA-N Ethylene oxide Chemical compound C1CO1 IAYPIBMASNFSPL-UHFFFAOYSA-N 0.000 description 1
- PIICEJLVQHRZGT-UHFFFAOYSA-N Ethylenediamine Chemical compound NCCN PIICEJLVQHRZGT-UHFFFAOYSA-N 0.000 description 1
- 101000666627 Homo sapiens Ammonium transporter Rh type C Proteins 0.000 description 1
- 239000005956 Metaldehyde Substances 0.000 description 1
- KWIUHFFTVRNATP-UHFFFAOYSA-O N,N,N-trimethylglycinium Chemical compound C[N+](C)(C)CC(O)=O KWIUHFFTVRNATP-UHFFFAOYSA-O 0.000 description 1
- 239000004698 Polyethylene Substances 0.000 description 1
- VBIIFPGSPJYLRR-UHFFFAOYSA-M Stearyltrimethylammonium chloride Chemical compound [Cl-].CCCCCCCCCCCCCCCCCC[N+](C)(C)C VBIIFPGSPJYLRR-UHFFFAOYSA-M 0.000 description 1
- NJSSICCENMLTKO-HRCBOCMUSA-N [(1r,2s,4r,5r)-3-hydroxy-4-(4-methylphenyl)sulfonyloxy-6,8-dioxabicyclo[3.2.1]octan-2-yl] 4-methylbenzenesulfonate Chemical compound C1=CC(C)=CC=C1S(=O)(=O)O[C@H]1C(O)[C@@H](OS(=O)(=O)C=2C=CC(C)=CC=2)[C@@H]2OC[C@H]1O2 NJSSICCENMLTKO-HRCBOCMUSA-N 0.000 description 1
- GBZYLRAWNGCKOK-UHFFFAOYSA-M [Br-].C[S+](CCCCCCCCCCCCCCCC)C Chemical compound [Br-].C[S+](CCCCCCCCCCCCCCCC)C GBZYLRAWNGCKOK-UHFFFAOYSA-M 0.000 description 1
- USDJGQLNFPZEON-UHFFFAOYSA-N [[4,6-bis(hydroxymethylamino)-1,3,5-triazin-2-yl]amino]methanol Chemical compound OCNC1=NC(NCO)=NC(NCO)=N1 USDJGQLNFPZEON-UHFFFAOYSA-N 0.000 description 1
- 238000010521 absorption reaction Methods 0.000 description 1
- 238000004220 aggregation Methods 0.000 description 1
- 230000002776 aggregation Effects 0.000 description 1
- 238000013019 agitation Methods 0.000 description 1
- 150000008431 aliphatic amides Chemical class 0.000 description 1
- 239000003513 alkali Substances 0.000 description 1
- BHELZAPQIKSEDF-UHFFFAOYSA-N allyl bromide Chemical compound BrCC=C BHELZAPQIKSEDF-UHFFFAOYSA-N 0.000 description 1
- 230000009435 amidation Effects 0.000 description 1
- 238000007112 amidation reaction Methods 0.000 description 1
- 229910021529 ammonia Inorganic materials 0.000 description 1
- 229910000387 ammonium dihydrogen phosphate Inorganic materials 0.000 description 1
- 239000008346 aqueous phase Substances 0.000 description 1
- 125000003118 aryl group Chemical group 0.000 description 1
- 229960003237 betaine Drugs 0.000 description 1
- 230000015572 biosynthetic process Effects 0.000 description 1
- 229910052799 carbon Inorganic materials 0.000 description 1
- 125000004432 carbon atom Chemical group C* 0.000 description 1
- 229920006317 cationic polymer Polymers 0.000 description 1
- YMKDRGPMQRFJGP-UHFFFAOYSA-M cetylpyridinium chloride Chemical compound [Cl-].CCCCCCCCCCCCCCCC[N+]1=CC=CC=C1 YMKDRGPMQRFJGP-UHFFFAOYSA-M 0.000 description 1
- 230000001143 conditioned effect Effects 0.000 description 1
- 125000004122 cyclic group Chemical group 0.000 description 1
- 238000000354 decomposition reaction Methods 0.000 description 1
- 230000008021 deposition Effects 0.000 description 1
- 235000014113 dietary fatty acids Nutrition 0.000 description 1
- 230000000694 effects Effects 0.000 description 1
- 238000004945 emulsification Methods 0.000 description 1
- 239000000194 fatty acid Substances 0.000 description 1
- 229930195729 fatty acid Natural products 0.000 description 1
- 150000004665 fatty acids Chemical class 0.000 description 1
- 238000007429 general method Methods 0.000 description 1
- 235000021384 green leafy vegetables Nutrition 0.000 description 1
- 125000005842 heteroatom Chemical group 0.000 description 1
- CVVIJWRCGSYCMB-UHFFFAOYSA-N hydron;piperazine;dichloride Chemical compound Cl.Cl.C1CNCCN1 CVVIJWRCGSYCMB-UHFFFAOYSA-N 0.000 description 1
- 230000002427 irreversible effect Effects 0.000 description 1
- 239000002655 kraft paper Substances 0.000 description 1
- 235000020778 linoleic acid Nutrition 0.000 description 1
- OYHQOLUKZRVURQ-HZJYTTRNSA-N linoleic acid group Chemical group C(CCCCCCC\C=C/C\C=C/CCCCC)(=O)O OYHQOLUKZRVURQ-HZJYTTRNSA-N 0.000 description 1
- JDSHMPZPIAZGSV-UHFFFAOYSA-N melamine Chemical compound NC1=NC(N)=NC(N)=N1 JDSHMPZPIAZGSV-UHFFFAOYSA-N 0.000 description 1
- 230000008018 melting Effects 0.000 description 1
- 238000002844 melting Methods 0.000 description 1
- GKKDCARASOJPNG-UHFFFAOYSA-N metaldehyde Chemical compound CC1OC(C)OC(C)OC(C)O1 GKKDCARASOJPNG-UHFFFAOYSA-N 0.000 description 1
- 235000019837 monoammonium phosphate Nutrition 0.000 description 1
- SZPHJWIVTRIHBG-UHFFFAOYSA-N octadec-1-en-1-one Chemical class CCCCCCCCCCCCCCCCC=C=O SZPHJWIVTRIHBG-UHFFFAOYSA-N 0.000 description 1
- WTBAHSZERDXKKZ-UHFFFAOYSA-N octadecanoyl chloride Chemical compound CCCCCCCCCCCCCCCCCC(Cl)=O WTBAHSZERDXKKZ-UHFFFAOYSA-N 0.000 description 1
- 235000021313 oleic acid Nutrition 0.000 description 1
- 150000002889 oleic acids Chemical class 0.000 description 1
- 238000010979 pH adjustment Methods 0.000 description 1
- 125000001997 phenyl group Chemical group [H]C1=C([H])C([H])=C(*)C([H])=C1[H] 0.000 description 1
- 229920000768 polyamine Polymers 0.000 description 1
- 229920000573 polyethylene Polymers 0.000 description 1
- 238000006116 polymerization reaction Methods 0.000 description 1
- 150000003254 radicals Chemical class 0.000 description 1
- 238000001228 spectrum Methods 0.000 description 1
- 230000006641 stabilisation Effects 0.000 description 1
- 238000011105 stabilization Methods 0.000 description 1
- 239000004094 surface-active agent Substances 0.000 description 1
- 239000003784 tall oil Substances 0.000 description 1
- 239000004634 thermosetting polymer Substances 0.000 description 1
- 238000009736 wetting Methods 0.000 description 1
- 239000000080 wetting agent Substances 0.000 description 1
Classifications
-
- D—TEXTILES; PAPER
- D21—PAPER-MAKING; PRODUCTION OF CELLULOSE
- D21H—PULP COMPOSITIONS; PREPARATION THEREOF NOT COVERED BY SUBCLASSES D21C OR D21D; IMPREGNATING OR COATING OF PAPER; TREATMENT OF FINISHED PAPER NOT COVERED BY CLASS B31 OR SUBCLASS D21G; PAPER NOT OTHERWISE PROVIDED FOR
- D21H17/00—Non-fibrous material added to the pulp, characterised by its constitution; Paper-impregnating material characterised by its constitution
- D21H17/03—Non-macromolecular organic compounds
- D21H17/05—Non-macromolecular organic compounds containing elements other than carbon and hydrogen only
- D21H17/17—Ketenes, e.g. ketene dimers
Definitions
- sized paper can be made by forming an aqueous non-ionic or anionic suspension of cellulose papermaking fibers, adjusting the pH of the suspension to within the range of 5 to 9, adding thereto a non-ionic or anionic emulsion of a hydrophobic ketene dimer, sheeting the suspension, and curing the sheets at an elevated temperature.
- deposition of ketene dimer from emulsion form uponthe fibers results from the pH adjustment described.
- paper of substantially and often phenomenally improved sizing can be produced by replacing the non-ionic or anionic ketene dimer emulsion in the above process with a cationic emulsion.
- paper possessing outstanding sizing can be made by forming an aqueous suspension of papermaking fibers, adding thereto a small but effective amount as sizing agent of a cationic emulsion of a hydrophobic ketene dimer, sheeting the suspension, and developing the sizing properties of the dimer by curing the sheets at an elevated temperature.
- the ketene dimer in the emulsion is self-substantive and is rapidly adsorbed by the fibers, an effective amount usually being adsorbed while the emulsion is being distributed therethrough.
- the process of the present invention does not depend upon the pre-adjustment of the pH of the pulp to any particular value. Better results, however, are generally obtained when the pH of the suspension is maintained at a value less than 5 or in excess of 9, depending upon the adsorption characteristics of the particular agent added.
- the present invention does not primarily depend upon the particular amount of cationic ketene dimer added.
- the scope of the invention includes the addition of emulsified ketene dimer in effective amount between 0.1% and 3% of the dry weight of the fibers.
- Best sizing per increment of ketene dimer added occurs in the range of A1%%% (ketene dimer on the dry weight of the fibers). This is an unusually low preferred range and evidently results from two factors associated with the cationic nature or" the emulsion. The first is that the adsorption of the ketene dimer is apparently substantially more uniform with decreased aggregation of the emulsion particles so that a larger fiber area is initially protected. The second is that adsorption is more com plete. The evidence is that at least 50% of the ketene dimer in preferred emulsions is deposited on the fibers.
- the cationic dispersing agents referred to may be monomeric or high molecular weight hydrophilic or watersoluble basic nitrogenous surface-active agents.
- the dispersing agent in the final cured sheet has a high molecular weight, in excess of 2,000.
- the low molecular Weight agents are not irreversibly adsorbed by the fibers and thus act to some extent as re-Wetting agents, whereas the high molecular weight agents and the agents which are converted t high molecular form on the fibers are irreversibly adsorbed so that their re-Wetting prop erties are suppressed.
- the papermaking process of the present invention is applicable to any type of hydrated cellulose fiber at any convenient consistency of the fibrous suspension.
- the preferred consistency is that at which permits rapid and uniform distribution of the sizing emulsion to take place and is usually 0.5%6%, based on the dry weight of the fibers.
- the pH of the suspension need not be pre-adjusted.
- the emulsion is added at any convenient point in the papermaking system ahead of the wire, and if desired, the pH may be adjusted to any predetermined optimum value, the thermosetting amino-triazineformaldehyde acid colloids for example being generally best adsorbed at pH 4.5 and the macropolyalkylenepolyamines being best adsorbed at about pH 10.
- the fibrous suspension should be gently stirred for a few moments to distribute the emulsion uniformly through the suspension and allow adsorption to go to substantial equilibrium. In preferred instances, as much as of the dimer is adsorbed by the fibers.
- the suspension is then sheeted and the resulting web is dried according to normal practice. Adsorption of the ketene dimer is substantially irreversible, so that the pH of the Web during formation can be adjusted to any desired value.
- reaction of the ketene dimer with cellulose is favored by acid and alkali, so that we prefer to sheet the suspension at a pH in the range of 5-6 or 8-9.
- the Web is dried at normal temperatures which are generally sufficient to develop a substantial part of the sizing properties of the ketene dimer. It is preferred to complete the reaction of the ketene dimer with the cellulose by forming the paper into rolls having a temperature in the range of 250 C. or thereabouts so as to prolong curing conditions until reaction of the ketene dimer with the cellulose fiber has gone to substantial completion.
- the emulsions of the present invention essentially consist of a cationic emulsion of a hydrophobic organic ketene dimer in aqueous medium, the ketene dimer thus being the dispersed phase and the aqueous medium being the continuous phase.
- the emulsions may be prepared in any convenient way and the invention does not depend upon the particular method selected.
- the ketene dimer may be directly emulsified in water containing a water-soluble cationic organic dispersing agent. If desired, the ketene dimer may be emulsified first in'water and the dispersing agent added separately during the operation, and in certain instances the emulsifying agent may be pre-dispersed in the ketene dimer.
- the ketene dimers are generally solids melting below 100 C. and may be liquids as in the case of the ketene dimers prepared from tall oil fatty acids (chiefly a mixture of linoleic and oleic acids).
- the liquid ketene dimers may be emulsified directly with water containing the emulsifying agent and the normally solid dimers are generally best emulsified in molten form or in benzene, etc. solution. Unnecessary heating should be avoided to minimize decomposition.
- the emulsions are advantage ously homogenized hot to decrease particle size and improve stability and then cooled so as to form a soiidin'- liquid dispersion.
- the emulsions may be prepared at any convenient solids content. Before use they are advantageously diluted to 1%-5% solids by weight so as to favor rapid and uniform distribution throughout the fibrous suspension.
- hydrophilic organic cationic dispersing agent renders at least part of the emulsified ketene dimer autosubstantive when added to an aqueous suspension of papermaking cellulose fibers. In practice somewhat more is added. The precise amount of dispersing agent needed varies from instance to instance depending chiefly on the surface characteristics of the kete'ne dimer and the dispersing agent and the optimum amount is hence most easily determined by laboratory trial.
- the dispersing'agent may be any surface-active hydrophilic cationic nitrogen base material, and may be mono meric or polymeric.
- monomeric nitrogen bases containing at least one hydrophobic organic aliphatic group.
- bases include the aliphatic ammonium salts, e.g., octadecyl trimethyl ammonium chloride and 9,10-octadecenyl dimethyl-Z-hydroxyethyl ammonium chloride; the higher aliphatic amide quaternaries, e.g., ootadecanamidopropyl dimethyl 2-l1ydroxyethyl ammonium chloride; aliphatic amines, e.g., the reaction product of one mol of octa'decylamine' with 2 mols of ethylene oxide; the higher aliphatic amido amines suchas the reaction product of 2.5 mols of octadecanoyl chloride or oleoyl chloride with one mol of triethylenetetramine; higher amide-amine soaps, e
- hydrophilic cationic organic basic nitrogenous compounds having molecular weights in excess of 2,000 and more particularly in excess-of' 10,000. I have found-three types of these higher molecular weight materials'to be'particularly useful.
- the first type embraces the high molecular weight Water-soluble cationic non-thermosetting polyalkylenepolyamines of which polyethylenimine is typical. Such polyethylenimines are well adsorbed at alkaline pH values andtliuspermit the manufacture of well-sized paper having n'o metal or formaldehyde content. Similar materials may be made by condensation of lower polyethylene polyamines with 1,3-dichlo1opropane, by condensation of ammonia or lower polyalkylenepolyamines with epi chlorohydrin', or by condensation of methylenebisaerylamide with ethylenediamine.
- the second type embraces the water-soluble non-thermoset'ting high molecular Weight linear carbon polymer carrying suflicient cationic groups to render the" moiecule as a whole" cationic.
- suchpolymer may carry a suificient number of amide groups as are customary for the production of pa'pe'r'of improved dry strength.
- the ratio of quaternary groups to amide groups is between about 20:80 and 5:95 and the ratio of the total number of quaternary groups and amide groups to the carbon atoms of the chain is between about A; :1 and /s:1.
- Linear resins of this type have the advantage of usefulness over a broad pH spectrum and have the property of producing paper of substantial dry strength without concomitant wet strength.
- Particularly eifective resins maybe formed by cop'oly merizing 1 mol of p-(chloromethyl) styrene with 9 mols of acrylamide and reacting the product with trimeth'ylamine to convert the chlororr'iethyl groups to quaternary ammonium groups.
- the third type are amide-aldehyde condensates in partially polymerized hydrophili'c cationic form.
- Such materials may be prepared by reacting an amido corriipoiind, for example melamine, guana'r'nine, urea, anthems, for'r'noguanamine or acetoguanar'r'iine with formaldehyde (preferably in the presence of a small amount of a wat'ersoluble polyalkylene-polyanline) first under alkaline conditions and then under acid conditions until a substantial viscosity has been achieved, after which the, solution may be neutralized for stabilization purposes.
- formaldehyde preferably in the presence of a small amount of a wat'ersoluble polyalkylene-polyanline
- Resins of, these types are cellulose substantive anda niiinber are widely'used the manufacture of wet-strength paper. As prepared; they; typically have molecular weights in the range 500 1 500 but grow to a molecular weight far in eiic'es s" of 10,000 on curing.
- ком ⁇ онент - gardless of molecular weight should be at least siifiieint to render the emulsified ketene dimer substantive to cellulose fibers in aqueous suspension.
- the amount of cationic agent being roughly 5%20% of the weight of the ketene dimer; It is a feature of the invention that very much more of the cationic dispersing agent may be present and, if desired,- the amount may be increased so that the wet or dry strength'of the paper is significantly improved.
- the amount of cationic agent maybe in creased so that it is between and 1 ,00O% the weight of the ketene dimer or more.
- Suchresins when of the curing type, develop their strengthening properties ahead of the time needed to develop the sizing properties of the'ketehe dimer. I
- Example 1 The following illustrates the preparation of a stable cationic emulsion of a ketene' dimersi'ze'ns'ing a typical monomeric cationic dispersing agent'as emulsifier;
- An emulsification' medium was prepared by adding7.2 cc. of a 35% by weight solution of octa'clecanamidopropyl dimethyl Z-hydroxyethyl ammonium dihydrogen phosphate in aqueous isopropanol to 250 cc. of water at 65 C. (equivalent to 10% of dispersing agent bas'edonthe weight of ketene dimer).
- the resulting emulsion was homogenized hot and a nearly White emulsion was obtained.
- the emulsion was rapidly cooled to room temperature to'preserve particle size, and'a creamysuspension was obtained.
- the suspension separated slightlyafter 24 hours, but became uniform with slight agitation.
- Example 2 The procedure of Example 1 was repeated except that 3.6 ml. of a 35% aqueous N-octadecylpyn'diniumchloride solution was used as the dispersing agent (equivalent to based on the dry weight of the ketene dimer). A similar emulsion was obtained.
- Example 3 The procedure of Example 1 was repeated except that 2.5 gm. of the zwitterion form of powdered octadecanamidopropyl dimethyl Z-carboxymethyl ammonium chloride (a betaine) in place of the emulsifying agent therein used. A similar suspension was obtained.
- a betaine powdered octadecanamidopropyl dimethyl Z-carboxymethyl ammonium chloride
- Example 4 The following illustrates the preparation of a ketene dimer sizing dispersion of a cationic thermosetting paper wet strength resin as dispersing agent. A large excess of the resin is used so that the emulsion is useful for the production of well-sized paper of good wet strength.
- Example 1 The procedure of Example 1 was repeated except that the amount of ketene dimer was decreased to 5 gm., the amount of water was decreased by 100 gm., and the quaternary ammonium solution was replaced by 100 gm. of a 12% by volume aqueous solution of a melamineformaldehyde acid colloid prepared by acidifying trimethylolmelamine solution according to US. Patent No. 2,345,543 using hydrochloric acid as the acid.
- Example 5 A ketene dimer sizing dispersion was prepared by the method of Example 1 replacing the emulsifying agent solution used therein with an equal amount of a 35% by weight solution of the non-colloidal water-soluble cationis wet-strength melamine-formaldehyde-iminobispropylamine-glycol resin prepared according to the general method of copending Wooding et a1.
- Example 6 The following illustrates the preparation of a ketene dimer sizing dispersion by use of a small amount of a cationic linear carbon chain polymer carrying amide and quaternary ammonium groups.
- Example 1 The procedure of Example 1 was repeated except that the solution of quaternary ammonium dispersing agent was replaced by 7.2 gm. of a 35% (solids basis) solution of the cationic polymer formed by copolymerizing 95 mols of acrylamide with 5 mols of diallyl dimethyl ammonium chloride. During polymerization only one of the allyl groups reacted, so that the product was essentially a linear carbon chain polymer carrying amide ar quaternary ammonium groups.
- the polymer was a material known to act as a dr: strength agent for paper. If desired, the amount of pol mer may be greatly increased so as to form an emulsio effective in producing paper of improved dry strength 2 well as sizing.
- Example 7 The following illustrates the preparation of a size b the method of Example 6 wherein the amide groups ar replaced by phenyl groups.
- Example 6 The procedure of Example 6 was repeated except the the polymer was prepared by copolymerizing 1 mol of 2 methyl-S-vinyl-pyridine with 5 mols of styrene and quz ternizing the product with 1 mol of allyl bromide.
- Example 8 The procedure of Example 1 was repeated except tha a 33% solids aqueous solution of high molecular weigh polyethylenimine (Gardner-Holdt viscosity of K at 25 C.) was used as sole emulsifying agent. A very goot alkaline emulsion was obtained.
- Example 9 The following illustrates the manufacture of sized paper using typical cationic ketene dimer sizes according to tht present invention.
- the pulp was a bleached sulfite-bleached hardwooc kraft (/50 ratio) pulp (selected because of its difiicult; to size).
- the pulp has been beaten to a Green freeness o: 440 ml. and was used at a consistency of 0.6% based or the dry weight of the fibers.
- the sizing emulsions were diluted tr 1% solids with water before use to facilitate distributior through the fiber suspension.
- the pH of the pulp suspension was adjusted to the values shown in the table below.
- the sizing emulsions were used at the pH at which they were prepared, and were added to the fibrous suspensions in amounts as shown in the table below.
- the suspensions were gently stirred for three minutes to allow adsorption of the ketene dimer solids to go to completion, the pH of the suspensions adjusted to the values shown in the table, and handsheets made and tested according to standard laboratory practice.
- the sheets were formed in each instance at basis weights oi 200 lb.
- a process for the manufacture of sized paper of imvroved tensile strength which comprises forming an aqueus suspension of cellulose papermaking fibers, adding hereto an emulsion of a hydrophobic ketene dimer in an ⁇ queous medium containing a thermosetting cationic tmido-aldehyde condensation product in acid condensed et hydrophilic stage as paper-strengthening agent, the veight of said ketene dimer being between and 3% )f the dry weight of the fibers and the weight of said :ationic nitrogenous paper-strengthening agent being be- ;ween about A and 3% of the dry weight of the fibers, miformly distributing said added emulsion through said aqueous suspension whereby a substantial proportion of ;aid added ketene dimer and paper-strengthening agent are uniformly adsorbed on the surface of said fibers, sheeting said suspension to form a water-laid web at about pH 4.5,
- a cationic emulsion of a hydrophobic organic ketene dimer wherein the ketene dimer is the dispersed phase in a continuous phase and the aqueous phase contains a thermosetting hydrophilic cationic melamine-formaldehyde wet-strength acid colloid as principal emulsifying agent.
Description
United States Patent 3,046,186 CATIONHZ' SIZING EMULSIGNS AND PAPER SIZED TIEREWITH Herbert G. Arlt, In, Glenbrook, Conn, assignor to American Cyanamid Company, New York, N.Y., a corporation of Maine N0 Drawing. Filed June 12, 1957, Ser. No. 665,124 3 Claims. (Cl. 162-'-167) and liquid-in-liquid types.
Osberg US. Patent No. 2,785,067 discloses that sized paper can be made by forming an aqueous non-ionic or anionic suspension of cellulose papermaking fibers, adjusting the pH of the suspension to within the range of 5 to 9, adding thereto a non-ionic or anionic emulsion of a hydrophobic ketene dimer, sheeting the suspension, and curing the sheets at an elevated temperature. According to the patent, deposition of ketene dimer from emulsion form uponthe fibers results from the pH adjustment described. I
The hydrophobic ketene dimers have the theoretical formula RCH=CO RHCG=O wherein the Rs represent the same or different hydrophobic radicals, and cure by reaction with the cellulose; cf. Technical Association of the Pulp and Paper Industry (TAPPI) 39, 21-23 (1956).
The discovery has now been made that paper of substantially and often phenomenally improved sizing can be produced by replacing the non-ionic or anionic ketene dimer emulsion in the above process with a cationic emulsion. In other words, I have found that paper possessing outstanding sizing can be made by forming an aqueous suspension of papermaking fibers, adding thereto a small but effective amount as sizing agent of a cationic emulsion of a hydrophobic ketene dimer, sheeting the suspension, and developing the sizing properties of the dimer by curing the sheets at an elevated temperature.
The ketene dimer in the emulsion is self-substantive and is rapidly adsorbed by the fibers, an effective amount usually being adsorbed while the emulsion is being distributed therethrough. I have regularly found it possible by use of cationic emulsions on the one hand to make a substantial decrease in the amount of ketene dimer needed to produce a given level of sizing, and on the other hand, to produce a paper having a water-repellence which has rarely, if ever, been exceeded by paper made according to the beater-addition process.
The process of the present invention does not depend upon the pre-adjustment of the pH of the pulp to any particular value. Better results, however, are generally obtained when the pH of the suspension is maintained at a value less than 5 or in excess of 9, depending upon the adsorption characteristics of the particular agent added.
The present invention does not primarily depend upon the particular amount of cationic ketene dimer added. The scope of the invention includes the addition of emulsified ketene dimer in effective amount between 0.1% and 3% of the dry weight of the fibers.
Best sizing per increment of ketene dimer added occurs in the range of A1%%% (ketene dimer on the dry weight of the fibers). This is an unusually low preferred range and evidently results from two factors associated with the cationic nature or" the emulsion. The first is that the adsorption of the ketene dimer is apparently substantially more uniform with decreased aggregation of the emulsion particles so that a larger fiber area is initially protected. The second is that adsorption is more com plete. The evidence is that at least 50% of the ketene dimer in preferred emulsions is deposited on the fibers.
The cationic dispersing agents referred to may be monomeric or high molecular weight hydrophilic or watersoluble basic nitrogenous surface-active agents. In general, I have found that better sizing is obtained where the dispersing agent in the final cured sheet has a high molecular weight, in excess of 2,000. Evidently the low molecular Weight agents are not irreversibly adsorbed by the fibers and thus act to some extent as re-Wetting agents, whereas the high molecular weight agents and the agents which are converted t high molecular form on the fibers are irreversibly adsorbed so that their re-Wetting prop erties are suppressed.
More in detail, the papermaking process of the present invention is applicable to any type of hydrated cellulose fiber at any convenient consistency of the fibrous suspension. The preferred consistency is that at which permits rapid and uniform distribution of the sizing emulsion to take place and is usually 0.5%6%, based on the dry weight of the fibers. The pH of the suspension need not be pre-adjusted. The emulsion is added at any convenient point in the papermaking system ahead of the wire, and if desired, the pH may be adjusted to any predetermined optimum value, the thermosetting amino-triazineformaldehyde acid colloids for example being generally best adsorbed at pH 4.5 and the macropolyalkylenepolyamines being best adsorbed at about pH 10. Preferably, the fibrous suspension should be gently stirred for a few moments to distribute the emulsion uniformly through the suspension and allow adsorption to go to substantial equilibrium. In preferred instances, as much as of the dimer is adsorbed by the fibers. The suspension is then sheeted and the resulting web is dried according to normal practice. Adsorption of the ketene dimer is substantially irreversible, so that the pH of the Web during formation can be adjusted to any desired value. However, reaction of the ketene dimer with cellulose is favored by acid and alkali, so that we prefer to sheet the suspension at a pH in the range of 5-6 or 8-9.
The Web is dried at normal temperatures which are generally sufficient to develop a substantial part of the sizing properties of the ketene dimer. It is preferred to complete the reaction of the ketene dimer with the cellulose by forming the paper into rolls having a temperature in the range of 250 C. or thereabouts so as to prolong curing conditions until reaction of the ketene dimer with the cellulose fiber has gone to substantial completion.
The emulsions of the present invention essentially consist of a cationic emulsion of a hydrophobic organic ketene dimer in aqueous medium, the ketene dimer thus being the dispersed phase and the aqueous medium being the continuous phase.
The emulsions may be prepared in any convenient way and the invention does not depend upon the particular method selected. The ketene dimer may be directly emulsified in water containing a water-soluble cationic organic dispersing agent. If desired, the ketene dimer may be emulsified first in'water and the dispersing agent added separately during the operation, and in certain instances the emulsifying agent may be pre-dispersed in the ketene dimer.
The ketene dimers are generally solids melting below 100 C. and may be liquids as in the case of the ketene dimers prepared from tall oil fatty acids (chiefly a mixture of linoleic and oleic acids). The liquid ketene dimers may be emulsified directly with water containing the emulsifying agent and the normally solid dimers are generally best emulsified in molten form or in benzene, etc. solution. Unnecessary heating should be avoided to minimize decomposition. The emulsions are advantage ously homogenized hot to decrease particle size and improve stability and then cooled so as to form a soiidin'- liquid dispersion. The emulsions may be prepared at any convenient solids content. Before use they are advantageously diluted to 1%-5% solids by weight so as to favor rapid and uniform distribution throughout the fibrous suspension.
Use of the hydrophilic organic cationic dispersing agent renders at least part of the emulsified ketene dimer autosubstantive when added to an aqueous suspension of papermaking cellulose fibers. In practice somewhat more is added. The precise amount of dispersing agent needed varies from instance to instance depending chiefly on the surface characteristics of the kete'ne dimer and the dispersing agent and the optimum amount is hence most easily determined by laboratory trial.
The dispersing'agent may be any surface-active hydrophilic cationic nitrogen base material, and may be mono meric or polymeric.
As monomeric agents there may be used monomeric nitrogen bases containing at least one hydrophobic organic aliphatic group. Among such bases are the aliphatic ammonium salts, e.g., octadecyl trimethyl ammonium chloride and 9,10-octadecenyl dimethyl-Z-hydroxyethyl ammonium chloride; the higher aliphatic amide quaternaries, e.g., ootadecanamidopropyl dimethyl 2-l1ydroxyethyl ammonium chloride; aliphatic amines, e.g., the reaction product of one mol of octa'decylamine' with 2 mols of ethylene oxide; the higher aliphatic amido amines suchas the reaction product of 2.5 mols of octadecanoyl chloride or oleoyl chloride with one mol of triethylenetetramine; higher amide-amine soaps, e.g., the product obtained by heating mols of stearic acid with diethylenetriamine at 200 C. until 1.5 mols has reacted by way of amidation (leaving 03 mol of stearic acid in soap'form); the higher aliphatic substituted hetero'cyclic amines such as N-octadecyl piperazine and N-octadecyl piperidine; the higher aliphatic substituted cyclic quaternaries including 1-cyclohexyl-1,4,4-trimethyl piperazinium dichloride; aryl quaternaries, e.g., N-hexadecyl pyridinium chloride; and sulfonium compounds such as hexadecyl dimethyl sulfonium bromide.
For reasons already stated, I have discovered it ad antageous touse as emulsifying agents hydrophilic cationic organic basic nitrogenous compounds having molecular weights in excess of 2,000 and more particularly in excess-of' 10,000. I have found-three types of these higher molecular weight materials'to be'particularly useful.
The first type embraces the high molecular weight Water-soluble cationic non-thermosetting polyalkylenepolyamines of which polyethylenimine is typical. Such polyethylenimines are well adsorbed at alkaline pH values andtliuspermit the manufacture of well-sized paper having n'o metal or formaldehyde content. Similar materials may be made by condensation of lower polyethylene polyamines with 1,3-dichlo1opropane, by condensation of ammonia or lower polyalkylenepolyamines with epi chlorohydrin', or by condensation of methylenebisaerylamide with ethylenediamine.
The second type embraces the water-soluble non-thermoset'ting high molecular Weight linear carbon polymer carrying suflicient cationic groups to render the" moiecule as a whole" cationic. Advantageously, suchpolymer may carry a suificient number of amide groups as are customary for the production of pa'pe'r'of improved dry strength. Preferably the ratio of quaternary groups to amide groups is between about 20:80 and 5:95 and the ratio of the total number of quaternary groups and amide groups to the carbon atoms of the chain is between about A; :1 and /s:1. Linear resins of this type have the advantage of usefulness over a broad pH spectrum and have the property of producing paper of substantial dry strength without concomitant wet strength.
Particularly eifective resins maybe formed by cop'oly merizing 1 mol of p-(chloromethyl) styrene with 9 mols of acrylamide and reacting the product with trimeth'ylamine to convert the chlororr'iethyl groups to quaternary ammonium groups.
The third type are amide-aldehyde condensates in partially polymerized hydrophili'c cationic form. Such materials may be prepared by reacting an amido corriipoiind, for example melamine, guana'r'nine, urea, anthems, for'r'noguanamine or acetoguanar'r'iine with formaldehyde (preferably in the presence of a small amount of a wat'ersoluble polyalkylene-polyanline) first under alkaline conditions and then under acid conditions until a substantial viscosity has been achieved, after which the, solution may be neutralized for stabilization purposes. There may also be used the water-soluble" resins formed by reacting urea and formaldehyde in the presence-or a miner amount of glycidyl dimethyl 3-ureidopropyl ammonium chloride; or the watch-soluble thermosetting condensation pfodticts of a noniohic of cationic linear non thermosetting carbon chain polymer carrying" unsubstituted amide greens with an equal weight of ohe or more of the foregoing cationic thermosetting polymers. Resins of, these types are cellulose substantive anda niiinber are widely'used the manufacture of wet-strength paper. As prepared; they; typically have molecular weights in the range 500 1 500 but grow to a molecular weight far in eiic'es s" of 10,000 on curing.
As stated, he amount of cationic dispersing agent, re-
- gardless of molecular weight, should be at least siifiieint to render the emulsified ketene dimer substantive to cellulose fibers in aqueous suspension. In such minimal amount the material has no significant effect upon the properties of the paper the amount of cationic agent being roughly 5%20% of the weight of the ketene dimer; It is a feature of the invention that very much more of the cationic dispersing agent may be present and, if desired,- the amount may be increased so that the wet or dry strength'of the paper is significantly improved. For this purpose the amount of cationic agent maybe in creased so that it is between and 1 ,00O% the weight of the ketene dimer or more. Suchresins, when of the curing type, develop their strengthening properties ahead of the time needed to develop the sizing properties of the'ketehe dimer. I
The invention will'be more particularly described with reference to the examples. The examples-constitute em= bodiments of the invention and are not to be construed as limitations thereon.
Example 1 The following illustrates the preparation of a stable cationic emulsion of a ketene' dimersi'ze'ns'ing a typical monomeric cationic dispersing agent'as emulsifier;
An emulsification' medium was prepared by adding7.2 cc. of a 35% by weight solution of octa'clecanamidopropyl dimethyl Z-hydroxyethyl ammonium dihydrogen phosphate in aqueous isopropanol to 250 cc. of water at 65 C. (equivalent to 10% of dispersing agent bas'edonthe weight of ketene dimer). Into this with rapidag'itation was slowly' poured 25 gm. of molten hexadecyl ketene dimer at 60. The resulting emulsion was homogenized hot and a nearly White emulsion was obtained. The emulsion was rapidly cooled to room temperature to'preserve particle size, and'a creamysuspension was obtained. The suspension separated slightlyafter 24 hours, but became uniform with slight agitation.
Example 2 The procedure of Example 1 was repeated except that 3.6 ml. of a 35% aqueous N-octadecylpyn'diniumchloride solution was used as the dispersing agent (equivalent to based on the dry weight of the ketene dimer). A similar emulsion was obtained.
Example 3 The procedure of Example 1 was repeated except that 2.5 gm. of the zwitterion form of powdered octadecanamidopropyl dimethyl Z-carboxymethyl ammonium chloride (a betaine) in place of the emulsifying agent therein used. A similar suspension was obtained.
Example 4 The following illustrates the preparation of a ketene dimer sizing dispersion of a cationic thermosetting paper wet strength resin as dispersing agent. A large excess of the resin is used so that the emulsion is useful for the production of well-sized paper of good wet strength.
The procedure of Example 1 was repeated except that the amount of ketene dimer was decreased to 5 gm., the amount of water was decreased by 100 gm., and the quaternary ammonium solution was replaced by 100 gm. of a 12% by volume aqueous solution of a melamineformaldehyde acid colloid prepared by acidifying trimethylolmelamine solution according to US. Patent No. 2,345,543 using hydrochloric acid as the acid.
Example 5 A ketene dimer sizing dispersion was prepared by the method of Example 1 replacing the emulsifying agent solution used therein with an equal amount of a 35% by weight solution of the non-colloidal water-soluble cationis wet-strength melamine-formaldehyde-iminobispropylamine-glycol resin prepared according to the general method of copending Wooding et a1. U.S. application Serial No. 629,774, filed on December 21, 1956, now U.S. Patent No. 2,856,314.
Example 6 The following illustrates the preparation of a ketene dimer sizing dispersion by use of a small amount of a cationic linear carbon chain polymer carrying amide and quaternary ammonium groups.
The procedure of Example 1 was repeated except that the solution of quaternary ammonium dispersing agent was replaced by 7.2 gm. of a 35% (solids basis) solution of the cationic polymer formed by copolymerizing 95 mols of acrylamide with 5 mols of diallyl dimethyl ammonium chloride. During polymerization only one of the allyl groups reacted, so that the product was essentially a linear carbon chain polymer carrying amide ar quaternary ammonium groups.
The polymer was a material known to act as a dr: strength agent for paper. If desired, the amount of pol mer may be greatly increased so as to form an emulsio effective in producing paper of improved dry strength 2 well as sizing.
Example 7 The following illustrates the preparation of a size b the method of Example 6 wherein the amide groups ar replaced by phenyl groups.
The procedure of Example 6 was repeated except the the polymer was prepared by copolymerizing 1 mol of 2 methyl-S-vinyl-pyridine with 5 mols of styrene and quz ternizing the product with 1 mol of allyl bromide.
Example 8 The procedure of Example 1 was repeated except tha a 33% solids aqueous solution of high molecular weigh polyethylenimine (Gardner-Holdt viscosity of K at 25 C.) was used as sole emulsifying agent. A very goot alkaline emulsion was obtained.
Example 9 The following illustrates the manufacture of sized paper using typical cationic ketene dimer sizes according to tht present invention.
The pulp was a bleached sulfite-bleached hardwooc kraft (/50 ratio) pulp (selected because of its difiicult; to size). The pulp has been beaten to a Green freeness o: 440 ml. and was used at a consistency of 0.6% based or the dry weight of the fibers.
In each instance, the sizing emulsions were diluted tr 1% solids with water before use to facilitate distributior through the fiber suspension. The pH of the pulp suspension was adjusted to the values shown in the table below. The sizing emulsions were used at the pH at which they were prepared, and were added to the fibrous suspensions in amounts as shown in the table below. After addition, the suspensions were gently stirred for three minutes to allow adsorption of the ketene dimer solids to go to completion, the pH of the suspensions adjusted to the values shown in the table, and handsheets made and tested according to standard laboratory practice. The sheets were formed in each instance at basis weights oi 200 lb. (25" x 40"/500 ream) for the water adsorption and lactic acid tests and at 50 lb. for the remaining tests. The sheets were pressed between blotters and oven-cured for 12 hours at 100 C. The sheets were then conditioned for 24 hours at 50% relative humidity and 73 F. and tested as shown in the table.
Results are as follows:
Sizing Tests Emulsifier pH Run No. H2O Absorption 4 Lactic Acid Ink Tensile Strength Ketene Penetra- Bky Dimer, Ex. Percent 7 Size Pulp 8 Sheet Percent Percent tion Sec. percent 1 No. Deer. Sec. Dry Wet 6 Lb. per inch, adjusted to 50 1b. basis weight (25" x 40"/5001b. ream).
I claim:
1. A process for the manufacture of sized paper of imvroved tensile strength which comprises forming an aqueus suspension of cellulose papermaking fibers, adding hereto an emulsion of a hydrophobic ketene dimer in an \queous medium containing a thermosetting cationic tmido-aldehyde condensation product in acid condensed et hydrophilic stage as paper-strengthening agent, the veight of said ketene dimer being between and 3% )f the dry weight of the fibers and the weight of said :ationic nitrogenous paper-strengthening agent being be- ;ween about A and 3% of the dry weight of the fibers, miformly distributing said added emulsion through said aqueous suspension whereby a substantial proportion of ;aid added ketene dimer and paper-strengthening agent are uniformly adsorbed on the surface of said fibers, sheeting said suspension to form a water-laid web at about pH 4.5, and heating said web to dry the same and to develop at least a substantial part respectively of the sizing and wet strengthening properties of the ketene dimer and paper strengthening agent thereon.
2. Sized paper formedwby heating a water-laid web having adsorbed thereon a hydrophobic organic ketene dimer and a thermosetting cationic amido-aldehyde condensation product.
3. As a new composition of matter a cationic emulsion of a hydrophobic organic ketene dimer wherein the ketene dimer is the dispersed phase in a continuous phase and the aqueous phase contains a thermosetting hydrophilic cationic melamine-formaldehyde wet-strength acid colloid as principal emulsifying agent.
References Cited in the file of this patent UNITED STATES PATENTS 2,559,220 Maxwell =et al. July 3, 19-51 2,627,477 Downey Feb. 3, 1953 2,698,793 Landes et al. Jan. 4, 1955 2,762,270 Keirn et al. Sept. 11, 1956 2,772,310 Morris Nov. 27, 1956 2,785,067 Osberg Mar. 12, 1957 2,865,743 Weisgerber Dec. 23, 1958
Claims (1)
1. A PROCESS FOR THE MANUFACTURE OF SIZED PAPER OF IMPROVED TENSILE STRENGTH WHICH COMPRISES FORMING AN AQUEOUS SUSPENSION OF CELLULOSE PAPERMAKING FIBERS, ADDING THERETO AN EMULSION OF A HYDROPHOBIC KETENE DIMER IN AN AQUEOUS MEDIUM CONTAINING A THERMOSETTING CATIONIC AMIDO-ALDEHYDE CONDENSATION PRODUCT IN ACID CONDENSED YET HYDROPHILIC STAGE AS PAPER-STRENGTHENING AGENT, THE WEIGHT OF SAID KETENE DIMER BEING BETWEEN 1/10% AND 3% OF THE DRY WEIGHT OF THE FIBERS AND THE WEIGHT OF SAID CATIONIC NITROGENOUS PAPER-STRENGTHENING AGENT BEING BETWEEN ABOUT 1/4% AND 3% OF THE DRY WEIGHT OF THE FIBERS, UNIFORMLY DISTRIBUTING SAID ADDED EMULSION THROUGH SAID AQUEOUS SUSPENSION WHEREBY A SUBSTANTIAL PROPORTION OF SAID ADDED KETENE DIMER AND PAPER-STRENGTHENING AGENT ARE UNIFORMLY ADSORBED ON THE SURFACAE OF SAID FIBERS, SHEETING SAID SUSPENSION TO FORM A WATER-LAID WEB AT ABOUT PH 4.5, AND HEATING SAID WEB TO DRY THE SAME AND TO DEVELOP AT LEAST A SUBSTANTIAL PART RESPECTIVELY OF THE SIZING AND WET STRENGTHENING PROPERTIES OF THE KETENE DIMER AND PAPER STRENGHTENING AGENT THEREON.
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WO1998033979A1 (en) * | 1997-02-05 | 1998-08-06 | Akzo Nobel N.V. | Sizing of paper |
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US6165259A (en) * | 1997-02-05 | 2000-12-26 | Akzo Nobel N.V. | Aqueous dispersions of hydrophobic material |
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US5314721A (en) * | 1992-01-14 | 1994-05-24 | Bayer Aktiengesellschaft | Process for sizing paper |
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US6315824B1 (en) | 1996-02-02 | 2001-11-13 | Rodrigue V. Lauzon | Coacervate stabilizer system |
WO1998033979A1 (en) * | 1997-02-05 | 1998-08-06 | Akzo Nobel N.V. | Sizing of paper |
US6165259A (en) * | 1997-02-05 | 2000-12-26 | Akzo Nobel N.V. | Aqueous dispersions of hydrophobic material |
WO2007139500A1 (en) * | 2006-06-01 | 2007-12-06 | Akzo Nobel N.V. | Sizing of paper |
US20070277949A1 (en) * | 2006-06-01 | 2007-12-06 | Akzo Nobel N.V. | Sizing of paper |
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