US3062282A - Initiation of in situ combustion in a carbonaceous stratum - Google Patents

Initiation of in situ combustion in a carbonaceous stratum Download PDF

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US3062282A
US3062282A US710908A US71090858A US3062282A US 3062282 A US3062282 A US 3062282A US 710908 A US710908 A US 710908A US 71090858 A US71090858 A US 71090858A US 3062282 A US3062282 A US 3062282A
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stratum
borehole
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combustion
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Arthur R Schleicher
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Phillips Petroleum Co
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    • EFIXED CONSTRUCTIONS
    • E21EARTH DRILLING; MINING
    • E21BEARTH DRILLING, e.g. DEEP DRILLING; OBTAINING OIL, GAS, WATER, SOLUBLE OR MELTABLE MATERIALS OR A SLURRY OF MINERALS FROM WELLS
    • E21B43/00Methods or apparatus for obtaining oil, gas, water, soluble or meltable materials or a slurry of minerals from wells
    • E21B43/16Enhanced recovery methods for obtaining hydrocarbons
    • E21B43/24Enhanced recovery methods for obtaining hydrocarbons using heat, e.g. steam injection
    • E21B43/243Combustion in situ

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  • This invention relates to ⁇ a process for initiating in situ combustion in a carbonaceous stratus and to the recovery of hydrocarbons therefrom.
  • the ignition ⁇ of carbonaceous material in a stratum around a borehole therein followed by injection of air thru the ignition -borehole and recovery of product hydrooarbons and combustion gas thru another borehole in the stratum is a direct air drive process for effecting in situ combustion and recovery of hydrocarbons from the stratum.
  • the stratum usually plugs in front of the combusion zone because a heavy viscous fluid bank collects in the stratum in Iadvance of the combustion zone which prevents movement of air to the combustion process.
  • inverse air injection has been resorted to.
  • a combustion zone is established around an ignition borehole by any suitable means and air is fed thru the stratum to the combustion zone from one or more surrounding boreholes.
  • an object of the invention to provide a novel and improved process for initiating in situ combustion in a permeable carbonaceous stratum containing tar or highly viscous hydrocarbon material. Another object is to provide -a process for initiating in situ combustion by direct air injection which avoids plugging of the ⁇ stratum due to the congealing of iluidized heavy hydrocarbon material in the stratum in advance of the combustion zone.
  • a broad aspect of the invention comprises heating a section of the stratum -to be ignited around an ignition borehole therein to a temperature below the ignition temperature of the carbonaceous material but sufficiently high to render more fluid and less viscous the heavy hydrocarbon material in the stratum and passing a flushing fluid thru the hot ⁇ section of the stratum so as to drive the heavy liquid hydrocarbon therefrom and removing this hydrocarbon from the formation and thereafter igniting the remaining carbonaceous material in the hot sect-ion of stratum so as to establish in situ combustion therein.
  • the section of stratum immediately surrounding the ignition borehole is heated by any suitable means such 4as by a downhole gas or electric heater, or by means of a pyrotechnic, and ushing fluid is passed thru the hot section either from the ignition borehole to one or more surround-ing boreholes which may be in a ring pattern, such 'as a 5-spot or 7-spot well pattern, or thru the boreholes in the ring so that the heavy hydrocarbon material is flushed into the ignition borehole.
  • In-line ignition boreholes may be utilized with in-line boreholes on either side of the line of ignition boreholes.
  • the ushing uid may comprise -air or an inert gas such -as nitrogen.
  • flushing fluids include light hydrocarbons such as the normally gaseous hydrocarbons ethane, propane, butane, and the corresponding olens as well as normally liquid hydrocarbons such as benzene, gasoline, etc.
  • the liquid is forced into the stratum around the ignition borehole either thru the ignition borehole or thru boreholes positioned in a ring pattern Iaround the ignition borehole and closely spaced thereto, preferably, within the range of 2 to 10 feet.
  • Another method of operation comprises injecting flushing liquid into the stratum thru an ignition borehole by pressurizing the same so as to prive the solvent into the stratum a short distance in the range of 2 to 10 feet and then depressurizing the ignition borehole and driving the solvent and dissolved tar back into the ignition borehole by injecting gas into the surrounding boreholes.
  • the solvent should not be used so as to completely remove all tar from the section of stratum around the ignition borehole but should leave enough for combustion fuel.
  • this section of stratum is heated to the ignition temperature of the residual hydrocarbon material and the hot stratum is then contacted with an oxygen-containing gas such as oxygen-enriched air or pureoxygen so as to ignite and burn the carbonaceous material therein and establish in situ combustion in the stratum.
  • an oxygen-containing gas such as oxygen-enriched air or pureoxygen
  • the surrounding boreholes may be spaced anywhere from a few feet to a thousand feet or more from the Iignition borehole; however the closely surrounding bore holes utilized in the ilushing process are preferably spaced a distance in the range of 2 to 25 feet from the ignition borehole.
  • the preheating of the section of stratum surrounding the ignition borehole in which in situ combustion is to be initiated may be effected entirely by hot air or other hot gas injected into the formation either thru the ignition borehole or thru the boreholes closely spaced around the ignition borehole.
  • the section of stratum is raised in temperature so as to melt and/ or render more iluid the hydrocarbon material in the section of stratum and as it is rendered more fluid, it is driven either into the ignition borehole or into the surrounding boreholes, depending upon the injection point or points.
  • the temperature of the section of stratum should not be raised to the ignition temperature of the carbonaceous material until suicient heavy hydrocarbon is removed from the section of stratum to avoid the possibility of plugging when ignition by direct air injection is utilized.
  • the gas may be suiciently hot to heat the section of stratum to a temperature above ignition temperature of the carbonaceous material.
  • the same may be removed by means of a pump or bucket or all or any portion of it may be burned in the hole in order to further heat the surrounding section of stratum and raise the same to ignition temperature for the ignition step effected by introducing combustion supporting gas thereinto.
  • FIGURES 1 and 2 are elevations thru an oil or tar bearing stratum showing well or borehole positions and arrangement of some equipment for effecting the invention.
  • a central well or borehole is surrounded by a plurality of wells or boreholes 12.
  • Each of the wells is provided with tubing or conduit 14 for injecting or withdrawing fluids from the boreholes.
  • Central well 10 is shown provided with a downhole heater 16.
  • Each of the boreholes penetrates permeable carbonaceous stratum 18.
  • the preheated area surrounding ignition well 10 is identified by numeral 2t) and the preheated section of the stratum around borehole 1t) in FIGURE 2 is identified by numeral 22. Sections and 22 represent either heated areas from which heavy liquid hydrocarbons have been flushed or solvent extracted areas.
  • the section 20 around ignition well 10 is heated by a gas tired or electric heater 16 and air is injected into formation 18 thru auxiliary wells 12 spaced a substantial distance from well 10, either in a ring pattern with well 10 centrally located or in-line on either side of a series of in-line wells 10.
  • the heating of section 20 ⁇ is continued until the temperature thereof is in the range of 300 F. to just below the ignition temperature of the hydrocarbon therein thereby rendering more uid or melting the tar present in the stratum in section 20.
  • the injected air passes thru the heated section 20 and flushes the liquid tar or other highly viscous hyrocarbon into well 10 from which it is removed by any suitable means or method.
  • lt is preferred to heat section 20 to the desired temperature for fiuidizing and removing the heater 16 before flushing the liquid hydrocarbon from the heated section and burning the melted tar in borehole 10, either as it arrives therein or after the ushing step is well under way or completed.
  • the heating and ushing are controlled so as to leave sufficient residual hydrocarbon material in section 20 to provide adequate fuel for in situ combustion and movement of the combustion front thru this section of stratum to the surrounding stratum.
  • the temperature of section 20 is raised either by burning the liquid hydrocarbon in borehole 10 or by removing the same and positioning downhole heater 16 in heating position and again applying heat to section 20 so as to raise the temperature thereof to suitable ignition temperature.
  • Oxygen-containing gas is then injected li either thru wells 12 or well 10 so as to ignite the stratum in section 20 and establish in situ combustion.
  • a combustion zone By continuing the injection of air thru wells 12 while injecting from an outer ring of wells, a combustion zone can be moving outwardly from wells 12 and another one inwardly toward well 10 with the combustion in the latter feeding on the residual carbon produced in the stratum intermediate wells 12 and 10 by the first burning wave effected by inverse air injection thru wells 12.
  • Produced hydrocarbons and combustion gases are usually recovered thru well 10 which is a production well, but production may be recovered thru wells 12 after the combustion zone passes beyond these wells.
  • the embodiment of the invention illustrated in FIG- URE 2 comprises heating section 22 intermediate wells 10 and 12 by any suitable means, such as heater 16, and injecting flushing 'liuid thru well 10 to drive liquefied hydrocarbons from section 22 into auxiliary wells 12 from which the liquid hydrocarbon is recovered by any suitable means.
  • wells 12 are spaced more closely to well 10 than in the embodiment shown in FlGURE l, this spacing being in the range of about 2 to 25 feet.
  • a process for initiating in situ combustion in a permeable stratum containing hydrocarbon material which forms a highly viscous liquid upon heating which comprises heating a section of said stratum around an ignition borehole therein to an elevated temperature below the ignition temperature 0f the hydrocarbon material so as to render said material more uid; passing a flushing uid thru said section between said ignition borehole and an offset borehole in said stratum so as to move ⁇ said viscous liquid to one of said boreholes; removing the flushed out liquid; thereafter initiating combustion in said section of stratum around Isaid ignition borehole; and feeding free oxygen to the resulting combustion zone so as to drive said Zone outwardly from said borehole thru and stratum.
  • a process for initiating in situ combustion in a permeable stratum containing hydrocarbon material which forms a highly viscous liquid upon heating which comprises heating a section of said stratum around an ignition borehole therein so as to render said material more Huid; passing a non-combustion supporting flushing fluid thru said section between said ignition borehole and an offset borehole in said lstratum so as to move said viscous liquid to one of said boreholes; removing the ushed out liquid; thereafter initiating combustion in said section of stratum around said ignition borehole; and feeding free oxygen to the resulting combustion zone so as to drive said zone outwardly from said borehole thru said stratum.
  • a process for initiating in situ combustion in a permeable stratum containing hydrocarbon material which forms a highly viscous liquid upon heat-ing said stratum which comprises heating a section ⁇ of said stratum around lan ignition borehole therein to a temperature above about 300 F.
  • heat lfor the initial Iheating step is supplied by injecting lhot air as ushing gas.
  • a process for initiating in situ combustion in a permeable stratum containing hydrocarbon material which forms a highly viscous liquid upon heating said stratum which comprises heating a section of said stratum around van ignition borehole therein to a temperature above about 300 F.

Description

Nov. 6, 1962 A. R. scHLElcHER INITIATION OF' IN SITU COMBUSTION IN A CARBONACEOUS STRATUM Filed Jan. 24, 1958 n. 0R TAR FORMATION INJECTION r 0R PRoDucTmN f-/|4- DEN ERBUR OIL OR TAR FORMATION INVENTOR. v A. R. SCHLEICHER BYav-v# United States Patent iiice 3,062,282 Patented Nov. 6, 1962 3,662,262 IATIQN F EN SlTU CGMBUSTGN IN A CARBNACEUS STRATUM Arthur R. Schleicher, Urbana, lll., assiguor to Phillips Petroleum Company, a corporation of Delaware Filed Eau. 24, 1958, Ser. No. 71),908 13 Claims. (Cl. 16o-1l) This invention relates to `a process for initiating in situ combustion in a carbonaceous stratus and to the recovery of hydrocarbons therefrom.
In situ combustion in the recovery of hydrocarbons from underground strata containing carbonaceous material is becoming more prevalent in the petroleum industry. 11n this technique of production, combustion is initiated in the carbonaceous stratum and the resulting cornbustion zone is caused to move thru the stratum by either inverse or direct air drive whereby the heat of combustion of a substantial proportion of the hydrocarbon in the stratum drives out and usually upgrades a substantial proportion of the remaining hydrocarbon material.
The ignition `of carbonaceous material in a stratum around a borehole therein followed by injection of air thru the ignition -borehole and recovery of product hydrooarbons and combustion gas thru another borehole in the stratum is a direct air drive process for effecting in situ combustion and recovery of hydrocarbons from the stratum. In this type of operation the stratum usually plugs in front of the combusion zone because a heavy viscous fluid bank collects in the stratum in Iadvance of the combustion zone which prevents movement of air to the combustion process. To overcome this difficulty and permit the continued progress of the combustion zone thru the stratum, inverse air injection has been resorted to. By this technique, a combustion zone is established around an ignition borehole by any suitable means and air is fed thru the stratum to the combustion zone from one or more surrounding boreholes.
Field tests have shown that with most strata it is easier to initiate in situ combustion utilizing direct injection of air or other free-oXygen-containing gas thru the heated ignition borehole into the stratum to be ignited and, except for the plugging of the formation during initial combustion or shortly thereafter by the melted tar highly viscous hydrocarbon material which tends to congeal and plug the formation when the viscous liquid reaches a cooler zone in advance of the combustion front, direct Iair injection Would usually be more desirable. When starting a fire in the stratum by inverse air injection into the hot ignition borehole utilizing a downhole heater to heat the stratum, melted tar or other viscous hydrocarbon is driven into the ignition borehole and burns therein with damage to the downhole equipment. The instant invention is concerned with a method or process for initiating combustion in a carbonaceous stratum containing meltable tar or highly viscous hydrocarbon material which avoids the problems enumerated above.
Accordingly, it is an object of the invention to provide a novel and improved process for initiating in situ combustion in a permeable carbonaceous stratum containing tar or highly viscous hydrocarbon material. Another object is to provide -a process for initiating in situ combustion by direct air injection which avoids plugging of the `stratum due to the congealing of iluidized heavy hydrocarbon material in the stratum in advance of the combustion zone. Other objects of the invention will become apparent upon consideration of the accompanying disclosure.
A broad aspect of the invention comprises heating a section of the stratum -to be ignited around an ignition borehole therein to a temperature below the ignition temperature of the carbonaceous material but sufficiently high to render more fluid and less viscous the heavy hydrocarbon material in the stratum and passing a flushing fluid thru the hot `section of the stratum so as to drive the heavy liquid hydrocarbon therefrom and removing this hydrocarbon from the formation and thereafter igniting the remaining carbonaceous material in the hot sect-ion of stratum so as to establish in situ combustion therein. The section of stratum immediately surrounding the ignition borehole is heated by any suitable means such 4as by a downhole gas or electric heater, or by means of a pyrotechnic, and ushing fluid is passed thru the hot section either from the ignition borehole to one or more surround-ing boreholes which may be in a ring pattern, such 'as a 5-spot or 7-spot well pattern, or thru the boreholes in the ring so that the heavy hydrocarbon material is flushed into the ignition borehole. In-line ignition boreholes may be utilized with in-line boreholes on either side of the line of ignition boreholes. The ushing uid may comprise -air or an inert gas such -as nitrogen. CO2 or combustion gas may .also be utilized and the gas may be preheated to increase the effectiveness of the ilushing step. Other flushing fluids include light hydrocarbons such as the normally gaseous hydrocarbons ethane, propane, butane, and the corresponding olens as well as normally liquid hydrocarbons such as benzene, gasoline, etc.
When utilizing liquid hydrocarbons or other liquid solvents for tar and semi-solid hydrocarbon materials in the stratum as flushing iluid, the liquid is forced into the stratum around the ignition borehole either thru the ignition borehole or thru boreholes positioned in a ring pattern Iaround the ignition borehole and closely spaced thereto, preferably, within the range of 2 to 10 feet. Another method of operation comprises injecting flushing liquid into the stratum thru an ignition borehole by pressurizing the same so as to prive the solvent into the stratum a short distance in the range of 2 to 10 feet and then depressurizing the ignition borehole and driving the solvent and dissolved tar back into the ignition borehole by injecting gas into the surrounding boreholes. The solvent should not be used so as to completely remove all tar from the section of stratum around the ignition borehole but should leave enough for combustion fuel.
ln any event, after removing melted )and/or dissolved tar and heavy hydrocarbon from the `section of stratum around the ignition borehole, this section of stratum is heated to the ignition temperature of the residual hydrocarbon material and the hot stratum is then contacted with an oxygen-containing gas such as oxygen-enriched air or pureoxygen so as to ignite and burn the carbonaceous material therein and establish in situ combustion in the stratum. After ignition and establishment of in situ combustion, the combustion Zone is preferably driven or advanced thru the stratum outwardly from the ignition borehole by inverse air injection thru surrounding boreholes. The surrounding boreholes may be spaced anywhere from a few feet to a thousand feet or more from the Iignition borehole; however the closely surrounding bore holes utilized in the ilushing process are preferably spaced a distance in the range of 2 to 25 feet from the ignition borehole.
The preheating of the section of stratum surrounding the ignition borehole in which in situ combustion is to be initiated may be effected entirely by hot air or other hot gas injected into the formation either thru the ignition borehole or thru the boreholes closely spaced around the ignition borehole. In this manner the section of stratum is raised in temperature so as to melt and/ or render more iluid the hydrocarbon material in the section of stratum and as it is rendered more fluid, it is driven either into the ignition borehole or into the surrounding boreholes, depending upon the injection point or points. When using air as the flushing and heating gas, the temperature of the section of stratum should not be raised to the ignition temperature of the carbonaceous material until suicient heavy hydrocarbon is removed from the section of stratum to avoid the possibility of plugging when ignition by direct air injection is utilized. When utilizing a heating and flushing gas which does not support combustion, the gas may be suiciently hot to heat the section of stratum to a temperature above ignition temperature of the carbonaceous material. When heating the section of stratum around the ignition borehole by a radiant downhole heat source, such as a heater, it is feasible to heat the formation over an extended period without injecting ushing gas until the temperature of the section of stratum is in the range of about 300 F. to the ignition temperature of the hydrocarbon material in the stratum (about 500 to 600 F.) and thereafter injecting non-combustion supporting flushing fluid into the section of stratum so as to drive the viscous liquid hydrocarbon material therefrom. After driving the viscous hydrocarbon into the ignition borehole, the same may be removed by means of a pump or bucket or all or any portion of it may be burned in the hole in order to further heat the surrounding section of stratum and raise the same to ignition temperature for the ignition step effected by introducing combustion supporting gas thereinto.
A more complete understanding of the invention may be obtained by reference to the accompanying schematic drawing of which FIGURES 1 and 2 are elevations thru an oil or tar bearing stratum showing well or borehole positions and arrangement of some equipment for effecting the invention.
Referring to the drawing a central well or borehole is surrounded by a plurality of wells or boreholes 12. Each of the wells is provided with tubing or conduit 14 for injecting or withdrawing fluids from the boreholes. Central well 10 is shown provided with a downhole heater 16. Each of the boreholes penetrates permeable carbonaceous stratum 18. In FIGURE l, the preheated area surrounding ignition well 10 is identified by numeral 2t) and the preheated section of the stratum around borehole 1t) in FIGURE 2 is identified by numeral 22. Sections and 22 represent either heated areas from which heavy liquid hydrocarbons have been flushed or solvent extracted areas.
ln the embodiment of the invention illustrated in FIG- URE l, the section 20 around ignition well 10 is heated by a gas tired or electric heater 16 and air is injected into formation 18 thru auxiliary wells 12 spaced a substantial distance from well 10, either in a ring pattern with well 10 centrally located or in-line on either side of a series of in-line wells 10. The heating of section 20` is continued until the temperature thereof is in the range of 300 F. to just below the ignition temperature of the hydrocarbon therein thereby rendering more uid or melting the tar present in the stratum in section 20. The injected air passes thru the heated section 20 and flushes the liquid tar or other highly viscous hyrocarbon into well 10 from which it is removed by any suitable means or method. lt is preferred to heat section 20 to the desired temperature for fiuidizing and removing the heater 16 before flushing the liquid hydrocarbon from the heated section and burning the melted tar in borehole 10, either as it arrives therein or after the ushing step is well under way or completed.
The heating and ushing are controlled so as to leave sufficient residual hydrocarbon material in section 20 to provide adequate fuel for in situ combustion and movement of the combustion front thru this section of stratum to the surrounding stratum. When the ushing step is completed, the temperature of section 20 is raised either by burning the liquid hydrocarbon in borehole 10 or by removing the same and positioning downhole heater 16 in heating position and again applying heat to section 20 so as to raise the temperature thereof to suitable ignition temperature. Oxygen-containing gas is then injected li either thru wells 12 or well 10 so as to ignite the stratum in section 20 and establish in situ combustion. ln the event injection of air thru well 10 is utilized i or initiating combustion, the flow of air is cut off to this well after a substantial combustion zone has been established and injection of air thru boreholes 12 is utilized to feed the combustion Zone and move the same outwardly from borehole 10 by inverse movement of air. If air is injected initially thru boreholes 12 to initiate combustion in section 20, reversal of air flow is not required since the combustion zone will progress outwardly from well 10 to wells 12. When the combustion zone reaches wells 12, injection may be initiated thru an outer ring of wells so as to continue the movement of the combustion zone thru the stratum toward the outer ring of wells. By continuing the injection of air thru wells 12 while injecting from an outer ring of wells, a combustion zone can be moving outwardly from wells 12 and another one inwardly toward well 10 with the combustion in the latter feeding on the residual carbon produced in the stratum intermediate wells 12 and 10 by the first burning wave effected by inverse air injection thru wells 12. Produced hydrocarbons and combustion gases are usually recovered thru well 10 which is a production well, but production may be recovered thru wells 12 after the combustion zone passes beyond these wells.
The embodiment of the invention illustrated in FIG- URE 2 comprises heating section 22 intermediate wells 10 and 12 by any suitable means, such as heater 16, and injecting flushing 'liuid thru well 10 to drive liquefied hydrocarbons from section 22 into auxiliary wells 12 from which the liquid hydrocarbon is recovered by any suitable means. in the embodiment shown in FIGURE 2, wells 12 are spaced more closely to well 10 than in the embodiment shown in FlGURE l, this spacing being in the range of about 2 to 25 feet. After initiation of combustion in section 22 in accordance with the invention as described hereinbefore and advancement of the combustion zone to the vicinity of wells 12, injection from an outer ring of wells is utilized to move the combustion front further thru the formation. It is also feasible to position a series of ignition wells along a line intermediate parallel rows of auxiliary wells 12 and effect the flushing and in situ combustion in similar manner to that described in connection with FIGURES 1 and 2. Where the permeability of the stratum is low it may be desirable to horizontally fracture and prop the same in conventional manner.
Certain modifications of the invention will become apparent to those skilled in the art and the illustrative details disclosed are not to be construed as imposing unnecessary limitations on the invention.
I claim:
l. A process for initiating in situ combustion in a permeable stratum containing hydrocarbon material which forms a highly viscous liquid upon heating, which comprises heating a section of said stratum around an ignition borehole therein to an elevated temperature below the ignition temperature 0f the hydrocarbon material so as to render said material more uid; passing a flushing uid thru said section between said ignition borehole and an offset borehole in said stratum so as to move `said viscous liquid to one of said boreholes; removing the flushed out liquid; thereafter initiating combustion in said section of stratum around Isaid ignition borehole; and feeding free oxygen to the resulting combustion zone so as to drive said Zone outwardly from said borehole thru and stratum.
2. A process for initiating in situ combustion in a permeable stratum containing hydrocarbon material which forms a highly viscous liquid upon heating, which comprises heating a section of said stratum around an ignition borehole therein so as to render said material more Huid; passing a non-combustion supporting flushing fluid thru said section between said ignition borehole and an offset borehole in said lstratum so as to move said viscous liquid to one of said boreholes; removing the ushed out liquid; thereafter initiating combustion in said section of stratum around said ignition borehole; and feeding free oxygen to the resulting combustion zone so as to drive said zone outwardly from said borehole thru said stratum.
3. The process of claim 1 wherein said ilushing gas is air, said flushing `step and same is contacted with free oxygen while at said temperature so as to effect the ignition step.
4. The process of claim l wherein the ushing uid is passed thru said section of stratum from said olset borehole to said ignition borehole.
5. The process of claim 4 wherein the viscous hydrocarbon ushed into said ignition borehole is ignited and burned therein so as to heat said section of stratum to ignition temperature yand free oxygen is passed thru said said stratum from said offset borehole to said ignition borehole to initiate combustion Within said stratum.
6. The process of claim 1 wherein said flushing fluid is passed thru said section of stratum from said ignition borehole to at least one borehole spaced therefrom within the range of about 2 to 25 feet.
7. The process of claim 6 wherein heating of said section of Stratum is continued thru said ignition borehole after the flushing step so as `to raise said section to the ignition temperature and said section is contacted with free oxygen while at said temperature to initiate combustion of said hydrocarbon material.
8. A process for initiating in situ combustion in a permeable stratum containing hydrocarbon material which forms a highly viscous liquid upon heat-ing said stratum, which comprises heating a section `of said stratum around lan ignition borehole therein to a temperature above about 300 F. but below ignition temperature of said material in contact with air by applying heat to the walls of said borehole and injecting air thru said borehole into said stratum and withdrawing same -thru a plurality of boreholes positioned in -a ring pattern around said ignition borehole closely spaced therefrom, whereby highly viscous hydrocarbon material is flushed into said boreholes; removing said viscous material from said boreholes; thereafter continuing the heating step so as to raise the temperature of said section to ignition temperature; `and contacting said section with air so as to ignite same and establish in situ combustion therein` 9. The process of claim 8 wherein the Iair for the ignition -step is injected thru said boreholes and combustion gas and produced hydrocarbons are withdrawn thru said ignition borehole.
10. The process of claim 8 wherein the air for the ignition step is injected thru said ignition borehole and combustion gases and produced hydrocarbons are withdrawn thru said boreholes.
11. The process of claim 8 wherein heat lfor the initial Iheating step is supplied by injecting lhot air as ushing gas.
l2. A process for initiating in situ combustion in a permeable stratum containing hydrocarbon material which forms a highly viscous liquid upon heating said stratum, which comprises heating a section of said stratum around van ignition borehole therein to a temperature above about 300 F. but below ignition temperature of said material in contact with air by applying heat to Ithe walls of said borehole 4and injecting air thru a plurality of boreholes .positioned in a ring pattern around said ignition borehole and withdrawing same thru said ignition borehole, whereby highly viscous hydrocarbon material is flushed into said ignition borehole; removing said material from said borehole; thereafter continuing the heating step so as to raise the temperature of said section to ignition temperature; and contacting lsaid section with air so as to ignite -sa-rne `and establish in situ combustion therein.
13. The process of claim 12 wherein heat is applied to the wall of said ignition borehole by a downhole heater, said heater is removed 'after the llushing step, said viscous material is removed from said borehole by burning same therein to heat said section to ignition ternperature, and ignition is eiect-ed by injecting air thru said boreholes so Ias to force sarne toward said ignition borehole.
References Cited in the le of this patent UNITED STATES PATENTS 1,520,012 Conrader Dec. 23, 1924 2,300,348 Dana Oct. 27, 1942 2,584,606 Merriam Feb. 5, 1952 2,670,047 Mayes May 23, 1954 2,793,696 Morse May 28, 1957 2,906,337 Hennig Sept. 29, 1959 November 6, 1962 Patent No7 3,062,282
Arthur IL, Schleicher he above numbered patt error appears in t Ratent should read as It is hereby certified tha said Letters ent requiring correction and that the corrected below.
after "said" insert section of Column 5, line 8,
rting temperature after stratum is heated to combustion-suppe the n. I
Signed and sealed this 3rd day of September l963 (SEAL) Attest:
' DAVID L. LADD ERNEST W. SWIDEF.
Commissioner of Patents Attesting Officer

Claims (1)

1. A PROCESS FOR INITIATING IN SITU COMBUSTION IN A PERMEABLE STRATUM CONTAINING HYDROCARBON METERIAL WHICH FORMS A HIGHLY VISCOUS LIQUID UPON HEATING, WHICH COMPRISES HEATING A SECTION OF SAID STRATUM AROUND AN IGNITION BOREHOLE THEREIN TO AN ELEVATED TEMPERATURE BELOW THE IGNITION TEMPERATURE OF THE HYDROCARBON MATERIAL SO AS TO RENDER SAID MATERIAL MORE FLUID; PASSING A FLUSH ING FLUID THRU SAID SECTION BETWEEN SAID IGNITION BOREHOLE AND AN OFFSET BOREHOLE IN SAID STRATUM SO AS TO MOVE SAID VISCOUS LIQUID TO ONE OF SAID BOREHOLES; REMOVING THE FLUSHED OUT LIQUID; THEREAFTER INITIATING COMBUSTION IN SAID SECTION OF STRATUM AROUND SAID IGNITION BOREHOLE; AND FEEDING FREE OXYGEN TO THE RESULTING COMBUSTION ZONE SO AS TO DRIVE SAID ZONE OUTWARDLY FROM SAID BOREHOLE THRU AND STRATUM.
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Cited By (47)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US3149670A (en) * 1962-03-27 1964-09-22 Smclair Res Inc In-situ heating process
US3174543A (en) * 1961-02-23 1965-03-23 Socony Mobil Oil Co Inc Method of recovering oil by in-situ produced carbon dioxide
US3246693A (en) * 1963-06-21 1966-04-19 Socony Mobil Oil Co Inc Secondary recovery of viscous crude oil
US3386507A (en) * 1966-10-03 1968-06-04 Phillips Petroleum Co Oil well performance
US3460621A (en) * 1967-05-22 1969-08-12 Pan American Petroleum Corp Cyclic steam injection and gas drive
US3848671A (en) * 1973-10-24 1974-11-19 Atlantic Richfield Co Method of producing bitumen from a subterranean tar sand formation
US3874452A (en) * 1973-03-23 1975-04-01 Texaco Inc Recovery of viscous petroleum from asphaltic petroleum containing formations such as tar sand deposits
US4042027A (en) * 1973-03-23 1977-08-16 Texaco Inc. Recovery of petroleum from viscous asphaltic petroleum containing formations including tar sand deposits
US4274487A (en) * 1979-01-11 1981-06-23 Standard Oil Company (Indiana) Indirect thermal stimulation of production wells
US4384613A (en) * 1980-10-24 1983-05-24 Terra Tek, Inc. Method of in-situ retorting of carbonaceous material for recovery of organic liquids and gases
WO2001081239A2 (en) * 2000-04-24 2001-11-01 Shell Internationale Research Maatschappij B.V. In situ recovery from a hydrocarbon containing formation
US20030080604A1 (en) * 2001-04-24 2003-05-01 Vinegar Harold J. In situ thermal processing and inhibiting migration of fluids into or out of an in situ oil shale formation
US20030079877A1 (en) * 2001-04-24 2003-05-01 Wellington Scott Lee In situ thermal processing of a relatively impermeable formation in a reducing environment
US20030098605A1 (en) * 2001-04-24 2003-05-29 Vinegar Harold J. In situ thermal recovery from a relatively permeable formation
US6588504B2 (en) 2000-04-24 2003-07-08 Shell Oil Company In situ thermal processing of a coal formation to produce nitrogen and/or sulfur containing formation fluids
US20030173085A1 (en) * 2001-10-24 2003-09-18 Vinegar Harold J. Upgrading and mining of coal
US20030173081A1 (en) * 2001-10-24 2003-09-18 Vinegar Harold J. In situ thermal processing of an oil reservoir formation
US20030196801A1 (en) * 2001-10-24 2003-10-23 Vinegar Harold J. In situ thermal processing of a hydrocarbon containing formation via backproducing through a heater well
US6698515B2 (en) 2000-04-24 2004-03-02 Shell Oil Company In situ thermal processing of a coal formation using a relatively slow heating rate
US6715546B2 (en) 2000-04-24 2004-04-06 Shell Oil Company In situ production of synthesis gas from a hydrocarbon containing formation through a heat source wellbore
US6715548B2 (en) 2000-04-24 2004-04-06 Shell Oil Company In situ thermal processing of a hydrocarbon containing formation to produce nitrogen containing formation fluids
US20050269095A1 (en) * 2004-04-23 2005-12-08 Fairbanks Michael D Inhibiting reflux in a heated well of an in situ conversion system
US7011154B2 (en) 2000-04-24 2006-03-14 Shell Oil Company In situ recovery from a kerogen and liquid hydrocarbon containing formation
US7066254B2 (en) 2001-04-24 2006-06-27 Shell Oil Company In situ thermal processing of a tar sands formation
US7073578B2 (en) 2002-10-24 2006-07-11 Shell Oil Company Staged and/or patterned heating during in situ thermal processing of a hydrocarbon containing formation
US7090013B2 (en) 2001-10-24 2006-08-15 Shell Oil Company In situ thermal processing of a hydrocarbon containing formation to produce heated fluids
US7096953B2 (en) 2000-04-24 2006-08-29 Shell Oil Company In situ thermal processing of a coal formation using a movable heating element
US7104319B2 (en) 2001-10-24 2006-09-12 Shell Oil Company In situ thermal processing of a heavy oil diatomite formation
US7121342B2 (en) 2003-04-24 2006-10-17 Shell Oil Company Thermal processes for subsurface formations
US7165615B2 (en) 2001-10-24 2007-01-23 Shell Oil Company In situ recovery from a hydrocarbon containing formation using conductor-in-conduit heat sources with an electrically conductive material in the overburden
US20070045266A1 (en) * 2005-04-22 2007-03-01 Sandberg Chester L In situ conversion process utilizing a closed loop heating system
US20070095536A1 (en) * 2005-10-24 2007-05-03 Vinegar Harold J Cogeneration systems and processes for treating hydrocarbon containing formations
US20070199707A1 (en) * 2006-02-27 2007-08-30 Grant Hocking Enhanced Hydrocarbon Recovery By Convective Heating of Oil Sand Formations
US20080035348A1 (en) * 2006-04-21 2008-02-14 Vitek John M Temperature limited heaters using phase transformation of ferromagnetic material
WO2008051495A2 (en) * 2006-10-20 2008-05-02 Shell Oil Company Systems and processes for use in treating subsurface formations
US20090071652A1 (en) * 2007-04-20 2009-03-19 Vinegar Harold J In situ heat treatment from multiple layers of a tar sands formation
US20090189617A1 (en) * 2007-10-19 2009-07-30 David Burns Continuous subsurface heater temperature measurement
US20090260823A1 (en) * 2008-04-18 2009-10-22 Robert George Prince-Wright Mines and tunnels for use in treating subsurface hydrocarbon containing formations
US20100089586A1 (en) * 2008-10-13 2010-04-15 John Andrew Stanecki Movable heaters for treating subsurface hydrocarbon containing formations
US8327932B2 (en) 2009-04-10 2012-12-11 Shell Oil Company Recovering energy from a subsurface formation
US8631866B2 (en) 2010-04-09 2014-01-21 Shell Oil Company Leak detection in circulated fluid systems for heating subsurface formations
US8701769B2 (en) 2010-04-09 2014-04-22 Shell Oil Company Methods for treating hydrocarbon formations based on geology
US8820406B2 (en) 2010-04-09 2014-09-02 Shell Oil Company Electrodes for electrical current flow heating of subsurface formations with conductive material in wellbore
US9016370B2 (en) 2011-04-08 2015-04-28 Shell Oil Company Partial solution mining of hydrocarbon containing layers prior to in situ heat treatment
US9033042B2 (en) 2010-04-09 2015-05-19 Shell Oil Company Forming bitumen barriers in subsurface hydrocarbon formations
US9309755B2 (en) 2011-10-07 2016-04-12 Shell Oil Company Thermal expansion accommodation for circulated fluid systems used to heat subsurface formations
US10047594B2 (en) 2012-01-23 2018-08-14 Genie Ip B.V. Heater pattern for in situ thermal processing of a subsurface hydrocarbon containing formation

Citations (6)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US1520012A (en) * 1921-03-28 1924-12-23 Conrader Rudolph Method of treating oil wells and apparatus therefor
US2300348A (en) * 1941-04-21 1942-10-27 Frank E Dana Method for cleaning oil wells
US2584606A (en) * 1948-07-02 1952-02-05 Edmund S Merriam Thermal drive method for recovery of oil
US2670047A (en) * 1949-04-22 1954-02-23 Socony Vacuum Oil Co Inc Method of initiating subterranean combustion
US2793696A (en) * 1954-07-22 1957-05-28 Pan American Petroleum Corp Oil recovery by underground combustion
US2906337A (en) * 1957-08-16 1959-09-29 Pure Oil Co Method of recovering bitumen

Patent Citations (6)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US1520012A (en) * 1921-03-28 1924-12-23 Conrader Rudolph Method of treating oil wells and apparatus therefor
US2300348A (en) * 1941-04-21 1942-10-27 Frank E Dana Method for cleaning oil wells
US2584606A (en) * 1948-07-02 1952-02-05 Edmund S Merriam Thermal drive method for recovery of oil
US2670047A (en) * 1949-04-22 1954-02-23 Socony Vacuum Oil Co Inc Method of initiating subterranean combustion
US2793696A (en) * 1954-07-22 1957-05-28 Pan American Petroleum Corp Oil recovery by underground combustion
US2906337A (en) * 1957-08-16 1959-09-29 Pure Oil Co Method of recovering bitumen

Cited By (400)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US3174543A (en) * 1961-02-23 1965-03-23 Socony Mobil Oil Co Inc Method of recovering oil by in-situ produced carbon dioxide
US3149670A (en) * 1962-03-27 1964-09-22 Smclair Res Inc In-situ heating process
US3246693A (en) * 1963-06-21 1966-04-19 Socony Mobil Oil Co Inc Secondary recovery of viscous crude oil
US3386507A (en) * 1966-10-03 1968-06-04 Phillips Petroleum Co Oil well performance
US3460621A (en) * 1967-05-22 1969-08-12 Pan American Petroleum Corp Cyclic steam injection and gas drive
US3874452A (en) * 1973-03-23 1975-04-01 Texaco Inc Recovery of viscous petroleum from asphaltic petroleum containing formations such as tar sand deposits
US4042027A (en) * 1973-03-23 1977-08-16 Texaco Inc. Recovery of petroleum from viscous asphaltic petroleum containing formations including tar sand deposits
US3848671A (en) * 1973-10-24 1974-11-19 Atlantic Richfield Co Method of producing bitumen from a subterranean tar sand formation
US4274487A (en) * 1979-01-11 1981-06-23 Standard Oil Company (Indiana) Indirect thermal stimulation of production wells
US4384613A (en) * 1980-10-24 1983-05-24 Terra Tek, Inc. Method of in-situ retorting of carbonaceous material for recovery of organic liquids and gases
US6880635B2 (en) 2000-04-24 2005-04-19 Shell Oil Company In situ production of synthesis gas from a coal formation, the synthesis gas having a selected H2 to CO ratio
WO2001081239A2 (en) * 2000-04-24 2001-11-01 Shell Internationale Research Maatschappij B.V. In situ recovery from a hydrocarbon containing formation
WO2001081239A3 (en) * 2000-04-24 2002-05-23 Shell Oil Co In situ recovery from a hydrocarbon containing formation
GB2379469A (en) * 2000-04-24 2003-03-12 Shell Int Research In situ recovery from a hydrocarbon containing formation
US20090101346A1 (en) * 2000-04-24 2009-04-23 Shell Oil Company, Inc. In situ recovery from a hydrocarbon containing formation
US7798221B2 (en) * 2000-04-24 2010-09-21 Shell Oil Company In situ recovery from a hydrocarbon containing formation
US8225866B2 (en) 2000-04-24 2012-07-24 Shell Oil Company In situ recovery from a hydrocarbon containing formation
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US8789586B2 (en) 2000-04-24 2014-07-29 Shell Oil Company In situ recovery from a hydrocarbon containing formation
US7096941B2 (en) 2000-04-24 2006-08-29 Shell Oil Company In situ thermal processing of a coal formation with heat sources located at an edge of a coal layer
US6581684B2 (en) 2000-04-24 2003-06-24 Shell Oil Company In Situ thermal processing of a hydrocarbon containing formation to produce sulfur containing formation fluids
US7096953B2 (en) 2000-04-24 2006-08-29 Shell Oil Company In situ thermal processing of a coal formation using a movable heating element
US6588503B2 (en) 2000-04-24 2003-07-08 Shell Oil Company In Situ thermal processing of a coal formation to control product composition
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US6591907B2 (en) 2000-04-24 2003-07-15 Shell Oil Company In situ thermal processing of a coal formation with a selected vitrinite reflectance
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US7086468B2 (en) 2000-04-24 2006-08-08 Shell Oil Company In situ thermal processing of a hydrocarbon containing formation using heat sources positioned within open wellbores
US7036583B2 (en) 2000-04-24 2006-05-02 Shell Oil Company In situ thermal processing of a hydrocarbon containing formation to increase a porosity of the formation
US7017661B2 (en) 2000-04-24 2006-03-28 Shell Oil Company Production of synthesis gas from a coal formation
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US20040211554A1 (en) * 2001-04-24 2004-10-28 Vinegar Harold J. Heat sources with conductive material for in situ thermal processing of an oil shale formation
US20040211557A1 (en) * 2001-04-24 2004-10-28 Cole Anthony Thomas Conductor-in-conduit heat sources for in situ thermal processing of an oil shale formation
US20030080604A1 (en) * 2001-04-24 2003-05-01 Vinegar Harold J. In situ thermal processing and inhibiting migration of fluids into or out of an in situ oil shale formation
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US20030164239A1 (en) * 2001-04-24 2003-09-04 Wellington Scott Lee In situ thermal processing of an oil shale formation in a reducing environment
US20030102130A1 (en) * 2001-04-24 2003-06-05 Vinegar Harold J. In situ thermal recovery from a relatively permeable formation with quality control
US20030111223A1 (en) * 2001-04-24 2003-06-19 Rouffignac Eric Pierre De In situ thermal processing of an oil shale formation using horizontal heat sources
US7096942B1 (en) 2001-04-24 2006-08-29 Shell Oil Company In situ thermal processing of a relatively permeable formation while controlling pressure
US20030116315A1 (en) * 2001-04-24 2003-06-26 Wellington Scott Lee In situ thermal processing of a relatively permeable formation
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US20030148894A1 (en) * 2001-04-24 2003-08-07 Vinegar Harold J. In situ thermal processing of an oil shale formation using a natural distributed combustor
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US20030146002A1 (en) * 2001-04-24 2003-08-07 Vinegar Harold J. Removable heat sources for in situ thermal processing of an oil shale formation
US20030142964A1 (en) * 2001-04-24 2003-07-31 Wellington Scott Lee In situ thermal processing of an oil shale formation using a controlled heating rate
US20030141068A1 (en) * 2001-04-24 2003-07-31 Pierre De Rouffignac Eric In situ thermal processing through an open wellbore in an oil shale formation
US20030141067A1 (en) * 2001-04-24 2003-07-31 Rouffignac Eric Pierre De In situ thermal processing of an oil shale formation to increase permeability of the formation
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US20030141066A1 (en) * 2001-04-24 2003-07-31 Karanikas John Michael In situ thermal processing of an oil shale formation while inhibiting coking
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US20030136558A1 (en) * 2001-04-24 2003-07-24 Wellington Scott Lee In situ thermal processing of an oil shale formation to produce a desired product
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US20030131996A1 (en) * 2001-04-24 2003-07-17 Vinegar Harold J. In situ thermal processing of an oil shale formation having permeable and impermeable sections
US7040400B2 (en) 2001-04-24 2006-05-09 Shell Oil Company In situ thermal processing of a relatively impermeable formation using an open wellbore
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US7051808B1 (en) 2001-10-24 2006-05-30 Shell Oil Company Seismic monitoring of in situ conversion in a hydrocarbon containing formation
US7461691B2 (en) 2001-10-24 2008-12-09 Shell Oil Company In situ recovery from a hydrocarbon containing formation
US7063145B2 (en) 2001-10-24 2006-06-20 Shell Oil Company Methods and systems for heating a hydrocarbon containing formation in situ with an opening contacting the earth's surface at two locations
US7066257B2 (en) 2001-10-24 2006-06-27 Shell Oil Company In situ recovery from lean and rich zones in a hydrocarbon containing formation
US20030196801A1 (en) * 2001-10-24 2003-10-23 Vinegar Harold J. In situ thermal processing of a hydrocarbon containing formation via backproducing through a heater well
US20030173081A1 (en) * 2001-10-24 2003-09-18 Vinegar Harold J. In situ thermal processing of an oil reservoir formation
US7077199B2 (en) 2001-10-24 2006-07-18 Shell Oil Company In situ thermal processing of an oil reservoir formation
US7077198B2 (en) 2001-10-24 2006-07-18 Shell Oil Company In situ recovery from a hydrocarbon containing formation using barriers
US8627887B2 (en) 2001-10-24 2014-01-14 Shell Oil Company In situ recovery from a hydrocarbon containing formation
US20050092483A1 (en) * 2001-10-24 2005-05-05 Vinegar Harold J. In situ thermal processing of a hydrocarbon containing formation using a natural distributed combustor
US7090013B2 (en) 2001-10-24 2006-08-15 Shell Oil Company In situ thermal processing of a hydrocarbon containing formation to produce heated fluids
US20030173085A1 (en) * 2001-10-24 2003-09-18 Vinegar Harold J. Upgrading and mining of coal
US20030196810A1 (en) * 2001-10-24 2003-10-23 Vinegar Harold J. Treatment of a hydrocarbon containing formation after heating
US20040040715A1 (en) * 2001-10-24 2004-03-04 Wellington Scott Lee In situ production of a blending agent from a hydrocarbon containing formation
US7100994B2 (en) 2001-10-24 2006-09-05 Shell Oil Company Producing hydrocarbons and non-hydrocarbon containing materials when treating a hydrocarbon containing formation
US6991045B2 (en) 2001-10-24 2006-01-31 Shell Oil Company Forming openings in a hydrocarbon containing formation using magnetic tracking
US7114566B2 (en) 2001-10-24 2006-10-03 Shell Oil Company In situ thermal processing of a hydrocarbon containing formation using a natural distributed combustor
US6969123B2 (en) 2001-10-24 2005-11-29 Shell Oil Company Upgrading and mining of coal
US20030201098A1 (en) * 2001-10-24 2003-10-30 Karanikas John Michael In situ recovery from a hydrocarbon containing formation using one or more simulations
US7128153B2 (en) 2001-10-24 2006-10-31 Shell Oil Company Treatment of a hydrocarbon containing formation after heating
US7156176B2 (en) 2001-10-24 2007-01-02 Shell Oil Company Installation and use of removable heaters in a hydrocarbon containing formation
US7165615B2 (en) 2001-10-24 2007-01-23 Shell Oil Company In situ recovery from a hydrocarbon containing formation using conductor-in-conduit heat sources with an electrically conductive material in the overburden
US6932155B2 (en) 2001-10-24 2005-08-23 Shell Oil Company In situ thermal processing of a hydrocarbon containing formation via backproducing through a heater well
US7121341B2 (en) 2002-10-24 2006-10-17 Shell Oil Company Conductor-in-conduit temperature limited heaters
US8224164B2 (en) 2002-10-24 2012-07-17 Shell Oil Company Insulated conductor temperature limited heaters
US7219734B2 (en) 2002-10-24 2007-05-22 Shell Oil Company Inhibiting wellbore deformation during in situ thermal processing of a hydrocarbon containing formation
US8238730B2 (en) 2002-10-24 2012-08-07 Shell Oil Company High voltage temperature limited heaters
US8224163B2 (en) 2002-10-24 2012-07-17 Shell Oil Company Variable frequency temperature limited heaters
US7073578B2 (en) 2002-10-24 2006-07-11 Shell Oil Company Staged and/or patterned heating during in situ thermal processing of a hydrocarbon containing formation
US7121342B2 (en) 2003-04-24 2006-10-17 Shell Oil Company Thermal processes for subsurface formations
US7360588B2 (en) 2003-04-24 2008-04-22 Shell Oil Company Thermal processes for subsurface formations
US8579031B2 (en) 2003-04-24 2013-11-12 Shell Oil Company Thermal processes for subsurface formations
US7942203B2 (en) 2003-04-24 2011-05-17 Shell Oil Company Thermal processes for subsurface formations
US20050269094A1 (en) * 2004-04-23 2005-12-08 Harris Christopher K Triaxial temperature limited heater
US8355623B2 (en) 2004-04-23 2013-01-15 Shell Oil Company Temperature limited heaters with high power factors
US7510000B2 (en) 2004-04-23 2009-03-31 Shell Oil Company Reducing viscosity of oil for production from a hydrocarbon containing formation
US7424915B2 (en) 2004-04-23 2008-09-16 Shell Oil Company Vacuum pumping of conductor-in-conduit heaters
US7431076B2 (en) 2004-04-23 2008-10-07 Shell Oil Company Temperature limited heaters using modulated DC power
US7320364B2 (en) 2004-04-23 2008-01-22 Shell Oil Company Inhibiting reflux in a heated well of an in situ conversion system
US7490665B2 (en) 2004-04-23 2009-02-17 Shell Oil Company Variable frequency temperature limited heaters
US7481274B2 (en) 2004-04-23 2009-01-27 Shell Oil Company Temperature limited heaters with relatively constant current
US20050269095A1 (en) * 2004-04-23 2005-12-08 Fairbanks Michael D Inhibiting reflux in a heated well of an in situ conversion system
US20050269089A1 (en) * 2004-04-23 2005-12-08 Sandberg Chester L Temperature limited heaters using modulated DC power
US7353872B2 (en) 2004-04-23 2008-04-08 Shell Oil Company Start-up of temperature limited heaters using direct current (DC)
US7357180B2 (en) 2004-04-23 2008-04-15 Shell Oil Company Inhibiting effects of sloughing in wellbores
US7383877B2 (en) 2004-04-23 2008-06-10 Shell Oil Company Temperature limited heaters with thermally conductive fluid used to heat subsurface formations
US20050269090A1 (en) * 2004-04-23 2005-12-08 Vinegar Harold J Temperature limited heaters with thermally conductive fluid used to heat subsurface formations
US20050269088A1 (en) * 2004-04-23 2005-12-08 Vinegar Harold J Inhibiting effects of sloughing in wellbores
US20050269091A1 (en) * 2004-04-23 2005-12-08 Guillermo Pastor-Sanz Reducing viscosity of oil for production from a hydrocarbon containing formation
US7370704B2 (en) 2004-04-23 2008-05-13 Shell Oil Company Triaxial temperature limited heater
US20070137856A1 (en) * 2005-04-22 2007-06-21 Mckinzie Billy J Double barrier system for an in situ conversion process
US8027571B2 (en) 2005-04-22 2011-09-27 Shell Oil Company In situ conversion process systems utilizing wellbores in at least two regions of a formation
US7986869B2 (en) 2005-04-22 2011-07-26 Shell Oil Company Varying properties along lengths of temperature limited heaters
US7942197B2 (en) 2005-04-22 2011-05-17 Shell Oil Company Methods and systems for producing fluid from an in situ conversion process
US8070840B2 (en) 2005-04-22 2011-12-06 Shell Oil Company Treatment of gas from an in situ conversion process
US7860377B2 (en) 2005-04-22 2010-12-28 Shell Oil Company Subsurface connection methods for subsurface heaters
US7831134B2 (en) 2005-04-22 2010-11-09 Shell Oil Company Grouped exposed metal heaters
US8224165B2 (en) 2005-04-22 2012-07-17 Shell Oil Company Temperature limited heater utilizing non-ferromagnetic conductor
US8233782B2 (en) 2005-04-22 2012-07-31 Shell Oil Company Grouped exposed metal heaters
US7575053B2 (en) 2005-04-22 2009-08-18 Shell Oil Company Low temperature monitoring system for subsurface barriers
US7575052B2 (en) 2005-04-22 2009-08-18 Shell Oil Company In situ conversion process utilizing a closed loop heating system
US7546873B2 (en) 2005-04-22 2009-06-16 Shell Oil Company Low temperature barriers for use with in situ processes
US7527094B2 (en) 2005-04-22 2009-05-05 Shell Oil Company Double barrier system for an in situ conversion process
US8230927B2 (en) 2005-04-22 2012-07-31 Shell Oil Company Methods and systems for producing fluid from an in situ conversion process
US20070144732A1 (en) * 2005-04-22 2007-06-28 Kim Dong S Low temperature barriers for use with in situ processes
US7500528B2 (en) 2005-04-22 2009-03-10 Shell Oil Company Low temperature barrier wellbores formed using water flushing
US20070119098A1 (en) * 2005-04-22 2007-05-31 Zaida Diaz Treatment of gas from an in situ conversion process
US20070108200A1 (en) * 2005-04-22 2007-05-17 Mckinzie Billy J Ii Low temperature barrier wellbores formed using water flushing
US7435037B2 (en) 2005-04-22 2008-10-14 Shell Oil Company Low temperature barriers with heat interceptor wells for in situ processes
US20070045265A1 (en) * 2005-04-22 2007-03-01 Mckinzie Billy J Ii Low temperature barriers with heat interceptor wells for in situ processes
US20070045266A1 (en) * 2005-04-22 2007-03-01 Sandberg Chester L In situ conversion process utilizing a closed loop heating system
US20080107577A1 (en) * 2005-10-24 2008-05-08 Vinegar Harold J Varying heating in dawsonite zones in hydrocarbon containing formations
US7635025B2 (en) 2005-10-24 2009-12-22 Shell Oil Company Cogeneration systems and processes for treating hydrocarbon containing formations
US7584789B2 (en) 2005-10-24 2009-09-08 Shell Oil Company Methods of cracking a crude product to produce additional crude products
US20070221377A1 (en) * 2005-10-24 2007-09-27 Vinegar Harold J Solution mining systems and methods for treating hydrocarbon containing formations
US7581589B2 (en) 2005-10-24 2009-09-01 Shell Oil Company Methods of producing alkylated hydrocarbons from an in situ heat treatment process liquid
US20070095536A1 (en) * 2005-10-24 2007-05-03 Vinegar Harold J Cogeneration systems and processes for treating hydrocarbon containing formations
US20070125533A1 (en) * 2005-10-24 2007-06-07 Minderhoud Johannes K Methods of hydrotreating a liquid stream to remove clogging compounds
US20070127897A1 (en) * 2005-10-24 2007-06-07 John Randy C Subsurface heaters with low sulfidation rates
US7562706B2 (en) 2005-10-24 2009-07-21 Shell Oil Company Systems and methods for producing hydrocarbons from tar sands formations
US20070131427A1 (en) * 2005-10-24 2007-06-14 Ruijian Li Systems and methods for producing hydrocarbons from tar sands formations
US20070131420A1 (en) * 2005-10-24 2007-06-14 Weijian Mo Methods of cracking a crude product to produce additional crude products
US8151880B2 (en) 2005-10-24 2012-04-10 Shell Oil Company Methods of making transportation fuel
US8606091B2 (en) 2005-10-24 2013-12-10 Shell Oil Company Subsurface heaters with low sulfidation rates
US7559367B2 (en) 2005-10-24 2009-07-14 Shell Oil Company Temperature limited heater with a conduit substantially electrically isolated from the formation
US7559368B2 (en) 2005-10-24 2009-07-14 Shell Oil Company Solution mining systems and methods for treating hydrocarbon containing formations
US7556096B2 (en) 2005-10-24 2009-07-07 Shell Oil Company Varying heating in dawsonite zones in hydrocarbon containing formations
US7556095B2 (en) 2005-10-24 2009-07-07 Shell Oil Company Solution mining dawsonite from hydrocarbon containing formations with a chelating agent
US7549470B2 (en) 2005-10-24 2009-06-23 Shell Oil Company Solution mining and heating by oxidation for treating hydrocarbon containing formations
US20070131419A1 (en) * 2005-10-24 2007-06-14 Maria Roes Augustinus W Methods of producing alkylated hydrocarbons from an in situ heat treatment process liquid
US20070199707A1 (en) * 2006-02-27 2007-08-30 Grant Hocking Enhanced Hydrocarbon Recovery By Convective Heating of Oil Sand Formations
US7604054B2 (en) * 2006-02-27 2009-10-20 Geosierra Llc Enhanced hydrocarbon recovery by convective heating of oil sand formations
US20080035705A1 (en) * 2006-04-21 2008-02-14 Menotti James L Welding shield for coupling heaters
US20100272595A1 (en) * 2006-04-21 2010-10-28 Shell Oil Company High strength alloys
US7673786B2 (en) 2006-04-21 2010-03-09 Shell Oil Company Welding shield for coupling heaters
US20080173450A1 (en) * 2006-04-21 2008-07-24 Bernard Goldberg Time sequenced heating of multiple layers in a hydrocarbon containing formation
US7610962B2 (en) 2006-04-21 2009-11-03 Shell Oil Company Sour gas injection for use with in situ heat treatment
US7866385B2 (en) 2006-04-21 2011-01-11 Shell Oil Company Power systems utilizing the heat of produced formation fluid
US7912358B2 (en) 2006-04-21 2011-03-22 Shell Oil Company Alternate energy source usage for in situ heat treatment processes
US7635023B2 (en) 2006-04-21 2009-12-22 Shell Oil Company Time sequenced heating of multiple layers in a hydrocarbon containing formation
US8192682B2 (en) 2006-04-21 2012-06-05 Shell Oil Company High strength alloys
US20080035346A1 (en) * 2006-04-21 2008-02-14 Vijay Nair Methods of producing transportation fuel
US7533719B2 (en) 2006-04-21 2009-05-19 Shell Oil Company Wellhead with non-ferromagnetic materials
US7683296B2 (en) 2006-04-21 2010-03-23 Shell Oil Company Adjusting alloy compositions for selected properties in temperature limited heaters
US7793722B2 (en) 2006-04-21 2010-09-14 Shell Oil Company Non-ferromagnetic overburden casing
US20080173442A1 (en) * 2006-04-21 2008-07-24 Vinegar Harold J Sulfur barrier for use with in situ processes for treating formations
US8083813B2 (en) 2006-04-21 2011-12-27 Shell Oil Company Methods of producing transportation fuel
US7631689B2 (en) 2006-04-21 2009-12-15 Shell Oil Company Sulfur barrier for use with in situ processes for treating formations
US20080038144A1 (en) * 2006-04-21 2008-02-14 Maziasz Phillip J High strength alloys
US20080173449A1 (en) * 2006-04-21 2008-07-24 Thomas David Fowler Sour gas injection for use with in situ heat treatment
US20080173444A1 (en) * 2006-04-21 2008-07-24 Francis Marion Stone Alternate energy source usage for in situ heat treatment processes
US20080035348A1 (en) * 2006-04-21 2008-02-14 Vitek John M Temperature limited heaters using phase transformation of ferromagnetic material
US7785427B2 (en) 2006-04-21 2010-08-31 Shell Oil Company High strength alloys
US7597147B2 (en) 2006-04-21 2009-10-06 Shell Oil Company Temperature limited heaters using phase transformation of ferromagnetic material
US20080174115A1 (en) * 2006-04-21 2008-07-24 Gene Richard Lambirth Power systems utilizing the heat of produced formation fluid
US7604052B2 (en) 2006-04-21 2009-10-20 Shell Oil Company Compositions produced using an in situ heat treatment process
US8857506B2 (en) 2006-04-21 2014-10-14 Shell Oil Company Alternate energy source usage methods for in situ heat treatment processes
US7677314B2 (en) 2006-10-20 2010-03-16 Shell Oil Company Method of condensing vaporized water in situ to treat tar sands formations
US7730947B2 (en) 2006-10-20 2010-06-08 Shell Oil Company Creating fluid injectivity in tar sands formations
US20080277113A1 (en) * 2006-10-20 2008-11-13 George Leo Stegemeier Heating tar sands formations while controlling pressure
US20090014180A1 (en) * 2006-10-20 2009-01-15 George Leo Stegemeier Moving hydrocarbons through portions of tar sands formations with a fluid
WO2008051822A2 (en) * 2006-10-20 2008-05-02 Shell Oil Company Heating tar sands formations to visbreaking temperatures
US20090014181A1 (en) * 2006-10-20 2009-01-15 Vinegar Harold J Creating and maintaining a gas cap in tar sands formations
US7631690B2 (en) 2006-10-20 2009-12-15 Shell Oil Company Heating hydrocarbon containing formations in a spiral startup staged sequence
US7635024B2 (en) 2006-10-20 2009-12-22 Shell Oil Company Heating tar sands formations to visbreaking temperatures
WO2008051495A3 (en) * 2006-10-20 2008-10-30 Shell Oil Co Systems and processes for use in treating subsurface formations
WO2008051822A3 (en) * 2006-10-20 2008-10-30 Shell Oil Co Heating tar sands formations to visbreaking temperatures
US20080128134A1 (en) * 2006-10-20 2008-06-05 Ramesh Raju Mudunuri Producing drive fluid in situ in tar sands formations
GB2461362A (en) * 2006-10-20 2010-01-06 Shell Int Research Systems and processes for use in treating subsurface formations
US7644765B2 (en) 2006-10-20 2010-01-12 Shell Oil Company Heating tar sands formations while controlling pressure
US20080217004A1 (en) * 2006-10-20 2008-09-11 De Rouffignac Eric Pierre Heating hydrocarbon containing formations in a checkerboard pattern staged process
US7673681B2 (en) 2006-10-20 2010-03-09 Shell Oil Company Treating tar sands formations with karsted zones
JP2010507738A (en) * 2006-10-20 2010-03-11 シエル・インターナシヨネイル・リサーチ・マーチヤツピイ・ベー・ウイ Heating the tar sand formation to a viscosity-reducing temperature
US7677310B2 (en) 2006-10-20 2010-03-16 Shell Oil Company Creating and maintaining a gas cap in tar sands formations
US20080135254A1 (en) * 2006-10-20 2008-06-12 Vinegar Harold J In situ heat treatment process utilizing a closed loop heating system
US7681647B2 (en) 2006-10-20 2010-03-23 Shell Oil Company Method of producing drive fluid in situ in tar sands formations
US20080135244A1 (en) * 2006-10-20 2008-06-12 David Scott Miller Heating hydrocarbon containing formations in a line drive staged process
US20080135253A1 (en) * 2006-10-20 2008-06-12 Vinegar Harold J Treating tar sands formations with karsted zones
US20080217003A1 (en) * 2006-10-20 2008-09-11 Myron Ira Kuhlman Gas injection to inhibit migration during an in situ heat treatment process
WO2008051495A2 (en) * 2006-10-20 2008-05-02 Shell Oil Company Systems and processes for use in treating subsurface formations
US7703513B2 (en) 2006-10-20 2010-04-27 Shell Oil Company Wax barrier for use with in situ processes for treating formations
US7562707B2 (en) 2006-10-20 2009-07-21 Shell Oil Company Heating hydrocarbon containing formations in a line drive staged process
US7540324B2 (en) 2006-10-20 2009-06-02 Shell Oil Company Heating hydrocarbon containing formations in a checkerboard pattern staged process
US8555971B2 (en) 2006-10-20 2013-10-15 Shell Oil Company Treating tar sands formations with dolomite
US8191630B2 (en) 2006-10-20 2012-06-05 Shell Oil Company Creating fluid injectivity in tar sands formations
US7717171B2 (en) 2006-10-20 2010-05-18 Shell Oil Company Moving hydrocarbons through portions of tar sands formations with a fluid
US7730945B2 (en) 2006-10-20 2010-06-08 Shell Oil Company Using geothermal energy to heat a portion of a formation for an in situ heat treatment process
US7730946B2 (en) 2006-10-20 2010-06-08 Shell Oil Company Treating tar sands formations with dolomite
US20080142217A1 (en) * 2006-10-20 2008-06-19 Roelof Pieterson Using geothermal energy to heat a portion of a formation for an in situ heat treatment process
US7845411B2 (en) 2006-10-20 2010-12-07 Shell Oil Company In situ heat treatment process utilizing a closed loop heating system
US7841401B2 (en) 2006-10-20 2010-11-30 Shell Oil Company Gas injection to inhibit migration during an in situ heat treatment process
US20080185147A1 (en) * 2006-10-20 2008-08-07 Vinegar Harold J Wax barrier for use with in situ processes for treating formations
US20080142216A1 (en) * 2006-10-20 2008-06-19 Vinegar Harold J Treating tar sands formations with dolomite
US20080217015A1 (en) * 2006-10-20 2008-09-11 Vinegar Harold J Heating hydrocarbon containing formations in a spiral startup staged sequence
US20090095480A1 (en) * 2007-04-20 2009-04-16 Vinegar Harold J In situ heat treatment of a tar sands formation after drive process treatment
US20090120646A1 (en) * 2007-04-20 2009-05-14 Dong Sub Kim Electrically isolating insulated conductor heater
US20090095476A1 (en) * 2007-04-20 2009-04-16 Scott Vinh Nguyen Molten salt as a heat transfer fluid for heating a subsurface formation
US7841425B2 (en) 2007-04-20 2010-11-30 Shell Oil Company Drilling subsurface wellbores with cutting structures
US7931086B2 (en) 2007-04-20 2011-04-26 Shell Oil Company Heating systems for heating subsurface formations
US7841408B2 (en) 2007-04-20 2010-11-30 Shell Oil Company In situ heat treatment from multiple layers of a tar sands formation
US20090126929A1 (en) * 2007-04-20 2009-05-21 Vinegar Harold J Treating nahcolite containing formations and saline zones
US8662175B2 (en) 2007-04-20 2014-03-04 Shell Oil Company Varying properties of in situ heat treatment of a tar sands formation based on assessed viscosities
US20090090509A1 (en) * 2007-04-20 2009-04-09 Vinegar Harold J In situ recovery from residually heated sections in a hydrocarbon containing formation
US20090078461A1 (en) * 2007-04-20 2009-03-26 Arthur James Mansure Drilling subsurface wellbores with cutting structures
US9181780B2 (en) 2007-04-20 2015-11-10 Shell Oil Company Controlling and assessing pressure conditions during treatment of tar sands formations
US20090095479A1 (en) * 2007-04-20 2009-04-16 John Michael Karanikas Production from multiple zones of a tar sands formation
US7832484B2 (en) 2007-04-20 2010-11-16 Shell Oil Company Molten salt as a heat transfer fluid for heating a subsurface formation
US7798220B2 (en) 2007-04-20 2010-09-21 Shell Oil Company In situ heat treatment of a tar sands formation after drive process treatment
US7849922B2 (en) 2007-04-20 2010-12-14 Shell Oil Company In situ recovery from residually heated sections in a hydrocarbon containing formation
US8327681B2 (en) 2007-04-20 2012-12-11 Shell Oil Company Wellbore manufacturing processes for in situ heat treatment processes
US7950453B2 (en) 2007-04-20 2011-05-31 Shell Oil Company Downhole burner systems and methods for heating subsurface formations
US20090071652A1 (en) * 2007-04-20 2009-03-19 Vinegar Harold J In situ heat treatment from multiple layers of a tar sands formation
US8381815B2 (en) 2007-04-20 2013-02-26 Shell Oil Company Production from multiple zones of a tar sands formation
US20090321075A1 (en) * 2007-04-20 2009-12-31 Christopher Kelvin Harris Parallel heater system for subsurface formations
US8042610B2 (en) 2007-04-20 2011-10-25 Shell Oil Company Parallel heater system for subsurface formations
US8791396B2 (en) 2007-04-20 2014-07-29 Shell Oil Company Floating insulated conductors for heating subsurface formations
US20090095477A1 (en) * 2007-04-20 2009-04-16 Scott Vinh Nguyen Heating systems for heating subsurface formations
US8459359B2 (en) 2007-04-20 2013-06-11 Shell Oil Company Treating nahcolite containing formations and saline zones
US20090084547A1 (en) * 2007-04-20 2009-04-02 Walter Farman Farmayan Downhole burner systems and methods for heating subsurface formations
US20090194329A1 (en) * 2007-10-19 2009-08-06 Rosalvina Ramona Guimerans Methods for forming wellbores in heated formations
US8146669B2 (en) 2007-10-19 2012-04-03 Shell Oil Company Multi-step heater deployment in a subsurface formation
US8146661B2 (en) 2007-10-19 2012-04-03 Shell Oil Company Cryogenic treatment of gas
US8113272B2 (en) 2007-10-19 2012-02-14 Shell Oil Company Three-phase heaters with common overburden sections for heating subsurface formations
US8162059B2 (en) 2007-10-19 2012-04-24 Shell Oil Company Induction heaters used to heat subsurface formations
US8011451B2 (en) 2007-10-19 2011-09-06 Shell Oil Company Ranging methods for developing wellbores in subsurface formations
US7866386B2 (en) 2007-10-19 2011-01-11 Shell Oil Company In situ oxidation of subsurface formations
US7866388B2 (en) 2007-10-19 2011-01-11 Shell Oil Company High temperature methods for forming oxidizer fuel
US8536497B2 (en) 2007-10-19 2013-09-17 Shell Oil Company Methods for forming long subsurface heaters
US8196658B2 (en) 2007-10-19 2012-06-12 Shell Oil Company Irregular spacing of heat sources for treating hydrocarbon containing formations
US20090189617A1 (en) * 2007-10-19 2009-07-30 David Burns Continuous subsurface heater temperature measurement
US20090194282A1 (en) * 2007-10-19 2009-08-06 Gary Lee Beer In situ oxidation of subsurface formations
US8272455B2 (en) 2007-10-19 2012-09-25 Shell Oil Company Methods for forming wellbores in heated formations
US20090194524A1 (en) * 2007-10-19 2009-08-06 Dong Sub Kim Methods for forming long subsurface heaters
US20090194269A1 (en) * 2007-10-19 2009-08-06 Vinegar Harold J Three-phase heaters with common overburden sections for heating subsurface formations
US20090200031A1 (en) * 2007-10-19 2009-08-13 David Scott Miller Irregular spacing of heat sources for treating hydrocarbon containing formations
US20090200854A1 (en) * 2007-10-19 2009-08-13 Vinegar Harold J Solution mining and in situ treatment of nahcolite beds
US20090200025A1 (en) * 2007-10-19 2009-08-13 Jose Luis Bravo High temperature methods for forming oxidizer fuel
US8240774B2 (en) 2007-10-19 2012-08-14 Shell Oil Company Solution mining and in situ treatment of nahcolite beds
US8276661B2 (en) 2007-10-19 2012-10-02 Shell Oil Company Heating subsurface formations by oxidizing fuel on a fuel carrier
US20090260823A1 (en) * 2008-04-18 2009-10-22 Robert George Prince-Wright Mines and tunnels for use in treating subsurface hydrocarbon containing formations
US8162405B2 (en) 2008-04-18 2012-04-24 Shell Oil Company Using tunnels for treating subsurface hydrocarbon containing formations
US9528322B2 (en) 2008-04-18 2016-12-27 Shell Oil Company Dual motor systems and non-rotating sensors for use in developing wellbores in subsurface formations
US20090260824A1 (en) * 2008-04-18 2009-10-22 David Booth Burns Hydrocarbon production from mines and tunnels used in treating subsurface hydrocarbon containing formations
US20090272535A1 (en) * 2008-04-18 2009-11-05 David Booth Burns Using tunnels for treating subsurface hydrocarbon containing formations
US20090272533A1 (en) * 2008-04-18 2009-11-05 David Booth Burns Heated fluid flow in mines and tunnels used in heating subsurface hydrocarbon containing formations
US20090272578A1 (en) * 2008-04-18 2009-11-05 Macdonald Duncan Charles Dual motor systems and non-rotating sensors for use in developing wellbores in subsurface formations
US8752904B2 (en) 2008-04-18 2014-06-17 Shell Oil Company Heated fluid flow in mines and tunnels used in heating subsurface hydrocarbon containing formations
US8636323B2 (en) 2008-04-18 2014-01-28 Shell Oil Company Mines and tunnels for use in treating subsurface hydrocarbon containing formations
US8177305B2 (en) 2008-04-18 2012-05-15 Shell Oil Company Heater connections in mines and tunnels for use in treating subsurface hydrocarbon containing formations
US8172335B2 (en) 2008-04-18 2012-05-08 Shell Oil Company Electrical current flow between tunnels for use in heating subsurface hydrocarbon containing formations
US8562078B2 (en) 2008-04-18 2013-10-22 Shell Oil Company Hydrocarbon production from mines and tunnels used in treating subsurface hydrocarbon containing formations
US8151907B2 (en) 2008-04-18 2012-04-10 Shell Oil Company Dual motor systems and non-rotating sensors for use in developing wellbores in subsurface formations
US9022118B2 (en) 2008-10-13 2015-05-05 Shell Oil Company Double insulated heaters for treating subsurface formations
US20100089586A1 (en) * 2008-10-13 2010-04-15 John Andrew Stanecki Movable heaters for treating subsurface hydrocarbon containing formations
US20100108310A1 (en) * 2008-10-13 2010-05-06 Thomas David Fowler Offset barrier wells in subsurface formations
US20100108379A1 (en) * 2008-10-13 2010-05-06 David Alston Edbury Systems and methods of forming subsurface wellbores
US8256512B2 (en) 2008-10-13 2012-09-04 Shell Oil Company Movable heaters for treating subsurface hydrocarbon containing formations
US20100101784A1 (en) * 2008-10-13 2010-04-29 Vinegar Harold J Controlling hydrogen pressure in self-regulating nuclear reactors used to treat a subsurface formation
US20100101783A1 (en) * 2008-10-13 2010-04-29 Vinegar Harold J Using self-regulating nuclear reactors in treating a subsurface formation
US20100096137A1 (en) * 2008-10-13 2010-04-22 Scott Vinh Nguyen Circulated heated transfer fluid heating of subsurface hydrocarbon formations
US20100089584A1 (en) * 2008-10-13 2010-04-15 David Booth Burns Double insulated heaters for treating subsurface formations
US8267170B2 (en) 2008-10-13 2012-09-18 Shell Oil Company Offset barrier wells in subsurface formations
US8353347B2 (en) 2008-10-13 2013-01-15 Shell Oil Company Deployment of insulated conductors for treating subsurface formations
US8881806B2 (en) 2008-10-13 2014-11-11 Shell Oil Company Systems and methods for treating a subsurface formation with electrical conductors
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US9127538B2 (en) 2010-04-09 2015-09-08 Shell Oil Company Methodologies for treatment of hydrocarbon formations using staged pyrolyzation
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US10047594B2 (en) 2012-01-23 2018-08-14 Genie Ip B.V. Heater pattern for in situ thermal processing of a subsurface hydrocarbon containing formation

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