US3211618A - Base for cosmetics - Google Patents

Base for cosmetics Download PDF

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Publication number
US3211618A
US3211618A US119270A US11927061A US3211618A US 3211618 A US3211618 A US 3211618A US 119270 A US119270 A US 119270A US 11927061 A US11927061 A US 11927061A US 3211618 A US3211618 A US 3211618A
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United States
Prior art keywords
base
oil
wax
cosmetics
weight
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Expired - Lifetime
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US119270A
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Kambersky Helene
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Classifications

    • AHUMAN NECESSITIES
    • A61MEDICAL OR VETERINARY SCIENCE; HYGIENE
    • A61KPREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
    • A61K8/00Cosmetics or similar toiletry preparations
    • A61K8/18Cosmetics or similar toiletry preparations characterised by the composition
    • A61K8/92Oils, fats or waxes; Derivatives thereof, e.g. hydrogenation products thereof
    • A61K8/927Oils, fats or waxes; Derivatives thereof, e.g. hydrogenation products thereof of insects, e.g. shellac
    • AHUMAN NECESSITIES
    • A61MEDICAL OR VETERINARY SCIENCE; HYGIENE
    • A61KPREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
    • A61K8/00Cosmetics or similar toiletry preparations
    • A61K8/02Cosmetics or similar toiletry preparations characterised by special physical form
    • A61K8/04Dispersions; Emulsions
    • A61K8/06Emulsions
    • AHUMAN NECESSITIES
    • A61MEDICAL OR VETERINARY SCIENCE; HYGIENE
    • A61KPREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
    • A61K8/00Cosmetics or similar toiletry preparations
    • A61K8/18Cosmetics or similar toiletry preparations characterised by the composition
    • A61K8/30Cosmetics or similar toiletry preparations characterised by the composition containing organic compounds
    • A61K8/31Hydrocarbons
    • AHUMAN NECESSITIES
    • A61MEDICAL OR VETERINARY SCIENCE; HYGIENE
    • A61QSPECIFIC USE OF COSMETICS OR SIMILAR TOILETRY PREPARATIONS
    • A61Q1/00Make-up preparations; Body powders; Preparations for removing make-up
    • A61Q1/02Preparations containing skin colorants, e.g. pigments
    • A61Q1/10Preparations containing skin colorants, e.g. pigments for eyes, e.g. eyeliner, mascara

Definitions

  • Austrian patent specification No. 142,033 it is known from Austrian patent specification No. 142,033 to use aqueous wax emulsions containing a volatile oil, such as turpentine, for such cosmetics.
  • a volatile oil such as turpentine
  • Austrian Patent No. 159,218 it is proposed to add a volatile constituent consisting of an ester of a volatile acid, e.g., formic acid ester.
  • an excellent base for cosmetics can be obtained on the basis of aqueous wax emulsions if the previously used turpentine is replaced by a mixture of linear parafiins of highest purity and free of aromatics, particularly of isoparaifins having a boiling range between about 160 C. and about 200 C.
  • a mixture which has proved particularly suitable comprises isoparafiins of highest purity, having a boiling range of about 180 C. and about 190 C, which can be obtained by catalytic processes from cracked gases and other low-boiling petroleum hydrocarbons and is available, e.g., under the trade name Shellsol-T.
  • the paraffins provided according to the invention together with an emulsifier, the desired pigments and perfumes and, 1f desired, a substance acting as an odor carrier, such as terpmeol, give a homogeneous emulsion of excellent quality.
  • Suitable emulsifiers include, above all, mixtures of higher fatty alcohols and/or fatty alcohol sulfonates, such as the products known under the trade name Lanette Wax.
  • the base for cosmetics according to the invention contains preferably about 10-60% parafiins, depending on the desired consistency of the cosmetic. Owing to the ease with which these parafiins can be emulsified, and because of their odorlessness and harmlessness, the paraf' fins may be used in such large quantities that it is possible, as contrasted with the use of turpentine, to make a cosmetic, e.g., a mascara, in semiliqu-id form. Such a cosmetic has the advantage that it can be applied easily and in a very thin layer.
  • the base for cosmetics according to the invention may desirably contain small additions of a drying oil and/ or a fatty oil.
  • a drying oil such as linseed oil
  • the fatty oil such as castor oil, improves the suppleness and supplies a nutritive substance to the skin.
  • Example 1 Percent by weight Beeswax 20 Shellsol-T (isoparaflin mixture boiling point between C. and about C.) 60 Castor oil 2 Lanette Wax 5 Water 13
  • Example 2 Beeswax 30 Shellsol-T 12 Castor oil 8 Lanette Wax N 10 Water 40
  • Example 3 Beeswax 25 Shellsol-T 30 Lanette Wax N 10 Water 3 5
  • Example 4 Beeswax 26 Shellsol-T "30 Castor oil 5 Linseed oil 4 Lanette Wax N 10 Water 25 I claim:
  • a base for a mascara comprising an aqueous emulsion containing, by weight, about 20-30% wax, about lO-60% of a mixture of linear paraffins substantially free of aromatics, which mixture has a boiling range between about 160 C. and about 200 C., about 5-10% of an ern-ulsifier selected from the class consisting of higher fatty alcohols, higher fatty alcohol sulfonates and mixtures thereof, and about 10-40% water.
  • a base as claimed in claim 1 which contains up to 5 percent by weight of a drying oil.
  • a base as claimed in claim 1 which contains up to 10 percent by weight of a fatty oil.
  • a base as claimed in claim 1 which contains up to percent by weight of a drying oil and up to percent by weight of a fatty oil.
  • a base as claimed in claim 1 which contains up to 5 percent by weight linseed oil and up to 10 percent by weight castor oil.

Description

United States Patent Ofiice 3,211,618 Patented Oct. 12, 1965 3,211,618 BASE F OR COSMETICS Helene Kambersky, Hegelgasse 6, Vienna, Austria No Drawing. Filed June 26, 1961, Ser. No. 119,270 Claims priority, application Austria, July 8, 1960, A 5,282/60 Claims. (Cl. 167-85) This invention relates to a base for a cosmetic, particularly a cosmetic for eyelashes and eyebrows.
It is known from Austrian patent specification No. 142,033 to use aqueous wax emulsions containing a volatile oil, such as turpentine, for such cosmetics. In Austrian Patent No. 159,218 it is proposed to add a volatile constituent consisting of an ester of a volatile acid, e.g., formic acid ester.
Whereas these cosmetics have good adherence because the volatile substances evaporate soon after application to leave a fine water-insoluble film, the turpentine content of about 50%, which was required, involved the disadvantage that the turpentine in such high concentration had a strong odor and was not tolerable by sensitive persons owing to its known irritating effect on the skin. In Austrian patent specification No. 188,854 it was proposed to add a drying oil, such as linseed oil, and a fatty oil, such as castor oil, to an aqueous emulsion of wax and turpentine. This enables a reduction of the content of turpentine to less than one half of the amount previously required without reducing the suppleness and adherence of the cosmetic. Nevertheless, the odor and sometimes also the irritating effect of turpentine was still a disadvantage when the same was used even in smaller amounts.
It has now been found that an excellent base for cosmetics, particularly for mascara and eyebrow paint, can be obtained on the basis of aqueous wax emulsions if the previously used turpentine is replaced by a mixture of linear parafiins of highest purity and free of aromatics, particularly of isoparaifins having a boiling range between about 160 C. and about 200 C. A mixture which has proved particularly suitable comprises isoparafiins of highest purity, having a boiling range of about 180 C. and about 190 C, which can be obtained by catalytic processes from cracked gases and other low-boiling petroleum hydrocarbons and is available, e.g., under the trade name Shellsol-T.
These products consist of a colorless, highly fluid, oily liquid which is odorless and chemically inert. They are distinguished from turpentine by having a beneficial ef fect on the skin. There is no irritation experienced whatever. When a cosmetic prepared with these products has been applied, e.g., to the eyelashes, moreover the cosmetics will dry within a few minutes to form a nonsmearing, firmly adhering, moisture-resisting film.
It has been found that when the components of the cosmetic are emulsified in the usual manner, the paraffins provided according to the invention together with an emulsifier, the desired pigments and perfumes and, 1f desired, a substance acting as an odor carrier, such as terpmeol, give a homogeneous emulsion of excellent quality. Suitable emulsifiers include, above all, mixtures of higher fatty alcohols and/or fatty alcohol sulfonates, such as the products known under the trade name Lanette Wax.
The base for cosmetics according to the invention contains preferably about 10-60% parafiins, depending on the desired consistency of the cosmetic. Owing to the ease with which these parafiins can be emulsified, and because of their odorlessness and harmlessness, the paraf' fins may be used in such large quantities that it is possible, as contrasted with the use of turpentine, to make a cosmetic, e.g., a mascara, in semiliqu-id form. Such a cosmetic has the advantage that it can be applied easily and in a very thin layer. Besides, it is more economical in consumption than the previous, thicker emulsions, which adhere to the tube walls so that when the contents of the tube are gradually consumed, part of it always remains in the tube without utilization, whereas the more fluid product can easily be squeezed out of the tube and be entirely removed therefrom.
The base for cosmetics according to the invention may desirably contain small additions of a drying oil and/ or a fatty oil. The presence of a drying oil, such as linseed oil, promotes a rapid drying of the cosmetic on the surface to which it is applied and prevents a subsequent smearing or sticking together of eyelash hairs. The fatty oil, such as castor oil, improves the suppleness and supplies a nutritive substance to the skin.
The quantitative proportions of the components may lie Within the following limits:
Percent by weight Wax (beeswax, ceresine or the like) 20-30 Paraffin mixture 10-60 Emulsifier (such as Lanetta Wax N) 5-10 Water 10-40 Drying oil, such as linseed oil 0-5 Fatty oil, such as castor oil 0-8 In the following examples, specific compositions of the base for cosmetics according to the invention are disclosed, whereas the invention is not restricted thereto.
Example 1 Percent by weight Beeswax 20 Shellsol-T (isoparaflin mixture boiling point between C. and about C.) 60 Castor oil 2 Lanette Wax 5 Water 13 Example 2 Beeswax 30 Shellsol-T 12 Castor oil 8 Lanette Wax N 10 Water 40 Example 3 Beeswax 25 Shellsol-T 30 Lanette Wax N 10 Water 3 5 Example 4 Beeswax 26 Shellsol-T "30 Castor oil 5 Linseed oil 4 Lanette Wax N 10 Water 25 I claim:
1. A base for a mascara, comprising an aqueous emulsion containing, by weight, about 20-30% wax, about lO-60% of a mixture of linear paraffins substantially free of aromatics, which mixture has a boiling range between about 160 C. and about 200 C., about 5-10% of an ern-ulsifier selected from the class consisting of higher fatty alcohols, higher fatty alcohol sulfonates and mixtures thereof, and about 10-40% water.
2. A base as claimed in claim 1, which contains up to 5 percent by weight of a drying oil.
3. A base as claimed in claim 1, which contains up to 10 percent by weight of a fatty oil.
4. A base as claimed in claim 1, which contains up to percent by weight of a drying oil and up to percent by weight of a fatty oil.
5. A base as claimed in claim 1, in which said Wax comprises beeswax.
6. A base as claimed in claim 1, which contains up to 5 percent by weight of linseed oil.
7. A base as claimed in claim 1, which contains up to 10 percent by weight of castor oil.
8. A base as claimed in claim 1, which contains up to 5 percent by weight linseed oil and up to 10 percent by weight castor oil.
9. A base as claimed in claim 1, which said mixture consists of isoparaffins.
10. A base as claimed in claim 9, in which said mixture has a boiling range between about C. and about C.
4- References Cited by the Examiner UNITED STATES PATENTS 5 FOREIGN PATENTS 208,806 6/57 Australia.
OTHER REFERENCES Bennett, Commercial Waxes, Chem. Pub. Co., New York, 1956, pp. 509, 537, 604, 611.
Shellsol T, Shell Oil Co., New York, booklet pp. 1-3, February 1961.
Zimmerman et al., Handbook of Material Trade Names 15 Industrial Research Service, Dover, N.H., Supp. 1 to 1950 Ed. (1956), pp. 213 214.
JULIAN S. LEVITT, Primary Examiner.
MORRIS O. WOLK, LEWIS GOTTS, Examiners.

Claims (1)

1. A BASE FOR A MASCARA, COMPRISING AN AQUEOUS EMULSION CONTAINING, BY WEIGHT, ABOUT 20-30% WAX, ABOUT 10-60% OF A MIXTURE OF LINEAR PARAFFINS SUBSTANTIALLY FREE OF AROMATICS, WHICH MIXTURE HAS A BOILING RANGE BETWEEN ABOUT 160*C. AND ABOUT 200*C., ABOUT 5-10% OF AN EMULSIFIER SELECTED FROM THE CLASS CONSISTING OF HIGHER FATTY ALCOHOLS, HIGHER FATTY ALCOHOL SULFONATES AND MIXTURES THEREOF, AND ABOUT 10-40% WATER.
US119270A 1960-07-08 1961-06-26 Base for cosmetics Expired - Lifetime US3211618A (en)

Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
AT528260A AT217639B (en) 1960-07-08 1960-07-08 Basis for make-up

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US3211618A true US3211618A (en) 1965-10-12

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US (1) US3211618A (en)
AT (1) AT217639B (en)
BE (1) BE605774A (en)
CH (1) CH404087A (en)
DE (1) DE1134797B (en)
GB (1) GB926862A (en)
NL (1) NL266499A (en)

Cited By (15)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US3439088A (en) * 1964-06-16 1969-04-15 Exxon Research Engineering Co Cosmetic preparations-wax rouge and foundation make-up
JPS50125044A (en) * 1974-03-19 1975-10-01
US4117110A (en) * 1974-03-18 1978-09-26 Globol Werk Gmbh Solid air-improving composition
US4124720A (en) * 1970-11-09 1978-11-07 Wenmaekers Georges E J Therapeutic hydrodispersible emulsion
US4165385A (en) * 1973-05-29 1979-08-21 Dianis Creations, Inc. Water-in-oil emulsion for skin moisturizing
JPS5520733A (en) * 1978-08-01 1980-02-14 Shiseido Co Ltd Cosmetic
US4229432A (en) * 1978-04-19 1980-10-21 Bristol-Myers Company Antiperspirant stick composition
US4383875A (en) * 1981-08-26 1983-05-17 Plough, Inc. Method for making cosmetic pencils
US4537766A (en) * 1983-02-02 1985-08-27 Plough, Inc. Long-wearing eyeshadow compositions
US4545983A (en) * 1981-08-26 1985-10-08 Plough, Inc. Method for making cosmetic pencils
WO2002036092A2 (en) * 2000-11-04 2002-05-10 Michael Petry Mixture for treating skin
FR2949970A1 (en) * 2009-09-15 2011-03-18 Oreal USE OF A SICCATIVE OIL FOR PROTECTING THE COLOR FROM THE WASHING OF KERATINIC FIBERS ARTIFICIALLY DYED; COLORING PROCESSES
WO2011116283A3 (en) * 2010-03-19 2013-01-10 Kao Corporation Hair care products containing conjugated unsaturated oils
US20150366783A1 (en) * 2012-06-21 2015-12-24 L'oreal Cosmetic composition comprising hydrophobic silica aerogel particles, a wax, a hydrocarbon oil and a fatty alcohol and/or a fatty acid
US10813867B2 (en) 2012-06-21 2020-10-27 L'oreal Cosmetic composition comprising an aequeous dispersion of hydrophobic silica aerogel particles and a particular alcohol

Families Citing this family (5)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
GB1579935A (en) * 1976-12-09 1980-11-26 Beecham Group Ltd Cosmetic products for treating the skin
DE3441587A1 (en) * 1984-11-14 1986-05-22 Henkel KGaA, 4000 Düsseldorf Evaporation-inhibiting additive for plant protection agent spray liquors
DE3507380A1 (en) * 1985-03-02 1986-09-04 Henkel KGaA, 4000 Düsseldorf ANTI-EVAPORATING AGENTS
PL255501A1 (en) * 1984-11-14 1987-06-01 Henkel Kgaa Water evaporation retarding additive and method of obtaining the same
JP2503303B2 (en) * 1990-11-20 1996-06-05 三菱鉛筆株式会社 Oil-based batting pen type eye liner-cosmetics

Citations (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US2566716A (en) * 1951-09-04 Combined cleaning and polishing

Patent Citations (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US2566716A (en) * 1951-09-04 Combined cleaning and polishing

Cited By (23)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US3439088A (en) * 1964-06-16 1969-04-15 Exxon Research Engineering Co Cosmetic preparations-wax rouge and foundation make-up
US4124720A (en) * 1970-11-09 1978-11-07 Wenmaekers Georges E J Therapeutic hydrodispersible emulsion
US4165385A (en) * 1973-05-29 1979-08-21 Dianis Creations, Inc. Water-in-oil emulsion for skin moisturizing
US4117110A (en) * 1974-03-18 1978-09-26 Globol Werk Gmbh Solid air-improving composition
JPS50125044A (en) * 1974-03-19 1975-10-01
JPS5227695B2 (en) * 1974-03-19 1977-07-21
US4229432A (en) * 1978-04-19 1980-10-21 Bristol-Myers Company Antiperspirant stick composition
JPS5520733A (en) * 1978-08-01 1980-02-14 Shiseido Co Ltd Cosmetic
US4545983A (en) * 1981-08-26 1985-10-08 Plough, Inc. Method for making cosmetic pencils
US4383875A (en) * 1981-08-26 1983-05-17 Plough, Inc. Method for making cosmetic pencils
US4537766A (en) * 1983-02-02 1985-08-27 Plough, Inc. Long-wearing eyeshadow compositions
WO2002036092A2 (en) * 2000-11-04 2002-05-10 Michael Petry Mixture for treating skin
WO2002036092A3 (en) * 2000-11-04 2002-07-25 Michael Petry Mixture for treating skin
EP2363110A1 (en) * 2009-09-15 2011-09-07 L'Oréal Use of drying oils for protecting the color of artificially colored keratin fibers against washing; method for coloring hair
CN102018636A (en) * 2009-09-15 2011-04-20 莱雅公司 Usage of drying oil for wash-protecting the color of artificially dyed keratin fibers
FR2949970A1 (en) * 2009-09-15 2011-03-18 Oreal USE OF A SICCATIVE OIL FOR PROTECTING THE COLOR FROM THE WASHING OF KERATINIC FIBERS ARTIFICIALLY DYED; COLORING PROCESSES
US8088174B2 (en) 2009-09-15 2012-01-03 L'oreal S.A. Method for wash-protecting the color of artificially dyed keratin fibers
CN102018636B (en) * 2009-09-15 2012-12-26 莱雅公司 Usage of drying oil for wash-protecting the color of artificially dyed keratin fibers
WO2011116283A3 (en) * 2010-03-19 2013-01-10 Kao Corporation Hair care products containing conjugated unsaturated oils
AU2011227080B2 (en) * 2010-03-19 2014-10-02 Kao Corporation Hair care products containing conjugated unsaturated oils
US20150366783A1 (en) * 2012-06-21 2015-12-24 L'oreal Cosmetic composition comprising hydrophobic silica aerogel particles, a wax, a hydrocarbon oil and a fatty alcohol and/or a fatty acid
US10588850B2 (en) * 2012-06-21 2020-03-17 L'oreal Cosmetic composition comprising hydrophobic silica aerogel particles, a wax, a hydrocarbon oil and a fatty alcohol and/or a fatty acid
US10813867B2 (en) 2012-06-21 2020-10-27 L'oreal Cosmetic composition comprising an aequeous dispersion of hydrophobic silica aerogel particles and a particular alcohol

Also Published As

Publication number Publication date
NL266499A (en)
BE605774A (en) 1961-11-03
DE1134797B (en) 1962-08-16
AT217639B (en) 1961-10-10
GB926862A (en) 1963-05-22
CH404087A (en) 1965-12-15

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