US3220409A - Face mask - Google Patents
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- US3220409A US3220409A US98903A US9890361A US3220409A US 3220409 A US3220409 A US 3220409A US 98903 A US98903 A US 98903A US 9890361 A US9890361 A US 9890361A US 3220409 A US3220409 A US 3220409A
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- mask
- fibers
- nose
- air
- bridge
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- A—HUMAN NECESSITIES
- A41—WEARING APPAREL
- A41D—OUTERWEAR; PROTECTIVE GARMENTS; ACCESSORIES
- A41D13/00—Professional, industrial or sporting protective garments, e.g. surgeons' gowns or garments protecting against blows or punches
- A41D13/05—Professional, industrial or sporting protective garments, e.g. surgeons' gowns or garments protecting against blows or punches protecting only a particular body part
- A41D13/11—Protective face masks, e.g. for surgical use, or for use in foul atmospheres
- A41D13/1107—Protective face masks, e.g. for surgical use, or for use in foul atmospheres characterised by their shape
- A41D13/1138—Protective face masks, e.g. for surgical use, or for use in foul atmospheres characterised by their shape with a cup configuration
- A41D13/1146—Protective face masks, e.g. for surgical use, or for use in foul atmospheres characterised by their shape with a cup configuration obtained by moulding
Definitions
- the present invention relates to face masks and more particularly to face masks having a high filter eificiency but which nevertheless can be manufactured at sufiiciently low cost to permit disposal of the mask after having been worn but once.
- Face masks of the present invention are particularly useful as surgical masks where the mask is to be used but a single time and then discarded.
- surgery it is the practice of the surgeon, attending nurses and others who are working with the patient to wear masks covering the nose and mouth to prevent or reduce, insofar as possible, infection of the patient or the wearer through air-borne bacteria.
- gauze masks which may take different forms and which are usually in the form of a gauze strip of several ply. The gauze mask is tied so as to cover the nose and mouth of wearer.
- gauze masks are sterilized in the hospital autoclave or other sterilizing equipment which the hospital may have and, when placed on the face prior to the operation, are supposedly in a sterile state. These gauze masks are relatively expensive and are used repeatedly by the hospital because of their cost, being washed and sterilized between each use.
- FIG. 1 is a persepective view of a mask made in ac cordance with the present invention
- FIG. 2 is a top view of the mask of FIG. 1;
- FIG. 3 is a view taken along line 33 of FIG. 2;
- FIG. 4 is an illustrative view showing the mask illustrated by FIGS. 1-3 as worn by a subject;
- FIG. 5 is a mask with flutes extending over the cupped portion of the mask from top to bottom;
- FIG. 6 is a mask with reinforcing ribs but without flutes.
- the mask as illustrated in FIGS. 14 has an upper por tion 10 which is adapted to fit over the nose bridge of the wearer and a lower portion 11 which is adapted to fit around the wearers chin.
- the upper portion 10 is formed estates Patented Nov. 3Q, 1965 with a ridge section 12 which coincides with the top of the bridge of a wearers nose and indented side sections 13 which are adapted to fit along either side of the nose bridge just above the nostrils to give a snug fit.
- the rim portion 14 extends around the periphery of the mask and has its outer edge 15, which is adapted to contact the wearers face, formed with a slight radius to provide good contact with the wearers face without causing irritation which would occur if there were sharp edges.
- This curved edge extends around the periphery of the mask and also preferably extends as a U-shaped channel 17 along the base of the mask near the tab sections 16 to which attaching strings 13 would be secured. Through the use of this curved edge, a good seal can be obtained between the mask and the face of a wearer so that there is no leakage of inhaled and exhaled air around the edge of the mask with the result the air passes through the mask and is filtered.
- the main body 19 of the mask is cupped out from the rim and is the portion of the mask designed to filter the exhaled and inhaled air.
- this portion of the mask is preferably formed with flutes 20 having peaks 21 and valleys 22.
- these flutes extend crosswise of the mask and decrease in size as they approach the sides of the mask.
- the flutes are further formed so that they tend to spread out near the center portion of the mask and come together near the edges of the same.
- the mask is formed of fibers which are molded together in the shape shown. These fibers may initially be in the form of a fiber batt or sheet which is placed between the dies for molding the mask, or the fibers may be floated down on top of one-half of the die before the second half of the die is placed thereon and the mask molded.
- the fibers have intermixed therewith a thermoplastic material which, in the preferred construction, is in the form of thermoplastic fibers which are blended together with the non-thermoplastic fibers to form the fiber body which is molded into the mask.
- the fibers are tightly compacted or compressed in the nose area 10, along the valleys 22 of the flutes, and in the rim area 14.
- the turned edge 15 and flanges 16 are also formed of tightly compacted fibers. This higher compression of the fibers in the areas indicated, with resulting greater compacting of the same, makes these particular areas stronger and somewhat more rigid than the areas in which the fibers have not been as tightly compacted, thus forming a strong resilient frame surrounding an area of fibers which are compacted to a substantially less degree.
- the degree of compacting substantially affects the resistance to air flow. Accordingly, a substantially lower resistance to air flow is obtained in these relatively lightly compacted areas.
- the mask of FIG. 5 differs primarily from the mask of FIGS. 14 in that the flutes 20' extend lengthwise of the mask rather than across the same.
- the valleys of the flutes 20 of the mask of FIG. 5 are compressed to a substantially greater degree than the ridges in a manner similar to that described in connection with the flutes 20 of the mask of FIGS. 1-4 so as to obtain the added structural strength which these relatively tightly compacted areas provide.
- the valleys of the flutes are more tightly compacted than the ridges
- the fibers along the ridges could, if desired, be compacted to a greater degree than those in the valleys in which case the strengthening structural ribs would extend along the ridges of the flutes while the valley areas would act primarily to filter the air.
- these structural ribs of more tightly compressed fibers extend along the valleys of the flutes, as illustrated in FIGS. 1-5.
- the mask of FIG. 6 differs from the mask of FIGS. 1-4 and the mask of FIG. 5 primarily in that it contains no flutes. Also, the structural ribs 23 of tightly compacted fibers are spaced equally from each other throughout their entire length as they extend across the cupped portion of the mask.
- the areas of greater compression in the mask are obtained by so forming the dies that there is substantially less clearance between the dies in the areas where greater compression is to be obtained.
- a mixture of non-thermoplastic and thermoplastic fibers are used. Synthetic fibers are preferably used as the nonthermoplastic fibers because of the uniformity in length and denier that can be obtained, viscose rayon fibers being preferred. However, other non-thermoplastic fibers, such as cotton and other natural fibers, may be used in place of the rayon fibers if desired. Any thermoplastic fiber may be used that would stand up under the temperatures to which the mask may be subjected during sterilization and storage.
- thermoplastic fibers generally preferred in practicin the present invention are those sold under the trade-name Vinyon, these fibers being formed of the copolymers of vinyl chloride and vinyl acetate. These Vinyon fibers generally melt at a temperature within the range of about 275 to 300 F., softening at a temperature of about 125 to 140 F., and becoming tacky at a temperature of about 185 to 215 F.
- a web is first formed of a mixture of Vinyon and rayon fibers having a denier of about 0.5 to 5.5, the Vinyon and rayon fibers varying in ratio from about by weight Vinyon fibers and 90% by weight rayon fibers to about 45% by weight Vinyon fibers and 55% by weight rayon fibers.
- the mask is then formed by placing the web of blended fibers within the die and compressing the same at a temperature sufficiently high to bond the thermoplastic fibers to the adjacent non-thermoplastic fibers.
- the die is so formed that the areas of the die in which the less compacted part of the mask is formed are spaced about 0.008 to 0.012
- the web of fibers is sub jected to an over-all die pressure of about 10 to 75 pounds per square inch, most of this pressure being placed around the rim, over the nose section, and along th ribs of the mask where the clearance between the two die members is substantially less than in the remaining part of the dies.
- the high filter efficiency for air-borne bacteria of the masks of the present invention and the low resistance to air flow is well illustrated by the following table which gives the bacteria filter efficiency and resistance to air flow of masks formed of the same weight of fibers, the only change being in the proportion of viscose rayon fibers to Vinyon fibers used.
- the fiber batt used in pre paring the masks has a weight of 7 .43 oz. per square yard and the fibers have a length of about 1.5 inches and a denier of 1.5.
- the masks each have an area of approx imately 27.83 square inches.
- Bacteria filtration efiiciency is evaluated in vitro using a standard bacteria aerosol.
- the air resistance is nieas' ured at an air flow through the masks of 85.5 liters of air per minute.
- the treatment with the polyvinyl alcohol has been found to stabilize the porosity of the mask under such sterilization conditions. Also, with masks containing from about and less Vinyon fibers where there is substantial handling of the mask, there is a tendency for the surface fibers to become flutfed with the possibility that some of the fibers may become detached. This is undesirable particularly under operating conditions in a hospital. .Also, the fluffed masks are substantially less comfortable to wear.
- the coating spray of polyvinyl alcohol has been found to bond together the surface fibers of the mask without having appreciable deleterious effect on the permeability of the mask so that the mask can be subjected to substantial handling without the surface fibers becoming loosened.
- the polyvinyl alcohol coating is preferably applied by spraying onto the molded mask a water solution containing up to 10% by weight of the polyvinyl alcohol.
- polyvinyl alcohol is preferably used, other resin binders which are not softened at normal sterilization temperatures and which will deposit at the junctures of fibers in minute globules, as opposed to a continuous film, may be used.
- resin binders which are not softened at normal sterilization temperatures and which will deposit at the junctures of fibers in minute globules, as opposed to a continuous film, may be used.
- materials that may be used for this purpose are, for example, methyl cellulose,
- hydroxy ethyl cellulose polyacrylates, polyamides, and polyesters.
- Example A batt of fibers comprising 25% Vinyon and 75% rayon uniformly blended is used.
- the fiber length of both the Vinyon and the rayon fibers is 1% inches and the fiber denier is 1.5.
- This batt has a thickness prior to molding of about /8 to inch and a weight of 5.14 ounces per square yard.
- the fiber batt is placed in a mold having a female and male member which when engaged without anything placed therebetween touch in areas where greatest fiber compression is to be applied and are separated about 0.01 inch in areas where the least fiber compression is to be applied.
- the fabric is placed between the molds and the molds pressed together for about 2.5 seconds with a pressure of 65 p..i., the molds being heated to a temperature of 290 to 300 F. while the fabric is therebetween.
- Sections of the mask as marked in FIG. 2, namely, sections 1, 2, 3, 4 and 5, are cut from the molded mask and tested for resis tance to air flow which varies directly with the degree of fiber compactness. These areas give resistances such as shown by the following table:
- fiber lengths may be used in preparing the masks of the present invention, it is generally preferred not to use fibers of less than inch because of the greater possibility of such fibers coming loose when the mask is in use.
- the masks of the present invention have been described as being particularly suitable for surgical use, the masks may be used in any application where a mask of high filter efiiciency and low air resistance is needed and are particularly suitable for use in those areas where inexpensive, disposable masks having high filter efliciencies are required.
- the invention is susceptible of many modifications Within its spirit and accordingly is to be limited only by the scope of the appended claims.
- a fiber mask comprising a raised cup shaped central portion adapted to fit over the mouth and nostrils of a wearer and having a relatively low resistance to the flow of air therethrough at air velocities comparable to those of normal breathing, a rim portion extending around said raised central portion and a nose-bridge-contacting portion, the fibers of said rim portion and nose-bridge-contact-ing portion being more densely compacted than the major portion of the fibers of said raised central portion and acting to strengthen said mask, said ri-m portion and nose-bridge-contacting portion being more resistant to the flow of air and structurally stronger than most of said raised central portion.
- An air permeable fiber mask having a raised, center portion adapted to fit over the mouth and nostrils of a wearer, ribs extending across said raised center portion and forming a part thereof, a nose-bridge-contacting portion and a rim portion extending around said mask and adjacent the outer edge ofthe same, the fibers forming said nose-bridge-contacting portion, rim portion and ribs being compacted to a substantially greater degree than the remainder of said mask and acting to strengthen the same, the center portion of said mask having substantially less resistance to air flow than said rim portion and said nosebridge portion.
- An air permeable mask of fibrous material comprising a raised central portion adapted to fit over the mouth and nostrils of a wearer and having a relatively low resistance to the flow of air therethrough at air velocities comparable to those of normal breathing, a rim portion, reinforcing ribs extending across said raised portion and forming a part of the same, and a nosebridge-contacting portion, the fibers of said rim portion, reinforcing ribs and nose-bridge-contacting portion being compressed to a substantially greater degree than the fibers of said mask in said raised portion between said rim portion, nose-bridge-contacting portion and ribs, the center portion of said mask having substantially less resistance to air flow than said rim portion and said nosebridge-contacting portion.
- a mask of claim 3 in which the outer edge of said mask has an outward radial turn and in which the fibers of said outer edge are compacted to a substantially greater degree than the fibers in said raised central portion between said ribs.
- a mask of fibrous material comprising a raised, central portion adapted to fit over the mouth and nostrils of a wearer, flutes extending across said raised portion and forming a part thereof, a rim portion and a nosebridge-contact-ing portion, the fibers in said rim portion, in said nose-bridge-contacting portion and in the valleys of said flutes being compressed to a substantially greater degree than the fibers of said mask in said raised portion between said rim portion, nose-bridge-contacting portion and flute valleys, the center portion of said mask having substantially less resistance to air flow than said center portion between said flute valleys.
- a mask of claim 5 in which said flutes merge together as they approach the rim of said mask and spread out as they approach the center of said raised portion.
- a mask of claim 8 wherein 55% to by weight of said mask is of non-thermoplastic fibers and the remainder of thermoplastic fibers.
- a mask of claim 10 wherein said non-thermoplastic fibers are viscose rayon fibers.
- An air permeable fiber mask having a raised, center portion adapted to fit over the mouth and nostrils of a wearer, ribs extending across said raised center portion and forming a part thereof, a nose-bridge-contacting portion and a rim portion extending around said mask and adjacent the outer edge of the same, the fibers forming said nose-bridge-contacting portion, rim portion and ribs being compacted to a substantially greater degree than '7 the remainder of said mask and acting to strengthen the same, the center portion of said mask having substantially less resistance to air flow than said rim portion and said nose-bridge portion, and the outer surface of said mask having an air permeable coating of polyvinyl alcohol.
Description
I Nov. 30, 1965 G. J. LILOIA ETAL 3,220,409
FACE MASK Filed March 28. 1961 2 Sheets-Sheet 1 INVENTORS. 62-76440 J Lao/,4 Mzz/A/ 5W0 ATTO R N EY Nov. 30, 1965 a. J. LILOIA ETAL FACE MASK 2 Sheets-Sheet 2 Filed March 28, 1961 l/ /I I l l/ INVENTORS: 352410 J [/4044 z/n/w 5mm 4 MAM,
ATTORNEY United States Patent C) corporation of New Jersey Filed Mar. 28, B61, Ser. No. 98,903 13 Claims. (Cl. 128146) The present invention relates to face masks and more particularly to face masks having a high filter eificiency but which nevertheless can be manufactured at sufiiciently low cost to permit disposal of the mask after having been worn but once.
Face masks of the present invention, although suitable generally for uses where high filter efiiciency is desired, are particularly useful as surgical masks where the mask is to be used but a single time and then discarded. In surgery, it is the practice of the surgeon, attending nurses and others who are working with the patient to wear masks covering the nose and mouth to prevent or reduce, insofar as possible, infection of the patient or the wearer through air-borne bacteria. It is common practice to use for this purpose gauze masks which may take different forms and which are usually in the form of a gauze strip of several ply. The gauze mask is tied so as to cover the nose and mouth of wearer. These gauze masks are sterilized in the hospital autoclave or other sterilizing equipment which the hospital may have and, when placed on the face prior to the operation, are supposedly in a sterile state. These gauze masks are relatively expensive and are used repeatedly by the hospital because of their cost, being washed and sterilized between each use.
It is accordingly an object of the present invention to prepare a mask which can be sterilized but which also can be manufactured at a relatively low cost while still having a high filter efiiciency. Since the possibility of respiratory type infections being transmitted to the patient is increased by wetting of the mask with saliva or mucous containing infectious organisms, it is a further object to form a mask which is maintained well away from the mouth and nostrils of the wearer and which is structurally stabilized so that it will maintain a preformed cupped shape. It is still a further object of the present invention to form a cupped structurally stabilized mask which, although having a high filter efliciency, offers very little resistance to air flow at the air velocities which are encountered with normal breathing so that air inhaled or exhaled by the wearer passes through the mask whereby it is filtered rather than passing between the edge of the mask and the wearers face. Also, a mask offering very little resistance to air flow therethrough is substantially more comfortable to wear. Other objects and advantages will become apparent from the following description taken in connection with the accompanying drawings, wherein are set forth by way of illustration and example certain embodiments of this invention.
Referring to the drawings:
FIG. 1 is a persepective view of a mask made in ac cordance with the present invention;
FIG. 2 is a top view of the mask of FIG. 1;
FIG. 3 is a view taken along line 33 of FIG. 2;
FIG. 4 is an illustrative view showing the mask illustrated by FIGS. 1-3 as worn by a subject;
FIG. 5 is a mask with flutes extending over the cupped portion of the mask from top to bottom; and
FIG. 6 is a mask with reinforcing ribs but without flutes.
The mask as illustrated in FIGS. 14 has an upper por tion 10 which is adapted to fit over the nose bridge of the wearer and a lower portion 11 which is adapted to fit around the wearers chin. The upper portion 10 is formed estates Patented Nov. 3Q, 1965 with a ridge section 12 which coincides with the top of the bridge of a wearers nose and indented side sections 13 which are adapted to fit along either side of the nose bridge just above the nostrils to give a snug fit.
The rim portion 14 extends around the periphery of the mask and has its outer edge 15, which is adapted to contact the wearers face, formed with a slight radius to provide good contact with the wearers face without causing irritation which would occur if there were sharp edges. This curved edge extends around the periphery of the mask and also preferably extends as a U-shaped channel 17 along the base of the mask near the tab sections 16 to which attaching strings 13 would be secured. Through the use of this curved edge, a good seal can be obtained between the mask and the face of a wearer so that there is no leakage of inhaled and exhaled air around the edge of the mask with the result the air passes through the mask and is filtered.
The main body 19 of the mask is cupped out from the rim and is the portion of the mask designed to filter the exhaled and inhaled air. In order to increase the filter area, this portion of the mask is preferably formed with flutes 20 having peaks 21 and valleys 22. In the preferred construction, which is shown in FIGS. 1-4, these flutes extend crosswise of the mask and decrease in size as they approach the sides of the mask. The flutes are further formed so that they tend to spread out near the center portion of the mask and come together near the edges of the same. With this construction, more flexibility of the mask is obtained between the chin portion and the nose covering portion, making it somewhat easier to talk when the mask in in place.
The mask is formed of fibers which are molded together in the shape shown. These fibers may initially be in the form of a fiber batt or sheet which is placed between the dies for molding the mask, or the fibers may be floated down on top of one-half of the die before the second half of the die is placed thereon and the mask molded. The fibers have intermixed therewith a thermoplastic material which, in the preferred construction, is in the form of thermoplastic fibers which are blended together with the non-thermoplastic fibers to form the fiber body which is molded into the mask.
In order to obtain the maximum degree of strength while at the same time maintaining a high filter efliciency, the fibers are tightly compacted or compressed in the nose area 10, along the valleys 22 of the flutes, and in the rim area 14. The turned edge 15 and flanges 16 are also formed of tightly compacted fibers. This higher compression of the fibers in the areas indicated, with resulting greater compacting of the same, makes these particular areas stronger and somewhat more rigid than the areas in which the fibers have not been as tightly compacted, thus forming a strong resilient frame surrounding an area of fibers which are compacted to a substantially less degree. The degree of compacting substantially affects the resistance to air flow. Accordingly, a substantially lower resistance to air flow is obtained in these relatively lightly compacted areas. This gives a mask which has substantial structural strength but which at the same time has an extremely low resistance to air flow throughout most of the cupped portion 19. As a result, the mask so formed offers very little resistance to air flow while maintaining its molded shape. Accordingly, the air inhaled and exhaled by the wearer passes readily through the mask and at the same time a good seal is maintained around the periphery of the mask between the mask and face of the wearer.
By tightly compressing the fibers of the mask in the area 12 where it extends over the ridge of the nose of the wearer and in the areas 13 where it extends down along the side of the nose bridge, sufiicient resiliency is obtained in the nose section so that it fits snugly around the bridge of a wearers nose, making it unnecessary to use a moldable metal strip, as has heretofore been proposed, to obtain a snug fit in this particular area.
The mask of FIG. 5 differs primarily from the mask of FIGS. 14 in that the flutes 20' extend lengthwise of the mask rather than across the same. The valleys of the flutes 20 of the mask of FIG. 5 are compressed to a substantially greater degree than the ridges in a manner similar to that described in connection with the flutes 20 of the mask of FIGS. 1-4 so as to obtain the added structural strength which these relatively tightly compacted areas provide. Although in the mask of FIGS. 1-4 and in the mask of FIG. 5 the valleys of the flutes are more tightly compacted than the ridges, the fibers along the ridges could, if desired, be compacted to a greater degree than those in the valleys in which case the strengthening structural ribs would extend along the ridges of the flutes while the valley areas would act primarily to filter the air. However, it is preferred to have these structural ribs of more tightly compressed fibers extend along the valleys of the flutes, as illustrated in FIGS. 1-5.
Not only is the structural stability of the mask substantially improved by more tightly compacting the fibers around the base of the mask but this greater compacting of the fibers in this area substantially improves the resistance of the base portion of the mask to perspiration which is encountered while the mask is being Worn. Without this greater compacting of the fibers at the base of the mask, the mask would be softened during wear due to wetting by perspiration. This would detrimentally affect the close fit between the mask and face with resulting leakage of air around the base.
The mask of FIG. 6 differs from the mask of FIGS. 1-4 and the mask of FIG. 5 primarily in that it contains no flutes. Also, the structural ribs 23 of tightly compacted fibers are spaced equally from each other throughout their entire length as they extend across the cupped portion of the mask.
The areas of greater compression in the mask are obtained by so forming the dies that there is substantially less clearance between the dies in the areas where greater compression is to be obtained. In the preferred practice of forming masks of the present invention, a mixture of non-thermoplastic and thermoplastic fibers are used. Synthetic fibers are preferably used as the nonthermoplastic fibers because of the uniformity in length and denier that can be obtained, viscose rayon fibers being preferred. However, other non-thermoplastic fibers, such as cotton and other natural fibers, may be used in place of the rayon fibers if desired. Any thermoplastic fiber may be used that would stand up under the temperatures to which the mask may be subjected during sterilization and storage. The thermoplastic fibers generally preferred in practicin the present invention are those sold under the trade-name Vinyon, these fibers being formed of the copolymers of vinyl chloride and vinyl acetate. These Vinyon fibers generally melt at a temperature within the range of about 275 to 300 F., softening at a temperature of about 125 to 140 F., and becoming tacky at a temperature of about 185 to 215 F.
In the practice of the present invention, a web is first formed of a mixture of Vinyon and rayon fibers having a denier of about 0.5 to 5.5, the Vinyon and rayon fibers varying in ratio from about by weight Vinyon fibers and 90% by weight rayon fibers to about 45% by weight Vinyon fibers and 55% by weight rayon fibers. The mask is then formed by placing the web of blended fibers within the die and compressing the same at a temperature sufficiently high to bond the thermoplastic fibers to the adjacent non-thermoplastic fibers. In the preferred practice of the present invention, the die is so formed that the areas of the die in which the less compacted part of the mask is formed are spaced about 0.008 to 0.012
inch from each other for a web weight of 4 to 8 oz. per
square yard when the die is fully closed and the re- 5 maining areas of the remainder of the die areas are in contact. In molding the mask, the web of fibers is sub jected to an over-all die pressure of about 10 to 75 pounds per square inch, most of this pressure being placed around the rim, over the nose section, and along th ribs of the mask where the clearance between the two die members is substantially less than in the remaining part of the dies.
The high filter efficiency for air-borne bacteria of the masks of the present invention and the low resistance to air flow is well illustrated by the following table which gives the bacteria filter efficiency and resistance to air flow of masks formed of the same weight of fibers, the only change being in the proportion of viscose rayon fibers to Vinyon fibers used. The fiber batt used in pre paring the masks has a weight of 7 .43 oz. per square yard and the fibers have a length of about 1.5 inches and a denier of 1.5. The masks each have an area of approx imately 27.83 square inches.
Mask
Resistance to Air Flow, Inches Water Difference Bacteria Filtration Efficiency in Percent Baeteria Removal Fiber Formula Bacteria filtration efiiciency is evaluated in vitro using a standard bacteria aerosol. The air resistance is nieas' ured at an air flow through the masks of 85.5 liters of air per minute.
It has been found that if masks formed in the manner described are sterilized in an autoclave and a group of the masks are sterilized together with one mask being superimposed over the other some sticking between the fibers of adjacent masks occurs at the relatively high temperatures of about 225 to 280 F. at which autoclave sterilization is generally done. Since the masks are primarily designed for use in hospitals where autoclave sterilization is generally used, it is highly desirable to avoid such sticking. It has been discovered that this sticking can be avoided by spraying the mask with a small amount of polyvinyl alcohol. It has also been found that with sterilization under autoclave conditions the porosity of the mask may be affected because of softening of the thermoplastic Vinyon fibers. The treatment with the polyvinyl alcohol has been found to stabilize the porosity of the mask under such sterilization conditions. Also, with masks containing from about and less Vinyon fibers where there is substantial handling of the mask, there is a tendency for the surface fibers to become flutfed with the possibility that some of the fibers may become detached. This is undesirable particularly under operating conditions in a hospital. .Also, the fluffed masks are substantially less comfortable to wear. The coating spray of polyvinyl alcohol has been found to bond together the surface fibers of the mask without having appreciable deleterious effect on the permeability of the mask so that the mask can be subjected to substantial handling without the surface fibers becoming loosened.
The polyvinyl alcohol coating is preferably applied by spraying onto the molded mask a water solution containing up to 10% by weight of the polyvinyl alcohol. Although polyvinyl alcohol is preferably used, other resin binders which are not softened at normal sterilization temperatures and which will deposit at the junctures of fibers in minute globules, as opposed to a continuous film, may be used. Among other materials that may be used for this purpose are, for example, methyl cellulose,
hydroxy ethyl cellulose, polyacrylates, polyamides, and polyesters.
The following example, which is given for the purpose of illustration only and does not limit the invention, will help to better describe the mask manufacture.
Example A batt of fibers comprising 25% Vinyon and 75% rayon uniformly blended is used. The fiber length of both the Vinyon and the rayon fibers is 1% inches and the fiber denier is 1.5. This batt has a thickness prior to molding of about /8 to inch and a weight of 5.14 ounces per square yard. The fiber batt is placed in a mold having a female and male member which when engaged without anything placed therebetween touch in areas where greatest fiber compression is to be applied and are separated about 0.01 inch in areas where the least fiber compression is to be applied. The fabric is placed between the molds and the molds pressed together for about 2.5 seconds with a pressure of 65 p..i., the molds being heated to a temperature of 290 to 300 F. while the fabric is therebetween. The molds are then separated and the molded mask removed. Sections of the mask, as marked in FIG. 2, namely, sections 1, 2, 3, 4 and 5, are cut from the molded mask and tested for resis tance to air flow which varies directly with the degree of fiber compactness. These areas give resistances such as shown by the following table:
Air Resistance to 8.5
Liters Air Per Minute Measured in Inches Water Dir- Mask Section fer entl alAreaof When a mask similarly formed is placed on the face with tie strings extending around the back of the head to hold the same firmly in place, it offers little resistance to breathing. The mask has a bacteria filter efficiency for air passing through the same of about 82% and a resistance to air flow through the entire mask at 85.5 liters of air per minute in inches of water differential of 0.11 inch.
Although a wide range of fiber lengths may be used in preparing the masks of the present invention, it is generally preferred not to use fibers of less than inch because of the greater possibility of such fibers coming loose when the mask is in use.
Although the masks of the present invention have been described as being particularly suitable for surgical use, the masks may be used in any application where a mask of high filter efiiciency and low air resistance is needed and are particularly suitable for use in those areas where inexpensive, disposable masks having high filter efliciencies are required. The invention is susceptible of many modifications Within its spirit and accordingly is to be limited only by the scope of the appended claims.
Having thus described our invention, we claim:
1. A fiber mask comprising a raised cup shaped central portion adapted to fit over the mouth and nostrils of a wearer and having a relatively low resistance to the flow of air therethrough at air velocities comparable to those of normal breathing, a rim portion extending around said raised central portion and a nose-bridge-contacting portion, the fibers of said rim portion and nose-bridge-contact-ing portion being more densely compacted than the major portion of the fibers of said raised central portion and acting to strengthen said mask, said ri-m portion and nose-bridge-contacting portion being more resistant to the flow of air and structurally stronger than most of said raised central portion.
2. An air permeable fiber mask having a raised, center portion adapted to fit over the mouth and nostrils of a wearer, ribs extending across said raised center portion and forming a part thereof, a nose-bridge-contacting portion and a rim portion extending around said mask and adjacent the outer edge ofthe same, the fibers forming said nose-bridge-contacting portion, rim portion and ribs being compacted to a substantially greater degree than the remainder of said mask and acting to strengthen the same, the center portion of said mask having substantially less resistance to air flow than said rim portion and said nosebridge portion.
3. An air permeable mask of fibrous material comprising a raised central portion adapted to fit over the mouth and nostrils of a wearer and having a relatively low resistance to the flow of air therethrough at air velocities comparable to those of normal breathing, a rim portion, reinforcing ribs extending across said raised portion and forming a part of the same, and a nosebridge-contacting portion, the fibers of said rim portion, reinforcing ribs and nose-bridge-contacting portion being compressed to a substantially greater degree than the fibers of said mask in said raised portion between said rim portion, nose-bridge-contacting portion and ribs, the center portion of said mask having substantially less resistance to air flow than said rim portion and said nosebridge-contacting portion.
4. A mask of claim 3 in which the outer edge of said mask has an outward radial turn and in which the fibers of said outer edge are compacted to a substantially greater degree than the fibers in said raised central portion between said ribs.
5. A mask of fibrous material comprising a raised, central portion adapted to fit over the mouth and nostrils of a wearer, flutes extending across said raised portion and forming a part thereof, a rim portion and a nosebridge-contact-ing portion, the fibers in said rim portion, in said nose-bridge-contacting portion and in the valleys of said flutes being compressed to a substantially greater degree than the fibers of said mask in said raised portion between said rim portion, nose-bridge-contacting portion and flute valleys, the center portion of said mask having substantially less resistance to air flow than said center portion between said flute valleys.
6. A mask of claim 5 in which said flutes merge together as they approach the rim of said mask and spread out as they approach the center of said raised portion.
7. A mask of claim 6 in which said flutes extend across said raised portion from one side of said mask to the other.
8. A mask of claim 2 in which said mask is formed of non-thermoplastic fibers bonded together with a thermoplastic material.
9. A mask of claim 8 wherein said non-thermoplastic fibers comprise at least 55% by weight of said mask.
10. A mask of claim 8 wherein 55% to by weight of said mask is of non-thermoplastic fibers and the remainder of thermoplastic fibers.
11. A mask of claim 10 wherein said non-thermoplastic fibers are viscose rayon fibers.
12. A mask of claim 2 wherein said mask contains 55 to 90% by weight of viscose rayon fibers and 10% to 45% by weight fibers formed of vinyl chloride-vinyl acetate copolymers having softening through melting temperatures within the range of about to 300 F.
13. An air permeable fiber mask having a raised, center portion adapted to fit over the mouth and nostrils of a wearer, ribs extending across said raised center portion and forming a part thereof, a nose-bridge-contacting portion and a rim portion extending around said mask and adjacent the outer edge of the same, the fibers forming said nose-bridge-contacting portion, rim portion and ribs being compacted to a substantially greater degree than '7 the remainder of said mask and acting to strengthen the same, the center portion of said mask having substantially less resistance to air flow than said rim portion and said nose-bridge portion, and the outer surface of said mask having an air permeable coating of polyvinyl alcohol.
References Cited by the Examiner UNITED STATES PATENTS 2,173,781 9/1939 Gi'bello 128141 2,376,871 5/1945 Fink 128146 2,521,984 9/1950 Lang 55-514 Brown 55514 Hill 128-146 Lancaster 128-156 Haliczer 128-146 FOREIGN PATENTS Great Britain. Great Britain.
10 RICHARD A. GAUDET, Primary Examiner.
JORDAN FRANKLIN, Examiner.
Claims (1)
1. A FIBER MASK COMPRISING A RAISED CUP SHAPED CENTRAL PORTION ADAPTED TO FIT OVER THE MOUTH AND NOSTRILS OF A WEARER AND HAVING A RELATIVELY LOW RESISTANCE TO THE FLOW OF AIR THERETHROUGH AT AIR VELOCITIES COMPARABLE TO THOSE OF NORMAL BREATHING, A RIM PORTION EXTENDING AROUND SAID RAISED CENTRAL PORTION AND A NOSE-BRIDGE-CONTACTING PORTION, THE FIBERS OF SAID RIM PORTION AND NOSE-BRIDGE-CONTACTING PORTION BEING MORE DENSELY COMPACTED THAN THE MAJOR PORTION OF THE FIBERS OF SAID RAISED CENTRAL PORTION AND ACTING TO STRENGTHEN SAID MASK, SAID RIM PORTION AND NOSE-BRIDGE-CONTACTING PORTION BEING MORE RESISTANT TO THE FLOW OF AIR AND STRUCTURALLY STRONGER THAN MOST OF SAID RAISED CENTRAL PORTION.
Priority Applications (2)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
US98903A US3220409A (en) | 1961-03-28 | 1961-03-28 | Face mask |
GB11885/62A GB937799A (en) | 1961-03-28 | 1962-03-28 | Masks |
Applications Claiming Priority (1)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
US98903A US3220409A (en) | 1961-03-28 | 1961-03-28 | Face mask |
Publications (1)
Publication Number | Publication Date |
---|---|
US3220409A true US3220409A (en) | 1965-11-30 |
Family
ID=22271477
Family Applications (1)
Application Number | Title | Priority Date | Filing Date |
---|---|---|---|
US98903A Expired - Lifetime US3220409A (en) | 1961-03-28 | 1961-03-28 | Face mask |
Country Status (2)
Country | Link |
---|---|
US (1) | US3220409A (en) |
GB (1) | GB937799A (en) |
Cited By (55)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
US3315674A (en) * | 1964-12-28 | 1967-04-25 | Sierra Engineering Company | Filter mask facelet |
US3333585A (en) * | 1964-12-14 | 1967-08-01 | Minnesota Mining & Mfg | Cold weather face mask |
US3386231A (en) * | 1966-12-23 | 1968-06-04 | American Air Filter Co | Pocket-type filter |
US3613678A (en) * | 1970-02-24 | 1971-10-19 | Minnesota Mining & Mfg | Filtration mask |
US3779244A (en) * | 1971-02-03 | 1973-12-18 | Johns Manville | Disposable face respirator |
DE2362630A1 (en) * | 1973-12-17 | 1975-06-19 | Johnson & Johnson | Surgical facial masks prodn. - from thermoplastic filaments aligned perpendicular to direction of air flow |
US4195629A (en) * | 1970-10-23 | 1980-04-01 | Halbrand, Inc. | Face mask |
US4228798A (en) * | 1979-05-01 | 1980-10-21 | Deaton David W | Suction receptacle with hygroscopic filter |
US4300549A (en) * | 1980-01-07 | 1981-11-17 | Surgikos | Operating room face mask |
FR2485933A1 (en) * | 1980-07-07 | 1982-01-08 | Moldex Metric Products Inc | DISPOSABLE FACIAL MASK |
US4384577A (en) * | 1981-04-03 | 1983-05-24 | Moldex/Metric Products, Inc. | Disposable face mask |
EP0121299A2 (en) * | 1983-02-01 | 1984-10-10 | Minnesota Mining And Manufacturing Company | Molded nonwoven shaped articles |
US4550856A (en) * | 1984-02-29 | 1985-11-05 | Parmelee Ind Inc | Face mask and dispenser assembly |
EP0162546A1 (en) * | 1984-03-27 | 1985-11-27 | Minnesota Mining And Manufacturing Company | Molded fibrous filtration products |
US4616647A (en) * | 1984-08-13 | 1986-10-14 | Parmelee Industries, Inc. | Molded fiber disposable face mask having enhanced nose and chin filter-seals |
EP0209838A1 (en) * | 1985-07-15 | 1987-01-28 | New England Thermoplastics Incorporated | Face mask |
US4643182A (en) * | 1983-04-20 | 1987-02-17 | Max Klein | Disposable protective mask |
US4719911A (en) * | 1986-10-20 | 1988-01-19 | Carrico George L | Air filter mask with mouth retention means |
US5553608A (en) * | 1994-07-20 | 1996-09-10 | Tecnol Medical Products, Inc. | Face mask with enhanced seal and method |
US5656368A (en) * | 1992-08-04 | 1997-08-12 | Minnesota Mining And Manufacturing Company | Fibrous filtration face mask having corrugated polymeric microfiber filter layer |
US5699792A (en) * | 1994-07-20 | 1997-12-23 | Tecnol Medical Products, Inc. | Face mask with enhanced facial seal |
US5704349A (en) * | 1987-10-02 | 1998-01-06 | Tecnol Medical Products, Inc. | Surgical face mask with darkened glare-reducing strip and visor |
US5706804A (en) * | 1996-10-01 | 1998-01-13 | Minnesota Mining And Manufacturing Company | Liquid resistant face mask having surface energy reducing agent on an intermediate layer therein |
US5724964A (en) * | 1993-12-15 | 1998-03-10 | Tecnol Medical Products, Inc. | Disposable face mask with enhanced fluid barrier |
US5765556A (en) * | 1992-12-16 | 1998-06-16 | Tecnol Medical Products, Inc. | Disposable aerosol mask with face shield |
US5863312A (en) * | 1992-10-23 | 1999-01-26 | Wolfe; Michael | Non-entraining filter |
US6041782A (en) * | 1997-06-24 | 2000-03-28 | 3M Innovative Properties Company | Respiratory mask having comfortable inner cover web |
US6070265A (en) * | 1999-04-03 | 2000-06-06 | Tasbas; Hedy T. | Nose warmer |
US6093230A (en) * | 1998-10-12 | 2000-07-25 | Allegiance Corporation | Filter assembly comprising two filter elements separated by a hydrophobic foam |
US20040055605A1 (en) * | 2002-09-24 | 2004-03-25 | Kimberly-Clark Worldwide, Inc. | Easy gripping face mask |
US20040055078A1 (en) * | 2002-09-24 | 2004-03-25 | Kimberly-Clark Worldwide, Inc. | Easy gripping face mask |
US6868984B2 (en) | 2002-09-24 | 2005-03-22 | Kimberly-Clark Worldwide, Inc. | Method of dispensing a face mask |
US6923182B2 (en) | 2002-07-18 | 2005-08-02 | 3M Innovative Properties Company | Crush resistant filtering face mask |
US20050194010A1 (en) * | 2004-03-05 | 2005-09-08 | Sankot Philip W. | Disposable contagion transmission prevention device and method of using a disposable contagion transmission prevention device |
US20050199238A1 (en) * | 2004-03-12 | 2005-09-15 | Shuei-Wun Ciou | Mask with grooved baffle |
US20060074390A1 (en) * | 2004-10-06 | 2006-04-06 | Kimberly-Clark Worldwide, Inc. | Absorbent article dispensing system |
US20090211581A1 (en) * | 2008-02-26 | 2009-08-27 | Vishal Bansal | Respiratory mask with microporous membrane and activated carbon |
US20090320848A1 (en) * | 2008-06-30 | 2009-12-31 | Eric Steindorf | Collapse Resistant Respirator |
US20100229871A1 (en) * | 2009-06-17 | 2010-09-16 | Gustav David Marx | Pop-open respiratory etiquette device |
WO2011041333A1 (en) | 2009-09-30 | 2011-04-07 | Wilcox Heather J | Male urinary incontinence device |
WO2012003565A1 (en) * | 2010-07-06 | 2012-01-12 | Gustav David Marx | Pop-open respiratory etiquette device |
JP2012161475A (en) * | 2011-02-07 | 2012-08-30 | Midori Anzen Co Ltd | Mask |
JP2015033470A (en) * | 2013-08-08 | 2015-02-19 | 日本バイリーン株式会社 | Cup type mask |
CN104510031A (en) * | 2014-12-26 | 2015-04-15 | 王彤 | Humidifying piece and humidifying mask with same |
USD740932S1 (en) * | 2013-09-24 | 2015-10-13 | 3M Innovative Properties Company | Respirator with raised face seal flexing region |
USD746439S1 (en) | 2013-12-30 | 2015-12-29 | Kimberly-Clark Worldwide, Inc. | Combination valve and buckle set for disposable respirators |
USD776258S1 (en) * | 2013-09-24 | 2017-01-10 | 3M Innovative Properties Company | Respirator with face seal multiple flexing region |
USD787659S1 (en) * | 2013-09-24 | 2017-05-23 | 3M Innovative Properties Company | Respirator with face seal flexing region |
USD787660S1 (en) * | 2014-05-22 | 2017-05-23 | 3M Innovative Properties Company | Respirator mask having a face seal flexing region |
KR20190054490A (en) * | 2017-11-13 | 2019-05-22 | 쓰리엠 이노베이티브 프로퍼티즈 캄파니 | Shell structure and mask including same |
US10835704B1 (en) | 2019-05-15 | 2020-11-17 | Applied Research Associates, Inc. | Reusable respiratory protection device |
US20220295912A1 (en) * | 2021-03-16 | 2022-09-22 | Cherackal Chacko | Smart Mask |
USD967950S1 (en) * | 2020-06-19 | 2022-10-25 | Shanghai Yuanqin Purification Technology Co., Ltd. | Particulate respirator |
US11877604B2 (en) | 2007-05-03 | 2024-01-23 | 3M Innovative Properties Company | Maintenance-free respirator that has concave portions on opposing sides of mask top section |
US11904191B2 (en) | 2007-05-03 | 2024-02-20 | 3M Innovative Properties Company | Anti-fog respirator |
Families Citing this family (3)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
DE1298420B (en) * | 1966-10-29 | 1969-06-26 | Medizintechnik Leipzig Veb | Production of respiratory protection half masks from flat dust filter material |
US4419993A (en) * | 1981-12-10 | 1983-12-13 | Minnesota Mining & Manufacturing Company | Anti-fogging surgical mask |
US4807619A (en) * | 1986-04-07 | 1989-02-28 | Minnesota Mining And Manufacturing Company | Resilient shape-retaining fibrous filtration face mask |
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US2173781A (en) * | 1936-06-08 | 1939-09-19 | Nobel Francaise Soc | Fabric for masks and protective clothing |
US2376871A (en) * | 1941-05-24 | 1945-05-29 | Fink Rudolph | Respirator mask |
US2521984A (en) * | 1947-05-19 | 1950-09-12 | American Felt Co | Fibrous unit |
US2548942A (en) * | 1947-06-06 | 1951-04-17 | Electrolux Corp | Air filter |
US2578007A (en) * | 1947-12-04 | 1951-12-11 | John D Hill | Respirator |
US2720477A (en) * | 1953-04-30 | 1955-10-11 | Plastic Film Corp | Plastic bandage or adhesive tape and process of manufacture |
US2752916A (en) * | 1953-10-28 | 1956-07-03 | Haliczer Marcus | Accordion-folded face mask |
GB780710A (en) * | 1953-04-02 | 1957-08-07 | Nat Res Dev | Improvements in or relating to respirators |
GB780709A (en) * | 1953-04-02 | 1957-08-07 | Mini Of Supply | Improvements in or relating to filters for removing suspended particles from gases |
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US2173781A (en) * | 1936-06-08 | 1939-09-19 | Nobel Francaise Soc | Fabric for masks and protective clothing |
US2376871A (en) * | 1941-05-24 | 1945-05-29 | Fink Rudolph | Respirator mask |
US2521984A (en) * | 1947-05-19 | 1950-09-12 | American Felt Co | Fibrous unit |
US2548942A (en) * | 1947-06-06 | 1951-04-17 | Electrolux Corp | Air filter |
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Cited By (73)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
US3333585A (en) * | 1964-12-14 | 1967-08-01 | Minnesota Mining & Mfg | Cold weather face mask |
US3315674A (en) * | 1964-12-28 | 1967-04-25 | Sierra Engineering Company | Filter mask facelet |
US3386231A (en) * | 1966-12-23 | 1968-06-04 | American Air Filter Co | Pocket-type filter |
US3613678A (en) * | 1970-02-24 | 1971-10-19 | Minnesota Mining & Mfg | Filtration mask |
US4195629A (en) * | 1970-10-23 | 1980-04-01 | Halbrand, Inc. | Face mask |
US3779244A (en) * | 1971-02-03 | 1973-12-18 | Johns Manville | Disposable face respirator |
DE2362630A1 (en) * | 1973-12-17 | 1975-06-19 | Johnson & Johnson | Surgical facial masks prodn. - from thermoplastic filaments aligned perpendicular to direction of air flow |
US4228798A (en) * | 1979-05-01 | 1980-10-21 | Deaton David W | Suction receptacle with hygroscopic filter |
US4300549A (en) * | 1980-01-07 | 1981-11-17 | Surgikos | Operating room face mask |
FR2485933A1 (en) * | 1980-07-07 | 1982-01-08 | Moldex Metric Products Inc | DISPOSABLE FACIAL MASK |
US4319567A (en) * | 1980-07-07 | 1982-03-16 | Moldex/Metric Products, Inc. | Disposable face mask |
DE3126562A1 (en) * | 1980-07-07 | 1982-08-12 | Moldex/Metric Products, Inc., 90230 Culver City, Calif. | DISPOSABLE FACE MASK |
US4384577A (en) * | 1981-04-03 | 1983-05-24 | Moldex/Metric Products, Inc. | Disposable face mask |
EP0121299A2 (en) * | 1983-02-01 | 1984-10-10 | Minnesota Mining And Manufacturing Company | Molded nonwoven shaped articles |
EP0121299A3 (en) * | 1983-02-01 | 1986-07-16 | Minnesota Mining And Manufacturing Company | Molded nonwoven shaped articles |
US4643182A (en) * | 1983-04-20 | 1987-02-17 | Max Klein | Disposable protective mask |
US4550856A (en) * | 1984-02-29 | 1985-11-05 | Parmelee Ind Inc | Face mask and dispenser assembly |
EP0162546A1 (en) * | 1984-03-27 | 1985-11-27 | Minnesota Mining And Manufacturing Company | Molded fibrous filtration products |
US4616647A (en) * | 1984-08-13 | 1986-10-14 | Parmelee Industries, Inc. | Molded fiber disposable face mask having enhanced nose and chin filter-seals |
EP0209838A1 (en) * | 1985-07-15 | 1987-01-28 | New England Thermoplastics Incorporated | Face mask |
US4641645A (en) * | 1985-07-15 | 1987-02-10 | New England Thermoplastics, Inc. | Face mask |
US4719911A (en) * | 1986-10-20 | 1988-01-19 | Carrico George L | Air filter mask with mouth retention means |
US5704349A (en) * | 1987-10-02 | 1998-01-06 | Tecnol Medical Products, Inc. | Surgical face mask with darkened glare-reducing strip and visor |
US5753343A (en) * | 1992-08-04 | 1998-05-19 | Minnesota Mining And Manufacturing Company | Corrugated nonwoven webs of polymeric microfiber |
US5656368A (en) * | 1992-08-04 | 1997-08-12 | Minnesota Mining And Manufacturing Company | Fibrous filtration face mask having corrugated polymeric microfiber filter layer |
US5804295A (en) * | 1992-08-04 | 1998-09-08 | Minnesota Mining And Manufacturing Company | Fibrous filtration face mask having corrugated polymeric microfiber filter layer |
US5763078A (en) * | 1992-08-04 | 1998-06-09 | Minnesota Mining And Manufacturing Company | Filter having corrugated nonwoven webs of polymeric microfiber |
US5863312A (en) * | 1992-10-23 | 1999-01-26 | Wolfe; Michael | Non-entraining filter |
US5765556A (en) * | 1992-12-16 | 1998-06-16 | Tecnol Medical Products, Inc. | Disposable aerosol mask with face shield |
US5724964A (en) * | 1993-12-15 | 1998-03-10 | Tecnol Medical Products, Inc. | Disposable face mask with enhanced fluid barrier |
US5699792A (en) * | 1994-07-20 | 1997-12-23 | Tecnol Medical Products, Inc. | Face mask with enhanced facial seal |
US5694925A (en) * | 1994-07-20 | 1997-12-09 | Tecnol Medical Products, Inc. | Face mask with enhanced seal and method |
US5553608A (en) * | 1994-07-20 | 1996-09-10 | Tecnol Medical Products, Inc. | Face mask with enhanced seal and method |
US5706804A (en) * | 1996-10-01 | 1998-01-13 | Minnesota Mining And Manufacturing Company | Liquid resistant face mask having surface energy reducing agent on an intermediate layer therein |
US6041782A (en) * | 1997-06-24 | 2000-03-28 | 3M Innovative Properties Company | Respiratory mask having comfortable inner cover web |
US6093230A (en) * | 1998-10-12 | 2000-07-25 | Allegiance Corporation | Filter assembly comprising two filter elements separated by a hydrophobic foam |
US6070265A (en) * | 1999-04-03 | 2000-06-06 | Tasbas; Hedy T. | Nose warmer |
US6923182B2 (en) | 2002-07-18 | 2005-08-02 | 3M Innovative Properties Company | Crush resistant filtering face mask |
US20040055605A1 (en) * | 2002-09-24 | 2004-03-25 | Kimberly-Clark Worldwide, Inc. | Easy gripping face mask |
US20040055078A1 (en) * | 2002-09-24 | 2004-03-25 | Kimberly-Clark Worldwide, Inc. | Easy gripping face mask |
US6868984B2 (en) | 2002-09-24 | 2005-03-22 | Kimberly-Clark Worldwide, Inc. | Method of dispensing a face mask |
US6945249B2 (en) | 2002-09-24 | 2005-09-20 | Kimberly-Clark Worldwide, Inc. | Easy gripping face mask |
US6948499B2 (en) * | 2002-09-24 | 2005-09-27 | Kimberly-Clark Worldwide, Inc. | Easy gripping face mask |
US20050194010A1 (en) * | 2004-03-05 | 2005-09-08 | Sankot Philip W. | Disposable contagion transmission prevention device and method of using a disposable contagion transmission prevention device |
US20050199238A1 (en) * | 2004-03-12 | 2005-09-15 | Shuei-Wun Ciou | Mask with grooved baffle |
US20060074390A1 (en) * | 2004-10-06 | 2006-04-06 | Kimberly-Clark Worldwide, Inc. | Absorbent article dispensing system |
US11904191B2 (en) | 2007-05-03 | 2024-02-20 | 3M Innovative Properties Company | Anti-fog respirator |
US11877604B2 (en) | 2007-05-03 | 2024-01-23 | 3M Innovative Properties Company | Maintenance-free respirator that has concave portions on opposing sides of mask top section |
US20090211581A1 (en) * | 2008-02-26 | 2009-08-27 | Vishal Bansal | Respiratory mask with microporous membrane and activated carbon |
US20090320848A1 (en) * | 2008-06-30 | 2009-12-31 | Eric Steindorf | Collapse Resistant Respirator |
US8113201B2 (en) | 2008-06-30 | 2012-02-14 | Kimberly-Clark Worldwide, Inc. | Collapse resistant respirator |
US8439038B2 (en) | 2008-06-30 | 2013-05-14 | Kimberly-Clark Worldwide, Inc. | Collapse resistant respirator |
US8267088B2 (en) | 2008-06-30 | 2012-09-18 | Kimberly-Clark Worldwide, Inc. | Collapse resistant respirator |
US20100229871A1 (en) * | 2009-06-17 | 2010-09-16 | Gustav David Marx | Pop-open respiratory etiquette device |
US8006694B2 (en) | 2009-06-17 | 2011-08-30 | Gustav David Marx | Pop-open respiratory etiquette device |
US8277426B2 (en) | 2009-09-30 | 2012-10-02 | Wilcox Heather J | Male urinary incontinence device |
WO2011041333A1 (en) | 2009-09-30 | 2011-04-07 | Wilcox Heather J | Male urinary incontinence device |
WO2012003565A1 (en) * | 2010-07-06 | 2012-01-12 | Gustav David Marx | Pop-open respiratory etiquette device |
JP2012161475A (en) * | 2011-02-07 | 2012-08-30 | Midori Anzen Co Ltd | Mask |
JP2015033470A (en) * | 2013-08-08 | 2015-02-19 | 日本バイリーン株式会社 | Cup type mask |
USD740932S1 (en) * | 2013-09-24 | 2015-10-13 | 3M Innovative Properties Company | Respirator with raised face seal flexing region |
USD776258S1 (en) * | 2013-09-24 | 2017-01-10 | 3M Innovative Properties Company | Respirator with face seal multiple flexing region |
USD787659S1 (en) * | 2013-09-24 | 2017-05-23 | 3M Innovative Properties Company | Respirator with face seal flexing region |
USD746439S1 (en) | 2013-12-30 | 2015-12-29 | Kimberly-Clark Worldwide, Inc. | Combination valve and buckle set for disposable respirators |
USD787660S1 (en) * | 2014-05-22 | 2017-05-23 | 3M Innovative Properties Company | Respirator mask having a face seal flexing region |
CN104510031A (en) * | 2014-12-26 | 2015-04-15 | 王彤 | Humidifying piece and humidifying mask with same |
KR20190054490A (en) * | 2017-11-13 | 2019-05-22 | 쓰리엠 이노베이티브 프로퍼티즈 캄파니 | Shell structure and mask including same |
KR102593052B1 (en) | 2017-11-13 | 2023-10-25 | 쓰리엠 이노베이티브 프로퍼티즈 캄파니 | Shell structure and mask including same |
JP2019108649A (en) * | 2017-11-13 | 2019-07-04 | スリーエム イノベイティブ プロパティズ カンパニー | Shell structure and mask having the same |
US10835704B1 (en) | 2019-05-15 | 2020-11-17 | Applied Research Associates, Inc. | Reusable respiratory protection device |
USD967950S1 (en) * | 2020-06-19 | 2022-10-25 | Shanghai Yuanqin Purification Technology Co., Ltd. | Particulate respirator |
US20220295912A1 (en) * | 2021-03-16 | 2022-09-22 | Cherackal Chacko | Smart Mask |
US11622586B2 (en) * | 2021-03-16 | 2023-04-11 | Cherackal Chacko | Patient face mask for identifying vaccination status and controlling movement within a medical facility |
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