US3307928A - Gasoline additives for enhancing engine cleanliness - Google Patents
Gasoline additives for enhancing engine cleanliness Download PDFInfo
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- US3307928A US3307928A US254878A US25487863A US3307928A US 3307928 A US3307928 A US 3307928A US 254878 A US254878 A US 254878A US 25487863 A US25487863 A US 25487863A US 3307928 A US3307928 A US 3307928A
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- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07D—HETEROCYCLIC COMPOUNDS
- C07D207/00—Heterocyclic compounds containing five-membered rings not condensed with other rings, with one nitrogen atom as the only ring hetero atom
- C07D207/02—Heterocyclic compounds containing five-membered rings not condensed with other rings, with one nitrogen atom as the only ring hetero atom with only hydrogen or carbon atoms directly attached to the ring nitrogen atom
- C07D207/30—Heterocyclic compounds containing five-membered rings not condensed with other rings, with one nitrogen atom as the only ring hetero atom with only hydrogen or carbon atoms directly attached to the ring nitrogen atom having two double bonds between ring members or between ring members and non-ring members
- C07D207/34—Heterocyclic compounds containing five-membered rings not condensed with other rings, with one nitrogen atom as the only ring hetero atom with only hydrogen or carbon atoms directly attached to the ring nitrogen atom having two double bonds between ring members or between ring members and non-ring members with hetero atoms or with carbon atoms having three bonds to hetero atoms with at the most one bond to halogen, e.g. ester or nitrile radicals, directly attached to ring carbon atoms
- C07D207/36—Oxygen or sulfur atoms
- C07D207/40—2,5-Pyrrolidine-diones
- C07D207/404—2,5-Pyrrolidine-diones with only hydrogen atoms or radicals containing only hydrogen and carbon atoms directly attached to other ring carbon atoms, e.g. succinimide
- C07D207/408—Radicals containing only hydrogen and carbon atoms attached to ring carbon atoms
- C07D207/412—Acyclic radicals containing more than six carbon atoms
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- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07F—ACYCLIC, CARBOCYCLIC OR HETEROCYCLIC COMPOUNDS CONTAINING ELEMENTS OTHER THAN CARBON, HYDROGEN, HALOGEN, OXYGEN, NITROGEN, SULFUR, SELENIUM OR TELLURIUM
- C07F9/00—Compounds containing elements of Groups 5 or 15 of the Periodic System
- C07F9/02—Phosphorus compounds
- C07F9/04—Reaction products of phosphorus sulfur compounds with hydrocarbons
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- C—CHEMISTRY; METALLURGY
- C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
- C10L—FUELS NOT OTHERWISE PROVIDED FOR; NATURAL GAS; SYNTHETIC NATURAL GAS OBTAINED BY PROCESSES NOT COVERED BY SUBCLASSES C10G, C10K; LIQUEFIED PETROLEUM GAS; ADDING MATERIALS TO FUELS OR FIRES TO REDUCE SMOKE OR UNDESIRABLE DEPOSITS OR TO FACILITATE SOOT REMOVAL; FIRELIGHTERS
- C10L1/00—Liquid carbonaceous fuels
- C10L1/10—Liquid carbonaceous fuels containing additives
- C10L1/14—Organic compounds
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- C—CHEMISTRY; METALLURGY
- C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
- C10L—FUELS NOT OTHERWISE PROVIDED FOR; NATURAL GAS; SYNTHETIC NATURAL GAS OBTAINED BY PROCESSES NOT COVERED BY SUBCLASSES C10G, C10K; LIQUEFIED PETROLEUM GAS; ADDING MATERIALS TO FUELS OR FIRES TO REDUCE SMOKE OR UNDESIRABLE DEPOSITS OR TO FACILITATE SOOT REMOVAL; FIRELIGHTERS
- C10L1/00—Liquid carbonaceous fuels
- C10L1/10—Liquid carbonaceous fuels containing additives
- C10L1/14—Organic compounds
- C10L1/143—Organic compounds mixtures of organic macromolecular compounds with organic non-macromolecular compounds
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- C—CHEMISTRY; METALLURGY
- C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
- C10L—FUELS NOT OTHERWISE PROVIDED FOR; NATURAL GAS; SYNTHETIC NATURAL GAS OBTAINED BY PROCESSES NOT COVERED BY SUBCLASSES C10G, C10K; LIQUEFIED PETROLEUM GAS; ADDING MATERIALS TO FUELS OR FIRES TO REDUCE SMOKE OR UNDESIRABLE DEPOSITS OR TO FACILITATE SOOT REMOVAL; FIRELIGHTERS
- C10L1/00—Liquid carbonaceous fuels
- C10L1/10—Liquid carbonaceous fuels containing additives
- C10L1/14—Organic compounds
- C10L1/18—Organic compounds containing oxygen
- C10L1/192—Macromolecular compounds
- C10L1/198—Macromolecular compounds obtained otherwise than by reactions involving only carbon-to-carbon unsaturated bonds homo- or copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon to carbon double bond, and at least one being terminated by an acyloxy radical of a saturated carboxylic acid, of carbonic acid
- C10L1/1983—Macromolecular compounds obtained otherwise than by reactions involving only carbon-to-carbon unsaturated bonds homo- or copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon to carbon double bond, and at least one being terminated by an acyloxy radical of a saturated carboxylic acid, of carbonic acid polyesters
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- C—CHEMISTRY; METALLURGY
- C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
- C10L—FUELS NOT OTHERWISE PROVIDED FOR; NATURAL GAS; SYNTHETIC NATURAL GAS OBTAINED BY PROCESSES NOT COVERED BY SUBCLASSES C10G, C10K; LIQUEFIED PETROLEUM GAS; ADDING MATERIALS TO FUELS OR FIRES TO REDUCE SMOKE OR UNDESIRABLE DEPOSITS OR TO FACILITATE SOOT REMOVAL; FIRELIGHTERS
- C10L1/00—Liquid carbonaceous fuels
- C10L1/10—Liquid carbonaceous fuels containing additives
- C10L1/14—Organic compounds
- C10L1/18—Organic compounds containing oxygen
- C10L1/192—Macromolecular compounds
- C10L1/198—Macromolecular compounds obtained otherwise than by reactions involving only carbon-to-carbon unsaturated bonds homo- or copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon to carbon double bond, and at least one being terminated by an acyloxy radical of a saturated carboxylic acid, of carbonic acid
- C10L1/1985—Macromolecular compounds obtained otherwise than by reactions involving only carbon-to-carbon unsaturated bonds homo- or copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon to carbon double bond, and at least one being terminated by an acyloxy radical of a saturated carboxylic acid, of carbonic acid polyethers, e.g. di- polygylcols and derivatives; ethers - esters
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- C—CHEMISTRY; METALLURGY
- C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
- C10L—FUELS NOT OTHERWISE PROVIDED FOR; NATURAL GAS; SYNTHETIC NATURAL GAS OBTAINED BY PROCESSES NOT COVERED BY SUBCLASSES C10G, C10K; LIQUEFIED PETROLEUM GAS; ADDING MATERIALS TO FUELS OR FIRES TO REDUCE SMOKE OR UNDESIRABLE DEPOSITS OR TO FACILITATE SOOT REMOVAL; FIRELIGHTERS
- C10L1/00—Liquid carbonaceous fuels
- C10L1/10—Liquid carbonaceous fuels containing additives
- C10L1/14—Organic compounds
- C10L1/22—Organic compounds containing nitrogen
- C10L1/234—Macromolecular compounds
- C10L1/238—Macromolecular compounds obtained otherwise than by reactions involving only carbon-to-carbon unsaturated bonds
- C10L1/2383—Polyamines or polyimines, or derivatives thereof (poly)amines and imines; derivatives thereof (substituted by a macromolecular group containing 30C)
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- C—CHEMISTRY; METALLURGY
- C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
- C10L—FUELS NOT OTHERWISE PROVIDED FOR; NATURAL GAS; SYNTHETIC NATURAL GAS OBTAINED BY PROCESSES NOT COVERED BY SUBCLASSES C10G, C10K; LIQUEFIED PETROLEUM GAS; ADDING MATERIALS TO FUELS OR FIRES TO REDUCE SMOKE OR UNDESIRABLE DEPOSITS OR TO FACILITATE SOOT REMOVAL; FIRELIGHTERS
- C10L1/00—Liquid carbonaceous fuels
- C10L1/10—Liquid carbonaceous fuels containing additives
- C10L1/14—Organic compounds
- C10L1/24—Organic compounds containing sulfur, selenium and/or tellurium
- C10L1/2431—Organic compounds containing sulfur, selenium and/or tellurium sulfur bond to oxygen, e.g. sulfones, sulfoxides
- C10L1/2437—Sulfonic acids; Derivatives thereof, e.g. sulfonamides, sulfosuccinic acid esters
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- C—CHEMISTRY; METALLURGY
- C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
- C10L—FUELS NOT OTHERWISE PROVIDED FOR; NATURAL GAS; SYNTHETIC NATURAL GAS OBTAINED BY PROCESSES NOT COVERED BY SUBCLASSES C10G, C10K; LIQUEFIED PETROLEUM GAS; ADDING MATERIALS TO FUELS OR FIRES TO REDUCE SMOKE OR UNDESIRABLE DEPOSITS OR TO FACILITATE SOOT REMOVAL; FIRELIGHTERS
- C10L1/00—Liquid carbonaceous fuels
- C10L1/10—Liquid carbonaceous fuels containing additives
- C10L1/14—Organic compounds
- C10L1/26—Organic compounds containing phosphorus
- C10L1/2691—Compounds of uncertain formula; reaction of organic compounds (hydrocarbons acids, esters) with Px Sy, Px Sy Halz or sulfur and phosphorus containing compounds
Definitions
- an object of this invention to provide a method of maintaining engine cleanliness irrespective of the depletion of the detergents ordinarily employed in lubricating oil.
- the objects of this invention are obtained in part by employing a combination of detergent additives in gasoline which survive combustion and are continuously added to the engine crankcase oil. It has been found that adding the detergent in this manner enhances overall engine cleanliness, not merely the cleanliness of those engine parts contacted with the gasoline.
- the detergent additives seep past the rings into the lubricating oil, and also may inhibit sludge precursors in the gasoline so as to prevent deposit formation. The effect is that of maintaining continuous detergent action in the engine.
- the additives of this invention in addition to reducing crankcase sludge and the like, reduce intake system deposits, prevent corrosion, and improve gasoline storage stability.
- the improved detergent action is obtained by employing a combination of additives.
- This combination substantially reduces crankcase sludge.
- the combination when added to gasoline, the combination causes a haze to be formed if the gasoline comes into contact with small quantities of water. Such contacting is almost inevitable. In many instances, the haze has no serious effect on the use of the gasoline.
- carburetor icing and fuel line freezing Therefore, such a haze is undesirable. Elimination of this haze caused by the combination of detergents presented a difficult problem.
- Many additives and combinations of dehazing additives were tried and found to be ineffective in eliminating the haze caused by the detergent additives of this invention.
- a combination of additives was discovered which is quite effective in reducing and in many cases virtually eliminating the haze.
- the additives of the combination must be employed in certain critical proportions as described hereinafter.
- the combination of detergent additives is best employed in conjunction with a high boiling oil.
- the two detergent additives and the high boiling oil have utility when employed individually, but enhanced results, with regard to reduction of crankcase sludge, are obtained by employing the additives in combination.
- the first is a polyolefin succinimide having the following formula:
- R is polyisobutylene having a molecular weight of from 780 to 1500.
- the succinimide having the above formula is hereinafter referred to as Additive A.
- the polyisobutylene succinimide can be prepared by azeotropically distilling polyisobutylene succinic anhydride, prepared from 900 mol wt. polyisobutylene, with an amine. The distillation is performed until no additional water is formed.
- the second additive utilized in this invention is a phosphosulfurized hydrocarbon, and preferably a phosphosulfurized polyolefin.
- the phosphosulfurization agent may be P 8 P 5 P 5 P 5 or their mixtures, or mixtures of elemental phosphorus and sulfur or other materials.
- P 5 is preferred.
- P 5 phosphorus pentasulfide
- a preferred range is about 5 to 25, e.g. 10 to 20, wt. percent.
- Hydrocarbons to be treated should, of course, be reactive with the phosphosulfurizing agent. They include olefins, diolefins, acetylenes, aromatics, cyclic aliphatics, and various mixtures of these such as are found in petroleum fractions, condensation products of petroleum fractions, hydrogenated coals, synthetically produced hydrocarbons and the like. Preferred are lubricating oil distillates and base stocks such as bright stock residue and the like and polyolefins.
- the phosphosulfurized hydrocarbons which are utilized as one constituent of the additive combination of the invention are prepared by reacting a C to C olefin polymer with a sulfide of phosphorus.
- Olefinic polymers prepared by the polymerization or copolymerization of low molecular weight olefins and diolefins such as ethylene, propylene, butylene, isobutylene, butadiene, isoprene, and cyclopentadiene, are suitable materials for the phosphosulfurization.
- Polymers of monoolefins wherein the molecular weight ranges from about 500 to about 20,000 and preferably ranges from about 600 to about 10,000, e.g.
- 700 to 2,000 are particularly effective in preparing the phosphosulfurized hydrocarbons of the invention.
- the most preferred polyolefin employed is a polyisobutylene or polybutene having an average molecular weight of 700 to 1,200, e.g. 94-0.
- One method of carrying out such a polymerization reaction is to employ a Friedel-Crafts catalyst such as boron fluoride or aluminum trichloride at low temperatures in the range of from about F. to about 40 F.
- a Friedel-Crafts catalyst such as boron fluoride or aluminum trichloride
- Other methods familiar to those skilled in the art, carried out at higher temperatures and with other polymerization catalysts may also be used as described, for example, in US. Patent 2,768,999.
- the resulting acidic phosphosulfurized hydrocarbon reaction product is then hydrolyzed by steam stripping the product at a temperature of between 100 C. and 200 C., e.g. 140 C. to 160 C., for a period of time, e.g. l to 6 hours, sufficient to reduce the volatile by-product odor and to bring the acid number to at least 25 and the sulfur content to less than 1.5 wt. percent.
- a temperature of between 100 C. and 200 C. e.g. 140 C. to 160 C.
- a period of time e.g. l to 6 hours
- the hydrolyzed phosphosulfurized polyolefin is then preferably treated with ethylene oxide or urea. Moreover, the hydrolyzed phosphosulfurized polyolefin is further stabilized and improved by reacting the acidic hydrolyzed product with a neutralizing agent such that its titratable acidity is at least partially reduced.
- Neutralizing agents include the alkali and alkaline earth and metal hydroxides, carbonates and oxides, but preferably include those ashless basic reagents such as ammonia and alkyl and aryl substituted amines and polyamines as previously described.
- the amount of neutralizing agent employed is usually between 1 to 50% by weight of the acidic product, e.g., 1 to 20 wt. percent, or from 1 to about 10* moles, e.g., 2 to moles, of agent to moles of acidic product, e.g., 2 to 6 moles.
- a most preferred class of basic reagents includes organic epoxide compounds such as aryl substituted alkyl epoxides like styrene epoxide; alicylic epoxides like cyclopentene epoxide; halosubstituted alkylene epoxides such as chloropropylene oxide; and particularly C to C alkylene oxides such as ethylene oxide, propylene oxide, butene oxide, and the like. From 1 to moles of these epoxides are reacted with each mole of acidic product as described more fully in British Patent 792,553, hereby incorporated by reference. Although the neutralized product is preferred and the hydrolyzed and neutralized product most preferred, the untreated P 8 polyolefin reaction product itself may be employed, but generally would somewhat reduce the effectiveness.
- organic epoxide compounds such as aryl substituted alkyl epoxides like styrene epoxide; alicylic
- the preferred phosphosulfurized polyolefin is prepared as follows:
- ADDITIVE B Polybutene having a molecular weight of from 700 to 1200, e.g., 940, is reacted with P 8 as described above.
- the phosphosulfurized polybutene is then hydrolyzed by steam stripping at a temperature of about 150 C. for a time sufiicient to bring the acid number to at least 25.
- the product is then ethoxylated by reacting it with from 1 to 6 moles of ethylene oxide per mole of acidic product. This additive is hereinafter referred to as Additive B.
- the third additive of this invention is a high boiling solvent oil of petroleum derivation.
- the oil should have a boiling range of within 350 F. to 800 F. at 10 mm. of Hg and preferably between 400 F. and 700 F.
- the oil should have'a viscosity within the range of from 45 SSU/ 210 F. to 150 SSU/210" F.
- Typical inspection for an oil of this type is as follows:
- the motor fuels in which the additives are employed in order to enhance engine cleanliness are conventional petroleum distillate fuels boiling in the gasoline boiling point range employed in internal combustion, preferably spark ignition, engines. They are supplied in a number of different grades depending upon the type of service for which they are intended. The additives may be employed in all of these grade-s but are particularly useful in motor and aviation gasolines.
- Motor gasolines as referred to in connection with the present invention are defined by ASTM Specification D43958T in Types A, B and C. They are composed of a mixture of various types of hydrocarbons including aromatics, olefins, parafiins, isoparafiins, naphthenes and, occasionally, diolefins.
- Suitable gasolines to which the polymeric additives of the instant invention may be added are those gasolines having an octane number range of 83 to 105 or higher, such as a clear octane number of over 90, for example, over or 100, and comprising over 20% by volume of aromatic hydrocarbons and less than 30% by volume of olefinic hydrocarbons. They are derived from petroleum crude oil by refining processes such as fractional distillation, catalytic cracking, hydroforming, alkylation, isomerization, polymerization and solvent extraction. Motor gasolines normally have boiling ranges between about 70 F.
- aviation gasolines have narrower boiling ranges of between F. and 330 F.
- the vapor pressures of gasoline as determined by ASTM Method D-86 vary between about 7 and about 15 p.s.i. at 100 F.
- the copolymers may also be employed in aviation gasolines which have properties similar to those of motor gasolines, but normally have somewhat higher octane numbers and narrower boiling ranges.
- the prop erties of aviation gasolines are set forth in US. Military Specification MIL-F-5572 and ASTM Specification D-91-0-57T.
- the copolymeric additives employed in accordance with the invention may be used in gasolines with other additive agents conventionally used in such fuels. It is common practice to employ from about 0.5 to about 7.0 cc./ gal. of alkyl lead antiknock agents, such as tetraethyl lead, tetramethyl lead, dimethyl diethyl lead or a similar alkyl lead antiknock agent or olefinic lead antiknock agents such as tetravinyl lead, triethyl vinyl lead, and the like, or a combination thereof, in both motor gasolines and in aviation gasolines, e.g., 1.0 to 3.0 cc. of tetraethyl leadtetramethyl lead combination.
- alkyl lead antiknock agents such as tetraethyl lead, tetramethyl lead, dimethyl diethyl lead or a similar alkyl lead antiknock agent or olefinic lead antiknock agents such as tetravinyl lead,
- Antiknock agents may also include other organometallic additives containing lead, iron, nickel, lithium, manganese and the like.
- Other additives such as those conventionally employed in gasolines may be used such as corrosion inhibitors, antioxidants, antistatic agents, lead octane appreciators like t-butyl acetate, auxiliary scavengers like tri-B-chloroethyl phosphate, dyes, anti-icing agents like isopropanol, hexylene glycol and the like.
- the additives are employed in a range of ratios from 1:3 to 3:1 parts by volume of the polyolefin succinimide to the phosphosulfurized polyolefin, the preferred range of ratios being from 1:1 to 3 :1 parts by volume of the polyolefin succinirnide to the phosphosulfu-rized polyolefin. The preferred ratio being 2/ 1.
- the additive combination comprising the polyolefin succinimide and the phosphosulfurized polyolefin is employed in gasoline in a minor amount sufficient to enhance engine cleanliness. The combination is advantageously utilized in concentrations ranging from 0.1 to .001 vol. percent, and preferably from .03 to .01 vol. percent.
- the high boiling oil assists the additive combination through the combustion zone into the crankcase of an engine.
- the oil is utilized in concentrations of from 0.005 to 0.5 vol. percent, and preferably from 0.005 to 0.25 vol. percent.
- Example 1 Ford 4-45 sludging tests were performed in order to determine the sludge inhibiting effect of the additive combination.
- the additive combination consisting of 2 parts by volume of Additive A to 1 part by volume of Additive B was added in a concentration of 0.02 vol. percent to a gasoline having the following specifications:
- the gasoline composition was then employed in a 6- cylinder Ford engine, and said engine was operated for 55 hours, then inspected, and test was continued to 110 hours.
- the following engine. parts were examined:
- Run 3 The results obtained in Run 3 were better than those obtained in either Runs 1 or 2.
- the total amount of additive combination was the same as the quantity of Additive A employed in Run 2. Even though improvement is difiicult to obtain above a merit rating of 9, the additive combination, Run 3, proved to be superior to Additive A.
- the additives described are effective in enhancing engine cleanliness.
- the addition of these additives to gasoline creates a problem of haze formation.
- the water haze will not seriously affect the operation of internal combustion engines.
- the haze promotes carburetor icing and fuel line freezing and is, thus, undesirable.
- Dodecylbenzene sulfonic 'acid is one of the additives of the combination employed to effect a separation of gasoline and water.
- This additive can be prepared by reacting dodecylbenzene with concentrated sulfuric acid. This material is readily available on the market.
- EMCOL P-lO hereafter referred to as additive D is dodecylbenzene sulfonic acid.
- the second additive is an ethoxylated fatty acid polyester.
- This additive can be prepared by reacting a dimeric fatty acid, e.g., dimeric oleic acid, with trirnethylol propane. The resulting polyester product is then reacted with ethylene oxide in a ratio of 2 parts by weight of the polyester per part of ethylene oxide.
- RMS 5790 is the ethoxylated fatty acid polyester employed in the following tests and is hereafter referred to as Additive E.
- the dehazing additive combination is effective in concentrations of from p.p.m. to 40 p.p.m., and preferably from 17 p.p.m. to 35 p.p.m.
- the weight ratio of dodecylbenzene sulfonic acid to ethoxylated fatty acid polyester is from 0.3 to 4.5, and preferably from 0.67 to 2.4
- Haze formation presents two problems to be solved. First, a suitable additive must eliminate the water haze in the gasoline. Second, it must separate the gasoline from the water phase which may accumulate in storage tanks and the like. In short, an additive must effect a complete separation of gasoline and water.
- Example 3 Haze tests were performed in order to determine the efficacy of the dehazing additive combination. A gasoline having the following specifications was employed in the tests:
- Additive A and Additive B in a weight ratio of 2:1 were added to the gasoline.
- Additive C was added in a concentration of 0.1 vol. percent.
- Additive D and Additive E in a weight ratio of 3 :2 were added to the gasoline containing Additives A, B and C.
- To 450 ml. of this fuel composition was added 1 vol. percent of service station water bottoms.
- the composition was then stirred in a Waring Blendor for 1 minute at 3500 rpm. Tests were run with various concentrations of additives. The results appear in Table III.
- the gasoline composition was examined 6 hours after stirring and given a haze rating. A rating of 1 corresponds to a completely clear composition whereas a composition with a rating of 8 was very hazy.
- the additive combination not only provides a clear gasoline phase, but also a clear water phase. In short, the combination effects a complete separation of gasoline and water.
- Example 4 The dehazing additive combination should be employed within a narrow range of ratios of Additive D to Additive E.
- a 450 ml. sample of the gasoline composition was combined with 1 vol. percent water and stirred in a blender for 1 minute at 3500 rpm.
- the gasoline phase and the Water phase were then examined for clarity. The base cleared within 6 hours.
- FIGURE 12345 was determined from data obtained as follows:
- Example 3 To the gasoline, described in Example 3, were added 0.1 vol. percent of Additive C and 0.021 vol. percent of the detergent combination consisting of 2 parts of Additive A to 1 part by volume of Additive B. To a number of 450 ml. samples of this gasoline concentration, the dehazing additive combination, Additive D and Additive E were added in various concentrations and proportions.
- FIGURE abcd delineates an area wherein a complete separation of gasoline is not effected, but where the results are better than the gasoline containing only Additives A, B and C. Outside of FIGURE ab-cd there results a gasoline in water emulsion, a water in gasoline emulsion, or both.
- this invention provides a useful package of gasoline additives. It provides a combination of detergent additives which continuously enhance over-all engine cleanliness. Moreover, by employing certain high boiling oils with said combination, the detergent effect can be greatly enhanced, especially over long periods of operation. In addition, a combination of dehazing additives is provided which, when used in critical proportions, obviates the problem of haze formation encountered when detergents are added to gasoline.
- a motor fuel composition comprising a major proportion of a petroleum distillate fuel boiling in the gasoline range, a minor amount suflicient to enhance engine cleanliness, of an additive combination comprising:
- R is a polyolefin having a molecular weight of from 780 to 1500, x is in the range of from 1 to 3 inclusive, and R is selected from the class consisting of:
- H H H H N/ l ⁇ C CH3 and (B) a phosphosulfurized polyolefin having a molecular weight of from 500 to about 20,000; wherein said additive combination is employed in the ratio of from 1:1 to 3:1 parts by volume of the polyolefin succinimide per part by volume of the phosphosulfurized polyolefin;
- additive combination comprising:
- said second additive combination being employed in a weight ratio of dodecylbenzene sulfonic acid to ethoxylated fatty acid ester in a range of from 0.3:1 to 4.5:1.
- said first named additive combination constitutes from 0.001 to 0.1 volume percent of the motor fuel.
- a fuel according to claim 1 containing from 0.005 to 0.5 volume percent of a high boiling oil having a viscosity of from 45 SSU/2l0 F. to SSU/210 F.
- a motor fuel according to claim 1 wherein x l, R3 is i f /CCR1 N and R is a polyolefin having a molecular weight of from 780 to 1500.
- a motor fuel according to claim 1 containing a minor amount of a solvent oil of petroleum derivation having a boiling range within 350 to 800 F. at 10 mm. Hg.
Description
Mach 7, 196.7; M. CHAIKw Ky ET AL 3,307,928
GASOLINE ADDITIVES FOR ENHANCING ENGINE CLEANLINESS Filed Jan. 30,1963
A RANGE OF EFFECTIVE EMCOL P-lO/RMS 5790 CONCENTRATIONS (AND RATIOS) DEFINED FOR DETERGENT CONTAINING FUEL d l 4 I C A N w m m E IR LE mm FII| ||||L mm Mm HW D,C, .AB 5 m EMCOL P-IO, ppm
MICHAEL CHAIKIVSKY JOHN D TURNER lnven'lors LOUIS N. CALVINO Patent Attorney United States Patent 3,307,928 GASOLINE ADDITIVES FOR ENHANCING ENGINE CLEANLINESS Michael Chaikivsky, Elizabeth, John D. Turner, North Plainfield, and Louis N. Calvino, Scotch Plains, N.J., assignors to Esso Research and Engineering Company, a corporation of Delaware Filed Jan. 30, 1963, Ser. No. 254,878 7 Claims. (Cl. 44-63) This invention relates to an improve-d motor fuel composition, and particularly to internal combustion engine fuels containing multifunctional additives which are especially useful in enhancing overall engine cleanliness.
Despite the high efiiciency of modern gasoline engines, complete combustion of fuel introduced into the combustion chambers of such engines seldom, if ever, occurs. Studies have shown that certain polynuclear aromatic compounds and other relatively high boiling materials present in gasolines are only partially burned and that the exhaust and blow-by gases formed in the combustion chambers of gasoline engines contain trace amounts of hydrocarbons. Apparently these hydrocarbons undergo complex cracking, polymerization and oxidation reactions to form sludge and varnish precursors which enter the crankcase past the piston rings. Deposits, sludge and varnish formed in this manner seriously affect the operation of a gasoline engine. Thesedeposits promote wear, valve lifter sticking and generally poor engine performance and indirectly contribute to surface ignition, spark plug fouling, octane requirement increase, and other combustion difficulties.
In the past, various detergent and dispersant type additives have been employed in the nonvolatile, high boiling crankcase mineral lubricating oil to effect engine cleanliness. This procedure has been effective to a degree. However, in those cases where the oil is left in the engine over relatively long periods, the detergent additives are depleted. This, of course, results in a reduction in the cleaning effectiveness of the lubricating oil.
It is, therefore, an object of this invention to provide a method of maintaining engine cleanliness irrespective of the depletion of the detergents ordinarily employed in lubricating oil.
It is another object of this invention to provide superior detergent additives for enhancing overall engine cleanliness.
It is a further object of this invention to provide an additive package which does not cause a water haze to form in the gasoline.
The objects of this invention are obtained in part by employing a combination of detergent additives in gasoline which survive combustion and are continuously added to the engine crankcase oil. It has been found that adding the detergent in this manner enhances overall engine cleanliness, not merely the cleanliness of those engine parts contacted with the gasoline. The detergent additives seep past the rings into the lubricating oil, and also may inhibit sludge precursors in the gasoline so as to prevent deposit formation. The effect is that of maintaining continuous detergent action in the engine.
There are other substantial advantages to be obtained from employing the detergent additives in gasoline. The additives of this invention, in addition to reducing crankcase sludge and the like, reduce intake system deposits, prevent corrosion, and improve gasoline storage stability.
The improved detergent action is obtained by employing a combination of additives. This combination substantially reduces crankcase sludge. However, when added to gasoline, the combination causes a haze to be formed if the gasoline comes into contact with small quantities of water. Such contacting is almost inevitable. In many instances, the haze has no serious effect on the use of the gasoline. However, in cold weather there exists the problems of carburetor icing and fuel line freezing. Therefore, such a haze is undesirable. Elimination of this haze caused by the combination of detergents presented a difficult problem. Many additives and combinations of dehazing additives were tried and found to be ineffective in eliminating the haze caused by the detergent additives of this invention. A combination of additives was discovered which is quite effective in reducing and in many cases virtually eliminating the haze. The additives of the combination must be employed in certain critical proportions as described hereinafter.
The combination of detergent additives is best employed in conjunction with a high boiling oil.
The two detergent additives and the high boiling oil have utility when employed individually, but enhanced results, with regard to reduction of crankcase sludge, are obtained by employing the additives in combination.
In this invention, three additives are employed in order to enhance engine cleanliness. The first is a polyolefin succinimide having the following formula:
ADDITIV E A The preferred polyolefin succinimide has the following formula:
wherein R is polyisobutylene having a molecular weight of from 780 to 1500. The succinimide having the above formula is hereinafter referred to as Additive A.
The polyisobutylene succinimide can be prepared by azeotropically distilling polyisobutylene succinic anhydride, prepared from 900 mol wt. polyisobutylene, with an amine. The distillation is performed until no additional water is formed.
The second additive utilized in this invention is a phosphosulfurized hydrocarbon, and preferably a phosphosulfurized polyolefin. The phosphosulfurization agent may be P 8 P 5 P 5 P 5 or their mixtures, or mixtures of elemental phosphorus and sulfur or other materials. A sulfide of phosphorus, especially phosphorus pentasulfide (P 5 is preferred. Generally, in the range of about 1.0 to 50.0% by weight, based on the hydrocarbon, of phosphosulfurizing agent is used. A preferred range is about 5 to 25, e.g. 10 to 20, wt. percent.
Hydrocarbons to be treated should, of course, be reactive with the phosphosulfurizing agent. They include olefins, diolefins, acetylenes, aromatics, cyclic aliphatics, and various mixtures of these such as are found in petroleum fractions, condensation products of petroleum fractions, hydrogenated coals, synthetically produced hydrocarbons and the like. Preferred are lubricating oil distillates and base stocks such as bright stock residue and the like and polyolefins.
The phosphosulfurized hydrocarbons which are utilized as one constituent of the additive combination of the invention are prepared by reacting a C to C olefin polymer with a sulfide of phosphorus. Olefinic polymers prepared by the polymerization or copolymerization of low molecular weight olefins and diolefins such as ethylene, propylene, butylene, isobutylene, butadiene, isoprene, and cyclopentadiene, are suitable materials for the phosphosulfurization. Polymers of monoolefins wherein the molecular weight ranges from about 500 to about 20,000 and preferably ranges from about 600 to about 10,000, e.g. 700 to 2,000 are particularly effective in preparing the phosphosulfurized hydrocarbons of the invention. The most preferred polyolefin employed is a polyisobutylene or polybutene having an average molecular weight of 700 to 1,200, e.g. 94-0.
One method of carrying out such a polymerization reaction is to employ a Friedel-Crafts catalyst such as boron fluoride or aluminum trichloride at low temperatures in the range of from about F. to about 40 F. Other methods familiar to those skilled in the art, carried out at higher temperatures and with other polymerization catalysts may also be used as described, for example, in US. Patent 2,768,999.
The resulting acidic phosphosulfurized hydrocarbon reaction product is then hydrolyzed by steam stripping the product at a temperature of between 100 C. and 200 C., e.g. 140 C. to 160 C., for a period of time, e.g. l to 6 hours, sufficient to reduce the volatile by-product odor and to bring the acid number to at least 25 and the sulfur content to less than 1.5 wt. percent. This method is more fully described in British Patent 838,928.
The hydrolyzed phosphosulfurized polyolefin is then preferably treated with ethylene oxide or urea. Moreover, the hydrolyzed phosphosulfurized polyolefin is further stabilized and improved by reacting the acidic hydrolyzed product with a neutralizing agent such that its titratable acidity is at least partially reduced. Neutralizing agents include the alkali and alkaline earth and metal hydroxides, carbonates and oxides, but preferably include those ashless basic reagents such as ammonia and alkyl and aryl substituted amines and polyamines as previously described. The amount of neutralizing agent employed is usually between 1 to 50% by weight of the acidic product, e.g., 1 to 20 wt. percent, or from 1 to about 10* moles, e.g., 2 to moles, of agent to moles of acidic product, e.g., 2 to 6 moles.
A most preferred class of basic reagents includes organic epoxide compounds such as aryl substituted alkyl epoxides like styrene epoxide; alicylic epoxides like cyclopentene epoxide; halosubstituted alkylene epoxides such as chloropropylene oxide; and particularly C to C alkylene oxides such as ethylene oxide, propylene oxide, butene oxide, and the like. From 1 to moles of these epoxides are reacted with each mole of acidic product as described more fully in British Patent 792,553, hereby incorporated by reference. Although the neutralized product is preferred and the hydrolyzed and neutralized product most preferred, the untreated P 8 polyolefin reaction product itself may be employed, but generally would somewhat reduce the effectiveness.
The preferred phosphosulfurized polyolefin is prepared as follows:
ADDITIVE B Polybutene having a molecular weight of from 700 to 1200, e.g., 940, is reacted with P 8 as described above. The phosphosulfurized polybutene is then hydrolyzed by steam stripping at a temperature of about 150 C. for a time sufiicient to bring the acid number to at least 25. The product is then ethoxylated by reacting it with from 1 to 6 moles of ethylene oxide per mole of acidic product. This additive is hereinafter referred to as Additive B.
The third additive of this invention is a high boiling solvent oil of petroleum derivation. The oil should have a boiling range of within 350 F. to 800 F. at 10 mm. of Hg and preferably between 400 F. and 700 F. The oil should have'a viscosity within the range of from 45 SSU/ 210 F. to 150 SSU/210" F. Typical inspection for an oil of this type is as follows:
ADDITIVE C Gravity, API 28.8 Sulfur, wt. percent 0.40 Neutralization No. D974 0.02 Aniline Point, F. 273.5 ASTM distillation, 10 mm. Hg vacuum:
IBP, F. 353
10% Point, F. 464
50% Point, F. 534
% Point, F. 626
F.B.P. F. 694 Conradson carbon residue 0.1 Vis/210 F., SSU 60.7
The oil, Additive C, is the one which was employed in tests hereinafter described.
The motor fuels in which the additives are employed in order to enhance engine cleanliness are conventional petroleum distillate fuels boiling in the gasoline boiling point range employed in internal combustion, preferably spark ignition, engines. They are supplied in a number of different grades depending upon the type of service for which they are intended. The additives may be employed in all of these grade-s but are particularly useful in motor and aviation gasolines. Motor gasolines as referred to in connection with the present invention are defined by ASTM Specification D43958T in Types A, B and C. They are composed of a mixture of various types of hydrocarbons including aromatics, olefins, parafiins, isoparafiins, naphthenes and, occasionally, diolefins. Those motor fuels containing at least 10% by volume of thermally or catalytically cracked high aromatic components may be especially benefitted from the instant invention. Suitable gasolines to which the polymeric additives of the instant invention may be added are those gasolines having an octane number range of 83 to 105 or higher, such as a clear octane number of over 90, for example, over or 100, and comprising over 20% by volume of aromatic hydrocarbons and less than 30% by volume of olefinic hydrocarbons. They are derived from petroleum crude oil by refining processes such as fractional distillation, catalytic cracking, hydroforming, alkylation, isomerization, polymerization and solvent extraction. Motor gasolines normally have boiling ranges between about 70 F. and about 450 F., while aviation gasolines have narrower boiling ranges of between F. and 330 F. The vapor pressures of gasoline as determined by ASTM Method D-86 vary between about 7 and about 15 p.s.i. at 100 F. The copolymers may also be employed in aviation gasolines which have properties similar to those of motor gasolines, but normally have somewhat higher octane numbers and narrower boiling ranges. The prop erties of aviation gasolines are set forth in US. Military Specification MIL-F-5572 and ASTM Specification D-91-0-57T.
The copolymeric additives employed in accordance with the invention may be used in gasolines with other additive agents conventionally used in such fuels. It is common practice to employ from about 0.5 to about 7.0 cc./ gal. of alkyl lead antiknock agents, such as tetraethyl lead, tetramethyl lead, dimethyl diethyl lead or a similar alkyl lead antiknock agent or olefinic lead antiknock agents such as tetravinyl lead, triethyl vinyl lead, and the like, or a combination thereof, in both motor gasolines and in aviation gasolines, e.g., 1.0 to 3.0 cc. of tetraethyl leadtetramethyl lead combination. Antiknock agents may also include other organometallic additives containing lead, iron, nickel, lithium, manganese and the like. Other additives such as those conventionally employed in gasolines may be used such as corrosion inhibitors, antioxidants, antistatic agents, lead octane appreciators like t-butyl acetate, auxiliary scavengers like tri-B-chloroethyl phosphate, dyes, anti-icing agents like isopropanol, hexylene glycol and the like.
Catalytically and thermally cracked and reformed gasolines containing a high aromatic content, whether leaded or unleaded, are particularly prone to yield excessive crankcase sludge and induction system deposits and are improved by addition of the applicants polymeric additives.
Enhanced engine cleanliness is obtained by employing the polyolefin succinimide and the phosphosulfurized polyolefin in combination in gasoline.
The additives are employed in a range of ratios from 1:3 to 3:1 parts by volume of the polyolefin succinimide to the phosphosulfurized polyolefin, the preferred range of ratios being from 1:1 to 3 :1 parts by volume of the polyolefin succinirnide to the phosphosulfu-rized polyolefin. The preferred ratio being 2/ 1. The additive combination comprising the polyolefin succinimide and the phosphosulfurized polyolefin is employed in gasoline in a minor amount sufficient to enhance engine cleanliness. The combination is advantageously utilized in concentrations ranging from 0.1 to .001 vol. percent, and preferably from .03 to .01 vol. percent.
The high boiling oil assists the additive combination through the combustion zone into the crankcase of an engine. The oil is utilized in concentrations of from 0.005 to 0.5 vol. percent, and preferably from 0.005 to 0.25 vol. percent.
The efiicacy of the additive combination is demonstrated by the following example.
Example 1 Ford 4-45 sludging tests were performed in order to determine the sludge inhibiting effect of the additive combination. The additive combination consisting of 2 parts by volume of Additive A to 1 part by volume of Additive B was added in a concentration of 0.02 vol. percent to a gasoline having the following specifications:
ASTM distillation:
B.P., F. 131 50% B.P., F. 215 90% B.P., F. 330 F.B.P., F. 425 Gravity, API 59.3 Reid vapor pressure 9.6 ASTM Gum 2.2 TEL, cc./gal. 2.1
The gasoline composition was then employed in a 6- cylinder Ford engine, and said engine was operated for 55 hours, then inspected, and test was continued to 110 hours. The following engine. parts were examined:
Rocker Arm Cover P.R.C. Cover Rocker Arm Assembly Crankcase (oil pan) Cylinderhead Crankshaft Timing Gear Cover hours only) TABLE I.-FORD 4-45 TESTS Push Rod Chamber Run Base* Base plus .021 Vol. Base plus .014 Vol.
Percent Additive A Percent Additive A and .007 Additive B Sludge:
55 hours. 7. 9 9.1 9. 5 110 hours 6. 4 7. 4 7. 9
*Average of four base tests,
The data show that Additive A is effective in enhancing engine cleanliness. The merit ratings, 9.1 and 7.4 (110 hours), obtained by using .021 vol. percent of Additive A were substantially better than the merit ratings, 7.9 and 6.4, obtained by using only the base gasoline.
The results obtained in Run 3 were better than those obtained in either Runs 1 or 2. In Run 3, the total amount of additive combination was the same as the quantity of Additive A employed in Run 2. Even though improvement is difiicult to obtain above a merit rating of 9, the additive combination, Run 3, proved to be superior to Additive A.
Example 2 TABLE II.FO RD 4-45 SLUD GING TEST Base plus .014 Vol. Percent Additive A plus .007 Vol. Percent Additive B plus 0.1 Vol. Percent H.B.O.,
Additive C Sludge:
55 hours 9. 6 110 hours 8. 8
The oil proved to be effective in enhancing the effect of the additive combination. It is seen that the merit ratings obtained are better than those of the additive combination as depicted in Table I. There was almost a one merit improvement in performance as is seen in comparing the data in Run 3 of Table I with the above data.
Infrared studies show that more of the detergent additive survives combustion and passes into the crankcase when a high boiling oil is used in conjunction with said detergent additives. It is believed that the oil protects the less stable detergent additives. This oil also enhances performance of other detergents added to gasoline.
The above examples clearly demonstrate the enhanced cleanliness obtained by the use of a combination of a polyolefin succinimide and a phosphosulfurized polyolefin. The examples also show that the efiicacy of the combination can be improved, particularly over long periods of operation, by utilizing 'a high boiling oil in conjunction with said combination.
The additives described are effective in enhancing engine cleanliness. However, the addition of these additives to gasoline creates a problem of haze formation. Under most operating conditions, the water haze will not seriously affect the operation of internal combustion engines. However, in cold weather, the haze promotes carburetor icing and fuel line freezing and is, thus, undesirable.
At first blush, it might appear that the problem could be easily solved by employing any known dehazer or demulsifier. However, many such materials were tried, individually and in combination, and found to be ineffective.
It has now been discovered that a particular combination of additives employed in critical proportions greatly reduce and in many instances virtually eliminate the haze problem.
ADDITIVE D Dodecylbenzene sulfonic 'acid is one of the additives of the combination employed to effect a separation of gasoline and water. This additive can be prepared by reacting dodecylbenzene with concentrated sulfuric acid. This material is readily available on the market. For example, EMCOL P-lO hereafter referred to as additive D is dodecylbenzene sulfonic acid.
ADDITIV E E The second additive is an ethoxylated fatty acid polyester. This additive can be prepared by reacting a dimeric fatty acid, e.g., dimeric oleic acid, with trirnethylol propane. The resulting polyester product is then reacted with ethylene oxide in a ratio of 2 parts by weight of the polyester per part of ethylene oxide. For example, RMS 5790 is the ethoxylated fatty acid polyester employed in the following tests and is hereafter referred to as Additive E.
The dehazing additive combination is effective in concentrations of from p.p.m. to 40 p.p.m., and preferably from 17 p.p.m. to 35 p.p.m. The weight ratio of dodecylbenzene sulfonic acid to ethoxylated fatty acid polyester is from 0.3 to 4.5, and preferably from 0.67 to 2.4
Haze formation presents two problems to be solved. First, a suitable additive must eliminate the water haze in the gasoline. Second, it must separate the gasoline from the water phase which may accumulate in storage tanks and the like. In short, an additive must effect a complete separation of gasoline and water.
The efficacy of the instant additive combination is demonstrated by the following example:
Example 3 Haze tests were performed in order to determine the efficacy of the dehazing additive combination. A gasoline having the following specifications was employed in the tests:
ASTM Distillation:
I.B.P. 90 10% B.P 106 50% B.P 196 90% B.P 302 F.B.P. 360 Gravity, API 59 Reid vapor pressure 11.0 Sulfur, wt. percent 0.20 Research octane number 98 Motor octane number 88 Tetraethyl lead, cc./ gal 2.5
Additive A and Additive B in a weight ratio of 2:1 were added to the gasoline. Additive C was added in a concentration of 0.1 vol. percent.
Service station Water bottoms were added to 450 ml. of the gasoline composition in a concentration of 1 vol. percent. The fuel was then placed in a Waring Blendor for 1 minute at 3500 r.p.m. After 6 hours, the fuel was still very hazy.
Additive D and Additive E in a weight ratio of 3 :2 were added to the gasoline containing Additives A, B and C. To 450 ml. of this fuel composition was added 1 vol. percent of service station water bottoms. The composition was then stirred in a Waring Blendor for 1 minute at 3500 rpm. Tests were run with various concentrations of additives. The results appear in Table III. The gasoline composition was examined 6 hours after stirring and given a haze rating. A rating of 1 corresponds to a completely clear composition whereas a composition with a rating of 8 was very hazy.
TABLE III Haze Results (6 hrs. Additive A plus Additive C, Additive D after stirring) Additive B, Vol. Vol. Percent plus Addi- Percent tive E, p.p.m. Gasoline Water Phase Phase 0.1 36 1 Clear. 0. l 25 1 D0. 0. 1 18 1 Do. 0. 1 9 1 D0.
These data show that the instant dehazing additive combination is effective in eliminating haze caused by the detergent additives throughout a rather broad range of concentrations. The data show that the dehazing combination is effective at low concentrations that may result due to dilution occurring during handling of the fuel.
The additive combination not only provides a clear gasoline phase, but also a clear water phase. In short, the combination effects a complete separation of gasoline and water.
Example 4 The dehazing additive combination should be employed within a narrow range of ratios of Additive D to Additive E.
A 450 ml. sample of the gasoline composition was combined with 1 vol. percent water and stirred in a blender for 1 minute at 3500 rpm. The gasoline phase and the Water phase were then examined for clarity. The base cleared within 6 hours.
The accompanying drawing depicts a phase diagram which shows the concentrations and proportions of the additive combination which are effective. The area delineated by FIGURE 1-2345 is one in which the additive combination effected essentially a complete separation of gasoline and water. This separation is obtained by employing the additive combination in a concentration of from 17 to 35 p.p.m. and within a range of weight ratios of from about 0.67/1 to 2.4/1 parts of EMCOL P-10 to RMS 5790. FIGURE 12345 was determined from data obtained as follows:
To the gasoline, described in Example 3, were added 0.1 vol. percent of Additive C and 0.021 vol. percent of the detergent combination consisting of 2 parts of Additive A to 1 part by volume of Additive B. To a number of 450 ml. samples of this gasoline concentration, the dehazing additive combination, Additive D and Additive E were added in various concentrations and proportions.
FIGURE abcd delineates an area wherein a complete separation of gasoline is not effected, but where the results are better than the gasoline containing only Additives A, B and C. Outside of FIGURE ab-cd there results a gasoline in water emulsion, a water in gasoline emulsion, or both.
In summary, this invention provides a useful package of gasoline additives. It provides a combination of detergent additives which continuously enhance over-all engine cleanliness. Moreover, by employing certain high boiling oils with said combination, the detergent effect can be greatly enhanced, especially over long periods of operation. In addition, a combination of dehazing additives is provided which, when used in critical proportions, obviates the problem of haze formation encountered when detergents are added to gasoline.
What is claimed is:
1. A motor fuel composition comprising a major proportion of a petroleum distillate fuel boiling in the gasoline range, a minor amount suflicient to enhance engine cleanliness, of an additive combination comprising:
(A) A polyolefin succinirnide having the following formula:
wherein R is a polyolefin having a molecular weight of from 780 to 1500, x is in the range of from 1 to 3 inclusive, and R is selected from the class consisting of:
(l-LR.
\C-OH and (2) H H H H N/ l \C= CH3 and (B) a phosphosulfurized polyolefin having a molecular weight of from 500 to about 20,000; wherein said additive combination is employed in the ratio of from 1:1 to 3:1 parts by volume of the polyolefin succinimide per part by volume of the phosphosulfurized polyolefin;
and a second additive combination in an amount sufiicient to substantially separate said petroleum distillate fuel from water which it may contact, said additive combination comprising:
(C) dodecylbenzene sulfonic acid, and
(D) an ethoxylated fatty acid polyester,
said second additive combination being employed in a weight ratio of dodecylbenzene sulfonic acid to ethoxylated fatty acid ester in a range of from 0.3:1 to 4.5:1. 2. A motor fuel according to claim 1 wherein said first named additive combination constitutes from 0.001 to 0.1 volume percent of the motor fuel.
3. A fuel according to claim 1 containing from 0.005 to 0.5 volume percent of a high boiling oil having a viscosity of from 45 SSU/2l0 F. to SSU/210 F.
4. A motor fuel according to claim 1 wherein x=l, R3 is i f /CCR1 N and R is a polyolefin having a molecular weight of from 780 to 1500.
5. A motor fuel according to claim 1 containing a minor amount of a solvent oil of petroleum derivation having a boiling range within 350 to 800 F. at 10 mm. Hg.
6. A motor fuel according to claim 1 wherein said second additive combination is in a concentration of from 10 to 40 p.p.m.
7. A motor fuel according to claim 1 wherein said ratio is from 0.67:1 to 24:1 and said second additive combination is in a concentration of from 17 to 35 p.p.m.
References Cited by the Examiner UNITED STATES PATENTS 2,296,069 9/ 1942 Talbert 44-76 2,316,739 4/1943 Cook et a1. 44-76 2,334,239 11/ 1943 Barnett 252-56 X 2,371,333 3/1945 Johnston 25251.5 2,568,876 9/1951 White et a1. 252-51.5 2,700,022 1/ 1955 Clayton 252-56 2,995,428 8/1961 Godar 252-402 X 3,018,250 1/1962 Anderson 252-51.5 X 3,018,291 1/1962 Anderson 25251.5 X 3,024,195 3/1962 Drummond 252-515 3,048,544 8/1962 Stewart 252-51.5 3,068,082 12/1952 Paris 44-63 3,080,223 3/ 1963 Monnikendam 44-62 3,131,150 4/1964 Stuart et al 252-51.5 3,154,560 10/1964 Osuch 252-51.5 3,172,892 3/1965 Le Suer 252-51.5 3,216,936 11/1965 Le Suer 252-51.5 3,219,666 11/1965 Norman 25251.S
FOREIGN PATENTS 792,553 7/ 1956 Great Britain. 838,928 10/ 1958 Great Britain.
OTHER REFERENCES Esters by Glyco, published by Glyco Products Inc., Brooklyn 1, New York, January 1954.
Polyethylene Glycol Esters, publicized by Kessler Chemical Co., Inc., Philadelphia 35, Pa., received in US. Patent Office Dec. 20, 1948.
DANIEL E. WYMAN, Primary Examiner.
C. O. THOMAS, J. E. DEMPSEY, Y. H. SMITH,
Assistant Examiners.
Claims (1)
1. A MOTOR FUEL COMPOSITION COMPRISING A MAJOR PROPORTION OF A PETROLEUM DISTILLATE FUEL BOILING IN THE GASOLINE RANGE, A MINOR AMOUNT SUFFICIENT TO ENHANCE ENGINE CLEANLINESS, OF AN ADDITIVE COMBINATION COMPRISING: (A) A POLYOLEFIN SUCCINIMIDE HAVING THE FOLLOWING FORMULA:
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US254878A US3307928A (en) | 1963-01-30 | 1963-01-30 | Gasoline additives for enhancing engine cleanliness |
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EP0435631A1 (en) * | 1989-12-22 | 1991-07-03 | Ethyl Petroleum Additives Limited | Diesel fuel compositions |
EP0441014A1 (en) * | 1990-02-06 | 1991-08-14 | Ethyl Petroleum Additives Limited | Compositions for control of induction system deposits |
WO1991013950A1 (en) * | 1990-03-15 | 1991-09-19 | The Lubrizol Corporation | Two-cycle engine fuel composition |
EP0526129A1 (en) * | 1991-07-29 | 1993-02-03 | Ethyl Petroleum Additives, Inc. | Compositions for control of octane requirement increase |
US5256165A (en) * | 1992-01-06 | 1993-10-26 | Texaco Inc | Gasoline detergent additive mixture of mono-and bis-succinimides and heavy oil |
US5511517A (en) * | 1994-02-10 | 1996-04-30 | Ethyl Corporation | Reducing exhaust emissions from otto-cycle engines |
US5551957A (en) * | 1992-05-06 | 1996-09-03 | Ethyl Corporation | Compostions for control of induction system deposits |
US5876467A (en) * | 1994-02-15 | 1999-03-02 | Basf Aktiengesellschaft | Use of carboxylic esters as fuel additives or lubricant additives and their preparation |
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GB838928A (en) * | 1955-09-08 | 1960-06-22 | Exxon Standard Sa | Oxyalkylated phosphosulphurised hydrocarbons and lubricating compositions therefrom |
US3068082A (en) * | 1957-08-15 | 1962-12-11 | Monsanto Chemicals | Rust inhibited hydrocarbon fuel |
US2995428A (en) * | 1957-10-21 | 1961-08-08 | Petrolite Corp | Thermally stable distillate fuels |
US3219666A (en) * | 1959-03-30 | 1965-11-23 | Derivatives of succinic acids and nitrogen compounds | |
US3172892A (en) * | 1959-03-30 | 1965-03-09 | Reaction product of high molecular weight succinic acids and succinic anhydrides with an ethylene poly- amine | |
US3048544A (en) * | 1959-06-10 | 1962-08-07 | California Research Corp | Lubricant composition |
US3018250A (en) * | 1959-08-24 | 1962-01-23 | California Research Corp | Lubricating oil compositions containing nu-dialkylaminoalkyl alkenyl succinimides |
US3024195A (en) * | 1959-08-24 | 1962-03-06 | California Research Corp | Lubricating oil compositions of alkylpiperazine alkenyl succinimides |
US3018291A (en) * | 1959-08-24 | 1962-01-23 | California Research Corp | Nu-dialkylaminoalkyl alkenyl succinimides |
US3080223A (en) * | 1960-06-29 | 1963-03-05 | Exxon Research Engineering Co | Stabilized distillate fuels |
US3131150A (en) * | 1961-04-12 | 1964-04-28 | California Research Corp | Lubricating oil compositions containing n-substituted alkenyl succinimides in combination with polyamines |
US3154560A (en) * | 1961-12-04 | 1964-10-27 | Monsanto Co | Nu, nu'-azaalkylene-bis |
US3216936A (en) * | 1964-03-02 | 1965-11-09 | Lubrizol Corp | Process of preparing lubricant additives |
Cited By (17)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
US3443918A (en) * | 1965-09-21 | 1969-05-13 | Chevron Res | Gasoline composition |
US4666460A (en) * | 1985-04-12 | 1987-05-19 | Chevron Research Company | Modified succinimides (III) |
US4668246A (en) * | 1985-04-12 | 1987-05-26 | Chevron Research Company | Modified succinimides (IV) |
US4783275A (en) * | 1985-04-12 | 1988-11-08 | Chevron Research Company | Modified succinimides (IV) |
EP0388991A1 (en) * | 1985-11-08 | 1990-09-26 | The Lubrizol Corporation | Fuel compositions |
US5575823A (en) * | 1989-12-22 | 1996-11-19 | Ethyl Petroleum Additives Limited | Diesel fuel compositions |
EP0435631A1 (en) * | 1989-12-22 | 1991-07-03 | Ethyl Petroleum Additives Limited | Diesel fuel compositions |
EP0441014A1 (en) * | 1990-02-06 | 1991-08-14 | Ethyl Petroleum Additives Limited | Compositions for control of induction system deposits |
WO1991013950A1 (en) * | 1990-03-15 | 1991-09-19 | The Lubrizol Corporation | Two-cycle engine fuel composition |
US5944858A (en) * | 1990-09-20 | 1999-08-31 | Ethyl Petroleum Additives, Ltd. | Hydrocarbonaceous fuel compositions and additives therefor |
EP0526129A1 (en) * | 1991-07-29 | 1993-02-03 | Ethyl Petroleum Additives, Inc. | Compositions for control of octane requirement increase |
US5256165A (en) * | 1992-01-06 | 1993-10-26 | Texaco Inc | Gasoline detergent additive mixture of mono-and bis-succinimides and heavy oil |
US5551957A (en) * | 1992-05-06 | 1996-09-03 | Ethyl Corporation | Compostions for control of induction system deposits |
US5511517A (en) * | 1994-02-10 | 1996-04-30 | Ethyl Corporation | Reducing exhaust emissions from otto-cycle engines |
US5876467A (en) * | 1994-02-15 | 1999-03-02 | Basf Aktiengesellschaft | Use of carboxylic esters as fuel additives or lubricant additives and their preparation |
WO1999035217A1 (en) * | 1998-01-10 | 1999-07-15 | Lubrizol Adibis Holdings (Uk) Limited | Fuel composition |
US6235068B1 (en) | 1998-01-10 | 2001-05-22 | The Lubrizol Corporation | Fuel composition |
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