US3310109A - Process and apparatus for combination upgrading of oil in situ and refining thereof - Google Patents

Process and apparatus for combination upgrading of oil in situ and refining thereof Download PDF

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US3310109A
US3310109A US409407A US40940764A US3310109A US 3310109 A US3310109 A US 3310109A US 409407 A US409407 A US 409407A US 40940764 A US40940764 A US 40940764A US 3310109 A US3310109 A US 3310109A
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fraction
oil
outlet
vapor
liquid
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John W Marx
William B Belknap
Joseph C Trantham
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Phillips Petroleum Co
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Phillips Petroleum Co
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    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10G—CRACKING HYDROCARBON OILS; PRODUCTION OF LIQUID HYDROCARBON MIXTURES, e.g. BY DESTRUCTIVE HYDROGENATION, OLIGOMERISATION, POLYMERISATION; RECOVERY OF HYDROCARBON OILS FROM OIL-SHALE, OIL-SAND, OR GASES; REFINING MIXTURES MAINLY CONSISTING OF HYDROCARBONS; REFORMING OF NAPHTHA; MINERAL WAXES
    • C10G9/00—Thermal non-catalytic cracking, in the absence of hydrogen, of hydrocarbon oils
    • C10G9/34—Thermal non-catalytic cracking, in the absence of hydrogen, of hydrocarbon oils by direct contact with inert preheated fluids, e.g. with molten metals or salts
    • C10G9/36—Thermal non-catalytic cracking, in the absence of hydrogen, of hydrocarbon oils by direct contact with inert preheated fluids, e.g. with molten metals or salts with heated gases or vapours
    • C10G9/38—Thermal non-catalytic cracking, in the absence of hydrogen, of hydrocarbon oils by direct contact with inert preheated fluids, e.g. with molten metals or salts with heated gases or vapours produced by partial combustion of the material to be cracked or by combustion of another hydrocarbon
    • E—FIXED CONSTRUCTIONS
    • E21—EARTH DRILLING; MINING
    • E21B—EARTH DRILLING, e.g. DEEP DRILLING; OBTAINING OIL, GAS, WATER, SOLUBLE OR MELTABLE MATERIALS OR A SLURRY OF MINERALS FROM WELLS
    • E21B43/00—Methods or apparatus for obtaining oil, gas, water, soluble or meltable materials or a slurry of minerals from wells
    • E21B43/16—Enhanced recovery methods for obtaining hydrocarbons
    • E21B43/24—Enhanced recovery methods for obtaining hydrocarbons using heat, e.g. steam injection
    • E21B43/243—Combustion in situ
    • E—FIXED CONSTRUCTIONS
    • E21—EARTH DRILLING; MINING
    • E21B—EARTH DRILLING, e.g. DEEP DRILLING; OBTAINING OIL, GAS, WATER, SOLUBLE OR MELTABLE MATERIALS OR A SLURRY OF MINERALS FROM WELLS
    • E21B43/00—Methods or apparatus for obtaining oil, gas, water, soluble or meltable materials or a slurry of minerals from wells
    • E21B43/34—Arrangements for separating materials produced by the well
    • E21B43/35—Arrangements for separating materials produced by the well specially adapted for separating solids

Definitions

  • This invention relates to a process for producing oil by in situ combustion to upgrade the oil and refining the upgraded oil in the field near the well head.
  • Low gravity crude oil is particularly difficult to produce even though the pressure in the stratum containing the oil is substantial.
  • the primary recovery is limited to about 2 or 3 percent of the in-place oil even though the static reservoir pressure is 1400 p.s.i. This leaves most of the oil in the stratum to be recovered by secondary production methods. It has been found that this 8.5 API gravity oil can be produced by reverse in situ combustion so as to upgrade the oil to about 26 to 27 API gravity as it leaves the well head.
  • the invention is concerned with a process for producing and upgrading a heavy oil in situ and recovering various fractions of the upgraded oil from the water-containing effiuent from the well head.
  • an object of this invention is to provide a combination process for upgrading a heavy oil in situ and refining the upgraded oil. Another object is to provide a process for refining an upgraded oil produced by in situ combustion and containing substantial concentrations of water while avoiding the formation of heavy oil-water or water-oil emulsions. A further object is to provide a refining process for recovering various oil fractions from upgraded crude oil produced by in situ combustion and containing large concentrations of water.
  • a broad aspect of the invention comprises producing an upgraded oil from a heavy oil-bearing stratum by in situ combustion whereby the upgraded hot eifiuent contains substantial concentrations of Water and is at an elevated pressure, passing the vaporous efiluent from the well head of the production well thru a pressure reducing valve to substantially reduce the pressure thereof and cooling the resulting vapor stream to a temperature not substantially above 500 F. to recover a liquid heavy oil fraction and a separate vapor stream comprising oils boiling above about 500 F. and water.
  • the foregoing procedure comprising cooling the in situ combustion effiuent to a temperature of not more than 500 F.
  • the heavy cut is separately recovered at about 500 F. and the Water in the Well eflluent remains in vapor form and is passed along with the lower boiling hydrocarbons to a second cooling step to cool same to a temeprature substantially below the boiling point of the Water in the vaporous stream and, preferably, to about 100 F.
  • the cooled stream comprising liquid hydrocarbons and water as well as vaporous hydrocarbons is separated into water, liquid oil, and light hydrocarbon gases.
  • the liquid oil fraction is then passed to a conventional fractionator to separate the same into several cuts of different boiling ranges.
  • the invention is applicable to the production of oil produced by any forward or reverse drive in situ combustion process.
  • a direct or forward drive process the temperature of the produced efiluent is not sufli-ciently high for application of the invention until the fire front approaches or passes the production Well. Since the combustion zone moves in a reverse direction to the flow of air in a reverse burning process and the products from the combustion zone pass thru burned over hot sand behind the combustion front on the way to the production well, the efiluent from the reverse burning process is usually above 1000 F. Due to the fact that some oxygen from the injected air bypasses the hot combustion zone and appears in the production Well, well bore fires destroy substantial quantities of the produced oil and damage well equipment unless precautions are taken.
  • a heavy oil bearing stratum 10 is penetrated by a production well 12.
  • a combustion zone 14 has been moved out from well 12 into the stratum by injection of combustion-supporting gas thru one or more offset injection wells.
  • the produced efiluent is recovered thru tubing string 16 and water injected from line 18 thru spray head 20 in sufficient quantity to reduce the temperature of the hot efiluent to the range of about SOD-800 F.
  • the hot effluent under substantial pressure in the range of about 500-2000 p.s.i.g. and at a temperature in the range of 500-800 F. is passed thru line 22 to a sand trap 24 for removal of any sand contained in the produced efiluent.
  • the sand-free eflluent is passed thru line 26 to a liquid-gas separator 28.
  • An expansion valve 30 substantially reduces the pressure of the efiluent to the range of about 250400 p.S.i.g. and, preferably, to about 300 p.s.i.g.
  • Expanded efiluent is cooled in a suitable cooler, preferably, an air fin type cooler 32 to reduce the temperature to not more thanabout 500 P. so that the oil in the vaporous stream boiling above this temperature is condensed and is recovered from separator 28 thru line 34.
  • the uncondensed vapors including water and lower :boil ing hydrocarbons are passed overhead thru line 36 to a second gas-liquid separator 38.
  • Air fin cooler 40 in line 36 economically reduces the temperature of the vaporous stream therein substantially and water cooler 42 further reduces the temperature to substantially below the boiling point of water at ambient pressure, such as about F. This condenses most of the water and the hydrocarbon fraction of the efiluent boiling above 100 F.
  • separator 38 water and oil are separated by phase separation in the lower section thereof and water is withdrawn thru line 44 while the oil fraction is with-drawn thru line 46 and passed to fractionating tower 48.
  • the overhead gaseous stream from separator 38 is passed thru line 50 and thru a demister 52 from which separated liquid is removed thru line 54 and gaseous material is passed thru line 56 as exhaust gas with gas for analysis being taken off in a side stream thru line 58.
  • the liquid oil from line 46 is separated into various fractions in fractionator 48 in conventional manner, recovering the heavier oil th-ru line 60 as a bottoms fraction, the intermediate oil thru line 62 as a side cut, and the light oil fraction overhead thru lines 64 and 66 which connect with a surgetank -68.
  • Reflux is passed from surge tank 68 to the upper section of the fractionator via line 70.
  • Reboiler means 72 for heating the lower section of fractionator 48 is provided.
  • the upgraded oil from stratum is quenched to a temperature in the range of 500-800 F. at a pressure of about 1400 p.s.i.g. About 23 barrels of water per hour and 11 barrels of oil per hour constitute the hot efiluent passing into sand trap 24.
  • Valve is set to control the pressure downstream thereof at about 300 p.s.i.g. Air fin cooler 32 reduces the temperature to about 500 F. when cooling is required to reduce the efiluent temperature.
  • the oil fraction boiling above about 500 F. recovered thru line 34 amounts to 5.3 b./hr.
  • the overhead vapor stream is cooled from about 500 F. to about 100 F.
  • the condensed Water is recovered thru line 44 at the rate of about 23 b./ hr. and the condensed oil i passed thru line 46 at about 100 F. to fractionator 48.
  • the fractionation in tower 48 is maintained at a pressure of about 50 p.s.i.g. with a reboiler temperature of about 525 F.
  • the heavier oil having a boiling range of 400500 F. is recovered thru line '60 at the rate of about 2 b./ hr. while the intermediate oil fraction having a boiling range of 300400 F. is recovered thru line '62 at the rate of 1.7 b./hr.
  • the light hydrocarbon overhead fraction having a boiling range of 100-300 F. is recovered thru line 66 at the rate of 2 b/ hr.
  • a counterfiow combustion test was run on the 8.5 API gravity oil referred to above at a pressure of about 250 p.s.i.g. and an oil of 265 API gravity was produced. The test demonstrated that counterflow or reverse combustion at elevated pressures produces rather light oils.
  • a sample of the 26.5 API gravity oil was fractionated in conventional manner into 4 different boiling range fractions and the data from the distillation are presented in the table below.
  • a process for producing selected hydrocarbons from subterranean oil sand penetrated by an injection well and a production well which comprises the steps of:
  • step (b) recovering the vapor stream of step (a) from said production well;
  • step (c) removing any sand contained in the vapor stream of step (b);
  • step (d) reducing the pressure of the vapor stream of step (c) to about 300 p.s.i.g. and the temperature to not more than about 500 F.;
  • step (e) separating the liquid oil from the vapor fraction of the stream of step (d) under the pressure and temperature conditions of step (d) and separately recovering each fraction;
  • step (f) further cooling the vapor fraction of step (e) to a temperature substantially below the boiling point of water at ambient pressure to separate a water fraction, a liquid oil fraction, and a vapor fraction and separately recovering each fraction;
  • a process for producing selected hydrocarbons from subterranean oil sand penetrated by an injection well and a production well which comprises the steps of:
  • step (b) water quenching the efiiuent from step (a) within said production well to a temperature in the range of 500 to 800 F. and a pressure in the range of 500 to 2000 p.s.i.g.;
  • step (c) recovering the vapor stream of step (b) from said production well;
  • step (d) removing any sand contained in the vapor stream of step (c);
  • step (e) reducing the pressure of the sand-free vapor stream of step (d) to about 300 p.s.i.g. and the temperature to not more than about 500 F.;
  • step (f) separating the liquid oil from the vapor fraction of the stream of step (e) under the pressure and temperature conditions of step (e) and separately recovering each fraction;
  • step (g) further cooling the vapor fraction of step (f) to a temperature substantially below the boiling point of water at ambient pressure to separate a Water fraction, a liquid oil fraction, and a vapor fraction and separately recovering each fraction;
  • step (h) fractionating the oil fraction of step (g) into an overhead light hydrocarbon fraction, at least one intermediate fraction, and a heavier bottom fraction and separately recovering each fraction.
  • step (a) is a reverse drive operation with air being injected thru said injection well and ignition initiated at said production well.
  • step (e) temperature reduction in step (e) is elTected principally by indirect heat exchange with air in air fin cooler and in step (g) first by indirect heat exchange with air in an air fin cooler and then by indirect heat exchange with Water.
  • Apparatus comprising in combination:
  • a first liquid vapor separator having an inlet for an oil feed, an outlet for liquid oil in a lower section, and a vapor outlet in an upper section;
  • a second liquid-vapor separator having a feed inlet in an intermediate section, a water outlet in a lower section, -a liquid oil outlet in a section intermediate said water outlet and said feed inlet;
  • the apparatus of claim 5 including:
  • a first liquid-vapor separator having an inlet for an oil feed, an outlet for liquid oil in a lower section, and a vapor outlet in an upper section;
  • a second liquid-vapor separator having a feed inlet in an intermediate section, a water outlet in a lower section, a liquid oil outlet in a section intermediate said water outlet and said feed inlet;
  • a fractionator having a feed inlet for liquid oil in an intermediate section, an outlet for a bottoms fraction, an outlet for an overhead fraction, an outlet for an intermediate fraction, a reboiler connected With the lower section; a reflux means connected with'the upper section thereof and with the overhead outlet; and

Description

March 21, 1967 w, MARX ETAL 3,310,109
PROCESS AND APPARATUS FOR COMBINATION UPGRADING OF OIL IN SITU AND REFINING THEREOF Filed NOV. 6, 1964 of :o GS/DI ow 3 mokww 558mm mmjoou Im IW @v NR 3 o I m moJ 9 :o E mm 5.528 msEmFZ mm m w z 96 3 2m .5256 vajhmm 20 CG; 0K
5 M RP m 0A T E MXN N N R R m AR O w w A Y B United States Patent Ofifice 3,310,109 Patented Mar. 21, 1967 3,310,109 PROCESS AND APPARATUS FOR COMBENATION UPGRADING OF OIL IN SITU AND REFENING THEREOF John W. Marx, William B. Belknap, and Joseph C. Trantham, Bartlesville, Okla, assignors to Phillips Petroleum Company, a corporation of Delaware Filed Nov. 6, 1964, Ser. No. 409,407 7 Claims. (Cl. 166-7) This invention relates to a process for producing oil by in situ combustion to upgrade the oil and refining the upgraded oil in the field near the well head.
Low gravity crude oil is particularly difficult to produce even though the pressure in the stratum containing the oil is substantial. In one well known sand bearing a heavy high viscosity crude having an API gravity of 8.5", the primary recovery is limited to about 2 or 3 percent of the in-place oil even though the static reservoir pressure is 1400 p.s.i. This leaves most of the oil in the stratum to be recovered by secondary production methods. It has been found that this 8.5 API gravity oil can be produced by reverse in situ combustion so as to upgrade the oil to about 26 to 27 API gravity as it leaves the well head.
The invention is concerned with a process for producing and upgrading a heavy oil in situ and recovering various fractions of the upgraded oil from the water-containing effiuent from the well head.
Accordingly, an object of this invention is to provide a combination process for upgrading a heavy oil in situ and refining the upgraded oil. Another object is to provide a process for refining an upgraded oil produced by in situ combustion and containing substantial concentrations of water while avoiding the formation of heavy oil-water or water-oil emulsions. A further object is to provide a refining process for recovering various oil fractions from upgraded crude oil produced by in situ combustion and containing large concentrations of water. Other objects of the invention will become apparent to one skilled in the art upon consideration of the accompanying disclosure.
A broad aspect of the invention comprises producing an upgraded oil from a heavy oil-bearing stratum by in situ combustion whereby the upgraded hot eifiuent contains substantial concentrations of Water and is at an elevated pressure, passing the vaporous efiluent from the well head of the production well thru a pressure reducing valve to substantially reduce the pressure thereof and cooling the resulting vapor stream to a temperature not substantially above 500 F. to recover a liquid heavy oil fraction and a separate vapor stream comprising oils boiling above about 500 F. and water. The foregoing procedure comprising cooling the in situ combustion effiuent to a temperature of not more than 500 F. and, preferably, at about 500 F., has the effect of preventing the formation of very refractory water-oil emulsions which are a serious problem when the heavy cut and the water are condensed together. The heavy cut is separately recovered at about 500 F. and the Water in the Well eflluent remains in vapor form and is passed along with the lower boiling hydrocarbons to a second cooling step to cool same to a temeprature substantially below the boiling point of the Water in the vaporous stream and, preferably, to about 100 F. The cooled stream comprising liquid hydrocarbons and water as well as vaporous hydrocarbons is separated into water, liquid oil, and light hydrocarbon gases. The liquid oil fraction is then passed to a conventional fractionator to separate the same into several cuts of different boiling ranges.
One method of upgrading the high gravity crude oil is disclosed in the copending application of I. C. Trantham and I. W. Marx, S.N. 383,285, filed July 17, 1964, now
US. Patent No. 3,232,345. However, the invention is applicable to the production of oil produced by any forward or reverse drive in situ combustion process. In a direct or forward drive process the temperature of the produced efiluent is not sufli-ciently high for application of the invention until the fire front approaches or passes the production Well. Since the combustion zone moves in a reverse direction to the flow of air in a reverse burning process and the products from the combustion zone pass thru burned over hot sand behind the combustion front on the way to the production well, the efiluent from the reverse burning process is usually above 1000 F. Due to the fact that some oxygen from the injected air bypasses the hot combustion zone and appears in the production Well, well bore fires destroy substantial quantities of the produced oil and damage well equipment unless precautions are taken. The injection of water or other fluid coolant into the production well adjacent the pro ducing zone to reduce the efiluent temperature to the range of 500800 F. is practiced. This results in incorporating in the upgraded oil a substantial quantity of water in addition to formation or connate water vaporized in the combustion phase of the process and water formed by combustion.
A more complete understanding of the invention may be obtained by reference to the accompanying schematic drawing which is a flow in accordance with a preferred embodiment of the process.
Referring to the drawing, a heavy oil bearing stratum 10 is penetrated by a production well 12. A combustion zone 14 has been moved out from well 12 into the stratum by injection of combustion-supporting gas thru one or more offset injection wells. The produced efiluent is recovered thru tubing string 16 and water injected from line 18 thru spray head 20 in sufficient quantity to reduce the temperature of the hot efiluent to the range of about SOD-800 F.
The hot effluent under substantial pressure in the range of about 500-2000 p.s.i.g. and at a temperature in the range of 500-800 F. is passed thru line 22 to a sand trap 24 for removal of any sand contained in the produced efiluent. The sand-free eflluent is passed thru line 26 to a liquid-gas separator 28. An expansion valve 30 substantially reduces the pressure of the efiluent to the range of about 250400 p.S.i.g. and, preferably, to about 300 p.s.i.g.
Expanded efiluent is cooled in a suitable cooler, preferably, an air fin type cooler 32 to reduce the temperature to not more thanabout 500 P. so that the oil in the vaporous stream boiling above this temperature is condensed and is recovered from separator 28 thru line 34. The uncondensed vapors including water and lower :boil ing hydrocarbons are passed overhead thru line 36 to a second gas-liquid separator 38. Air fin cooler 40 in line 36 economically reduces the temperature of the vaporous stream therein substantially and water cooler 42 further reduces the temperature to substantially below the boiling point of water at ambient pressure, such as about F. This condenses most of the water and the hydrocarbon fraction of the efiluent boiling above 100 F. In separator 38 water and oil are separated by phase separation in the lower section thereof and water is withdrawn thru line 44 while the oil fraction is with-drawn thru line 46 and passed to fractionating tower 48. The overhead gaseous stream from separator 38 is passed thru line 50 and thru a demister 52 from which separated liquid is removed thru line 54 and gaseous material is passed thru line 56 as exhaust gas with gas for analysis being taken off in a side stream thru line 58.
The liquid oil from line 46 is separated into various fractions in fractionator 48 in conventional manner, recovering the heavier oil th-ru line 60 as a bottoms fraction, the intermediate oil thru line 62 as a side cut, and the light oil fraction overhead thru lines 64 and 66 which connect with a surgetank -68. Reflux is passed from surge tank 68 to the upper section of the fractionator via line 70. Reboiler means 72 for heating the lower section of fractionator 48 is provided.
To illustrate the invention the upgraded oil from stratum is quenched to a temperature in the range of 500-800 F. at a pressure of about 1400 p.s.i.g. About 23 barrels of water per hour and 11 barrels of oil per hour constitute the hot efiluent passing into sand trap 24. Valve is set to control the pressure downstream thereof at about 300 p.s.i.g. Air fin cooler 32 reduces the temperature to about 500 F. when cooling is required to reduce the efiluent temperature. The oil fraction boiling above about 500 F. recovered thru line 34 amounts to 5.3 b./hr. The overhead vapor stream is cooled from about 500 F. to about 100 F. when passing thru heat exchangers and 42 with a substantial portion of the cooling being effected in the air fin cooler. This condenses substantially all of the water in the stream passing into separator 38 along with the oil boiling above 100 F. The condensed Water is recovered thru line 44 at the rate of about 23 b./ hr. and the condensed oil i passed thru line 46 at about 100 F. to fractionator 48. The fractionation in tower 48 is maintained at a pressure of about 50 p.s.i.g. with a reboiler temperature of about 525 F. The heavier oil having a boiling range of 400500 F. is recovered thru line '60 at the rate of about 2 b./ hr. while the intermediate oil fraction having a boiling range of 300400 F. is recovered thru line '62 at the rate of 1.7 b./hr. The light hydrocarbon overhead fraction having a boiling range of 100-300 F. is recovered thru line 66 at the rate of 2 b/ hr.
A counterfiow combustion test was run on the 8.5 API gravity oil referred to above at a pressure of about 250 p.s.i.g. and an oil of 265 API gravity was produced. The test demonstrated that counterflow or reverse combustion at elevated pressures produces rather light oils. A sample of the 26.5 API gravity oil was fractionated in conventional manner into 4 different boiling range fractions and the data from the distillation are presented in the table below.
Certain modifications of the invention will become apparent to those skilled in the art and the illustrative details disclosed are not to be construed as imposing unnecessary limitations on the invention.
We claim:
1. A process for producing selected hydrocarbons from subterranean oil sand penetrated by an injection well and a production well, which comprises the steps of:
(a) heating said oil by in situ combustion of a portion thereof so as to heat and crack another substantial portion thereof to lighter normally gaseous and liquid hydrocarbons, thereby producing an efiluent vapor stream at a temperature in the range of about 500 to 800 F. and a pressure in the range of about 500 to 2000 p.s.i.g.;
(b) recovering the vapor stream of step (a) from said production well;
(c) removing any sand contained in the vapor stream of step (b);
(d) reducing the pressure of the vapor stream of step (c) to about 300 p.s.i.g. and the temperature to not more than about 500 F.;
(e) separating the liquid oil from the vapor fraction of the stream of step (d) under the pressure and temperature conditions of step (d) and separately recovering each fraction;
(f) further cooling the vapor fraction of step (e) to a temperature substantially below the boiling point of water at ambient pressure to separate a water fraction, a liquid oil fraction, and a vapor fraction and separately recovering each fraction; and
(g) fractionating the oil fraction of (f) into an overhead light hydrocarbon fraction, at least one intermediate fraction, and a heavier bottoms fraction.
2. A process for producing selected hydrocarbons from subterranean oil sand penetrated by an injection well and a production well, which comprises the steps of:
(a) heating said oil by in situ combustion of a portion thereof so as to heat and crack another substantial portion thereof to lighter normally gaseous and liquid hydrocarbons, thereby producing an effluent vapor stream in said production well comprising oil and combustion gases at a temperature of at least 1000 F.;
(b) water quenching the efiiuent from step (a) within said production well to a temperature in the range of 500 to 800 F. and a pressure in the range of 500 to 2000 p.s.i.g.;
(c) recovering the vapor stream of step (b) from said production well;
(d) removing any sand contained in the vapor stream of step (c);
(e) reducing the pressure of the sand-free vapor stream of step (d) to about 300 p.s.i.g. and the temperature to not more than about 500 F.;
(f) separating the liquid oil from the vapor fraction of the stream of step (e) under the pressure and temperature conditions of step (e) and separately recovering each fraction;
(g) further cooling the vapor fraction of step (f) to a temperature substantially below the boiling point of water at ambient pressure to separate a Water fraction, a liquid oil fraction, and a vapor fraction and separately recovering each fraction; and
(h) fractionating the oil fraction of step (g) into an overhead light hydrocarbon fraction, at least one intermediate fraction, and a heavier bottom fraction and separately recovering each fraction.
3. The process of claim 2 wherein the oil in said sand is a heavy viscous crude oil and the combustion of step (a) is a reverse drive operation with air being injected thru said injection well and ignition initiated at said production well.
4. The process of claim 2 wherein temperature reduction in step (e) is elTected principally by indirect heat exchange with air in air fin cooler and in step (g) first by indirect heat exchange with air in an air fin cooler and then by indirect heat exchange with Water.
5. Apparatus comprising in combination:
(1) a well head connected by casing and tubing with an oil producing zone;
(2) a sand trap connected by a first conduit with said Well head for flow of fluid from said zone to said trap;
(3) a first liquid vapor separator having an inlet for an oil feed, an outlet for liquid oil in a lower section, and a vapor outlet in an upper section;
(4) a second conduit connecting said sand trap with the oil feed inlet of (3);
(5) an expansion valve and an air fin cooler down stream thereof in said second conduit;
(6) a second liquid-vapor separator having a feed inlet in an intermediate section, a water outlet in a lower section, -a liquid oil outlet in a section intermediate said water outlet and said feed inlet;
(7) a third conduit connecting the vapor outlet of the first separtor of (3) with the feed inlet of the second separator of (6);
(8) an air fin cooler and a water cooler downstream thereof in the third conduit of (7 (9) a fractionator having a feed inlet for liquid oil in an intermediate section, an outlet for a bottoms fraction, an outlet for an overhead fraction, an outlet for an intermediate fraction, a reboiler connected with the lower section; a reflux means connected with the upper section thereof and with the overhead outlet; and
(10) a fourth conduit connecting the liquid oil outlet of the second separator of (6) with the feed inlet of the fractionator of (9).
6. The apparatus of claim 5 including:
(11) spray means adjacent the lower end of the casing and the producing zone of (1) and (12) a water line connected With the spray means of 7. Apparatus comprising in combination:
(1) a well head connected by casing and tubing with an oil producing zone;
(2) a first liquid-vapor separator having an inlet for an oil feed, an outlet for liquid oil in a lower section, and a vapor outlet in an upper section;
(3) a first conduit connecting said well head with the feed inlet to the first separator of (2);
(4) an expansion valve and an indirect heat exchanger downstream thereof in the first conduit of (3);
(5) a second liquid-vapor separator having a feed inlet in an intermediate section, a water outlet in a lower section, a liquid oil outlet in a section intermediate said water outlet and said feed inlet;
(6) a second conduit connecting the vapor outlet of the first separator of (3) with the feed inlet of the second separator of (5);
(7) indirect heat exchange means in the second conduit of (6); Y
(8) a fractionator having a feed inlet for liquid oil in an intermediate section, an outlet for a bottoms fraction, an outlet for an overhead fraction, an outlet for an intermediate fraction, a reboiler connected With the lower section; a reflux means connected with'the upper section thereof and with the overhead outlet; and
(9) a third conduit connecting the liquid oil outlet of the second separator of (5) with the feed inlet of the fractionator of (8).
References Cited by the Examiner UNITED STATES PATENTS 2,327,187 8/1943 Hill 208354 X 2,426,110 8/ 1947 McCorquodale et al. 208354 X 2,900,312 8/1959 Gilmore 208354 3,202,219 8/1965 Parker 1667 X 3,240,270 3/1966 Marx 16611 X 3,254,711 6/1966 Parker 1667 CHARLES E. OCONNELL, Primary Examiner.
S. J. NOVOSAD, Assistaiit Examiner.

Claims (2)

1. A PROCESS FOR PRODUCING SELECTED HYDROCARBONS FROM SUBTERRANEAN OIL SAND PENETRATED BY AN INJECTION WELL AND A PRODUCTION WELL, WHICH COMPRISES THE STEPS OF: (A) HEATING SAID OIL BY IN SITU COMBUSTION OF A PORTION THEREOF SO AS TO HEAT AND CRACK ANOTHER SUBSTANTIAL PORTION THEREOF TO LIGHTER NORMALLY GASEOUS AND LIQUID HYDROCARBONS, THEREBY PRODUCING AN EFFLUENT VAPOR STREAM AT A TEMPERATURE IN THE RANGE OF ABOUT 500 TO 800*F. AND A PRESSURE IN THE RANGE OF ABOUT 500 TO 2000 P.S.I.G.; (B) RECOVERING THE VAPOR STREAM OF STEP (A) FROM SAID PRODUCTION WELL; (C) REMOVING ANY SAND CONTAINED IN THE VAPOR STREAM OF STEP (B); (D) REDUCING THE PRESSURE OF THE VAPOR STREAM OF STEP (C) TO ABOUT 300 P.S.I.G. AND THE TEMPERATURE TO NOT MORE THAN ABOUT 500*F.; (E) SEPARATING THE LIQUID OIL FROM THE VAPOR FRACTION OF THE STREAM OF STEP (D) UNDER THE PRESSURE AND TEMPERATURE CONDITIONS OF STEP (D) AND SEPARATELY RECOVERING EACH FRACTION; (F) FURTHER COOLING THE VAPOR FRACTION OF STEP (E) TO A TEMPERATURE SUBSTANTIALLY BELOW THE BOILING POINT OF WATER AT AMBIENT PRESSURE TO SEPARATE A WATER FRACTION, A LIQUID OIL FRACTION, AND A VAPOR FRACTION AND SEPARATELY RECOVERING EACH FRACTION; AND (G) FRACTIONATING THE OIL FRACTION OF (F) INTO AN OVERHEAD LIGHT HYDROCARBON FRACTION, AT LEAST ONE INTERMEDIATE FRACTION, AND A HEAVIER BOTTOMS FRACTION.
7. APPARATUS COMPRISING IN COMBINATION: (1) A WELL HEAD CONNECTED BY CASING AND TUBING WITH AN OIL PRODUCING ZONE; (2) A FIRST LIQUID-VAPOR SEPARATOR HAVING AN INLET FOR AN OIL FEED, AN OUTLET FOR LIQUID OIL IN A LOWER SECTION, AND A VAPOR OUTLET IN AN UPPER SECTION; (3) A FIRST CONDUIT CONNECTING SAID WELL HEAD WITH THE FEED INLET TO THE FIRST SEPARATOR OF (2); (4) AN EXPANSION VALVE AND AN INDIRECT HEAT EXCHANGER DOWNSTREAM THEREOF IN THE FIRST CONDUIT OF (3); (5) A SECOND LIQUID-VAPOR SEPARATOR HAVING A FEED INLET IN AN INTERMEDIATE SECTION, A WATER OUTLET IN A LOWER SECTION, A LIQUID OIL OUTLET IN A SECTION INTERMEDIATE SAID WATER OUTLET AND SAID FEED INLET; (6) A SECOND CONDUIT CONNECTING THE VAPOR OUTLET OF THE FIRST SEPARATOR OF (3) WITH THE FEED INLET OF THE SECOND SEPARATOR OF (5); (7) INDIRECT HEAT EXCHANGE MEANS IN THE SECOND CONDUIT OF (6); (8) A FRACTIONATOR HAVING A FEED INLET FOR LIQUID OIL IN AN INTERMEDIATE SECTION, AN OUTLET FOR A BOTTOMS FRACTION, AN OUTLET FOR AN OVERHEAD FRACTION, AN OUTLET FOR AN INTERMEDIATE FRACTION, A REBOILER CONNECTED WITH THE LOWER SECTION; A REFLUX MEANS CONNECTED WITH THE UPPER SECTION THEREOF AND WITH THE OVERHEAD OUTLET; AND (9) A THIRD CONDUIT CONNECTING THE LIQUID OIL OUTLET OF THE SECOND SEPARATOR OF (5) WITH THE FEED INLET OF THE FRACTIONATOR OF (8).
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Cited By (44)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US3380913A (en) * 1964-12-28 1968-04-30 Phillips Petroleum Co Refining of effluent from in situ combustion operation
US3442332A (en) * 1966-02-01 1969-05-06 Percival C Keith Combination methods involving the making of gaseous carbon dioxide and its use in crude oil recovery
US3759324A (en) * 1972-05-25 1973-09-18 Kobe Inc Cleaning apparatus for oil well production
US4303127A (en) * 1980-02-11 1981-12-01 Gulf Research & Development Company Multistage clean-up of product gas from underground coal gasification
US4778586A (en) * 1985-08-30 1988-10-18 Resource Technology Associates Viscosity reduction processing at elevated pressure
US4818371A (en) * 1987-06-05 1989-04-04 Resource Technology Associates Viscosity reduction by direct oxidative heating
US20020027001A1 (en) * 2000-04-24 2002-03-07 Wellington Scott L. In situ thermal processing of a coal formation to produce a selected gas mixture
US6588504B2 (en) 2000-04-24 2003-07-08 Shell Oil Company In situ thermal processing of a coal formation to produce nitrogen and/or sulfur containing formation fluids
US20030173080A1 (en) * 2001-04-24 2003-09-18 Berchenko Ilya Emil In situ thermal processing of an oil shale formation using a pattern of heat sources
US20030192693A1 (en) * 2001-10-24 2003-10-16 Wellington Scott Lee In situ thermal processing of a hydrocarbon containing formation to produce heated fluids
US20030192691A1 (en) * 2001-10-24 2003-10-16 Vinegar Harold J. In situ recovery from a hydrocarbon containing formation using barriers
US20040020642A1 (en) * 2001-10-24 2004-02-05 Vinegar Harold J. In situ recovery from a hydrocarbon containing formation using conductor-in-conduit heat sources with an electrically conductive material in the overburden
US6698515B2 (en) 2000-04-24 2004-03-02 Shell Oil Company In situ thermal processing of a coal formation using a relatively slow heating rate
US6715546B2 (en) 2000-04-24 2004-04-06 Shell Oil Company In situ production of synthesis gas from a hydrocarbon containing formation through a heat source wellbore
US6715548B2 (en) 2000-04-24 2004-04-06 Shell Oil Company In situ thermal processing of a hydrocarbon containing formation to produce nitrogen containing formation fluids
US20040074838A1 (en) * 2002-10-10 2004-04-22 Hemstock Christopher A. Desanding apparatus and system
US20040144541A1 (en) * 2002-10-24 2004-07-29 Picha Mark Gregory Forming wellbores using acoustic methods
US7640987B2 (en) 2005-08-17 2010-01-05 Halliburton Energy Services, Inc. Communicating fluids with a heated-fluid generation system
US7770643B2 (en) 2006-10-10 2010-08-10 Halliburton Energy Services, Inc. Hydrocarbon recovery using fluids
US7809538B2 (en) 2006-01-13 2010-10-05 Halliburton Energy Services, Inc. Real time monitoring and control of thermal recovery operations for heavy oil reservoirs
US7832482B2 (en) 2006-10-10 2010-11-16 Halliburton Energy Services, Inc. Producing resources using steam injection
US7866388B2 (en) 2007-10-19 2011-01-11 Shell Oil Company High temperature methods for forming oxidizer fuel
WO2011033685A1 (en) * 2009-09-18 2011-03-24 Toyo Engineering Corporation Method of partially upgrading heavy oil at well-site
US7942203B2 (en) 2003-04-24 2011-05-17 Shell Oil Company Thermal processes for subsurface formations
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US9327214B2 (en) 2012-02-13 2016-05-03 Specialized Desanders Inc. Desanding apparatus and a method of using same
US9861921B2 (en) 2013-12-16 2018-01-09 Specialized Desanders Inc. Desanding apparatus and a method of using the same
US9909405B2 (en) 2012-02-13 2018-03-06 Specialized Desanders Inc. Desanding apparatus and a method of using same
US9938812B2 (en) 2012-02-13 2018-04-10 Specialized Desanders Inc. Desanding apparatus and a method of using same
US10047594B2 (en) 2012-01-23 2018-08-14 Genie Ip B.V. Heater pattern for in situ thermal processing of a subsurface hydrocarbon containing formation
US10487636B2 (en) 2017-07-27 2019-11-26 Exxonmobil Upstream Research Company Enhanced methods for recovering viscous hydrocarbons from a subterranean formation as a follow-up to thermal recovery processes
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Citations (6)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US2327187A (en) * 1939-08-31 1943-08-17 Stanolind Oil & Gas Company Recovery of distillate hydrocarbons from well fluids
US2426110A (en) * 1942-10-14 1947-08-19 Sun Oil Co Distillation of crude petroleum
US2900312A (en) * 1957-10-16 1959-08-18 Phillips Petroleum Co Fractionation
US3202219A (en) * 1962-02-09 1965-08-24 Phillips Petroleum Co Apparatus for protection of in situ combustion wells
US3240270A (en) * 1958-05-02 1966-03-15 Phillips Petroleum Co Recovery of hydrocarbons by in situ combustion
US3254711A (en) * 1963-08-29 1966-06-07 Phillips Petroleum Co Natural gasoline conservation during in situ combustion

Patent Citations (6)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US2327187A (en) * 1939-08-31 1943-08-17 Stanolind Oil & Gas Company Recovery of distillate hydrocarbons from well fluids
US2426110A (en) * 1942-10-14 1947-08-19 Sun Oil Co Distillation of crude petroleum
US2900312A (en) * 1957-10-16 1959-08-18 Phillips Petroleum Co Fractionation
US3240270A (en) * 1958-05-02 1966-03-15 Phillips Petroleum Co Recovery of hydrocarbons by in situ combustion
US3202219A (en) * 1962-02-09 1965-08-24 Phillips Petroleum Co Apparatus for protection of in situ combustion wells
US3254711A (en) * 1963-08-29 1966-06-07 Phillips Petroleum Co Natural gasoline conservation during in situ combustion

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US3380913A (en) * 1964-12-28 1968-04-30 Phillips Petroleum Co Refining of effluent from in situ combustion operation
US3442332A (en) * 1966-02-01 1969-05-06 Percival C Keith Combination methods involving the making of gaseous carbon dioxide and its use in crude oil recovery
US3759324A (en) * 1972-05-25 1973-09-18 Kobe Inc Cleaning apparatus for oil well production
US3802501A (en) * 1972-05-25 1974-04-09 Kobe Inc Cleaning apparatus for oil well production
US4303127A (en) * 1980-02-11 1981-12-01 Gulf Research & Development Company Multistage clean-up of product gas from underground coal gasification
US4778586A (en) * 1985-08-30 1988-10-18 Resource Technology Associates Viscosity reduction processing at elevated pressure
US4818371A (en) * 1987-06-05 1989-04-04 Resource Technology Associates Viscosity reduction by direct oxidative heating
US5008085A (en) * 1987-06-05 1991-04-16 Resource Technology Associates Apparatus for thermal treatment of a hydrocarbon stream
US6725928B2 (en) 2000-04-24 2004-04-27 Shell Oil Company In situ thermal processing of a coal formation using a distributed combustor
US6588504B2 (en) 2000-04-24 2003-07-08 Shell Oil Company In situ thermal processing of a coal formation to produce nitrogen and/or sulfur containing formation fluids
US20020053431A1 (en) * 2000-04-24 2002-05-09 Wellington Scott Lee In situ thermal processing of a hydrocarbon containing formation to produce a selected ratio of components in a gas
US20020132862A1 (en) * 2000-04-24 2002-09-19 Vinegar Harold J. Production of synthesis gas from a coal formation
US6581684B2 (en) 2000-04-24 2003-06-24 Shell Oil Company In Situ thermal processing of a hydrocarbon containing formation to produce sulfur containing formation fluids
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US20030196788A1 (en) * 2001-10-24 2003-10-23 Vinegar Harold J. Producing hydrocarbons and non-hydrocarbon containing materials when treating a hydrocarbon containing formation
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US8220539B2 (en) 2008-10-13 2012-07-17 Shell Oil Company Controlling hydrogen pressure in self-regulating nuclear reactors used to treat a subsurface formation
US8434555B2 (en) 2009-04-10 2013-05-07 Shell Oil Company Irregular pattern treatment of a subsurface formation
US8851170B2 (en) 2009-04-10 2014-10-07 Shell Oil Company Heater assisted fluid treatment of a subsurface formation
US8327932B2 (en) 2009-04-10 2012-12-11 Shell Oil Company Recovering energy from a subsurface formation
US8448707B2 (en) 2009-04-10 2013-05-28 Shell Oil Company Non-conducting heater casings
WO2011033685A1 (en) * 2009-09-18 2011-03-24 Toyo Engineering Corporation Method of partially upgrading heavy oil at well-site
EA026096B1 (en) * 2009-09-18 2017-03-31 Тойо Инджиниринг Корпорейшн Method of partially upgrading heavy oil at well-site
US8833453B2 (en) 2010-04-09 2014-09-16 Shell Oil Company Electrodes for electrical current flow heating of subsurface formations with tapered copper thickness
US8820406B2 (en) 2010-04-09 2014-09-02 Shell Oil Company Electrodes for electrical current flow heating of subsurface formations with conductive material in wellbore
US8631866B2 (en) 2010-04-09 2014-01-21 Shell Oil Company Leak detection in circulated fluid systems for heating subsurface formations
US8739874B2 (en) 2010-04-09 2014-06-03 Shell Oil Company Methods for heating with slots in hydrocarbon formations
US8701769B2 (en) 2010-04-09 2014-04-22 Shell Oil Company Methods for treating hydrocarbon formations based on geology
US9022109B2 (en) 2010-04-09 2015-05-05 Shell Oil Company Leak detection in circulated fluid systems for heating subsurface formations
US9033042B2 (en) 2010-04-09 2015-05-19 Shell Oil Company Forming bitumen barriers in subsurface hydrocarbon formations
US9399905B2 (en) 2010-04-09 2016-07-26 Shell Oil Company Leak detection in circulated fluid systems for heating subsurface formations
US8701768B2 (en) 2010-04-09 2014-04-22 Shell Oil Company Methods for treating hydrocarbon formations
US9127523B2 (en) 2010-04-09 2015-09-08 Shell Oil Company Barrier methods for use in subsurface hydrocarbon formations
US9127538B2 (en) 2010-04-09 2015-09-08 Shell Oil Company Methodologies for treatment of hydrocarbon formations using staged pyrolyzation
US9016370B2 (en) 2011-04-08 2015-04-28 Shell Oil Company Partial solution mining of hydrocarbon containing layers prior to in situ heat treatment
US9062525B2 (en) * 2011-07-07 2015-06-23 Single Buoy Moorings, Inc. Offshore heavy oil production
US20130008663A1 (en) * 2011-07-07 2013-01-10 Donald Maclean Offshore heavy oil production
US9309755B2 (en) 2011-10-07 2016-04-12 Shell Oil Company Thermal expansion accommodation for circulated fluid systems used to heat subsurface formations
US10047594B2 (en) 2012-01-23 2018-08-14 Genie Ip B.V. Heater pattern for in situ thermal processing of a subsurface hydrocarbon containing formation
US9327214B2 (en) 2012-02-13 2016-05-03 Specialized Desanders Inc. Desanding apparatus and a method of using same
US9909405B2 (en) 2012-02-13 2018-03-06 Specialized Desanders Inc. Desanding apparatus and a method of using same
US9938812B2 (en) 2012-02-13 2018-04-10 Specialized Desanders Inc. Desanding apparatus and a method of using same
US9861921B2 (en) 2013-12-16 2018-01-09 Specialized Desanders Inc. Desanding apparatus and a method of using the same
US11142681B2 (en) 2017-06-29 2021-10-12 Exxonmobil Upstream Research Company Chasing solvent for enhanced recovery processes
US10487636B2 (en) 2017-07-27 2019-11-26 Exxonmobil Upstream Research Company Enhanced methods for recovering viscous hydrocarbons from a subterranean formation as a follow-up to thermal recovery processes
US11002123B2 (en) 2017-08-31 2021-05-11 Exxonmobil Upstream Research Company Thermal recovery methods for recovering viscous hydrocarbons from a subterranean formation
US11261725B2 (en) 2017-10-24 2022-03-01 Exxonmobil Upstream Research Company Systems and methods for estimating and controlling liquid level using periodic shut-ins

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