US3351434A - Liquid-liquid two-phase contactor - Google Patents
Liquid-liquid two-phase contactor Download PDFInfo
- Publication number
- US3351434A US3351434A US462294A US46229465A US3351434A US 3351434 A US3351434 A US 3351434A US 462294 A US462294 A US 462294A US 46229465 A US46229465 A US 46229465A US 3351434 A US3351434 A US 3351434A
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- US
- United States
- Prior art keywords
- liquid
- liquids
- solution
- disks
- component
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- Expired - Lifetime
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Classifications
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01F—MIXING, e.g. DISSOLVING, EMULSIFYING OR DISPERSING
- B01F27/00—Mixers with rotary stirring devices in fixed receptacles; Kneaders
- B01F27/05—Stirrers
- B01F27/11—Stirrers characterised by the configuration of the stirrers
- B01F27/112—Stirrers characterised by the configuration of the stirrers with arms, paddles, vanes or blades
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01D—SEPARATION
- B01D11/00—Solvent extraction
- B01D11/04—Solvent extraction of solutions which are liquid
- B01D11/0446—Juxtaposition of mixers-settlers
- B01D11/0457—Juxtaposition of mixers-settlers comprising rotating mechanisms, e.g. mixers, mixing pumps
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01F—MIXING, e.g. DISSOLVING, EMULSIFYING OR DISPERSING
- B01F27/00—Mixers with rotary stirring devices in fixed receptacles; Kneaders
- B01F27/05—Stirrers
- B01F27/11—Stirrers characterised by the configuration of the stirrers
- B01F27/115—Stirrers characterised by the configuration of the stirrers comprising discs or disc-like elements essentially perpendicular to the stirrer shaft axis
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01F—MIXING, e.g. DISSOLVING, EMULSIFYING OR DISPERSING
- B01F27/00—Mixers with rotary stirring devices in fixed receptacles; Kneaders
- B01F27/60—Mixers with rotary stirring devices in fixed receptacles; Kneaders with stirrers rotating about a horizontal or inclined axis
- B01F27/73—Mixers with rotary stirring devices in fixed receptacles; Kneaders with stirrers rotating about a horizontal or inclined axis with rotary discs
Definitions
- This invention relates generally to what is known as a two-phase contactor. More specifically, this invention relates to a unique type of two-phase contactor that is particularly designed and useful a a liquid extractor used with two immiscible liquids.
- the two-phase contactor generally utilizes a plurality of elements which are dipped into a liquid, exposed to gas and then returned to the liquid.
- This type of device can also be used with two immiscible liquids in which case the element pass through one liquid into the other and then return to the first liquid.
- One purpose of passing the disks alternately through the different liquids is to extract from one liquid a particular component and transfer it in the second liquid.
- An example of this type of an application would be the transfer of an acid from hexane to water or the transfer of penicillin from a fermentation media to an organic liquid, after which the organic liquid is evaporated leaving the penicillin concentrate.
- the two-phase contactor of this invention overcomes the problems described above by providing a disk having a unique configuration which effectively transfers a component of one solution into the second solution while still permitting the liquids to flow thorugh the contactor.
- Another object of this invention is to provide a new and improved two-phase contactor as an extractor in connection with two immiscible liquids.
- FIG. 1 is an isometric View of a two-phase contactor of this invention
- FIG. 2 is a front view of the preferred disk for use in the two-phase contactor of this invention.
- FIG. 3 is a front view of an alternate disk for use in the two-phase contactor of this invention.
- the two-phase contactor of this invention is illustrated as a liquid-liquid extractor having a tank 11 with a first solution 12 flowing in the lower portion of the tank and a second solution 13 flowing in the upper portion of the tank.
- a horizontally disposed shaft 14 is rotatably mounted in a pair of spaced apart bearings 15 and a plurality of disks 16 are mounted on the shaft 14 intermediate the bearings 15 for rotation in a substantially vertical plane.
- the disks are located so that about one-half of each disk is in contact with each of the two solutions in the tank.
- a suitable source of power such as an electric motor is provided for rotating the shaft.
- the shaft is rotated at a relatively slow speed to avoid creating an excess amount of turbulence in the contactor tank.
- the tank 11 is provided with appropriate inlets and outlets to control the flow of the various solution through the tank. Specifically, as shown, there is an inlet 18 in the upper portion of the tank at one end thereof and an outlet 19 at the other end of the tank in the upper portion. In the lower portion of the tank there is an inlet 20 at one end and an outlet 21 at the other. It is preferred that the solution in the lower portion of the tank flows countercurrent to the solution in the upper portion of the tank. Therefore, appropriate pumping means such as pumps 23, 24 are provided to direct the flow of the solutions in the desired directions.
- the preferred disk 16 as illustrated in FIG. 2 is basically a flat circular member with a plurality of pie shaped sections removed. Hence, the disk has a plurality of rather wide, arcuately spaced spokelike members 17 extending radially outward from a hub 25.
- the purpose of having the disk in this configuration is to provide a sufficient space between the spokelike members 17 to allow liquid to fiow longitudinally through the tank as the disks are being rotated. It is important that the width of the space between the spokelike members is sufficient to prevent filming over by the liquids or solutions being treated.
- FIG. 3 An alternate disk 30 is illustrated in FIG. 3.
- a plurality of arcuately spaced members 31 extend radially outward from a hub 32 and form therebetween radial slots 33.
- the disks 30 have the advantage of having a more uniform width throughout their length and thereby allow for a greater amount of liquid to flow at the radially inner portion of the disk members as compared to disk 16 while also providing more surface area on the disk for use as a transfer agent.
- the disks 16 tend to break up any filming over of the solutions more quickly than the disks 30 and, hence, are preferred for use with more viscous solutions.
- the two immiscible liquids or solutions are pumped through the two-phase contactor tank in their different strata.
- the disks 16 are wetted by the solution containing the component to be transferred.
- the component is transferred to the second solution in which it is more soluble than the first solution.
- the second solution is then removed from the tank through the outlet and the component separated therefrom.
- the material of the disk has to be carefully chosen so that it is only wettable by the solution containing the component to be transferred.
- the second solution is not only insoluble in the first solution, but is also of substantialiy different density so that it is easily separated from the first solution.
- the component has to be more soluble in the second solution than the first solution so that the component will transfer from the first solution to the second as the disks rotate through the second solution.
- the disks are rotated at relatively slow speeds to avoid creating excessive turbulence which creates stable emulsions which in turn prevent complete separation of the solutions after transfer of the component.
- Another use of the two-phase contactor in connection with two immiscible liquids is a heat transfer device. This is accomplished by the disks as they rotate through a solution to pick up the hotter liquid and pass it through the cooler liquid whereby the cooler liquid picks up heat from the hotter liquid.
- the hotter liquid remains separate from the cooler liquid because of the differences in densities and solubility between solutions.
- the process could be reversed so that the cooler liquid is more wettable than the hotter liquid and thereby will be picked up by the disk and passed through the hotter liquid so as to cool that liquid.
- An apparatus for contacting first and second immiscible liquids comprising: an elongated tank having its longitudinal axis generally horizontal, a shaft extending longitudinally of and rotatably mounted in said tank, means for rotating said shaft, a plurality of disks wettable by said first liquid and not wettable by said second liquid mounted on and axially spaced along said shaft and positioned within said tank, means for introducing said first and second liquids near opposite ends of said tank, means for conducting said first and second liquids in countercurrent relation through and for withdrawing them near opposite ends of said tank, said disks having arcuately spaced radially extending members in planes perpendicular to the axis of said shaft protruding to the outer periphery of the disks and forming generally V- shaped slots therebetween, the width of said slots being 1.1 sufficiently large to prevent said liquids from filming over between adjacent radially extending members.
- a liquid-liquid contacting process comprising the steps of flowing through an elongated vessel a first liquid having a component to be extracted, flowing through said vessel in contact with and countercurrent to said first liquid, a second liquid immiscible with and of different density from said first liquid and in which said component is more soluble than in said first liquid, and rotating within said vessel, about an axis generally parallel to the interface between said liquids, disks which are wettable by said first liquid and are not wettable by said second liquid and having arcuately spaced, radially extending portions in planes perpendicular to said axis and radial slots therebetween of sufficient width to prevent said liquids from filming over between adjacent radially extending portions, said disks being rotated at a sufficiently slow speed to prevent formation of a stable emulsion of said first and second liquids.
Description
United States Patent 3,351,434 LIQUID-LIQUID TWO-PHASE CONTAUTUR Patrick G. Grimes, Milwaukee, and Marvin C. Raether,
Middleton, Wis, assignors to Allis-Chalmers Manufacturing Company, Milwaukee, Wis.
Filed June 8, 1965, Ser. No. 462,34 3 Claims. (Cl. 23-310) This invention relates generally to what is known as a two-phase contactor. More specifically, this invention relates to a unique type of two-phase contactor that is particularly designed and useful a a liquid extractor used with two immiscible liquids.
The two-phase contactor generally utilizes a plurality of elements which are dipped into a liquid, exposed to gas and then returned to the liquid. This type of device can also be used with two immiscible liquids in which case the element pass through one liquid into the other and then return to the first liquid. One purpose of passing the disks alternately through the different liquids is to extract from one liquid a particular component and transfer it in the second liquid. An example of this type of an application would be the transfer of an acid from hexane to water or the transfer of penicillin from a fermentation media to an organic liquid, after which the organic liquid is evaporated leaving the penicillin concentrate.
The primary difficulty encountered in utilizing a twophase contactor in handling two immiscible liquids has been the problem of getting a sufiicient volume of the liquids to flow through the contactor because of the interference of the disk. Some attempts were made to overcome this problem by forming holes in the disk but it was found that these holes tended to film over and form a wall and thereby prevent further flow of liquid through the openings.
The two-phase contactor of this invention overcomes the problems described above by providing a disk having a unique configuration which effectively transfers a component of one solution into the second solution while still permitting the liquids to flow thorugh the contactor.
Therefore, it is the object of this invention to provide a new and improved two-phase contactor.
Another object of this invention is to provide a new and improved two-phase contactor as an extractor in connection with two immiscible liquids.
Other objects and advantages will be apparent from the following description when read in connection with the accompanying drawings, in which:
FIG. 1 is an isometric View of a two-phase contactor of this invention;
FIG. 2 is a front view of the preferred disk for use in the two-phase contactor of this invention; and
FIG. 3 is a front view of an alternate disk for use in the two-phase contactor of this invention.
Referring more specifically to the drawings by characters of reference, the two-phase contactor of this invention is illustrated as a liquid-liquid extractor having a tank 11 with a first solution 12 flowing in the lower portion of the tank and a second solution 13 flowing in the upper portion of the tank. A horizontally disposed shaft 14 is rotatably mounted in a pair of spaced apart bearings 15 and a plurality of disks 16 are mounted on the shaft 14 intermediate the bearings 15 for rotation in a substantially vertical plane. The disks are located so that about one-half of each disk is in contact with each of the two solutions in the tank. A suitable source of power such as an electric motor is provided for rotating the shaft. Preferably the shaft is rotated at a relatively slow speed to avoid creating an excess amount of turbulence in the contactor tank.
The tank 11 is provided with appropriate inlets and outlets to control the flow of the various solution through the tank. Specifically, as shown, there is an inlet 18 in the upper portion of the tank at one end thereof and an outlet 19 at the other end of the tank in the upper portion. In the lower portion of the tank there is an inlet 20 at one end and an outlet 21 at the other. It is preferred that the solution in the lower portion of the tank flows countercurrent to the solution in the upper portion of the tank. Therefore, appropriate pumping means such as pumps 23, 24 are provided to direct the flow of the solutions in the desired directions.
The preferred disk 16 as illustrated in FIG. 2 is basically a flat circular member with a plurality of pie shaped sections removed. Hence, the disk has a plurality of rather wide, arcuately spaced spokelike members 17 extending radially outward from a hub 25. The purpose of having the disk in this configuration is to provide a sufficient space between the spokelike members 17 to allow liquid to fiow longitudinally through the tank as the disks are being rotated. It is important that the width of the space between the spokelike members is sufficient to prevent filming over by the liquids or solutions being treated.
An alternate disk 30 is illustrated in FIG. 3. In this disk a plurality of arcuately spaced members 31 extend radially outward from a hub 32 and form therebetween radial slots 33. The disks 30 have the advantage of having a more uniform width throughout their length and thereby allow for a greater amount of liquid to flow at the radially inner portion of the disk members as compared to disk 16 while also providing more surface area on the disk for use as a transfer agent. The disks 16 tend to break up any filming over of the solutions more quickly than the disks 30 and, hence, are preferred for use with more viscous solutions.
In operation, the two immiscible liquids or solutions are pumped through the two-phase contactor tank in their different strata. As the shaft 14 rotates, the disks 16 are wetted by the solution containing the component to be transferred. As the wetted disk moves through the second solution the component is transferred to the second solution in which it is more soluble than the first solution. The second solution is then removed from the tank through the outlet and the component separated therefrom.
To elfectively carry out the transfer of a component from one solution into the second solution, the material of the disk has to be carefully chosen so that it is only wettable by the solution containing the component to be transferred. Furthermore, the second solution is not only insoluble in the first solution, but is also of substantialiy different density so that it is easily separated from the first solution. Also, the component has to be more soluble in the second solution than the first solution so that the component will transfer from the first solution to the second as the disks rotate through the second solution. The disks are rotated at relatively slow speeds to avoid creating excessive turbulence which creates stable emulsions which in turn prevent complete separation of the solutions after transfer of the component.
Experimental work has shown that materials such as polymerized fluorcarbon and polymerized acrylic have unique characteristics which make them wettable by one solution and not by another. It has been further found that the roughing of the surface of these materials affects the amount of liquid that they will pick up in either phase. As an example, in a contactor used as an extractor between an aqueous solution and an organic solution such as hexane, a polymerized acrylic disk will be wetted by the aqueous solution and transfer a component of this solution to the organic solution. Hence, for each particular application the material of the disk has to be chosen after consideration of the materials being treated, the direction of transfer, and the component to be transferred.
Another use of the two-phase contactor in connection with two immiscible liquids is a heat transfer device. This is accomplished by the disks as they rotate through a solution to pick up the hotter liquid and pass it through the cooler liquid whereby the cooler liquid picks up heat from the hotter liquid. The hotter liquid remains separate from the cooler liquid because of the differences in densities and solubility between solutions. Of course, the process could be reversed so that the cooler liquid is more wettable than the hotter liquid and thereby will be picked up by the disk and passed through the hotter liquid so as to cool that liquid.
Although but two embodiments of this invention have been illustrated and described, it will be apparent to those skilled in the art that various changes and modifications can be made herein without departing from the spirit of the invention or from the scope of the appended claims.
The embodiments of the invention in which an exclusive property or privilege is claimed are defined as follows:
1. An apparatus for contacting first and second immiscible liquids comprising: an elongated tank having its longitudinal axis generally horizontal, a shaft extending longitudinally of and rotatably mounted in said tank, means for rotating said shaft, a plurality of disks wettable by said first liquid and not wettable by said second liquid mounted on and axially spaced along said shaft and positioned within said tank, means for introducing said first and second liquids near opposite ends of said tank, means for conducting said first and second liquids in countercurrent relation through and for withdrawing them near opposite ends of said tank, said disks having arcuately spaced radially extending members in planes perpendicular to the axis of said shaft protruding to the outer periphery of the disks and forming generally V- shaped slots therebetween, the width of said slots being 1.1 sufficiently large to prevent said liquids from filming over between adjacent radially extending members.
2. The apparatus of claim 1 in which the slots in said disks have substantially uniform width in an arcuate direction along substantially their entire radial dimension.
3. A liquid-liquid contacting process comprising the steps of flowing through an elongated vessel a first liquid having a component to be extracted, flowing through said vessel in contact with and countercurrent to said first liquid, a second liquid immiscible with and of different density from said first liquid and in which said component is more soluble than in said first liquid, and rotating within said vessel, about an axis generally parallel to the interface between said liquids, disks which are wettable by said first liquid and are not wettable by said second liquid and having arcuately spaced, radially extending portions in planes perpendicular to said axis and radial slots therebetween of sufficient width to prevent said liquids from filming over between adjacent radially extending portions, said disks being rotated at a sufficiently slow speed to prevent formation of a stable emulsion of said first and second liquids.
References Cited 754,337 8/1956 Great Britain. REUBEN FRIEDMAN, Primary Examiner.
I. DECESARE, Assistant Examiner.
Claims (1)
- 3. A LIQUID-LIQUID CONTACTING PROCESS COMPRISING THE STEPS OF FLOWING THROUGH AN ELONGATED VESSEL A FIRST LIQUID HAVING A COMPONENT TO BE EXTRACTED, FLOWING THROUGH SAID VESSEL IN CONTACT WITH AND COUNTERCURRENT TO SAID FIRST LIQUID, A SECOND LIQUID IMMISCIBLE WITH AND OF DIFFERENT DENSITY FROM SAID FIRST LIQUID AND IN WHICH SAID COMPONENT IS MORE SOLUBLE THAN IN SAID FIRST LIQUID, AND ROTATING WITHIN SAID VESSEL, ABOUT AN AXIS GENERALLY PARALLEL TO THE INTERFACE BETWEEN SAID LIQUIDS, DISKS WHICH ARE WETTABLE BY SAID FIRST LIQUID AND ARE NOT WETTABLE BY SAID SECOND LIQUID AND HAVING ARCUATELY SPACED, RADIALLY EXTENDING PORTIONS IN PLANES PERPENDICULAR TO SAID AXIS AND RADIAL SLOTS THEREBETWEEN OF SUFFICIENT WIDTH TO PREVENT SAID LIQUIDS FROM FILMING OVER BETWEEN ADJACENT RADIALLY EXTENDING PORTIONS, SAID DISKS BEING ROTATED AT A SUFFICIENTLY SLOW SPEED TO PREVENT FORMATION OF A STABLE EMULSION OF SAID FIRST AND SECOND LIQUIDS.
Priority Applications (5)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
US462294A US3351434A (en) | 1965-06-08 | 1965-06-08 | Liquid-liquid two-phase contactor |
IL25899A IL25899A (en) | 1965-06-08 | 1966-06-01 | Two-phase contactor apparatus |
GB25274/66A GB1134709A (en) | 1965-06-08 | 1966-06-07 | Improvements in or relating to two-phase contactor apparatus |
DE19661517979 DE1517979A1 (en) | 1965-06-08 | 1966-06-08 | Two-phase contact device |
CH824966A CH443226A (en) | 1965-06-08 | 1966-06-08 | Apparatus for bringing two immiscible liquids into contact |
Applications Claiming Priority (1)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
US462294A US3351434A (en) | 1965-06-08 | 1965-06-08 | Liquid-liquid two-phase contactor |
Publications (1)
Publication Number | Publication Date |
---|---|
US3351434A true US3351434A (en) | 1967-11-07 |
Family
ID=23835914
Family Applications (1)
Application Number | Title | Priority Date | Filing Date |
---|---|---|---|
US462294A Expired - Lifetime US3351434A (en) | 1965-06-08 | 1965-06-08 | Liquid-liquid two-phase contactor |
Country Status (5)
Country | Link |
---|---|
US (1) | US3351434A (en) |
CH (1) | CH443226A (en) |
DE (1) | DE1517979A1 (en) |
GB (1) | GB1134709A (en) |
IL (1) | IL25899A (en) |
Cited By (8)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
US4276701A (en) * | 1979-03-21 | 1981-07-07 | Richter Gedeon Vegyeszeti Gyar Rt | Apparatus for the drying of wet, pasty and/or fusible materials |
US4491565A (en) * | 1983-01-20 | 1985-01-01 | Uop Inc. | Countercurrent liquid-liquid contacting apparatus |
US4753722A (en) * | 1986-06-17 | 1988-06-28 | Merichem Company | Treatment of mercaptan-containing streams utilizing nitrogen based promoters |
US5306831A (en) * | 1992-10-15 | 1994-04-26 | Shell Oil Company | Sorbitan ester purification process |
US6491829B2 (en) * | 1999-12-24 | 2002-12-10 | Takashi Nishimoto | Method and unit for processing contaminated liquid |
WO2012123441A1 (en) * | 2011-03-14 | 2012-09-20 | Maschinenfabrik Gustav Eirich Gmbh & Co. Kg | Method for granulating or agglomerating and tool therefor |
CN103585781A (en) * | 2013-12-03 | 2014-02-19 | 姜向前 | Vertical continuous-cooling crystallization machine |
US9308470B2 (en) | 2013-03-12 | 2016-04-12 | The Chem-Pro Group Llc | Liquid-liquid extractor |
Families Citing this family (2)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
CA1266843A (en) * | 1985-04-09 | 1990-03-20 | Voest-Alpine Industrieanlagenbau Gmbh | Apparatus for continuously recovering ethanol from fermentable sugar solutions |
RU2768952C1 (en) * | 2021-01-14 | 2022-03-25 | Общество с ограниченной ответственностью "Старт-Катализатор" | Heat exchanger |
Citations (8)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
US2029688A (en) * | 1932-12-03 | 1936-02-04 | Standard Oil Co | Process and apparatus for contacting two materials |
US2139871A (en) * | 1937-08-06 | 1938-12-13 | Standard Oil Co | Process and apparatus for contacting two liquids |
GB754337A (en) * | 1953-01-23 | 1956-08-08 | Bayer Ag | Extraction apparatus |
US3082259A (en) * | 1954-11-23 | 1963-03-19 | Bayer Ag | Process for obtaining pure trimethylopropane |
US3143395A (en) * | 1959-07-14 | 1964-08-04 | Shell Oil Co | Method of operating a fluid mixer with rotating baffles |
FR1368810A (en) * | 1963-05-30 | 1964-08-07 | Zimmer Verfahrenstechnik | Extraction column with movable elements |
US3154390A (en) * | 1960-02-01 | 1964-10-27 | Kerr Mc Gee Oil Ind Inc | Process for intermixing immiscible liquids |
US3259374A (en) * | 1962-02-09 | 1966-07-05 | Henschel Werke A G | Process and apparatus for the continuous treatment of plastic materials |
-
1965
- 1965-06-08 US US462294A patent/US3351434A/en not_active Expired - Lifetime
-
1966
- 1966-06-01 IL IL25899A patent/IL25899A/en unknown
- 1966-06-07 GB GB25274/66A patent/GB1134709A/en not_active Expired
- 1966-06-08 CH CH824966A patent/CH443226A/en unknown
- 1966-06-08 DE DE19661517979 patent/DE1517979A1/en active Pending
Patent Citations (8)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
US2029688A (en) * | 1932-12-03 | 1936-02-04 | Standard Oil Co | Process and apparatus for contacting two materials |
US2139871A (en) * | 1937-08-06 | 1938-12-13 | Standard Oil Co | Process and apparatus for contacting two liquids |
GB754337A (en) * | 1953-01-23 | 1956-08-08 | Bayer Ag | Extraction apparatus |
US3082259A (en) * | 1954-11-23 | 1963-03-19 | Bayer Ag | Process for obtaining pure trimethylopropane |
US3143395A (en) * | 1959-07-14 | 1964-08-04 | Shell Oil Co | Method of operating a fluid mixer with rotating baffles |
US3154390A (en) * | 1960-02-01 | 1964-10-27 | Kerr Mc Gee Oil Ind Inc | Process for intermixing immiscible liquids |
US3259374A (en) * | 1962-02-09 | 1966-07-05 | Henschel Werke A G | Process and apparatus for the continuous treatment of plastic materials |
FR1368810A (en) * | 1963-05-30 | 1964-08-07 | Zimmer Verfahrenstechnik | Extraction column with movable elements |
Cited By (14)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
US4276701A (en) * | 1979-03-21 | 1981-07-07 | Richter Gedeon Vegyeszeti Gyar Rt | Apparatus for the drying of wet, pasty and/or fusible materials |
US4491565A (en) * | 1983-01-20 | 1985-01-01 | Uop Inc. | Countercurrent liquid-liquid contacting apparatus |
US4753722A (en) * | 1986-06-17 | 1988-06-28 | Merichem Company | Treatment of mercaptan-containing streams utilizing nitrogen based promoters |
US5306831A (en) * | 1992-10-15 | 1994-04-26 | Shell Oil Company | Sorbitan ester purification process |
US6491829B2 (en) * | 1999-12-24 | 2002-12-10 | Takashi Nishimoto | Method and unit for processing contaminated liquid |
CN103391809A (en) * | 2011-03-14 | 2013-11-13 | 德国古斯塔夫·爱立许机械制造有限公司 | Method for granulating or agglomerating and tool therefor |
WO2012123441A1 (en) * | 2011-03-14 | 2012-09-20 | Maschinenfabrik Gustav Eirich Gmbh & Co. Kg | Method for granulating or agglomerating and tool therefor |
RU2577360C2 (en) * | 2011-03-14 | 2016-03-20 | Машиненфабрик Густав Айрих Гмбх Унд Ко. Кг | Method of pelletising or nodulising and tool to this end |
AU2012228387B2 (en) * | 2011-03-14 | 2016-09-22 | Maschinenfabrik Gustav Eirich Gmbh & Co. Kg | Method for granulating or agglomerating and tool therefor |
CN103391809B (en) * | 2011-03-14 | 2016-10-26 | 德国古斯塔夫·爱立许机械制造有限公司 | For the method granulated and lump and the instrument being used for the method |
US11014055B2 (en) | 2011-03-14 | 2021-05-25 | Maschinenfabrik Gustav Eirich Gmbh & Co Kg | Method for granulating or agglomerating and tool therefor |
US9308470B2 (en) | 2013-03-12 | 2016-04-12 | The Chem-Pro Group Llc | Liquid-liquid extractor |
CN103585781A (en) * | 2013-12-03 | 2014-02-19 | 姜向前 | Vertical continuous-cooling crystallization machine |
CN103585781B (en) * | 2013-12-03 | 2016-06-08 | 姜向前 | Vertical Continuous Cooling Crystallization machine |
Also Published As
Publication number | Publication date |
---|---|
DE1517979A1 (en) | 1970-03-12 |
IL25899A (en) | 1969-09-25 |
GB1134709A (en) | 1968-11-27 |
CH443226A (en) | 1967-09-15 |
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